ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Polymer and Materials Science  (3,047)
  • 1980-1984  (3,047)
  • 1982  (3,047)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 1-14 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Wasserstoffversprödung von KonstruktionswerkstoffenDie Wasserstoffversprödung wird sowohl als Teilaspekt der Spannungsrißkorrosion als auch als eigenständiges Phänomen betrachtet. Im ersten Teil der vorliegenden Übersicht werden die Methoden erörtert, die heute zur Klärung der Rolle von Wasserstoffversprödung bei der Spannungsrißkorrosion benutzt werden. Dabei wird eine Betrachtungsweise eingeführt, die sich auf alle Werkstoffe anwenden läßt. Der zweite Teil behandelt diejenigen Aspekte der Versprödungstheorie, die bisher noch nicht geklärt werden konnten, so z. B. die Ergebnisse der Schallemissionsanalyse, die Lage der durch Wasserstoffversprödung erzeugten Bruchzone vor der Rißspitze oder die kritische Wasserstoffkonzentration; dabei werden einige in neuerer Zeit zur Klärung vorgeschlagene Untersuchungsmethoden behandelt.
    Notes: Hydrogen embrittlement (HE) is considered to be part of stress corrosion cracking (SCC) problem and as a phenomenon of its own. In the first part of the review the present day methods for an identification of the role of HE in SCC are discussed and a general approach for any construction material is proposed to solve this question. The second part is concerned with those aspects of the HE theory which; are still not clear (acoustic data, the disposition of the fracture zones by HE ahead of the crack tip, critical hydrogen concentration) and with some newly proposed experiments.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 14-24 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Erosion corrosion in a wet steam loopIn a technical loop of a power plant erosion corrosion behaviour of the steels C 22.8, 15 Mo 3 and 10 Cr Mo 9 10 was investigated in test periods up to 78 days under definite conditions in wet steam of a relative steam content of about 75% at a temperature of 185 to 200°C and flow velocities up to 180 m/s. For comparison one test was carried out also in hot steam. By gravimetric, metallographic, SEM- and Xray-diffraction analysis essential information was obtained on the kinetics of erosion corrosion and the structure of oxide coatings. The rate of erosion corrosion shows a high dependence on time and steel composition and decrease in the above mentioned order. Structure and quality of the oxide layer also show a remarkable dependence on steel composition.
    Notes: In einer großtechnischen Versuchsstrecke eines Kraftwerkes wurde das Erosionskorrosions-Verhalten der Werkstoffe C 22.8, 15 Mo 3 und 10 Cr Mo 9 10 in Naßdampf mit einem relativen Dampfgehalt von etwa 75% bei 185-200°C bei Strömungsgeschwindigkeiten bis zu 180 m/s in Langzeitversuchen (bis zu 78 Tagen) untersucht. Vergleichsweise wurde auch die Beanspruchung durch Heißdampf mit in die Untersuchungen einbezogen. Durch gravimetrische, metallografische, REM- und Röntgenfeinstruktur-Untersuchungen wurden wesentliche Erkenntnisse zum zeitlichen Verlauf der Erosionskorrosion sowie über den Aufbau der Oxidschichten erhalten. Der Abtrag durch Erosionskorrosion zeigt eine starke Zeitabhängigkeit und nimmt in der o. a. Reihenfolge der Werkstoffe deutlich ab. Struktur und Eigenschaften der Oxidschichten lassen ebenfalls eine deutliche Abhängigkeit von der Stahlzusammensetzung erkennen.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 39-47 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 29-34 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations into the oxidic passive layer produced on iron by permanganateBy means of potential measurements on iron electrodes which was passivated by permanganate, and by application of the radiotracer technique the conditions of layer formation could been optimized. From stabil formed layer electrodes the electrode reaction and by registration of the drift of pH value during the immersion in unbuffered electrolyte solutions the isoelectric range of their outside layer component was determined. The galvanostatic cathodic reduction of the layer additional informations about the existence of several layer components was obtained. On the basis of this experiments a model to the qualitative composition of passive layer which formed on iron in permanganate solutions is suggested.
    Notes: Mittels Potentialmessungen an durch Permanganat passivierten Eisenelektroden in passivatorfreien Lösungen und durch Anwendung der Radiotracertechnik konnten die Schichtbildungsbedingungen optimiert werden. Von stabil erzeugten Deckschichtelektroden wurde die Elektrodenreaktion und außerdem durch Erfassung der Drift des pH Wertes bei Immersion in ungepufferte Elektrolytlösungen der isoelektrische Bereich ihrer äußeren Schichtkomponente ermittelt. Die galvanostatische kathodische Reduktion der Deckschicht führte zu weiteren Informationen über die Existenz einzelner Schichtkomponenten. Auf der Basis dieser Untersuchungen wird ein Modell über die qualitative Zusammensetzung der in Permanganatlosungen auf Eisen entstehenden Passivschicht vorgeschlagen.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 35-39 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Mössbauer and ESCA investigations on the formation of oxidic iron phases in aqueous solution under the influence of organic corrosion inhibitorsCorrosion layers on steel grown in water of well defined hardness and chloride concentration were studied by Mossbauer and ESCA spectroscopy with particular emphasis on the influence of added organic inhibitors. Relatively thick layers were found with an unexpectedly small iron content (as FeOOH). The layers contain a remarkable amount of constituent ions from the solution and fragments of the inhibitors. The latter seem to be decomposed by the corrosive medium: It is assumed that the whole organic molecule determines the kind of transportation of the inhibitor to the iron metal, but that the inhibition itself is due to functional groups only.
