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  • 1
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    Springer Berlin Heidelberg | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: Characeae, a family of calcifying green algae, are common in carbonate-rich freshwaters. The southwestern shoreline of Lake Ganau (Kurdistan Region, northeastern Iraq) harbors dense and thick mats of these algae (genus Chara). On the lake bottom and along the shore, carbonate sands and rocks rich in the remains of stems, branches, nodes, and whorls of Chara are deposited. These deposits show all stages of growth and degradation of characean algae, including replacement and lithification into limestone. The replacement of the fragments by fine-grained calcite preserved delicate microstructures of Chara, such as cortical walls, cell shape, inner and outer layers of the stems, and reproductive organs. Based on roundness, sorting, the degree of lithification, and preserved microstructures of the grains (fragments), three facies were recognized. The first is represented by a newly formed lime sand facies showing elongated grains, poor sorting, and reduced roundness, with pristine preservation of characean surface microstructures. The second is a weathered lime sand facies, which shows better sorting and good roundness, whereas internal structures of characean fragments are still well preserved. The third is comprised of a lithified lime sand facies (grainstone), with very well sorted and rounded grains, and poorly preserved external and internal structures of the characeans. As compared to the newly formed lime sand facies, the grainstone facies shows an increase in grain size by more than 30 %, owing to precipitation of micritic lamina of possible microbial origin. Eventually, the Characeae-derived lime sands are lithified into oolitic limestones with sparry calcite cement, forming a grainstone microfacies. The present study has important implications for the interpretation of pre-Quaternary environments, as it records all stages of the fossilization process of characean green algae and highlights the role of these algae in the formation of oolitic carbonate rocks.
    Keywords: Characeae; Chara; Ooids; Green algae; Carbonate sand; Freshwater carbonates; Facies ; 551 ; Earth Sciences; Sedimentology; Biogeosciences; Geochemistry; Paleontology; Ecology
    Language: English
    Type: article , publishedVersion
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  • 2
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    Springer Berlin Heidelberg | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: This study evaluates and compares the trends in CO2 emissions for the manufacturing industries of three countries: two developed countries (Germany and Sweden) that have applied several measures to promote a shift towards a low-carbon economy and one developing country (Colombia) that has shown substantial improvements in the reduction of CO2 emissions. This analysis is conducted using panel data cointegration techniques to infer causality between CO2 emissions, production factors and energy sources. The results indicate a trend of producing more output with less pollution. The trends for these countries’ CO2 emissions depend on investment levels, energy sources and economic factors. Furthermore, the trends in CO2 emissions indicate that there are emission level differences between the two developed countries and the developing country. Moreover, the study confirms that it is possible to achieve economic growth and sustainable development while reducing greenhouse gas emissions, as Germany and Sweden demonstrate. In the case of Colombia, it is important to encourage a reduction in CO2 emissions through policies that combine technical and economic instruments and incentivise the application of new technologies that promote clean and environmentally friendly processes.
    Keywords: CO2 emissions; Manufacturing industries; Panel data model ; 551 ; Environment; Climate Change; Climate Change Impacts; Oceanography; Geography (general); Regional/Spatial Science; Nature Conservation
    Language: English
    Type: article , publishedVersion
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  • 3
    Publication Date: 2023-07-03
    Description: Absolute gravimeters are used in geodesy, geophysics and physics for a wide spectrum of applications. Stable gravimetric measurements over timescales from several days to decades are required to provide relevant insight into geophysical processes. Users of absolute gravimeters participate in comparisons with a metrological reference in order to monitor the temporal stability of the instruments and determine the bias to that reference. However, since no measurement standard of higher-order accuracy currently exists, users of absolute gravimeters participate in key comparisons led by the International Committee for Weights and Measures. These comparisons provide the reference values of highest accuracy compared to the calibration against a single gravimeter operated at a metrological institute. The construction of stationary, large-scale atom interferometers paves the way for a new measurement standard in absolute gravimetry used as a reference with a potential stability up to 1 nm/s 2 at 1 s integration time. At the Leibniz University Hannover, we are currently building such a very long baseline atom interferometer with a 10-m-long interaction zone. The knowledge of local gravity and its gradient along and around the baseline is required to establish the instrument’s uncertainty budget and enable transfers of gravimetric measurements to nearby devices for comparison and calibration purposes. We therefore established a control network for relative gravimeters and repeatedly measured its connections during the construction of the atom interferometer. We additionally developed a 3D model of the host building to investigate the self-attraction effect and studied the impact of mass changes due to groundwater hydrology on the gravity field around the reference instrument. The gravitational effect from the building 3D model is in excellent agreement with the latest gravimetric measurement campaign which opens the possibility to transfer gravity values with an uncertainty below the 10 nm/s2 level.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Niedersächsisches Ministerium für Wissenschaft und Kultur http://dx.doi.org/10.13039/501100010570
