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  • Other Sources  (47)
  • American Geophysical Union  (38)
  • American Chemical Society
  • 1995-1999  (47)
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Source
Keywords
Publisher
Years
Year
  • 1
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    Mineral Physics & Crystallography - A Handbook of Physical Constants (1995)
    American Geophysical Union
    In:  Washington, D.C., American Geophysical Union, vol. 1, (ISBN 0-521-81734-X)
    Details
    Publication Date: 1995
    Keywords: Handbook of mineralogy ; Rock mechanics ; Physical properties of rocks ; Handbook of physics ; Geochemistry
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    BIBLIOGRAPHY SEISMOLOGY
  • 2
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    Elastic constants of mantle minerals at high temperature (1995)
    American Geophysical Union
    In:  Mineral Physics & Crystallography - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 37, pp. 64-97, (ISBN 3-540-24988-5)
    Details
    Publication Date: 1995
    Keywords: Laboratory measurements ; Physical properties of rocks ; Review article ; Mineralogy
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    BIBLIOGRAPHY SEISMOLOGY
  • 3
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    Seismic traveltime tables (1995)
    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. 1, pp. 126-143, (ISBN: 3-540-23712-7)
    Details
    Publication Date: 1995
    Keywords: Review article ; Seismology ; Travel time ; Handbook of geophysics
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    BIBLIOGRAPHY SEISMOLOGY
  • 4
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    Classification of rocks and their abundances on the Earth (1995)
    American Geophysical Union
    In:  Professional Paper, Rock Physics & Phase Relations - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 14, no. 16, pp. 1-7, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Physical properties of rocks ; Mineralogy ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 5
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    Isotopic decay data (1995)
    American Geophysical Union
    In:  Professional Paper, Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. 16, pp. 271-282, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Review article ; radioactivity ; Handbook of geophysics ; Handbook of physics
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    BIBLIOGRAPHY SEISMOLOGY
  • 6
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    Rheology of rocks (1995)
    American Geophysical Union
    In:  Professional Paper, Rock Physics & Phase Relations - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 1002, no. 231, pp. 148-165, (ISBN 1-4020-1729-4)
    Details
    Publication Date: 1995
    Keywords: Rheology ; Inelastic ; Rock mechanics ; Physical properties of rocks ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 7
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    Seismic models of the Earth: Elastic and anelastic (1995)
    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. 4, pp. 88-103, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Review article ; Earth model, also for more shallow analyses ! ; Rheology ; Seismology
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    BIBLIOGRAPHY SEISMOLOGY
  • 8
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    Free oscillations: Frequencies and attenuations (1995)
    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. 4, pp. 104-125, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Review article ; (The Earth's free) oscillations ; Attenuation ; Rheology
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    BIBLIOGRAPHY SEISMOLOGY
  • 9
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    Acoustic velocity and attenuation in porous rocks (1995)
    American Geophysical Union
    In:  Professional Paper, Open-File Rept., Rock Physics & Phase Relations - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 22, no. 16, pp. 20-34, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Physical properties of rocks ; Attenuation ; porosity ; Velocity ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 10
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    Deep-crustal seismology of continental margins (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. 10, no. 28, pp. 309-314
    Details
    Publication Date: 1995
    Keywords: Seismics (controlled source seismology) ; Deep seismic sounding (espec. cont. crust) ; Plate tectonics ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 11
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    Nuclear magnetic resonance spectroscopy of Silicates and Oxides in geochemistry and geophysics (1995)
    American Geophysical Union
    In:  Bull., Open-File Rept., Mineral Physics & Crystallography - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 24, no. 16, pp. 303-331, (ISBN 1-86239-165-3, vi + 330 pp.)
    Details
    Publication Date: 1995
    Keywords: NMR ; Spectrum ; Spectral analysis ; Geochemistry ; Physical properties of rocks ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 12
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    Natural radioactivity of the crust and mantle (1995)
    American Geophysical Union
    In:  Professional Paper, Open-File Rept., Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. 16, pp. 283-291, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Review article ; radioactivity ; isotopes ; Geothermics
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    BIBLIOGRAPHY SEISMOLOGY
  • 13
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    Plate motions and crustal deformation (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by, Washington, D.C., American Geophysical Union, vol. 10, no. 302, pp. 365-369
    Details
    Publication Date: 1995
    Keywords: Plate tectonics ; Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Seismicity ; Geodesy ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 14
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    Magnitudes and moments of earthquakes (1995)
    American Geophysical Union
    In:  Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, pp. 206-213
    Details
    Publication Date: 1995
    Keywords: Review article ; Seismology ; Magnitude ; Energy (of earthquakes) ; seismic Moment
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    BIBLIOGRAPHY SEISMOLOGY
  • 15
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    Thermal conductivity of rocks and minerals (1995)
    American Geophysical Union
    In:  Professional Paper, Rock Physics & Phase Relations - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 1, no. 16, pp. 105-126, (ISBN 1-86239-165-3, vi + 330 pp.)
