ALBERT

Beschreibung: Airglow and chemical processes in the terrestrial mesosphere and lower thermosphere are reviewed, and initial parameterizations of the processes applicable to multidimensional models are presented. The basic processes by which absorbed solar energy participates in middle atmosphere energetics for absorption events in which photolysis occurs are illustrated. An approach that permits the heating processes to be incorporated in numerical models is presented.

Beschreibung: Attention is given to a program to compare stratospheric models and measurements to calculate the atmospheric effects of emissions of a projected fleet of High Speed Civil Transports on the stratosphere is presented. The goals of the effort is to establish a standard set of atmospheric measurements that can be used to test the reliability of atmospheric chemistry models, develop a method for evaluating model/data comparisons, and direct the first major international stratospheric model/data comparison.

Beschreibung: Multispectra aerosol extinction data for the fall and spring of 1987 measured by the SAGE II sensor are employed to determine the physical characteristics of aerosols within the springtime Antarctic polar vortex. Attention is given to the physical processes that give rise to the apparent springtime 'cleansing' of the Antarctic stratosphere. The inferred vertical and radial structure compare favorably with in situ measurements but yield a previously unavailable 2D structure to the distribution of aerosols within the polar vortex. The springtime 'cleansing' of the Antarctic stratosphere is found to be a result of both large-scale subsidence and the preferential removal of large particles by the nucleation and subsequent sedimentation of polar stratospheric clouds.

Beschreibung: The NASA Langley 3D GCM chemical transport model is used to investigate the distribution of atmospheric N2O up to 60 km altitude. The transport characteristics of the model is evaluated without the complications of a detailed chemical formulation for all of the relevant stratospheric minor constituents. Interpretation of the yearly average zonal mean N2O distribution in terms of transport by the yearly averaged meridional circulation and stratospheric photochemical loss indicates large regions in the Northern Hemisphere stratosphere where dynamical mixing apparently plays a large role in maintaining the N2O distribution. In these regions, slopes of the N2O mixing ratio isopleths are maintained by competition between advection by the meridional circulation acting to steepen and dynamical mixing acting to flatten the slopes.

Beschreibung: An extended version of the Nimbus 7/TOMS ozone data set from the period January 1, 1979 to December 31, 1991 is presented. It is shown that the ozone-trend data indicate that regions of enhanced ozone depletion rates have formed at middle and high latitudes during recent years. The seasonal dependence and geographical extent of the enhanced ozone-depletion rates for the Northern and Southern hemispheres are examined. The variability of the long-term ozone trend determination is discussed via consideration of the differences among 11-, 12-, and 13-yr trend calculations. The effects of the Mount Pinatubo eruption and other volcanic eruptions on the TOMS equatorial zonal average ozone measurements, and its influence on long-term trend determinations are discussed. On the basis of a determination of the aerosol phase function using TOMS data, the effect of stratospheric aerosols on determination of ozone amounts from TOMS are shown to be less than 1 percent.

Beschreibung: The HALOE experiment measures vertical profiles of aerosol extinction at five infrared wavelengths. Four of these observations are obtained using a combination of gas filter and broadband radiometer measurements in bands of HF, HCl, CH4, and NO centered at wavelengths of 2.45, 3.40, 3.45, and 5.26 microns, respectively. The fifth is obtained using broadband radiometer measurements of CO2 transmission at 2.79 microns. Error analysis shows that the random extinction uncertainties are generally less than 10 percent in the aerosol layer, increasing to over 20 percent at the profile tops. HALOE spectral extinction measurements are shown to be consistent with predicted spectral extinction for stratospheric sulfate aerosol. Profile comparisons between HALOE and independent sources result in generally good agreement in the shape and magnitude of peak extinction and the altitude where the peak extinction occurs. In addition, global aerosol distributions obtained from the data are consistent with expected aerosol morphology. Although the validation is preliminary, the HALOE aerosol data appear to be of excellent quality and to accurately represent optical characteristics and distribution of the aerosols.

Beschreibung: Regular measurements of stratospheric ozone concentration profiles have been made at Table Mountain, California, since February 1988. During the period up to the end of December 1991, 435 independent profiles were measured by the differential absorption lidar technique. These long-term results and an evaluation of their quality are presented in this paper. The large number of measurements made allowed the development of a short-term, 4-year, climatology of the ozone concentration profile at this specific location (34.4 deg N, - 117.7 deg W). The effects of the eruption of Mount Pinatubo were not observed in the lidar measurements until August 1991, so that the results presented here can essentially be considered as the pre-Pinatubo climatology.

Beschreibung: The mass and number relationships occurring within the atmospheric dimethylsulfide/cloud condensation nuclei (CCN)/climate system, using simultaneous measurements of particulate phase mass size distributions of nss SO4(2-), methanesulfonic acid (MSA), and NH4(+); number size distributions of particles having diameters between 0.02 and 9.6 microns; CCN concentrations at a supersaturation of 0.3 percent; relative humidity; and temperature, obtained for the northeastern Pacific Ocean in April and May 1991. Based on these measurements, particulate nss SO4(2-), MSA, and NH4(+) mass appeared to be correlated with both particle effective surface area and number in the accumulation mode size range (0.16 to 0.5 micron). No correlations were found in the size range below 0.16 micron. A correlation was also found between nss SO4(2-) mass and the CCN number concentration, such that a doubling of the SO4(2-) mass corresponded to a 40 percent increase in the CCN number concentration. However, no correlation was found between MSA mass and CCN concentration.

Beschreibung: Column ozone measurements obtained from a Spin-scan Ozone Imager (SOI) aboard the Dynamics Explorer I (DE-I) satellite are discussed. The orbital geometry has many features similar to the Molniya satellite orbits. The ozone imagery obtained from DE-I are unique in being synoptic views of a region of continental scale for a period of a few hours. A brief description of the instrument, data, and orbit is followed by a discussion of some applications of DE-I data and the potential usefulness of an ozone imager aboard a satellite in a Molniya-type orbit.

Beschreibung: The Colima Volcanic Complex at the western end of the Mexican Volcanic Belt is the most active andesitic volcano in Mexico. Short-wavelength infrared data from the Landsat Thematic Mapper satellite were used to determine the temperature and fractional area of radiant picture elements for two January data acquisitions in 1985 and 1986. The 1986 data showed four 28.5 m by 28.5 m pixels (picture elements) whose hot subpixel components had temperatures ranging from 511-774 C and areas of 1.8-13 sq m. The 1985 data had no radiating areas above background temperatures. Ground observations and measurements in November 1985 and February 1986 reported the presence of hot fumaroles at the summit with temperatures of 135-895 C. This study demonstrates the utility of satellite data for monitoring volcanic activity.

Beschreibung: The paper discusses the atmospheric distribution of natural and man-made nonmethane hydrocarbons (NMHCs), the major species of airborne NMHCs, and their sources and sinks. Particular attention is given to the techniques for measuring atmospheric NMHCs; diurnal and seasonal variations of atmospheric NMHCs and differences between rural, urban, and marine environments; latitudinal and vertical distributions; and available stratospheric NMHC measurements. A formula defining the atmospheric lifetime of a NMHC from its reaction rates with OH and O3 is presented.

Beschreibung: The published ocean tidal angular momentum results of Seiler (1991) are used to predict the effects of the most important semidiurnal, diurnal, and long period ocean tides on the earth's rotation. The separate, as well as combined, effects of ocean tidal currents and sea level height changes on the length-of-day, UT1, and polar motion are computed. The predicted polar motion results reported here account for the presence of the free core nutation and are given in terms of the motion of the celestial ephemeris pole so that they can be compared directly to the results of observations. Outside the retrograde diurnal tidal band, the summed effect of the semidiurnal and diurnal ocean tides studied here predict peak-to-peak polar motion amplitudes as large as 2 mas. Within the retrograde diurnal tidal band, the resonant enhancement caused by the free core nutation leads to predicted polar motion amplitudes as large as 9 mas.

Beschreibung: We compute the polar-motion excitation function due to the atmospheric angular momentum (AAM) for both IB (inverted-barometer) and non-IB cases, as well as the excitation function from geodetically observed Earth orientation data for the period 1980-1990. The two are then compared in studying the AAM contribution to the polar motion excitation. The polar drifts with periods longer than about two years have similar characteristics, but the comparison is inconclusive because of data uncertainties. For the seasonal wobble excitation, the agreement is poor except for the prograde annual wobble, indicating the influence of other geophysical excitations than AAM. For the Chandler wobble excitation, a correlation coefficient of 0.53 for non-IB and 0.58 for IB are found for 1986-1990. Together with a coherence spectral analysis, they clearly demonstrate a strong contribution of AAM to the Chandler wobble excitation.

Beschreibung: It is contended that statistical data do not support the claim of Gosling et al. (1991) to the effect that the initial speed of a solar wind driver gas close to the sun appears to be the most crucial factor in determining if an earthward direct event will be effective in exciting a large geomagnetic disturbance. It is argued that the time intervals are much too large to observe the storm-time B sub Z dependence. Gosling et al. reply that this comment is based on a serious misunderstanding of their conclusions.