    Description: https://www.bipm.org/kcdb
    Keywords: ddc:526 ; Atom interferometry ; Gravity acceleration ; Absolute gravimetry ; Gravimeter reference
    Language: English
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  • 4
    Publication Date: 2023-07-03
    Description: XGM2019e is a combined global gravity field model represented by spheroidal harmonics up to degree and order (d/o) 5399, corresponding to a spatial resolution of 2′ (~ 4 km). As data sources, it includes the satellite model GOCO06s in the longer wavelength range up to d/o 300 combined with a ground gravity grid which also covers the shorter wavelengths. The ground data consist over land and ocean of gravity anomalies provided by courtesy of NGA (15′ resolution, identical to XGM2016) augmented with topographically derived gravity information over land (EARTH2014). Over the oceans, gravity anomalies derived from satellite altimetry are used (DTU13 with a resolution of 1′). The combination of the satellite data with the ground gravity observations is performed by using full normal equations up to d/o 719 (15′). Beyond d/o 719, a block-diagonal least squares solution is calculated for the high-resolution ground gravity data (from topography and altimetry). All calculations are performed in the spheroidal harmonic domain. In the spectral band up to d/o 719, the new model shows a slightly improved behaviour in the magnitude of a few mm RMS over land as compared to preceding models such as XGM2016, EIGEN6c4 or EGM2008 when validated with independent geoid information derived from GNSS/levelling. Over land and in the spectral range above d/o 719, the accuracy of XGM2019e marginally suffers from the sole use of topographic forward modelling, and geoid differences at GNSS/levelling stations are increased in the order of several mm RMS in well-surveyed areas, such as the US and Europe, compared to models containing real gravity data over their entire spectrum, e.g. EIGEN6c4 or EGM2008. However, GNSS/levelling validation also indicates that the performance of XGM2019e can be considered as globally more consistent and independent of existing high-resolution global models. Over the oceans, the model exhibits an enhanced performance (equal or better than preceding models), which is confirmed by comparison of the MDT’s computed from CNES/CLS 2015 mean sea surface and the high-resolution geoid models. The MDT based on XGM2019e shows fewer artefacts, particularly in the coastal regions, and fits globally better to DTU17MDT which is considered as an independent reference MDT.
    Description: European Space Agency http://dx.doi.org/10.13039/501100000844
    Keywords: ddc:526 ; Gravity ; Combined gravity field model ; Spherical harmonics ; Spheroidal harmonics ; Full normal equation systems ; High-performance computing
    Language: English
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  • 5
    Publication Date: 2023-07-03
    Description: The iteratively reweighted least-squares approach to self-tuning robust adjustment of parameters in linear regression models with autoregressive (AR) and t-distributed random errors, previously established in Kargoll et al. (in J Geod 92(3):271–297, 2018. https://doi.org/10.1007/s00190-017-1062-6), is extended to multivariate approaches. Multivariate models are used to describe the behavior of multiple observables measured contemporaneously. The proposed approaches allow for the modeling of both auto- and cross-correlations through a vector-autoregressive (VAR) process, where the components of the white-noise input vector are modeled at every time instance either as stochastically independent t-distributed (herein called “stochastic model A”) or as multivariate t-distributed random variables (herein called “stochastic model B”). Both stochastic models are complementary in the sense that the former allows for group-specific degrees of freedom (df) of the t-distributions (thus, sensor-component-specific tail or outlier characteristics) but not for correlations within each white-noise vector, whereas the latter allows for such correlations but not for different dfs. Within the observation equations, nonlinear (differentiable) regression models are generally allowed for. Two different generalized expectation maximization (GEM) algorithms are derived to estimate the regression model parameters jointly with the VAR coefficients, the variance components (in case of stochastic model A) or the cofactor matrix (for stochastic model B), and the df(s). To enable the validation of the fitted VAR model and the selection of the best model order, the multivariate portmanteau test and Akaike’s information criterion are applied. The performance of the algorithms and of the white noise test is evaluated by means of Monte Carlo simulations. Furthermore, the suitability of one of the proposed models and the corresponding GEM algorithm is investigated within a case study involving the multivariate modeling and adjustment of time-series data at four GPS stations in the EUREF Permanent Network (EPN).