    Notes: Korrosionsschichten auf Stahl nach Exposition in Wasser mit bestimmter Härte und Chloridgehalt wurden hinsichtlich der Wirksamkeit beigefügter organischer Inhibitoren mittels Mößbauer- und ESCA-Spektroskopie untersucht. Es entstehen relativ dicke Schichten mit einem unerwartet niedrigen Eisengehalt in Form von FeOOH. Die Schichten enthalten merkliche Mengen von Ionen aus der Testlösung und auch Abbauprodukte der Inhibitormoleküle. Letztere werden anscheinend in dem korrosiven Medium zersetzt. Es ist anzunehmen, daß das Gesamtmolekül zwar den Transport des Inhibitors zum Metall beeinflußt, die eigentliche Inhibierung aber allein durch funktionelle Gruppen erfolgt.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 25-28 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Einfluß von Chloridionen auf das Korrosionsverhalten von Eisen-Nickel-Legierungen in SchwefelsäureDer Einfluß von Chloridionen auf das Korrosionsverhalten von binären Eisen-Nickel-Legierungen in Schwefelsäure wurde durch Messung des Polarisationswiderstandes und der potentiodynamischen Polarisation ermittelt. Für die untersuchten Legierungen wird ein mäßiger Inhibitoreffekt der Chloridionen festgestellt, und zwar in Abhängigkeit, vom pH des Mediums sowie von der Zusammensetzung und dem Gefüge der untersuchten Legierungen. Es wurde gezeigt, daß die Chloridionen die kathodische Wasserstoffentwicklung inhibieren und die anodische Metallauflösung stimulieren, wobei der Einfluß auf die kathodische Reaktion stärker ist. Mit Hilfe der Atomabsorptionsanalyse konnte festgestellt werden, daß bei der Korrosion keine bevorzugte Auflösung einer der beiden Legierungskomponenten stattfindet.
    Notes: The effect of chloride ions on the corrosion behaviour of binary iron-nickel alloys in sulphuric acid solutions has been investigated using polarization resistance and potentiodynamic polarization measurements. A moderate inhibition effect of the chloride ions on the corrosion of these alloys has been found, which depends on the pH of the medium, as well as on the composition and the structure of the alloys investigated. It has been shown that the action of the chloride ions on the partial corrosion reactions is reflected by an inhibition of the cathodic hydrogen evolution reaction and by an activation of the anodic metal dissolution reaction, the first effect being stronger. Using atomic absorption analysis it has been established that no preferentional dissolution of the alloy components in the presence and in the absence of chloride ions occurs during the corrosion of the iron-nickel alloys.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 47-55 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 55-74 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 75-75 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 11
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 12
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 75-76 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 13
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R1 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 14
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R3 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 15
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R9 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 16
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R4 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 17
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R18 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 18
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R18 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 19
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R19 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 20
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R19 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 21
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 22
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 77-82 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Detaillierte Untersuchung von zwei nichtrostenden Stählen nach 20 000 Stunden Oxidation in CO2/2% CO bei hohem DruckMit Hilfe von Rasterelektronenmikroskopie, Mikrosonde und Kernmikrosonde wurden zwei Proben von 18/8-Stählen eingehend untersucht; die Proben waren repräsentativ für die beiden Extreme des nach einem parabolischen Zeitgesetz bei 600°C gewachsenen Zunders. Auf dem im Vakuum angelassenen Stahl 316 erfolgte die Zunderbildung mit hoher Geschwindigkeit, wobei innen eine vorwiegend einheitliche Spinellschicht vorlag, jedoch mit einem chromreichen und nickelarmen Spinell (geheiltes Oxid) an der Grenzfläche Metall/Zunder. Das darunter befindliche Metall war stark aufgekohlt, wobei die Kohlenstoffkonzentration in der Nähe der Metalloberfläche etwa 1 Gew.-% betrug. Bei dem Material mit geringerer Verzunderungsgeschwindigkeit war die innere Zunderschicht komplexer aufgebaut und das Metall weniger stark aufgekohlt. Die Ergebnisse werden unter Berücksichtigung der Zusammensetzung der inneren Oxidschicht und der unter Ausheilung erfolgenden Schichtbildung erläutert, wobei dem dort vorliegenden Sauerstoffpotential der geschwindigkeitsbestimmende Einfluß zugeschrieben wird.
    Notes: Detailed examination has been carried out on two specimens of 18/8 steels representing the extremes of the rates of parabolic duplex scale growth at 600°C using metallography, scanning electron microscopy, microprobe and nuclear microprobe analysis.The high growth rate material, vacuum annealed 316, had an inner layer of mainly a uniform spinel but with a chromium rich low nickel spinel (healed oxide) at the metal interface. The underlying alloy was extensively carburised with a carbon concentration near the metal surface of ∼1 wt%. The low growth rate material had a more complex inner layer and a much lower degree of carburisation. The results are explained in terms of the composition of the inner oxide and the rate of healing layer formation being controlled by the prevailing oxygen potential there.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 23
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 83-88 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: A study of the dealloying resistance of noble metal dental alloys.In connection with the development of low gold dental alloys the corrosion resistance of homogeneous gold-palladium-silver-experimental alloys was investigated in a chloride solution. Analogous measurements were made with several noble metal containing intermetallic phases which may be present in dental alloys of more complex composition. The results indicate a high corrosion resistance of the homogeneous gold-palladium-silver-alloys, since their free corrosion potentials are always situated within a region of their anodic polarization curves, where the current density of metal dissolution is extremely low. Within the composition limits of these alloys the substitution of gold by palladium did not reduce the extension of this “region of immunity” in a significant way. Intermetallic phases, however, as present in the systems silver-tin, silver-palladium-tin and silver-palladium-indium show a clearly restricted “region of immunity” and, at the free corrosion potential, are dissolved at a relatively high rate.
    Notes: Im Zusammenhang mit der Entwicklung goldarmer Dentallegierungen wurde in einem Chloridelektrolyten die, Korrosionsbeständigkeit homogener Gold-Palladium-Silber-Modellegierungen untersucht. Analoge Messungen wurden an verschiedenen edelmetallhaltigen intermetallischen Phasen durchgeführt, die in komplizierter zusammengesetzten Dentallegierungen auftreten können. Die Meßergebnisse zeigen, daß die Gold-Palladium-Silber-Legierungen eine hohe Korrosionsbeständigkeit aufweisen, da ihre Korrosionspotentiale durchweg in jenem Bereich ihrer anodischen Stromspannungskurve liegen, in dem die Geschwindigkeit der Metallauflösung extrem klein ist. Die Ausdehnung dieses “Resistenzbereiches” wird nicht wesentlich verkleinert, wenn innerhalb der hier vorgegebenen Grenzen Gold teilweise durch Palladium substituiert wird. Intermetallische Phasen der Systeme Silber-Zinn, Silber-Palladium-Zinn und Silber-Palladium-Indium weisen dagegen einen deutlich eingeschränkten Resistenzbereich auf und werden bereits beim Korrosionspotential vergleichsweise schnell aufgelöst.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 24
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 94-98 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Methode zur Eliminierung der verstärkten anodischen Korrosion von mit anodisch geschützten Apparaten verbundenen AnlagenZwei Methoden zur Eliminierung des ungünstigen Einflusses von anodischem Schutz auf mit diesen Apparaturen verbundenen Anlagen werden untersucht; dabei werden mit einem Stahl des Typs Cr 18 9 NiTi in 50%iger Schwefelsäure bis 20°C Modellmessungen unter potentiostatischen Bedingungen durchgeführt. Die Verwendung eines isolierenden Abschnitts im kritischen Potentialbereich bei der Passivierung von Rohren führt nicht zur Ausschaltung der verstärkten Korrosion, die durch den anodischen Schutz einer größeren Apparatur bedingt ist. Vollkommen ausschalten lässt sich der negative Effekt hingegen durch Sekundärelektroden, die einen elektrischen Strom liefern, so daß der gewünschte Potentialabfall erreicht wird.
