ALBERT

Description: How much of the interannual variation in the satellite derived radiation balance can be purely attributed to changes taking place at the land surface, was examined. The role of surface latent heating was examined in relation to its control of the precipitation pattern from one year to the next.

Description: As a check on structure safety aspects, two approaches in seismic analysis for the large 70-m antennas are presented. The first approach, commonly used by civil engineers, utilizes known recommended design response spectra. The second approach, which is the full transient analysis, is versatile and applicable not only to earthquake loading but also to other dynamic forcing functions. The results obtained at the fundamental structural frequency show that the two approaches are in good agreement with each other and both approaches show a safe design. The results also confirm past 64-m antenna seismic studies done by the Caltech Seismology Staff.

Description: The major criterion for the Atmospheric General Circulation Experiment (AGCE) design is that it be possible to realize strong baroclinic instability in the spherical configuration chosen. A configuration was selected in which a hemispherical shell of fluid is subjected to latitudinal temperature gradients on its spherical boundaries and the latitudinal boundaries are insulators. Work in the laboratory with a cylindrical version of this configuration revealed more instabilities than baroclinic instability. Since researchers fully expect these additional instabilities to appear in the spherical configuration also, they decided to continue the laboratory cylindrical annulus studies. Four flow regimes were identified: an axisymmetric Hadley circulation, boundary layer convection, baroclinic waves and deep thermal convection. Regime diagrams were prepared.

Description: A two-layer truncated baroclinic spectral model was developed to study the long-term evolution of disturbances to a baroclinically unstable mean flow. Topography and crudely-parameterized radiative processes were accounted for. As a result of Robert Schlaak's discovery of the underlying barotropic nature of the index oscillation as well as reviewers suggestions about the original manuscript, the model has been revised to allow for barotropic as well as baroclinic wave-mean flow interactions. The form-drag exerted by the topography on the barotropic part of the mean flow is larger than on the baroclinic part and thus researchers anticipate significant changes from the original calculations on the index oscillation when it is strongly modulated by topography. Researchers believe that since the index oscillation accounts for a significant portion of atmospheric temporal variance, the long term predictability could be improved if reliable forecasts of the index oscillation were available. Two spectral models of the index oscillation, one barotropic and the other baroclinic, have been developed. The latter allows for moisture, radiation, land-sea temperature countrasts, and energy exchanges with the underlying surface.

Description: Recent atmospheric calculation suggest that the prebiological atmosphere was most probably composed of nitrogen, carbon dioxide, and water vapor, resulting from volatile outgassing, as opposed to the older view of a strongly reducing early atmosphere composed of methane, ammonia, and hydrogen. Photochemical calculations indicate that methane would have been readily destroyed via reaction with the hydroxyl radical produced from water vapor and that ammonia would have been readily lost via photolysis and rainout. The rapid loss of methane and ammonia, coupled with the absence of a significant source of these gases, suggest that atmospheric methane and ammonia were very short lived, if they were present at all. An early atmosphere of N2, CO2, and H2O is stable and leads to the chemical production of a number of atmospheric species of biological significance, including oxygen, ozone, carbon monoxide, formaldehyde, and hydrogen cyanide. Using a photochemical model of the early atmosphere, the chemical productionof these species over a wide range of atmospheric parameters were investigated. These calculations indicate that early atmospheric levels of O3 were significantly below the levels needed to provide UV shielding. The fate of volcanically emitted sulfur species, e.g., sulfur dioxide and hydrogen sulfide, was investigated in the early atmosphere to assess their UV shielding properties. The photochemical calculations show that these species were of insufficient levels, due in part to their short photochemical lifetimes, to provide UV shielding.

Description: A false-color multipolarization version of one of the images of Owens Valley area acquired by the JPL Synthetic Aperture Radar (SAR) is given. A geologic map of the alluvial fans there (Gillespie, 1982) is also given for comparison. In general, brightness in the multipolarization images can be seen to be inversely proportional to the age of the surfaces. A more detailed investigation of the relationship between backscatter and age of the surfaces was undertaken with calibrated aircraft SAR data. The quantitative relationship between backscatter coefficient and age for the three polarizations is shown. The straight lines connecting the measured data points imply a steady-state process, although the process or processes leading to this relationship may have operated at rates that varied with climate fluctuations, such as the glacial ages. It is expected that the relationship between radar brightness and age is a consistent one, and that with the wider availability of calibrated radar backscatter data, these relationships can be less well-known areas. The effect of variable such as past climate fluctuations, tectonic disturbance, and rock type must be understood before extension beyond the Mojave Desert region can be attempted.

Description: Mobile Very Long Base Interferometry (VLBI) and Global Positioning System (GPS) geodetic measurements have many error sources in common. Calibration of the effects of water vapor on signal transmission through the atmosphere, however, remains the primary limitation to the accuracy of vertical crustal motion measurements made by either technique. The two primary methods of water vapor calibration currently in use for mobile VLBI baseline measurements were evaluated: radiometric measurements of the sky brightness near the 22 GHz emission line of free water molecules and surface meteorological measurements used as input to an atmospheric model. Based upon a limited set of 9 baselines, it is shown that calibrating VLBI data with water vapor radiometer measurements provides a significantly better fit to the theoretical decay model than calibrating the same data with surface meteorological measurements. The effect of estimating a systematic error in the surface meteorological calibration is shown to improve the consistency of the vertical baseline components obtained by the two calibration methods. A detailed error model for the vertical baseline components obtained indicates current mobile VLBI technology should allow accuracies of order 3 cm with WVR calibration and 10 cm when surface meteorological calibration is used.

Description: Meteorologists and astrophysicists interested in large scale planetary and solar circulations have come to recognize the importance of rotation and stratification in determining the character of these flows. In particular, the effect of latitude-dependent Coriolis force on nonlinear convection is thought to play a crucial role in such phenomena as differential rotation on the Sun, cloud band orientation on Jupiter, and the generation of magnetic fields in thermally driven dynamos. The continuous low-gravity environment of the orbiting space shuttle offers a unique opportunity to make laboratory studies of such large-scale thermally driven flows under the constraint imposed by rotation and sphericity. This is possible because polarization forces in a dielectric liquid, which are linearly dependent on fluid temperature, give rise to an effectively radial buoyancy force when a radial electrostatic field is imposed. The Geophysical Fluid Flow Cell (GFFC) is an implementation of this ideal in which fluid is contained between two rotating hemispheres that are differentially heated and stressed with a large a-c voltage. The experiment, to be flown on Spacelab III (currently set for launch April 29, 1985), will explore non-linear mode selection and high Rayleigh number turbulence in a rotating convecting spherical shell of liquid. Experiments will be carried out in a low driving parameter range where some limited numerical experimentation is currently feasible, as well as in a parameter range significantly beyond numerical computation for many years.

Description: Comparisons are presented of satellite, rocket, and balloon ozone profiles near Natal, Brazil (5.9 deg S, 35.2 deg W). The low variability of stratospheric ozone at Natal during March and April of 1985 has allowed intercomparisons of reasonably large data sets, rather than a small number of paired satellite/in situ comparisons. There are sharp differences between the profile from the SBUV instrument on Nimbus 7 and the in situ measurements. These results support the conclusions of the NASA Ozone Trends Panel that there is an instrumental cause for the very large changes in upper stratospheric ozone seen by SBUV. Along with other comparisons, these results are being used in a reassessment of the SBUV instrument and its data reduction procedures. The agreement between the ozone profiles from the SAGE II instrument on the ERBS satellite and the rocket values is excellent over the full range of comparisons. Both SAGE II and ROCOZ-A must convert from altitude to pressure for intercomparisons with SME and with SBUV-type instruments. The conversion between pressure and altitude is as important as the ozone measurements, especially in the upper stratosphere where the scale height for ozone is approximately half that for pressure.

Description: A recent reanalysis of the International Latitude Serivce (ILS) polar motion data-day has been processed using Kalman filtering techniques to generate the polar motion excitation function over the time-span from 1960 to 1965. The resulting excitation function has been examined for the effects of 1960 Chile in an attempt to determine experimentally how large earthquake affect polar motion. The resulting upper bound of about 75 x 10 to the 22nd N-m for a 10-deg dip (about 36 x 10 to the 22nd N-m for 20-deg dip) is consistent with results obtained from previous seismic studies, including a recent normal mode excitation result. Following future great earthquakes, monitoring of polar motion by space-based techniques such as VLBI should continue at high temporal resolution for several weeks in order to directly measure the rheological parameters of the upper mantle.