Beschreibung: Total Ozone Mapping Spectrometer (TOMS) measurements of equatorial total ozone following the eruption of Mt. Pinatubo show a decrease of up to 6 percent over climatology. Ozone losses begin approximately a month following the eruption, consistent with the time required for the SO2 to convert to sulfuric acid aerosol. The thick aerosol layer interferes with the TOMS retrieval, but this interference is small and easily accounted for in the retrieval. Ozone values remain below climatology until December, 1991. Ozonesonde data from Natal, Brazil taken before and two months after the eruption support TOMS observations of ozone loss. These sondes show that the ozone loss region is confined to a 2-3 km thick layer between 24 and 28 km.

Beschreibung: An improved model of the Earth's gravitational field is developed from a combination of conventional satellite tracking, satellite altimeter measurements, and surface gravimetric data (GEM-T3). This model gives improved performance for the computation of satellite orbital effects as well as a superior representation of the geoid from that achieved in any previous Goddard Earth Model. The GEM-T3 model uses altimeter data directly to define the orbits, geoid, and dynamic height fields. Altimeter data acquired during the GEOS-3 (1975-1976), SEASAT (1978), and GEOSAT (1986-1987) missions were used to compute GEM-T3. In order to accommodate the non-gravitational signal mapped by these altimeters, spherical harmonic models of the dynamic height of the ocean surface were recovered for each mission simultaneously with the gravitational field. The tracking data utilized in the solution includes more than 1300 arcs of data encompassing 31 different satellites. The observational data base is highly dependent on SLR, but also includes TRANET Doppler, optical, S-Band average range-rate and satellite-to-satellite tracking acquired between ATS-6 and GEOS-3. The GEM-T3 model has undergone extensive error calibration.

Beschreibung: This article describes the design and initial tests of the GPS portion of a system for making seafloor geodesy measurements. In the planned system, GPS antennas on a floating platform will be used to measure the location of an acoustic transducer, attached below the platform, which interrogates an array of transponders on the seafloor. Since the GPS antennas are necessarily some distance above the transducer, a short-baseline GPS interferometer consisting of three antennas is used to measure the platform's orientation. A preliminary test of several crucial elements of the system was performed. The test involved a fixed antenna on the pier and a second antenna floating on a buoy about 80 m away. GPS measurements of the vertical component of this baseline, analyzed independently by two groups using different software, agree with each other and with an independent measurement within a centimeter. The first test of an integrated GPS/acoustic system took place in the Santa Cruz Basin off the coast of southern California in May 1990. In this test a much larger buoy, designed and built at SIO, was equipped with three GPS antennas and an acoustic transducer that interrogated a transponder on the ocean floor. Preliminary analysis indicates that the horizontal position of the transponder can be determined with a precision of about a centimeter.

Beschreibung: Paleomagnetic data from the Mojave Desert around Barstow, California, suggest 55 to 75 deg of clockwise rotation of this area in earliest Miocene time, followed by 23 deg of counterclockwise rotation in the Early Miocene, and no rotation after 18 Ma. Earliest Miocene clockwise rotation of the Barstow area is suggested by data from nine sites in the Oligocene-Miocene Lane Mountain Quartz Latite and Jackhammer Formation and may be related to oroclinal bending of the southern Sierra Nevada batholith. Data from 13 sites in the Early Miocene Pickhandle Formation indicate counterclockwise rotation, which coincides with Early Miocene E-NE - W-SW extension and detachment faulting in the Mojave Desert. These results suggest that Miocene extension in the Mojave Desert is related to similarly oriented extension in the Colorado River extensional corridor. Early Miocene to Pliocene rocks of the Andesite and Dacite of the Calico Mountains, Barstow Formation, Andesite of Murphy's Well, and Black Mountain Basalt show no evidence for significant rotation of the Barstow area after 18 Ma. Most other paleomagnetic data from elsewhere in the Mojave are consistent with a lack of significant post-18 Ma rotations, suggesting that post-10 Ma right-lateral faulting there has produced relatively little crustal rotation.

Beschreibung: This study investigates the energy budget in the current disruption region of the magnetotail, coincident with a pre-onset thin current sheet, around substorm onset time using published observational data and theoretical estimates. We find that the current disruption/dipolarization process typically requires energy inflow into the primary disruption region. The disruption dipolarization process is therefore endoenergetic, i.e., requires energy input to operate. Therefore we argue that some other simultaneously operating process, possibly a large scale magnetotail instability, is required to provide the necessary energy input into the current disruption region.

Beschreibung: The rate at which molecular oxygen absorbs radiation in the O2(X3Sigma-g - b1Sigma-g) transition is calculated using a line-by-line radiative transfer model. This rate is critical to the determination of the population of the O2(b1Sigma-g) state required for studies of the O2(b1Sigma-g - X3Sigma-g) dayglow, the O2(a1Delta-g - X3Sigma-g) dayglow, and possibly the rates of oxidation of H2 and N2O. Previous evaluations of this rate (which is sometimes called the g-factor) have significantly overestimated its value. The rate is tabulated as a function of altitude, pressure, and solar zenith angle.

Beschreibung: Turbulence in stably and unstably stratified media is studied, and the results are used to construct a subgrid simulation (SGS) model for use in large eddy simulation (LES). It was found that, although the assumption of inertiality of the subgrid scales is reasonable for the case of unstable stratification, it ceases to be so in the case of stable stratification, where gravity removes kinetic energy from the eddies: the generation of gravity waves becomes the dominant physical process, with dissipation relegated to higher wavenumbers. Preliminary results show that the total kinetic energy dissipation length scale increases with stability, in accordance with LES results but in disagreement with Deardorff's model that suggests a decrease of all dissipation scales in presence of stratification.

Beschreibung: Data obtained from the Wind and Temperature Spectrometer on the Dynamics Explorer during high solar activity show new evidence for the presence of vertical winds of a significant magnitude in the equatorial thermosphere. They reveal a latitudinal structure that can be related to the recently discovered equatorial temperature and wind anomaly (ETWA). In the local evening hours, the vertical winds usually are downward around the dip equator and collocated with the temperature minimum of ETWA. In general, they are upward at about 24 deg dip latitude away from the dip equator and are collocated with the ETWA temperature crests. The magnitude of the vertical winds is in the 10-40 m/s range. It is proposed that the temperature and pressure ridges, formed by the excess ion drag on the zonal winds around the two crests and ordered by the relatively lower ion drag at the trough of the well known equatorial ionization anomaly, drive a new wind system in the meridional plane and that the measured vertical winds form part of this wind system.

Beschreibung: The Halogen Occultation Experiment (HALOE) uses solar occultation to measure vertical profiles of O3, HCl, HF, CH4, H2O, NO, NO2, aerosol extinction, and temperature versus pressure with an instantaneous vertical field of view of 1.6 km at the earth limb. Latitudinal coverage is from 80 deg S to 80 deg N over the course of 1 year and includes extensive observations of the Antarctic region during spring. The altitude range of the measurements extends from about 15 km to about 60-130 km, depending on channel. Experiment operations have been essentially flawless, and all performance criteria either meet or exceed specifications. Internal data consistency checks, comparisons with correlative measurements, and qualitative comparisons with 1985 atmospheric trace molecule spectroscopy (ATMOS) results are in good agreement. Examples of pressure versus latitude cross sections and a global orthographic projection for the September 21 to October 15, 1992, period show the utility of CH4, HF, and H2O as tracers, the occurrence of dehydration in the Antarctic lower stratosphere, the presence of the water vapor hygropause in the tropics, evidence of Antarctic air in the tropics, the influence of Hadley tropical upwelling, and the first global distribution of HCl, HF, and NO throughout the stratosphere. Nitric oxide measurements extend through the lower thermosphere.

Beschreibung: Literature data on mid-latitude balloon soundings of CO2 and aircraft sampling in the lower polar stratosphere during the winter are used as a fundamental test of tracer transport in the middle atmospheric version of the GISS GCM (Rind et al., 1990) to predict the propagation into the stratosphere of the annual increase and annual cycle of CO2. The results predict significant propagation of the CO2 annual cycle into the lower stratosphere, an effect which must be accounted for when interpreting observations.

Beschreibung: The role of airglow losses in reducing the efficiency of solar heating in the Hartley, Huggins, and Chappuis bands of ozone in the Herzberg, Ly alpha, Schumann-Runge continuum, and in Schumann-Runge bands of molecular oxygen is investigated together with the role of heating due to seven chemical reactions in the middle atmosphere. The results of calculations of bulk efficiencies demonstrate that airglow and chemiluminescent emission significantly reduce the amount of energy available for heat throughout the mesosphere and lower thermosphere.

Beschreibung: Magnetic field and energetic particle observations from six spacecraft in the near-earth magnetotail are described and combined with ground magnetograms to document for the first time the magnetospheric substorm activity during a 30-hour long transit of an interplanetary cloud at 1 AU. During an earlier 11-hr interval when B(z) was continuously positive, the magnetosphere was quiescent, while in a later 18-hr interval when B(z) was uninterruptedly negative a large magnetic storm was set off. In the latter interval the substorm onsets recurred on average every 50 min. Their average recurrence frequency remained relatively undiminished even when the magnetic cloud B(z) and other measures of the interplanetary energy input decreased considerably. These results concur with current models of magnetospheric substorms based on deterministic nonlinear dynamics. The substorm onset occurred when the cloud's magnetic field had a persistent northward component but was predominantly westward pointing.

