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  • 1
    Publication Date: 2024-04-04
    Description: Second-generation anticoagulant rodenticides (SGARs) are widely used to control rodent populations, resulting in the serious secondary exposure of predators to these contaminants. In the United Kingdom (UK), professional use and purchase of SGARs were revised in the 2010s. Certain highly toxic SGARs have been authorized since then to be used outdoors around buildings as resistance-breaking chemicals under risk mitigation procedures. However, it is still uncertain whether and how these regulatory changes have influenced the secondary exposure of birds of prey to SGARs. Based on biomonitoring of the UK Common Buzzard (Buteo buteo) collected from 2001 to 2019, we assessed the temporal trend of exposure to SGARs and statistically determined potential turning points. The magnitude of difenacoum decreased over time with a seasonal fluctuation, while the magnitude and prevalence of more toxic brodifacoum, authorized to be used outdoors around buildings after the regulatory changes, increased. The summer of 2016 was statistically identified as a turning point for exposure to brodifacoum and summed SGARs that increased after this point. This time point coincided with the aforementioned regulatory changes. Our findings suggest a possible shift in SGAR use to brodifacoum from difenacoum over the decades, which may pose higher risks of impacts on wildlife.
    Keywords: apex predator ; conditional inference trees ; effectiveness evaluation ; regulatory changes ; seasonal fluctuation
    Repository Name: National Museum of Natural History, Netherlands
    Type: info:eu-repo/semantics/article
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  • 2
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science & Technology, American Chemical Society (ACS), 58(9), pp. 4302-4313, ISSN: 0013-936X
    Publication Date: 2024-03-28
    Description: The pollution of the marine environment with plastic debris is expected to increase, where ocean currents and winds cause their accumulation in convergence zones like the North Pacific Subtropical Gyre (NPSG). Surface-floating plastic (〉330 μm) was collected in the North Pacific Ocean between Vancouver (Canada) and Singapore using a neuston catamaran and identified by Fourier-transform infrared spectroscopy (FT-IR). Baseline concentrations of 41,600–102,700 items km–2 were found, dominated by polyethylene and polypropylene. Higher concentrations (factors 4–10) of plastic items occurred not only in the NPSG (452,800 items km–2) but also in a second area, the Papaha̅naumokua̅kea Marine National Monument (PMNM, 285,200 items km–2). This second maximum was neither reported previously nor predicted by the applied ocean current model. Visual observations of floating debris (〉5 cm; 8–2565 items km–2 and 34–4941 items km–2 including smaller “white bits”) yielded similar patterns of baseline pollution (34–3265 items km–2) and elevated concentrations of plastic debris in the NPSG (67–4941 items km–2) and the PMNM (295–3748 items km–2). These findings suggest that ocean currents are not the only factor provoking plastic debris accumulation in the ocean. Visual observations may be useful to increase our knowledge of large-scale (micro)plastic pollution in the global oceans.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 3
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), 58(10), pp. 4637-4647, ISSN: 0013-936X
    Publication Date: 2024-04-08
    Description: Marine dissolved organic matter (DOM) is an important component of the global carbon cycle, yet its intricate composition and the sea salt matrix pose major challenges for chemical analysis. We introduce a direct injection, reversed-phase liquid chromatography ultrahigh resolution mass spectrometry approach to analyze marine DOM without the need for solid-phase extraction. Effective separation of salt and DOM is achieved with a large chromatographic column and an extended isocratic aqueous step. Postcolumn dilution of the sample flow with buffer-free solvents and implementing a counter gradient reduced salt buildup in the ion source and resulted in excellent repeatability. With this method, over 5,500 unique molecular formulas were detected from just 5.5 nmol carbon in 100 μL of filtered Arctic Ocean seawater. We observed a highly linear detector response for variable sample carbon concentrations and a high robustness against the salt matrix. Compared to solid-phase extracted DOM, our direct injection method demonstrated superior sensitivity for heteroatom-containing DOM. The direct analysis of seawater offers fast and simple sample preparation and avoids fractionation introduced by extraction. The method facilitates studies in environments, where only minimal sample volume is available e.g. in marine sediment pore water, ice cores, or permafrost soil solution. The small volume requirement also supports higher spatial (e.g., in soils) or temporal sample resolution (e.g., in culture experiments). Chromatographic separation adds further chemical information to molecular formulas, enhancing our understanding of marine biogeochemistry, chemodiversity, and ecological processes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), ISSN: 0013-936X
    Publication Date: 2024-04-08
    Description: Marine permeable sediments are important sites for organic matter turnover in the coastal ocean. However, little is known about their role in trapping dissolved organic matter (DOM). Here, we examined DOM abundance and molecular compositions (9804 formulas identified) in subtidal permeable sediments along a near- to offshore gradient in the German North Sea. With the salinity increasing from 30.1 to 34.6 PSU, the DOM composition in bottom water shifts from relatively higher abundances of aromatic compounds to more highly unsaturated compounds. In the bulk sediment, DOM leached by ultrapure water (UPW) from the solid phase is 54 ± 20 times more abundant than DOM in porewater, with higher H/C ratios and a more terrigenous signature. With 0.5 M HCl, the amount of leached DOM (enriched in aromatic and oxygen-rich compounds) is doubled compared to UPW, mainly due to the dissolution of poorly crystalline Fe phases (e.g., ferrihydrite and Fe monosulfides). This suggests that poorly crystalline Fe phases promote DOM retention in permeable sediments, preferentially terrigenous, and aromatic fractions. Given the intense filtration of seawater through the permeable sediments, we posit that Fe can serve as an important intermediate storage for terrigenous organic matter and potentially accelerate organic matter burial in the coastal ocean.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 5
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science & Technology, American Chemical Society (ACS), 57(17), pp. 6799-6807, ISSN: 0013-936X
    Publication Date: 2023-08-16
    Description: Plastic pollution has become ubiquitous with very high quantities detected even in ecosystems as remote as arctic sea ice and deepsea sediments. Ice algae growing underneath sea ice are released upon melting and can form fast-sinking aggregates. In this pilot study, we sampled and analyzed the ice algaeMelosira arcticaand ambient sea water from three locations in the Fram Strait to assess their microplastic content and potential as a temporary sink and pathway to the deep seafloor. Analysis by μ-Raman and fluorescence microscopy detected microplastics (≥2.2 μm) in all samples at concentrations ranging from 1.3 to 5.7 × 104 microplastics (MP) m−3 in ice algae and from 1.4 to 4.5 × 103 MP m−3 in sea water, indicating magnitude higher concentrations in algae. On average, 94% of the total microplastic particles were identified as 10 μm or smaller in size and comprised 16 polymer types without a clear dominance. The high concentrations of microplastics found in our pilot study suggest thatM. arctica could trap microplastics from melting ice and ambient sea water. The algae appear to be a temporary sink and could act as a key vector to food webs near the sea surface and on the deep seafloor, to which its fast-sinking aggregates could facilitate an important mechanism of transport.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 6
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), 57(15), pp. 6033-6039, ISSN: 0013-936X
    Publication Date: 2024-04-17
    Description: Plastic pollution is an international environmental problem. Desire to act is shared from the public to policymakers, yet motivation and approaches are diverging. Public attention is directed to reducing plastic consumption, cleaning local environments, and engaging in citizen science initiatives. Policymakers and regulators are working on prevention and mitigation measures, while international, regional, and national bodies are defining monitoring recommendations. Research activities are focused on validating approaches to address goals and comparing methods. Policy and regulation are eager to act on plastic pollution, often asking questions researchers cannot answer with available methods. The purpose of monitoring will define which method is implemented. A clear and open dialogue between all actors is essential to facilitate communication on what is feasible with current methods, further research, and development needs. For example, some methods can already be used for international monitoring, yet limitations including target plastic types and sizes, sampling strategy, available infrastructure and analytical capacity, and harmonization of generated data remain. Time and resources to advance scientific understanding must be balanced against the need to answer pressing policy issues.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 7
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), 53(15), pp. 8747-8756, ISSN: 0013-936X
    Publication Date: 2024-04-12
    Description: Recent studies pointed to a high ice nucleating activity (INA) in the Arctic sea surface microlayer (SML). However, related chemical information is still sparse. In the present study, INA and free glucose concentrations were quantified in Arctic SML and bulk water samples from the marginal ice zone, the ice-free ocean, melt ponds, and open waters within the ice pack. T50 (defining INA) ranged from −17.4 to −26.8 °C. Glucose concentrations varied from 0.6 to 51 μg/L with highest values in the SML from the marginal ice zone and melt ponds (median 16.3 and 13.5 μg/L) and lower values in the SML from the ice pack and the ice-free ocean (median 3.9 and 4.0 μg/L). Enrichment factors between the SML and the bulk ranged from 0.4 to 17. A positive correlation was observed between free glucose concentration and INA in Arctic water samples (T50(°C) = (−25.6 ± 0.6) + (0.15 ± 0.04)·Glucose(μg/L), RP = 0.66, n = 74). Clustering water samples based on phytoplankton pigment composition resulted in robust but different correlations within the four clusters (RP between 0.67 and 0.96), indicating a strong link to phytoplankton-related processes. Since glucose did not show significant INA itself, free glucose may serve as a potential tracer for INA in Arctic water samples.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 8
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    American Chemical Society (ACS)
    In:  EPIC3Analytical Chemistry, American Chemical Society (ACS), 90(24), pp. 14188-14197, ISSN: 0003-2700
    Publication Date: 2024-04-09
    Description: Investigating the biogeochemistry of dissolved organic matter (DOM) requires the synthesis of data from several complementary analytical techniques. The traditional approach to data synthesis is to search for correlations between measurements made on the same sample using different instruments. In contrast, data fusion simultaneously decomposes data from multiple instruments into the underlying shared and unshared components. Here, Advanced Coupled Matrix and Tensor Factorization (ACMTF) was used to identify the molecular fingerprint of DOM fluorescence fractions in Arctic fjords. ACMTF explained 99.84% of the variability with six fully shared components. Individual molecular formulas were linked to multiple fluorescence components and vice versa. Molecular fingerprints differed in diversity and oceanographic patterns, suggesting a link to the biogeochemical sources and diagenetic state of DOM. The fingerprints obtained through ACMTF were more specific compared to traditional correlation analysis and yielded greater compositional insight. Multivariate data fusion aligns extremely complex, heterogeneous DOM data sets and thus facilitates a more holistic understanding of DOM biogeochemistry.
