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  • Articles  (239)
  • Chemistry  (233)
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  • 1
    ISSN: 1432-0789
    Keywords: Key words Grasslands ; Management ; Microbial biomass ; Bacteria ; Fungi ; Nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  There is much interest in the development of agricultural land management strategies aimed at enhancing reliance on ecosystem self-regulation rather than on artificial inputs such as fertilisers and pesticides. This study tested the usefulness of measures of soil microbial biomass and fungal:bacterial biomass ratios as indicators of effective conversion from an intensive grassland system, reliant mainly on fertilisers for crop nutrition, to a low-input system reliant mainly on self-regulation through soil biological pathways of nutrient turnover. Analysis of soils from a wide range of meadow grassland sites in northern England, along a gradient of long-term management intensity, showed that fungal:bacterial biomass ratios (measured by phospholipid fatty acid analysis; PLFA) were consistently and significantly higher in the unfertilised than the fertilised grasslands. There was also some evidence that microbial biomass, measured by chloroform fumigation and total PLFA, was higher in the unfertilised than in the fertilised grasslands. It was also found that levels of inorganic nitrogen (N), in particular nitrate-N, were significantly higher in the fertilised than in the unfertilised grasslands. However, microbial activity, measured as basal respiration, did not differ between the sites. A field manipulation trial was conducted to determine whether the reinstatement of traditional management on an improved mesotrophic grassland, for 6 years, resulted in similar changes in the soil microbial community. It was found that neither the cessation of fertiliser applications nor changes in cutting and grazing management significantly affected soil microbial biomass or the fungal:bacterial biomass ratio. It is suggested that the lack of effects on the soil microbial community may be related to high residual fertility caused by retention of fertiliser N in the soil. On the basis of these results it is recommended that following the reinstatement of low-input management, the measurement of a significant increase in the soil fungal:bacterial biomass ratio, and perhaps total microbial biomass, may be an indicator of successful conversion to a grassland system reliant of self-regulation.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0975
    Keywords: Key words Otolith ; Chemistry ; ICP-MS ; Stock discrimination ; Epinephelus striatus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract  We examined the utility of otolith minor and trace element chemistry, assayed with inductively coupled plasma mass spectrometry (ICP-MS), as a means of delineating population structure in the Nassau grouper (Epinephelus striatus). We characterized the elemental composition of otoliths collected in 1993 from three locations in Exuma Sound, Bahamas and from Glover Reef, Belize in 1995. A single location in Exuma Sound was sampled in 1994 to test temporal variability in otolith composition. Five elements (Ca, Zn, Sr, Ba and Pb) were routinely detected, at levels significantly above background, by solution-based ICP-MS. Results from analysis of variance of elemental data, expressed as a ratio to Ca, indicated that there were no significant differences among the Exuma locations for any element, but significant variability was found between Glover Reef and the pooled Exuma localities for Zn/Ca, Sr/Ca and Ba/Ca ratios. Significant inter-annual differences at one Exuma Sound location was restricted to Ba/Ca ratios. Discriminant function analysis correctly classified 86% and 95% of the Belize and pooled Exuma sites, respectively. Otoliths from Belize were characterized by low Zn/Ca and high Ba/Ca and Pb/Ca ratios compared to otoliths from fish collected in Exuma Sound. Although differences in Ba levels may be related to upwelling at Glover Reef, more data are needed to definitely link otolith composition with regional differences in water chemistry.
