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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 2667-2675 
    ISSN: 0009-2940
    Keywords: Alkene ligands ; 1,6-Dienes ; Nickel complex ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1,6-Heptadiene Nickel(0) Complexes:rac/meso-(μ-η2,η2-C7{Ni(η 2,η2-C7H12)}2 und L-Ni(η2,η2-C7H12)Ni(CDT) dissolves in 1,6-heptadiene with displacement of the CDT to yield the dinuclear homoleptic product rac/meso-(μ- η2,η2-C7H12){Ni(η2, η2-C7H12)}2 (1) as a mixture of stereoisomers, in which the nickel atoms are trigonal-planar coordinated by a chelating 1,6-diene ligand and one C=C bond of a bridging diene ligand. The stereoisomers differ in the coordination mode of the bridging diene ligand.-The bridging diene ligand in 1 can be displaced by various donor/acceptor molecules. In pentane, 1 reacts with ethene to yield a solution of mononuclear (C2H4)Ni(η2,η2-C7H12) (2). With alkynes unstable complexes are formed of which the anticipated ethyne derivative (C2H2)Ni(η2,η2-C7H12) (3) decomposes explosively at - 100°C. With isocyanides, methylenephosphoranes, methyllithium, amines, pyridines, phosphanes, and phosphites (i.e. C, N, P donors) crystalline complexes of type L-Ni(η2.η2 C7H12) have been obtained, of which the derivatives with L=tBuN = C 4, Me3PCH2 5, LiCH3 6, C7H13N7, C5H5N 8, Me3P 9, iPr3P 10, Ph3P 11, (PhO)3P 12 are characterized here. For 11 the crystal structure has been determined.
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  • 2
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/article
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  • 3
    Unknown
    Cambridge, Mass : MIT Press
    Keywords: United States, Economic conditions, 1981-2001. ; United States, Economic policy, 1993-2001.
    Notes: U.S. monetary policy during the 1990s / N. Gregory Mankiw -- Fiscal policy and Social Security policy during the 1990s / Douglas W. Elmendorf, Jeffrey B. Liebman, David W. Wilcox -- Tax policy from 1990 to 2001 / Eugene Steuerle -- Between meltdown and moral hazard : the international monetary and financial policies of the Clinton administration / J. Bradford DeLong, Barry Eichengreen -- International trade policy in the 1990s / Robert Z. Lawrence -- The "new economy" and information technology policy / Pamela Samuelson, Hal R. Varian -- Antitrust policy in the Clinton administration / Robert E. Litan, Carl Shapiro -- Energy policy during the 1990s / Paul L. Joskow -- National environmental policy during the Clinton years / Robert W. Hahn, Robert N. Stavins -- Putting students and workers first? : education and labor policy in the 1990s / Alan B. Krueger, Cecelia E. Rouse -- The Clinton legacy for America's poor / Rebecca M. Blank, David T. Ellwood -- Health policy in the Clinton era : once bitten, twice shy / David Cutler, Jonathan Gruber -- Medicare / Joseph P. Newhouse -- The process of economic policy-making during the Clinton administration / Jonathan M. Orszag, Peter R. Orszag, Laura D. Tyson
    Pages: xii, 1119 p.
    ISBN: 0-585-44277-0
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  • 4
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 5
    Publication Date: 2022-04-08
    Description: This case study examined the structural change in Lusatia caused by the system change from a centrally planned economy to a market economy in the period 1990-2015. It analysed the structural change process and the structural policies implemented as a reaction to this process with the objective to make this knowledge available for future structural change processes in other (coal) regions by deploying various qualitative and quantitative methods of empirical social and economic research. A discourse analysis helped to recognise who supported which structural policy approaches and why - and thus gives indications of the possible relevance of experiences for other regions.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 6
    Publication Date: 2022-02-18
    Description: Das Vorhaben analysiert 1.) die Argumente verschiedener Positionen im Wachstumsdiskurs und formuliert eine idealtypische "vorsorgeorientierte Postwachstumsposition". Er präsentiert zudem Ursachen von Wirtschaftswachstum und identifiziert gesellschaftliche Bereiche, deren Funktion vom Wirtschaftswachstum abhängen könnte. Darüber hinaus werden Reformvorschläge diskutiert, um diese Wachstumsabhängigkeit zu verringern. Das Vorhaben untersucht 2.) die Relevanz der Postwachstumsdebatte für Ressourcenpolitik und eine entsprechende Instrumentierung. Außerdem werden 3.) konstitutive Kernelemente einer nachhaltigen (Postwachstums-)Gesellschaft bestimmt. Das Vorhaben setzt damit Impulse zur gesellschaftlichen Debatte über die Ausgestaltung und Instrumentierung von Transformationspfaden für "gesellschaftliches Wohlergehen innerhalb planetarer Grenzen".
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 7
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-06-20
    Description: Der Materialverbrauch entwickelter Volkswirtschaften wird von verschiedener Seite als zentraler Indikator für die ökologische Zukunftsfähigkeit industriellen Wirtschaftens angesehen: die vom Menschen verursachten Stoffströme seien zu hoch und müßten reduziert werden, um die Ökosphäre als Grundlage menschlichen Lebens und Wirtschaftens nachhaltig zu sichern. Am Wuppertal Institut wurden daher erstmals Zeitreihen verschiedener Kategorien des gesamtwirtschaftlichen Materialverbrauchs ermittelt und publiziert. Internationale Vergleichsdaten existieren für die USA, die Niederlande und Japan. In diesem Papier werden nun Vergleiche anderer Art angestellt: wie entwickelte sich in den letzten drei Jahrzehnten das ökologische Belastungspotential der deutschen Volkswirtschaft, gemessen an den Materialströmen, im Vergleich zu ökonomischen Eckdaten, wie dem realen Bruttoinlandsprodukt, der Beschäftigung, oder des Kapitalstocks. Das Ziel dieses Papiers besteht darin, die Zeitreihen dieser ökologischen Indikatoren denen solcher ökonomischer Größen gegenüberzustellen, mit denen sie in einem produktionstheoretischen Zusammenhang stehen. Auf Basis derartiger Arbeiten sind vertiefende und empirisch abgesicherte Aussagen zu einer Entkopplung des BIP vom Materialverbrauch sowie zu den Möglichkeiten eines technischen Fortschritts möglich, der arbeitsschaffend und umweltsparend verläuft.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 8
    Publication Date: 2020-02-12
    Description: To test the injection behaviour of CO2 into brine-saturated rock and to evaluate the dependence of geophysical properties on CO2 injection, flow and exposure experiments with brine and CO2 were performed on sandstone samples of the Stuttgart Formation representing potential reservoir rocks for CO2 storage. The sandstone samples studied are generally fine-grained with porosities between 17 and 32% and permeabilities between 1 and 100 mD. Additional batch experiments were performed to predict the long-term behaviour of geological CO2 storage. Reservoir rock samples were exposed over a period of several months to CO2-saturated reservoir fluid in high-pressure vessels under in situ temperature and pressure conditions. Petrophysical parameters, porosity and the pore radius distribution were investigated before and after the experiments by NMR (Nuclear Magnetic Resonance) relaxation and mercury injection. Most of the NMR measurements of the tested samples showed a slight increase of porosity and a higher proportion of large pores.
    Keywords: 550 - Earth sciences
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  • 9
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 10
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    In:  Publikationen der Deutschen Gesellschaft für Photogrammetrie, Fernerkundung und Geoinformation ; 22
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 11
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 12
    Publication Date: 2022-02-18
    Description: The German government aims to achieve virtually climate-neutral building stock by 2050 to tackle climate change. To realise this goal, comprehensive policy packages based on neoclassical economic theory are in place to foster energy efficiency investment. However, in the building sector, there is increasingly a gap between this aspiration and the reality. It is claimed that one of the main reasons for this is that the existing policy framework fails to address the specific characteristics and needs of different groups of building owners. This is a particular challenge in Germany, where 80% of all dwellings are owned privately and 37% are rented out by small private landlords (SPL). Despite the significant numbers of SPL, they often follow black box decision-making processes when considering energy renovations. In this study, the author uses an explanatory model to understand the decision-making processes of SPL, combining theoretical aspects from different research disciplines. This model was applied to a low-demand housing market in a neighbourhood in the Ruhr area. Eighteen semi-structured interviews (each lasting between 37 and 115 min) were conducted, demonstrating that in addition to economic factors, the values, beliefs, norms and routines of SPL - as well as their personal capabilities and contextual factors - play an important role in their decision-making. Based on the findings, recommendations are made for enhancing the effectiveness of existing energy efficiency policies and other supporting instruments (e.g. tenancy law and social legislation), tailored to the specific needs of SPL.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 13
    ISSN: 0009-2940
    Keywords: Dinuclear rhodium and iridium complexes ; Bis(cyclopentadienyl)methane dianion as bridging ligand ; Substitution and bridge-splitting reactions ; Rhodium complexes ; Iridium complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bis(cyclopentadienyl)methane-Bridged Dinuclear Complexes, IV[1].  -  Synthesis, Structure, and Reactivity of Dinuclear Rhodium and Iridium Complexes in the Oxidation State +I and +III with the Bis(cyclopentadienyl)methane Dianion as Bridging LigandThe rhodium compounds [CH2(C5H4)2][Rh(L)(C2H4)]2 (2, 4) were prepared from [RhCl(L)(C2H4)]2 (1, 3) and CH2(C5H4)2Li2 in 92 and 73% yield, respectively. The reaction of 4 with Cl2, Br2, and I2 led to the almost quantitative formation of the dihalogeno derivatives [CH2(C5H4)2][RhX2(PiPr3)]2 (6-8), which on treatment with excess NaBH4 and methanol gave the dihydride [CH2(C5H4)2][RhH2(PiPr3)]2 (10). From [RhCl(C8H14)2]2 (12), PiPr3, and CH2(C5H5)2 the chloro(hydrido)rhodium complex [CH2(C5H4)2][RhH(Cl)(PiPr3)]2 (13) was obtained. Protonation of 10 with CF3CO2H in the presence of NH4PF6 gave the PF6 salt of the hydrido-bridged cation {[CH2(C5H4)2]-[RhH(PiPr3)]2(μ-H)}+ (14) of which the crystal structure was determined. In solution, fluxional behavior of the cation was observed. The dimethyl compound [CH2(C5H4)2][Rh(CH3)2-(PiPr3)]2 (17), prepared from 6, 7, or 8 and LiCH3 or CH3MgI in 80% yield, reacted with CF3CO2H at  -  78° C to give the tri-fluoroacetato derivative 18; this on treatment with P(OMe)3 and dmpe formed the dicationic complexes 19 and 20, respectively. The dinuclear iridium compounds [CH2(C5H4)2]-[Ir(olefin)2]2 (26, 27) and [CH2(C5H4)2][Ir(C8H12)]2 (28) were prepared from [IrCl(L)2]2 (23-25) and CH2(C5H4)2Li2 and used for the synthesis of {[CH2(C5H4)2][IrX2]2}n (29, 30). Compounds 29 and 30 served as starting materials for the preparation of the dinuclear derivatives [CH2(C5H4)2][IrX2(L)]2 (31-34) and {[CH2(C5H4)2][IrBr2]2(μ-dipy)} (35) and finally also for the dihydrido complex [CH2(C5H4)2][IrH2(PiPr3)]2 (36).