    Notes: Two techniques for eliminating the unsiderable effect of anodic protection on installations connected to the protected equipment were tested. Model measurements were carried out in a 50% solution of sulfuric acid at 20°C with a type FeCr 18 Ni9 Ti stainless steel under potentiostatic conditions.The use of an insulating section in the critical range of potentials in the case of tubing passivation does not fully eliminate the increased corrosion due to anodic protection of a major piece of equipment. However, the undesirable effect can be eliminated entirely by installing secondary electrodes which pass electric current so as to set up the desired drop of potential.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 25
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 89-93 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigation of the effect of galvanic corrosion between steel in concrete and steel in soilThe investigation of cathodic polarization of steel in concrete on samples of portland cement and blast furnace cement revealed that oxygen reduction on steel in portland cement is less hindered than on steel in blast furnace cement. As to the magnitude of the cathodic current the aeration of the samples is important. Dry stored samples before measuring case a higher current density than wet stored ones. A significant relationship of the cathodic current depending on the water/cement value and the storage time of concrete could not be ascertained. The polarization resistances for portland cement samples lie within 86 and 3000 kΩ · cm2 and for blast furnace cement samples between 430 and 5100 kΩ · cm2.The measurements of the anodic current densities on corrosion cells of steel in concrete/steel in solution and steel in wet sand respectively rendered, by varying the cathode/anode aspect ratio from 1000: 1 to 1: 1, values for portland cement samples between 560 and 1,2 μAJcm2 (corresponding to an annual corrosion of 6,5 and 0,014 mm respectively), and for blast furnace cement samples values between 730 and 0,28 μA/cm2 (corresponding to an annual corrosion rate of 8,5 and 0,003 mm respectively). A decrease of the anodic current density variable with time could not be observed during the 28 days of measurements.On account of the investigations the following conclusions can be made:A formation of a corrosion cell with steel in concrete/steel in soil is particularly then to be expected if the concrete is dry on one side, e.g. the foundation of a building where oxygen diffuses by way of the gas pores in the concrete from the inner side to the cathode. This is less serious if the concrete is fully embedded in soil and thoroughly moistened. In this case the transport of oxygen has to be carried via waterfilled pores.
    Notes: Die Untersuchung der kathodischen Polarisation von Stahl in Beton an Proben aus Portland- und Hochofenzement ergab, daß die Sauerstoffreduktion an Stahl in Portlandzement weniger gehemmt ist als an Stahl in Hochofenzement. für die Größe der kathodischen Ströme ist die Belüftung des Betons wichtig. Trocken vorgelagerte Proben liefern höhere Stromdichten als naß vorgelagerte. Eine deutliche Abhängigkeit der kathodischen Stromdichte vom Wasser/Zement-Wert und von der Auslagerungszeit des Betons konnte nicht festgestellt werden. Die Potarisationswiderstände liegen für Portlandzementproben zwischen 86 und 3000 kΩ · cm2, für Hochofenzementproben zwischen 430 und 5100 kΩ · cm2.Die Messung der anodischen Stromdichte an Korrosionselementen Stahl in Beton/Stahl in Lösung bzw. feuchtem Sand lieferte bei Variation des Flächenverhältnisses Kathode/Anode von 1000: 1 bis 1: 1 für Portlandzement-Proben. Werte zwischen 560 und 1,2 μA/cm2 (entsprechend einer Abtragungsrate von 6,5 bzw. 0,014 mm/a), für Hochofenzementproben zwischen 730 and 0,28 μA/cm2 (entsprechend einer Abtragungsrate von 8,5 bzw. 0,003 mm/a). Ein zeitlicher Abfall der Anodenstromdichte bei Messungen über 28 Tage konnte nicht beobachtet werden.Aufgrund der Untersuchungen lassen sich folgende Schlußfolgerungen ziehen:Eine Elementbildung Stahl in Beton/Stahl im Erdboden ist besonders dann zu erwarten, wenn der Beton von einer Seite trocken ist, z. B. das Fundament eines Gebäudes, in welchem von der Innenseite der Sauerstoff über die Gasporen im Beton zur Kathode diffundiert. Sie ist weniger gravierend, wenn der Beton voll im Erdboden eingebettet und durchfeuchtet ist. In diesem Fall muß der Sauerstofftransport über die mit Wasser gefüllten Poren im Beton erfolgen.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 26
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 103-106 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 27
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 107-114 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 28
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Inhibitors of corrosion 27 (1). Inhibitors of the corrosion of copper Does there exist a structure-effect-relation?Over 570 compounds of greatly varying structure have been tested under controlled conditions in agitation and pH-stat experiments designed to measure their effect as corrosion-protection agents for copper metal. The data were handled via a “SORT-F”-computer program, and the results so obtained show mostly a relationship with Pearson's “Hard-Soft” principle. Tailor-made synthesis of inhibitors following the principle is nevertheless of little value.
