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  • Articles  (192,968)
  • Institute of Electrical and Electronics Engineers (IEEE)
  • American Chemical Society (ACS)
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  • 1
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science & Technology, American Chemical Society (ACS), 57(17), pp. 6799-6807, ISSN: 0013-936X
    Publication Date: 2023-08-16
    Description: Plastic pollution has become ubiquitous with very high quantities detected even in ecosystems as remote as arctic sea ice and deepsea sediments. Ice algae growing underneath sea ice are released upon melting and can form fast-sinking aggregates. In this pilot study, we sampled and analyzed the ice algaeMelosira arcticaand ambient sea water from three locations in the Fram Strait to assess their microplastic content and potential as a temporary sink and pathway to the deep seafloor. Analysis by μ-Raman and fluorescence microscopy detected microplastics (≥2.2 μm) in all samples at concentrations ranging from 1.3 to 5.7 × 104 microplastics (MP) m−3 in ice algae and from 1.4 to 4.5 × 103 MP m−3 in sea water, indicating magnitude higher concentrations in algae. On average, 94% of the total microplastic particles were identified as 10 μm or smaller in size and comprised 16 polymer types without a clear dominance. The high concentrations of microplastics found in our pilot study suggest thatM. arctica could trap microplastics from melting ice and ambient sea water. The algae appear to be a temporary sink and could act as a key vector to food webs near the sea surface and on the deep seafloor, to which its fast-sinking aggregates could facilitate an important mechanism of transport.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
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    Institute of Electrical and Electronics Engineers (IEEE)
    In:  EPIC3IEEE Journal of Selected Topics in Applied Earth Observations and Remote Sensing, Institute of Electrical and Electronics Engineers (IEEE), 14, pp. 4894-4914, ISSN: 1939-1404
    Publication Date: 2023-12-21
    Description: icrowave radiometry has provided valuable spaceborne observations of Earth’s geophysical properties for decades. The recent SMOS, Aquarius, and SMAP satellites have demonstrated the value of measurements at 1400 MHz for observ- ing surface soil moisture, sea surface salinity, sea ice thickness, soil freeze/thaw state, and other geophysical variables. However, the information obtained is limited by penetration through the subsur- face at 1400 MHz and by a reduced sensitivity to surface salinity in cold or wind-roughened waters. Recent airborne experiments have shown the potential of brightness temperature measurements from 500–1400 MHz to address these limitations by enabling sensing of soil moisture and sea ice thickness to greater depths, sensing of temperature deep within ice sheets, improved sensing of sea salinity in cold waters, and enhanced sensitivity to soil moisture under veg- etation canopies. However, the absence of significant spectrum re- served for passive microwave measurements in the 500–1400 MHz band requires both an opportunistic sensing strategy and systems for reducing the impact of radio-frequency interference. Here, we summarize the potential advantages and applications of 500–1400 MHz microwave radiometry for Earth observation and review recent experiments and demonstrations of these concepts. We also describe the remaining questions and challenges to be addressed in advancing to future spaceborne operation of this technology along with recommendations for future research activities.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 3
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    Institute of Electrical and Electronics Engineers (IEEE)
    In:  EPIC3IEEE Transactions on Geoscience and Remote Sensing, Institute of Electrical and Electronics Engineers (IEEE), 61, pp. 1-16, ISSN: 0196-2892
    Publication Date: 2024-01-18
    Description: Radio-echo sounding (RES) reveals patches of high backscatter in basal ice units, which represent distinct englacial features in the bottom parts of glaciers and ice sheets. Their material composition and physical properties are largely unknown due to their direct inaccessibility but could provide significant information on the physical state as well as on present and past processes at the ice-sheet base. Here, we investigate the material properties of basal ice units by comparing measured airborne radar data with synthetic radar responses generated using electromagnetic (EM) forward modeling. The observations were acquired at the onset of the Jutulstraumen Ice Stream in western Dronning Maud Land (DML) (East Antarctica) and show strong continuous near-basal reflections of up to 200-m thickness in the normally echo-free zone (EFZ). Based on our modeling, we suggest that these high-backscatter units are most likely composed of point reflectors with low dielectric properties, suggesting thick packages of englacial entrained debris. We further investigate the effects of entrained particle size, and concentration in combination with different dielectric properties, which provide useful information to constrain the material composition of radar-detected units of high backscatter. The capability and application of radar wave modeling in complex englacial environments is therefore a valuable tool to further constrain the composition of basal ice and the physical conditions at the ice base.
