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  • doped ceriadisorderpair distribution functionhigh-resolution X-ray powder diffractionpercolationhierarchysolid electrolyteselectron spin resonance  (2)
  • grazing-incidence small-angle X-ray scatteringGISAXSbeam footprintlithographic inspectiongratings  (2)
  • EIGERhybrid pixel detectorselectron crystallographySAPO-34  (1)
  • International Union of Crystallography (IUCr)  (5)
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Schlagwörter
Verlag/Herausgeber
  • International Union of Crystallography (IUCr)  (5)
Erscheinungszeitraum
  • 1
    Publikationsdatum: 2018-06-26
    Beschreibung: An error in the paper by Pflüger, Soltwisch, Probst, Scholze & Krumrey [IUCrJ (2017), 431–438] is corrected.
    Schlagwort(e): grazing-incidence small-angle X-ray scatteringGISAXSbeam footprintlithographic inspectiongratings
    Digitale ISSN: 2052-2525
    Thema: Geologie und Paläontologie , Physik
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Publikationsdatum: 2017-05-25
    Beschreibung: Grazing-incidence small-angle X-ray scattering (GISAXS) is often used as a versatile tool for the contactless and destruction-free investigation of nanostructured surfaces. However, due to the shallow incidence angles, the footprint of the X-ray beam is significantly elongated, limiting GISAXS to samples with typical target lengths of several millimetres. For many potential applications, the production of large target areas is impractical, and the targets are surrounded by structured areas. Because the beam footprint is larger than the targets, the surrounding structures contribute parasitic scattering, burying the target signal. In this paper, GISAXS measurements of isolated as well as surrounded grating targets in Si substrates with line lengths from 50 µm down to 4 µm are presented. For the isolated grating targets, the changes in the scattering patterns due to the reduced target length are explained. For the surrounded grating targets, the scattering signal of a 15 µm × 15 µm target grating structure is separated from the scattering signal of 100 µm × 100 µm nanostructured surroundings by producing the target with a different orientation with respect to the predominant direction of the surrounding structures. As virtually all lithographically produced nanostructures have a predominant direction, the described technique allows GISAXS to be applied in a range of applications, e.g. for characterization of metrology fields in the semiconductor industry, where up to now it has been considered impossible to use this method due to the large beam footprint.
    Schlagwort(e): grazing-incidence small-angle X-ray scatteringGISAXSbeam footprintlithographic inspectiongratings
    Digitale ISSN: 2052-2525
    Thema: Geologie und Paläontologie , Physik
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Publikationsdatum: 2018-02-15
    Beschreibung: Electron crystallography is a discipline that currently attracts much attention as method for inorganic, organic and macromolecular structure solution. EIGER, a direct-detection hybrid pixel detector developed at the Paul Scherrer Institut, Switzerland, has been tested for electron diffraction in a transmission electron microscope. EIGER features a pixel pitch of 75 × 75 µm2, frame rates up to 23 kHz and a dead time between frames as low as 3 µs. Cluster size and modulation transfer functions of the detector at 100, 200 and 300 keV electron energies are reported and the data quality is demonstrated by structure determination of a SAPO-34 zeotype from electron diffraction data.
    Schlagwort(e): EIGERhybrid pixel detectorselectron crystallographySAPO-34
    Digitale ISSN: 2052-2525
    Thema: Geologie und Paläontologie , Physik
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Publikationsdatum: 2015-08-01
    Beschreibung: A new hierarchical approach is presented for elucidating the structural disorder in Ce1−xGdxO2−x/2 solid solutions on different scale lengths. The primary goal of this investigation is to shed light on the relations between the short-range and the average structure of these materials via an analysis of disorder on the mesocopic scale. Real-space (pair distribution function) and reciprocal-space (Rietveld refinement and microstructure probing) analysis of X-ray powder diffraction data and electron spin resonance (ESR) investigations were carried out following this approach. On the local scale, Gd- and Ce-rich droplets (i.e. small regions a few ångströms wide) form, exhibiting either a distorted fluorite (CeO2) or a C-type (Gd2O3) structure in the whole compositional range. These droplets can then form C-type nanodomains which, for Gd concentrations xGd ≤ 0.25, are embedded in the fluorite matrix. At the site percolation threshold pC for a cubic lattice (xGd = pC ≃ 0.311), C-type nanodomains percolate inside each crystallite and a structural phase transformation is observed. When this occurs, the peak-to-peak ESR line width ΔHpp shows a step-like behaviour, which can be associated with the increase in Gd–Gd dipolar interactions. A general crystallographic rationale is presented to explain the fluorite-to-C-type phase transformation. The approach shown here could be adopted more generally in the analysis of disorder in other highly doped materials.
    Schlagwort(e): doped ceriadisorderpair distribution functionhigh-resolution X-ray powder diffractionpercolationhierarchysolid electrolyteselectron spin resonance
    Digitale ISSN: 2052-2525
    Thema: Geologie und Paläontologie , Physik
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    facet.materialart.
    Unbekannt
    International Union of Crystallography (IUCr)
    In: IUCrJ
    Publikationsdatum: 2015-08-23
    Schlagwort(e): doped ceriadisorderpair distribution functionhigh-resolution X-ray powder diffractionpercolationhierarchysolid electrolyteselectron spin resonance
    Digitale ISSN: 2052-2525
    Thema: Geologie und Paläontologie , Physik
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
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