    Repository Name: EPIC Alfred Wegener Institut
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  • 9
    Publication Date: 2018-12-16
    Description: Journal of Chemical & Engineering Data DOI: 10.1021/acs.jced.8b00783
    Print ISSN: 0021-9568
    Electronic ISSN: 1520-5134
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 10
    Publication Date: 2018-03-06
    Description: Biochemistry DOI: 10.1021/acs.biochem.8b00106
    Print ISSN: 0006-2960
    Electronic ISSN: 1520-4995
    Topics: Biology , Chemistry and Pharmacology
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  • 11
    Publication Date: 2018-03-06
    Description: Biochemistry DOI: 10.1021/acs.biochem.7b01235
    Print ISSN: 0006-2960
    Electronic ISSN: 1520-4995
    Topics: Biology , Chemistry and Pharmacology
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  • 12
    Publication Date: 2018-03-06
    Description: Biochemistry DOI: 10.1021/acs.biochem.7b01271
    Print ISSN: 0006-2960
    Electronic ISSN: 1520-4995
    Topics: Biology , Chemistry and Pharmacology
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  • 13
    Publication Date: 2018-03-06
    Description: Biochemistry DOI: 10.1021/acs.biochem.7b00947
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  • 14
    Publication Date: 2018-03-06
    Description: Biochemistry DOI: 10.1021/acs.biochem.8b00179
    Print ISSN: 0006-2960
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  • 15
    Publication Date: 2018-03-06
    Description: Biochemistry DOI: 10.1021/acs.biochem.8b00135
    Print ISSN: 0006-2960
    Electronic ISSN: 1520-4995
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  • 16
    Publication Date: 2018-03-06
    Description: Biochemistry DOI: 10.1021/acs.biochem.8b00110
    Print ISSN: 0006-2960
    Electronic ISSN: 1520-4995
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  • 17
    Publication Date: 2018-03-06
    Description: Biochemistry DOI: 10.1021/acs.biochem.7b01293
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  • 18
    Publication Date: 2018-12-14
    Description: The Journal of Organic Chemistry DOI: 10.1021/acs.joc.8b02494
    Print ISSN: 0022-3263
    Electronic ISSN: 1520-6904
    Topics: Chemistry and Pharmacology
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  • 19
    Publication Date: 2018-12-14
    Description: Journal of the American Chemical Society DOI: 10.1021/jacs.8b10203
    Print ISSN: 0002-7863
    Electronic ISSN: 1520-5126
    Topics: Chemistry and Pharmacology
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  • 20
    Publication Date: 2018-12-14
    Description: Journal of the American Chemical Society DOI: 10.1021/jacs.8b10428
    Print ISSN: 0002-7863
    Electronic ISSN: 1520-5126
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  • 21
    Publication Date: 2018-12-14
    Description: Journal of the American Chemical Society DOI: 10.1021/jacs.8b11548
    Print ISSN: 0002-7863
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  • 22
    Publication Date: 2018-12-16
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.8b10492
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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  • 23
    Publication Date: 2018-02-06
    Description: Journal of Proteome Research DOI: 10.1021/acs.jproteome.7b00915
    Print ISSN: 1535-3893
    Electronic ISSN: 1535-3907
    Topics: Chemistry and Pharmacology
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  • 24
    Publication Date: 2018-02-06
    Description: Journal of the American Chemical Society DOI: 10.1021/jacs.7b12886
    Print ISSN: 0002-7863
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  • 25
    Publication Date: 2018-01-24
    Description: Organic Letters DOI: 10.1021/acs.orglett.7b03741
    Print ISSN: 1523-7060
    Electronic ISSN: 1523-7052
    Topics: Chemistry and Pharmacology
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  • 26
    Publication Date: 2018-02-06
    Description: Journal of Proteome Research DOI: 10.1021/acs.jproteome.7b00777
    Print ISSN: 1535-3893
    Electronic ISSN: 1535-3907
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  • 27
    Publication Date: 2018-02-06
    Description: Journal of the American Chemical Society DOI: 10.1021/jacs.7b12877
    Print ISSN: 0002-7863
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  • 28
    Publication Date: 2018-02-16
    Description: Journal of Chemical & Engineering Data DOI: 10.1021/acs.jced.7b00872
    Print ISSN: 0021-9568
    Electronic ISSN: 1520-5134
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 29
    Publication Date: 2018-02-16
    Description: Journal of Chemical Information and Modeling DOI: 10.1021/acs.jcim.7b00638
    Topics: Chemistry and Pharmacology
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  • 30
    Publication Date: 2018-02-16
    Description: Journal of Chemical Information and Modeling DOI: 10.1021/acs.jcim.7b00649
    Topics: Chemistry and Pharmacology
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  • 31
    Publication Date: 2018-02-16
    Description: The Journal of Organic Chemistry DOI: 10.1021/acs.joc.8b00043
    Print ISSN: 0022-3263
    Electronic ISSN: 1520-6904
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  • 32
    Publication Date: 2018-02-16
    Description: The Journal of Organic Chemistry DOI: 10.1021/acs.joc.7b03041
    Print ISSN: 0022-3263
    Electronic ISSN: 1520-6904
    Topics: Chemistry and Pharmacology
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  • 33
    Publication Date: 2018-02-16
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.7b12251
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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  • 34
    Publication Date: 2018-02-16
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.7b10849
    Electronic ISSN: 1520-5207
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  • 35
    Publication Date: 2018-02-16
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.7b12122
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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  • 36
    Publication Date: 2018-02-16
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.7b11889
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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  • 37
    Publication Date: 2018-02-16
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.7b10152
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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  • 38
    Publication Date: 2018-02-16
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.7b12243
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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  • 39
    Publication Date: 2018-01-02
    Description: Energies, Vol. 11, Pages 44: Transient Stability Analysis of Islanded AC Microgrids with a Significant Share of Virtual Synchronous Generators Energies doi: 10.3390/en11010044 Authors: Chang Yuan Peilin Xie Dan Yang Xiangning Xiao As an advanced control method that could bring extra inertia and damping characteristics to inverter-based distributed generators, the virtual synchronous generator (VSG) has recently drawn considerable attention. VSGs are expected to enhance the frequency regulation capability of the local power grid, especially the AC microgrid in island mode. However, the cost of that performance promotion is potential instability. In this paper, the unstable phenomena of the islanded microgrid dominated by SGs and distributed generators (DSs) are addressed after mathematical modeling and detailed eigenvalue analyses respectively. The influence of VSG key parameters, e.g., virtual inertia, damping factor, and droop coefficient on system stability is investigated, and the corresponding mathematical calculation method of unstable region is obtained. The theoretical analysis is well supported by time domain simulation results. The predicted frequency oscillation suggests the consideration of stability constrain during the VSG parameters design procedure.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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  • 40
    Publication Date: 2018-01-02
    Description: Energies, Vol. 11, Pages 77: Anisotropy in Thermal Recovery of Oil Shale—Part 1: Thermal Conductivity, Wave Velocity and Crack Propagation Energies doi: 10.3390/en11010077 Authors: Guoying Wang Dong Yang Zhiqin Kang Jing Zhao In this paper, the evolution of thermal conductivity, wave velocity and microscopic crack propagation both parallel and perpendicular to the bedding plane in anisotropic rock oil shale were studied at temperatures ranging from room temperature to 600 °C. The results show that the thermal conductivity of the perpendicular to bedding direction (KPER) (PER: perpendicular to beeding direction), wave velocity of perpendicular to bedding diretion (VPER), thermal conduction coefficient of parallel to beeding direction (KPAR) and wave velocity of parallel to beeding direction (VPAR) (PAR: parallel to bedding direction) decreased with the increase in temperature, but the rates are different. KPER and VPER linearly decreased with increasing temperature from room temperature to 350 °C, with an obvious decrease at 400 °C corresponding to a large number of cracks generated along the bedding direction. KPER, VPER, KPAR and VPAR generally maintained fixed values from 500 °C to 600 °C. 400 °C has been identified as the threshold temperature for anisotropic evolution of oil shale thermal physics. In addition, the relationship between the thermal conductivity and wave velocity based on the anisotropy of oil shale was fitted using linear regression. The research in this paper can provide reference for the efficient thermal recovery of oil shale, thermal recovery of heavy oil reservoirs and the thermodynamic engineering in other sedimentary rocks.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 41
    Publication Date: 2018-01-02
    Description: Energies, Vol. 11, Pages 64: Practical On-Board Measurement of Lithium Ion Battery Impedance Based on Distributed Voltage and Current Sampling Energies doi: 10.3390/en11010064 Authors: Xuezhe Wei Xueyuan Wang Haifeng Dai Battery impedance based state estimation methods receive extensive attention due to its close relation to internal dynamic processes and the mechanism of a battery. In order to provide impedance for a battery management system (BMS), a practical on-board impedance measuring method based on distributed signal sampling is proposed and implemented. Battery cell perturbing current and its response voltage for impedance calculation are sampled separately to be compatible with BMS. A digital dual-channel orthogonal lock-in amplifier is used to calculate the impedance. With the signal synchronization, the battery impedance is obtained and compensated. And the relative impedance can also be obtained without knowing the current. For verification, an impedance measuring system made up of electronic units sampling and processing signals and a DC-AC converter generating AC perturbing current is designed. A type of 8 Ah LiFePO4 battery is chosen and the valuable frequency range for state estimations is determined with a series of experiments. The battery cells are connected in series and the impedance is measured with the prototype. It is shown that the measurement error of the impedance modulus at 0.1 Hz–500 Hz at 5 °C–35 °C is less than 4.5% and the impedance phase error is less than 3% at <10 Hz at room temperature. In addition, the relative impedance can also be tracked well with the designed system.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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  • 42
    Publication Date: 2018-01-02
    Description: Energies, Vol. 11, Pages 80: Well Test Analysis for Fractured and Vuggy Carbonate Reservoirs of Well Drilling in Large Scale Cave Energies doi: 10.3390/en11010080 Authors: Cuiqiao Xing Hongjun Yin Kexin Liu Xingke Li Jing Fu A well test analysis model for fractured and vuggy carbonate reservoir of wells drilling in large scale cave considering wellbore storage and skin factor is established in this paper. The Laplace transformation and Stehfest numerical inversion are applied to obtain the results of wellbore pressure. Through the sensitivity analysis of different parameters for the well test typical curves, it is found that the change of the well test curves is in accordance with the theoretical analysis. With the increase of skin factor, the hump of well test typical curves is steeper. The storage ratio influences the depth and width of the concave in the pressure derivative curves. The cross flow coefficient mainly affects the position of the concave occurrence in the pressure derivative curves. The dimensionless reservoir radius mainly affects the middle and late stages of the log-log pressure type curves, and the later well test curves will be upturned for sealed boundary. The duration of the early stage of the log-log curves will become longer when drilling in large scale cave. The effective well radius is increased to a certain extent, which is in full agreement with the conclusions in this paper. The size of the caves has the same effect on the well test typical curves as wellbore storage coefficient. Due to acidification, fracturing, and other reasons, the boundary of the cave will collapse. Therefore, considering the wellbore storage coefficient and skin effect is very important during well testing. However, the existing models for well testing of fractured and vuggy carbonate reservoir often ignore the wellbore storage coefficient and skin effect. For fractured and vuggy carbonate reservoirs of well drilling in large scale cave, the existing models are not applicable. Since the previous models are mostly based on the triple-porosity medium and the equivalent continuum. The well test model for well drilling in large scale cave of fracture-cavity carbonate reservoirs with wellbore storage coefficient and skin factor in this work has significant application value for oil field.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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  • 43