    Repository Name: EPIC Alfred Wegener Institut
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  • 4
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    Institute of Electrical and Electronics Engineers (IEEE)
    In:  EPIC3IEEE Transactions on Geoscience and Remote Sensing, Institute of Electrical and Electronics Engineers (IEEE), 57(1), pp. 623-623, ISSN: 0196-2892
    Publication Date: 2024-03-20
    Description: There was a typographical error in [1, eq. (18)]. Instead of (Formula Presented). The equation describes the second-order statistics of the interferometric phases. Its significance lies in the fact that from it, one can derive the statistical properties of a wide range of quantities estimated from an interferometric stack, including the closure phases that we addressed in the paper. The other equations, numerical results, and the conclusions remain unaffected, because the error was of a purely typographical nature.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , notRev
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  • 5
    Publication Date: 2024-04-04
    Description: Second-generation anticoagulant rodenticides (SGARs) are widely used to control rodent populations, resulting in the serious secondary exposure of predators to these contaminants. In the United Kingdom (UK), professional use and purchase of SGARs were revised in the 2010s. Certain highly toxic SGARs have been authorized since then to be used outdoors around buildings as resistance-breaking chemicals under risk mitigation procedures. However, it is still uncertain whether and how these regulatory changes have influenced the secondary exposure of birds of prey to SGARs. Based on biomonitoring of the UK Common Buzzard (Buteo buteo) collected from 2001 to 2019, we assessed the temporal trend of exposure to SGARs and statistically determined potential turning points. The magnitude of difenacoum decreased over time with a seasonal fluctuation, while the magnitude and prevalence of more toxic brodifacoum, authorized to be used outdoors around buildings after the regulatory changes, increased. The summer of 2016 was statistically identified as a turning point for exposure to brodifacoum and summed SGARs that increased after this point. This time point coincided with the aforementioned regulatory changes. Our findings suggest a possible shift in SGAR use to brodifacoum from difenacoum over the decades, which may pose higher risks of impacts on wildlife.
    Keywords: apex predator ; conditional inference trees ; effectiveness evaluation ; regulatory changes ; seasonal fluctuation
    Repository Name: National Museum of Natural History, Netherlands
    Type: info:eu-repo/semantics/article
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  • 6
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science & Technology, American Chemical Society (ACS), 58(9), pp. 4302-4313, ISSN: 0013-936X
    Publication Date: 2024-03-28
    Description: The pollution of the marine environment with plastic debris is expected to increase, where ocean currents and winds cause their accumulation in convergence zones like the North Pacific Subtropical Gyre (NPSG). Surface-floating plastic (〉330 μm) was collected in the North Pacific Ocean between Vancouver (Canada) and Singapore using a neuston catamaran and identified by Fourier-transform infrared spectroscopy (FT-IR). Baseline concentrations of 41,600–102,700 items km–2 were found, dominated by polyethylene and polypropylene. Higher concentrations (factors 4–10) of plastic items occurred not only in the NPSG (452,800 items km–2) but also in a second area, the Papaha̅naumokua̅kea Marine National Monument (PMNM, 285,200 items km–2). This second maximum was neither reported previously nor predicted by the applied ocean current model. Visual observations of floating debris (〉5 cm; 8–2565 items km–2 and 34–4941 items km–2 including smaller “white bits”) yielded similar patterns of baseline pollution (34–3265 items km–2) and elevated concentrations of plastic debris in the NPSG (67–4941 items km–2) and the PMNM (295–3748 items km–2). These findings suggest that ocean currents are not the only factor provoking plastic debris accumulation in the ocean. Visual observations may be useful to increase our knowledge of large-scale (micro)plastic pollution in the global oceans.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 7
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), 58(10), pp. 4637-4647, ISSN: 0013-936X
    Publication Date: 2024-04-08
    Description: Marine dissolved organic matter (DOM) is an important component of the global carbon cycle, yet its intricate composition and the sea salt matrix pose major challenges for chemical analysis. We introduce a direct injection, reversed-phase liquid chromatography ultrahigh resolution mass spectrometry approach to analyze marine DOM without the need for solid-phase extraction. Effective separation of salt and DOM is achieved with a large chromatographic column and an extended isocratic aqueous step. Postcolumn dilution of the sample flow with buffer-free solvents and implementing a counter gradient reduced salt buildup in the ion source and resulted in excellent repeatability. With this method, over 5,500 unique molecular formulas were detected from just 5.5 nmol carbon in 100 μL of filtered Arctic Ocean seawater. We observed a highly linear detector response for variable sample carbon concentrations and a high robustness