Beschreibung: High time resolution interplanetary magnetic field and plasma measurements of an interplanetary magnetic cloud and its interaction with the earth's magnetosphere on January 14/15, 1988 are interpreted and discussed. It is argued that the data are consistent with the theoretical model of magnetic clouds as flux ropes of local straight cylindrical geometry. The data also suggest that this cloud is aligned with its axis in the ecliptic plane and pointing in the east-west direction. Evidence consisting of the intensity and directional distribution of energetic particle in the magnetic cloud argues in favor of the connectedness of the magnetic field lines to the sun's surface. The intensities of about 0.5 MeV ions is rapidly enhanced and the particles stream in a collimated beam along the magnetic field preferentially from the west of the sun. The particles travel form a flare site along the cloud magnetic field lines, which are thus presumably still attached to the sun.

Beschreibung: The paper extends the servo model of Rishbeth et al. (1978) and applies it to fit the height and plasma density of the nighttime F2 layer, as measured from the Arecibo Observatory during solar maximum by Burnside (1984). The model equations are integrated numerically to fit the observed peak height and density. The model adequately reproduces the observed behavior of the F2 layer. The additional terms in the extended servo-height equation affect the peak height computation by no more than 10 percent on average. The applied current is generally eastward though it becomes westward during the postmidnight collapse or descent of the layer. Differences between model and optically measured meridional wind speeds appear to be related to the presence of large vertical shears in the wind. The observed peak density can be reproduced to within 20 to 40 percent accuracy. Variable plasmaspheric fluxes of the order of 10 exp 13/sq m s contribute to the maintenance and variability of the nighttime peak density.

Beschreibung: The formation of the auroral bulge is investigated on the basis of all-sky TV auroral data with high spatial and temporal resolution. Ways in which the discrete auroral structures within the poleward expanding bulge develop systematically toward the west, the east, and also equatorward from a localized breakup region are shown. Auroral structure at the western end of the bulge (a surge) develops with clockwise rotation as viewed along the magnetic field direction. At the eastern part of the bulge, thin auroral features propagate eastward from the breakup region. Around the central meridian of the bulge, auroral features expand equatorward and become north-south aligned (the N-S aurora). The N-S aurora and the eastward propagating aurora develop into diffuse and pulsating aurora after the expansion. It is suggested that these discrete auroral structures in the bulge develop along the plasma streamlines in a localized distorted two-cell equipotential distribution.

Beschreibung: A retrieval method was developed to estimate the solar backscatter ultraviolet (SBUV) satellite albedo for the ozone profiler wavelengths using ground-based ultraviolet measurements. For the present investigation the Umkehr was used as the ground-based ultraviolet measurement. Simulated SBUV data and Umkehr data theoretically computed from a priori ozone profiles observed by the SAGE II satellite were used to develop the retrieval algorithm and to test its capability. The test indicated that albedos for the SBUV ozone profiler wavelengths should allow estimates to a precision of +/- 5 percent or better, depending on the accuracy of the ultraviolet measurement. Retrievals using actual Umkehr observations were also performed to provide a preliminary look at the magnitude and annual variation of retrieved albedos. A case study was performed, comparing retrieved albedos with SBUV-measured albedos. The SBUV albedo change was seen to be approximately twice as large as the albedo changes estimated by the Umkehr method. Results of the investigation suggest that the method of estimation may be useful for determining the drift rate of the SBUV calibration.

Beschreibung: Displacements observed for the Landers earthquake indicate that the depth of the bottom of the rupture is shallower towards the northern end. Displacements were dominantly symmetric and the rupture extended farther south on the Johnson Valley fault than has been mapped on the basis of surface ground offsets. The combined geodetic moment for the Landers and Big Bear earthquakes agrees well with teleseismic estimates.

Beschreibung: The correlation of long-wavelength gravity anomalies in northern Eurasia with seismic velocity anomalies in the upper mantle reverses in sign between western and eastern Eurasia. The difference between western and eastern Eurasia can be explained by the presence of a low-viscosity zone in the uppermost mantle beneath eastern Eurasia that is absent to the west. The location of the lateral change in viscosity corresponds with the geologic boundary between the older shields and platforms of the Baltics, Russia, and Siberia and the younger, geologically active mountain belts of eastern Asia. This relation provides evidence that differences in the strength of the upper mantle control the locus of intracontinental deformation.

Beschreibung: The paper investigates the impact of the Mt. Pinatubo eruptions on the total column ozone measured from the Nimbus 8 TOMS and the NOAA-11 SBUV/2 spectrometers. Within a few months after the eruptions, the total column ozone decreased by 5-6 percent in the tropics, 3-4 percent at midlatitudes, and 6-9 percent at high latitudes in the Northern Hemisphere. After the effects of quasi-biennial oscillations and interannual variability are taken into account, the decrease in the column ozone attributed to volcanic eruptions at these latitudes may not be more than 2-4 percent. The most noticeable effect on the Pinatubo eruptions, as observed during the El Chichon period, is the breakdown of the phase relation between ozone and temperature. This is attributed to additional heating in the lower stratosphere caused by volcanic aerosols.

Beschreibung: Continuous optical observations of cusp/cleft auroral activities within approximately equal to 09-15 MLT and 70-76 deg magnetic latitude are studied in relation to changes in solar wind dynamic pressure and interplanetary magnetic field (IMF) variability. The observed latitudinal movements of the cusp/cleft aurora in response to IMF B(sub z) changes may be explained as an effect of a variable magnetic field intensity in the outer dayside magnetosphere associated with the changing intensity of region 1 field-aligned currents and associated closure currents. Ground magnetic signatures related to such currents were observed in the present case (January 10, 1993). Strong, isolated enhancements in solar wind dynamic pressure (Delta p/p is greater than or equal to 0.5) gave rise to equatorward shifts of the cusp/cleft aurora, characteristic auroral transients, and distinct ground magnetic signatures of enhanced convection at cleft latitudes. A sequence of auroral events of approximately equal to 5-10 min recurrence time, moving eastward along the poleward boundary of the persistent cusp/cleft aurora in the approximately equal to 10-14 MLT sector, during negative IMF B(sub z) and B(sub y) conditions, were found to be correlated with brief pulses in solar wind dynamic pressure (0.1 is less than Delta p/p is less than 0.5). Simultaneous photometer observations from Ny Alesund, Svalbard, and Danmarkshavn, Greenland, show that the events often appeared on the prenoon side (approximately equal to 10-12 MLT), before moving into the postnoon sector in the case we study here, when IMF B(sub y) is less than 0. In other cases, similar auroral event sequences have been observed to move westward in the prenoon sector, during intervals of positive B(sub y). Thus a strong prenoon/postnoon asymmetry of event occurence and motion pattern related to the IMF B(sub y) polarity is observed. We find that this category of auroral event sequence is stimulated bursts of electron precipitation that originate from magnetosheath plasma that has accessed that dayside magnetosphere in the noon or near-noon sector, possibly at high latitudes, partly governed by the IMF orientation as well as by solar wind dynamic pressure pulses.

Beschreibung: In late July and early August of 1991, a major suborbital scientific campaign (NLC-91) involving scientists from eight countries was conducted at ESRANGE, Kiruna, Sweden and at Heiss Island, Russia. The purpose of the program was to investigate the chemical, dynamical, and electrodynamical properties of the polar summer mesosphere. Thirty one rocket flights were coordinated with two coherent radar facilities, European Incoherent Scatter (EISCAT) and Cornell Univesity Portable Radar Interferometer (CUPRI), and with other ground-based observatories and facilities. This permitted direct comparison between the in situ measurements and those obtained by remote sensing of the mesosphere via continuous ground-based monitoring. The primary objectives of the campaign were to study noctilucent clouds (NLCs) and polar mesospheric summer echoes (PMSEs), including their possible relationship to local aerosols and/or small scale turbulence. This overview describes the scientific program, discusses the geophysical conditions during launch activities, and reviews some of the preliminary results. More detailed results can be found in the papers which follow.

Beschreibung: Analysis of Upper Altmosphere Research Satellite (UARS) Microwave Limb Sounder (MLS) observations in early January 1992 shows a clear relationship between predicted polar stratospheric cloud formation along the back trajectory and elevated ClO amounts. These findings are in good agreement with aircraft observations. The MLS observed variation of ClO amounts within the vortex also fits the pattern of ClO change as a result of air parcel solar exposure and nitric acid photolysis. Outside the polar vortex, the occasional highly elevated ClO appear statistically consistent with MLS measurement noise.

Beschreibung: Stratospheric aerosols, collected near 19 km altitude on wire impactors over western North America from August 20, 1991 to May 11, 1993, show strong influence of the June 1991 Mt. Pinatubo eruption. Lognormal size distributions are bimodal; each of the mode radii increases and reaches maximum value at about 15 months after eruption. The second (large particle) mode becomes well developed then, and about 40% of the droplets are larger than 0.4 micron radius. The eruption of Mt. Spurr (Alaska) may also have contributed to this. Sulfate mass loading decays exponentially (e-folding 216 days), similar to El Chichon. Silicates are present in samples only immediately after eruption. Two years after eruption, sulfate mass loading is about 0.4 micrograms/cu m, about an order of magnitude higher than background pre-volcanic values. Aerosol size distributions are still bimodal with a very well-defined large droplet mode.