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  • 14
    Publication Date: 2020-02-12
    Description: Multibeam bathymetry revealed the occurrence of numerous craterlike depressions, so-called pockmarks, on the sea floor of the Hammerfest Basin and the Loppa High, south-western Barents Sea. To investigate whether these pockmarks are related to ongoing gas seepage, microbial processes associated with methane metabolism were analyzed using geochemical, biogeochemical and microbiological techniques. Gravity cores were collected along transects crossing individual pockmarks, allowing a direct comparison between different locations inside (assumed activity center), on the rim, and outside of a pockmark (reference sites). Concentrations of hydrocarbons in the sediment, particularly methane, were measured as headspace (free) gas, and in the occluded and adsorbed gas fraction. Down to a depth of 2.6 m below sea floor (mbsf) sulfate reduction rates were quantified by radiotracer incubations. Concentrations of dissolved sulfate in the porewater were determined as well. Neither the sulfate profiles nor the gas measurements show any evidence of microbial activity or active fluid venting. Methane concentrations and sulfate reduction rates were extremely low or even below the detection limit. The results show that the observed sediment structures are most likely paleo-pockmarks, their formation probably occurred during the last deglaciation.
    Keywords: 550 - Earth sciences
    Language: English
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  • 15
    Publication Date: 2020-02-12
    Description: To study the applicability of the passive seismic interferometry technique to near-surface geological studies, seismic noise recordings from a small scale 2-D array of seismic stations were performed in the test site of Nauen (Germany). Rayleigh wave Green's functions were estimated for different frequencies. A tomographic inversion of the traveltimes estimated for each frequency from the Green's functions is then performed, allowing the laterally varying 3-D surface wave velocity structure below the array to be retrieved at engineering–geotechnical scales. Furthermore, a 2-D S-wave velocity cross-section is obtained by combining 1-D velocity structures derived from the inversion of the dispersion curves extracted at several points along a profile where other geophysical analyses were performed. It is shown that the cross-section from passive seismic interferometry provides a clear image of the local structural heterogeneities that are in excellent agreement with georadar and geoelectrical results. Such findings indicate that the interferometry analysis of seismic noise is potentially of great interest for deriving the shallow 3-D velocity structure in urban areas.
    Keywords: 550 - Earth sciences
    Language: English
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  • 16
    ISSN: 0009-2940
    Keywords: Metal dithiolenes ; Dipyridinioethylene dihalides ; Charge-Transfer complexes ; Electrical conductivity ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Charge-Transfer Complexes of Metal Dithiolenes, XIII[1]. - cis-trans-Photoisomerisable Viologens as Redoxactive Acceptors  -  Synthesis and Electrical ConductivityIon Pair Charge-Transfer (IPCT) complexes of the type [A2+[ML2]2-} (1a-f to 4a-f) are synthesized from dianionic metal dithiolenes [M = Ni, Zn, L = cis-1,2-dicyano-1,2-ethene-dithiolate (mnt2-), 2-thioxo-1,3-dithiol-4,5-dithiolate (dmit2-)] and dicationic viologens [A2+ = 4,4′-(1,2-ethenediyl)bis(1-alkylpyridinium)]. The acceptors can exist as cis/trans isomers and may have coordinating properties in the case of 1-cyanoalkyl groups. The IPCT bands are in the range of 500 to 1200 nm and their energy follows the Hush-Marcus relation. For the nickel complexes the reorganization energy amounts to 73, for the zinc compounds to 115 kJ/mol. As shown by X-ray analysis of {A2+[Ni(mnt)2]2-} (2d), A2+ = trans-4,4′-(1,2-ethenediyl)-bis[1-(3-cyanopropyl)pyridinium], the structure consists of stacks of alternating donors and acceptors with a typical plane-to-plane distance of 350 pm. There is no interaction between the cyano group of the acceptor and the nickel atom of the donor. The electrical conductivities of the nickel compounds are in the range of 5 · 10-6 to 3 · 10-11 Ω-1 cm-1, and the corresponding activation energies vary from 0.24 to 0.61 eV. For the dmit complexes these values agree well with the free activation enthalpy of the electron transfer reaction A2+ + [ML2]2- → A+ + [ML2]- calculated from the Hush-Marcus model. This suggests that charge carrier generation occurs by electron transfer. When a trans acceptor is replaced by its cis isomer in [A2+[NiL2]2-}, conductivity changes from 5 · 10-7 to 5 · 10-6 Ω-1 cm-1 and the activation energy from 0.43 to 0.24 eV, when L - dmit2- but stays at about 1 · 10-8 Ω-1 cm-1 for L = mnt2-.
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  • 17
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    In:  Natural Hazards
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 18
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    In:  Hydrological Sciences Journal - Journal des Sciences Hydrologiques
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 19
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 90 (1957), S. 264-277 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus N-Acetyl-D-glucosamin läßt sich kristallisiertes Chromogen III in einer Ausbeute von 40% d. Th. gewinnen. Dieselbe Verbindung wird, wie es die Theorie verlangt, auch aus N-Acetyl-D-galaktosamin erhalten. Es handelt sich um D(+)-5-Dihydroxyäthyi-3-acetamino-furan (I). Diese Konstitution wird gesichert durch eine Synthese der DL-Verbindung, die von Äpfelsäure (4 kg) ausgeht und 17 Reaktionsschritte erforderlich gemacht hat. Das synthet. Racemat stimmt mit dem Chromogen III, das wir aus einem künstlichen Gemisch von 50% D- und 50% L-Acetylglucosamin erhalten haben, genau überein. Aus dem Chromogen III wurde durch katalytische Hydrierung, Abspaltung der Acetylgruppe und Umsetzung mit Methyljodid ein quartäres Ammoniumsalz erhalten, das sich vom Muscarin durch Austausch der end-ständigen CH3-Gruppe gegen CH2OH unterscheidet; die sterischen Verhältnisse an 2 C-Atomen sind noch unbekannt.
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  • 20
    Publication Date: 2020-02-12
    Description: In the framework of the Dead Sea Integrated Research project (DESIRE), 59 seismological stations were deployed in the region of the Dead Sea Basin. Twenty of these stations recorded data of sufficiently high quality between May and September 2007 to be used for ambient seismic noise analysis. Empirical Green’s functions are extracted from cross-correlations of long term recordings. These functions are dominated by Rayleigh waves, whose group velocities can be measured in the frequency range from 0.1 to 0.5 Hz. Analysis of positive and negative correlation lags of the Green’s functions makes it possible to identify the direction of the source of the incoming energy. Signals with frequencies higher than 0.2 Hz originate from the Mediterranean Sea, while low frequencies arrive from the direction of the Red Sea. Travel times of the extracted Rayleigh waves were measured between station pairs for different frequencies, and tomographically inverted to provide independent velocity models. Four such 2D models were computed for a set of frequencies, all corresponding to different sampling depths, and thus together giving an indication of the velocity variations in 3D extending to a depth of 10 km. The results show low velocities in the Dead Sea Basin, consistent with previous studies suggesting up to 8 km of recent sedimentary infill in the Basin. The complex structure of the western margin of the Basin is also observed, with sedimentary infill present to depths not exceeding 5 km west of the southern part of the Dead Sea. The high velocities associated with the Lisan salt diapir are also observed down to a depth of ~5 km. The reliability of the results is confirmed by checkerboard recovery tests.
    Keywords: 550 - Earth sciences
    Language: English
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  • 21
    Publication Date: 2020-02-12
    Description: This study predicts the subsurface temperature distribution of Germany's capital Berlin. For this purpose, a data-based lithosphere-scale 3D structural model is developed incorporating 21 individual geological units. This model shows a horizontal grid resolution of (500 x 500) m and provides the geometric base for two different approaches of 3D thermal simulations, (i) calculations of the steady-state purely conductive thermal field and (ii) simulations of coupled fluid flow and heat transport. The results point out fundamentally different structural and thermal configurations for potential geothermal target units. The top of the Triassic Middle Buntsandstein strongly varies in depth (159‑2,470 m below sea level) and predicted temperatures (15‑95°C), mostly because of the complex geometry of the underlying Permian Zechstein salt. The top of the sub-salt Sedimentary Rotliegend is rather flat (2,890‑3,785 m below sea level) and reveals temperatures of 85-139°C. The predicted 70°C-isotherm is located at depths of about 1,500‑2,200 m cutting the Middle Buntsandstein over large parts of Berlin. The 110°C‑isotherm at 2,900‑3,700 m depth widely crosscuts the Sedimentary Rotliegend. Groundwater flow results in subsurface cooling the extent of which is strongly controlled by the geometry and the distribution of the Tertiary Rupelian Clay. The cooling effect is strongest where this clay-rich aquitard is thinnest or missing thus facilitating deep reaching forced convective flow. The differences between the purely conductive and coupled models highlight the need for investigations of the complex interrelation of flow- and thermal fields to properly predict temperatures in sedimentary systems.