Description: The Clark Mountains in eastern California form a rugged, highly dissected area nearly 5000 ft above sea level, with Clark Mountain rising to 8000 ft. The rocks of the Clark Mountains and the Mescal Range just to the south are Paleozoic carbonate and clastic rocks, and Mesozoic clastic and volcanic rocks standing in pronounced relief above the fractured Precambrian gneisses to the east. The Permian Kaibab Limestone and the Triassic Moenkopi and Chinle Formations are exposed in the Mescal Range, which is the only place in California where these rocks, which are typical of the Colorado Plateau, are found. To the west, the mountains are bordered by the broad alluvial plains of Shadow Valley. Cima Dome, which is an erosional remnant carved on a batholithic intrusion of quartz monzonite, is found at the south end of the valley. To the east of the Clark and Mescal Mountains is found the Ivanpah Valley, in the center of which is located the Ivanpah Play. Studies of the Clark Mountains with the airborne visible/infrared imaging spectrometer are briefly described.

Description: Microwave limb-sounding can be used to improve understanding of earth's upper atmosphere. This paper summarizes general features of the technique. An experiment being developed for the Upper Atmosphere Research Satellite is described. Plans for the future Earth Observing System are discussed.

Description: Seasonal and diurnal emissions of NO and N2O from agricultural sites in Jamestown, Virginia and Boulder, Colorado are estimated in terms of soil temperature; percent moisture; and exchangeable nitrate, nitrite, and ammonium concentrations. The techniques and procedures used to analyze the soil parameters are described. The spatial and temporal variability of the NO and N2O emissions is studied. A correlation between NO fluxes in the Virginia sample and nitrate concentration, temperature, and percent moisture is detected, and NO fluxes for the Colorado site correspond with temperature and moisture. It is observed that the N2O emissions are only present when percent moisture approaches or exceeds the field capacity of the soil. The data suggest that NO is produced primarily by nitrification in aerobic soils, and N2O is formed by denitrification in anaerobic soils.

Description: Mass spectrometer measurements of ozone made during two balloon flights included its heavy isotopes at mass 49 and 50. Both flights were flown during the day and during summer from Palestine, TX. At float altitudes above 42 km the enrichments in heavy ozone were 41 percent and 23 percent, respectively. The enrichment appears to be mass independent since, at high altitudes, both 49 and 50 show the same enhancement. During the descent the enrichment in heavy ozone decreased, faster during the first flight than during the second, reaching values between 15 and 20 percent above 30 km. Near and below this altitude another increase is observed. During a night flight, previously reported, an enhancement in heavy ozone of over 40 percent at 32 km was found, decreasing both toward higher and lower altitudes.

Description: The observation of a geomagnetic signature in the zonal eastward plasma flow, which is a striking feature of the equatorial ionosphere in the evening quadrant is reported. These observations were derived fronm (E x B)/B-squared measurements made with the cylindrical double-floating-probe experiment carried on the Dynamics Explorer 2 satellite. The signature consists of a crest-trough-crest effect in the latitude dependence of the eastward plasma flow with the crests at + or - 8 dip latitude and the trough nearly centered at the dip equator at all geographic longitudes. This phenomenon can be readily interpreted in terms of the altitude dependence of the F region dynamo electric field, and it is related to dip equator signatures in the plasma density and the magnetic declination which have been reported earlier.

Description: The ROCOZ-A radiometer measures ozone by long pathlength photometry in the stratosphere and lower mesosphere. After a rocket launch to an apogee of 70 km, the instrument measures the solar ultraviolet irradiance over its four filter wavelengths as it descends on a parachute. The fundamental values from ROCOZ-A are ozone overburdens versus radar altitude from 53 to 20 km. The slope of these values gives ozone number density. At one standard deviation the repeatability of the ozone overburden measurements averages 2.4 percent. For ozone number density the repeatability averages 3.2 percent with a significant increase at altitudes below the ozone number density maximum. The accuracy limits for overburden and number density are estimated at 5-7 percent. With auxiliary measurements of pressure and temperature, ozone results are also produced in terms of ozone mixing ratio, albeit with a slight broadening of the estimated accuracy limits. The vertical response of ROCOZ-A ozone measurements (full width at half maximum) is 4 km. The assembly of ROCOZ-A profiles can be used to compare with measurements from each of the current NASA and NOAA satellite ozone instruments. In addition, the repeatability of ROCOZ-A allows the use of this instrument as a transfer standard between satellite instruments with different fundamental ozone measurements.

Description: A possible cause of the large plasma flow velocities parallel to the magnetic field (which were observed in spacecraft experiments) near the boundary of the plasma sheet in the earth's magnetotail is considered in the framework of a magnetohydrodynamic model. It is shown for steady-state configurations that high parallel flow velocities can be expected to exist on field lines connecting to a region of weak magnetic field. The physical mechanism causing large values of the parallel velocity component can be visualized as a strong imbalance of perpendicular mass flux into and out of magnetic flux tubes passing through regions where the magnetic field is weak and inhomogeneous. The value of the parallel velocity component is evaluated, and it is found that it can substantially exceed the perpendicular velocity (by as much as a factor of 40). The results are applied to the earth's magnetotail; it is found that this mechanism is able to explain the parallel flow velocities near the boundary of the plasma sheet in the range of several hundreds of km/s.

Description: This paper presents a representative example of an enhancement in energetic ion flux associated with the International Sun-Earth Explorer 3 (ISEE 3) spacecraft's encounter with a traveling compression region (TCR). Data from the energetic particle anisotropy spectrometer (EPAS) instrument on ISEE 3 are studied, along with magnetic field data from the vector helium magnetometer. It is concluded that the ion enhancements seen are spatial in nature, thus supporting the idea that TCRs are the lobe signatures of plasmoids moving along the magnetotail, away from earth.

Description: The spatial and temporal characteristics of ozone density measured from the SBUV (Solar Backscatter Ultraviolet) spectrometer on Nimbus-7 and the UV and the UV and the IR spectrometers on SME (Solar Mesosphere Explorer) are compared in the altitude region near 50 km where the three data sets overlap. Their temporal characteristics, when averaged over the same longitude range, are remarkably similar with respect to seasonal variations and short term fluctuations induced by transient planetary waves. The long term trends in the three data sets, however, differ significantly with each other. Over the three year period after 1982 ozone mixing ratio at 1 mb decreased by about 10 percent based on SEUV measurements but increased by 12 and 30 percent respectively based on SME-IR and SME-UV measurements. None of these estimates are consistent with the predicted decrease of about 2 percent based on solar UV flux and temperature changes during this period.

Description: The phase diagram of FeO has been experimentally determined to pressures of 155 GPa and temperatures of 4000 K using shock-wave and diamond-cell techniques. A metallic phase of FeO is observed at pressures greater than 70 GPa and temperatures exceeding 1000 K. The metallization of FeO at high pressures implies that oxygen can be present as the light alloying element of the earth's outer core, in accord with the geochemical predictions of Ringwood (1977 and 1979). The high pressures necessary for this metallization suggest that the core has acquired its composition well after the initial stages of the earth's accretion. Direct experimental observations at elevated pressures and temperatures indicate that core-forming alloy can react chemically with oxides such as those forming the mantle. The core and mantle may never have reached complete chemical equilibrium, however. If this is the case, the core-mantle boundary is likely to be a zone of active chemical reactions.

Description: A method for calculating the photodissociation rates needed for photochemical modeling of the stratosphere, which includes the effects of molecular scattering, is described. The procedure is based on Sokolov's method of averaging functional correction. The radiation model and approximations used to calculate the radiation field are examined. The approximated diffuse fields and photolysis rates are compared with exact data. It is observed that the approximate solutions differ from the exact result by 10 percent or less at altitudes above 15 km; the photolysis rates differ from the exact rates by less than 5 percent for altitudes above 10 km and all zenith angles, and by less than 1 percent for altitudes above 15 km.

Description: Data from the BOIC which consisted of three balloon missions conducted in Palestine, Texas from June 1983 to March 1984 are presented. The BOIC was to assess the ability to perform ozone measurements from balloon platforms. The accuracy and precision of the various ozone measurement systems, which were composed of a photometer, a mass spectrometer, and solar UV absorption sensors, are evaluated. The ozone observations obtained with the instruments on the three flight missions are analyzed and intercompared. The flight in situ data are also compared to the National Bureau of Standards reference photometer, satellite measurements, and under simulated stratospheric pressure and ozone concentrations.