Beschreibung: Comparisons are presented between Nimbus 7 LIMS (Limb Infrared Monitor of the Stratosphere) mapped temperatures and both Datasonde and sphere in situ rocketsonde temperature measurements. With this approach up to 666 LIMS/Datasonde pairs were obtained for various pressure levels to look for small biases in LIMS temperatures as a function of altitude, latitude and season. Between 10-1 hPa LIMS and Datasonde agree everywhere to better than +/- 2 K with the exception of a warm bias of about 3 K at 2 hPa at high latitudes. However, LIMS is colder than the Datasonde by about 4 K at 0.4 hPa and by about 8-10 K at 0.1 hPa. When compared with the more accurate sphere temperatures the bias at 0.1 hPa is reduced by nearly one-half. These results indicate that the LIMS zonal mean constituent profiles are nearly free of temperature bias, except perhaps at 0.1 hPa.

Beschreibung: The carbon monoxide (CO) reference scale created by the National Oceanic and Atmospheric Administration/Climate Monitoring and Diagnostics Laboratory (NOAA/CMDL) is used to quantify measurements of CO in the atmosphere, calibrate standards of other laboratories and to otherwise provide reference gases to the community measuring atmospheric CO. This reference scale was created based upon a set of primary standards prepared by gravimetric methods at CMDL and has been propagated to a set of working standards. In this paper we compare CO mixing ratios assigned to the working standards by three approaches: (1) calibration against the original gravimetric standards, (2) calibration using only working standards as the reference gas, and (3) calibration against three new gravimetric standards prepared to CMDL. The agreement between these values was typically better than 1%. The calibration histories of CMDL working standards are reviewed with respect to expected rates of CO change in the atmosphere. Using a Monte Carlo approach to simulate the effect of drifting standards on calculated mixing ratios, we conclude that the error solely associated with the maintenance of standards will limit the ability to detect small CO changes in the atmosphere. We also report results of intercalibration experiments conducted between CMDL and the Diode Laser Sensor Group (DACOM) at the NASA Langley Research Center (Hampton, Virginia), and CMDL and the Fraunhofer-Institut (Garmisch-Partenkirchen, Germany). Each laboratory calibrated several working standards for CO using their reference gases, and these results were compared to calibrations conducted by CMDL. The intercomparison of eight standards (CO concentrations between approximately 100 and approximately 165 ppb) by CMDL and NASA agreed to better than +/- 2%. The calibration of six standards (CO concentrations between approximately 50 and approximately 210 ppb) by CMDL and the Fraunhofer-Institut agreed to within +/- 2% for four standards, and to within +/- 5% for all six standards.

Beschreibung: Measurements of the ratio OH/HO2, NO, O3, ClO, and BrO were obtained at altitudes from 15-20 km and latitudes from 15-60 deg N. A method is presented for interpreting the rates of chemical transformations that (1) are responsible for over half the ozone removal rate in the lower stratosphere via reactions of HO2; and (2) control the abundance of HO2 through coupling to nitrogen and halogen radicals. The results show our understanding of the chemical reactions controlling the partitioning of OH and HO2 is complete and accurate and that the potential effects of 'missing chemistry' are strickly constrained in the region of the atmosphere encompassed by the observations. The analysis demonstrates that the sensitivity of the ratio OH/HO2 to changes in NO is described to within 12% by current models. This reduces by more than a factor of 2 the effect of uncertainty in the coupling of hydrogen and nitrogen radicals on the analysis of the potential effects of perturbations to odd notrogen in the lower statosphere.

Beschreibung: The northern piedmont of the western Kunlun mountains (Xinjiang, China) is marked at its easternmost extremity, south of the Hotan-Qira oases, by a set of normal faults trending N50E for nearly 70 km. Conspicuous on Landsat and SPOT images, these faults follow the southeastern border of a deep flexural basin and may be related to the subsidence of the Tarim platform loaded by the western Kunlun northward overthrust. The Hotan-Qira normal fault system vertically offsets the piedmont slope by 70 m. Highest fault scarps reach 20 m and often display evidence for recent reactivations about 2 m high. Successive stream entrenchments in uplifted footwallls have formed inset terraces. We have leveled topographic profiles across fault scarps and transverse abandoned terrace risers. The state of degradation of each terrace edge has been characterized by a degradation coefficient tau, derived by comparison with analytical erosion models. Edges of highest abandoned terraces yield a degradation coefficient of 33 +/- 4 sq.m. Profiles of cumulative fault scarps have been analyzed in a similar way using synthetic profiles generated with a simple incremental fault scarp model.

Beschreibung: Previous observations have shown that during periods of steady magnetospheric convection (SMC) a large amount of magnetic flux crosses the plasma sheet (corresponding to approximately 10 deg wide auroral oval at the nightside) and that the magnetic configuration in the midtail is relaxed (the curent sheet is thick and contains enhanced B(sub Z). These signatures are typical for the substorm recovery phase. Using near-geostationary magnetic field data, magnetic field modeling and a noval diagostic technique (isotropic boundary algorithm), we show that in the near-Earth tail the magnetic confirguration is very stretched during the SMC events. This stretching is caused by an intense, thin westward current. Because of the srongly depressed B(sub Z), there is a large radial gradient in the near-tail magetic field. These signatures have been peviously associated only with the substorm growth phase. Our results indicate that during the SMC periods the magnetic configuration is very peculiar, with co-existing thin near-Earth current sheet and thick midtail plasma sheet. The deep local minimum of the equatorial B(sub Z) that devleops at R approximately 12 R(sub E) is consistent with steady, adiabatic, Earthward convection in the midtail. These results impose contraints on the existing substorm theories, and call for an explanation of how such a stressed configuration can persist for such a long time without tail current disruptions that occur at the end of a substorm growth phase.

Beschreibung: We report an observation of Petschek-type magnetic reconnection at a distant neutral line (X = -230 R(sub e)) with a full set of signatures of the magnetic merging process. These features include a reversal of plasma flows from earthward to tailward, a pair of slow shocks and the magnetic field X-type line. These two slow shocks are shown to satisfy the shock criteria used by Feldman et al. (1987). The spacecraft first crosses a slow shock to enter the earthward flowing plasmasheet with velocity of about 440 km/s. The embedded magnetic field has a positive B(sub z) component. The spacecraft next enters a region of tailward plasma flow with speed approximately 670 km/s and an embedded negative B(sub z), indicating entry into the plasmasheet tailward of the X-line. These observed velocities are comparable to calculated velocities based on Rankine-Hugoniot conservation relationships. The spacecraft subsequently returns into the south tail lobe by crossing another slow shock. Coplanarity analyses shows that the two slow shocks have orientations consistent with that predicted by the Petschek reconnection model. We note that this event occurs during northward interplanetary magnetic fields. Thus, a magnetic stress built-up in the distant tail may be responsible for this reconnection process.

Beschreibung: A method is presented for analytically representing the magnetic field due to the cross-tail current and its closure on the magnetopause. It is an extension of a method used by Tsyganenko (1989b) to confine the dipole field inside an ellipsoidal magnetopause using a scalar potential. Given a model of the cross-tail current, the implied net magnetic field is obtained by adding to the cross-tail current field a potential field B = - del gamma, which makes all field lines divide into two disjoint groups, separated by the magnetopause (i.e., the combined field is made to have zero normal component with the magnetopause). The magnetopause is assumed to be an ellipsoid of revolution (a prolate spheroid) as an approximation to observations (Sibeck et al., 1991). This assumption permits the potential gamma to be expressed in spheroidal coordinates, expanded in spheroidal harmonics and its terms evaluated by performing inversion integrals. Finally, the field outside the magnetopause is replaced by zero, resulting in a consistent current closure along the magnetopause. This procedure can also be used to confine the modeled field of any other interior magnetic source, though the model current must always flow in closed circuits. The method is demonstrated on the T87 cross-tail current, examples illustrate the effect of changing the size and shape of the prescribed magnetopause and a comparison is made to an independent numerical scheme based on the Biot-Savart equation.

Beschreibung: We have found that image data acquired with NASA's airborne Thermal Infrared Multispectral Scanner (TIMS) can be used to make estimates of the SO2 content of volcanic plumes. TIMS image data are most applicable to the study of partially transparent SO2 plumes, such as those released during quiescent periods or nonexplosive eruptions. The estimation procedure is based on the LOWTRAN 7 radiative transfer code, which we use to model the radiance perceived by TIMS as it views the ground through an SO2 plume. The input to the procedure includes the altitudes of the aircraft and ground, the altitude and thickness of the SO2 plume, the emissivity of the ground, and altitude profiles of the atmospheric pressure, temperature, and relative humidity. We use the TIMS data to estimate both ground temperatures beneath a plume and SO2 concentrations within a plume. Applying our procedure to TIMS data acquired over Mount Etna, Sicily, on July 29, 1986, we estimate that the SO2 flux from the volcano was approximately 6700 t d(exp -1). The use of TIMS to study SO2 plumes represents a bridge between highly localized methods, such as correlation spectroscopy or direct sampling, and small-scale mapping techniques involving satellite instruments such as the Total Ozone Mapping Spectrometer or Microwave Limb Sounder. We require further airborne experiments to refine our estimation procedure. This refinement is a necessary preparation for the schedueled 1998 launch of the Advanced Spaceborne Thermal Emission and Reflectance Radiometer, which will allow large-scale multispectral thermal infrared image data to be collected over virtually any volcano on Earth at least once every 16 days.

