ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
Language
Number of Hits per Page
Default Sort Criterion
Default Sort Ordering
Size of Search History
Default Email Address
Default Export Format
Default Export Encoding
Facet list arrangement
Maximum number of values per filter
Auto Completion
Topics (search only within journals and journal articles that belong to one or more of the selected topics)
Show more topics
Feed Format
Maximum Number of Items per Feed
Permalink If you want to be able to use settings permanently, you must save your settings and then set a Bookmark to the permalink
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    facet.materialart.
    Unknown
    Comparison of Raman and Fourier Transform Infrared Spectroscopy for the Quantification of Microplastics in the Aquatic Environment (2018)
    American Chemical Society (ACS)
    In:  Environmental Science & Technology, 52 (22). pp. 13279-13288.
    Details
    Publication Date: 2020-01-02
    Description: Microplastics (MPs, 〈5 mm) have been reported as emerging environmental contaminants, but reliable data are still lacking. We compared the two most promising techniques for MP analysis, namely, Raman and Fourier transform infrared (FTIR) spectroscopy, by analyzing MPs extracted from North Sea surface waters. Microplastics 〉500 μm were visually sorted and manually analyzed by μ-Raman and attenuated total reflection (ATR)-FTIR spectroscopy. Microplastics ≤500 μm were concentrated on gold-coated filters and analyzed by automated single-particle exploration coupled to μ-Raman (ASPEx-μ-Raman) and FTIR imaging (reflection mode). The number of identified MPs 〉500 μm was slightly higher for μ-Raman (+23%) than ATR-FTIR analysis. Concerning MPs ≤500 μm, ASPEx-μ-Raman quantified two-times higher MP numbers but required a four-times higher analysis time compared to FTIR imaging. Because ASPEx-μ-Raman revealed far higher MP concentrations (38–2621 particles m–3) compared to the results of previous water studies (0–559 particles m–3), the environmental concentration of MPs ≤500 μm may have been underestimated until now. This may be attributed to the exceptional increase in concentration with decreasing MP size found in this work. Our results demonstrate the need for further research to enable time-efficient routine application of ASPEx-μ-Raman for reliable MP counting down to 1 μm.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OCEANREP)
  • 2
    facet.materialart.
    Unknown
    Grand Canonical Monte Carlo Simulations on Phase Equilibria of Methane, Carbon Dioxide, and Their Mixture Hydrates (2018)
    American Chemical Society (ACS)
    In:  The Journal of Physical Chemistry B, 122 (42). pp. 9724-9737.
    Details
    Publication Date: 2021-01-08
    Description: The cage occupancy plays a crucial role in the thermodynamic stability of clathrate hydrates and is an important quantity for understanding the CO2–CH4 replacement phenomenon. In this work, the occupancy isotherms of pure CH4, pure CO2, and their mixture in sI and sII hydrates are studied by GCMC + MD simulations. The adsorption of CH4 and CO2 + CH4 in the sI and sII hydrates can be categorized as the one-site Langmuir type. The calculated occupancy ratio θL/θS and the abundance ratio of CO2 to CH4 vary with the temperature and pressure, which provide the prerequisite information for the prediction of CH4 recovery yield at different conditions in the CO2–CH4 gas exchange process. The phase equilibria of clathrate hydrates of pure gases and mixtures are explored and the corresponding heat of dissociation and hydration numbers are determined. The current investigation provides new perspectives to understand the mechanism behind the gas adsorption behavior of clathrate hydrates.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OCEANREP)
  • 3
    facet.materialart.
    Unknown
    Use of Waste-Derived Biochar to Remove Copper from Aqueous Solution in a Continuous-Flow System (2017)
    American Chemical Society (ACS)
    In:  Industrial & Engineering Chemistry Research, 56 (44). pp. 12755-12762.
    Details
    Publication Date: 2020-02-06
    Description: The discharges from industrial processes constitute the main source of copper contamination in aqueous ecosystems. In this study we investigated the capacity of different types of biochar (derived from chicken manure, eucalyptus, corncob, olive mill and pine sawdust) to remove copper from aqueous solution in a continuous-flow system. The flow rate of the system strongly influenced the amount of copper retained. The adsorption to the corncob biochar varied from 5.51 to 3.48 mg Cu g-1 as the flux decreased from 13 to 2.5 mL min-1. The physicochemical characteristics of biochar determine the copper retention capacity and the underlying immobilization mechanisms. Biochars with high inorganic contents retain the largest amounts of copper and may be suitable for using in water treatment systems to remove heavy metals. The copper retention capacity of the biochars ranged between ~1.3 and 26 mg g-1 and varied in the following order: chicken manure 〉 olive mill 〉〉 corncob 〉 eucalyptus 〉 sawdust pine.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OCEANREP)
  • 4
    facet.materialart.