Description: An analysis procedure has been developed for derivation of information about the photochemical behavior of ozone near 1 mbar by explicitly accounting for the dynamical transport terms in the continuity equation for perturbations from the zonal mean. The procedure is shown to be valid using data from a numerical transport model and is then applied to LIMS ozone and temperature data, using geostrophic winds to estimate the transport terms. The data study is restricted to March at 2, 1, and 0.7 mbar. Because the temperature deviations are dynamically produced, large temperature deviations are associated with significant ozone transport terms. The anticorrelation between the deviations of ozone and temperature disappears when the transport terms are small. The derived photochemical information is compared to photochemical theory. Although there is overall agreement in the magnitude as well as the latitude, altitude, and time dependencies, discrepancies are suggested which may be related to the long-standing failure of photochemical models to calculate ozone accurately near 1 mbar. The theory suggests that the addition of Cl(x) to the stratosphere will affect the relationship of ozone and temperature at 2 and 1 mbar. Comparison of the photochemical information derived from future ozone and temperature measurements with the results of the present analysis should provide a critical test of the photochemical scheme thought to describe the behavior of odd chlorine in the stratosphere.

Description: A detailed statistical analysis of monthly averages of ozonesond readings is performed to assess trends in ozone in the troposphere and the lower to midstratosphere. Regression time series models, which include seasonal and trend factors, are estimated for 13 stations located mainly in the midlatitudes of the Northern Hemisphere. At each station, trend estimates are calculated for 14 'fractional' Umkehr layers covering the altitude range from 0 to 33 km. For the 1970-1982 period, the main findings indicate an overall negative trend in ozonesonde data in the lower stratosphere (15-21 km) of about -0.5 percent per year, and some evidence of a positive trend in the troposphere (0-5 km) of about 0.8 percent per year. An in-depth sensitivity study of the trend estimates is performed with respect to various correction procedures used to normalize ozonesonde readings to Dobson total ozone measurements. The main results indicate that the negative trend findings in the 15- to 21-km altitude region are robust to the normalization procedures considered.

Description: ISEE particle and wave data are noted to furnish substantial support for the basic features of the velocity dispersed model at the foreshock boundary that was proposed by Filbert and Kellogg (1979). Among many remaining discrepancies between this model and observation, it is noted that unstable reduced velocity distributions have been discovered behind the thin boundary proposed by the model, and that these are at suprathermal energies lying far below those explainable in terms of an oscillating, two-stream instability. Although the long-theorized unstable beam of electrons has been found in the foreshock, there is still no ready explanation of the means by which it could have gotten there.

Description: Theoretical models of planetary-atmosphere tidal fields are examined analytically, comparing models based on geometric-height coordinates with those employing log-pressure coordinates. The relationship between the linearized meteorological variables in the two systems is explored for classical tidal theory and its reduction to the Laplace tidal equation, and it is shown that identical horizontal and vertical equations are obtained. Also considered are the tidal zonal-mean bilinear flux convergences and their Eliassen-Palm formulations. Numerical results for problems involving the earth and Mars atmospheres are presented in graphs and discussed.

Description: The analytical results of Zurek (1986) are applied to compare the vertical-structure equations obtained by Dickinson and Geller (1968) and Lindzen and McKenzie (1967) in solving the classical tidal equations for planetary atmospheres when Newtonian cooling (NC) is included as part of diabatic tidal forcing. The two diabatic forcings are found to be different when the basic state temperature varies with height, and it is recommended that a log-pressure NC formulation be used whenever temperature is made a function of pressure in the radiative-damping calculation. Scaling arguments are presented to show that the choice of NC formulation has significant effects only in cases where the radiative time constants are short (such as the thin CO2 atmosphere of Mars). Numerical computations for that case indicate a difference of 20 percent in amplitude and 15 deg in phase for the (probably meteorologically significant) 4.1-d wavenumber-one Rossby tidal mode.

Description: Recent ground-based infrared solar spectra at 0.02 per cm resolution in the 3000 per cm region have been analyzed for the atmospheric content of HCl. Nonlinear spectral least-squares fitting applied to spectra obtained at several zenith angles shows little sensitivity of the results to tropospheric HCl but provides an accurate measurement of the total column amount.

Description: This review presents a summary of past work on the ISEE-3 distant tail magnetic field observations. An attempt has been made to bring the many results together as a coherent whole, in the hope that the reader can envision the direction of future research necessary to achieve an understanding of the dynamics of the magnetotail from 60 to 240 earth radii and perhaps beyond.

Description: Ozone measurements from 1970 to 1984 from the Nimbus 4 backscattered ultraviolet and the Nimbus 7 solar backscattered ultraviolet spectrometers show significant decrease in total ozone only after 1979. The downward trend is most apparent in October south of 70 deg S in the longitude zone 0 to 30 deg W where planetary wave activity is weak. Outside this longitude region, the trend in total ozone is much smaller due to strong interannual variability of wave activity. This paper gives a phenomenological description of ozone depletion in the Antarctic region based on vertical advection and transient planetary waves.

Description: A more detailed examination of the TOMS observations reveals a number of important aspects of the Antarctic ozone depletion. First, it is noted that the presence of large scale disturbances around the edge of the ozone hole can lead to highly variable station observations. Second, an examination of the zonal mean total ozone for the seven Octobers shows that the large systematic decline is not simply confined to the polar region but exists at midlatitudes as well. Integrations of the total ozone from the South Pole northwards show that a portion of the systematic trend of decreasing Antarctic total ozone (prior to 1985) seems to be due to a redistribution of total ozone to subpolar and midlatitude regions. That is, decreases at high latitudes are compensated by increases at lower latitudes. The correlation between zonal mean total ozone and 70 mb zonal mean temperatures from polar to midlatitudes shows that the systematic decreases in total ozone is well correlated with a systematic decrease in stratospheric temperatures.

Description: The ozone profiles measured by SBUV in the region of the Antarctic ozone minimum are in error as archived for altitudes below the 7 mb level in the atmosphere because of the lack of a reasonable climatology to use for the initial guess profile. The ozone profile error in this region is examined, and it is shown that use of a reasonable climatology in this unusual region results in ozone profiles that agree substantially better with the balloon observations available from the Syowa station. The corrected profiles show that by 1984 there was 35 percent less ozone in the 15 to 30 km region than in 1979, and 14 percent less even in the 40 to 50 km region.

Description: Daytime and nighttime vertical profiles of the tropospheric trace gas N2O were determined from grab sample collections off the Atlantic and Gulf coasts of Florida. The grab samples were collected during the week of October 7-13, 1984, from a Lear jet during descent spirals over an altitude range of 12.5-0.3 km in approximately 1.2-km intervals. During this period there were two distinct airflow regimes sampled: (1) the surface boundary layer (less than 2 km), in which the wind direction was typically easterly; and (2) the regime above the boundary layer, which was predominantly characterized by westerly flow. N2O mixing ratios, normalized to dry air, were determined from 148 daytime and nighttime samplings. N2O was found to be uniformly mixed at all altitudes at 301.9 + or - 2.4 parts per billion by volume.

Description: Mobile Very Long Base Interferometry (VLBI) and Global Positioning System (GPS) geodetic measurements have many error sources in common. Calibration of the effects of water vapor on signal transmission through the atmosphere, however, remains the primary limitation to the accuracy of vertical crustal motion measurements made by either technique. The two primary methods of water vapor calibration currently in use for mobile VLBI baseline measurements were evaluated: radiometric measurements of the sky brightness near the 22 GHz emission line of free water molecules and surface meteorological measurements used as input to an atmospheric model. Based upon a limited set of 9 baselines, it is shown that calibrating VLBI data with water vapor radiometer measurements provides a significantly better fit to the theoretical decay model than calibrating the same data with surface meteorological measurements. The effect of estimating a systematic error in the surface meteorological calibration is shown to improve the consistency of the vertical baseline components obtained by the two calibration methods. A detailed error model for the vertical baseline components obtained indicates current mobile VLBI technology should allow accuracies of order 3 cm with WVR calibration and 10 cm when surface meteorological calibration is used.

Description: Techniques employed to map the global distribution of stratospheric aerosols using SAGE II data at four wavelengths (385, 453, 525 and 1020 microns) are described. The methods were devised to integrate the 900 data points scanned by the instrument with account taken of the different times the vertical profiles were obtained. The data have been used to calculate the O3, H2O, NO2 and aerosol optical thicknesses. Sample details of data gathered during April 1985 are discussed, with emphasis on difficulties being encountered in analyzing the differences being observed in the dawn and dusk data.