Beschreibung: We determine the improvement in baseline length precision and accuracy using new atmospheric delay mapping functions and MTT by analyzing the NASA Crustal Dynamics Project research and development (R&D) experiments and the International Radio Interferometric Surveying (IRIS) A experiments. These mapping functions reduce baseline length scatter by about 20% below that using the CfA2.2 dry and Chao wet mapping functions. With the newer mapping functions, average station vertical scatter inferred from observed length precision (given by length repeatabilites) is 11.4 mm for the 1987-1990 monthly R&D series of experiments and 5.6 mm for the 3-week-long extended research and development experiment (ERDE) series. The inferred monthly R&D station vertical scatter is reduced by 2 mm or by 7 mm is a root-sum-square (rss) sense. Length repeatabilities are optimum when observations below a 7-8 deg elevation cutoff are removed from the geodetic solution. Analyses of IRIS-A data from 1984 through 1991 and the monthly R&D experiments both yielded a nonatmospheric unmodeled station vertical error or about 8 mm. In addition, analysis of the IRIS-A exeriments revealed systematic effects in the evolution of some baseline length measurements. The length rate of change has an apparent acceleration, and the length evolution has a quasi-annual signature. We show that the origin of these effects is unlikely to be related to atmospheric modeling errors. Rates of change of the transatlantic Westford-Wettzell and Richmond-Wettzell baseline lengths calculated from 1988 through 1991 agree with the NUVEL-1 plate motion model (Argus and Gordon, 1991) to within 1 mm/yr. Short-term (less than 90 days) variations of IRIS-A baseline length measurements contribute more than 90% of the observed scatter about a best fit line, and this short-term scatter has large variations on an annual time scale.

Beschreibung: Vertical ocean loading amplitudes are determined by analysis of IRIS geodetic Very Long Baseline Interferometry (VLBI) data. The 4 nearly diurnal (K(sub 1), P(sub 1), O(sub 1), Q(sub 1)) and 4 nearly semidiurnal (K(sub 2), S(sub 2), M(sub 2), and N(sub 2)) component amplitudes can be inferred from the data with accuracies of 1-2 mm. Uncertainties of total displacements can approach 1 cm. Empirically determined total displacements are considerably larger than the values calculated from two geophysical models. The Scherneck model is found to give a better representation of VLBI delay data than the model of Pagiatakis by about 3 mm in residuals at 6 sites. Empirical estimation of the ocean loading amplitudes reduces Chi squared by 3067 for the 96 additional degrees of freedom in a fit to 273,000 IRIS VLBI observations, and reduces the RMS residuals by 3 mm relative to a fit using the fixed Scherneck model. Vertical ocean loading amplitudes can thus be inferred from VLBI data at a level which improves the overall model, but detailed assessment of individual tidal components is presently obscured by incomplete modeling at the tidal frequencies.

Beschreibung: We explore the implications of indicating the biosphere's self-organization by the trend over time of the net entropic flow from the Earth's surface, the actual physical boundary of virtually all biotic mass. This flow, derived from the radiative surface entropy budget, is approximately inversely related to the surface temperature when the solar incident flux remains constant. In the geophysiological ('gaian') interpretation, biospheric self-organization has increased with the progressive colonization of the continents and evolutionary developments in the land biota, as a result of surface cooling arising from biotic enhancement of weathering. The key site for this self-organization is at the interface between land and atmosphere, the soil, where carbon is sequestered by its reaction (as carbonic and organic acids) with calcium magnesium silicates. Along with disequilibrium (steady-state) levels of carbon dioxide in the atmosphere, the occurrence of differentiated soil is the critical material evidence for biospheric self-organization, whether it be geophysiological or geochemical (ie., purely result of inorganic reactions). The computed equilibrium levels of carbon dioxide and corresponding equilibrium temperatures in the past are dramatically different from the steady-state levels. With future solar luminosity increase, the biospheric capacity for climatic regulation will decrease, leading to the ending of self-organization some two billion years from now. The Earth's surface will then approach chemical equilibrium with respect to the carbonate-silicate cycle.

Beschreibung: By the middle of the decade, several new Laser Geodynamic Satellites will be launched to join the current constellation comprised of the laser geodynamic satellite (LAGEOS) (US), Starlette (France), Ajisai (Japan), and Etalon I and II (USSR). The satellites to be launched, LAGEOS II and III (US & Italy), and Stella (France), will be injected into orbits that differ from the existing constellation so that geodetic and gravimetric quantities are sampled to enhance their resolution and accuracy. An examination of various possible tracking strategies adopted by the network of laser tracking stations has revealed that the recovery of precise geodetic parameters can be obtained over shorter intervals than is currently obtainable with the present constellation of satellites. This is particularly important in the planning of mobile laser tracking operations, given a network of permanently operating tracking sites. Through simulations, it is shown that laser tracking of certain satellite passes, pre-selected to provide optimal sky-coverage, provides the means to acquire a sufficient amount of data to allow the recovery of 1 cm station positions.

Beschreibung: The Global Positioning System (GPS) has become, in recent years, the main space-based system for surveying and navigation in many military, commercial, cadastral, mapping, and scientific applications. Better receivers, interferometric techniques (DGPS), and advances in post-processing methods have made possible to position fixed or moving receivers with sub-decimeter accuracies in a global reference frame. Improved methods for obtaining the orbits of the GPS satellites have played a major role in these achievements; this paper gives a personal view of the main developments in GPS orbit determination.

Beschreibung: The long-wavelength thermal anomalies in the lower mantle have been mapped out using several seismic tomographic models in conjunction with thermodynamic parameters derived from high-pressure mineral physics experiments. These parameters are the depth variations of thermal expansivity and of the proportionality factor between changes in density and seismic velocity. The giant plume-like structures in the lower mantle under the Pacific Ocean and Africa have outer fringes with thermal anomalies around 300-400 K, but very high temperatures are found in the center of the plumes near the base of the core-mantle boundary. These extreme values can exceed +1500 K and may reflect large hot thermal anomalies in the lower mantle, which are supported by recent measurements of high melting temperatures of perovskite and iron. Extremely cold anomalies, around -1500 K, are found for anomalies in the deep mantle around the Pacific rim and under South America. Numerical simulations show that large negative thermal anomalies in the mid-lower mantle have modest magnitudes of around -500 K. correlation pattern exists between the present-day locations of cold masses in the lower mantle and the sites of past subduction since the Cretaceous. Results from correlation analysis show that the slab mass-flux in the lower mantle did not conform to a steady-state nature but exhibited time-dependent behavior.

Beschreibung: Measurements of total ozone at Macquarie Island (55 deg S, 159 deg E) reveal statistically significant reductions of approximately twelve percent during July to September when comparing the mean levels for 1987-90 with those in the seventies. A back-correction of 1963-79 Macquarie Island monthly mean ozone data is described which enabled this comparison.

Beschreibung: The satellite observation of a large, about 40-mV/m, transient electric field disturbance over Hurricane Debbie in September 1982 is reported. The electric field event is viewed as a spheric disturbance from a lightning discharge in the active weather system located beneath the satellite. To elucidate this observation of upward moving electrons in the ionosphere associated with a lightning event, several mechanisms for electron acceleration by electric field with components, E(parallel), along the magnetic field are compared. 'Runaway' electrons were accelerated in about 1 ms by a downward directed E(parallel) pulse of about 1 V/m magnitude. Such fields can result from rapidly exposed, negative space charges near the tops of clouds during positive cloud-to-ground discharges. HF frequency Fourier components of the E(parallel) pulse must propagate through the low-conducting nighttime atmosphere to the ionosphere with little dissipation.

Beschreibung: The seasonal behavior of low latitude mesospheric ozone, as observed by the SMM satellite solar occultation experiment, is detailed for the 1985-1989 period. Annual as well as semi-annual waves are observed in the 50-70 km altitude region. In the latitude range of +/- 30 deg the ozone phase and amplitude are functions of temperature and seasonal changes in solar flux. Temperature is the controlling factor for the equatorial region and seasonal changes in solar flux become more dominant at latitudes outside the equatorial zone (greater than +/- 15 deg). There is a hemispheric asymmetry in the ozone annual wave in the 20-30 deg region, with Northern Hemispheric ozone having a larger amplitude than Southern Hemispheric ozone.

Beschreibung: The present study compares small-scale (less than 100 km) features in ER-2 measurements of ClO, O3, H2O, N2O, and NO(y) outside the lower stratospheric Arctic vortex of 1988-1989 with features on potential vorticity maps from ECMWF. The potential vorticity maps are obtained from T106 analyses and forecasts. Some of the plots were truncated to lower resolution (T63 or T42) which smooths out the finer-scale structure. Comparison of these lower resolution plots shows how much detail is lost by excessive smoothing. It is also evident that the forecast plots lose fine-scale structure due to dissipation in the model resulting mainly from horizontal diffusion. It is concluded that blobs of air on the maps at latitudes between the vortex edge and 25 deg N having potential vorticities characteristic of the vortex did indeed originate from the vortex, but that the real atmosphere is more sharply differentiated than the meteorological analyses, implying that the potential vorticity maps underestimate the amount of peeled-off material.