    Details
    Publication Date: 1995
    Keywords: Geothermics ; Physical properties of rocks ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 16
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    Electrical conductivity models of the crust and the mantle (1995)
    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. XVI:, pp. 190-205, (ISBN: 3-540-23712-7)
    Details
    Publication Date: 1995
    Keywords: Review article ; Geoelectrics ; Earth model, also for more shallow analyses !
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    BIBLIOGRAPHY SEISMOLOGY
  • 17
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    Models of mantle viscosity (1995)
    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Mineral Physics & Crystallography - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 3, no. 1, pp. 227-236, (ISBN: 3-540-23712-7)
    Details
    Publication Date: 1995
    Keywords: Rheology ; Inelastic ; Modelling ; Review article ; Geothermics ; Earth model, also for more shallow analyses !
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    BIBLIOGRAPHY SEISMOLOGY
  • 18
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    Contributions in Dynamics of the Solid Earth and Other Planets (1995)
    American Geophysical Union
    In:  Bull., Open-File Rept., U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994, Washington, D.C., American Geophysical Union, vol. 65, no. 1, pp. 23-40, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Review article ; Seismology ; Tectonics ; Plate tectonics ; Volcanology ; Earthquake hazard ; Earthquake precursor: prediction research ; Earth rotation ; Geochemistry ; Nuclear explosion ; Source ; Deep seismic sounding (espec. cont. crust) ; GeodesyY ; Chaotic behaviour ; Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Rock mechanics ; remote ; sensing ; Mineralogy ; Geodesy ; Global Positioning System ; Very Long Baseline Interferometry ; Satellite Laser Ranging ; Gravimetry, Gravitation ; Planetology
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    BIBLIOGRAPHY SEISMOLOGY
  • 19
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    Rock Physics & Phase Relations - A Handbook of Physical Constants (1995)
    American Geophysical Union
    In:  Washington, D.C., American Geophysical Union, vol. 1, (ISBN 0-521-81734-X)
    Details
    Publication Date: 1995
    Keywords: Handbook of geophysics ; Rock mechanics ; Physical properties of rocks ; Handbook of physics
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    BIBLIOGRAPHY SEISMOLOGY
  • 20
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    Global Earth Physics: A Handbook of Physical Constants (1995)
    American Geophysical Union
    In:  Washington, American Geophysical Union, vol. 1, (ISBN 0-521-81734-X)
    Details
    Publication Date: 1995
    Keywords: Handbook of geophysics ; Plate tectonics ; TIDES ; Geomagnetics ; Geothermics ; Seismology ; Geoelectrics ; Earth model, also for more shallow analyses ! ; Gravimetry, Gravitation ; Paleomagnetism ; isotopes ; Geochemistry ; Oceanography ; Volcanology ; physical ; constants
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    BIBLIOGRAPHY SEISMOLOGY
  • 21
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    Elasticity of minerals, glasses, and melts (1995)
    American Geophysical Union
    In:  Mineral Physics & Crystallography - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 17, no. 16, pp. 303-331, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Mineralogy ; Physical properties of rocks ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 22
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    Present plate motions and plate boundaries (1995)
    American Geophysical Union
    In:  Professional Paper, Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. 16, pp. 66-87, (ISBN: 3-540-23712-7)
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    Publication Date: 1995
    Keywords: Plate tectonics ; Modelling ; Review article ; Geodesy ; Paleomagnetism
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    BIBLIOGRAPHY SEISMOLOGY
  • 23
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    Rock failure (1995)
    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Rock Physics & Phase Relations - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 1, no. 4, pp. 127-147, (ISBN 0080419208)
    Details
    Publication Date: 1995
    Keywords: Rock mechanics ; Geochemistry ; Physical properties of rocks ; Mineralogy ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 24
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    Seismic source modeling (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. 10, no. SC.TECH./SEM.16/R.60, pp. 299-308
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    Publication Date: 1995
    Keywords: Source ; Modelling ; Seismology ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 25
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    Lithosphere dynamics and continental deformation (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. 10, no. SC.TECH./SEM.16/R.60, pp. 379-383
    Details
    Publication Date: 1995
    Keywords: Tectonics ; rifting ; basins ; Fault zone ; Stress ; Fluids ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 26
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    Earthquake geodesy and hazard monitoring (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. C 560, 183 pp., no. M79-E-11 [79127 Arto 129], pp. 249-255, (ISBN 3-933346-037)