    Notes: Mehr als 570 Verbindungen der unterschiedlichsten Struktur wurden unter Standardbedingungen im “Schüttelversuch” und pH-statisch auf ihre Korrosionsschutzwirkung gegenüber Kupfer getestet und mit Hilfe eines Computers ausgewertet. Die erhaltenen Ergebnisse stehen relativ häufig in Übereinstimmung mit Dem “Hart-Weich-Konzept” von Pearson. Eine gezielte Synthese von Inhibitoren, die sich in diesem Konzept orientiert, ist jedoch nicht möglich.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 29
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 114-120 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 30
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 120-120 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 31
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R21 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 32
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R22 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 33
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R32 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 34
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R37 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 35
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R25 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 36
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R38 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 37
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R38 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 38
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R39 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 39
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R40 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 40
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 41
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 121-131 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Korrosion und Inhibierung in der ErdölindustrieDie Arbeit behandelt einige repräsentative Typen der durch Wasser verursachten Korrosion in verschiedenen Bereichen der Erdölindustrie. Dazu werden die grundlegenden Vorgänge untersucht, die zu diesen Korrosionsproblemen führen. Außerdem werden die Methoden erörtert, die zur Verhütung der Korrosion benutzt werden und die eine Veränderung der einwirkenden Medien und die Verwendung von Korrosionsinhibitoren zur Grundlage haben.
    Notes: This lecture reviews some representative types of aqueous corrosion problems encountered in the various facets of the petroleum industry. The fundamental processes underlying these corrosion problems are examined. In addition, commonly used methods for corrosion prevention and control which rely on modification of the corrosive environment or the use of corrosion inhibitors are discussed.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 42
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 143-145 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Potentiokinetische Kriterien bei Lochkorrosion von nichtrostenden Stählen in ChloridlösungenAus den bei 314 Versuchen mit CrNi(MoTiCu)-Stählen in Eisening III-Chloridlösung erhaltenen potentiokinetischen Kurven wurden sieben Parameter auf ihre Eignung zum Beschreiben der Lochkorrosionsbeständigkeit in Natriumchloridlösung untersucht.
    Notes: The adequacy of 7 parameters of potentiokinetic curves for evaluating the resistance to pitting corrosion in sodium chloride solutions was quantitatively assessed by reference to immersion testing in ferric chloride solutions for 11 type CrNi (MoTiCu) stainless steels on the basis of 314 experimental runs.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 43
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 132-143 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Neue nichtrostende Stähle für meerestechnische Anwendungen. Teil 1: Korrosion und mechanische Eigenschaften von ferritischen nichtrostenden StählenUntersucht wurden zwei experimentelle ferritische nichtrostende Stähle mit sehr niedrigem Gehalt an Einschlüssen (%, 22 Cr, 4,5 Ni, 3 Mo bzw. 22 Cr, 2,5 Ni, 3 Mo, Ti), hergestellt im Laboratorium und ein entsprechender handelsüblicher Stahl (%, 21 Cr, 3 Mo, Ti). Mit Hilfe von elektrochemischen und anderen Laboratoriumsmethoden wurde die Beständigkeit gegen örtliche Korrosion (Loch- und Spaltkorrosion) in Chloridlösung untersucht und such die Beständigkeit gegen interkristalline Korrosion und Spannungsrißkorrosion ermittelt; dazu warden auch bei Raumtemperatur die Zugfestigkeit und Schlagzähigkeit untersucht. Die Stähle der Typen 22 Cr - 2,5 Ni - 3 Mo -Ti und 21 Cr - 3 Mo - Ti sind danach unabhängig von ihrer Wärmebehandlung immun gegen interkristalline Korrosion und zeigen Beständigkeit gegen Lochkorrosion, die allerdings temperaturabhängig ist. Die Beständigkeit von 22 Cr - 2,5 Ni - 3 Mo gegen Spaltkorrosion ist beträchtlich besser als die des untersuchten handelsüblichen Stahls. Allgemein waren die experimentellen Stähle in heißen Chloridlösungen immun gegen Spannungsrißkorrosion.
    Notes: Two experimental ELI ferritic stainless steels (22 Cr - 2.5 Ni - 3 Mo and 22 Cr - 2.5 Ni - 3 Mo - Ti) prepared in laboratory and a commercial one (21 Cr - 3 Mo - Ti) were investigated.Electrochemical and laboratory exposure tests were carried out to define the localized corrosion resistance (pitting and crevice) of such steels in chloride solution. Intergranular and stress corrosion resistance was also evaluated. Room temperature tension tests and impact tests were performed.22 Cr - 2.5 Ni - 3 Mo - Ti and 21 Cr - 3 Mo - Ti steels are immune to intergranular corrosion whatever temperature they are heat treated at and have the same pitting corrosion resistance as a function of temperature; crevice corrosion of 22 Cr - 2.5 Ni - 3 Mo is decidely better than in the commercial 21 Cr - 3 Mo - Ti.The experimental steels were immune to stress corrosion in hot chloride environment.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 44
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Electrolytic tunnel etching of aluminium foilThe most effective method of etching aluminum foil for high voltage electrolytic capacitors is the electrolytic tunnel etching with direct current in an aqueous solution of chloride salts. Surprisingly the classical electrochemical method for determining the potentiostatic current-time curves of annealed high purity aluminum foil delivers a pure tunnel etching in a narrow range around the pitting potential. The potentiostatic current-time curves show the dynamic of the very fast and on an already etched aluminum foil not repeatable process of forming the tunnels (tunnel diameter ca. 0.2 μm; tunnel length 10-100 μm) and immediate after tunnel formation the about 1000 times slower and controllable process of widening these tunnels in the region of passivation current density.
    Notes: Elektrolytische Gleichstrom-Tunnelätzung von Aluminiumfolie in wäßriger Chloridlösung ist das effektivste Verfahren zur Herstellung hochwertiger Anodenfolien für Hochvolt-Elektrolyt-Kondensatoren. Überraschenderweise ergibt auch die klassische elektrochemische Methode der Ermittlung potentiostatischer Strom-Zeitkurven an rekristallisierter Reinst-Aluminiumfolie in einem begrenzten Potentialbereich in der Umgebung des Lochfraßpotentials eine reine Tunnelätzung. Potentiostatische Strom-Zeitkurven widerspiegeln die Dynamik der sehr schnell und an einer bereits geätzten Folie nicht wiederholbar ablaufenden Tunnelbildung (Tunneldurchmesser etwa 0,2 μm; Tunnellänge 10-100 μm) und der zeitlich daran anschließenden etwa 1000fach langsameren und im Existenzbereich der Passivstromdichte steuerbaren Tunnelerweiterung.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 45
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 163-169 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 46
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 150-154 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Einfluß von Lanthaniden und der Stabilität von Sulfideinschlüssen auf die örtliche Korrosion niedriglegierter StähleDer Einfluß der Seltenen Erden (RE) auf die Passivierbarkeit und die Anfälligkeit zum Chlorid-Durchbruch niedriglegierter Stähle wurde untersucht. Die Analyse mit einer Elektronenmikrosonde hat gezeigt, daß der Effekt von der Art der RE abhängig ist und mit einer Änderung der Zusammensetzung und Morphologie der MnS-Einschlüsse, die die Stähle ohne RE aufweisen, verknüpft ist. La scheint das ungünstigste Element zu sein. Die Instabilität der La-Sulfide in Luft führt zu ihrer spontanen Oxidierung. Die Oxidationsprodukte wachsen wie „Blumen“ auf der Metalloberfläche, was die Lochbildung begünstigt.