Beschreibung: The empirical models related to solar-terrestrial sciences are listed and described which are available in the form of computer programs. Also included are programs that use one or more of these models for application specific purposes. The entries are grouped according to the region of their solar-terrestrial environment to which they belong and according to the parameter which they describe. Regions considered include the ionosphere, atmosphere, magnetosphere, planets, interplanetary space, and heliosphere. Also provided is the information on the accessibility for solar-terrestrial models to specify the magnetic and solar activity conditions.

Beschreibung: Present understanding of the earth's atmosphere is briefly reviewed. The structure and composition of the atmosphere are described. The origin of the atmosphere and the factors involved in global atmospheric change are addressed.

Beschreibung: Results of ozone and Aitken condensation nuclei measurements made over the rain forest in equatorial Africa during February 12-25, 1988 are presented. The results indicate the presence of a layer between 1 and 4 km altitude where these species are strongly enriched. Based on information derived from simultaneous measurements of other chemical and meteorological parameters, satellite imagery, and trajectory calculations, this enrichment is attributed to emissions from biomass burning in sub-Saharan Africa, from which ozone is formed by photochemical reactions.

Beschreibung: On April 9-11, 1983, the ISEE 3 spacecraft was continuously located within the earth's magnetotail for more than 36 hours at downstream distances of X = -76 to -80 R(e). During this span of time, 12 major intervals of substorm activity were observed in the AL index with good ISEE 3 telemetry coverage for 11 of them. In addition, there were two small substorms outside of these intervals, both with complete observations in the distant tail. This unusual ISEE 3 data set provides a unique opportunity to test the predictions of the near-earth neutral line model. In particular, the hypothesis that energy stored in the tail lobes during the growth phase is later dissipated, in part, through the release of one or more plasmoids following expansion phase onset is examined. Clear growth phase enhancements in the lobe magnetic field intensity preceded the onsets of nine of the substorms. Plasmoids, or their lobe signatures, traveling compression regions (TCRs), were observed at ISEE 3 in association with all 11 of the major substorm intervals for which there were ISEE observations, as well as for the two small substorms. No plasmoids or TCRs were observed in the absence of substorm activity. If these ISEE 3 observations are representative, then the release of plasmoids down the tail may be a feature common to all substorms.

Beschreibung: Daily determinations of the earth's pole position from GPS observations obtained during the first GPS IERS and Geodynamics (GIG) experiment are interpreted in terms of atmospheric wind and pressure fluctuations. Evidence is reported for atmospheric excitation of the rapid polar motions observed during the 23-day period from 22 January to 13 February, 1991. It is demonstrated that atmospheric wind and pressure fluctuations are mostly responsible for exciting the rapid polar motions observed during GIG '91.

Beschreibung: Using 21 days of GPS data from 21 globally distributed receivers operating during early 1991, a 7-parameter transformation between a GPS free-network solution and coordinates of 12 stations listed in the International Terrestrial Reference Frame (ITRF) is solved. Standard errors of GPS coordinates are derived by applying an orthogonal projection operator to the free-network covariance. The weighted rms difference between 33 transformed GPS and ITRF coordinates is 12 mm in the Northern Hemisphere. Best results are obtained by mapping ITRF coordinates to the epoch of this experiment assuming no vertical site motions. Fixing selected sites in the GPS solution to ITRF '90 does not improve the agreement. It is concluded that the use of fiducial constraints is unnecessary for global networks.

Beschreibung: Daily estimates of the earth's pole position have been obtained with measurements from a worldwide network of GPS receivers, obtained during the three week GIG '91 experiment in January-February 1991. For this short-term study, the GPS based polar motion series agrees with the other space based geodetic techniques (Very Long Baseline Interferometry and Satellite Laser Ranging) to about 0.4 mas rms, after the removal of mean biases of order 1-3 mas. The small error in day-to-day variability is not sensitive to the fiducial strategy used, nor are fiducial sites even necessary for monitoring high frequency pole position variability. The small biases indicate that the applied reference frames of the three geodetic techniques are nearly aligned, that the GPS fiducial errors are small, and that systematic errors in GPS are also small (of order 5 ppb). A well determined reference frame is necessary for monitoring the long-term stability of polar motion and for separating it from other long-term signals such as tectonic motion and internal systematic errors.

Beschreibung: Ground-based and airborne measurements of biomass-burning smoke particle optical properties, obtained with a view to aerosol-absorption properties, are presented as a function of time and atmospheric height. The wavelength dependence of the optical thickness can be explained by a log-normal size distribution, with particles' effective radius varying between 0.1 and 0.2 microns. The strong correlation noted between aerosol particle profile and CO profile indicates that smoke particulates constitute a good tracer for emission trace gases from tropical biomass burning.

Beschreibung: Results are presented from airborne measurements of aerosol mass loading, size distribution, and elemental composition obtained in a smoke plume from a fire at a Florida wildlife refuge. It is found that there was a high concentration of carbon-containing aerosols and salt crystals in the 0.1-0.2 micron size range; the composition and morphology of the aerosols differed with size. Aerosol mass concentrations are used in conjunction with those obtained for CO2 in order to calculate ratios of aerosol and CO2. The ratios are noted to be higher for the smoldering phase of the fire than for its flaming phase.

Beschreibung: Results derived from a spectroscopic analysis of the nu5 band R19 transition of C2H2 observed in solar spectra recorded at the Jungfraujoch station, Switzerland, between June 1986 and April 1991 are reported. A least-squares sine fit to the data reveals a seasonal variability with an amplitude of about +/-40 percent of the mean; the maximum occurs during mid-winter and the minimum in summer. In general, the observed seasonal observations are comparable with those derived from airborne in-situ measurements and those reported from ground-based stations.

Beschreibung: Recent findings, based on both ground-based and satellite measurements, have established that there has been an apparent downward trend in the total column amount of ozone over mid-latitude areas of the Northern Hemisphere in all seasons. Measurements of the altitude profile of the change in the ozone concentration have established that decreases are taking place in the lower stratosphere in the region of highest ozone concentration. Analysis of updated ozone records, through March of 1991, including 29 stations in the former Soviet Union, and analysis of independently calibrated satellite data records from the Total Ozone Mapping Spectrometer and Stratospheric Aerosol and Gas Experiment instruments confirm many of the findings originally derived from the Dobson record concerning northern midlatitude changes in ozone. The data from many instruments now provide a fairly consistent picture of the change that has occurred in stratospheric ozone levels.

Beschreibung: A portion of AVHRR data taken on December 5, 1987 at 06:15 GMT over a part of Antarctica is used here to show that many of the most significant dynamic features of ice sheets can be identified by a careful examination of AVHRR imagery. The relatively low resolution of this instrument makes it ideal for obtaining a broad view of the ice sheets, while its wide swath allows coverage of areas beyond the reach of high-resolution imagers either currently in orbit or planned. An interpretation is given of the present data, which cover the area of ice streams that drain the interior of the West Antarctic ice sheet into the Ross Ice Shelf.

Beschreibung: The effects of heterogeneous processing by a parameterized lower stratospheric sulfate aerosol layer on model calculations were examined using a 2D photochemical model. Model results were compared with zonally averaged LIMS data on HNO3 and NO2 and in situ measurements of NO, NO(y), and ClO, taken by the ER-2 aircraft. The results obtained are contradictory: some comparisons favor heterogeneous chemistry, and some do not. It is suggested that the assumptions made to parameterize the sulfate aerosol chemistry result in a rate of heterogeneous processing that is too vigorous.

Beschreibung: Ozone mixing ratios in the vicinity of the 525-K potential temperature surface in January and early February of 1990 were observed to decrease sharply across the edge of the vortex boundary, where the vortex position was estimated from Ertel's potential vorticity. The changes in NO(y) mixing ratio with respect to altitude measured on January 18 and 31 were quite well correlated with those of ozone between 15 and 24 km, indicating that NO(y) also had a large gradient across the edge of the vortex. This is interpreted as being mainly due to the significant denitrification that occurred inside the vortex. The total amount of gas and particulate phase HNO3 was close to the NO(y) amount at the altitude of the 22- to 23-km region, suggesting that the conversion of non-HNO3 reactive nitrogen to HNO3 had occurred with a PSC.

Beschreibung: Observations of the nearly inert, man-made chlorofluorocarbon CFC-115 obtained during January 1989 are used to infer the age of air in the lower stratosphere. These observations together with estimated release rates suggest an average age of high-latitude air at pressure altitudes near 17-21 km of about 3 to 5 yr. This information is used together with direct measurements of HCFC-22, HCFC-142b, CH3Br, H-1301, H-1211, and H-2402 to examine the fractional dissociation of these species within the Arctic polar lower stratosphere compared to that of CFC-11 and hence to estimate their local ozone depletion potentials in this region. It is shown that these HCFCs are much less efficiently dissociated within the stratosphere than CFC-11, lowering their ozone depletion potentials to only about 30-40 percent of their chlorine loading potentials. In contrast, the observations of CH3Br and the Halons considered confirm that they are rapidly dissociated within the stratosphere, with important implications for their ozone depletion potentials.

Beschreibung: Global Positioning System (GPS) data from a worldwide geodetic experiment were collected during a 3-week period early in 1991. Geocentric station coordinates were estimated using the GPS data, thus defining a dynamically determined reference frame origin which should coincide with the earth center of mass, or geocenter. The 3-week GPS average geocenter estimates agree to 7-13 cm with geocenter estimates determined from satellite laser ranging, a well-established technique. The RMS of daily GPS geocenter estimates were 4 cm for x and y, and 30 cm for z.