    Details
    Publication Date: 1995
    Keywords: Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Earthquake hazard ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 27
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    Crustal deformation (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. C 560, 183 pp., no. PL-TR-91-2097, pp. 371-377, (ISBN 3-933346-037)
    Details
    Publication Date: 1995
    Keywords: Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Geodesy ; Very Long Baseline Interferometry ; Satellite Laser Ranging ; Global Positioning System ; Plate tectonics ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 28
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    Intraslab earthquakes and phase changes in subducting lithosphere (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. C 560, 183 pp., no. 25, pp. 287-297, (ISBN 3-933346-037)
    Details
    Publication Date: 1995
    Keywords: Seismology ; Source ; Mineralogy ; Hypocentral depth ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 29
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    Marine geodynamics: Depth-age revisited (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. C 560, 183 pp., no. AFGL-TR-88-0314, pp. 413-418, (ISBN 3-933346-037)
    Details
    Publication Date: 1995
    Keywords: Plate tectonics ; evolution ; GeodesyY ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 30
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    Volcanic eruptions, prediction, hazard assessment, remote sensing, and societal implications (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. 10, no. paper SPWLA 90-H, pp. 257-262, (ISBN 3-933346-037)
    Details
    Publication Date: 1995
    Keywords: Volcanology ; Earthquake precursor: prediction research ; Earthquake hazard ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 31
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    Seismology and the test ban: A new era (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. 10, no. 89-144, pp. 269-273, (ISBN 0 08 042822 3)
    Details
    Publication Date: 1995
    Keywords: Seismology ; Nuclear explosion ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 32
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    Rock deformation: Ductile and brittle (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. C 560, 183 pp., no. 57, pp. 451-457, (ISBN 3-933346-037)
    Details
    Publication Date: 1995
    Keywords: Rock mechanics ; Rheology ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 33
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    New ideas about the physics of earthquakes (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. 1034, no. SAND 80-2048, pp. 283-286, (ISBN 3-933346-037)
    Details
    Publication Date: 1995
    Keywords: Source ; Seismology ; Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Energy (of earthquakes) ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 34
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    Volcano seismology, hazards assessment (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. C 560, 183 pp., no. 70, pp. 263-267, (ISBN 3-933346-037)
    Details
    Publication Date: 1995
    Keywords: Volcanology ; Earthquake hazard ; Seismology ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 35
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    Chaos, fractals, nonlinear phenomena in Earth sciences (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, vol. 10, no. 91-N-FA07-7-4, pp. 341-343, (ISBN 0 08 042822 3)
    Details
    Publication Date: 1995
    Keywords: Chaotic behaviour ; FractureT ; Non-linear effects ; Review article
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  • 36
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    Earthquake prediction, societal implications (1995)
    American Geophysical Union
    In:  U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994. Contributions in Dynamics of the Solid Earth and Other Planets, ed. by R. A. Pielke, Washington, D.C., American Geophysical Union, no. 43, pp. 243-247
    Details
    Publication Date: 1995
    Keywords: Earthquake precursor: prediction research ; Earthquake risk ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 37
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    Heat flow of the Earth (1995)
    American Geophysical Union
    In:  Bull., Open-File Rept., Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. 16, pp. 144-158, (ISBN 1-86239-165-3, vi + 330 pp.)
    Details
    Publication Date: 1995
    Keywords: Geothermics ; Review article
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    BIBLIOGRAPHY SEISMOLOGY
  • 38
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    Crustal structure of the Earth (1995)
    American Geophysical Union
    In:  Bull., Open-File Rept., Global Earth Physics: A Handbook of Physical Constants, Washington, American Geophysical Union, vol. 1, no. 1, pp. 214-224, (ISBN 1-86239-165-3, vi + 330 pp.)
    Details
    Publication Date: 1995
    Keywords: Review article ; Velocity depth profile ; Earth model, also for more shallow analyses ! ; Deep seismic sounding (espec. cont. crust)
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  • 39
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    Synthesis of polycrystalline methane hydrate, and its phase stability and mechanical properties at elevated pressure (1997)
    American Chemical Society
    In:  ACS Division of Fuel Chemistry Preprints, 42 (2). pp. 544-547.