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:526 ; Regression time series ; Vector-autoregressive model ; Cross-correlations ; Multivariate scaled t-distribution ; Self-tuning robust estimator ; Generalized expectation maximization algorithm ; Iteratively reweighted least squares ; Multivariate portmanteau test ; Monte Carlo simulation ; GPS time series
    Language: English
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  • 6
    Publication Date: 2023-07-03
    Description: For low Earth orbit (LEO) satellites, activities such as precise orbit determination, gravity field retrieval, and thermospheric density estimation from accelerometry require modeled accelerations due to radiation pressure. To overcome inconsistencies and better understand the propagation of modeling errors into estimates, we here suggest to extend the standard analytical LEO radiation pressure model with emphasis on removing systematic errors in time-dependent radiation data products for the Sun and the Earth. Our extended unified model of Earth radiation pressure accelerations is based on hourly CERES SYN1deg data of the Earth’s outgoing radiation combined with angular distribution models. We apply this approach to the GRACE (Gravity Recovery and Climate Experiment) data. Validations with 1 year of calibrated accelerometer measurements suggest that the proposed model extension reduces RMS fits between 5 and 27%, depending on how measurements were calibrated. In contrast, we find little changes when implementing, e.g., thermal reradiation or anisotropic reflection at the satellite’s surface. The refined model can be adopted to any satellite, but insufficient knowledge of geometry and in particular surface properties remains a limitation. In an inverse approach, we therefore parametrize various combinations of possible systematic errors to investigate estimability and understand correlations of remaining inconsistencies. Using GRACE-A accelerometry data, we solve for corrections of material coefficients and CERES fluxes separately over ocean and land. These results are encouraging and suggest that certain physical radiation pressure model parameters could indeed be determined from satellite accelerometry data.
    Description: Deutsches Zentrum für Luft- und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: ftp://ftp.tugraz.at/outgoing/ITSG/tvgogo/orbits/GRACE/
    Description: ftp://podaac-ftp.jpl.nasa.gov/allData/grace/L1B/JPL/
    Keywords: ddc:526 ; Solar radiation pressure ; Earth radiation pressure ; Satellite force models ; Parameter estimation
    Language: English
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  • 7
    Publication Date: 2023-07-03
    Description: Quantum optical technology provides an opportunity to develop new kinds of gravity sensors and to enable novel measurement concepts for gravimetry. Two candidates are considered in this study: the cold atom interferometry (CAI) gradiometer and optical clocks. Both sensors show a high sensitivity and long-term stability. They are assumed on board of a low-orbit satellite like gravity field and steady-state ocean circulation explorer (GOCE) and gravity recovery and climate experiment (GRACE) to determine the Earth’s gravity field. Their individual contributions were assessed through closed-loop simulations which rigorously mapped the sensors’ sensitivities to the gravity field coefficients. Clocks, which can directly obtain the gravity potential (differences) through frequency comparison, show a high sensitivity to the very long-wavelength gravity field. In the GRACE orbit, clocks with an uncertainty level of 1.0 × 10−18 are capable to retrieve temporal gravity signals below degree 12, while 1.0 × 10−17 clocks are useful for detecting the signals of degree 2 only. However, it poses challenges for clocks to achieve such uncertainties in a short time. In space, the CAI gradiometer is expected to have its ultimate sensitivity and a remarkable stability over a long time (measurements are precise down to very low frequencies). The three diagonal gravity gradients can properly be measured by CAI gradiometry with a same noise level of 5.0 mE/√Hz. They can potentially lead to a 2–5 times better solution of the static gravity field than that of GOCE above degree and order 50, where the GOCE solution is mainly dominated by the gradient measurements. In the lower degree part, benefits from CAI gradiometry are still visible, but there, solutions from GRACE-like missions are superior.
    Description: Deutsche Forschungsgemeinschaft
    Description: http://icgem.gfz-potsdam.de/tom_longtime
    Description: https://earth.esa.int/web/guest/-/goce-data-access-7219
    Description: ftp://podaac.jpl.nasa.gov/allData/grace/L1B/JPL/
    Keywords: ddc:526 ; Quantum optical sensors ; Optical clocks ; Relativistic geodesy ; Atomic gradiometry ; Gravity field
    Language: English
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  • 8
    Publication Date: 2023-06-21
    Description: The Gravity Recovery and Climate Experiment Follow-On (GRACE-FO) mission carries magnetometers that are dedicated to enhance the satellite’s navigation. After appropriate calibration and characterisation of artificial magnetic disturbances, these observations are valuable assets to characterise the natural variability of Earth’s magnetic field. We describe the data pre-processing, the calibration, and characterisation strategy against a high-precision magnetic field model applied to the GRACE-FO magnetic data. During times of geomagnetic quiet conditions, the mean residual to the magnetic model is around 1 nT with standard deviations below 10 nT. The mean difference to data of ESA’s Swarm mission, which is dedicated to monitor the Earth’s magnetic field, is mainly within ± 10 nT during conjunctions. The performance of GRACE-FO magnetic data is further discussed on selected scientific examples. During a magnetic storm event in August 2018, GRACE-FO reveals the local time dependence of the magnetospheric ring current signature, which is in good agreement with results from a network of ground magnetic observations. Also, derived field-aligned currents (FACs) are applied to monitor auroral FACs that compare well in amplitude and statistical behaviour for local time, hemisphere, and solar wind conditions to approved earlier findings from other missions including Swarm. On a case event, it is demonstrated that the dual-satellite constellation of GRACE-FO is most suitable to derive the persistence of auroral FACs with scale lengths of 180 km or longer. Due to a relatively larger noise level compared to dedicated magnetic missions, GRACE-FO is especially suitable for high-amplitude event studies. However, GRACE-FO is also sensitive to ionospheric signatures even below the noise level within statistical approaches. The combination with data of dedicated magnetic field missions and other missions carrying non-dedicated magnetometers greatly enhances related scientific perspectives.