    Publication Date: 2018-01-02
    Description: Energies, Vol. 11, Pages 32: High-Precision Speed Control Based on Multiple Phase-Shift Resonant Controllers for Gimbal System in MSCMG Energies doi: 10.3390/en11010032 Authors: Jian Feng Qing Wang Kun Liu The high precision speed control of gimbal servo system in magnetically suspended control moment gyro (MSCMG) suffers from periodic torque disturbances, which lead to periodic fluctuations in speed control. This paper proposes a novel multiple phase-shift resonant controller (MPRC) for a gimbal servo system to suppress the periodic torque ripples whose frequencies vary with the operational speed of the gimbal servo motor and high-speed motor. First, the periodic torque ripples caused by cogging torque, flux harmonics and the dynamic unbalance of the high speed rotor are analyzed. Second, the principle and structure of MPRC parallel with proportional integral (PI) controllers are discussed. The design and stability analysis of the proposed MPRC plus PI control scheme are given both for the current loop and speed loop. The closed-loop stability is ensured by adjusting the phase in the entire operational speed range. Finally, the effectiveness of the proposed control method is verified through simulation and experimental results.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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  • 44
    Publication Date: 2018-07-25
    Description: Remote Sensing, Vol. 10, Pages 1171: Multi-Criteria Evaluation of Snowpack Simulations in Complex Alpine Terrain Using Satellite and In Situ Observations Remote Sensing doi: 10.3390/rs10081171 Authors: Jesús Revuelto Grégoire Lecourt Matthieu Lafaysse Isabella Zin Luc Charrois Vincent Vionnet Marie Dumont Antoine Rabatel Delphine Six Thomas Condom Samuel Morin Alessandra Viani Pascal Sirguey This work presents an extensive evaluation of the Crocus snowpack model over a rugged and highly glacierized mountain catchment (Arve valley, Western Alps, France) from 1989 to 2015. The simulations were compared and evaluated using in-situ point snow depth measurements, in-situ seasonal and annual glacier surface mass balance, snow covered area evolution based on optical satellite imagery at 250 m resolution (MODIS sensor), and the annual equilibrium-line altitude of glaciers, derived from satellite images (Landsat, SPOT, and ASTER). The snowpack simulations were obtained using the Crocus snowpack model driven by the same, originally semi-distributed, meteorological forcing (SAFRAN) reanalysis using the native semi-distributed configuration, but also a fully distributed configuration. The semi-distributed approach addresses land surface simulations for discrete topographic classes characterized by elevation range, aspect, and slope. The distributed approach operates on a 250-m grid, enabling inclusion of terrain shadowing effects, based on the same original meteorological dataset. Despite the fact that the two simulations use the same snowpack model, being potentially subjected to same potential deviation from the parametrization of certain physical processes, the results showed that both approaches accurately reproduced the snowpack distribution over the study period. Slightly (although statistically significantly) better results were obtained by using the distributed approach. The evaluation of the snow cover area with MODIS sensor has shown, on average, a reduction of the Root Mean Squared Error (RMSE) from 15.2% with the semi-distributed approach to 12.6% with the distributed one. Similarly, surface glacier mass balance RMSE decreased from 1.475 m of water equivalent (W.E.) for the semi-distributed simulation to 1.375 m W.E. for the distribution. The improvement, observed with a much higher computational time, does not justify the recommendation of this approach for all applications; however, for simulations that require a precise representation of snowpack distribution, the distributed approach is suggested.
    Electronic ISSN: 2072-4292
    Topics: Architecture, Civil Engineering, Surveying , Geography
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  • 45
    Publication Date: 2018-07-25
    Description: Remote Sensing, Vol. 10, Pages 1169: Multi-Year Analyses of Columnar Aerosol Optical and Microphysical Properties in Xi’an, a Megacity in Northwestern China Remote Sensing doi: 10.3390/rs10081169 Authors: Xiaoli Su Junji Cao Zhengqiang Li Kaitao Li Hua Xu Suixin Liu Xuehua Fan A thorough understanding of aerosol optical properties and their spatio-temporal variability are required to accurately evaluate aerosol effects in the climate system. In this study, a multi-year study of aerosol optical and microphysical properties was firstly performed in Xi’an based on three years of sun photometer remote sensing measurements from 2012 to 2015. The multi-year average of aerosol optical depth (AOD) at 440 nm was about 0.88 ± 0.24 (mean ± SD), while the averaged Ångström Exponent (AE) between 440 and 870 nm was 1.02 ± 0.15. The mean value of single scattering albedo (SSA) was around 0.89 ± 0.03. Aerosol optical depth and AE showed different seasonal variation patterns. Aerosol optical depth was slightly higher in winter (0.99 ± 0.36) than in other seasons (~0.85 ± 0.20), while AE showed its minimum in spring (0.85 ± 0.05) due to the impact of dust episodes. The seasonal variations of volume particle size distribution, spectral refractive index, SSA, and asymmetry factor were also analyzed to characterize aerosols over this region. Based on the aerosol products derived from sun photometer measurements, the classification of aerosol types was also conducted using two different methods in this region. Results show that the dominant aerosol types are absorbers in all seasons, especially in winter, demonstrating the strong absorptivity of aerosols in Xi’an.
    Electronic ISSN: 2072-4292
    Topics: Architecture, Civil Engineering, Surveying , Geography
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  • 46
    Publication Date: 2018-07-25
    Description: Sustainability, Vol. 10, Pages 2593: Visual Analysis of the Height Ratio between Building and Background Vegetation. Two Rural Cases of Study: Spain and Sweden Sustainability doi: 10.3390/su10082593 Authors: Jacinto Garrido-Velarde María Jesús Montero-Parejo Julio Hernández-Blanco Lorenzo García-Moruno The perception of apparent sizes of buildings in a rural environment depends on the height ratio between the building and its surrounding vegetation, and it is this parameter which is currently used to assess the built landscapes. The impact of a contrasting height is less strong if the building does not exceed the horizon line. For buildings overshooting the skyline, the building’s level of sharpness and number of lines in contrast to the sky determines the impact of the scales, and vegetation in the background helps to reduce impact. The specific objectives of the present study were: (1) finding height–ratio thresholds between building and background vegetation, which may improve the integration of rural buildings in sky-sensitive locations, and; (2) comparing the results in two rural contexts with very different climatic conditions: Spain and Sweden. A survey of eighteen scenarios (nine Spanish and nine Swedish), all digitally modified with different relative height ratios between vegetation and buildings, was performed. The survey was evaluated by the public from both countries. Regardless of the country of origin, integration of the building was good or very good when the vegetation in background did not exceed one half of the height of the construction. These results may be translated to technical criteria for planning assessment.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 47
    Publication Date: 2018-07-25
    Description: Sensors, Vol. 18, Pages 2406: Adaptive Robust Unscented Kalman Filter via Fading Factor and Maximum Correntropy Criterion Sensors doi: 10.3390/s18082406 Authors: Zhihong Deng Lijian Yin Baoyu Huo Yuanqing Xia In most practical applications, the tracking process needs to update the data constantly. However, outliers may occur frequently in the process of sensors’ data collection and sending, which affects the performance of the system state estimate. In order to suppress the impact of observation outliers in the process of target tracking, a novel filtering algorithm, namely a robust adaptive unscented Kalman filter, is proposed. The cost function of the proposed filtering algorithm is derived based on fading factor and maximum correntropy criterion. In this paper, the derivations of cost function and fading factor are given in detail, which enables the proposed algorithm to be robust. Finally, the simulation results show that the presented algorithm has good performance, and it improves the robustness of a general unscented Kalman filter and solves the problem of outliers in system.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 48
    Publication Date: 2018-07-25
    Description: Sustainability, Vol. 10, Pages 2586: Conserving Tropical Forests: Can Sustainable Livelihoods Outperform Artisanal or Informal Mining? Sustainability doi: 10.3390/su10082586 Authors: Joshua Fisher Poonam Arora Sophia Rhee The viability of conservation efforts, including protected areas and buffer zones, depends on finding ways to make those strategies more attractive and viable for local populations. This paper presents a pilot study utilizing a rapid rural appraisal of livelihoods in the buffer zone of Tambopata National Reserve in Madre de Dios, Peru, threatened by illegal gold mining and logging. We evaluated three predominant economic activities—artisanal gold mining, Brazil nut harvesting, and fish farming—in terms of potential economic returns. The main research question we ask is whether the latter two potentially sustainable land uses can match or exceed the returns from mining. Contrary to popular belief, we find that enhancing value creation at product origin could make existing forest-friendly livelihoods as or more lucrative than extractive ones. This has implications on local conservation policy encouraging implementable strategies incentivizing sustainable livelihoods in tandem with, and in support of, conservation goals.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 49
    Publication Date: 2018-07-25
    Description: Water, Vol. 10, Pages 969: Assessment of Runoff Components Simulated by GLDAS against UNH–GRDC Dataset at Global and Hemispheric Scales Water doi: 10.3390/w10080969 Authors: Meizhao Lv Hui Lu Kun Yang Zhongfeng Xu Meixia Lv Xiaomeng Huang The current evaluations of global land data assimilation system (GLDAS) runoff were generally limited to the observation-rich areas. At the global and hemispheric scales, we assessed different runoff components performance of GLDAS (1.0 and 2.1) using the University of New Hampshire and Global Runoff Data Centre (UNH-GRDC) dataset. The results suggest that GLDAS simulations show considerable uncertainties, particularly in partition of surface and subsurface runoffs, in snowmelt runoff modeling, and in capturing the northern peak time. GLDAS1.0-CLM (common land model) produced more surface runoff almost globally; GLDAS-Noah generated more surface runoff over the northern middle-high latitudes and more subsurface runoff in the remaining areas; while the partition in GLDAS1.0-VIC (variable infiltration capacity) is almost opposite to that in Noah. Comparing to GLDAS1.0-Noah, GLDAS2.1-Noah improved the premature snow-melting tendency, but its snowmelt-runoff peak magnitude was excessively high in June and July. The discrepancies in northern primary peak times among precipitation and runoff is partly caused by the combination of rainfall and melting-snow over high-latitude, as well as the very different temporal–spatial distributions for snowmelt runoff simulated by GLDAS models. This paper can provide valuable guidance for GLDAS users, and contribute to the further improvement of hydrological parameterized schemes.