Description: Data on the characteristics of the stratospheric aerosol as measured with sensors on the SAM II and SAGE I satellites and with ground-based and airborne lidar are discussed. Emphasis is placed on the impact of the El Chichon eruptions. The volcanic cloud was tracked to an altitude of 30 km, and was observed to travel around the earth in 3 weeks. The maximum stratospheric loading is estimated at 12 Mtons, which increased the stratospheric optical depth to 0.15-2.0 at the peak period. The particulate loading was predicted to lower the Northern Hemisphere average temperatures by 0.4-0.5 C in 1984-85.

Description: Alongtrack data collected with the Earth Radiation Budget Experiment (ERBE) scanner instrument were used to study an observed limb-darkening phenomenon. A numerical model developed for the longwave exitance as a function of the SZA has agreed well with ERBE data, indicating that the atmosphere is in adiabatic, rather than radiative, equilibrium. A corrected form of the model has been defined for SZA over 60 deg. The model was used to parameterize diurnal data for the Sahara-Saudi and Australian deserts.

Description: Design features and the performance envelope of the SAGE II stratospheric aerosol monitoring instrument on the Earth Radiation Budget Satellite are described. SAGE II was designed to obtain vertical profiles of stratospheric aerosols, monitor global seasonal changes in aerosols, provide data on stratospheric circulation and the behavior of transient events such as volcanic particulate injections, and to investigate atmospheric chemistry. The mmeasurements are centered on extinctions due to aerosols, NO2, O3 and water vapor.

Description: Instruments on board the (presently two) satellites of the Earth Radiation Budget Experiment (ERBE) are collecting data for determining monthly averaged radiation exitances at the top of the atmosphere (TOA). To achieve the accuracy desired of the mission, radiances at the satellite are first calculated, with allowance made of sensor optical properties and the directionality of the TOA radiation field. The subsatellite surface type is classified to adjust for albedo changes and correction values are added for the types of cloud cover detected.

Description: Early results are reported from measurements of the diurnal variability of total and clear-sky regional radiative parameters by the ERBE instruments on one dedicated satellite and the polar-orbiting NOAA-9 satellite. Attention is focused on November 1984, the first complete data set. The scene is identified in terms of longwave and shortwave radiances (daytime) or longwave radiation (night) and maximum likelihood estimates carried out with the addition of Earth Radiation Budget data from Nimbus-7. Analysis of the first data set revealed significant differences between total and clear-sky albedo. The clear-sky and LRE both reach maximum around noon and minimum values at midnight.

Description: The Earth Radiation Budget Experiment (ERBE) is to be a three-satellite complement, of which two satellites were in orbit as of October 1984. Each satellite carries scanners for earth radiance sensing and one nonscanner for solar constant sensing. Of the four channels for earth scanning, two are dedicated to limb-to-limb observations and two view a swath 1000 km wide. Comparisons are made among the channel readings, thus far producing agreement to within 1 percent. Inversion techniques which are being applied to data gathered by the sensors are checked against equivalent procedures and results with the Nimbus-7 and GOES satellites.

Description: The effects changes in stratospheric ozone concentrations have on photochemical models of the atmosphere are evaluated. The study was spurred by the appearance of excessive stratosphere heating above 40 km in radiative transfer computations. A 20 percent reduction in ozone in the 40-55 m altitude interval would offset the anomalous heating values. Comparisons were made between calculated heating rates and in-situ data that included ozone concentrations. Heating rates decreased 0.4 C/day when clouds were present at the 300 mb level, and increased by 0.3 C/day with clouds at the 80 mb level.

Description: The SAGE II limb-scanning radiometer carried on the Earth Radiation Budget Satellite functions at wavelengths of 0.385, 0.45, 0.525, and 1.02 microns to identify vertical profiles of aerosol density by atmospheric extinction measurements from cloud tops upward. The data are being validated by correlating the satellite data with data gathered with, e.g., lidar, sunphotometer, and dustsonde instruments. Work thus far has shown that the 1 micron measurements from the ground and satellite are highly correlated and are therefore accurate to within measurement uncertainty.

Description: Nimbus-7 wide-FOV irradiance data collected from 1981-1985 are used to evaluate the effects of the El Chichon eruptions of 1982 on the earth radiation budget. The north polar region displayed a maximum response of 20 percent in the winter of 1982-1983, with the variation being most apparent in the near-IR 2.8 micron and 0.2-3.8 microns shortwave bands. The data indicate that the particle size distribution was constant for a year after eruptions.

Description: Laboratory kinetic studies suggest that an appreciable fraction of the ozone produced by recombination of atomic oxygen is vibrationally excited in the nu3 mode. Further, laboratory data are available for the physical quenching of nu3, its radiative relaxation, and its radiative excitation by resonant absorption. It is shown that these chemical and physical processes are likely to result in substantial departures from local thermodynamic equilibrium for the nu3 mode of ozone in the mesosphere and therefore have important effects on infrared mesospheric ozone measurments by emission in the 9.6-micron band. Implications of these effects on data from the Limb Infrared Monitor of the Stratosphere (Remsberg et al, 1984), particularly their night/day ratio, are discussed.

Description: Sm-Nd isotopic studies of anorthosites can be used to provide information on their ages of crystallization and metamorphism, contamination history, and mantle sources. Proterozoic anorthosites in the Grenville and Nain Provinces of eastern North America crystallized between about 1100 and 1600 Ma, and some were metamorphosed at about 1000 Ma. Grenville Province anorthosite massifs were derived from depleted mantle. It is not clear whether massifs and related mafic intrusions throughout the Nain Province of Labrador were derived from enriched mantle, or were contaminated by early Archean (greater than 3500 Ma) silicic crustal materials, heretofore thought to be restricted to coastal Labrador.

Description: The relation between rotational modulation of the ultraviolet solar irradiance and variations in atmospheric ozone has been investigated using Fourier transform harmonic analysis and cross-correlations. Ozone variations with the same period and phase as 13.5 day or 27-day solar flux variations occur at tropical and subtropical latitudes over a range of pressure levels centered about 3 mbar. The solar-forced oscillation is stronger in the summer hemisphere; as temperature-related variations would be stronger in winter. Changes in solar irradiance over the 11-year cycle can be estimated by scaling rotational modulation. Using this estimate and the ozone-sun relation obtained for rotational modulation yields solar cycle changes of 3.5 percent in 3 percent mixing ratio comparable to that predicted from halocarbons and 0.7 mbar in total ozone.

Description: Ozone profile data from the Solar Backscattered Ultraviolet Instrument on Nimbus 7 from 1979 to the present and clear cases of ozone destruction associated with five sudden proton events (SPEs) on June 7, 1979, August 21, 1979, October 13-14, 1981, July 13, 1982, and December 8, 1982 are found. During the SPE on July 13, 1982, the largest of this solar cycle, no depletion at all at 45 km is observed, but there is a 15 percent ozone depletion at 50 km increasing to 27 percent at 55 km, all at a solar zenith angle of 85 deg. A strong variation of the observed depletion with solar zenith angle is found, with maximum depletion occurring at the largest zenith angles (near 85 deg) decreasing to near zero for angles below about 70 deg. The observed depletion is short lived, disappearing within hours of the end of the SPE.

Description: Absorption cross-sections of ozone have been measured over the range 230 nm to 350 nm, and for temperatures 200 K to 300 K, with improved photometric accuracy and spectral resolution. These measurements are referred to the cross-section at the 253.65 nm mercury line by the Hearn value (1961), 1147 x 10 to the -20th/sq cm, and show an internal consistency of + or - 1 percent. Tables of ozone absorption cross-section in the ultraviolet have been prepared for intervals of 0.05 nm over the range 245 to 340 nm. at each wavelength entry in the table a set of coefficients has been derived that permits the cross-section to be computed as a function of temperature, between 200 K and 300 K, with an accuracy of 1 percent.

Description: Intercomparisons of remote and in-situ techniques used to measure stratospheric ozone are made using results obtained on the Balloon Intercomparison Campaign of 1982 and 1983. Two in-situ and four remote instruments participated. These included ECC ozonesondes, a UV absorption photometer, and microwave emission, IR emission, and absorption spectrometers. Differences are generally less than 15 percent, and are within the quoted error bars. Flights which involved different sets of instruments were made on four separate days, and results are intercompared in plots of ozone density versus altitude. A careful assessment of errors was made for each instrument, and a plot of absolute errors versus altitude is given.