    Keywords: 550 - Earth sciences
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  • 22
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 23
    Publication Date: 2020-02-12
    Description: Hyperspectral remote sensing data open up new opportunities for analyzing urban areas characterized by a large variety of spectrally distinct surface materials. Spectroscopic analysis using diagnostic spectral features yields the potential for automated identification and mapping of these materials. This study proposes a new approach for the determination and evaluation of such spectral features that are robust against spectral overlap between material classes and within-class variability. Analysis is based on comprehensive field and image spectral libraries of more than 21,000 spectra of surface materials widely-used in German cities. The robustness of the interactively defined spectral features is evaluated by a separability analysis. This method is performed based on confusion matrices for each material computed from classification results. For comparison this analysis is also performed for material-specific gray values of selected bands. The obtained commission and omission errors show superiority of the spectral features compared to gray values for most of the investigated materials. The results indicate that robust spectral features yield the potential for unsupervised detection of endmembers in hyperspectral image data.
    Keywords: 550 - Earth sciences
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  • 24
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Di-p-hydrido-bis[1,3-propanbis(dicyclohexylphosphin)]dinickel(Ni—Ni) - Der Bindungszustand in einem Dreizentren-Wasserstoff-überbrückten Ni—Ni-SystemDie Kristallstruktur der Titelverbindung [(C6H11)2PCH2CH2CH2P(C6H11)2NiH]2 (1) wurde aus 4051 Reflexen abgeleitet und zu einem R-Wert von 0.044 verfeinert. Lageparameter aller Wasserstoffatome konnten einer Differenz-Fourier-Synthese entnommen werden. Die Struktur der diamagnetischen Verbindung setzt sich aus zwei P2Ni-Untereinheiten zusammen, welche zweifach mit Wasserstoffatomen (Ni—H 1.6 Å) überbrückt sind. Hierdurch ergibt sich ein bindender Ni—Ni-Abstand von 2.441(1) Å. Im Kristallgitter bilden die Ebenen durch die P2Ni-Untereinheiten einen Interplanarwinkel von 63.3°. Theoretische Betrachtungen sagen für das freie Molekül eine quadratisch planare Anordnung voraus, doch ergibt sich für die Drehbewegung zur beobachteten Geometrie nur eine flache Potentialenergiefläche. Die gefundene Verdrillung resultiert aus starken intramolekularen Abstoßungskräften zwischen den Cyclohexylgruppen der zwei P2Ni-Einheiten.
    Notes: The crystal structure of the title compound, [(C6H11)2PCH2CH2CH2P(C6H11)2NiH]2 (1), has been determined from 4051 reflections and refined to a final R-value of 0.044. The positions of the hydrogen atoms (bridging and non-bridging) have been determined from a difference Fourier synthesis. The molecular structure of the diamagnetic compound consists of subunits doubly-bridged by hydrogen atoms. The Ni—Ni and average Ni—H distances are 2.441 and 1.6 Å, respectively. In the solid state the two planes of the P2Ni units form a dihedral angle of 63.3°. Theoretical considerations predict a square-planar structure for the idealized molecule with a soft potential energy surface for a twisting motion towards the observed geometry. The observed twist is the result of severe intramolecular repulsions between the cyclohexyl groups of the two P2Ni units.
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  • 25
    Publication Date: 2020-02-12
    Description: Das Gebiet südlich und östlich der Ostsee weist eine sehr geringe Bebenaktivität auf. Jedoch ist diese nicht vernachlässigbar klein, wie anhand der vier jüngsten Beben gezeigt wird, die Gegenstand dieser Untersuchung sind: in Mecklenburg-Vorpommern nahe Wittenburg, am 19. Mai 2000, Mw = 3,1 und Rostock am 21. Juli 2001, Mw = 3,4 sowie im Gebiet Kaliningrad (Russland) am 21. September 2004 zwei Beben mit Mw = 4,6 und 4,7. Lokalisierungen, Magnituden (ML und Mw und Herdflächenlösungen wurden für die ersten beiden genannten Beben berechnet. Für die Kaliningrad-Beben konnte die Herdtiefe mittels synthetischer Modellierungen bestimmt werden. Die Analyse der makroseismischen Beobachtungen zu den genannten Beben beruht auf der Anwendung einer neu entwickelten Inversionstechnik, die simultan die Lokalisierung sowie die Bestimmung der Herdtiefe und der Epizentralintensität erlaubt. Die anhand der Herdflächenlösungen erhaltenen Orientierungen der maximalen horizontalen Kompressionsspannungen sind in sehr guter Übereinstimmung mit dem bekannten regional unterschiedlich orientierten krustalen Spannungsfeld; d.h. maximale horizontale N-S Kompressionsspannung für das Wittenburg- und das Rostock-Beben und NNW-SSE für die Kaliningrad-Ereignisse. Mögliche Bruchstörungen, die ursächlich mit dem Beben in Verbindung stehen könnten, werden diskutiert. Es wird gezeigt, dass die jüngsten Beben zu keinen signifikanten Änderungen der Magnituden-Häufigkeitsverteilungen führen.
    Keywords: 550 - Earth sciences
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    Publication Date: 2020-02-12
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  • 27
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 438 (1978), S. 169-175 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Difluorophosphates of Tin (IV) and Antimony(V)Preparation and properties of SnCl2(PO2F2)2 (l), Cl4Sb(O2PF2) (2) and F4Sb(O2PF2) (3) are described. According to their vibrational spectra the structures are assumed. 31P-nmr spectra of 2 and 3 are given. 1 is characterised additional by its 119Sn-Mössbauer spectrum.
    Notes: Darstellung und Eigenschaften von SnCl2(PO2F2)2 (1), SbCl4(PO2F2) (2) und F4Sb(O2PF2) (3) werden beschrieben. Aus den Schwingungsspektren werden Strukturvorschläge abgeleitet. 31P-KMR-Spektren werden für 2 und 3 mitgeteilt, 1 wird zusätzlich durch das 119Sn-Mößbauer-Spektrum charakterisiert.
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  • 28
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    In:  International Journal of Climate Change Strategies and Management
    Publication Date: 2020-02-12
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    Publication Date: 2020-02-12
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  • 30
    Publication Date: 2024-01-29
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 31
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 32
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 115 (1982), S. 414-426 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Element-Organic Amine/Imine Compounds, XXII. λ3-Phosphazene Complexes of Zerovalent PlatinumThe reaction of Pt(COD)2 (COD = 1,5-cyclooctadiene) with the λ3-phosphazene RR'N—P=NR, R = (CH3)3C, R' = (CH3)3Si(1), gives the platinum(0) complex PtL3 (2) (L = λ3-phosphazene 1) whose structure has been elucidated by an X-ray analysis. 2 is used for the synthesis of the platinum(0) compounds PtL2L' (L' = R3M, M = P→b) (3) and PtLL2' (L' = R3P) (4).
    Notes: Die Umsetzung von Pt(COD)2 (COD = 1,5-Cyclooctadien) mit dem λ3-Phosphazen RR'N—P=NR, R = (CH3)3C, R' = (CH3)3Si(1), ergibt den Platin(0)-Komplex PtL3 (2) (L = λ3-Phosphazen 1), von dem eine Röntgenstrukturanalyse angefertigt wurde. Die Synthese der Platin(0)-Verbindungen PtL2L' (L' = R3M, M = P→b) (3) und PtLL2′ (L' = R3P) (4) erfolgte aus 2.
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  • 33
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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    Publication Date: 2020-02-12
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  • 35
    Publication Date: 2020-02-12
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    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 37
    Publication Date: 2022-02-18
    Description: Auf dem Weg in eine Ressourcenleichte Gesellschaft benötigen die betroffenen Akteurinnen und Akteure Leitbilder, an denen sie einen massiven Wandel wie diesen orientieren können. Der vorliegende Band stellt fünf solcher Leitbilder dar. Sie waren Hauptbestandteil des Projekts "Erfolgsbedingungen für Systemsprünge und Leitbilder einer ressourcenleichten Gesellschaft" und wurden mithilfe der Szenario -Methode erstellt. Inhaltlich wurden sie von Pionierinnen und Pionieren sowie Expertinnen und Experten ressourcenleichten Lebens erarbeitet, so dass alltagsnahe, praxistaugliche Elemente für die Leitbilder entwickelt wurden. Die Leitbilder zeigen eine große Spannbreite von Möglichkeiten, einen massiven gesellschaftlichen Wandel, wie er für eine Ressourcenleichte Gesellschaft nötig wäre, zu erreichen. Entsprechend unterschiedlich sind auch die möglichen Ressourcenschonungseffekte. Diese werden abschließend dargestellt und miteinander verglichen.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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    Publication Date: 2020-02-12
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    Publication Date: 2020-02-12
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    Publication Date: 2022-02-18
    Keywords: ddc:300
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  • 41
    Publication Date: 2020-02-12
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 43
    Publication Date: 2020-02-12
    Description: Since its first application on Sumatra-Andaman earthquake, back-projection analysis has been widely exploited to infer the time-evolution of the rupture fronts of mega-earthquakes. In this technique, selected seismic phases recorded at teleseismic distances by a network of sensors are shifted according to a possible source position and a velocity model, and a multichannel version of the cross-correlation function is estimated. In this way, the time dependent map of the seismic energy emission in the source area can be inferred. We have back-projected the mainshock of Maule earthquake (Mw 8.8), which nucleated on 27/02/2010 in central Chile and is one of the largest earthquakes recorded in modern times. We have analyzed P phases filtered in the frequency range (0.4-3) Hz recorded by three seismic arrays located in US, Africa and Antarctica. Relative time shifts between sensors (inferred by maximizing the cross-correlation function) have been estimated with respect to a 1D global velocity model (ak135) and have been refined introducing two corrections, a static correction anda dynamic correction. The former is the time shift induced by local effects in the sensor area, whereas the latter is the correction associated with the source-sensor path and is mostly affected by medium properties in the source area. We have inferred these two corrections by analyzing the waveforms of 23 aftershocks and foreshocks with high magnitude (〉5.3). In detail, static correction was chosen as the mean time shift averaged over all the events recorded by one station, while dynamic correction was the remaining part of the travel time after removing the 1Dmodel travel time and the static correction. Moreover, dynamic corrections (and hence the complete travel times)have been interpolated over all the source area by Kriging, a spatial interpolation method. Results show that high-frequency seismic energy emission mostly occurs along the coastline with a general northward migration during the event. Specifically, in the first minute of the rupture process, the energy emission occurs southerly from or close to the epicenter. Afterwards, seismic emission moves northwards, with a gap with respect to the first emission zone, and a further northward migration occurs till the end of emission. Both the spatial gap of seismic emission and the northward migration are in line with the results of other studies in the same area, whereas we find a shallower emission area and different emission features in the zone close to the epicenter. Results for different frequency bands and the analysis of secondary maxima of energy emission are being investigated. In particular, we are shifting towards higher frequencies looking at the frequency bands (1-4) Hz and (2-8) Hz. The former band displays an emission pattern similar to that of (0.4-3) Hz, but with a sharper gap of about 50 Km; the latter band hows coherent arrivals only during the first 80 s, with a clear energy emission south of the epicenter at the onset of the event and preserving the northward migration afterwards.