    Details
    Publication Date: 2018-04-11
    Description: Test specimens of methane hydrate were grown under static conditions by combining cold, pressurized CH4 gas with H2O ice grains, then warming the system to promote the reaction CH4 (g) + 6H2O (s???l) ??? CH4??6H2O. Hydrate formation evidently occurs at the nascent ice/liquid water interface, and complete reaction was achieved by warming the system above 271.5 K and up to 289 K, at 25-30 MPa, for approximately 8 hours. The resulting material is pure methane hydrate with controlled grain size and random texture. Fabrication conditions placed the H2O ice well above its melting temperature before reaction completed, yet samples and run records showed no evidence for bulk melting of the ice grains. Control experiments using Ne, a non-hydrate-forming gas, verified that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting is easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably at temperatures well above its melting point. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T= 140-200 K, Pc= 50-100 MPa, and ????= 10-4-10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to a higher degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; x-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.
    Type: Article , NonPeerReviewed
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  • 40
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    Vertinoid Polyketides from the Saltwater Culture of the FungusTrichodermalongibrachiatumSeparated from aHaliclonaMarine Sponge† (1998)
    American Chemical Society
    In:  The Journal of Organic Chemistry, 63 (26). pp. 10011-10014.
    Details
    Publication Date: 2020-05-11
    Type: Article , PeerReviewed
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  • 41
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    Polycrystalline Methane Hydrate: Synthesis from Superheated Ice, and Low-Temperature Mechanical Properties (1998)
    American Chemical Society
    In:  Energy & Fuels, 12 (2). pp. 201-211.
    Details
    Publication Date: 2018-04-11
    Description: We describe a new and efficient technique to grow aggregates of pure methane hydrate in quantities suitable for physical and material properties testing. Test specimens were grown under static conditions by combining cold, pressurized CH4 gas with granulated H2O ice, and then warming the reactants to promote the reaction CH4(g) + 6H2O(s→l) → CH4·6H2O (methane hydrate). Hydrate formation evidently occurs at the nascent ice/liquid water interface on ice grain surfaces, and complete reaction was achieved by warming the system above the ice melting point and up to 290 K, at 25−30 MPa, for approximately 8 h. The resulting material is pure, cohesive, polycrystalline methane hydrate with controlled grain size and random orientation. Synthesis conditions placed the H2O ice well above its melting temperature while reaction progressed, yet samples and run records showed no evidence for bulk melting of the unreacted portions of ice grains. Control experiments using Ne, a non-hydrate-forming gas, showed that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting are easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably to temperatures well above its ordinary melting point while reacting to form hydrate. Direct observations of the hydrate growth process in a small, high-pressure optical cell verified these conclusions and revealed additional details of the hydrate growth process. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T = 140−200 K, Pc = 50−100 MPa, and ε = 10-4−10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to an unusually high degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; X-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.
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  • 42
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    Gas Hydrates: Review of Physical/Chemical Properties (1998)
    American Chemical Society
    In:  Energy & Fuels, 12 (2). pp. 191-196.
    Details
    Publication Date: 2020-07-31
    Description: An overview is provided of time-independent physical/chemical properties as related to crystal structures. The following two points are illustrated in this review:  (1) Physical and chemical properties of structure I (sI) and structure II (sII) hydrates are well-defined; measurements have begun on sH. Properties of sI and sII are determined by the molecular structures, described by three heuristics:  (i) Mechanical properties approximate those of ice, perhaps because hydrates are 85 mol % water. Yet each volume of hydrate may contain as much as 180 volumes (STP) of the hydrate-forming species. (ii) Phase equilibrium is set by the size ratio of guest molecules within host cages, and three-phase (Lw−H−V) equilibrium pressure depends exponentially upon temperature. (iii) Heats of formation are set by the hydrogen-bonded crystals and are reasonably constant within a range of guest sizes. (2) Fundamental research challenges are (a) to routinely measure the hydrate phase (via diffraction, NMR, Raman, etc.), and (b) to formulate an acceptable model for hydrate formation kinetics. The reader may wish to investigate details of this review further, via references contained in several recent monographs.
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  • 43
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    Iridoid glycosides of Leonurus persicus (1999)
    American Chemical Society
    In:  Journal of Natural Products, 62 (6). pp. 811-816.