    Electronic ISSN: 2073-4441
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 50
    Publication Date: 2018-07-25
    Description: Remote Sensing, Vol. 10, Pages 1166: Inventory of Glaciers in the Shaksgam Valley of the Chinese Karakoram Mountains, 1970–2014 Remote Sensing doi: 10.3390/rs10081166 Authors: Haireti Alifu Yukiko Hirabayashi Brian Alan Johnson Jean-Francois Vuillaume Akihiko Kondoh Minoru Urai The Shaksgam Valley, located on the north side of the Karakoram Mountains of western China, is situated in the transition zone between the Indian monsoon system and dry arid climate zones. Previous studies have reported abnormal behaviors of the glaciers in this region compared to the global trend of glacier retreat, so the region is of special interest for glacier-climatological studies. For this purpose, long-term monitoring of glaciers in this region is necessary to obtain a better understanding of the relationships between glacier changes and local climate variations. However, accurate historical and up-to-date glacier inventory data for the region are currently unavailable. For this reason, this study conducted glacier inventories for the years 1970, 1980, 1990, 2000 and 2014 (i.e., a ~10-year interval) using multi-temporal remote sensing imagery. The remote sensing data used included Corona KH-4A/B (1965–1971), Hexagon KH-9 (1980), Landsat Thematic Mapper (TM) (1990/1993), Landsat Enhanced Thematic Mapper Plus (ETM+) (2000/2001), and Landsat Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS) (2014/2015) multispectral satellite images, as well as digital elevation models (DEMs) from the Shuttle Radar Topography Mission (SRTM), DEMs generated from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images (2005–2014), and Advanced Land Observing Satellite (ALOS) World 3D 30 m mesh (AW3D30). In the year 2014, a total of 173 glaciers (including 121 debris-free glaciers) (>0.5 km2), covering an area of 1478 ± 34 km2 (area of debris-free glaciers: 295 ± 7 km2) were mapped. The multi-temporal glacier inventory results indicated that total glacier area change between 1970–2014 was not significant. However, individual glacier changes showed significant variability. Comparisons of the changes in glacier terminus position indicated that 55 (32 debris-covered) glaciers experienced significant advances (~40–1400 m) between 1970–2014, and 74 (32 debris-covered) glaciers experienced significant advances (~40–1400 m) during the most recent period (2000–2014). Notably, small glaciers showed higher sensitivity to climate changes, and the glaciers located in the western part of the study site were exhibiting glacier area expansion compared to other parts of the Shaksgam Valley. Finally, regression analyses indicated that topographic parameters were not the main driver of glacier changes. On the contrary, local climate variability could explain the complex behavior of glaciers in this region.
    Electronic ISSN: 2072-4292
    Topics: Architecture, Civil Engineering, Surveying , Geography
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  • 51
    Publication Date: 2018-07-25
    Description: Sustainability, Vol. 10, Pages 2601: Researcher–Planner Dialogue on Environmental Justice and Its Knowledges—A Means to Encourage Social Learning Towards Sustainability Sustainability doi: 10.3390/su10082601 Authors: Aino Rekola Riikka Paloniemi Societies aiming for a sustainable future need more effective and legitimate planning and decision making practices, in which various actors together find pathways towards a sustainable transition. In this paper, we approach sustainability and environmental justice as epistemological (and ontological) challenges for land-use planning, and empirically analyse how action research could support planners’ social learning and planning towards fair and sustainable development. We analysed qualitatively the evolution of the researcher–planner dialogue while co-designing and developing better methods, means and practices to improve environmental justice in regional scale planning in Kymenlaakso Region, South-East Finland. We found that researcher-planner dialogue developed during cooperation. While in the beginning, social learning related to approaching environmental justice as a fair distribution of power evolved incrementally, later, when dialogue became more focused, communicative and reflective as an outcome of mutual frames and trust, learning occurred in a more transformative way. Such transformative learning concerned recognising youth as a silent group in the planning process and the means to involve their perceptions in planning. In order to support sustainability transformation in the future, we conclude that it is essential to create opportunities for such incremental and transformative social learning through innovative modes of interaction in various contexts.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 52
    Publication Date: 2018-07-25
    Description: Sustainability, Vol. 10, Pages 2602: Towards a Joint Local Energy Transition Process in Urban Districts: The GO2Zero Simulation Game Sustainability doi: 10.3390/su10082602 Authors: Geertje Bekebrede Ellen van Bueren Ivo Wenzler The depletion of fossil fuel sources for our energy system and the influence on overall CO2 emissions drive the need to more sustainable energy systems. The transition towards a renewable energy system cannot be seen as a purely technical issue; it is strongly embedded within society. In this study, we analyze the stakeholder complexities of the transition in urban districts and research the use of a simulation game to increase the understanding of the complexity of the transition. Surveys and observations were used to collect data about the learning experiences of playing the game GO2Zero. The results show that participants liked to play the game and they considered the game a valid representation of the system. Further, the participants agree that they obtained a better understanding of the complexity of the residential energy system and experienced a variety of challenges in the transition. Simulation games, like GO2Zero, could become valuable instruments in local energy transition processes as they offer a safe environment for novices and experts to jointly experiment with the challenges in this process. These experiences could support the design of the transition process by helping actors to formulate goals and collaborative strategies for achieving those goals. Future research will focus on the use of this game for experimenting with different strategies and instruments and to analyze their effects.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 53
    Publication Date: 2018-07-26
    Description: ACS Sustainable Chemistry & Engineering DOI: 10.1021/acssuschemeng.8b02528
    Electronic ISSN: 2168-0485
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 54
    Publication Date: 2018-07-26
    Description: Biochemistry DOI: 10.1021/acs.biochem.8b00593
    Print ISSN: 0006-2960
    Electronic ISSN: 1520-4995
    Topics: Biology , Chemistry and Pharmacology
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  • 55
    Publication Date: 2018-07-26
    Description: Crystal Growth & Design DOI: 10.1021/acs.cgd.8b00346
    Print ISSN: 1528-7483
    Electronic ISSN: 1528-7505
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 56
    Publication Date: 2018-07-26
    Description: Crystal Growth & Design DOI: 10.1021/acs.cgd.8b00547
    Print ISSN: 1528-7483
    Electronic ISSN: 1528-7505
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 57
    Publication Date: 2018-07-26
    Description: Diversity, Vol. 10, Pages 73: Weevils as Targets for Biological Control, and the Importance of Taxonomy and Phylogeny for Efficacy and Biosafety Diversity doi: 10.3390/d10030073 Authors: Barbara I. P. Barratt Matthew J. W. Cock Rolf G. Oberprieler Curculionidae are a large mainly herbivorous family of beetles, some of which have become crop pests. Classical biological control has been attempted for about 38 species in 19 genera, and at least moderate success has been achieved in 31 % of cases. Only two weevil species have been considered to be completely controlled by a biological control agent. Success depends upon accurately matching natural enemies with their hosts, and hence taxonomy and phylogeny play a critical role. These factors are discussed and illustrated with two case studies: the introduction of the braconid parasitoid Mictroctonus aethiopoides into New Zealand for biological control of the lucerne pest Sitona discoideus, a case of complex phylogenetic relationships that challenged the prediction of potential non-target hosts, and the use of a mymarid egg parasitoid, Anaphes nitens, to control species of the eucalypt weevil genus Gonipterus, which involves failure to match up parasitoids with the right target amongst a complex of very closely related species. We discuss the increasing importance of molecular methods to support biological control programmes and the essential role of these emerging technologies for improving our understanding of this very large and complex family.
    Electronic ISSN: 1424-2818
    Topics: Biology
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  • 58
    Publication Date: 2018-07-26
    Description: Forests, Vol. 9, Pages 448: Shifts in Growing Season of Tropical Deciduous Forests as Driven by El Niño and La Niña during 2001–2016 Forests doi: 10.3390/f9080448 Authors: Phan Kieu Diem Uday Pimple Asamaporn Sitthi Pariwate Varnakovida Katsunori Tanaka Sukan Pungkul Kumron Leadprathom Monique Y. LeClerc Amnat Chidthaisong This study investigated the spatiotemporal dynamics of tropical deciduous forest including dry dipterocarp forest (DDF) and mixed deciduous forest (MDF) and its phenological changes in responses to El Niño and La Niña during 2001–2016. Based on time series of Normalized Difference Vegetation Index (NDVI) extracted from Moderate Resolution Imaging Spectroradiometer (MODIS), the start of growing season (SOS), the end of growing season (EOS), and length of growing season (LOS) were derived. In absence of climatic fluctuation, the SOS of DDF commonly started on 106 ± 7 DOY, delayed to 132 DOY in El Niño year (2010) and advanced to 87 DOY in La Niña year (2011). Thus, there was a delay of about 19 to 33 days in El Niño and an earlier onset of about 13 to 27 days in La Niña year. The SOS of MDF started almost same time as of DDF on the 107 ± 7 DOY during the neutral years and delayed to 127 DOY during El Niño, advanced to 92 DOY in La Niña year. The SOS of MDF was delayed by about 12 to 28 days in El Niño and was earlier about 8 to 22 days in La Niña. Corresponding to these shifts in SOS and LOS of both DDF and MDF were also induced by the El Niño–Southern Oscillation (ENSO).
    Electronic ISSN: 1999-4907
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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  • 59
    Publication Date: 2018-07-26
    Description: ACS Sustainable Chemistry & Engineering DOI: 10.1021/acssuschemeng.8b02609
    Electronic ISSN: 2168-0485
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 60
    Publication Date: 2018-07-26
    Description: Entropy, Vol. 20, Pages 550: Information Geometry of Nonlinear Stochastic Systems Entropy doi: 10.3390/e20080550 Authors: Rainer Hollerbach Donovan Dimanche Eun-jin Kim We elucidate the effect of different deterministic nonlinear forces on geometric structure of stochastic processes by investigating the transient relaxation of initial PDFs of a stochastic variable x under forces proportional to -xn (n=3,5,7) and different strength D of δ-correlated stochastic noise. We identify the three main stages consisting of nondiffusive evolution, quasi-linear Gaussian evolution and settling into stationary PDFs. The strength of stochastic noise is shown to play a crucial role in determining these timescales as well as the peak amplitude and width of PDFs. From time-evolution of PDFs, we compute the rate of information change for a given initial PDF and uniquely determine the information length L(t) as a function of time that represents the number of different statistical states that a system evolves through in time. We identify a robust geodesic (where the information changes at a constant rate) in the initial stage, and map out geometric structure of an attractor as L(t→∞)∝μm, where μ is the position of an initial Gaussian PDF. The scaling exponent m increases with n, and also varies with D (although to a lesser extent). Our results highlight ubiquitous power-laws and multi-scalings of information geometry due to nonlinear interaction.