    Notes: Effect of alloying with rare earth elements RE (La, Pd + Nd, or so called “Mischmetall” containing Ce, Pr, Nd, La and traces of the other RE) on the ability to passivate and susceptibility to chloride breakdown of low alloys steels was investigated. Electron microprobe analysis revealed that the effect of RE depends upon the element and is connected with a modification of the composition and morphology of MnS inclusions present within the steels without RE addition. La seems to be most detrimental. The nonstability of La sulfide inclusions in air results in their spontaneous oxidation and growth into fantastic “flower-like” forms which facilitates the formation of corrosion pits.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 47
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 169-186 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 24 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 48
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 155-163 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Triphenylmethanfarben als Korrosionsinhibitoren für Aluminium-Kupfer-Legierungen in SalzsäureDie Inhibierung der Korrosion von Aluminium B 26 S in Salzsäure durch Triphenylmethan-, Anthrachinon- und Acridinfarben wurde unter Berücksichtigung von Säurekonzentration, Inhibitordosierung, Versuchsdauer und Temperatur untersucht. Im allgemeinen nimmt bei konstanter Säurekonzentration der Hemmwert von Malachitgrün, Methylviolett 6 B and „light green“ mit der Inhibitorkonzentration zu, während der von Fuchsinbase und Kristallviolett mit zunchmender lnhibitorkonzcntration geringer wird. Bei konstanter Inhibitorkonzentration nimmt andererseits die Wirksamkeit aller untersuchten Verbindungen (mit Ausnahme von Methylviolett 6 B und Acridinorange) mit steigender Säurekonzentration zu. Der Hemmwert aller untersuchten Verbindungen steigt im Temperaturbereich 20-50°C mit der Temperatur, während kein Einfluß der Versuchsdauer zu erkennen ist. Bei einer lnhibitorkonzentration von 0,1% in 0,5 M Salzsäure nimmt der Hemmwert in der folgenden Reihe zu: Fuchsinsäure (32%) 〈 Acridinorange 〈 Fuchsinbase (39%) 〈 Alizarinrot S (46%) 〈 Methylviolett 6 B (50%) 〈 Malachitgrun (64%) 〈 Kristallviolett (70%) 〈 „light green“ (80%).Die Wirkung der Inhibitoren scheint durch Absorption nach einer Langmuir-Adsorptionsisotherme bedingt zu sein. Das wird durch die Korrosionspotentiale bestätigt; allerdings dürfte bei galvanostatischer Polarisation die Kathode bevorzugt polarisiert werden.
    Notes: The inhibition of the corrosion of B 26 S aluminium in HCl solutions by triphenylmethane, anthraquinoid and acridine dyes has been studied in relation to the concentration of acid and inhibitor, duration of immersion and temperature. In general, at constant acid concentration, the inhibiting efficiency of malachite green, methyl violet 6 B and light green increases, whereas that of fuchsine base and crystal violet decreases as the inhibitor concentration increases. At constant inhibitor concentration the efficiency of all the compounds except methyl violet 6 B and acridine orange increases with increasing acid concentration. The inhibitive efficiency of all the compounds increases with temperature in the range 20-50°C, but no dependence can be recognized on the duration of immersion. At an inhibitor concentration of 0.1% in 0.5 M HCl the efficiency increases in the order: fuchsine acid (32%) 〈 acridine orange ≤ fuchsine base (39%) 〈 alizarin red S (46%) 〈 methyl violet 6 B (50%) 〈 malachite green (64%) 〈 crystal violet (70%) 〈 light green (80%).The inhibitors appear to function through adsorption following the Langmuir adsorption isotherm. From the corrosion potentials the inhibitors appear to function through general adsorption but under galvanostatic polarisation conditions, the cathode appears to be preferentially polarised.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 49
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 186-186 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 50
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 51
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 52
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 187-187 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 53
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 187-187 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 54
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 55
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 187-188 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 56
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 188-188 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 57
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 58
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 188-188 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 59
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R41 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 60
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R42 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 61
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R43 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 62
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R49 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 63
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R57 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 64
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R57 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 65
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R57 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 66
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R58 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 67
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R58 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 68
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 69
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Inhibiors of corrosion 28 (1). 2-Aminopyrimidine (2-AP) as an inhibior of the corrosion of copper in salt solutions under oxygen2-Aminopyrimidine is at present the best inhibitor known for the corrosion of copper, as measured under controlled conditions. A protective coating is created on the copper in conjunction with Cu1+ ion as these form leave the surface. The coating at the surface was studied on variation of: (a) the concentration of 2-AP and Cu2+ ions, (b) the rate of agitation of the liquid medium and (c) the type of anion present in the corrosive medium. Some insight into the nature of the coating process was obtained via a rest-potential/time measurements, current voltage curves, polarisation/resistance curves and experiments interrupted in the course of the corrosion, all carried out with/without 2-AP and with/without added Cu2+ ions.
    Notes: 2-Aminopyrimidin ist der z. Z. beste Inhibitor der Korrosion von Kupfer unter Standardbedingungen. Mit den aus der Oberfläche der Kupferprobe austretenden oder gebildeten Cu1+-Ionen baut sich eine Schutzschicht auf. Die Ausbildung dieser Deckschicht wird studiert als Funktion: (a) der Konzentration an 2-AP und der Cu2+-Ionen, (b) der Strömungsgeschwindigkeit und (c) in Abhängigkeit von der Art der Anionen im korrosiven Medium. Ruhepotential-Zeit-Messungen, Strom-Spannungskurven, Polarisationswiderstandskurven und Halteversuche, ohne und mit 2-AP sowie ohne und mit Cu2+-Ionen vermitteln einen Einblick in den Aufbau der Deckschicht.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 70
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 203-206 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Free- und Wilson-Beziehung zwischen der Molekülstruktur und der korrosionsinhibierenden Wirkung einiger ImidazolineIn unbelüfteten schwefelwasserstoffhaltigen Medien wurde die Inhibierung der Korrosion von Stahl N 80 durch eine homologe Reihe von Imidazolinen potentiokinetisch gemessen. Die dabei erhaltenen Daten wurden mit Hilfe der Free-Wilson-Beziehung mit der Struktur dieser Moleküle korreliert. Mit Hilfe dieser Beziehungen ist es gelungen, das Verhalten einiger Derivate exakt vorauszusagen.