Beschreibung: Observational and modeling studies have been conducted to examine the interaction between the chemical and dynamical processes that occur during springtime in the lower stratosphere of the Southern Hemisphere. The temporal evolution of the ozone distribution and the circulation during 1987 is contrasted with that for 1988 as an illustrative example of how dynamical processes and the resulting meteorological conditions modulate the ozone depletion. Concurrently with the observational analysis, an effort was initiated to simulate the ozone depletion during austral spring using a 3D chemical/transport model. The model includes a parameterized representation of the heterogeneous processes thought to be important in this region. The simulation indicates that the inclusion of this additional chemistry, which results in the release of free chlorine and the redistribution of odd nitrogen into reservoir species, reproduces many aspects of the observations.

Beschreibung: The paper reports both dc and ac measurements of equatorial electric fields from the San Marco D satellite. These measurements were performed with double floating probe sensors and have yielded a surprising number of new phenomena and effects in regions of equatorial spread-F. Among the phenomena observed are unexpected large-amplitude Rayleigh-Taylor updrafting velocities in equatorial bubbles.

Beschreibung: A global aerosol climatology is evolving from the NASA satellite experiments SAM II, SAGE I, and SAGE II. In addition, polar stratospheric cloud (PSC) data have been obtained from these experiments over the last decade. An undated reference model of the optical characteristics of the background aerosol is described and a new aerosol reference model derived from the latest available data is proposed. The aerosol models are referenced to the height above the tropopause. The impact of a number of volcanic eruptions is described. In addition, a model describing the seasonal, longitudinal, and interannual variations in PSCs is presented.

Beschreibung: A characteristic of Pc 5 pulsation in the morning sector is determined by use of ground magnetometer and riometer data, in conjunction with data acquired with satellites which include the magnetic fields above the ionosphere and electron fluxes at geosynchronous orbit. It is found that the onset of a flux increase in energetic electrons of 30 keV to 200 keV at geosynchronous orbit almost coincides with the onset of Pc 5 pulsation activity and riometer absorption on the ground. It is confirmed when the Pc 5 pulsation occurs on the ground, the large-scale Birkeland current system observed at ionospheric altitude splits into a number of small-scale Birkeland current pairs. It is inferred that the electron flux enhancement, presumably supplied from the tail plasma sheet associated with the substorm onset, provides stress to cause the background large-scale plasma vortex to split into the small-scale vortices. It is suggested that the field-aligned currents in the small-scale vortices propagate along the field lines and sustain the standing Alfvenic oscillations at several different, but neighboring shells of the field lines.

Beschreibung: A solar EUV index for aeronomical studies at earth, obtained from the Langmuir probe measurement of photoelectron current on the Pioneer Venus orbiter, is presented. To examine the potential of E sub EUV as a solar EUV flux index, the behavior of ionospheric parameters f sub 0 E, f sub 0 F1, and f sub 0 F2 are studied at midlatitude stations, and their relationship with E sub EUV and with the 10.7-cm solar radio flux is compared. f sub 0 F1 and f sub 0 F2 are found to be better correlated with E sub EUV than with the 10.7-cm flux. F sub 0 E is better correlated with the 10.7-cm flux, because the 10.7-cm flux is also a proxy for soft X-rays, which are an important ionizing source in the E region. A table is also presented for the EUV index, E sub EUV, for the period February 12, 1979, through most of 1991.

Beschreibung: Shuttle Solar Backscatter Ultraviolet (SSBUV) spectrometer observations of ozone concentrations in the upper stratosphere made in October 1989 are combined here with measurements made in October 1980 by the similar SBUV instruments on NASA's Nimbus-7 satellite. It is shown that the ozone concentration near 45 km has decreased during this period by about 7 +/- 2 percent. The trend is consistent with predictions of a 2D photochemical model.

Beschreibung: Simultaneous measurements of the stratospheric burdens of CO2, HCN, N2O, CH4, OCS, CF2Cl2, CFCl3, CHF2Cl and HF were made by the Jet propulsion Laboratory MkIV interferometer on board the NASA DC-8 aircraft during January and early February 1989 as part of the Airborne Arctic Stratosphere Experiment. Data were acquired on 11 flights at altitudes of up to 12 km over a geographic region covering the NE Atlantic Ocean, Iceland and Greenland. The results obtained show large variations in the burdens of these tracers due to the effects of transport. The tropospheric source gas burdens were reduced inside the polar vortex, suggesting that the air had subsided with respect to the surrounding midlatitude air. Increased HF burdens inside the vortex support this interpretation. The results obtained from the different tracers are highly consistent with each other and indicate that in the 15- to 20-km altitude range inside the vortex, surfaces of constant volume mixing ratio were located some 5-6 km lower in absolute altitude than outside the vortex. The results also indicate that the magnitude of this subsidence increases with altitude. These conclusions are consistent with other measurements.

Beschreibung: The paper uses particle size and volume measurements obtained with the forward scattering spectrometer probe model 300 during January and February 1989 in the Airborne Arctic Stratospheric Experiment to investigate processes important in the formation and growth of polar stratospheric cloud (PSC) particles. It is suggested on the basis of comparisons of the observations with expected sulfuric acid droplet deliquescence that in the Arctic a major fraction of the sulfuric acid droplets remain liquid until temperatures at least as low as 193 K. It is proposed that homogeneous freezing of the sulfuric acid droplets might occur near 190 K and might play a role in the formation of PSCs.

Beschreibung: The paper reports simultaneous measurements of the stratospheric burdens of H2O, HDO, OCS, CO2, O3, N2O, CO, CH4, CF2Cl2, CFCl3, CHF2Cl, C2H6, HCN, NO, NO2, HNO3, ClNO3, HOCl, HCl, and HF made by the JPL MkIV interferometer on board the NASA DC-8 aircraft during January and early February 1989 as part of the Airborne Arctic Stratosphere Experiment. Data were obtained on 11 flights at altitudes of up to 12 km over a geographic region covering the NE Atlantic Ocean, Iceland, and Greenland. Analyses of the chemically active gases reveal highly perturbed conditions within the vortex. The ClNO3 abundance was chemically enhanced near the edge of the vortex but was then depleted inside. NO2 was severely depleted inside the vortex. In contrast to Antarctica, H2O and HNO3 were both more abundant inside the vortex than outside. It is suggested that although the Arctic vortex did not get cold enough to produce any dehydration, or as vertically extensive denitrification as occurred in Antarctica, nevertheless, enough heterogeneous chemistry occurred to convert over 90 percent of the inorganic chlorine to active forms in the 14- to 27-km altitude range by early February 1989.

Beschreibung: Three-dimensional model simulations are used to describe the January 31, 1989 ozone minihole over Stavanger, Norway. This minihole is typical of many transient events in the lower stratosphere that arise because of cyclonic-scale disturbances in the troposphere. Although the ozone reduction is a short-lived reversible dynamical event, through heterogeneous chemical processes there can be a significant transfer of chlorine from reservoir molecules to active radicals. This chemically perturbed air is defined as processed air, and it is found that a single event can produce enough processed air to reduce the HCl in the entire polar vortex. Chemical processing on clouds associated with transient events is shown to be a major source of processed air in the polar vortex in December before background temperatures are cold enough for more uniform heterogeneous conversion.

Beschreibung: This paper presents the results of a series of total and spectral solar irradiance measurements made at ground surface (Table Mountain Facility, Calif., altitude 2.18 km). The spectral irradiance data are presented for the 0.3-3.0-micron spectral region for air mass 1.5.

Beschreibung: The hypothesis of Thorne (1977, 1980) and Baker et al. (1986, 1987) that the precipitation of energetic electrons is modifying the high-latitude ozone distribution in the Southern Hemisphere is tested by comparing electron density data from a ground-based partial reflection sounder with simultaneous satellite data on ozone mixing ratios taken at the 40 to 50 km altitude. The results do not support the theory that large electron densities coincide with ozone destruction. There is no evidence, for instance, that the January 15, 1984 ionization event had an associated ozone loss. Further experiments for investigating the relationship between the precipitating electrons and ozone depletion are suggested.

Beschreibung: The focus of this study is to write in terms of reported values the standard theoretical equation describing the earth's wobble, namely, the linearized conservation of angular momentum equation known as the Liouville equation. A relation between the locations of the rotation pole and the celestial ephemeris pole is first obtained to rewrite this equation in terms of the location of the reported pole. This is achieved in the time domain by considering the properties of the time-dependent transformation matrix that relates components of a position vector in the rotating, body-fixed frame to its components in the celestial, space-fixed frame.

Beschreibung: In the last three years, the European Geodetic Very Long Baseline Interferometry (VLBI) Network has grown to a total of six fixed antennas placed in Germany, Italy, Spain and Sweden, all equipped with the standard geodetic VLBI instrumentation and data recording systems. During this period of time, several experiments have been carried out using this interferometer providing data of very high quality due to the excellent sensitivity and performance of the European stations. The purpose of this paper is to study the consistency of the VLBI geodetic results on the European baselines with respect to the different degrees of freedom in the analysis procedure. Used to complete this study were both real and simulated data sets, two different software packages (OCCAM 3.0 and CALC 7.4/SOLVE), and a variety of data analysis strategies.