    Electronic ISSN: 1099-4300
    Topics: Chemistry and Pharmacology , Physics
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  • 61
    Publication Date: 2018-07-26
    Description: Crystal Growth & Design DOI: 10.1021/acs.cgd.8b00783
    Print ISSN: 1528-7483
    Electronic ISSN: 1528-7505
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 62
    Publication Date: 2018-07-26
    Description: Crystal Growth & Design DOI: 10.1021/acs.cgd.8b00718
    Print ISSN: 1528-7483
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    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 63
    Publication Date: 2018-07-26
    Description: Entropy, Vol. 20, Pages 553: Hierarchical Structure of Generalized Thermodynamic and Informational Entropy Entropy doi: 10.3390/e20080553 Authors: Pierfrancesco Palazzo The present research aimed at discussing the thermodynamic and informational aspects of entropy concept to propose a unitary perspective of its definitions as an inherent property of any system in any state. The dualism and the relation between physical nature of information and the informational content of physical states of matter and phenomena play a fundamental role in the description of multi-scale systems characterized by hierarchical configurations. A method is proposed to generalize thermodynamic and informational entropy property and characterize the hierarchical structure of its canonical definition at macroscopic and microscopic levels of a system described in the domain of classical and quantum physics. The conceptual schema is based on dualisms and symmetries inherent to the geometric and kinematic configurations and interactions occurring in many-particle and few-particle thermodynamic systems. The hierarchical configuration of particles and sub-particles, representing the constitutive elements of physical systems, breaks down into levels characterized by particle masses subdivision, implying positions and velocities degrees of freedom multiplication. This hierarchy accommodates the allocation of phenomena and processes from higher to lower levels in the respect of the equipartition theorem of energy. However, the opposite and reversible process, from lower to higher level, is impossible by virtue of the Second Law, expressed as impossibility of Perpetual Motion Machine of the Second Kind (PMM2) remaining valid at all hierarchical levels, and the non-existence of Maxwell’s demon. Based on the generalized definition of entropy property, the hierarchical structure of entropy contribution and production balance, determined by degrees of freedom and constraints of systems configuration, is established. Moreover, as a consequence of the Second Law, the non-equipartition theorem of entropy is enunciated, which would be complementary to the equipartition theorem of energy derived from the First Law.
    Electronic ISSN: 1099-4300
    Topics: Chemistry and Pharmacology , Physics
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  • 64
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    MDPI Publishing
    In: Entropy
    Publication Date: 2018-07-26
    Description: Entropy, Vol. 20, Pages 552: The Gibbs Paradox Entropy doi: 10.3390/e20080552 Authors: Simon Saunders The Gibbs Paradox is essentially a set of open questions as to how sameness of gases or fluids (or masses, more generally) are to be treated in thermodynamics and statistical mechanics. They have a variety of answers, some restricted to quantum theory (there is no classical solution), some to classical theory (the quantum case is different). The solution offered here applies to both in equal measure, and is based on the concept of particle indistinguishability (in the classical case, Gibbs’ notion of ‘generic phase’). Correctly understood, it is the elimination of sequence position as a labelling device, where sequences enter at the level of the tensor (or Cartesian) product of one-particle state spaces. In both cases it amounts to passing to the quotient space under permutations. ‘Distinguishability’, in the sense in which it is usually used in classical statistical mechanics, is a mathematically convenient, but physically muddled, fiction.
    Electronic ISSN: 1099-4300
    Topics: Chemistry and Pharmacology , Physics
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  • 65
    Publication Date: 2018-07-26
    Description: Energies, Vol. 11, Pages 1937: Evaluation of Fast Charging Efficiency under Extreme Temperatures Energies doi: 10.3390/en11081937 Authors: Germana Trentadue Alexandre Lucas Marcos Otura Konstantinos Pliakostathis Marco Zanni Harald Scholz Multi-type fast charging stations are being deployed over Europe as electric vehicle adoption becomes more popular. The growth of an electrical charging infrastructure in different countries poses different challenges related to its installation. One of these challenges is related to weather conditions that are extremely heterogeneous due to different latitudes, in which fast charging stations are located and whose impact on the charging performance is often neglected or unknown. The present study focused on the evaluation of the electric vehicle (EV) charging process with fast charging devices (up to 50 kW) at ambient (25 °C) and at extreme temperatures (−25 °C, −15 °C, +40 °C). A sample of seven fast chargers and two electric vehicles (CCS (combined charging system) and CHAdeMO (CHArge de Move)) available on the commercial market was considered in the study. Three phase voltages and currents at the wall socket, where the charger was connected, as well as voltage and current at the plug connection between the charger and vehicle have been recorded. According to SAE (Society of Automotive Engineers) J2894/1, the power conversion efficiency during the charging process has been calculated as the ratio between the instantaneous DC power delivered to the vehicle and the instantaneous AC power supplied from the grid in order to test the performance of the charger. The inverse of the efficiency of the charging process, i.e., a kind of energy return ratio (ERR), has been calculated as the ratio between the AC energy supplied by the grid to the electric vehicle supply equipment (EVSE) and the energy delivered to the vehicle’s battery. The evaluation has shown a varied scenario, confirming the efficiency values declared by the manufacturers at ambient temperature and reporting lower energy efficiencies at extreme temperatures, due to lower requested and, thus, delivered power levels. The lowest and highest power conversion efficiencies of 39% and 93% were observed at −25 °C and ambient temperature (+25 °C), respectively.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 66
    Publication Date: 2018-07-26
    Description: Entropy, Vol. 20, Pages 549: Entropy-Based Feature Extraction for Electromagnetic Discharges Classification in High-Voltage Power Generation Entropy doi: 10.3390/e20080549 Authors: Imene Mitiche Gordon Morison Alan Nesbitt Brian G. Stewart Philip Boreham This work exploits four entropy measures known as Sample, Permutation, Weighted Permutation, and Dispersion Entropy to extract relevant information from Electromagnetic Interference (EMI) discharge signals that are useful in fault diagnosis of High-Voltage (HV) equipment. Multi-class classification algorithms are used to classify or distinguish between various discharge sources such as Partial Discharges (PD), Exciter, Arcing, micro Sparking and Random Noise. The signals were measured and recorded on different sites followed by EMI expert’s data analysis in order to identify and label the discharge source type contained within the signal. The classification was performed both within each site and across all sites. The system performs well for both cases with extremely high classification accuracy within site. This work demonstrates the ability to extract relevant entropy-based features from EMI discharge sources from time-resolved signals requiring minimal computation making the system ideal for a potential application to online condition monitoring based on EMI.
    Electronic ISSN: 1099-4300
    Topics: Chemistry and Pharmacology , Physics
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  • 67
    Publication Date: 2018-07-26
    Description: Energies, Vol. 11, Pages 1934: Multi-Port Zero-Current Switching Switched-Capacitor Converters for Battery Management Applications Energies doi: 10.3390/en11081934 Authors: Yat Chi Fong Ka Wai Eric Cheng S. Raghu Raman Xiaolin Wang A novel implementation of multi-port zero-current switching (ZCS) switched-capacitor (SC) converters for battery management applications is presented. In addition to the auto-balancing feature offered by the SC technique, the proposed SC converter permits individual control of the charging or discharging current of the series-connected energy storage elements, such as the battery or super-capacitor cells. This approach enables advanced state control and accelerates the equalizing process by coordinated operation with the battery management system (BMS) and an adjustable voltage source, which can be implemented by a DC-DC converter interfaced to the energy storage string. Different configurations, including the single-input multi-output (SIMO), multi-input single-output (MISO) SC converters, and the corresponding altered circuits for string-to-cells, cells-to-string, as well as cells-to-cells equalizers, are discussed with a circuit analysis and derivation of the associated mathematical representation. The simulation study and experimental results indicated a significant increase in the balancing speed with the presence of BMS and closed-loop control of cell currents.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 68
    Publication Date: 2018-07-26
    Description: Materials, Vol. 11, Pages 1287: Polysaccharide-Based Aerogel Bead Production via Jet Cutting Method Materials doi: 10.3390/ma11081287 Authors: Imke Preibisch Philipp Niemeyer Yusuf Yusufoglu Pavel Gurikov Barbara Milow Irina Smirnova The aim of this work is to develop a method to produce spherical biopolymer-based aerogel particles, which is capable for scale-up in the future. Therefore, the jet cutting method is suggested. Amidated pectin, sodium alginate, and chitosan are used as a precursor (a 1–3 wt. % solution) for particle production via jet cutting. Gelation is realized via two methods: the internal setting method (using calcium carbonate particles as cross-linkers and citric and acidic acid for pH adjustment) and the diffusion method (in calcium chloride solutions). Gel particles are subjected to solvent exchange to ethanol and consequent supercritical drying with CO2. Spherical aerogel particles with narrow particle size distributions in the range of 400 to 1500 µm and a specific surface area of around 500 m2/g are produced. Overall, it can be concluded that the jet cutting method is suitable for aerogel particle production, although the shape of the particles is not perfectly spherical in all cases. However, parameter adjustment might lead to even better shaped particles in further work. Moreover, the biopolymer-based aerogel particles synthesized in this study are tested as humidity absorbers in drying units for home appliances, particularly for dishwashers. It has been shown that for several cycles of absorption and desorption of humidity, aerogel particles are stable with an absorption capacity of around 20 wt. %.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 69
    Publication Date: 2018-07-26
    Description: Materials, Vol. 11, Pages 1279: Computational Predictions and Microwave Plasma Synthesis of Superhard Boron-Carbon Materials Materials doi: 10.3390/ma11081279 Authors: Paul A. Baker Shane A. Catledge Sumner B. Harris Kathryn J. Ham Wei-Chih Chen Cheng-Chien Chen Yogesh K. Vohra Superhard boron-carbon materials are of prime interest due to their non-oxidizing properties at high temperatures compared to diamond-based materials and their non-reactivity with ferrous metals under extreme conditions. In this work, evolutionary algorithms combined with density functional theory have been utilized to predict stable structures and properties for the boron-carbon system, including the elusive superhard BC5 compound. We report on the microwave plasma chemical vapor deposition on a silicon substrate of a series of composite materials containing amorphous boron-doped graphitic carbon, boron-doped diamond, and a cubic hard-phase with a boron-content as high as 7.7 at%. The nanoindentation hardness of these composite materials can be tailored from 8 GPa to as high as 62 GPa depending on the growth conditions. These materials have been characterized by electron microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, and nanoindentation hardness, and the experimental results are compared with theoretical predictions. Our studies show that a significant amount of boron up to 7.7 at% can be accommodated in the cubic phase of diamond and its phonon modes and mechanical properties can be accurately modeled by theory. This cubic hard-phase can be incorporated into amorphous boron-carbon matrices to yield superhard materials with tunable hardness values.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 70
    Publication Date: 2018-07-26
    Description: Forests, Vol. 9, Pages 446: Plant Hydraulic Trait Covariation: A Global Meta-Analysis to Reduce Degrees of Freedom in Trait-Based Hydrologic Models Forests doi: 10.3390/f9080446 Authors: A. Rio Mursinna Erica McCormick Katie Van Horn Lisa Sartin Ashley M. Matheny Current vegetation modeling strategies use broad categorizations of plants to estimate transpiration and biomass functions. A significant source of model error stems from vegetation categorizations that are mostly taxonomical with no basis in plant hydraulic strategy and response to changing environmental conditions. Here, we compile hydraulic traits from 355 species around the world to determine trait covariations in order to represent hydraulic strategies. Simple and stepwise regression analyses demonstrate the interconnectedness of multiple vegetative hydraulic traits, specifically, traits defining hydraulic conductivity and vulnerability to embolism with wood density and isohydricity. Drought sensitivity is strongly (Adjusted R2 = 0.52, p < 0.02) predicted by a stepwise linear model combining rooting depth, wood density, and isohydricity. Drought tolerance increased with increasing wood density and anisohydric response, but with decreasing rooting depth. The unexpected response to rooting depth may be due to other tradeoffs within the hydraulic system. Rooting depth was able to be predicted from sapwood specific conductivity and the water potential at 50% loss of conductivity. Interestingly, the influences of biome or growth form do not increase the accuracy of the drought tolerance model and were able to be omitted. Multiple regression analysis revealed 3D trait spaces and tradeoff axes along which species’ hydraulic strategies can be analyzed. These numerical trait spaces can reduce the necessary input to and parameterization of plant hydraulics modules, while increasing the physical representativeness of such simulations.
