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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 1517-1527 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An exact formula has been presented to correlate the bending curvature cariation ratio, Ω, of any given bilayer structure comprising a solvent-swellable polymer layer with diffusion time, t, under case II diffusion. The formula can be used to determine the diffusion front velocity, v, for layered structures comprising a thick polymer film on a thin substrate or vice versa when subjected to solvent diffusion. According to this formula, there is little effect from plasticization or swelling in the transverse direction on the diffusion curve of Ω vs. t if the polymer layer to be investigated is relatively thin and its intrinsic hygroscopic strain ratio is less than unity. By using this model, the diffusion of N-methyl pyrollidinone (NMP) in a 18-μm rodlike pyromellitic dianhydride p-phenylene-diamine (PMDA-PDA) polymide film, coated on a 75-μm silicon substrate, is found to be case II with a diffusion front velocity of 1.84 × 10-7 cm/s. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 2239-2246 
    ISSN: 0887-6266
    Keywords: vapor deposition polymerization ; polyimide ; surface topology ; characterization ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Vapor deposition polymerized (VDP) polyimide (PI) thin films were prepared and characterized by using thermogravimetrical analysis (TGA), scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared (FTIR), and bending-beam techniques. The film properties investigated were thermal stability, wet-etching characteristics, surface topology, imidization characteristics, internal stress upon curing and thermal cycling, and hygroscopic stress upon moisture diffusion. Markedly different characteristics are observed for the VDP-PI films when comparing with the conventional ones. They seem denser in film structure and have better mechanical properties, but are somewhat less stable in thermal resistance. © 1996 John Wiley & Sons, Inc.
    Additional Material: 12 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 953-954 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 511-520 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aqueous solutions of alkanolamines are commonly used to strip acid gases (CO2 H2S) from hydrocarbon streams. Processes for stripping acid gases from gaseous streams are well understood; however, the application to liquids is not as advanced. Experimental data available are scarce for systems containing aqueous amine solutions and the constituents of liquefied petroleum gases. To this end, new data are presented for the equilibria in the system propane-water-methyldiethanolamine (MDEA). A knowledge of the phase behavior in this system is required to model the equilibria encountered in the more complex systems of industrial importance.This work is a comprehensive study of the phase equilibria in the system propane-3 M MDEA, including vapor-liquid, liquid-liquid, and vapor-liquid-liquid equilibria. Experimental measurements were made for temperatures between 0 and 150°C and pressures up to 20 MPa. The data were correlated using the Stryjek-Vera modification of the Peng-Robinson equation of state. In addition, a composition-dependent mixing rule was required to fit the data adequately.
    Additional Material: 12 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 43 (1994), S. 64-68 
    ISSN: 0006-3592
    Keywords: enantioselectivity ; Naproxen ; esterification ; lipase ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Improvement of stereoselective resolution of racemic Naproxen, 2-(6-methoxy-2-naphthyl)propionic acid, was attempted with esterifcation reaction by Candida cylindracea lipase. By carefully selecting the organic medium, a 72-time enhancement of yield of the desired S-ester was achieved. The optimal reaction temperature was approximately 53°C, and an alcohol concentration between 20 mM and 40 mM in an 80% (v/v) isooctane and 20% (v/v) toluene mixture was found. © 1994 John Wiley & Sons, Inc.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 41 (1993), S. 603-611 
    ISSN: 0006-3592
    Keywords: dynamics of lipolytic enzymes ; modal analysis ; biphasic systems ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Through simple model analysis, the mass action kinetic model for lipolytic enzymes in biphasic aqueous-organic systems can be simplified using the quasi-steady state assumption (or the quasi-equilibrium state assumption) for the adsorbed enzyme E* or the enzyme-substrate complex E*S. Some parameter combinations leading to the above assumptions are derived confirmed by full numerical integration of the whole enzymatic process. The results may be classified into three categories: (1) the quasi-equilibrium state assumption for E*, (2) the quasi-steady state assumption for E*, and (3) the quasi-steady state assumption for E*S. Further simplification for both E* and E*S is also discussed. © 1993 Wiley & Sons, Inc.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 4 (1990), S. 191-195 
    ISSN: 0268-2605