Beschreibung: Data from the Earth Radiation Budget Satellite (ERBS) and from the operational NOAA-9 satellite being placed in the archive of the earth Radiation Budget Experiment (ERBE) are discussed. The results of the ERBE data validation effort are reviewed along with ERBE solar constant observations and earth-viewing results. The latter include monthly average results for July 1985, annual average clear-sky fluxes, and annual average, zonal, and global results.

Beschreibung: The vertical profiles of ClO, HCl, HO2, and O3 were determined from thermal emission measurements by a balloon-borne spectrometer operating near 640 GHz. Results are in broad agreement with previous measurements and models, but differ significantly with model photochemistry for the ratio of ClO to HCl.

Beschreibung: Stratospheric aerosol from Mount Pinatubo heated the tropical lower stratosphere by about 0.3 K/day mainly due to absorption of terrestrial infrared radiation. This heating was dissipated by: (1) an observed increase in stratospheric temperatures, which enhanced the radiation cooling; (2) additional mean upward motion, observed for the aerosol cloud, which led to adiabatic cooling; and (3) reductions in ozone concentrations resulting from enhanced upward motions. Each of these processes operated on a different time scale: maximum temperatures were observed after about 90 days; maximum ozone losses of about -1.5 ppm occurred after 140 days when the enhanced vertical velocities effectively lifted the ozone profile by about 2 km. We believe this shows that ozone plays an important role in buffering vertical motion in the tropical lower stratosphere, and hence the residual Brewer Dobson circulation of the whole stratosphere.

Beschreibung: We present AMPTE UKS data from a well-studied magnetospheric flux transfer event, showing detailed ion phase-space distributions for each region of this layered event. We show that the perpendicular temperature anisotropy maximizes at the center of the event. This is inconsistent with recent suggestions that FTE signatures may result from the spacecraft moving into and then out of the magnetosheath via the plasma depletion layer. We present an explanation for the temperature anisotropy structure in terms of a reconnection model.

Beschreibung: Data from the NOAA-9 satellite on cloud amount and cloud upper boundary temperature, data from surface weather stations, and results of aerological sounding of the atmosphere are used to calculate the vertical profiles of upward, downward, and effective fluxes of longwave radiation. A comparison of satellite and surface data on cloud amount and underlying surface temperature is presented.

Beschreibung: Two comments on a work by Murthy (1991) concerning the abundances of siderophile elements in the earth's mantle are presented. In the first comment it is asserted that the basis of Murthy's extrapolation is the assumption that the Gibbs free energy change for the partitioning reaction is independent of temperature, and as this is generally not a valid assumption thermodynamically, and as this is contradicted by most experimental data, the issue of mantle siderophile elements remains unresolved. In the second comment it is asserted that the extrapolation method used by Murthy does not appear to be valid thermodynamically, and that an extrapolation based on generally accepted thermodynamic assumptions yields different results. In a reply, Murthy takes issue with the comments.

Beschreibung: Small areas of sharply reduced ozone density appear frequently in the maps produced from polar region total ozone mapping spectrometer (TOMS) data. These mini-holes are of the order of 1000 km in extent with a lifetime of a few days. On the basis of measurements from ground-based instruments, balloon-borne ozonesondes, and simultaneous measurements of aerosol and ozone concentrations during aircraft flights in the Arctic and Antarctic regions, the appearance of polar stratospheric clouds (PSCs) are frequently associated with false reductions in ozone derived from the TOMS albedo data. By combining radiative transfer calculations with the observed PSC and ozone data, it is shown that PSCs located near or above the ozone density maximum (with optical thickness greater than 0.1) can explain most of the differences between TOMS ozone data and ground or in situ ozone measurements. Several examples of real and false TOMS mini-hole phenomenon are investigated using data from the 1989 Airborne Arctic Stratospheric Expedition (AASE) and from balloon flights over Norway and Sweden.

Beschreibung: SAGE II multiwavelength aerosol extinction measurements are used to estimate mass- and extinction-to-backscatter conversion parameters. The basis of the analysis is the principal component analysis of the SAGE II extinction kernels to estimate both total aerosol mass and aerosol backscatter at a variety of wavelengths. Comparisons of coincident SAGE II extinction profiles with 0.694-micron aerosol backscatter profiles demonstrate the validity of the method.

Beschreibung: Changes in the earth's climate are induced by variations in the earth's orbital parameters which modulate the seasonal distribution of solar radiation. Periodicities in the geological climate record with cycles of 100, 41, and 23 kyr have been linked with changes in obliquity, eccentricity, and precession of the equinoxes. The effect of variations of eccentricity during a 100 kyr period is weak relative to the signals from obliquity and precession variations and it may therefore be expected that the 100 kyr signal in the climate record would be of low intensity. However, this signal dominates the climate record and internal nonlinear processes within the climate system have previously been proposed to account for this fact. The author shows that variations in the frequency of the obliquity cycle can give rise to strong 100-kyr forcing of climate.

Beschreibung: Measurements of total ozone at Macquarie Island (55 deg S, 159 deg E) reveal statistically significant reductions of approximately twelve percent during July to September when comparing the mean levels for 1987-90 with those in the seventies. In order to investigate the possibility that these ozone changes may not be a result of dynamic variability of the stratosphere, a simple linear model of ozone was created from statistical analysis of tropopause height and isentropic transient eddy heat flux, which were assumed representative of the dominant dynamic influences. Comparison of measured and modeled ozone indicates that the recent downward trend in ozone at Macquarie Island is not related to stratospheric dynamic variability and therefore suggests another mechanism, possibly changes in photochemical destruction of ozone.

Beschreibung: An analysis, based on the principles of stress balance in a 1-dimensional current sheet is presented, which considers the problem of closed magnetic flux transport into the deep tail by a 'viscous'-like interaction between the solar wind and the magnetosphere. The analysis is illustrated with an example of ISEE-3 data showing strong tailward plasma sheet flows on apparently closed field lines in the deep tail. Apart from narrow regions adjacent to the magnetopause, these flows are not driven by the scattering of magnetosheath plasma into the magnetosphere. The fraction of the magnetosheath momentum flux needed to be anomalously transferred into the plasma sheet to drive the flows is estimated. In the example this is 6 percent. No previously suggested mechanism (e.g., the Kelvin-Helmholtz instability) has been shown capable of providing anomalous momentum transport of this magnitude. The current understanding of the 'viscous' interaction between the solar wind and magnetosphere is thus insufficient to explain these observations.

Beschreibung: Simulation multiangle imagery have been used to investigate the capabilities of a novel method for retrieval of atmospheric aerosol optical properties over land; this method employs spatial contrasts within the imagery and compares the spatial Fourier transforms of the multiangle images at zero and nonzero spatial frequencies. While requiring the definition of a relationship between the angular variation of the Fourier transform of the intrinsic surface angular reflectance at the zero and nonzero frequencies, the method assumes no a priori knowledge about aerosols or surface characteristics. Sensitivities to various aerosol properties are assessed.

Beschreibung: Data from a worldwide Global Positioning System (GPS) tracking experiment have been used to determine variations in earth rotation (UT1-UTC) over a time period of three weeks. Kalman filtering and smoothing enabled changes in UT1-UTC over intervals of 2 to 24 hrs to be detected with the GPS data. Internal consistency checks and comparisons with other solutions from very long baseline interferometry (VLBI) and satellite laser ranging (SLR) indicate that the GPS UT1-UTC estimates are accurate to about 2 cm. Comparison of GPS-estimated variations in UT1-UTC with 2-hr time resolution over 4 days with predicted variations computed from diurnal and semidiurnal oceanic tidal contributions strongly suggests that the observed periodic sub-daily variations of about 0.1 msec are largely of tidal origin.

Beschreibung: The use of GPS navigation satellites to study earth-orientation parameters in real-time is examined analytically with simulations of network geometries. The Orbit Analysis covariance-analysis program is employed to simulate the block-II constellation of 18 GPS satellites, and attention is given to the budget for tracking errors. Simultaneous solutions are derived for earth orientation given specific satellite orbits, ground clocks, and station positions with tropospheric scaling at each station. Media effects and measurement noise are found to be the main causes of uncertainty in earth-orientation determination. A program similar to the Polaris network using single-difference carrier-phase observations can provide earth-orientation parameters with accuracies similar to those for the VLBI program. The GPS concept offers faster data turnaround and lower costs in addition to more accurate determinations of UT1 and pole position.

Beschreibung: Recent results indicate that the intense southward interplanetary magnetic fields (IMFs) responsible for great storms can reside in the postshock plasma preceding the driver gas of coronal mass ejections (CMEs) as well as in the driver gas itself. It is proposed here that strong southward fields in the postshock flow result from a major increase in the Russell-McPherron polarity effect through a systematic pattern of compression and draping within the ecliptic plane. Differential compression at the shock increases the Parker spiral angle and, consequently, the azimuthal field component that projects as a southward component onto earth's dipole axis. The resulting prediction is that southward fields in the postshock plasma maximize at the spring (fall) equinox in CMEs emerging from toward (away) sectors. This pattern produces a strong semiannual variation in postshock IMF orientation and may account at least in part for the observed semiannual variation of the occurrence of great geomagnetic storms.