    Details
    Publication Date: 2020-07-22
    Description: Two new iridoid glucosides, 6-O-acetylajugol (1) and 7,8-epoxy-8-epi-loganic acid (2), together with five known iridoid glucosides, galiridoside (3), ajugoside (4), 10-deoxygeniposidic acid (5), 7-deoxy-8-epi-loganic acid (6), and 8-O-acetylharpagide (7), have been isolated from the aerial parts of Leonurus persicus. Leucosceptoside A (8), eugenyl β-rutinoside (9), and kaempferol 3-O-glucoside (10) were also isolated. The structures of 1 and 2 were elucidated by extensive 1D- and 2D-NMR spectroscopy and molecular modeling. The structure of 3 was confirmed by single-crystal X-ray diffraction. Antimicrobial activity of compounds (1−10) was also evaluated against a panel of Gram-positive and Gram-negative bacteria and two strains of fungi.
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  • 44
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    New furanoid and seco-labdanoid diterpenes from Leonurus persicus (1996)
    American Chemical Society
    In:  Journal of Natural Products, 59 (2). pp. 131-134.
    Details
    Publication Date: 2020-07-22
    Description: Six new labdane diterpenoids, leopersin C (1), 15-epi-leopersin C (2), leopersin D (3), leopersin E (4), leopersin F (5), and 7-epi-leopersin F (6) were isolated from the aerial parts of Leonurus persicus. Their structures were elucidated by extensive use of 1D and 2D homonuclear and heteronuclear shift-correlated 1H−13C-NMR spectroscopic methods. Leopersin C (1) and 15-epi-leopersin C (2) were obtained as a C-15 epimeric mixture, and their structures were elucidated on this basis.
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  • 45
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    Further labdane diterpenoids isolated from Leonurus persicus (1997)
    American Chemical Society
    In:  Journal of Natural Products, 60 (9). pp. 874-879.
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    Publication Date: 2020-07-22
    Description: Seven new labdane diterpenoids, leopersin G−L (1−4, 6−7) and 15-epi-leopersin J (5), and two known ones, 13-hydroxyballonigrinolide (8) and ballotenol (9), were isolated from the aerial parts of Leonurus persicus along with β-sitosterol and stigmasterol. The structure determinations were mainly based on 1D and 2D NMR spectra. The stereochemical configuration of ballotenol (9) was reestablished by 2D ROESY spectroscopy and by single-crystal X-ray diffraction analysis.
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  • 46
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    Detailed 1H- and 13C-nmr investigations of some diterpenes isolated from Leonurus persicus (1995)
    American Chemical Society
    In:  Journal of Natural Products, 58 (10). pp. 1543-1554.
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    Publication Date: 2020-07-22
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  • 47
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    Automated In-Line Extraction of Uranium(VI) from Raffinate Streams with Online Detection by Cathodic Stripping Voltammetry (1995)
    American Chemical Society
    In:  Analytical Chemistry, 67 (21). pp. 3903-3910.
    Details
    Publication Date: 2014-02-04
    Description: An automated method for on-site monitoring of uranium(VI) in raffinate streams originating from nuclear fuel reprocessing plants is described. An in-line stripping procedure (based on liquid/liquid extraction) was developed to extract U(VI) from this stream, a solvent mixture of 20% tributyl phosphate and nitric acid in kerosene, into an aqueous sodium sulfate solution, Degradation products in the solvent mixture, especially dibutyl phosphate, give rise to very strong complexes and are responsible for moderate but constant U(VI) recoveries (similar to 50%), Optimal conditions for in-line stripping comprise a mixing ratio of extractant (0.5 M sodium sulfate in water)/solvent mixture of similar to 3 and a pumping rate of similar to 0.4 mL min(-1) of the solvent mixture. The determination of U(VI) was by on-line cathodic stripping voltammmetry (CSV), preceded by adsorptive collection of the U(VL) as an oxine complex onto a hanging mercury drop electrode, Quantities of 1-2 mL of the aqueous extract were pumped into the voltammmetric cell and diluted (1/5 to 1/10) with a background electrolyte containing 0.1 M PIPES buffer, 2 x 10(-4) M oxine, 10(-4) M EDTA, and 0.2 M hydrazine hydrate (pH 9.0), The CSV peak for U(VI) was obtained at -0.68 V with a detection limit of 20 nM in the raffinate stream using an adsorption time of 120 s, Both the inline stripping procedure and the on-line measurement were fully automated, with a relative standard deviation in the measurements of 〈 5%.
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