    Unknown
    Methane Bubble Size Distributions, Flux, and Dissolution in a Freshwater Lake (2017)
    American Chemical Society (ACS)
    In:  Environmental Science & Technolog, 51 (23). pp. 13733-13739.
    Details
    Publication Date: 2020-02-06
    Description: The majority of methane produced in many anoxic sediments is released via ebullition. These bubbles are subject to dissolution as they rise, and dissolution rates are strongly influenced by bubble size. Current understanding of natural methane bubble size distributions is limited by the difficulty in measuring bubble sizes over wide spatial or temporal scales. Our custom optical bubble size sensors recorded bubble sizes and release timing at 8 locations in Upper Mystic Lake, MA continuously for 3 months. Bubble size distributions were spatially heterogeneous even over relatively small areas experiencing similar flux, suggesting that localized sediment conditions are important to controlling bubble size. There was no change in bubble size distributions over the 3 month sampling period, but mean bubble size was positively correlated with daily ebullition flux. Bubble data was used to verify the performance of a widely used bubble dissolution model, and the model was then used to estimate that bubble dissolution accounts for approximately 10% of methane accumulated in the hypolimnion during summer stratification, and at most 15% of the diffusive air–water–methane flux from the epilimnion.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OCEANREP)
  • 5
    facet.materialart.
    Unknown
    Continuous Seasonal River Ebullition Measurements Linked to Sediment Methane Formation (2015)
    American Chemical Society (ACS)
    In:  Environmental Science & Technology, 49 (22). pp. 13121-13129.
    Details
    Publication Date: 2019-10-24
    Description: Laboratory sediment incubations and continuous ebullition monitoring over an annual cycle in the temperate Saar River, Germany confirm that impounded river zones can produce and emit methane at high rates (7 to 30 (g CH4 m–3 d–1) at 25 °C and 270 to 700 (g CH4 m–2 yr–1), respectively). Summer methane ebullition (ME) peaks were a factor of 4 to 10 times the winter minima, and sediment methane formation was dominated by the upper sediment (depths of 0.14 to 0.2 m). The key driver of the seasonal ME dynamics was temperature. An empirical model relating methane formation to temperature and sediment depth, derived from the laboratory incubations, reproduced the measured daily ebullition from winter to midsummer, although late summer and autumn simulated ME exceeded the observed ME. A possible explanation for this was substrate limitation. We recommend measurements of methanogenically available carbon sources to identify substrate limitation and help characterize variation in methane formation with depth and from site to site.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OCEANREP)
  • 6
    facet.materialart.
    Unknown
    High Pressure Rheology of Hydrate Slurries Formed from Water-in-Mineral Oil Emulsions (2014)
    American Chemical Society (ACS)
    In:  Industrial & Engineering Chemistry Research, 53 (17). pp. 6998-7007.
    Details
    Publication Date: 2018-01-03
    Description: Structure I methane hydrates are formed in situ from water-in-mineral oil emulsions in a high pressure rheometer cell. Viscosity is measured as hydrates form, grow, change under flow, and dissociate. Experiments are performed at varying water volume fraction in the original emulsion (0–0.40), temperature (0–6 °C), and initial pressure of methane (750–1500 psig). Hydrate slurries exhibit a sharp increase in viscosity upon hydrate formation, followed by complex behavior dictated by factors including continued hydrate formation, shear alignment, methane depletion/dissolution, aggregate formation, and capillary bridging. Hydrate slurries possess a yield stress and are shear-thinning fluids, which are described by the Cross model. Hydrate slurry viscosity and yield stress increased with increasing water volume fraction. As driving force for hydrate formation decreases (increasing temperature, decreasing pressure), hydrate slurry viscosity increases, suggesting that slower hydrate formation leads to larger and more porous aggregates. In total, addition of water to a methane saturated oil can cause more than a fifty-fold increase in viscosity if hydrates form.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OCEANREP)
  • 7
    facet.materialart.
    Unknown
    Structures of the Dimeric and Monomeric Chromanones, Gonytolides A–C, Isolated from the FungusGonytrichumsp. and Their Promoting Activities of Innate Immune Responses (2011)
    American Chemical Society (ACS)
    In:  Organic Letters, 13 (17). pp. 4624-4627.
    Details
    Publication Date: 2018-02-20
    Description: Innate immunity is the front line of self-defense against microbial infection. After searching for natural substances that regulate innate immunity using an ex vivo Drosophila culture system, we identified a novel dimeric chromanone, gonytolide A, as an innate immune promoter from the fungus Gonytrichum sp. along with gonytolides B and C. Gonytolide A also increased TNF-α-stimulated production of IL-8 in human umbilical vein endothelial cells.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OCEANREP)
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...