    Keywords: 550 - Earth sciences
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  • 44
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 45
    Publication Date: 2020-02-12
    Description: Temperature is one of the main parameters influencing the properties of CO2 during storage in saline aquifers since it along with pressure and co-constituents controls the phase behavior of the CO2/brine mixture. When the CO2 replaces brine as a free gas it is well known to affect the elastic properties of porous media considerably. In order to track the migration of geologically stored CO2 at the Ketzin site, 3D time-lapse seismic data were acquired by means of a baseline (pre-injection) survey in autumn 2005 and a first monitor survey in autumn 2009. During this period the temperature in the storage reservoir near the injection well was observed to have increased from 34 °C to 38 °C. This temperature increase led us to investigate the potential impact of temperature on the seismic response to the CO2 injection and on the CO2 mass estimations based on the Ketzin 4D seismic data. Two temperature scenarios in the reservoir (34 °C and 38 °C) were studied using multiphase fluid flow modeling. The simulations show that the impact of temperature on the seismic response is minor, but that the impact of the temperature on the CO2 mass estimations is significant and can, with the help of the multiphase fluid flow simulations, be explained mostly by the impact on the density of the CO2.
    Keywords: 550 - Earth sciences
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  • 46
    Publication Date: 2020-02-12
    Description: It has recently been shown that correlations of seismic noise can contain significant information about the Green's function along the station profile. Using an array of 38 temporary broad-band stations located in Finland between 1998 September and 1999 March, we study the resulting 703 noise correlations to understand how they are influenced by the directivity of the noise field. The latter information is obtained through f-k analysis of data from two permanent seismic arrays in Germany and Norway and from a subset of stations of the array in Finland. Both types of analysis confirm that the characteristic of the seismic noise is strongly frequency-dependent. At low frequencies (0.02-0.04 Hz), we observe diffuse noise and/or randomly distributed sources. In contrast, the noise is strongly direction-dependent and not fully diffuse in the intermediate period ranges (0.04-0.25 Hz) which correspond to the first and second micro seismic peak, created at the Irish and Scottish coast and the western coast of Norway In this frequency interval the noise is sufficiently close to a plane wave to introduce systematic errors in group velocities for station pairs which are not parallel to the direction of the dominant incident noise. Phase velocities calculated by slant stack over many traces are however correct, independently of profile direction. In the high-frequency band (0.25-1.0 Hz), the situation is a mix between the low-frequency and the intermediate frequency cases. Average phase velocities and individual group velocities from well-oriented profiles are in excellent agreement with results from Rayleigh wave studies of the area.
    Keywords: 550 - Earth sciences
    Language: English
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  • 47
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    In:  Publikationen der Deutschen Gesellschaft für Photogrammetrie, Fernerkundung und Geoinformation e.V. ; Bd. 21
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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    Publication Date: 2020-02-12
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    In:  Georessource Wasser - Herausforderung Globaler Wandel | Acatech-Studie
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 50
    Publication Date: 2022-02-18
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 51
    Publication Date: 2023-08-25
    Keywords: 550 - Earth sciences
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-11-10
    Description: Im Zentrum dieser Untersuchung steht die Aufbereitung der Erfahrungen mit den Elektrofahrzeugen in Einzelprojekten der Modellregionen Phase I hinsichtlich der energiebezogenen Parameter und der nach Fahrzeugsegmenten differenzierte Vergleich mit herkömmlichen Fahrzeugen. In der Literatur finden sich für die Klimabilanz von Elektrofahrzeugen unterschiedliche Bewertungsmethoden, deren Ergebnisse kurzfristig stark streuen und sich erst mittel- bis längerfristig perspektivisch annähern. In der vorliegenden Untersuchung werden drei Varianten zur Bilanzierung der klimarelevanten Emissionen gerechnet: a) Werden Elektrofahrzeuge mit Strom aus erneuerbaren Energien betrieben, ist ihre Klimabilanz deutlich besser als diejenige fossil betriebener Pkw. Wann, inwieweit und unter welchen Voraussetzungen (Herkunftsnachweis) eine direkte Zuordnung des Fahrstroms zu einer Stromerzeugung aus erneuerbaren Energien möglich ist, ist heute allerdings umstritten. b) Unter pragmatischen Gesichtspunkten bietet die Strommixmethode eine gute Orientierung für die klimabezogene Bewertung von Elektrofahrzeugen. Aufgrund der auf der Zeitachse planungsgemäß zunehmenden Anteile erneuerbarer Energien im Strommix führt dies für die Zeiten, in denen eine signifikante Durchdringung mit Elektrofahrzeugen zu erwarten ist, zu einer gegenüber heute deutlichen Verbesserung der spezifischen CO2-Emissionen und respektive Vorteilen gegenüber mit fossilen Kraftstoffen betriebenen Fahrzeugen. c) Legt man dem Kraftwerkseinsatz Merit Order als Regel des ökonomischen Betriebs zugrunde und betrachtet den Stromverbrauch von Elektrofahrzeugen als "zusätzlichen" Verbrauch gegenüber einem Zustand ohne Elektrofahrzeuge, stellt sich die Klimabilanz nicht so günstig dar.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 53
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organic Syntheses by Means of Transition Metal Complexes, 8 - Synthesis of Unsaturated δ-L-Lactones from Vinyloxiranes and Carbon Monoxide via Transition Metal ComplexesThe transition metal-assisted carbonylation of vinyloxiranes to unsaturated δ-lactones has been verified and studied mechanistically by use of organometallic model reactions. The light induced complexation of vinyloxiranes 1 by Fe(CO)5 was shown to be a multistep reaction in which diastereomeric cis-resp. trans- ferralactones 2 are formed. Complexes of both types (2k, 2k′) were characterized crystallographically and studied chemically concerning their reactions with nucleophiles and electrophiles. Reaction with primary amines gives ferralactames 7 by migration of the allyl group and inversion at C-1 as well as C-4 indicating an attack of amine at the exo-position of C-4. On the other hand the reaction with HO⊖ leads to the formation of CO23⊝ and diene complexes 10 with inversion at C-1 only, indicating that the reaction has been initiated by attack of HO⊖ at a terminal carbonyl group. On electrophilic attack ferralactones form allyl cations (14, 16) by opening of the CO - O bond. Carbonylation of ferralactones with CO in aprotic solvents give good yields of unsaturated δ-lactones (12). In the case of isoprene epoxide it has been shown that homogeneous catalytic cyclocarbonylation of vinyloxiranes can be of synthetic use.
    Notes: Anhand metallorganischer Modellreaktionen wurde die Cyclocarbonylierung von Vinyloxiranen zu ungesättigten δ-Lactonen untersucht. Die photochemisch initiierte Komplexierung von Vinyloxiranen 1 (X = O) an Fe(CO)5 verläuft mehrstufig und führt zu diastereomeren cis- bzw. trans-Ferralactonen 2. Vertreter beider Verbindungstypen (2k, 2 k′) wurden kristallographisch charakterisiert und chemisch bezüglich ihres Verhaltens gegenüber Nucleophilen und Elektrophilen studiert. Mit primären Aminen bilden sich Ferralactame 7 unter Wanderung des Allylsystems sowie unter Konfigurationsumkehr an C-1 und C-4, was den exo-Angriff des Amins an C-4 des Allylsystems beweist. Bei Einwirkung von HO⊝ hingegen zerfallen Ferralactone zu CO23⊝ und Dien-komplexen 10, wobei lediglich an C-1 eine Konfigurationsumkehr beobachtet wird. In diesem Fall greift HO⊝ somit an einer terminalen Carbonylgruppe an. Elektrophile bewirken die Spaltung der CO-O-Bindung unter Bildung von Allyl-Kationen (14, 16). Die Carbonylierung von Ferralactonen führt in aprotischen Lösungsmitteln in guten Ausbeuten zu ungesättigten S-Lactonen (12). Am Isoprenepoxid wurde gezeigt, daß auch die homogenkatalytische Cyclocarbonylierung von Vinyloxiranen gute Ausbeuten an δ-Lactonen ergibt und dieses Verfahren für Synthesen von Interesse ist.