Description: In the Balloon Ozone Intercomparison Campaign (BOIC), several in situ UV absorption photometers, two solar UV absorption photometers, electrochemical sondes, and a mass spectrometer were intercompared in three flight missions. Concurrent data from Umkehr and satellite observations are also intercompared. The National Bureau of Standards provided a 'standard' ozone source for intercomparing the in situ instruments and ground pressure. Preliminary findings indicate that the standard deviation of the sensitivities among 17 instruments against the NBS reference was about 11 percent. These differences appear in flight at the lower levels and change at higher altitudes, indicating height-dependent errors. The difference among five in-situ UV photometers flown together ranged by plus or minus 8 percent during ascent to about 41 km. During float at 42 km, the difference nearly doubled. During descent, the difference decreased to about 4 percent, which is much closer to the expected accuracy of these instruments. Results from UV solar radiometers have been systematically higher than those from UV photometers by 15 to 20 percent - a very important disagreement that needs to be resolved.

Description: Utilizing independent estimates of ozone and temperature fields from the SBUV (Nimbus 7) and NOAA operational satellites, respectively, for the period 1978-1981, the coefficient of variation between the two parameters is determined. This coefficient is defined as A = Delta-O3 x (T)/Delta T x (O3) wehre Delta is an incremental change in either temperature or ozone and the bracket is a mean state. In practice, A is determined on a daily basis by regression of ozone mixing ratio versus temperature around a latitude circle during the winter season and the bracket value is the daily zonal average. This has the advantage of keeping the solar zenith angle fixed for a daily value while allowing it to change during the season. This is done at 30, 10, 5, 2, and 1 mb from 20 deg to 60 deg latitude in both hemispheres. The results are summarized and compared with those determined from a one-dimensional photochemical model applied to different latitudes.

Description: Until recently, Umkehr data taken by 20 Dobson stations around the world have been the principal source of information about the behavior of upper stratospheric ozone. Umkehr results are used also for detecting drifts in satellite instruments and for determining intersatellite biases. However, a systematic evaluation of the quality of Umkehr data taken by the various stations has been lacking. Five years of ozone profile data from the Solar Backscattered Ultraviolet (SBUV) have been used to examine and intercompare the quality of Umkehr stations, and to assess the degradation of their performance after the El Chichon volcano eruption in southern Mexico. In contrast to Umkehr, the SBUV ozone measurments in layers 7 through 9 (1-8 mb) were unaffected by the massive amounts of dust and gases ejected by El Chichon.

Description: Ozone profile data are intercompared with those from the LIMS and SBUV flown on Nimbus 7, SAGE flown on Atmospheric Explorer Mission 2, and the Ultraviolet and Infrared Spectrometers flown on the SME. Ozone data were derived from the measurements with independently derived processing algorithms. The data cover different time periods and have different spatial and temporal resolutions. The similarities and differences between the individual data sets are determined with effort focused on directly comparing the spacecraft data sets in the form of individual profiles, zonal mean profiles and global analyses. Comparisons with ground data from balloons and Umkehr stations are made.

Description: A study is reported based on four years of SBUV data and five years of published ozonesonde data. The Solar Backscatter Ultraviolet Experiment (SBUV), has been operating continuously since November 1978, providing some 1000 profiles per day. The data are of excellent quality from about 50 km down to the tropopause. By combining the satellite-derived data with ozonesonde data, a data base of standard ozone profiles and variance/covariance matrices has been developed, defining the observed variation of the atmospheric ozone around the mean profiles. Highlights of the data base are presented along with parameters of an analytical fit that describes the essential features of the data set. Although the data base was created specifically for use as a priori profiles for SBUV and Umkehr retrievals, it should be useful in other remote sensing applications and in modeling the UV radiation fields in the stratosphere. Another suggested application is in estimating ozone above the peak altitude of the ozone balloons.

Description: An overview is given of the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) which was designed to observe the spatial characteristics of total ozone that were not resolved by the nadir-viewing Nimbus BUV and SBUV instruments. At the wavelengths suitable for total ozone measurements, the radiance is large enough that the entire daytime atmosphere could be surveyed with about 50-km resolution from a polar orbiting satellite. The resulting high spatial resolution TOMS ozone images are found to reflect the internal dynamic structure of the lower atmosphere. Features which can be identified and tracked include: planetary wave scale troughs and ridges, mesoscale cutoff lows and rapidly moving troughs, jet stream confluence and difluence areas, hurricanes, and polar night lows. These features control the ozone above any given location and account for nearly all the variance in the total ozone. The instrument has been used to track the volcanic eruption clouds from El Chichon, Mount St. Helens, Alaid, and smaller eruptions such as Galunggung. It would be feasible to use a similar instrument on a geostationary platform to obtain half-hourly maps. Determination of the vertical ozone distribution in the lower stratosphere using Radon transform principles would be of importance in measuring jet stream folds and the related troposphere-stratosphere exchange.

Description: Results are given of SBUV (solar backscattered ultraviolet instrument) measurements from Nimbus 7, when - one day per month - it is operated in a spectral scan mode, scanning from 160 nm to 400 nm in 0.2-nm steps. By measuring the intensity of a series of nitric oxide (NO) gamma band fluorescence features in this wavelength range, it has been possible to estimate the amount of NO in the upper stratosphere and mesosphere. The background of atmospherically scattered sunlight normally masks the much weaker NO gamma band emission, but these emission features are discriminated by subtracting a synthetic spectrum calculated for a model atmosphere that includes only Rayleigh scattering and absorption by ozone and oxygen. The resulting difference plot clearly reveals features resulting from processes not included in the simple model, such as NO gamma band emission. Nitric oxide is inferred by measuring the absolute intensity of various bands relative to the adjacent background and relating this intensity to total NO above an altitude determined by the backscattering contribution function for that band. NO observations near the solstice and at various latitudes are reported.

Description: Analyses of a three-year time series of rocket ozone measurements at Wallops Island, VA, a set of rocket ozone soundings across the Southern Hemisphere, and rocket soundings at Fort Churchill, Manitoba are reported. Evidence is obtained that the NOx budget is not simply explained by oxidation of biospheric nitrous oxide. I 1-D time-dependent photochemical model is used to compute the amount of NO2 required to maintain odd oxygen in a steady state after accounting for Chapman, odd hydrogen, and odd chlorine reactions. At Wallops Island, a mid-latitude station, the inferred seasonal variation of NOx is small with the fall and winter mixing ratios about 20 percent greater than the spring and summer values. The soundings at Fort Churchill require about the same NOx amount as at Wallops Island in the spring and summer months but more than twice this amount in late fall and winter. Results indicate that the nitrous oxide source of NOx is supplemented by a polar source during the fall and winter months. This is consistent with the descent of thermospheric air with its high nitric oxide content during the period of strong cooling in the polar night.

Description: An analysis is given of some results of the LIMS experiment, launched on the Nimbus 7 satellite on October 24, 1978 for the purpose of sounding the middle atmosphere composition and structure. One of the LIMS channels was centered spectrally in the 6 micron region to measure vertical profiles and the global distribution of NO2 mixing ratio. The data reveal that NO2 is highly variable with altitude, latitude, longitude and time. Steep latitudinal gradients are observed in high latitude winter ('the NO2 cliff') when a wave number one pattern exists in the geopotential height field. The daytime gradient under these conditions is less than that for the night. The summer hemisphere column amount is considerably greater (by a factor of about 2) than in the winter hemisphere. The largest mixing ratios occur at 4 mb at night (about 20 ppbv) and 9 mb in the day (about 7 ppbv) and the latitude region of the peak mixing ratio is skewed toward the Southern Hemisphere. The mixing ratio variability is greater at night (by a factor of about 2 to 3) than in the day and there are significant long-term changes revealed by mixing ratio time series analyses on a pressure vs time grid.

Description: The Limb Infrared Monitor of the Stratospheric water vapor channel data analysis has been extended from the 1. mb level (about 48 km) to the .3 mb level (about 60 km) through a radiance averaging procedure and better understanding of systematic errors. The data show H2O mixing ratio peaks near the .5 mb level varying from 4 to 7 ppmv with latitude and season. Above this level the mixing ratio drops off quickly with altitude, but, due to experimental uncertainties, at an uncertain rate. The stratospheric results are virtually the same as determined from the archived LIMS results with a tropical hygropause and enhanced H2O concentration in the lower levels at high winter latitudes.