    Electronic ISSN: 1999-4907
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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  • 71
    Publication Date: 2018-07-26
    Description: Journal of Medicinal Chemistry DOI: 10.1021/acs.jmedchem.7b01644
    Topics: Chemistry and Pharmacology
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  • 72
    Publication Date: 2018-07-26
    Description: The Journal of Organic Chemistry DOI: 10.1021/acs.joc.8b01268
    Print ISSN: 0022-3263
    Electronic ISSN: 1520-6904
    Topics: Chemistry and Pharmacology
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  • 73
    Publication Date: 2018-07-26
    Description: Journal of Chemical Information and Modeling DOI: 10.1021/acs.jcim.8b00261
    Topics: Chemistry and Pharmacology
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  • 74
    Publication Date: 2018-07-26
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.8b02342
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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  • 75
    Publication Date: 2018-07-26
    Description: The Journal of Organic Chemistry DOI: 10.1021/acs.joc.8b00632
    Print ISSN: 0022-3263
    Electronic ISSN: 1520-6904
    Topics: Chemistry and Pharmacology
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  • 76
    Publication Date: 2018-07-26
    Description: Journal of Medicinal Chemistry DOI: 10.1021/acs.jmedchem.8b00813
    Topics: Chemistry and Pharmacology
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  • 77
    Publication Date: 2018-07-26
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.8b03651
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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  • 78
    Publication Date: 2018-07-26
    Description: Materials, Vol. 11, Pages 1290: Compositional Dependence of Phase Selection in CoCrCu0.1FeMoNi-Based High-Entropy Alloys Materials doi: 10.3390/ma11081290 Authors: Ning Liu Chen Chen Isaac Chang Pengjie Zhou Xiaojing Wang To study the effect of alloy composition on phase selection in the CoCrCu0.1FeMoNi high-entropy alloy (HEA), Mo was partially replaced by Co, Cr, Fe, and Ni. The microstructures and phase selection behaviors of the CoCrCu0.1FeMoNi HEA system were investigated. Dendritic, inter-dendritic, and eutectic microstructures were observed in the as-solidified HEAs. A simple face centered cubic (FCC) single-phase solid solution was obtained when the molar ratio of Fe, Co, and Ni was increased to 1.7 at the expense of Mo, indicating that Fe, Co, and Ni stabilized the FCC structure. The FCC structure was favored at the atomic radius ratio δ ≤ 2.8, valence electron concentration (VEC) ≥ 8.27, mixing entropy ΔS ≤ 13.037, local lattice distortion parameter α2 ≤ 0.0051, and ΔS/δ2 > 1.7. Mixed FCC + body centered cubic (BCC) structures occurred for 4.1 ≤ δ ≤ 4.3 and 7.71 ≤ VEC ≤ 7.86; FCC or/and BCC + intermetallic (IM) mixtures were favored at 2.8 ≤ δ ≤ 4.1 or δ > 4.3 and 7.39 < VEC ≤ 8.27. The IM phase is favored at electronegativity differences greater than 0.133. However, ΔS, α2, and ΔS/δ2 were inefficient in identifying the (FCC or/and BCC + IM)/(FCC + BCC) transition. Moreover, the mixing enthalpy cannot predict phase structures in this system.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 79
    Publication Date: 2018-07-26
    Description: Materials, Vol. 11, Pages 1286: An Evaluation of Wetting and Adhesion of Three Bioceramic Root Canal Sealers to Intraradicular Human Dentin Materials doi: 10.3390/ma11081286 Authors: Jung-Hong Ha Hyeon-Cheol Kim Young Kyung Kim Tae-Yub Kwon Root canal sealers should have good wetting and adhesion with intraradicular dentin. This study evaluated the wetting and adhesion properties of three bioceramic root canal sealers on dentin using contact angle (CA) measurements and calculations based on the Owens–Wendt–Rabel–Kälble (OWRK) model and compared the properties with those of a resin sealer. Three bioceramic sealers (EndoSequence BC Sealer (BC); Endoseal MTA (EM); and MTA Fillapex (MF)) were tested, together with one epoxy resin-based sealer (AH Plus (AP)). Disc-shaped sealer specimens and human premolar teeth with flat and polished intraradicular dentin surfaces were prepared (n = 12). The CAs of two liquids (water and methylene iodide) were measured on the surfaces using the sessile drop method. The wetting and adhesion properties of the four sealers were calculated using the wetting envelope and isogram diagram, respectively. Group BC showed the best wettability among the four sealer groups. The best adhesion was achieved for group EM, followed by group BC, with a significant difference being present between the two groups (p < 0.05). The OWRK-based calculation indicated that the bioceramic BC and EM sealers showed superior wetting and adhesion properties to the AP sealers.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 80
    Publication Date: 2018-07-26
    Description: Materials, Vol. 11, Pages 1281: Investigation of Cutting Temperature during Turning Inconel 718 with (Ti,Al)N PVD Coated Cemented Carbide Tools Materials doi: 10.3390/ma11081281 Authors: Jinfu Zhao Zhanqiang Liu Qi Shen Bing Wang Qingqing Wang Physical Vapor Deposition (PVD) Ti1−xAlxN coated cemented carbide tools are commonly used to cut difficult-to-machine super alloy of Inconel 718. The Al concentration x of Ti1−xAlxN coating can affect the coating microstructure, mechanical and thermo-physical properties of Ti1−xAlxN coating, which affects the cutting temperature in the machining process. Cutting temperature has great influence on the tool life and the machined surface quality. In this study, the influences of PVD (Ti,Al)N coated cemented carbide tools on the cutting temperature were analyzed. Firstly, the microstructures of PVD Ti0.41Al0.59N and Ti0.55Al0.45N coatings were inspected. The increase of Al concentration x enhanced the crystallinity of PVD Ti1−xAlxN coatings without epitaxy growth of TiAlN crystals. Secondly, the mechanical and thermo-physical properties of PVD Ti0.41Al0.59N and Ti0.55Al0.45N coated tools were analyzed. The pinning effects of coating increased with the increasing of Al concentration x, which can decrease the friction coefficient between the PVD Ti1−xAlxN coated cemented carbide tools and the Inconel 718 material. The coating hardness and thermal conductivity of Ti1−xAlxN coatings increased with the increase of Al concentration x. Thirdly, the influences of PVD Ti1−xAlxN coated tools on the cutting temperature in turning Inconel 718 were analyzed by mathematical analysis modelling and Lagrange simulation methods. Compared with the uncoated tools, PVD Ti0.41Al0.59N coated tools decreased the heat generation as well as the tool temperature to reduce the thermal stress generated within the tools. Lastly, the influences of Ti1−xAlxN coatings on surface morphologies of the tool rake faces were analyzed. The conclusions can reveal the influences of PVD Ti1−xAlxN coatings on cutting temperature, which can provide guidance in the proper choice of Al concentration x for PVD Ti1−xAlxN coated tools in turning Inconel 718.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 81
    Publication Date: 2018-07-26
    Description: Materials, Vol. 11, Pages 1278: Study on Near-Net Forming Technology for Stepped Shaft by Cross-Wedge Rolling Based on Variable Cone Angle Billets Materials doi: 10.3390/ma11081278 Authors: Sutao Han Xuedao Shu Chang Shu Considering problems about concaves at the stepped shaft ends, this paper established the plastic flow kinetic theories about metal deforming during the cross-wedge rolling (CWR) process. By means of the DEFORM-3D finite element software and the point tracing method, the forming process of stepped shafts and the forming mechanism of concaves at shaft ends were studied. Based on the forming features of stepped shafts, rolling pieces were designed using variable cone angle billets. Single-factor tests were conducted to analyze the influence law of the shape parameters of billet with variable cone angle on end concaves, and rolling experiments were performed for verification. According to the results, during the rolling process of stepped shafts, concaves will come into being in stages, and the increasing tendency of its depth is due to the wave mode, the parameters of cone angle α, the first cone section length n. Furthermore, the total cone section length m has an increasingly weaker influence on the end concaves. Specifically, cone angle α has the most significant influence on the quality of shaft ends, which is about twice the influence of the total cone section length m. The concave depth will decrease at the beginning, and then increase with the increasing of the cone angle α and the first cone section length n, and it will decrease with the increasing of the total cone section length m. Finite element numerical analysis results are perfectly consistent with experimental results, with the error ratio being lower than 5%. The results provide a reliable theoretical basis for effectively disposing of end concave problems during CWR, rationally confirming the shape parameters of billets with a variable cone angle, improving the quality of stepped shaft ends, and realizing the near-net forming process of cross-wedge rolling without a stub bar.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 82
    Publication Date: 2018-07-26
    Description: Materials, Vol. 11, Pages 1276: Tool Wear Mechanism in Cutting of Stack CFRP/UNS A97075 Materials doi: 10.3390/ma11081276 Authors: Severo Raul Fernandez-Vidal Sergio Fernandez-Vidal Moises Batista Jorge Salguero The aeronautics industry’s competitiveness has led to the need to increase productivity with one shot drilling (OSD) systems capable of drilling stacks of dissimilar materials (fibre/metal laminates, FML) in order to reduce riveting times. Among the materials that constitute the current aeronautical models, composite materials and aluminium (Al) and titanium (Ti) alloys stand out. These one-pass machining techniques produce high-quality holes, especially when all the elements that have to be joined are made of the same material. This work has followed a conventional OSD strategy and the same cutting conditions applied to CFRP (carbo-fibre-reinforced polymer), Al and CFRP/Al stacked sheets to know the wear mechanisms produced. With this purpose, results were obtained by using current specific techniques, such as microstructural analysis, monitoring of the shear forces and analysis of macrogeometric deviations. It has been determined that when these drilling techniques are applied under the same cutting conditions to stacks of materials of a different nature, the results of the wear mechanisms acting on the tool differ from those obtained when machining each material separately. This article presents a comparison between the effects of tool wear during dry drilling of CFRP and UNS A97075 plates separately and when machined as stacks.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 83
    Publication Date: 2018-07-26
    Description: Sensors, Vol. 18, Pages 2420: Strain Transfer Characteristics of Resistance Strain-Type Transducer Using Elastic-Mechanical Shear Lag Theory Sensors doi: 10.3390/s18082420 Authors: Yongqian Li Zhigang Wang Chi Xiao Yinming Zhao Yaxin Zhu Zili Zhou The strain transfer characteristics of resistance strain gauge are theoretically investigated. A resistance strain-type transducer is modeled to be a four-layer and two-glue (FLTG) structure model, which comprises successively the surface of an elastomer sensitive element, a ground adhesive glue, a film substrate layer, an upper adhesive glue, a sensitive grids layer, and a polymer cover. The FLTG model is studied in elastic–mechanical shear lag theory, and the strain transfer progress in a resistance strain-type transducer is described. The strain transitional zone (STZ) is defined and the strain transfer ratio (STR) of the FLTG structure is formulated. The dependences of the STR and STZ on both the dimensional sizes of the adhesive glue and structural parameters are calculated. The results indicate that the width, thickness and shear modulus of the ground adhesive glue have a greater influence on the STZ ratio. To ensure that the resistance strain gauge has excellent strain transfer performance and low hysteresis, it is recommended that the paste thickness should be strictly controlled, and the STZ ratio should be less than 10%. Moreover, the STR strongly depends on the length and width of the sensitive grids.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 84
    Publication Date: 2018-07-26
    Description: Sensors, Vol. 18, Pages 2416: Design and Optimization of a Novel Three-Dimensional Force Sensor with Parallel Structure Sensors doi: 10.3390/s18082416 Authors: Guanyu Huang Dan Zhang Sheng Guo Haibo Qu To measure large external forces exerted on a loading platform, a novel three-dimensional force sensor is developed in this paper. The proposed sensor was designed with a parallel mechanism with three degrees of freedom. Kinematic analysis of this sensor was performed. Due to its structural characteristics, the working principle of the sensor was analyzed using a Jacobian matrix. The sensitivity diversity index and measuring capability were both calculated. The analysis showed that the proposed sensor is more suitable for measuring large forces than existing strain sensors. In addition, compared with existing strain sensors, this sensor is more suitable for measuring forces along the x and y axes. By changing the stiffness coefficients of the springs, the proposed sensor has reconfigurability. This sensor can change its measuring capability to meet different requirements. Next, the mode shapes and natural frequencies of the proposed sensor were performed. Finally, based on these performance indices, the design variables were optimized using a Multi-Objective Genetic Algorithm.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 85