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Soil & Tillage Research 30 (1994), S. 345-357 
    ISSN: 0167-1987
    Keywords: Catchment ; Management ; Productivity ; Sustainability ; Unit
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 88 (1999), S. 317-324 
    ISSN: 1437-3262
    Keywords: Key words Natural hazards ; Risk studies ; Floods ; Slope failures ; Snow avalanches ; Earthquakes ; Management ; multi-institutional ; interdisciplinary
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Although British Columbia experiences many natural hazards, there is as yet no unified policy to promote natural hazard management in the province. The problem is not in the quantity and quality of geoscience assessment of natural hazards, but instead, it is suggested, in the isolation of that work from broader risk perspectives and in the lack of clarity of division of responsibilities between various levels of government. The example of recent changes in perception of the terrain stability problem illustrates how natural hazard problems are driven by social and political priorities rather than by geoscience priorities.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 118 (1980), S. 128-151 
    ISSN: 1420-9136
    Keywords: Galactic cosmic rays ; Solar proton events ; Particle precipitation ; Chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract An assessment is made of the relative contribution of certain classes of energetic particle precipitation to the chemical composition of the middle atmosphere with emphasis placed on the production of odd nitrogen and odd hydrogen species and their subsequent role in the catalytic removal of ozone. Galactic cosmic radiation is an important source of odd nitrogen in the lower stratosphere but since the peak energy deposition occurs below the region where catalytic removal of O3 is most effective, it is questionable whether this mechanism is important in the overall terrestrial ozone budget. The precipitation of energetic solar protons can periodically produce dramatic enhancement in upper stratospheric NO. The long residence time of NO in this region of the atmosphere, where catalytic interaction with O3 is also most effective, mandates that this mechanism be included in future modelling of the global distribution of O3. Throughout the mesosphere the precipitation of energetic electrons from the outer radiation belt (60°≲Λ≲70°) can sporadically act as a major local source of odd hydrogen and odd nitrogen leading to observable O3 depletion. Future satellite studies should be directed at simultaneously measuring the precipitation flux and the concomitant atmosphere modification, and these results should be employed to develop more sophisticated models of this important coupling.
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  • 6
    ISSN: 1432-0495
    Keywords: Key words Arid lands ; Sustainable development ; Natural resources ; Management ; Geological setting ; Surficial geology ; Land systems ; Landsat images ; Surface water hydrology ; Drainage network ; Field experiments ; Infiltration characteristics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  This paper summarizes the information on the geology and natural resources of the Jordan Badia Research and Development Programme. The research focused on the issue of the environment in arid lands as an aid to provide practical options for sustainable development. This paper presents results of field studies in the following areas related to the sustainable development of the Safawi area in the northern Jordan Badia; geomorphology, including landform, soil, lands, processes and hazards, geology and physical resources and surface water hydrology. Tertiary-Quaternary continental basalt flows and tuffs cover approximately 11 000 km2, the majority of the Safawi area. In addition to extensive basalt lava flows, the programme area includes a variety of geological outcrops and potential sources of economic products that include the following: Tuff/Scoria, Zeolite/Olivine, Porcellanite, potential sources of aggregate/construction materials, ornamental stone, building stone, basalt for manufacturing of rock wool, and materials suitable for producing lightweight aggregate. The whole of the eastern Badia exhibits major fault systems, many of which were identified from Landsat TM images. The system of wadis which drains the Badia is extensive, with the general flow from the north to the south and south-west. A noticeable geomorphic surficial deposit occuring throughout much of the Badia is fine-grained, water-lain sediments that vary in size and character. The local designation for the fine sediment deposits is Qaa. An MSS scene for the area under consideration has been studied. Twelve major geomorphic subdivisions or zones can be identified. Individual land system units have been identified by traversing the programme area. Key sites have been visited based on Landsat TM image interpretation. To a large extent, key areas were subdivided after their initial identification on the Landsat scene and corroboration in the field. The surface drainage of the Badia region can be broadly divided into wadi systems, areas of distinct channelized flow, and Qaa, predominantly fine-grained sedimentary basins of low relief. Spatial variability in infiltration rates across the wadi-Qaa system were determined from field experiments. Infiltration rates were found to be medium-high in the wadi channels but decrease rapidly for the Qaa materials. Apparently runoff from wadi side slopes will be high, and water storage occurs along the wadi channels while ponding occurs in the Qaa areas.
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  • 7
    ISSN: 1432-0495
    Keywords: Key words Development ; Management ; Surface water resource ; Groundwater resource ; Irrigation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Intensive application of surface water in command areas of irrigation projects is creating water logging problems, and the increase of groundwater usage in agriculture, industry and domestic purposes (through indiscriminate sinking of wells) is causing continuous depletion of water levels, drying up of wells and quality problems. Thus the protect aquifers to yield water continuously at economical cost, the management of water resources is essential. Integrated geological, hydrological (surface and groundwater) and geochemical aspects have been studied for the development and management of water resources in drought-prone Cuddapah district. The main lithological units are crystallines, quartzites, shales and limestones. About 91 000 ha of land in the Cuddapah district is irrigated by canal water. A registered ayacut of about 47 000 ha is irrigated by 1368 minor irrigation tanks. A total of 503 spring channels are identified in the entire district originating from the rivers/streams, which has the capacity of irrigating about 8700 ha. The average seasonal rise in groundwater level is 7.32 m in quartzites, 5.35 m in crystallines, 3.82 m in shales, 2.50 m in limestones and 2.11 m in alluvium. Large quantities of groundwater are available in the mining areas which can be utilised and managed properly by the irrigation department/cultivators for the irrigation practices. Groundwater assessment studies revealed that 584 million m3 of groundwater is available for future irrigation in the district. From the chemical analysis, the quality of groundwater in various rock units is within the permissible limits for irrigation and domestic purposes, but at a few places the specific conductance, chloride and fluoride contents are high. This may be due to untreated effluents, improper drainage system and/or the application of fertilisers.