Description: LIMS, SAMS, SBUV and in-situ data have been used to infer species not measured but which are of photochemical interest, e.g., O(3P), O(1D), NO, N2O5, OH, HO2, ClO and HCl. (LIMS = limb infrared monitor of the stratosphere; SAMS = stratospheric and mesospheric sounder; and SBUV = solar backscattered ultraviolet instrument.) Production and loss of odd nitrogen have been calculated and estimates have been made of the odd nitrogen transport due to adiabatically driven circulation derived from LIMS data. Data used from LIMS include O3, NO2, HNO3, H2O and T. CH4 and N2O were taken from SAMS and the UV solar flux from the SBUV instrument. Species were inferred for periods in October, December, March and May. Results for December are discussed. Results indicate: (1) maximum stratospheric odd nitrogen levels of 25 ppbv; (2) evidence of odd nitrogen transport from the mesosphere appearing at 25 km in the wintertime polar latitudes; (3) the polar night build-up of high levels of N2O5 beginning after the autumnal equinox; and (4) the possibility of large downward fluxes of odd nitrogen into the troposphere during the winter at latitudes poleward of 60 degrees.

Description: LIMS data at vernal equinox conditions are used to study the photochemistry of the upper stratosphere. The results indicate, and it has been recently reported, that with the use of recommended reaction rates, current models underestimate ozone mixing ratio by 20-40 percent. For ozone, good agreement with data is realized with the modification of six key reaction rates within the published limits of uncertainty. These modifications also yield better agreement with data for daytime NO2. Model results for other parameters such as the ratio HNO3/NO2, OH mixing ratio, and the temperature sensitivity of O3 are compared with data.

Description: Theoretical two-dimensional and three-dimensional solutions to the radiative-transfer equation have been applied to the earth-atmosphere system. A field experiment was conducted to test this theory. In the experiment the upward radiance was measured above and below a haze layer during simultaneous measurements of the haze characteristics. The measurements were conducted at a narrow near-IR channel (773 + or - 22 nm) which represents the visible and near-IR spectral region. The aerosol vertical optical thickness at eight wavelengths, as well as the vertical and horizontal profiles of the scattering coefficient, the temperature, and dew point were measured at several locations. These measurements quantified the vertical and spatial structure of the atmospheric haze and the atmospheric radiation. The result was a well-defined radiative-transfer experiment. The experimental data set is used to quantify the haze effect on upward radiance, including the adjacency effect (the effect of a bright area on the upward radiance measured above a dark adjacent area), and to test radiative-transfer models for a plane-parallel atmosphere above a nonuniform surface. A comparison is given between the theoretical prediction of upward radiance above the haze and the measurement. Agreement between theory and the experiment is discussed.

Description: Following the solar proton event (SPE) of July 13, 1982, an increase in the strength of nitric oxide Gamma bands was observed in spectral scans of the atmospheric albedo made by the solar backscattered ultraviolet instrument on Nimbus 7. Analysis of the (10), (01), and (02) Gamma band strengths allow an estimate to be made of the cumulative amount of nitric oxide above an altitude of 50 km. An increase in nitric oxide in southern hemisphere high latitudes following the SPE amounting to about 5 x 10 to the 14th molecules per sq cm above an altitude of approximately 50 km is observed. The observed increase persists until the middle of September. A similar increase is not observed in the northern hemisphere, indicating that under summer conditions the mesospheric/thermospheric NO distribution returns to normal within a few days after the end of an SPE.

Description: Ionospheric electron content studies have revealed severe discrepancies between Faraday measurements and model predictions at low latitudes. In this investigation, satellite data of AE-C and Aeros and incoherent scatter data from Jicamarca, Peru and Arecibo, Puerto Rico are used to examine the latitudinal and diurnal extent of this disagreement. It is found that in the modified dip range -30 deg to +30 deg the present IRI relative layer shape underestimates the thickness of the topside electron density during both, day and night. The Bent model which was used as a source for the IRI description performs somewhat better in this critical dip range, though it does not reach the observed values. Also it does not show the observed diurnal variation. A correction to the IRI formula is proposed that guarantees better agreement with the satellite and incoherent scatter data.

Description: Since the first edition of IRI in 1978, considerable efforts have been directed towards an improved and refined electron temperature description. Finally, a new empirical model was presented at the COSPAR meeting at Graz, Austria, in 1984 (Bilitza et al.). Based mainly on satellite data it highlights a more detailed diurnal, seasonal, and altitudinal variation. The implementation of this model into the IRI framework is described. A first comparison with incoherent scatter measurements indicates the improved diurnal and seasonal performance of the model.

Description: Different models for the F2 peak altitude hmF2 are compared with mean values determined from incoherent scatter measurements of the radar stations Jicamarca, Peru and Arecibo, Puerto Rico at all local times. The investigation shows that the daytime hmF2 is fairly well represented by the most recent models, whereas at nighttime, higher peak altitudes are measured rather than predicted by either model. The observed diurnal structure is slightly misinterpreted by the models above Jicamarca and is strongly disagreeing above Arecibo.

Description: A brief description is given of how temporal and spatial variability in the earth's radiative behavior influences the goals of satellite radiation monitoring systems and how some previous systems have addressed the existing problems. Then, results of some simulations of radiation budget monitoring missions are presented. These studies led to the design of the Earth Radiation Budget Experiment (ERBE). A description is given of the temporal and spatial averaging algorithms developed for the ERBE data analysis. These algorithms are intended primarily to produce monthly averages of the net radiant exitance on regional, zonal, and global scales and to provide insight into the regional diurnal variability of radiative parameters such as albedo and long-wave radiant exitance. The algorithms are applied to scanner and nonscanner data for up to three satellites. Modeling of dialy shortwave albedo and radiant exitance with satellite samling that is insufficient to fully account for changing meteorology is discussed in detail. Studies performed during the ERBE mission and software design are reviewed. These studies provide quantitative estimates of the effects of temporally sparse and biased sampling on inferred diurnal and regional radiative parameters. Other topics covered include long-wave diurnal modeling, extraction of a regional monthly net clear-sky radiation budget, the statistical significance of observed diurnal variability, quality control of the analysis, and proposals for validating the results of ERBE time and space averaging.

Description: The Earth Radiation Budget Experiment carries a three-channel scanning radiometer and a set of nadir-looking wide and medium field-of-view instruments for measuring the radiation emitted from earth and the solar radiation reflected from earth. This paper describes the algorithms which are used to compute the radiant exitances at a reference level ('top of the atmosphere') from these measurements. Methods used to analyze data from previous radiation budget experiments are reviewed, and the rationale for the present algorithms is developed. The scanner data are converted to radiances by use of spectral factors, which account for imperfect spectral response of the optics. These radiances are converted to radiant exitances at the reference level by use of directional models, which account for anisotropy of the radiation as it leaves the earth. The spectral factors and directional models are selected on the basis of the scene, which is identified on the basis of the location and the long-wave and shortwave radiances. These individual results are averaged over 2.5 x 2.5 deg regions. Data from the wide and medium field-of-view instruments are analyzed by use of the traditional shape factor method and also by use of a numerical filter, which permits resolution enhancement along the orbit track.

Description: The history of satellite missions and their measurements of the earth radiation budget from the beginning of the space age until the present time are reviewed. The survey emphasizes the early struggle to develop instrument systems to monitor reflected shortwave and emitted long-wave exitances from the earth, and the problems associated with the interpretation of these observations from space. In some instances, valuable data sets were developed from satellite measurements whose instruments were not specifically designed for earth radiation budget observations.

Description: This paper gives an overview of the Earth Radiation Budget Experiment. The experiment consists of scanning and nonscanning radiometer packages on three spacecraft. One is a satellite with a 57 deg, inclination orbit which precesses around the earth once every 2 months. Packages are also flown on the sun-synchronous NOAA-F and NOAA-G operational meteorological satellites. The scanning radiometer includes three channels: shortwave, long-wave, and total. The nonscanner package encompasses a pair of wide-field-of-view radiometers and a pair of medium-field-of-view radiometers. Each pair consists of a total and a shortwave radiometer. The scientific importance and objectives of the mission are described, including the need for the three spacecraft and the utility of the complementary types of radiometers.