    Publication Date: 2018-07-26
    Description: Sensors, Vol. 18, Pages 2415: Cheeses Made from Raw and Pasteurized Cow’s Milk Analysed by an Electronic Nose and an Electronic Tongue Sensors doi: 10.3390/s18082415 Authors: Nuno I. P. Valente Alisa Rudnitskaya João A. B. P. Oliveira M. Teresa S. R. Gomes Elvira M. M. Gaspar Cheese prepared from whole milk, raw and pasteurized, were analysed by an electronic nose based on piezoelectric quartz crystals and an electronic tongue based on potentiometric sensors, immediately after their preparation and along ripening (after 7 and 21 days). Whey was also analysed by the potentiometric electronic tongue. Results obtained by the electronic nose and tongue were found to be complementary, with the electronic nose being more sensitive to differences in the milk and the electronic tongue being more sensitive to milk pasteurization. Electronic tongue was able to distinguish cheeses made from raw and pasteurized milk, both analysing the whey or the curd, with correct classification rate of 96% and 84%, respectively. Besides, the electronic nose was more sensitive than the electronic tongue to the ripening process, with large differences between samples after 7 and 21 days, while the electronic tongue was only sensitive to the initial maturation stages, with large difference between freshly prepared cheese and with seven days of maturation.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 86
    Publication Date: 2018-07-26
    Description: Sensors, Vol. 18, Pages 2412: Validation of the Accuracy and Convergence Time of Real Time Kinematic Results Using a Single Galileo Navigation System Sensors doi: 10.3390/s18082412 Authors: Zbigniew Siejka For the last two decades, the American GPS and Russian GLONASS were the basic systems used in global positioning and navigation. In recent years, there has been significant progress in the development of positioning systems. New regional systems have been created, i.e., the Japanese Quasi-Zenith Satellite System (QZSS) and Indian Regional Navigational Satellite System (IRNSS). A plan to build its own regional navigation system named Korean Positioning System (KPS) was announced South Korea on 5 February 2018. Currently, two new global navigation systems are under development: the European Galileo and the Chinese BeiDou. The full operability of both systems by 2020 is planned. The paper deals with a possibility of determination of the user’s position from individual and independent global navigation satellite system (GNSS). The article is a broader concept aimed at independent determination of precise position from individual GPS, GLONASS, BeiDou and Galileo systems. It presents real time positioning results (Real Time Kinematic-RTK) using signals from Galileo satellites only. During the test, 14 Galileo satellites were used and the number of simultaneously observed Galileo satellites varied from five to seven. Real-time measurements were only possible in certain 24-h observation windows. However, their number was completed within 6 days at the end of 2017 and beginning of 2018, so there was possible to infer about the current availability, continuity, convergence time and accuracy of the RTK measurements. In addition, the systematic errors were demonstrated for the Galileo system.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 87
    Publication Date: 2018-07-26
    Description: Sustainability, Vol. 10, Pages 2613: An E-Commerce Platform for Industrialized Construction Procurement Based on BIM and Linked Data Sustainability doi: 10.3390/su10082613 Authors: Dandan He Zhongfu Li Chunlin Wu Xin Ning Industrialized construction has raised the requirements of procurement methods used in the construction industry. The rapid development of e-commerce offers efficient and effective solutions, however the large number of participants in the construction industry means that the data involved are complex, and problems arise related to volume, heterogeneity, and fragmentation. Thus, the sector lags behind others in the adoption of e-commerce. In particular, data integration has become a barrier preventing further development. Traditional e-commerce platform, which considered data integration for common product data, cannot meet the requirements of construction product data integration. This study aimed to build an information-integrated e-commerce platform for industrialized construction procurement (ICP) to overcome some of the shortcomings existing platforms. We proposed a platform based on Building Information Modelling (BIM) and linked data, taking an innovative approach to data integration. It uses industrialized construction technology to support product standardization, BIM to support procurement process, and linked data to connect different data sources. The platform was validated using a case study. With the development of an e-commerce ontology, industrialized construction component information was extracted from BIM models and converted to Resource Description Framework (RDF) format. Related information from different data sources was also converted to RDF format, and Simple Protocol and Resource Description Framework Query Language (SPARQL) queries were implemented. The platform provides a solution for the development of e-commerce platform in the construction industry.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 88
    Publication Date: 2018-07-26
    Description: Sustainability, Vol. 10, Pages 2614: An Efficient Grid-Based K-Prototypes Algorithm for Sustainable Decision-Making on Spatial Objects Sustainability doi: 10.3390/su10082614 Authors: Hong-Jun Jang Byoungwook Kim Jongwan Kim Soon-Young Jung Data mining plays a critical role in sustainable decision-making. Although the k-prototypes algorithm is one of the best-known algorithms for clustering both numeric and categorical data, clustering a large number of spatial objects with mixed numeric and categorical attributes is still inefficient due to complexity. In this paper, we propose an efficient grid-based k-prototypes algorithm, GK-prototypes, which achieves high performance for clustering spatial objects. The first proposed algorithm utilizes both maximum and minimum distance between cluster centers and a cell, which can reduce unnecessary distance calculation. The second proposed algorithm as an extension of the first proposed algorithm, utilizes spatial dependence; spatial data tends to be similar to objects that are close. Each cell has a bitmap index which stores the categorical values of all objects within the same cell for each attribute. This bitmap index can improve performance if the categorical data is skewed. Experimental results show that the proposed algorithms can achieve better performance than the existing pruning techniques of the k-prototypes algorithm.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 89
    Publication Date: 2018-07-26
    Description: Sustainability, Vol. 10, Pages 2609: The Influence of the Backfilling Roadway Driving Sequence on the Rockburst Risk of a Coal Pillar Based on an Energy Density Criterion Sustainability doi: 10.3390/su10082609 Authors: Yi Xue Zhengzheng Cao Feng Du Lin Zhu The rockburst hazard has always been an important issue affecting the safety production of coal mines in China. The unreasonable sequencing of roadway driving can lead to the dynamic instability of coal pillars, which subsequently causes rockburst accidents in roadway backfilling mining engineering and poses a serious threat to the safety of the mines. Roadway backfilling mining technology is an effective approach with which to mine corner residual coal resources under buildings, railways, and rivers. An energy density criterion is established and programmed with FISH language using numerical analysis software for the rockburst risk evaluation of coal pillars. On this basis, a numerical simulation model is established based on four scheme types, namely, the sequential mining, one-roadway interval mining, two-roadway interval mining, and three-roadway interval mining schemes. The influence of the backfilling roadway driving sequence on coal pillar stability is investigated, and the change law of vertical stress and energy density factor of coal pillars in different driving sequences in roadway backfilling mining technology are analyzed. According to the research results, the maximum energy density factor value of 21,172 J/m4 for coal pillars in one-roadway interval mining is the lowest among the different schemes. Therefore, the one-roadway interval mining scheme is the optimal choice in roadway backfilling mining technology. The results can be treated as an important basis for the prevention and treatment of coal pillar instability and rockburst in roadway backfilling mining technology.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 90
    Publication Date: 2018-07-26
    Description: Sensors, Vol. 18, Pages 2409: The Bluetooth Mesh Standard: An Overview and Experimental Evaluation Sensors doi: 10.3390/s18082409 Authors: Mathias Baert Jen Rossey Adnan Shahid Jeroen Hoebeke Mesh networks enable a many-to-many relation between nodes, which means that each node in the network can communicate with every other node using multi-hop communication and path diversity. As it enables the fast roll-out of sensor and actuator networks, it is an important aspect within the Internet of Things (IoT). Utilizing Bluetooth Low Energy (BLE) as an underlying technology to implement such mesh networks has gained a lot of interest in recent years. The result was a variety of BLE meshing solutions that were not interoperable because of the lack of a common standard. This has changed recently with the advent of the Bluetooth Mesh standard. However, a detailed overview of how this standard operates, performs and how it tackles other issues concerning BLE mesh networking is missing. Therefore, this paper investigates this new technology thoroughly and evaluates its performance by means of three approaches, namely an experimental evaluation, a statistical approach and a graph-based simulation model, which can be used as the basis for future research. Apart from showing that consistent results are achieved by means of all three approaches, we also identify possible drawbacks and open issues that need to be dealt with.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 91
    Publication Date: 2018-07-26
    Description: Sustainability, Vol. 10, Pages 2604: Analysis of Guidelines and Identification of Characteristics Influencing the Deconstruction Potential of Buildings Sustainability doi: 10.3390/su10082604 Authors: Roberta Carvalho Machado Henor Artur de Souza Gustavo de Souza Veríssimo Growing concerns regarding environmental preservation and the fact that the construction industry is one of the sectors with the highest rates of resource consumption and waste generation, have encouraged the adoption of deconstruction as an alternative to the demolition of buildings at the end of their lifecycle. However, the choice of strategies to enable deconstruction requires an in-depth knowledge of how the building’s characteristics, combined with the procedures adopted in the deconstruction process, will affect the reutilization of materials and components. In this paper, characteristics relating to design for deconstruction (DfD) are identified and the influence of each characteristic on the viability of a deconstruction is analysed. A literature review is conducted to assess the guideline of DfD and to identify relevant characteristics. These characteristics are then divided into the following categories: direct influence enabling deconstruction; influence on the ease of the process; and, influence on prolonging a building’s lifecycle. A number of questions are suggested for analysing each characteristic, and these can be employed in the development of a methodology for evaluating a building’s deconstruction potential. The identification of characteristics involved in the deconstruction guidelines may assist in the optimization of projects and the planning of deconstruction processes.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 92
    Publication Date: 2018-07-26
    Description: Symmetry, Vol. 10, Pages 300: Computing Metric Dimension and Metric Basis of 2D Lattice of Alpha-Boron Nanotubes Symmetry doi: 10.3390/sym10080300 Authors: Zafar Hussain Mobeen Munir Maqbool Chaudhary Shin Min Kang Concepts of resolving set and metric basis has enjoyed a lot of success because of multi-purpose applications both in computer and mathematical sciences. For a connected graph G(V,E) a subset W of V(G) is a resolving set for G if every two vertices of G have distinct representations with respect to W. A resolving set of minimum cardinality is called a metric basis for graph G and this minimum cardinality is known as metric dimension of G. Boron nanotubes with different lattice structures, radii and chirality’s have attracted attention due to their transport properties, electronic structure and structural stability. In the present article, we compute the metric dimension and metric basis of 2D lattices of alpha-boron nanotubes.