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  • 54
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 120 (1987), S. 1987-2002 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organyl Complexes of (η-Cyclopentadienyl)(triorganophosphane)ironA series of organyliron complexes of the type Cp(L)2Fe—R (Cp = C5H5, C5H4Me, C5Me5; L = PhnMe3-nP, n = 0-3) (R = Me, Et, Bu, Ph, CH2CH2Ph, CH=CH2) have been prepared either from the corresponding iron chlorides (1-7) and organomagnesium compounds or from Cp(COD)FeLi (8, 9), organic halide, and phosphane. The thermal stability of the ethyliron complexes 17-24 towards β-H elimination (to give the (η2-ethylene)iron hydrides 37-39 or the Cp(L)2FeH compounds 40-48) increases with the basicity of the phosphane ligand and decreases with increasing methyl-substitution of the Cp ligand. The vinyliron compounds 29-32, 54 and 55 react with ethylene with insertion into the vinyl-Fe bond to give the (η3-crotyl)iron complexes 56-61 as the result of isomerization. The (η1, η2-alkenyl)iron compounds Cp(Me3P)Fe-[CH2]3-CH=CH2(Cp=C5H5 (62), C5Me5 (63) and (C5Me5)(Me3P)Fe-o-C6H4CH2CH=CH2 (67) were isolated and are stable at 20°C.
    Notes: Es wurde eine Reihe von Organyleisen-Komplexen des Types Cp(L)2Fe—R (Cp = C5H5, C5H4Me, C5Me5; L = PhnMe3-nP, n = 0-3) (R = Me, Et, Bu, Ph, CH2CH2Ph, CH=CH2) teilweise über die entsprechenden Eisenchloride (1-7) und Organomagnesium-Verbindungen, zum anderen Teil aus Cp(COD)FeLi (8, 9), Organohalogenid und Phosphan dargestellt. Die thermische Stabilität der Ethyleisen-Komplexe 17-24 gegenüber ß-H-Eliminierung zu den (η2-Ethylen)eisenhydriden 37-39 bzw. den Verbindungen Cp(L)2FeH (40-48) nimmt mit der Basizität des Phosphanliganden zu, jedoch mit zunehmender Methylsubstitution am Cp-Liganden ab. Die Vinyleisenverbindugen 29-32, 54, 55 reagieren mit Ethylen unter Insertion in die Vinyl-Fe-Bindung. Nach Isomerisierung entstehen die (η3-Crotyl)eisen-Komplexe 56-61. Als bei 20°C stabile (η1, η2-Alkenyl)eisen-Verbindungen wurden Cp(Me3P)Fe-[CH2]3-CH =CH2(Cp=C5H5 (62), C5Me5 (63) und (c5Me5)(ME3P)Fe-oC6H4CH2=CH2 (67) isoliert.
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  • 55
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    In:  Natural Hazards and Earth System Sciences (NHESS)
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 56
    Publication Date: 2020-02-12
    Description: The pilot study at the Ketzin site close to Berlin (Germany) aims at in-situ testing of geological storage of CO2 in a saline aquifer. Following site characterization and the drilling of one injection well and two observation wells, the in-situ field laboratory has been fully in use since CO2 injection started in June 2008. After two years of operation, about 36,000 tons of CO2 have been injected. This paper presents the key results from the second year of injection and the interdisciplinary monitoring concept in the frame of the European project CO2SINK (CO2 Storage by Injection into a Natural Saline Aquifer at Ketzin) and accompanying projects.
    Keywords: 550 - Earth sciences
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  • 57
    Publication Date: 2020-02-12
    Description: Within a few years after the German reunification, most open pit lignite mines in the Central German Lignite Mining District have been shut down leaving more than 200km2 of devastated land in Saxony (Germany) even now. These areas are in demand of short term conceptions for future landuse and suitable recultivation methods. This thesis investigates, how thermal infrared (TIR) remote sensing in particular can provide valuable information, which is required to assist the landuse planning in identifying and classifying critical areas. In order to establish the mining of the lignitic seams the overburden Quatemary and Tertiary sediments had been removed and dumped in conveyor bridge dumps. The Tertiary sediments contain the mineral pyrite, which reacts to sulfuric acid under wet oxidizing conditions. The acidification of the dumps is not only strongly affecting the chemical characteristics of groundwater and residual lakes but also the stability of slopes leaving the risk of slides and subsidences. For a risk assessment of the aff~cted areas the geochemical and mineralogical composition as well as compositional changes of the dumps have to be explored. This is giving strong motivation for the application of remote sensing methods to answer the short term demands of landuse planners. Hyperspectral scanner data were acquired over two open pits (Espenhain, Zwenkau). The used scanner is DLR's Digital Airbome Imaging Spectrometer (DAIS 7915) which records data in 79 bands from the visible to thermal infrared. To allow a quantitative approach by means of empirical methods, the airbome data had to undergo a number of correction procedures and accompanying ground truth measurements had to be carried out. For a quantitative analysis of the target area, the data were calibrated and atmospherically corrected. Atmospheric modeling is based on the software packages SENSAT and ATCOR using the MODTRAN code. Interna! distortions of the imagery were corrected from flight attitude information and the data were finally geocoded to Gauß-Krüger-coordinates. A total of 77 field sarnples were taken to develop quantification algorithms based on spectral characteristics. Chemical and mineralogical analyses (GFZ Potsdam) as well as thermal infrared laboratory spectrometry (2.5-14μm) were performed. The samples were found tobe mainly composed of quartz (50-90 weigth percent), alkaline feldspars (5-20 wt.% ), kaolinite (0-15 wt.%), illite (2-20 wt.%) and pyrite (0-4 wt.%). In the TIR, many rock-forming minerals (e.g. silicates) show characteristic spectral features. To investigate the influence of different grain sizes on the spectral behavior, the particulate material was ground to grain sizes 〈63μm. Both, the fine homogenized and the original dump sediments were measured. The mineralogical quantitative sarnple composition was correlated with the spectral features measured in the laboratory. Different approaches were investigated to quantify the rnineralogical composition including absorption band depths and spectral angle mapping (SAM). The analysis in the laboratory allowed a determination of kaolinite and quartz contents of the overburden dumps. By transferring the regressions obtained from laboratory spectroscopy to atmospherically corrected and calibrated DAIS 7915 data, quartz contents were successfully mapped. Due to the broad TIR bands of DAIS, the spectral features of kaolinite were not resolved in the airbome data. A temperature map derived from night-time DAIS thermal infrared data were evaluated with respect to exothermic pyrite oxidation, too. The fresh Tertiary dumps in Zwenkau show thermal anomalies which seem to be related to exothermic oxidation processes. As a final outlook, the potential of the ASTER sensor, which is planned to be launched in early 1999, was evaluated. The TIR bands of ASTER are likely tobe a powerful tool for the mapping of quartz contents of particulate material. However, the low geometric resolution in the thermal infrared (90m pixel size) causes limitations for a structural analysis. Therefore, the Multi-Sensor-Multi-Resolution Technique (MMT) was used to unmix the low resolution bands using the higher resolution reflective ASTER bands (15-30m pixel size). The results show a significant improvement of the images. The MMT algorithm allows a further spectral investigation of the unmixed TIR data. The results presented in this work show that remote sensing data can provide useful information for a quantitative assessment and monitoring of environmental impacts. The combined use of the wavelength region from the VIS to TIR produces characteristic features that allow a differentiation of the mineralogical components, which could not have been achieved with either data set separately.
    Keywords: 550 - Earth sciences
    Language: German
    Type: info:eu-repo/semantics/doctoralThesis
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  • 58
    Publication Date: 2022-02-18
    Description: Der Abschlussbericht mit den Ergebnissen der wissenschaftlichen Begleitforschung möchte darüber informieren, wie das Projekt entwickelt, initiiert, geplant und letztlich prozessual umgesetzt worden ist. Der erste Teil gibt insbesondere die im Prozess gewonnenen Erkenntnisse weiter und nennt erste Handlungsempfehlungen. Die darauffolgenden Kapitel bündeln die Ergebnisse der wissenschaftlichen Begleitforschung, welche zudem durch vier thematisch verschiedene Masterthesen im Untersuchungsraum ergänzt werden konnten. Zielgruppe für die erarbeiteten Handlungsempfehlungen sind all jene, die eine strategische Planung im Bereich des Ehrenamtes und des Klimaschutzes auf lokaler Ebene in den ländlichen Räumen (Südwestfalens) anstreben. Der Abschlussbericht mit seinen Erkenntnissen richtet sich an die Personen, Gruppen und Institutionen auf regionaler Ebene, die gemeinsam mit Partnern einen ganzheitlichen Klimaschutz im Ehrenamt zur räumlichen Entwicklung und Gestaltung systematisch vorantreiben wollen und dabei ähnliche Voraussetzungen und Strukturen aufweisen. Nicht zuletzt aber auch die, die von den gelebten Projekten und den gesammelten Erfahrungen lernen möchten. Daher sind folgende Zielgruppen insbesondere angesprochen: Dorfgemeinschaften, Vereine, Ehrenamtliche Gruppierungen (Bürgerstiftungen, Genossenschaften), LEADER-Arbeitsgruppen, Landkreise, Städte und Kommunen, Regionalmanager, Energie- und Umweltbeauftragte, Klimaschutzmanager, Unternehmen der Wertschöpfungsketten Energie- und Klima und viele mehr.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 59
    Publication Date: 2020-02-12
    Description: An automatic procedure is presented to retrieve rupture parameters for large earthquakes along the Sunda arc subduction zone. The method is based on standard array analysis and broadband seismograms registered within 30°–100° epicentral distance. No assumptions on source mechanism are required. By means of semblance the coherency of P waveforms is analysed at separate large-aperture arrays. Waveforms are migrated to a 10°×10° wide source region to study the spatio-temporal evolution of earthquakes at each array. The multiplication of the semblance source maps resulting at each array increases resolution. Start, duration, extent, direction, and propagation velocity are obtained and published within 25 min after the onset of the event. First preliminary results can be obtained even within 16 min. Their rapid determination may improve the mitigation of the earthquake and tsunami hazard. Real-time application will provide rupture parameters to the GITEWS project (German Indonesian Tsunami Early Warning System). The method is applied to the two M8.0 Sumatra earthquakes on 12 September 2007, to the M7.4 Java earthquake on 2 September 2009, and to major subduction earthquakes that have occurred along Sumatra and Java since 2000. Obtained rupture parameters are most robust for the largest earthquakes with magnitudes M≥8. The results indicate that almost the entire seismogenic part of the subduction zone off the coast of Sumatra has been ruptured. Only the great Sumatra event in 2004 and the M7.7 Java event on 17 July 2006 could reach to or close to the surface at the trench. Otherwise, the rupturing was apparently confined to depths below 25 km. Major seismic gaps seem to remain off the coast of Padang and the southern tip of Sumatra.