Description: The history of radiation budget studies from the early twentieth century to the advent of the space age is reviewed. By the beginning of the 1960's, accurate radiative models had been developed capable of estimating the global and zonally averaged components of the radiation budget, though great uncertainty in the derived parameters existed due to inaccuracy of the data describing the physical parameters used in the model, associated with clouds, the solar radiation, and the gaseous atmospheric absorbers. Over the century, the planetary albedo estimates had reduced from 89 to 30 percent.

Description: A detailed observational treatment of bidirectional electrons (about 50 to 500 eV) in the distant magnetotail (r not below 100 earth radii) is presented. It is found that electrons in this energy range commonly exhibit strong, field-aligned anisotropies in the tail lobes. Because of large tail motions, the ISEE 3 data provide extensive sampling of both the north and south lobes in rapid succession. These data directly demonstrate the strong asymmetries that exist between the north and south lobes at any one time. The bidirectional fluxes are found to occur predominantly in the lobe directly connected to the sunward interplanetary magnetic field in the open magnetosphere model (north lobe for away sectors and south lobe for toward sectors). Electron anisotropy and magnetic field data are presented which show the transition from unidirectional (sheath) electron populations to bidirectional (lobe) populations. The open nature of the distant magnetopause is demonstrated and it is shown that the source of the higher-energy, bidirectional lobe electrons is the tailward directed electron heat flux population in the distant magnetosheath. Taken together, the present evidence suggests that the bidirectional electrons that were observed in the distant tail are closely related to the polar rain electrons observed previously at lower altitudes. Furthermore, these data provide strong evidence that the distant tail is composed largely of open magnetic field lines in contradistinction to some recently advanced models.

Description: Studies have shown that atmospheric methane, CO and the gaseous OH radical are interdependent: if CH4, CO or OH is perturbed, background concentrations of the other two constituents are affected. Perturbations to OH alter photooxidation rates of numerous natural and anthropogenic trace gases and affect lifetimes of those species that pass from the earth's surface to the free troposphere and stratosphere. It is now known that global atmospheric methane concentrations are increasing; less definite data suggest that carbon monoxide is also increasing. Even before the measurements reported in nine literature references, modeling studies of CH4-CO-OH coupling had led to predictions (Chameides, Liu and Ciceronne, 1977; Sze, 1977; and Hameed, Pinto and Stewart 1979) of future increases of CH4 and CO. A photochemical model is used to look backwards in time by simulating the trace-gas composition of the unpolluted troposphere at the start of the industrial era (taken as 1860) and at intervals up to 1985. It is found that the OH concentration in the background troposphere has decreased significantly and O3 has increased due to increases of CH4 and CO; calculated changes depend on temporal trends of NOx (NOx = NO + NO2), for which no historical data are available. The calculations allow recent trace-gas trends affecting background chemistry and climate to be viewed in a longer-term context.

Description: The AMPTE artificial comet of Dec. 27, 1984, developed a well-defined core (maximum size about 160 x 100 km) of cold barium ions, surrounded by a diffuse coma, 500 km in diameter, consisting of ions extracted from the core. A plasma tail extended from the core, mainly directed away from the sun. The plasma tail and diffuse coma consisted of energetic ions (above 200 eV). Confounding predictions, the artificial comet survived for barely five minutes, and the core of the comet moved southward, rather than in the direction of the solar wind.

Description: Magnetometers aboard the IRM and UKS spacecraft monitored the magnetic field during the AMPTE artificial comet experiment of Dec. 27, 1984. Rapid photoionization of the released barium vapor resulted in the formation of a magnetic cavity, shielded from the ambient magnetic field.The presence of this highly conductive obstacle caused draping and compression of the solar wind magnetic field.

Description: Evidence is presented for strong coupling between the diurnal components of zonal neutral winds and ion drifts, suggesting that the relative importance of the E- and F-region dynamos be reevaluated. Measurements of zonal neutral winds in the equatorial region of the earth's thermosphere at an average altitude of about 350 km show that the nighttime zonal winds are very similar to the zonal ion-drifts. That similarity is examined, comparing the corresponding tidal components of the 24 hr variations of these two parameters. The amplitude spectrum of the neutral winds exhibits primary and secondary maxima at the diurnal and ter-diurnal frequencies respectively, while the ion-drift spectrum shows only the diurnal maximum. It is found that the simularity between neutral winds and ion-drifts is strongest in the diurnal mode where the phases differ by less than one half hour, the amplitude of the ion-drift being between 70 percent and 80 percent that of the neutral wind, suggesting a first-order relation between the two quantities. The largest difference is found in the steady component representing superrotation; under similar conditions of solar activity, the ions superrotate with a velocity of about 30 m/s and the neutrals with 10 m/s. For the ions, the steady component, the phase of the semi-diurnal component and the amplitude of the ter-diurnal component appear to be sensitive to solar activity and are responsible for the observed solar cycle variations in the times of eastward-to-westward reversals between 0400 and 0700 LT. The ion-drift diurnal amplitude and phase are relatively insensitive to changes in solar activity.

Description: The global distribution of nitrogen dioxide in the middle to upper stratosphere (25-45 km altitude) for the period February 1979 to November 1981 has been determined from observations of attenuated solar radiation in the visible region 0.385-0.45 micron by the Stratospheric Aerosol and Gas Experiment (SAGE) satellite instrument. The SAGE-derived NO2 vertical profiles compare well with observations by balloon- and aircraft-borne sensors. The global SAGE NO2 distributions generally show a maximum in mixing ratio of 8 parts per billion by volume at about 35 km altitude near the equatorial latitudes at local sunset. The location of the mixing ratio peak moves synchronously with the overhead sun for the four different seasons. High-latitude NO2 column content shows strong seasonal variation, with a maximum in local summer and a minimum in local winter. Selected data at high-latitude winter seasons are presented, suggesting that the large variation shown could be explained by the coupling of both dynamics and photochemistry of the NO(x) species. Finally, profiles of the ratio of sunset to sunrise NO2 mixing ratios, peaking at about a factor of two at 30 km, are shown.

Description: Observations of NO2 from the limb infrared monitor of the stratosphere (LIMS) experiment in high-latitude summer are presented. Appropriate selection of latitude and days during the month of May yields NO2 observations obtained during the afternoon and evening at solar zenith angles ranging from about 35-110 deg. These data show that the NO2 abundances in the stratosphere become strongly dependent on the solar zenith angle for angles exceeding about 80 deg. Model calculations and other observations suggest that from about 80-95 deg this dependence probably reflects variations in the propagation of the visible radiation that photodissociates NO2. The data obtained at zenith angles greater than about 95 deg provide clear evidence for the night decay of NO2 to form N2O5, and the observed decay rate is shown to be consistent with present theory.

Description: A statistical study of IMP 6, 7, and 8 magnetotail magnetic field measurements near the equatorial plane reveals new information about various aspects of magnetospheric structure. More magnetic flux crosses the equatorial plane on the dawn and dusk flanks of the tail than near midnight, but no evidence is found for a dependence on the interplanetary magnetic field sector polarity. Field magnitudes within 3 earth radii of the equatorial plane near dawn are more than twice as large as those near dusk for Xsm = -20 to -10 earth radii. The frequency of occurrence of southward fields is greatest near midnight, and such fields are seen almost twice as often for Xsm = -20 to -10 earth radii as for Xsm beyond -20 earth radii. This latter result supports the idea that the midnight region of the tail between 10 and 20 is a special location where neutral lines are particularly apt to form. Such a neutral line will approach nearest the earth in the midnight and premidnight region, where substorms are thought to have their onset.

Description: An analysis of the data on the asymmetries of the terrestrial thermospheric semiannual oscillation (SAO), recorded by satellites, radar stations, and rocket soundings (Hedin, 1983), is presented. The possible sources for the thermospheric SAO are discussed. An interpretation is presented of the hemispheric asymmetries of the thermospheric SAO in terms of gravity-wave activities, in which the proposed mechanism is associated with the hemispheric asymmetries in the atmospheric circulation due to the orographic differences between the two hemispheres. Consideration is given to the energy requirements for the observed hemispheric difference in the thermospheric SAO. The overall evidence supporting the proposed interpretation is discussed.