    Keywords: Blackfoot disease ; Taiwan ; arsenic ; fluorescent humic substances ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Blackfoot disease is endemic in Chia Yi and Tainan Counties in south-western Taiwan. Arsenic present in the drinking water taken from wells has been blamed for causing this disease. The discovery in 1975 of fluorescent compounds in these well waters led to the isolation of these substances, to their identification as humic substances containing a large number of elements (among them arsenic), and to the development of an animal model for blackfoot disease. Mice receiving aqueous solutions of these fluorescent substances at a daily dose of 5 mg per 20 g body mass for at least 22 days developed blackfoot and blacktail disease. Work with these fluorescent substances, their chemical properties, and their biological actions is reviewed.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 5 (1991), S. 507-512 
    ISSN: 0268-2605
    Keywords: Blackfoot disease ; fluorescence intensity ; arsenic ; pH ; TDS ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The relationship between the four components, (1) fluorescence intensity, (2) arsenic concentration, (3) pH and (4) total dissolved solids, (TDS) measured in well waters from areas in Taiwan where blackfoot disease (BFD) is endemic was studied, as well as the relationships between the four degrees of BFD and each of the above four symptomatic components, in order to evaluate the etiological factors of BFD more progressively. The following 95% confidence intervals were obtained in well water samples (n = 1189): fluorescence intensity, 26.837-32.570; arsenic concentration, 0.103-0.127 mg dm-3; pH, 7.466-7.519; and TDS 733.063-801.647 mg dm-3. Fluorescence intensities of the four degrees of BFD were not all the same (F = 64.54, P 〈 0.001), and nor were arsenic concentrations (F = 72.03, P 〈 0.001), pH values (F = 7.30, P 〈 0.001), nor TDS values (F = 10.76, P 〈 0.001). In addition, multiple comparisons indicate that the higher the epidemical degree, the higher the fluorescence intensities, arsenic concentrations and pH values become; however, such a relationship is not found for TDS values. Moreover, the fluorescence intensities have positive linear correlations with arsenic concentrations (r = 0.49, P 〈 0.001), pH (r = 0.25, P 〈 0.001), and TDS (r = 0.18, P 〈 0.001), as do the arsenic concentrations with pH (r = 0.22, P 〈 0.001). Of the four epidemical degree groups, pairs are not significantly different from one another in correlation coefficients between fluorescence intensity and arsenic concentration, which implies a steady relationship between fluorescent compounds and arsenic. We conclude that fluorescent compounds in well water, as possible etiological factors of BFD, are closely related to arsenic along with pH and TDS values in the areas where BFD is endemic. In addition, we infer that a complex is formed by fluorescent compounds, arsenic and other metals.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 8 (1994), S. 223-228 
    ISSN: 0268-2605
    Keywords: Humic acids ; blackfoot disease ; thrombosis ; vasculopathy ; gangrene ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Adult male Wistar rats averaging 380 g in weight were injected with single doses (100 mg kg-1 body weight) of humic acids intraperitoneally. ‘Black tails’ were noticed 12 days later. In severely affected regions, thrombosis with mild to moderate acute necrotizing vasculitis was seen in most of the blood vessels located in the dermis, subcutaneous fat and muscle. These blood vessels were markedly dilated. Frequently, colonies of a shortrod bacterium of varying sizes were observed in necrotic tissues. There was mild to moderate edema and minimal accumulation of mast cells and macrophages in the dermis. Acute fat necrosis with fibrin deposition was also seen in the subcutaneous fat. Based on the pathological findings, we diagnosed that the tails of Wistar rats which had been injected with humic acids had severe multifocal thrombosis and mild to moderate, multifocal, acute necrotizing vasculitis with bacterial colonization, mild dermatitis, and fat necrosis. The relevance of these observations to the discussions on arsenic as an etiological factor of human Blackfoot disease is examined.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 109-125 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The diffusional process in the chlorination of sulfonated poly(styrene-co-divinylbenzene) bead was investigated through a general model as well as direct observation with electron microprobe. Two modes of diffusion, namely the pore diffusion and gelular permeation, were analyzed by two system parameters through a two-phase model. The effective pore and gelular diffusivities estimated from the x-ray energy-dispersive analysis data on the chlorine profile and the conversion suggest that, even for the same crosslinking, the diffusivity of chlorine in the gelular bead is larger by several orders of magnitude than that for the gelular microparticle in the macroreticular bead.
    Additional Material: 8 Ill.
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