    Keywords: 550 - Earth sciences
    Language: English
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  • 60
    Publication Date: 2020-02-12
    Description: The Mw = 9.3 Sumatra earthquake of 26 December 2004 generated a tsunami that affected the entire Indian Ocean region and caused approximately 230 000 fatalities. In the response to this tragedy the German government funded the German Indonesian Tsunami Early Warning System (GITEWS) Project. The task of the GEOFON group of GFZ Potsdam was to develop and implement the seismological component. In this paper we describe the concept of the GITEWS earthquake monitoring system and report on its present status. The major challenge for earthquake monitoring within a tsunami warning system is to deliver rapid information about location, depth, size and possibly other source parameters. This is particularly true for coast lines adjacent to the potential source areas such as the Sunda trench where these parameters are required within a few minutes after the event in order to be able to warn the population before the potential tsunami hits the neighbouring coastal areas. Therefore, the key for a seismic monitoring system with short warning times adequate for Indonesia is a dense real-time seismic network across Indonesia with densifications close to the Sunda trench. A substantial number of supplementary stations in other Indian Ocean rim countries are added to strengthen the teleseismic monitoring capabilities. The installation of the new GITEWS seismic network – consisting of 31 combined broadband and strong motion stations – out of these 21 stations in Indonesia – is almost completed. The real-time data collection is using a private VSAT communication system with hubs in Jakarta and Vienna. In addition, all available seismic real-time data from the other seismic networks in Indonesia and other Indian Ocean rim countries are acquired also directly by VSAT or by Internet at the Indonesian Tsunami Warning Centre in Jakarta and the resulting "virtual" network of more than 230 stations can jointly be used for seismic data processing. The seismological processing software as part of the GITEWS tsunami control centre is an enhanced version of the widely used SeisComP software and the well established GEOFON earthquake information system operated at GFZ in Potsdam (http://geofon.gfz-potsdam.de/db/eqinfo.php). This recently developed software package (SeisComP3) is reliable, fast and can provide fully automatic earthquake location and magnitude estimates. It uses innovative visualization tools, offers the possibility for manual correction and re-calculation, flexible configuration, support for distributed processing and data and parameter exchange with external monitoring systems. SeisComP3 is not only used for tsunami warning in Indonesia but also in most other Tsunami Warning Centres in the Indian Ocean and Euro-Med regions and in many seismic services worldwide.
    Keywords: 550 - Earth sciences
    Language: English
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  • 61
    Publication Date: 2020-02-12
    Description: In this receiver function study, we investigate the structure of the crust beneath six seismic broadband stations close to the Sunda Arc formed by subduction of the Indo-Australian under the Sunda plate. We apply three different methods to analyse receiver functions at single stations. A recently developed algorithm determines absolute shear-wave velocities from observed frequency-dependent apparent incidence angles of P waves. Using waveform inversion of receiver functions and a modified Zhu and Kanamori algorithm, properties of discontinuities such as depth, velocity contrast, and sharpness are determined. The combination of the methods leads to robust results. The approach is validated by synthetic tests. Stations located on Malaysia show high-shear-wave velocities (V S) near the surface in the range of 3.4–3.6 km s − 1 attributed to crystalline rocks and 3.6–4.0 km s − 1 in the lower crust. Upper and lower crust are clearly separated, the Moho is found at normal depths of 30–34 km where it forms a sharp discontinuity at station KUM or a gradient at stations IPM and KOM. For stations close to the subduction zone (BSI, GSI and PSI) complexity within the crust is high. Near the surface low V S of 2.6–2.9 km s − 1 indicate sediment layers. High V S of 4.2 km s − 1 are found at depth greater than 6 and 2 km at BSI and PSI, respectively. There, the Moho is located at 37 and 40 km depth. At station GSI, situated closest to the trench, the subducting slab is imaged as a north-east dipping structure separated from the sediment layer by a 10 km wide gradient in V S between 10 and 20 km depth. Within the subducting slab V S ≈ 4.7 km s − 1. At station BSI, the subducting slab is found at depth between 90 and 110 km dipping 20° ± 8° in approximately N 60° E. A velocity increase in similar depth is indicated at station PSI, however no evidence for a dipping layer is found.
    Keywords: 550 - Earth sciences
    Language: English
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  • 62
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 63
    ISSN: 0009-2940
    Keywords: Nickel sandwich complex / Voltammetry, cyclic / Electrochemistry / Reductive dimerization / ESR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reduction of (Cyclobutadiene)(cyclopentadienyl)- and (1,5-Cyclooctadiene)(cyclopentadienyl)nickel CationsCyclic voltammetry of the four cationic Ni sandwich complexes [Ni(C5R5)(C4R4')]+ (2: R = H, R' = Ph; 3: R = H, R' = Me; 4; R = Me, R' = Ph; 5: R = R' = Me) shows reversible one-electron reductions for the phenyl derivatives 2 and 4 and a peak pattern characteristic of reductive dimerization/oxidative monomerization for the methyl derivatives 3 and 5. The product of the reduction of 3 was isolated and characterized analytically and by an X-ray structure determination as the dimer 6 of 3, linked through cyclobutenyl rings, the first example for a dimerization of an electron-rich sandwich complex at a substituted C atom. EPR spectra of the neutral complexes 2 and 4 are compared to those of (1,5-cyclooctadiene)(cyclopentadienyl)nickel (7) and are interpreted in terms of a substantial static Jahn-Teller distortion.
    Additional Material: 4 Ill.
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  • 64
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    In:  SPARC Newsletter ; Vol. 36
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 65
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    In:  CLEAN. CO2 Large-Scale Enhanced Gas Recovery in the Altmark Natural Gas Field | Geotechnologien science report ; 19 ; Advanced Technologies in Earth Sciences
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 66
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 67
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 68
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 69
    Publication Date: 2020-02-12
    Description: Important environmental parameters in arctic periglacial landscapes (i.e. permafrost temperature, activelayer depth, soil moisture, precipitation, vegetation cover) will very likely change in a warming climate. The thawing of permafrost, especially, might cause massive landscape changes due to thermokarst and an enhanced release of greenhouse gasses from the large amounts of carbon stored in frozen deposits, resulting in positive climate-warming feedback. For the identification, mapping, and quantification of such changes on various scales up to the entire circum-Arctic, remote sensing and spatial data analysis are essential tools. In this study an extensive field-work dataset including spectral surface properties, vegetation, soils, and geomorphology was acquired in the largest Arctic delta formed by a single river, the Siberian Lena River Delta. A portable field spectrometer (ASD FieldSpec Pro FR®) was used for spectral surveys of terrain surfaces, and optical satellite data (Landsat Enhanced Thematic Mapper (ETM+), CHRIS-Proba) were used for the characterization, manual mapping, and automatic classification of typical periglacial land-cover units in the Lena Delta. Qualitative data from soils, vegetation, soil moisture, and relief units were correlated with the field-spectral data and catalogued for a wide variety of surface types. The wide range of micro- and mesoscale variations of periglacial surface features in the delta results in distinctive spectral characteristics for different land-cover units. The three main delta terraces could also be spectrally separated and characterized. The present dataset provides a basis for further spectral data acquisitions in the Lena Delta and for comparisons with periglacial surfaces from other regions.
    Keywords: 550 - Earth sciences
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  • 70
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 71
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    München : Oekom-Verl. | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Description: Die ökologische Krise wird primär durch den zu hohen und weltweit steigenden Energie- und Ressourcenverbrauch verursacht. Das vorliegende Buch untersucht dessen Ursachen und Dynamik und forscht nach Möglichkeiten einer Eindämmung. Dabei zeigt sich, dass der Rückgriff auf Natur- und Ingenieurswissenschaften zur Bewältigung der ökologischen Krise nicht ausreicht. Um verstehen zu können, was menschliche Eingriffe in die Natur antreibt, ist auch die Kenntnis von sozial- und verhaltenswissenschaftlichen Zusammenhängen notwendig. In diesem Rahmen ist die Suffizienzstrategie, die auf Veränderung der Konsumstile zielt, von großer Bedeutung. Sie kann helfen, die negativen Einwirkungen auf die Umwelt in der erforderlichen Weise zu minimieren. Zugleich gilt sie jedoch vielen als unrealisierbar. Die dafür verantwortlichen Barrieren werden im Buch identifiziert und Strategien zu ihrer Überwindung gesucht.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: doctoralthesis , doc-type:doctoralThesis
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  • 72
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 531-539 
    ISSN: 0009-2940
    Keywords: 2,11-Diaza[3,3](2,6)pyridinophane ; N,N′-dimethyl- ; Tetraazamacrocyclic complexes ; cis-Octahedral coordination geometry ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The properties of the tetraazamacrocyclic compound N,N′-dimethyl-2,11-diaza[3,3](2,6)pyridinophane (L-N4Me2) as a ligand for some selected metal chlorides have been examined. The crystal structure of the uncoordinated ligand reveals a syn chair-chair conformation. In solution, the ligand displays fluctional behavior. Reaction of L-N4Me2 with the chlorides of copper(II), nickel(II), and cobalt(II) affords the complexes [Cu(L-N4Me2)Cl2] · H2O (3), [Ni(L-N4Me2)(H2O)Cl]Cl · H2O (4), and [Co(L-N4Me2)Cl2] · 2 H2O (5) in which the ligand adopts a syn boat-boat conformation. The crystal structures of 4 and 5 are presented. Due to the small cavity of the 12-membered ring of the ligand, exclusively distorted cis-octahedral coordination geometries are found at the metal sites. A comparison of structural data of several complexes with this ligand shows that the extent of the distortions from ideal octahedral geometry is mainly determined by the M-Npy bond strength. The electronic as well as the solution properties of the described complexes have been investigated by electronic absorption spectroscopy. ESR spectroscopy, and electrochemical methods.