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  • 8
    ISSN: 1432-0975
    Keywords: Key words Fragmentation ; Sexual reproduction ; Planula larvae ; Scleractinia ; Management ; Tourism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Natural and anthropogenic disturbances may fragment stony reef corals, but few quantitative data exist on the impacts of skeletal fragmentation on sexual reproduction in corals. We experimentally fragmented colonies of the branching coral Pocillopora damicornis and determined the number and size of planula larvae released during one lunar reproductive cycle. Partially fragmented colonies significantly delayed both the onset and peak period of planula release compared with intact control colonies. Most fragments removed from the corals died within 11–18 days, and released few planulae. The total number of planulae released per coral colony varied exponentially with remaining tissue volume, and was significantly lower in damaged versus undamaged colonies. However, the number of planulae produced per unit tissue volume, and planula size, did not vary with damage treatment. We conclude that even partial fragmentation of P. damicornis colonies (〈25% of tissue removed) decreases their larval output by reducing reproductive tissue volume. Repeated breakage of corals, such as caused by intensive diving tourism or frequent storms, may lead to substantially reduced sexual reproduction. Therefore, reef management should limit human activities that fracture stony corals and lead to decreases in colony size and reproductive output.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Boundary layer meteorology 85 (1997), S. 197-222 
    ISSN: 1573-1472
    Keywords: Turbulence ; Chemistry ; Closure ; Convective boundary layer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We study the interactions of chemistry and turbulent mixing of tracersin the convective boundary layer with a second-order closure model,including higher order chemistry terms. In order to limit the number of predictive equations we prescribe the profiles for ¯w¯Θ, ¯w¯θ ¯θ and the lengthscale l. However, for model validation we treat temperature and humidity asinert tracers, and compare the results with profiles observed during theAir Mass Transformation Experiment, and with similarity expressions for thesurface layer. We find good agreement of the mean profiles, but the (co-)variances are slightly underpredicted. Furthermore, the model usesdiagnostic equations expressing third moments of concentration in terms ofsecond moments and their vertical derivatives. They are compared withlarge-eddy model results, showing good agreement and, therefore, thesimplifications are justified. The model is applied to the transport of two gases subject to one bimolecular reaction. The importance of concentration correlations on themean transformation rate is studied. For two gases diffusing in oppositedirections we find for moderate and fast chemistry a 50% and90% decreased transformation rate due to the negatively correlatedconcentrations. These values are similar to large-eddy results of Schumannand Sykes et al. For two bottom-up tracers we find that the covariance ofboth reactive species is either positive or negative, increasing or reducingthe effective transformation rate depending on the Damköhler number (the ratio of the turbulent and the chemistry timescale). A significantdirect influence of chemistry on the flux divergence is found in bothcases. According to the model the effective transport to mid-levels of theboundary layer is increased when two reactive tracers diffuse in oppositedirections, and decreased in the case of two bottom-up tracers.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Earth, moon and planets 88 (2000), S. 35-58 
    ISSN: 1573-0794
    Keywords: Chemistry ; interplanetary dust particles (IDPs) ; Leonids ; meteor trails ; meteoroids ; meteors ; structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The cometary Leonid meteoroids represent a size range in between largest carbon-richIDPs and the smallest CI meteorites. Their dustball structure and chemistry offer anopportunity to constrain hierarchical dust accretion inferred from petrologic studies ofaggregate and cluster IDPs. The Leonid shower meteoroids of known ``comet ejection''ages provide an opportunity to study space weathering of cometary dust over periodsof up to several hundred years. The meteors and aggregate and cluster IDPs displaycontinuous thermal modification of organics and volatile element (Na, K-bearing phases), that occur as discrete minerals and amorphous solids each different response during kinetically controlled ablation. Leonid meteoroids are not excessively Na-rich. The occurrences of Leonid meteors can now be accurate predicted and combined withknowledge better models for the settling rates, collections of surviving dust becomea comet nucleus-sampling mission.
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