against the salt matrix. Compared to solid-phase extracted DOM, our direct injection method demonstrated superior sensitivity for heteroatom-containing DOM. The direct analysis of seawater offers fast and simple sample preparation and avoids fractionation introduced by extraction. The method facilitates studies in environments, where only minimal sample volume is available e.g. in marine sediment pore water, ice cores, or permafrost soil solution. The small volume requirement also supports higher spatial (e.g., in soils) or temporal sample resolution (e.g., in culture experiments). Chromatographic separation adds further chemical information to molecular formulas, enhancing our understanding of marine biogeochemistry, chemodiversity, and ecological processes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 8
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), ISSN: 0013-936X
    Publication Date: 2024-04-08
    Description: Marine permeable sediments are important sites for organic matter turnover in the coastal ocean. However, little is known about their role in trapping dissolved organic matter (DOM). Here, we examined DOM abundance and molecular compositions (9804 formulas identified) in subtidal permeable sediments along a near- to offshore gradient in the German North Sea. With the salinity increasing from 30.1 to 34.6 PSU, the DOM composition in bottom water shifts from relatively higher abundances of aromatic compounds to more highly unsaturated compounds. In the bulk sediment, DOM leached by ultrapure water (UPW) from the solid phase is 54 ± 20 times more abundant than DOM in porewater, with higher H/C ratios and a more terrigenous signature. With 0.5 M HCl, the amount of leached DOM (enriched in aromatic and oxygen-rich compounds) is doubled compared to UPW, mainly due to the dissolution of poorly crystalline Fe phases (e.g., ferrihydrite and Fe monosulfides). This suggests that poorly crystalline Fe phases promote DOM retention in permeable sediments, preferentially terrigenous, and aromatic fractions. Given the intense filtration of seawater through the permeable sediments, we posit that Fe can serve as an important intermediate storage for terrigenous organic matter and potentially accelerate organic matter burial in the coastal ocean.
    Repository Name: EPIC Alfred Wegener Institut
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  • 9
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    American Chemical Society (ACS)
    In:  EPIC3Analytical Chemistry, American Chemical Society (ACS), 90(24), pp. 14188-14197, ISSN: 0003-2700
    Publication Date: 2024-04-09
    Description: Investigating the biogeochemistry of dissolved organic matter (DOM) requires the synthesis of data from several complementary analytical techniques. The traditional approach to data synthesis is to search for correlations between measurements made on the same sample using different instruments. In contrast, data fusion simultaneously decomposes data from multiple instruments into the underlying shared and unshared components. Here, Advanced Coupled Matrix and Tensor Factorization (ACMTF) was used to identify the molecular fingerprint of DOM fluorescence fractions in Arctic fjords. ACMTF explained 99.84% of the variability with six fully shared components. Individual molecular formulas were linked to multiple fluorescence components and vice versa. Molecular fingerprints differed in diversity and oceanographic patterns, suggesting a link to the biogeochemical sources and diagenetic state of DOM. The fingerprints obtained through ACMTF were more specific compared to traditional correlation analysis and yielded greater compositional insight. Multivariate data fusion aligns extremely complex, heterogeneous DOM data sets and thus facilitates a more holistic understanding of DOM biogeochemistry.
    Repository Name: EPIC Alfred Wegener Institut
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  • 10
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), 53(15), pp. 8747-8756, ISSN: 0013-936X
    Publication Date: 2024-04-12
    Description: Recent studies pointed to a high ice nucleating activity (INA) in the Arctic sea surface microlayer (SML). However, related chemical information is still sparse. In the present study, INA and free glucose concentrations were quantified in Arctic SML and bulk water samples from the marginal ice zone, the ice-free ocean, melt ponds, and open waters within the ice pack. T50 (defining INA) ranged from −17.4 to −26.8 °C. Glucose concentrations varied from 0.6 to 51 μg/L with highest values in the SML from the marginal ice zone and melt ponds (median 16.3 and 13.5 μg/L) and lower values in the SML from the ice pack and the ice-free ocean (median 3.9 and 4.0 μg/L). Enrichment factors between the SML and the bulk ranged from 0.4 to 17. A positive correlation was observed between free glucose concentration and INA in Arctic water samples (T50(°C) = (−25.6 ± 0.6) + (0.15 ± 0.04)·Glucose(μg/L), RP = 0.66, n = 74). Clustering water samples based on phytoplankton pigment composition resulted in robust but different correlations within the four clusters (RP between 0.67 and 0.96), indicating a strong link to phytoplankton-related processes. Since glucose did not show significant INA itself, free glucose may serve as a potential tracer for INA in Arctic water samples.
    Repository Name: EPIC Alfred Wegener Institut
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