    Notes: In deaerated media containing hydrogen sulfide, the inhibition of the corrosion of N 80 steel by a homologous series of imidazolines was measured potentiokinetically. The data obtained were correlated to the structure of these molecules by means of Free and Wilson relationships. These correlations, allowed the behaviour of some derivatives to be predicted successfully.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 71
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations into the active/passive transition of 304 stainless steel in organic media containing water and hydrogen chloride Part 1. IR drop measurement by a computer-assisted Interrupter techniqueAn interrupter technique with computer-assisted calculation of the ohmic potential drop UΩ is described. It allows to measure UΩ while the working electrode is under potentiostatic control. As an additional result the differential double layer capacity CD is calculated, which includes some informations about the state of the working electrode surface.Experiments with the presented interrupter technique show, that just using a Luggin capillary is absolutely insufficient to avoid IR drop, especially in low conductive media: steady state current-potential curves will yield erroneous results of the kinetic parameters of the electrode reactions if the IR drop is not carefully eliminated.The described interrupter technique gives the same results for the ohmic resistance RΩ as eg AC techniques or potential pulse measurements. The value of RΩ measured is always associated with the primary current distribution.
    Notes: Die in dieser Arbeit vorgestellte computerunterstützte Unterbrechermethode erlaubt es, den ohmschen Spannungsabfall UΩ während potentiostatischen Versuchen direkt zu bestimmen. Zusätzlich wird die differentielle Doppelschichtkapazität CD als erste Information über den Oberflächenzustand der Arbeitselektrode berechnet.Untersuchungen mit dieser Methode haben gezeigt, daß der bloße Einsatz einer Haber-Luggin Kapillare zur Elimination des ohmschen Spannungsabfalls absolut ungenügend ist. Vor allem in schlecht leitfähigen Medien ist eine genaue Messung und Elimination von UΩ unerläßlich, wenn aus stationären Stromdichte/Potentialkurven korrekte kinetische Daten der Elektrodenreaktion berechnet werden sollen.Die beschriebene Unterbrechertechnik liefert denselben Wert für den ohmschen Widerstand RΩ wie z. B. AC Techniken oder Potentialpulsexperimente. Der gemessene Wert entspricht stets der primären Stromdichteverteilung.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 72
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 194-203 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion of chemical service glass enamel by acids containing fluorideIn cases a material must be found suitable for reactions that involve strong acids, the preferred protection against corrosion taken will be chemistry grade glass enamel. The high chemical resistance of these glass enamels depends on their silica basis which represents 65-75% in the oxide formula. The excellent anti-corrosion properties of these enamels may be endangered under service conditions if the glasses get into contact with traces of fluoride which may enter a process as contaminations of a raw material. In order to determine quantitatively the influence of the various parameters in this corrosion reaction of hydrofluoric acid with the glass network forming silica corrosion tests were carried out with glass-lined samples and fluoride containing acids. The corrosion rate was determined from the weight loss of the sample. Besides the liquid phase attack further corrosion testing was evaluated of glass enamel which was exposed to acid condensate containing fluoride.The attack of hydrofluoric acid on glass enamel was found to be more severe than expected from theoretical considerations. The relation of this attack has been determined in respect to time of exposure, volume to surface ratio, concentration of fluoride, pH value, temperature, and glass quality. The possible passivation of an acid which contains fluoride with silica additions has been checked in the experiments.The user of glass-lined equipment gets with the results presented a practical tool for a better understanding of the individual corrosion situation which helps to more precise decisions on counter measures.
    Notes: Chemieemail ist der bevorzugte Korrosionsschutz, wenn es gilt, ein geeignetes Material für Reaktionen, die den Einsatz starker Säuren erfordern, zu finden. Die hohe chemische Beständigkeit dieser Emails beruht darauf, daß sie bezogen auf den oxidischen Versatz zu etwa 65-75% aus Siliziumdioxid aufgebaut sind. Der hohe Korrosionsschutzwert der Emails kann in der Betriebspraxis gefährdet sein, wenn sie mit Fluoridspuren in Kontakt kommen, die z. B. über eine Rohmaterialverunreinigung in einen Prozeß eingeschleppt werden. Um die verschiedenen Einflußgrößen dieser Reaktionen der Flußsäure mit der Gerüstsubstanz des Glases quantitativ zu erkennen, wurden mit emaillierten Proben und fluoridhaltigen Säuren Korrosionsversuche durchgeführt. Aus dem Gewichtsverlust der Proben wurde die Korrosionsgeschwindigkeit bestimmt. Neben dem Flüssigphasenangriff wurde auch die Emailkorrosion durch fluoridhaltiges Säurekondensat untersucht.Der Flußsäureangriff auf Email wurde stärker gefunden, als sich nach theoretischen Überlegungen ableiten läßt. Die Abhängigkeit dieses Angriffs von der Beanspruchungszeit, dem Volumen-Oberflächenverhältnis, der Fluoridkonzentration, dem pH-Wert, der Temperatur und der Emailqualität ist bestimmt worden. Die Möglichkeit zur Passivierung der fluoridhaltigen Säure durch Kieselsäurezugaben ist im Experiment überpruft worden.Die Ergebnisse der vorliegenden Untersuchungen geben dem Betreiber emaillierten Geräts eine praktische Hilfe, die individuelle Korrosionssituation besser abschätzen und Gegenmaßnahmen gezielter einleiten zu können.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 73
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 220-226 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 74
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 226-238 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 75
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 239-246 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 76
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R61 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 77
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 213-220 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigation into the active/passive transition of 304 stainless steel in organic media containing water Part 2: Influence of water on the active dissolution and passivationThe influence of water on the corrosion and passivation of type 304 stainless steel has been studied in deaerated ethanolic solutions containing hydrogen chloride.The potentiostatic polarisation curves show that both, critical current density for passivation and passivation potential, strongly depend on the water content of the solution. A passivation model based on the assumption of a reversible primary passivation potential explains this influence of water and allows the determination of other kinetic parameters. The propounded passivation model also explains the result that the part of “passivated” surface at the maximum current density is the same for all water contents examined.The dominating influence of the water content is shown more clearly when measurements from methanolic and propanolic solutions are concerned. The passivation potential only depends on the water content and not on the type of alcohol.