    Description: European Space Agency (FR)
    Description: HEIBRIDS
    Description: Projekt DEAL
    Description: ftp://isdcftp.gfz-potsdam.de/grace-fo/MAGNETIC_FIELD
    Keywords: ddc:538.7 ; Earth’s magnetic field ; Geomagnetism ; Ionospheric currents ; Magnetospheric ring current ; Satellite-based magnetometers ; Platform magnetometers ; GRACE-FO
    Language: English
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  • 9
    Publication Date: 2023-06-21
    Description: The Niederschlag fluorite-barite vein deposit in the Western Erzgebirge, Germany, has been actively mined since 2013. We present the results of a first comprehensive study of the mineralogy, petrography, fluid inclusions, and trace element geochemistry of fluorite related to the Niederschlag deposit. Two different stages of fluorite mineralization are recognized. Stage I fluorite is older, fine-grained, associated with quartz, and forms complex breccia and replacement textures. Conversely, the younger Stage II fluorite is accompanied by barite and often occurs as banded and coarse crystalline open-space infill. Fluid inclusion and REY systematics are distinctly different for these two fluorite stages. Fluid inclusions in fluorite I reveal the presence of a low to medium saline (7–20% eq. w (NaCl+CaCl2)) fluid with homogenization temperatures of 140–180 °C, whereas fluorite II inclusions yield distinctly lower (80–120 °C) homogenization temperatures with at least two high salinity fluids involved (18–27% eq. w (NaCl+CaCl2)). In the absence of geochronological data, the genesis of the earlier generation of fluorite-quartz mineralization remains enigmatic but is tentatively related to Permian magmatism in the Erzgebirge. The younger fluorite-barite mineralization, on the other hand, has similarities to many fluorite-barite-Pb-Zn-Cu vein deposits in Europe that are widely accepted to be related to the Mesozoic opening of the northern Atlantic Ocean.
    Description: European Social Fund http://dx.doi.org/10.13039/501100004895
    Keywords: ddc:553.6 ; Fluorite ; Microthermometry ; Fluid inclusions ; Rare earth elements ; Geochemistry ; Metallogenesis ; Industrial minerals
    Language: English
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  • 10
    Publication Date: 2023-06-21
    Description: Ba zonation patterns in sanidine phenocrysts from mafic and intermediate phonolite and crystal-rich cumulates from the Laacher See volcano (12.9 ka) in western Germany document diffusion times suggestive of periodic recharge events throughout the magma reservoir’s entire lifespan of ~ 24 ky. Phenocrysts analysed from samples that formed late at the base of the compositionally zoned magma reservoir by mixing and mingling between a resident phonolite magma and recharging basanite show resorption and thin (2–10 μm) late-stage Ba-rich overgrowth. Short diffusion profiles across these boundaries give diffusion times of ~ 1.5–3 years at most, which are interpreted to be the maximum duration between the most recent recharge by the basanite and eruption. The lack of such late overgrowth in samples from other parts of the phonolite reservoir suggests that effect of this mixing and mingling was limited to the crystal-rich base. Sanidines in the cumulates, by contrast, are generally devoid of zoned crystals. Only rare cumulate crystals with resorbed outer boundaries and very thin overgrowths (a few microns) with very sharp compositional changes imply the remobilization of cumulates only months before eruption. Based on the diffusion timescales and storage temperatures obtained in a previous study, we present a genetic model for the conditions and timing of storage and (re-)activation of the magma system prior to the eruption of Laacher See, which is the largest volcanic event in Central Europe since the last glaciation.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Keywords: ddc:551.9 ; Laacher see ; Diffusion chronometry ; Barium ; BSE images ; Magma storage
    Language: English
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