    Additional Material: 6 Ill.
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  • 73
    Publication Date: 2022-02-18
    Description: Real-world laboratories are growing in popularity promising a contribution to both: the understanding and facilitation of societal transformation towards sustainability. Baden-Württemberg substantially funds real-world labs as part of the initiative "science for sustainability". To facilitate learning with and from these so-called BaWü-Labs, they are supported by accompanying research conducted by two teams. This article presents first insights and theses on real-world labs as a research format, based in particular on the work of the accompanying research team ForReal. The team supports the labs in their realization and in providing general insights, e.g. by learning from related international research approaches and dialog with international experts, and analyzes suitable quality features and methods (the latter together with the University of Basel team). The theses presented here put up for discussion first insights on real-world labs as a transformative research approach and reflect on them from a theoretical perspective. They illustrate the relevance of a goal-oriented use of methods and present learning processes as core characteristics of real-world labs. The theses were formulated based on discussions with the BaWü-Labs, exchange in international contexts as well as a thematic literature review.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 74
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    In:  Publikationen der Deutschen Gesellschaft für Photogrammetrie, Fernerkundung und Geoinformation e.V. ; Bd. 21
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 75
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 76
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    In:  Historical Earthquakes in Central Europe : Monographs Vol. 1 | Abhandlungen der Geologischen Bundesanstalt ; 48
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 77
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    In:  Scientific drilling : reports on deep earth sampling and monitoring
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 78
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    In:  Geophysical Journal International
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 79
    Publication Date: 2023-12-22
    Description: This Wuppertal Paper analyses the energy transition models of Colombia and Germany. The emphasis of the exercise is on an analysis of options for the complete decarbonization of the energy system in Colombia as a Global South country. To this end, it analyses the current situation, projections, public policy and narratives, and contrasts it with Germany as one of the countries of the Global North with which Colombia has historically maintained energy trade relations and is currently collaborating in the exploration of energy alternatives for decarbonization. Detailed analysis of sectoral energy consumption in Colombia shows the sectors with the highest fossil energy consumption (in this order): transport (fuels), industry (gas, coal), electricity generation (gas, coal) and residential (gas). We show the projected increase in demand for fuels and electricity, and calculate the amount of electricity theoretically needed to substitute fossil sources in each sector. We estimate the total electricity required for decarbonization via sector coupling and derive a first estimation of the range of additional renewable energy capacities needed to supply this demand. We find that required capacities are expectedly large (56-110 GW), depending on decarbonization pathways, and that export capacity beyond national demand may be limited. Our analysis of the policy and scenario arena in both countries finds that Colombia is still lacking both sector-specific decarbonization strategies and an embedding in a systemic vision of a systemic energy transition. Germany has more advanced sector strategies and (national) systemic visions, but lacks embedding assumptions on energy imports in a global-system analysis, i.e. in the analysis of an energy transition in potential exporting countries like Colombia. We formulate requirements to close these gaps in our conclusions.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 80
    Publication Date: 2020-02-12
    Description: The Erzincan strike-slip earthquake of March 13, 1992 ruptured a section of the North Anatolian fault (NAF) at the northern margin of the Erzincan basin. The focal depth of about 10 km was less than given by ISC and NEIC. Erzincan and the surrounding villages were considerably damaged. In the Erzincan basin and in the neighbouring mountains a seismic network of ten stations was installed. It was operating continuously from March 21 through June 16, 1992. More than 3,000 aftershocks were recorded of which 505 could be located. The spectral parameters of 394 and the fault-plane solutions of 53 aftershocks were determined. For the given region the frequency dependent coda Q was derived as Qc = 122*f^0.68. The aftershock area increased with time, reflecting the process of stress redistribution. Some events clustered in the immediate vicinity of the town of Erzincan close to the epicentre of the main event and seem to trace the NAF. Their source mechanism is similar to that of the main event (strike slip). About 150 aftershocks clustered in the southeastern part of the Erzincan basin where a concentration of the events in a small volume of 5 x 5 x 3 km^3 was observed. The majority of fault-plane solutions available for these aftershocks showed a normal faulting mechanism with an east-west directed extension. Most of the aftershocks southeast of the basin clustered between two lineaments that were mapped by satellite images. The P-wave velocity below the Erzincan basin, derived from travel-time residual analysis, is lower compared to areas NE and SW of the basin. Three-dimensional stress modelling of the Erzincan region qualitatively explains the occurrence of the aftershocks southeast of the basin. The calculated displacement distribution which exhibits the north-westward motion of the basin and tension at its southeastern margin, caused by the Erzincan earthquake, is in agreement with derived fault-plane solutions.
    Keywords: 550 - Earth sciences
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  • 81
    Publication Date: 2020-02-12
    Description: The Sumatran margin suffered three great earthquakes in recent years (Aceh-Andaman 26 December 2004 Mw = 9.1, Nias 28 March 2005 Mw = 8.7, Bengkulu 12 September 2007 Mw = 8.5). Here we present local earthquake data from a dense, amphibious local seismic network covering a segment of the Sumatran margin that last ruptured in 1797. The occurrence of forearc islands along this part of the Sumatran margin allows the deployment of seismic land-stations above the shallow part of the thrust fault. In combination with ocean bottom seismometers this station geometry provides high quality hypocentre location for the updip end of the seismogenic zone in an area where geodetic data are also available. In this region, the Investigator Fracture Zone (IFZ), which consists of 4 sub-ridges, is subducted below the Sunda plate. This topography appears to influence seismicity at all depth intervals. A well-defined linear streak of seismicity extending from 80 to 200 km depth lies along the prolongation of closely spaced IFZ sub-ridges. More intermediate depth seismicity is located to the southeast of this string of seismicity and is related to subducted rough oceanic seafloor. The plate interface beneath Siberut Island which ruptured last in 1797 is characterised by almost complete absence of seismicity.
    Keywords: 550 - Earth sciences
    Language: English
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  • 82
    Publication Date: 2023-10-09
    Description: Sustainable development is the 21st Century's wicked problem. After 40 years into this agenda have reversed only few unsustainable trends we hear the call for a paradigm shift, transformation, radical change or system innovations in order to finally change course. But what does this actually mean? And how do we put it into practice? This book describes the path ahead. It combines system transformation research with political economy and change leadership insights when discussing the need for a great mindshift in how human wellbeing, economic prosperity and healthy ecosystems are understood if the Great Transformations ahead are to lead to more sustainability. It shows that history is made by purposefully acting humans and introduces transformative literacy as a key skill in leading the radical incremental change strategies that wicked problems require, illustrating their nature through mapping pioneering practices and their commonalities.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Publication Date: 2020-02-12
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  • 84
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 85
    Publication Date: 2020-02-12
    Description: Rapid estimation of earthquake rupture propagation is essential to declare an early warning for tsunami-generating earthquakes. An increasing number of seismological methods have been developed to determine rupture parameters, such as length, velocity and propagation direction, especially since the occurrence of the Sumatra–Andaman earthquake that resulted in a devastating tsunami in the Indian Ocean region. Here, we present a new method to follow the rupture process in near real time by a polarization analysis of local and regional P phases that permits a faster determination of rupture properties than using teleseismic records. The new technique has the capability to provide detailed information in less than 10 min. Originally, the method stems from a single-station earthquake location method and is expanded here to monitor P-phase polarization variations through time. As the earthquake source moves away from the hypocentre, the backazimuth of an incoming P phase is expected to change accordingly. With polarization analysis we may be able to monitor the temporal change in Pwave backazimuth to follow the rupture process in near real time. Three component P phases are scanned to determine the azimuthal variation as a function of time. The backazimuth of a moving rupture front is determined by the first eigenvector of the covariance matrix. The linearity of the particle motion is used as a measure of the quality of the data. Seismic stations at local and regional distances (〉∼ 30◦) are used. We tested the new method with a theoretical simulation and observed seismograms of the Sumatra–Andaman earthquake (2004 December 26, Mw = 9.3), and we were able to follow the rupture for the first 200 s. For larger ruptures, stations at more than 30◦ epicentral distances would be required. The method is also successfully applied to the Wenchuan earthquake (2008 May 12, Mw = 8.0).
    Keywords: 550 - Earth sciences
    Language: English
    Type: info:eu-repo/semantics/article
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  • 86
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 54 (1907), S. 121-140 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die einzige Methode, um Kupfersuperoxyd CuO2.H2O zu erhalten, besteht in der Oxydation von fein verteiltem Kupferoxydhydrat durch Wasserstoffsuperoxyd (15-30%) in neutraler Lösung, wobei die Temperatur nahe dem 0-Punkte sein soll. Im feuchten Zustande zerfällt das Kupfersuperoxyd rasch unter Abgabe von Sauerstoff und Wasser, trocken geht dieser Zerfall nur langsam vor sich. Durch die Einwirkung von Chlor und Brom in alkalischer Lösung wird nur Kupferoxyd erhalten und sind die gegenteiligen Angaben von Krüger und Vitali unrichtig. Auch Persulfate bewirken in alkalischer Lösung keine Oxydation in Cuprisalzen. Durch Natriumsuperoxyd entsteht zwar Kupfersuperoxyd, doch tritt infolge der alkalischen Flüssigkeit ein außerordentlich rascher Zerfall desselben ein. Schliefslich ist die Beobachtung von W. Schmid unrichtig, der durch Behandlung von Cuprisulfat mit Mangansuperoxyd Kupfersuperoxyd erhalten haben will.