    Notes: Der Einfluß des Wassergehalts auf das Korrosions- und Passivierungsverhalten von nichtrostendem 18/9 Chromnickelstahl wurde in sauerstofffreien, salzsäurehaltigen Aethanol/Wasser Gemischen untersucht.Aus den stationären Stromdichte/Potentialkurven folgt, daß sowohl die kritische Stromdichte als auch das Passivierungspotential stark vom Wassergehalt abhängen. Ein auf der Annahme eines reversiblen primären Passivierungspotentials beruhendes Modell zur Passivierung erlaubt es, die experimentell gefundene Wasserabhängigkeit zu beschreiben und weitere kinetische Informationen zu bestimmen. Mit dem Modell läßt sich auch das Resultat erklären, wonach der Anteil bereits “passivierter” Oberfläche am Stromdichtemaximum unabhängig vom Wassergehalt der Lösung stets gleich groß ist.Der Einfluß des Wassergehalts auf die Passivierung wird noch deutlicher sichtbar, wenn Messungen aus Methanol- und Propanol/Wasser Gemischen herangezogen werden: es zeigt sich, daß das Passivierungspotential bei gleichem Wassergehalt unabhängig vom Lösungsmittel denselben Wert annimmt.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 78
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R62 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 79
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R63 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 80
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R73 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 81
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R81 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 82
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R82 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 83
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R82 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 84
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R84 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 85
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 86
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. R84 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 87
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 247-253 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations on the Influence of Dissolved Silica on the Corrosion of Chemical Service Glass Enamel in Hydrochloric AcidAt high temperatures chemical service glass enamel is being attacked by mineral acids more than expected in regard to the ion exchange theory. Taking as an example the corrosion test results of a glass enamel in 20% hydrochloric acid at 140 °C one can demonstrate that under adverse conditions all glass constituents will be dissolved almost equally during attack. This result is surprising in respect to the glass component silicon-dioxide, however, its solubility in the acid is increased to 70 ppm by the high temperature. This limit essentially determines the degree of the acid attack on the enamel. If the silica concentration of the attacking acid is low and fairly low amounts add because of short reaction times or high volume to surface ratios then the corrosion rate will be high. If the attacking acid already contains higher concentrations of silica the glass enamel corrosion will be strongly inhibited. On the basis of the quantitative results it is possible to recommend a procedure for testing glass-linings at 140 °C in 20% hydrochloric acid. For this application, too, the corrosion situation in the vapor phase and liquid phase of a technical size chemical reactor is being discussed.
    Notes: Chemieemail wird bei höheren Temperaturen von Mineralsäure stärker angegriffen als es den Erwartungen, basierend auf einer Ionentauschtheorie entspricht. Mit Ergebnissen von Korrosionsversuchen wird am Beispiel Email in 20% Salzsäure bei 140 °C belegt, daß unter ungünstigen Bedingungen die Emailbestandteile während dieses Angriffs in erster Näherung alle gleichmäßig gelöst werden. Dieses Ergebnis überrascht insbesondere hinsichtlich der Emailkomponente Siliziumdioxid, deren Löslichkeit in der Säure ist infolge erhöhter Temperatur jedoch auf etwa 70 ppm angestiegen. Dieser Grenzwert bestimmt im wesentlichen das Ausmaß des Säureangriffs auf Email. Liegt die Kieselsäurekonzentration der angreifenden Säure niedrig und wird bei kurzer Beanspruchungszeit oder bei großen Volumen Oberflächenverhältnissen relativ wenig Siliziumdioxid aufgenommen, so ist die Korrosionsrate hoch. Enthält die angreifende Säure bereits Siliziumdioxid in höheren Konzentrationen, ist die Emailkorrosion stark inhibiert. Aufgrund der quantitativen Ergebnisse ist es möglich, für den Einsatzfall 140 °C, 20% Salzsäure Empfehlungen für eine praxisgerechte Emailprüfung anzugeben. Am gleichen Beispiel wird die Korrosionssituation im Kondensat- und Flüssigkeitsraum eines entsprechend beaufschlagten großtechnischen Chemieapparates diskutiert.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 88
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 254-262 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Anodischer Korrosionsschutz von Schwefelsäureanlagen unter Berücksichtigung der WämerückgewinnungDer anodische Korrosionsschutz ermöglicht die Verwendung von Werkstoffen unter ungünstigen Bedingungen, vorausgesetzt sie sind passiv oder passivierbar. Bei der Handhabung von Schwefelsäure mit 93-99% kann man daher kostengünstige austenitische Stähle wie Werkstoff-Nr. 1.4541 und 1.4591 bei Temperaturen bis 160°C verwenden; dabei ergibt sich als günstiger Nebeneffekt die Tatsache, daß sich der Temperaturbereich zwischen 120 und 160°C gut zur Wärmerückgewinnung eignet. Anodischer Korrosionsschutz nach dem APR-System (anodic protection rectifier) ermöglicht den sicheren und preisgünstigen Schutz von Luftkühlern und mantellosen Rohrbündeln in Schwefelsäureanlagen. Die Ergebnisse, die bei Laboratoriumsuntersuchungen sowie in Pilot-Anlagen und unter technischen Bedingungen erhalten wurden, lassen erkennen, daß damit der langzeitige sichere Betrieb von Schwefelsäurekühlern möglich ist.
    Notes: Anodic protection makes it possible to keep materials which can be passivated in a “passive” state or to bring them into this state, even in unfavourable conditions.With sulphuric acid concentrations of 93-99% this method permits the use of inexpensive, stainless austenitic steels, e.g. 1.4541 and 1.4591, at temperatures of up to 160 °C. The temperature range from 120 °C to 160 °C, in particular, is suitable for heat recovery.Anodic protection by the APR-system provides safe and low-cost protection for air coolers and bare tube coolers in sulphuric acid plants. The results of laboratory, pilot plant and commercial trials show that in this way a safe operation of sulphuric acid coolers is possible on a long-term basis.
