Publikationsdatum:
2011-06-10
Beschreibung:
Intensive field experiments focused on fog chemistry were carried out in the northern suburb of Nanjing during the winters of 2006 and 2007. Thirty-seven fog water samples were collected in nine fog events. Based on the chemical analysis results of those samples and the simultaneous measurements of air pollution gases and atmospheric aerosols, the chemical characteristics of fog water and their relations with air pollutants during fog evolution were investigated. The results revealed an average total inorganic ionic concentration TIC = 21.18 meq/L, and the top three ion concentrations were those of SO 4 2− , NH 4 + and Ca 2+ (average concentrations 6.99, 5.95, 3.77 meq/L, respectively). However, the average pH value of fog water was 5.85, which is attributable to neutralization by basic ions (NH 4 + and Ca 2+ ). The average TIC value of fog water measured in advection–radiation fog was around 2.2 times that in radiation fog, and the most abundant cation was NH 4 + in advection–radiation fog and Ca 2+ in radiation fog. In dense fog episodes, the concentration variations of primary inorganic pollution gases showed a “V”-shaped pattern, while those of volatile organic compounds (VOCs) displayed a “Λ”-shaped pattern. The dense fog acted as both the source and sink of atmospheric aerosol particles; fog processes enhanced particle formation, leading to the phenomenon that the aerosol concentration after fog dissipation was higher than that before the fog, and at the same time, mass concentration of PM 10 reached the lowest value in the late stage of extremely dense fog episodes because of the progressive accumulated effect of wet deposition of large fog droplets. Both air pollution gases and aerosols loading controlled the ion compositions of fog water. The Ca 2+ in fog water originated from airborne particles, while SO 4 2− and NH 4 + were from both heterogeneous production and soluble particulate species. Content Type Journal Article Pages 1-16 DOI 10.1007/s00024-011-0342-y Authors Jun Yang, Key Laboratory of Atmospheric Physics and Environment, School of Atmospheric Physics, Nanjing University of Information Science and Technology, No. 219 Ningliu Road, Nanjing, 210044 China Yu-Jing Xie, Key Laboratory of Atmospheric Physics and Environment, School of Atmospheric Physics, Nanjing University of Information Science and Technology, No. 219 Ningliu Road, Nanjing, 210044 China Chun-E Shi, Anhui Institute of Meteorological Sciences, Hefei, 230031 China Duan-Yang Liu, Key Laboratory of Atmospheric Physics and Environment, School of Atmospheric Physics, Nanjing University of Information Science and Technology, No. 219 Ningliu Road, Nanjing, 210044 China Sheng-Jie Niu, Key Laboratory of Atmospheric Physics and Environment, School of Atmospheric Physics, Nanjing University of Information Science and Technology, No. 219 Ningliu Road, Nanjing, 210044 China Zi-Hua Li, Key Laboratory of Atmospheric Physics and Environment, School of Atmospheric Physics, Nanjing University of Information Science and Technology, No. 219 Ningliu Road, Nanjing, 210044 China Journal Pure and Applied Geophysics Online ISSN 1420-9136 Print ISSN 0033-4553
Print ISSN:
0033-4553
Digitale ISSN:
1420-9136
Thema:
Geologie und Paläontologie
,
Physik
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