    Electronic ISSN: 2073-8994
    Topics: Mathematics , Physics
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  • 93
    Publication Date: 2018-07-26
    Description: Sustainability, Vol. 10, Pages 2605: Building a More Sustainable Society? A Case Study on the Role of Sustainable Development in the Education and Early Career of Water and Environmental Engineers Sustainability doi: 10.3390/su10082605 Authors: Anu Vehmaa Meeri Karvinen Marko Keskinen Engineering education is critical for sustainability, given the key role that engineers have in shaping the development of our society. Yet, engineering studies have traditionally not been driven by sustainability-related knowledge and skills, but focused more on general computational skills and technical problem-solving. This has also been the case in our case study, which focuses on recent water and environmental engineering graduates in Finland. We studied the role that sustainable development has had in their education and early career through an extensive questionnaire and semi-structured interviews. The analysis was done in two ways: indirectly by comparing how well the key working life knowledge and skills recognized by the respondents correspond with sustainability-related skills, and directly by studying the graduates’ views towards the sustainable development and their possibilities to advance it in their work. The results show that although sustainability was not at the core of respondents’ studies, their key competencies correspond well with sustainability-related working life skills. The respondents also see that sustainable development has a central role in water and environmental engineering, although it is typically more visible at a strategic rather than a practical level. However, the results also indicate that several early-career engineers have deficient knowledge of sustainable development, and are therefore lacking the ability to fully connect the principles of sustainable development into their own expertise. Overall, the findings suggest that water and environmental engineers with their wide set of competencies have the potential to take on a larger role in building a more sustainable society. To ensure this, engineering education should emphasize the connection between the field and sustainable development and clearly link engineers’ core competencies with the skills required to promote sustainability.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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  • 94
    Publication Date: 2018-07-26
    Description: Sustainability, Vol. 10, Pages 2603: Historic Urban Landscapes: A Review on Trends and Methodologies in the Urban Context of the 21st Century Sustainability doi: 10.3390/su10082603 Authors: Arturo Azpeitia Santander Agustín Azkarate Garai-Olaun Ander de la Fuente Arana This article makes a critical reflection, questioning the notion of historical urban landscapes as a conceptual paradigm used for the basis of urban conservation in the twenty-first century. The study begins with a brief summary of the origins and subsequent evolution of this concept, highlighting the two key reference milestones: the Vienna Memorandum (UNESCO, 2005) and the Paris Recommendation (UNESCO, 2011). Subsequently, the focus of attention will be on highlighting the problems and difficulties posed by the management and protection of historic urban landscapes today. In this sense, the focus of attention will be placed on the assumption that change is an inherent part of the urban condition, since there is no consensus on what the limits of acceptable change in historic urban landscapes should be. It also emphasizes three factors that make this more difficult: (1) the reminiscences of the doctrines of the Weberian administration in the current models of government; (2) the subjective nature of the systems of indicators applied to the scope of historic cities; and (3) the opportunism of tactical urbanism, which, despite its shortcomings, is becoming an outstanding alternative for the methodological development of the historic urban landscapes.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 95
    Publication Date: 2018-07-26
    Description: Water, Vol. 10, Pages 981: Scenario-Based Economic Impact Analysis for Bridge Closures Due to Flooding: A Case Study of North Gyeongsang Province, South Korea Water doi: 10.3390/w10080981 Authors: Byungil Kim Sha Chul Shin Du Yon Kim Flooding has the ability to severely reduce the capacity of a transportation network. The closure of even a single bridge, which often acts as a critical link in transportation networks, can have a severe impact on the entire network. This impact can lead to significant economic costs resulting from increased travel distances for drivers. Despite the significance of these costs, however, notably few studies have been conducted to determine the societal economic cost that would be incurred due to bridge closures. One possible reason for the lack of studies investigating bridge closures due to flooding could stem from the difficultly in collecting data. To address this issue, the methodology presented in this paper uses modeling and data resources that are available for major cities in most developed countries, including those in South Korea. We evaluate the economic impact of the bridge closures using the new administrative capital of North Gyeongsang Province, South Korea as a case study. Scenarios for the closure of bridges are derived from channel surveys and hydraulic analyses. These methods are used to overcome a lack of adequate data on historical floods in the new city. Traffic is forecasted to estimate the number of road users that would be forced to take detours due to inundated bridges. Contrasting travel distances when bridges are and are not operational, economic costs incurred by bridge closures due to flooding are estimated. The results indicated that bridge closures would result in an economic cost of 1563 USD to 44,180 USD per day, depending on how many bridges are closed and how many people are living in the new city. The estimates from this study will act as guidelines for identifying cost-effective mitigation and preparedness strategies aimed at reducing the frequency and impact of bridge closures due to flooding.
    Electronic ISSN: 2073-4441
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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  • 96
    Publication Date: 2018-07-26
    Description: Water, Vol. 10, Pages 972: Microbial Function and Hydrochemistry within a Stratified Anchialine Sinkhole: A Window into Coastal Aquifer Interactions Water doi: 10.3390/w10080972 Authors: Madison C. Davis James R. Garey Anchialine sinkholes provide insight into coastal aquifer systems and coastal mixing processes. Aquifer microbial community function is usually inferred from hydrochemical information, but there are few direct studies of microbial communities in the Floridan Aquifer. Hospital Hole is a 43 m-deep stratified sinkhole under the Weeki Wachee River, FL, with three distinct brackish layers: a hypoxic layer, a chemocline and a sulfidic anoxic layer. Illumina sequencing and bioinformatic tools were used to reconstruct metabolic functions and interactions of microbial communities in each layer. Each layer appears to originate from different parts of the coastal mixing zone and has a distinct microbial community with unique functions, which are influenced by the respective hydrochemistry. Sulfide oxidation and nitrate reduction are the most abundant functions. Syntrophy between methane oxidizers, methanogens and sulfate reducers is present. Similarities between the hydrochemistry and potential connectivity of Hospital Hole and the Floridan Aquifer coastal mixing zone suggest that microbial communities of Hospital Hole could be a surrogate for the coastal mixing zone of the aquifer in the absence of direct studies. Understanding how groundwater microbial communities react to saltwater intrusion and nutrient flux will be useful in predicting how coastal aquifer regions might react to anthropogenic change.
    Electronic ISSN: 2073-4441
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 97
    Publication Date: 2018-07-26
    Description: Symmetry, Vol. 10, Pages 299: Game-Theoretic Solutions for Data Offloading in Next Generation Networks Symmetry doi: 10.3390/sym10080299 Authors: Muhammad Asif Shafi Ullah Khan Rashid Ahmad Dhananjay Singh In recent years, global mobile data traffic has seen an unprecedented increase. This is due to worldwide usage of smart devices, availability of fast internet connections, and the popularity of social media. The Mobile Network Operators (MNOs) are, therefore, facing problems in handling this huge traffic flow. Each type of traffic, including real-time video, audio, and text has its own Quality of Services (QoS) requirements which, if not met, may cause a sufficient loss of profit. Offloading of these traffics can be made more efficient so that values of QoS parameters are enhanced. In this work, we propose an incentive-based game-theoretic frame work for downloading data. The download of each type of data will get an incentive determined by the two-stage Stackelberg game. We model the communication among single Mobile Base Station (MBS) and multiple Access Points (APs) in a crowded metropolitan environment. The leader offers an economic incentive based on the traffic type and followers respond to the incentive and offload traffic accordingly. The model optimizes strategies of both the MBS and APs in order to make the best use of their utilities. For the analysis, we have used a combination of analytical and experimental methods. The numerical outcome characterized a direct process of the best possible offloading ratio and legalized the efficiency of the proposed game. Optimal incentives and optimal offloading was the achievement of our proposed game-theoretic approach. We have implemented the model in MATLAB, and the experimental results show a maximum payoff was achieved and the proposed scheme achieved Nash Equilibria.
    Electronic ISSN: 2073-8994
    Topics: Mathematics , Physics
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  • 98
    Publication Date: 2018-07-27
    Description: ACS Sustainable Chemistry & Engineering DOI: 10.1021/acssuschemeng.8b01511
    Electronic ISSN: 2168-0485
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 99
    Publication Date: 2018-07-27
    Description: ACS Sustainable Chemistry & Engineering DOI: 10.1021/acssuschemeng.8b01658
    Electronic ISSN: 2168-0485
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 100
    Publication Date: 2018-07-27
    Description: ACS Sustainable Chemistry & Engineering DOI: 10.1021/acssuschemeng.8b01684
    Electronic ISSN: 2168-0485
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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