    Additional Material: 25 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 89
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 262-273 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Erosion corrosion damages in power plantsIn feedwater-bearing, hot steam and wet steam bearing parts of power plants high flow velocities occur, which can result in severe damage due to erosion corrosion. The highly localized material erosion, which can be up to several millimeters deep and often leads to wall rupture within a relatively short time, adversely affects the safety and the availability of the plant.96 cases of damage registered in VdTÜV data bank were interpreted with regard to material and operating conditions of the damaged part. The characteristic appearance of hot steam erosion corrosion is described, using selected failures. Scanning electron microscope (SEM) investigations show that magnetite layer exists also in severely eroded area. SEM, metallographic and X-ray microanalyser investigations give information on structure and on adhesion of the magnetite layer on metal surface.
    Notes: In Dampfkesselanlagen treten in speisewasser-, in heißdampf- und in naßdampfführenden Bauteilen hohe Strömungsgeschwindigkeiten auf, die zu ernsten Schäden durch Erosionskorrosion führen können. Der stark lokalisierte, bis zu mehreren Millimetern tiefe Materialabtrag kann in relativ kurzer Zeit zum Wanddurchbruch führen und dadurch die Sicherheit und die Verfügbarkeit der Anlage erheblich beeinträchtigen.Aus der VdTÜV-Schadensdatei werden insgesamt 96 Schadensfälle im Hinblick auf Werkstoff, Bauteil und Betriebsbedingungen ausgewertet. Das markante Erscheinungsbild der Heißdampf-Erosionskorrosion wird anhand einiger ausgewählter Schadensbeispiele beschrieben. REM-Untersuchungen belegen die Existenz der Magnetitschicht auch in stark erodierten Bereichen. Zusammen mit metallographischen und röntgenmikroanalytischen Untersuchungen geben sie Hinweise zum Aufbau und zur Haftung der Magnetitschichten.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 90
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 285-289 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 91
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 281-284 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Verhalten von wirtschaftlich legierten MnAI-Stählen mit hohem Mn-Gehalt in wäßrigen LösungenUntersucht wurde das Korrosionsverhalten von austenitischen Stählen mit 19,8 - 32,5% Mn sowie 7,1 - 10,2% Al in verschiedenen wäßrigen Lösungen. Potentiodynamische Untersuchungen in 1 n Schwefelsäure zeigen hohe Stromdichten entweder im Aktiv- oder im Passivbereich und die Bildung eines dicken Films, der sich im Bereich des Aktiv/Passivübergangs ablöst. Potentiodynamische Untersuchungen in neutraler Pufferlösung zeigen ähnliches Verhalten wie bei anderen Eisenlegierungen. Im Fall von 1 n Natriumhydroxid ist die Korrosionsstromdichte im Passivbereich in Bezug auf die verschiedenen Manganoxide höher als die von reinem Eisen. Die Korrosionsbeständigkeit dieser Stähle ist durchweg schlechter als die von herkömmlichen austenitischen Stählen.
    Notes: The corrosion behaviour of high manganese (19.8 - 32.5%)aluminum (7.1 - 10.2%) austenitic steels in different aqueous solutions has been examined. Potentiodynamic tests in 1 N sulphuric acid solution show high current densities either in the active or in the passive region and the formation of a thick film which separates in active/passive transition zone. Potentiodynamic tests in neutral buffer solution show a behaviour similar to that of the other ferrous alloys. Potentiodynamic tests in 1 N sodium hydroxide basic solution show a corrosion current density in the passive region related to the different manganese oxides higher than that of pure iron. The corrosion resistance of these steels is always worse than that of conventional grades austenitic stainless steels.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 92
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Kinetics of H-Induced Stress Corrosion Cracking - Part 1: Important Features of Cracking with Regard to High Strength SteelsSome essential features of H-induced brittle cracking are outlined with regard to high strength steels. A literature survey shows that the electrochemical conditions at crack tips are self-controlling and can hardly be affected from outside. The increased H-solubility in strained lattice regions causes an interaction of interstitially absorbed hydrogen with stress fields. Highly strained lattice regions like crack tips and notches exert an attractive action on interstitially absorbed hydrogen which increases with increasing strength level of the steel.Theories of H-induced cracking of high strength steels and the kinetics of fracture are examined briefly. An estimate of the substantial forces acting during decohesion induced crack processes reveals the significance of the material strength for the kinetics of crack growth.Analogies to the H-induced crack growth characteristics of high strength aluminum and titanium alloys are pointed out. The common features of cracking lead to the supposition that decohesion processes may play an important role for H-induced cracking of titanium alloys, too.
    Notes: Anhand der Literatur wird auf einige wesentliche Aspekte des wasserstoffinduzierten spröden Bruches im Hinblick auf hochfeste Stähle eingegangen. Die Durchsicht zeigt, daß die elektrochemischen Bedingungen im Bereich der Rißspitze selbstregulierend sind und nur schwer von außen beeinflußt werden können. Die erhöhte Wasserstofflöslichkeit in aufgeweiteten Gitterbereichen bewirkt eine Wechselwirkung des interstitiell im Werkstoff gelösten Wasserstoffs mit Spannungsfeldern. Mit steigender Materialfestigkeit üben deshalb besonders hoch belastete Werkstoffbereiche, wie sie z. B. vor Rissen oder an Kerben vorliegen, eine zunehmende Sogwirkung auf gelösten Wasserstoff aus. Nachdem kurz auf Theorien und die Kinetik des wasserstoffinduzierten Bruches hochfester Stähle eingegangen wird, wird anhand einer überschlägigen Bilanz der wesentlichen, beim wasserstoffinduzierten Dekohäsionsbruch auftretenden Kräfte die Bedeutung der Werkstoffestigkeit für die Kinetik des Reißens herausgestellt.Parallelen zum wasserstoffinduzierten spröden Bruch hochfester Aluminium- und Titanlegierungen werden aufgezeigt. Die Gemeinsamkeiten im Bruchverhalten legen die Vermutung nahe, daß auch beim wasserstoffinduzierten Bruch von Titanlegierungen Dekohäsionsvorgänge von Bedeutung sind. Von Aluminiumlegierungen ist dieser Effekt bekannt.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 93
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 290-313 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 94
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 313-316 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 95
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 317-320 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 96
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 97
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 98
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 321-321 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 99
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 321-322 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 100
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...