    Type of Medium: Electronic Resource
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  • 87
    Publication Date: 2023-06-12
    Description: Der Gebäudebereich steht nicht nur aufgrund seiner Umweltwirkungen vor großen Herausforderungen. Bei der Einhaltung der Klima- und Nachhaltigkeitsziele spielen auch die mit langen Lebens- und Nutzungsdauern von Gebäuden einhergehenden Investitionszyklen eine entscheidende Rolle. Politische und planerische Maßnahmen werden bislang hauptsächlich im Rahmen von Effizienz- und Konsistenzstrategien entwickelt und umgesetzt, um Umweltwirkungen zu minimieren. Die Suffizienzstrategie erfährt im Vergleich dazu eine deutlich geringere Aufmerksamkeit. Ziel dieses Vorhabens ist es deshalb, Suffizienz für den Gebäudebereich zu definieren, geeignete technische und organisatorische Ansätze zu ihrer Unterstützung zu identifizieren sowie Vorschläge zu ihrer Verankerung in politischen und rechtlichen Rahmenbedingungen und Instrumenten zu erarbeiten und exemplarisch darzustellen.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: report , doc-type:report
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  • 88
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Studies on the Reactivity of Metal π-Complexes, XXII. Sandwich-like Dinuclear (Pd-Pd)-Complexes with Bridging Cyclopentadienyl and Allyl LigandsThe reaction of C5H5Pd(2-RC3H4) (2-RC3H4 = 2-R-allyl) with tertiary phosphines or phosphites in the molar ratio of 1:1 produces in practically quantitative yields the dinuclear complexes (C5H5)(2-RC3H4)Pd2L2 (4-20) in which palladium has the oxidation state +1. The crystal structure analysis of 5 (R = CH3, L = P(C6H5)3) and 12 (R = CH3, L = P(OC6H4-o-CH3)3) shows that the cyclopentadienyl as well as the allyl ligand is bonded in a sandwich manner to the Pd-Pd unit. The Pd-Pd distance of 267.9 (in 5) or 268.9 pm (in 12) is suggestive of a metal-metal bond. It is not possible to determine whether the cyclopentadienyl ring in 4-20 exists as a pentahapto- or trihapto-bonded ligand on the basis of the 1H- and 13C n. m. r. data. The reactivity of the dinuclear complexes is in agreement with square planar coordination of the metal atoms.
    Notes: Bei den Reaktionen von C5H5Pd(2-RC3H4) (2-RC3H4 = 2-R-Allyl) mit tertiären Phosphinen oder Phosphiten im Molverhältnis 1:1 entstehen in praktisch quantitativer Ausbeute die Zweikernkomplexe (C5H5)(2-RC3H4)Pd2L2 (4-20), in denen Palladium in der Oxidationszahl +1 vorliegt. Wie die Kristallstrukturanalysen von 5 (R = CH3, L = P(C6H5)3) und 12 (R = CH3, L = P(OC6H4-o-CH3)3) zeigen, sind sowohl der Cyclopentadienyl- als auch der Allyl-Ligand sandwichartig an die Pd2-Einheit gebunden. Der Pd-Pd-Abstand von 267.9 (in 5) bzw. 268.9 pm (in 12) weist auf das Vorliegen einer Metall-Metall-Bindung hin. Aufgrund der 1H- und 13C-NMR-Daten ist nicht zu entscheiden, ob in 4-20 der Cyclopentadienylring als pentahapto-oder trihapto-gebundener Ligand vorliegt. Die Reaktivität der Zweikernkomplexe steht mit einer quadratisch-planaren Koordination der Metallatome in Einklang.
    Additional Material: 3 Ill.
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  • 89
    facet.materialart.
    Unknown
    München : Oekom Verlag
    Publication Date: 2023-10-09
    Description: Wie gestalten wir Wohlstand zukunftsfähig - obwohl es immer weniger Erwerbsarbeit für alle gibt? Wie müssen Wettbewerb und Kooperation zusammenwirken? Wie verbessern wir die Balance zwischen den Marktgütern und den marktfreien Gütern, die heute so stark gefährdet erscheint? Marktfreie Güter wie menschliche Zuwendung, selbstbestimmte Lebensführung, gesellschaftliche Integration und soziale Verantwortlichkeit sind nicht zu kaufen. Sie werden in Familie und Gruppe, in Nachbarschaft und bürgerschaftlichem Engagement hervorgebracht. Und sie sind nötiger denn je - zumal in den städtischen Räumen. Ausgehend von empirischen Untersuchungen, zeichnen die Autoren die Ansätze und Perspektiven einer Tätigkeitsgesellschaft, in der sich Erwerbs- und Subsistenzwirtschaft produktiv ergänzen.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: book , doc-type:book
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  • 90
    Publication Date: 2023-12-22
    Description: Um die Treibhausgasneutralität bis 2045 zu erreichen, wird unter anderem erforderlich sein, dass die Industrie klimaneutrale Produktionsweisen entwickelt und umsetzt. Damit einher gehen gesellschaftliche Aushandlungsprozesse darüber, welche neuen Technologien eingesetzt werden und welche Auswirkungen vor Ort akzeptiert werden. Das Ausmaß an Akzeptanz gegenüber Technologien oder Infrastrukturen beeinflusst neben anderen Faktoren die spezifische Ausgestaltung der Transformation. Mangelnde Akzeptanz kann die Entwicklung von Transformationspfaden verlangsamen oder gar verhindern, und zu Protesten, beispielsweise von lokalen Initiativen oder von etablierten Klimaschutz- und Umweltverbänden, führen. Dieses Wuppertal Paper stellt die Frage in den Fokus, welchen Einfluss Protestbewegungen auf öffentliche Akzeptanz haben bzw. haben könnten. Grundlage dafür sind empirische Ergebnisse aus dem Projekt Protanz.NRW zu Protesten und Akzeptanz im Kontext der Industrietransformation in NRW. Darauf aufbauend wird ein Protest-Akzeptanz-Modell entwickelt und es werden Hypothesen abgeleitet, wie unterschiedliche Protestgruppen die öffentliche Akzeptanz von Technologien für die Industrietransformation in NRW beeinflussen können. Abschließend werden Handlungsempfehlungen für Politik und Industrie abgeleitet sowie Forschungsbedarfe aufgezeigt.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: workingpaper , doc-type:workingPaper
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  • 91
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 275-297 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Lewis Acidity of Nickel(0), I. Methyllithium Complexes of Nickel(0)The synthesis and properties of the methyllithium complexes of nickel(0) of the type (n-Donor)m-(LiCH3)Ni0(π-Ligand)n (1a-c, 16a-c, 20a-c) [n-Donor = chelating amine or THF; π-Ligand = CDT, ethene, or CO] are described. The structure of (PMDTA)(LiCH3)Ni(C2H4)2 (1b) has been determined by X-ray crystallography.  -  In these ate complexes, a carbanionic methyl group is σ-bonded to a nickel atom, the acceptor strength of which depend on the π-ligands. The chemical and spectroscopic properties indicate that the Ni—CH3 bond in the carbonyl complex is largely covalent whereas in the CDT and ethene compounds it is more polar. The CDT complex is thermolabile in solution. The findings are in agreement with the following series of increasing acceptor strength: Ni(CDT) 〈 Ni(C2H4)2 〈 Ni(CO)3.
    Notes: Es wird über die Synthese und Eigenschaften der Methyllithium-Komplexe von Nickel(0) (n-Donor)m(LiCH3)Ni0(π-Ligand)n Wir bezeichnen mitπ-Liganden solche Liganden, die als π-Akzeptoren mit einem Übergangsmetallatom dπ—pπ—oder dπ—dπ-Rückbindungen auszubilden vermögen (Alkene, CO, auch Phosphane);n-Donoren solche Liganden, die als „harte Basen“ (Ether, Amine) über ihre freien Elektronenpaare vornehmlich Hauptgruppenmetall-Ionen, d.h. „harte Säuren“ komplexieren;σ-Donoren solche Liganden, die  -  ohne über Akzeptororbitale zu verfügen  -  entweder polare Bindungen enthalten und Mehrzentrenbindungen eingehen können (Metallalkyle und -hydride) oder ein freies Elektronenpaar bereitstellen (Carbanionen, Phosphorane, Hydrid-Ion), wobei σ-Bindungen zu einem niederwertigen Übergangsmetallatom ausgebildet werden. (1a-c, 16a-c, 20a-c) mit Chelataminen oder THF als n-Donoren und CDTAbkürzungen: CDT = trans,trans,trans-l,5,9-Cyclooctadien; COT = Cyclooctatetraen; PMDTA = Pentamethyldiethylentriamin; TMEDA = Tetramethylethylendiamin; MA+A = Alkalimetall- bzw. quartäres Ammonium-Kation., Ethen oder CO als π-Liganden berichtet. Die Struktur von (PMDTA)(LiCH3)Ni(C2H4)2 (1b) wurde röntgenographisch bestimmt.  -  In diesen at-Komplexen ist eine carbanionische Methylgruppe über eine σ-Bindung an ein Nickelatom gebunden, dessen Akzeptorstärke von den π-Liganden abhängt. Chemische und spektroskopische Eigenschaften der Komplexe lassen für CDT oder Ethen als π-Liganden auf vergleichsweise polare, für den CDT-Komplex in Lösung dazu thermolabile Ni—CH3-Bindungen schließen, während für den Carbonyl-Komplex aufgrund von 13C-NMR-Daten eine überwiegend kovalente Ni—CH3-Bindung anzunehmen ist. Die Befunde stehen mit folgender Reihe zunehmender Akzeptorstärke im Einklang: Ni(CDT) 〈 Ni(C2H4)2 〈 Ni(CO)3.
    Additional Material: 5 Ill.
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