Description: In this paper, Solar Backscatter Ultraviolet (SBUV) measurements of solar irradiance and predictions from the Mg 280-nm index are compared with each other and with coincident Solar Mesosphere Explorer (SME) and rocket measurements. The SBUV irradiances show a systematic decrease with time not seen in the rocket measurements; a correction for this decrease is introduced. The scatter and overall structure in the SME spectra is 3-5 percent, of the order of or larger than most of the changes predicted by the Mg index. The corrected SBUV ratio and the Mg index prediction for it agree to within 1 percent. Such agreement supports a common origin for variations between solar maximum and minimum and those for individual rotations: the degree to which active regions cover the visible hemisphere of the sun.

Description: Daily average solar proton flux data for 1978 and 1979 are used in a proton energy degradation scheme to derive ion pair production rates and atomic nitrogen production rates. The latter are computed in a form suitable for inclusion in an atmopheric, two-dimensional, time-dependent photochemical model. Odd nitrogen distributions are computed from the model, including atomic nitrogen production from solar protons, and are compared with baseline distributions. The comparisons show that the average effect of the solar protons in 1978 and 1979 was to cause changes in odd nitrogen only above 10 mbar and at latitudes only above about 50 deg in both hemispheres. The influence of the solar proton-produced odd nitrogen on the local abundance of odd nitrogen depends primarily on the background odd nitrogen abundance as well as the altitude and season.

Description: Analyses of nonseasonal changes in total column ozone from satellite observations during the period 1970-86 suggest, when combined with analyses of Dobson network data, that the largest reduction in global ozone since 1959 occurred between 1978 and 1986. The existence of an Arctic region of enhanced ozone depletion with similar but less pronounced characteristics of the Antarctic region is described. Before 1983 large rates of decrease were confined to high latitudes, subsequently regions of large rates of ozone depletion have appeared at midlatitudes.

Description: The possible climatic effects of a drastic decrease in cloud condensation nuclei (CCN) associated with a severe reduction in the global marine phytoplankton abundance are investigated. Calculations suggest that a reduction in CCN of more than 80 percent and the resulting decrease in marine cloud albedo could have produced a rapid global warming of 6 C or more. Oxygen isotope analyses of marine sediments from many parts of the world have been interpreted as indicating a marked warming coincident with the demise of calcareous nannoplankton at the K/T boundary. Decreased marine cloud albedo and resulting high sea surface temperatures could have been a factor in the maintenance of low productivity in the 'Strangelove Ocean' period following the K/T extinctions.

Description: Measurements have been made of stratospheric N2O using the Stony Brook millimeter-wave remote sensing spectrometer at McMurdo Station, and NO2 mixing ratios are found that are less than 1.5 at 20 km and less than 1.10 at 25 km compared to values measured during the Antarctic summer. The observed mixing ratios are also much less than those predicted by global-scale models of stratospheric chemistry and dynamics. As the NO2 signal remained very weak when McMurdo was at the edges of the ozone hole and showed no signs of recovering during October, it is concluded that the geographical and temporal extent of the region of low NO2 is comparable to or greater than that of the ozone hole. These results argue against theories that require springtime upwelling to explain the Antarctic ozone hole. It is suggested that the air in the Antarctic lower stratosphere during late winter and early spring has been subjected to considerable downward transport.

Description: The effects of horizontal diffusion coefficients K(yy) and K(yz), computed directly from the residual circulation, on the N2O distribution in a photochemical model were investigated, using a modified version of the two-dimensional model of Guthrie et al. (1984). The residual circulation was computed using the NMC's temperature data and the heating rates reported by Rosenfield et al. (1987). As compared with the effect of the residual circulation alone, the use of horizontal diffusion coefficients produced substantial changes in the N2O distribution and increased the N2O's lifetime values by a few percent. It is suggested that trace gases, such as CH4, CFCl3, CF2Cl2, CH3Cl, and CCl4, which impact the NO(x), HO(x), and Cl(x) radical distributions and therefore ozone, will be influenced in a similar manner by the addition of more realistic diffusion fields.

Description: ISIS-1, ISIS-2, and DE-1 VLF electric field data from Kashima station, Japan are used to investigate characteristics of whistler triggered emissions in the topside ionosphere. The occurrence rate for nonducted whistler triggered emission is shown to be distributed randomly between L = 2.0 and 4.2, while the occurrence rate of ducted whistler triggered emissions increases with latitudes between L = 1.5 and 2.9, attains a maximum at L = 2.7, and abruptly drops off at L = 3.0. The findings indicate that some whistler triggered emissions may be generated by the interaction of whistlers with magnetospheric electrons.

Description: Global water redistriburtion between the oceans, atmosphere and continents causes changes in the earth's rotation and gravitational field. To conserve water mass, the effect of the small uniform change in sea-level must be considered. Explicit formulas are provided for these sea-level corrections to the gravitational Stokes coefficients, polar motion and length of day. In two recent publications, this sea-level correction term for polar motion was given incorrectly. These errors which arose from normalization conventions with the ocean function are corrected.

Description: In April 1986, during passage of the SAGE I satellite, the first simultaneous measurements of the atmospheric backscattering coefficient beta (pi, 10.6 microns) were made with an airborne CO2 lidar. Individual ratios of beta and the SAGE II extinction sigma (1.02 micron) are in reasonable accord with previously calculated values. The trend with height shows a distinctly nonlinear relation, which is probably attributable to steadily changing size distributions of aerosols.

Description: This paper reviews data on in situ balloon-borne measurements on stratospheric ozone concentrations and aerosol contents obtained prior to 1986, along with the measurements obtained in 1986 during the National Ozone Expedition. The data indicate that the phenomenon of ozone depletion appears to be shaped spatially and temporally by dynamical stratospheric phenomena. In terms of Antarctic stratospheric research, it appears that the most important problems at the moment involve delineating the springtime ozone depletion through accurate in situ measurements of temperature, trace gas, and particle size (in addition to remote sensing from space).

Description: Recent concern over possible long term stratospheric changes caused by the introduction of man-made compounds has increased the need for instrumentation that can accurately measure stratospheric minor constituents. The technique of radio spectroscopy at millimeter wavelengths was first used to observe rotational transitions of stratospheric ozone nearly two decades ago, but has not been highly developed until recently. A ground-based observing technique is reported which employs a millimeter-wave superheterodyne receiver and multichannel filter spectrometer for measurements of stratospheric constituents that have peak volume mixing ratios that are less than 10 to the -9th, more than 3 orders of magnitude less than that for ozone. The technique is used for an extensive program of observations of stratospheric chlorine monoxide and also for observations of other stratospheric trace gases such as (O-16)3, vibrationally excited (O-16)3, (O-18)2(O-16), N2O, HO2, and HCN. In the present paper, analysis of the observing technique is given, including the method of calibration and analysis of sources of error. The technique is found to be a reliable means of observing and monitoring important stratospheric trace constituents.

Description: Nineteen magnetic clouds are identified in the years from 1978 through 1982 and studied using superposed epoch analysis. The magnetic-field intensity, proton density and proton temperature are enhanced ahead of magnetic clouds that are preceded by shock, while strong magnetic-field intensity and low proton temperature are observed within the clouds. A relatively large (about 2.5 percent) decrease in cosmic-ray intensity is associated with magnetic clouds that are preceded by a shock, perhaps caused by the turbulent sheath behind an interplanetary shock ahead of the magnetic cloud, whereas only a small (0.5 percent) decrease in intensity is associated with the magnetic cloud itself. Magnetic clouds can produce geomagnetic activity with a decrease in Dst index of the order 100 gamma. The magnitude of the change in the Dst index for the case when southward fields arrive first is comparable to that for the case when northward fields arrive first, and the phase is such that geomagnetic activity is associated with southward fields.

Description: Balloon observations of NO and ozone near sunset and sunrise around 32 km were made on September 19 and October 4, 1985 from Aire sur l'Adour, France. The NO concentration built up rapidly after sunrise, remained fairly steady during the day, and decreased slowly near sunset. This variation is interpreted quantitatively in terms of current photochemistry in relation to ozone.

Description: The effect of line mixing on the effective blackbody brightness temperature of the earth in the region of the 15-micron nu 2 Q branch of CO2 is calculated. The procedures used to compute line mixing follow those used to successfully model mixing observed in laboratory spectra of two near-infrared CO2 Q branches. The atmospheric radiances are calculated between 664 and 670/cm, a spectral region that is of interest for sounding the upper troposphere and the stratosphere. Mixing was found to lower the observed brightness temperatures by as much as 3 K for some temperature profiles. Ignoring this effect would significantly impact the ability of advanced sounders to produce temperature retrievals which meet the projected accuracy requirement of 1 K/km.