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  • Other Sources  (229)
  • Elsevier  (229)
  • 1990-1994  (154)
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  • 1
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    Elsevier
    In:  Amsterdam, 432 pp., Elsevier, vol. 167, no. XVI:, pp. 385-389, (ISBN 1-56670-263-3)
    Publication Date: 1994
    Keywords: 93.1060 ; Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Textbook of geophysics ; Plate tectonics ; Fracture ; Tectonics ; Geol. aspects ; Rheology ; Stress ; cracks and fractures (.NE. fracturing) ; salt
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  • 2
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 31, no. 1, pp. 1-40, (ISBN 0-691-01019-6)
    Publication Date: 1994
    Keywords: Textbook of geophysics ; Geoelectrics ; Applied geophysics
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  • 3
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    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 177 (1). pp. 73-78.
    Publication Date: 2020-07-27
    Description: The periodicity of deposition of growth increments in the cuttlebone of juvenile Sepia officinalis was investigated under controlled conditions for a short period after hatching (19 days). The slope of time elapsed and increment counts was significantly different from 1 indicating that lamellae are not deposited on a daily basis. The relationship between increment counts and juvenile length was, however, highly significant. Also significant were the relationships between the number of growth increments and shell length and increment counts and cuttlebone area. These data show that the number of growth increments is related primarily to the growth rate of the juvenile rather than to its chronological age. Taking into account these data, the cuttlebone lamellae cannot be used for age determination in the juvenile cuttlefish just after hatching.
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  • 4
    Publication Date: 2018-06-15
    Description: The levels of four trace metals (Cd, Cu, Pb, and Zn) in the whole soft body and in different organs of the ocean quahog Arctica islandica were evaluated from four stations in Kiel Bay, Western Baltic. The relationships between the contents and concentrations of these metals and body size (weight and length) were also investigated. Double logarithmic plots of metal contents and concentrations against dry body weight and shell length, respectively, show straight-line relationships. The results indicate that smaller individuals have higher concentrations of Cu and Zn, two essential metals, while larger individuals have higher concentrations of Cd and Pb, two non-essential metals. The calculated regression slopes of metal content against dry-body weight revealed that Cd and Cu appear to be affected by maturation since two different slopes are observed for both metals before and after maturation. This was not obvious for Pb and Zn. Pooled slopes of metal content against dry-body weight for all animal sizes indicated that Cu and Zn have a one common slope of (0.82) and Cd and Pb another common one of (1.51). Plots of metal concentrations against shell length indicated also that Cu and Zn have one common slope of (−0.54) and Cd and Pb another one of (1.56). Moreover, it was possible to calculate one final slope of (1.53) for Cd and Pb from both content/weight and concentration/length plots. This indicates that A. islandica may have one metabolic strategy for the essential metals and another for the non-essential metals.
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  • 5
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    Elsevier
    In:  Aquaculture, 128 (1-2). pp. 143-152.
    Publication Date: 2017-05-11
    Description: A simple method of providing a regular supply of live food for the experimental culture of paralarval cephalopods is described. The primary food source utilized was hatched zoeae of large laboratory populations of the hermit crab, Pagurus prideaux. Zoeal size, swimming behaviour, and distribution in the water column make these zoeae a suitable live prey for rearing early post-hatching planktonic stages of cephalopods and probably other marine zooplanktivores. Ovigerous P. prideaux females were collected from the sea throughout the year at depths between 10 and 90 m in the NW Mediterranean and maintained at densities of up to 500 specimens · m−2. One month after spawning in aquaria, 38% of the females of P. prideaux started to incubate a second clutch of eggs. Other decapod crustacean species, such as Liocarcinus depurator and Dardanus arrosor, were maintained to use their zoeae as a food source for cephalopod paralarvae. P. prideaux zoeae were used as the sole or main food resource for rearing Loligo vulgaris and Octopus vulgaris, during the first 2 months of life. First feeding and initial growth in L. vulgaris and O. vulgaris paralarvae can be successfully stimulated using decapod zoeae with a total length equivalent to 50–100% of the cephalopod's mantle length.
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  • 6
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    Elsevier
    In:  Marine Pollution Bulletin, 28 (7). pp. 413-416.
    Publication Date: 2018-04-09
    Description: As long as salinity in the Baltic Sea was high (as it was between 1948 and 1982) the depth range between 70 and 100 m suffered frequent anoxia. However, when salinity was low and when the position of the halocline was deep (as it was in the first half of the century) oxygen conditions were good and long-lived macrofauna occurred. Should the present trend to lower salinities continue (building bridges across the Belt Sea and reducing salt water inflow would be helpful) one can foresee a recolonization by macrofauna in the depth range 70–100 m.
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  • 7
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    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 183 (1). pp. 41-52.
    Publication Date: 2019-09-23
    Description: The reproductive cycle of the sponge Halichondria panicea was investigated at Boknis Eck in the Western Kiel Bight over 2 yr, and over 1 yr on the island Helgoland in the North Sea and was compared with material collected earlier at Tjärnö at the Swedish west coast. Temperature and salinity were monitored at the different stations in order to determine whether different hydrographic conditions could be linked to differences in seasonal patterns of the reproductive cycle. The results showed H. panicea to be gonochoristic at all stations. The ratio of males to females varied between populations and years, but females predominated consistently. Comparison of the reproductive cycle in the years 1987 and 1989 at the brackish-water station Boknis Eck shows that high ambient winter and spring temperatures in 1989 resulted in a shorter period of oogenesis and earlier larval release, as compared to the year 1987. The reproductive cycle of the sponges at the fully marine station at Helgoland in 1989 and the brackish-water station at Tjärnö in 1978 under temperature and salinity conditions similar to those at Boknis Eck in 1989 showed the same seasonal pattern. We conclude that the lower salinities found at both Boknis Eck and Tjärnö do not cause a delay or slow-down of reproduction at these stations as compared to Helgoland. Under favourable temperature conditions, oogenesis was highly synchronous within the different populations, while it was more spread over time under the low ambient water temperatures at Boknis Eck in 1987.
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  • 8
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 41 (2). pp. 263-281.
    Publication Date: 2018-06-19
    Description: In the Deep Western Boundary Current (DWBC) mean velocities obtained by the F11/F12 dating method are far smaller (1–2 cm s−1) than direct velocity measurements (5–20 cm s−1). To resolve this discrepancy, a simple box model is presented that uses the ideas of Pickartet al. (1989, Physical Oceanography, 19, 940–951) to parametrize turbulent diffusion of the current with its surroundings. In contrast to previous models, however, the boundary conditions include all water masses forming the lower part of the DWBC (Denmark Strait Overflow Water, Iceland Scotland Overflow Water and Northeast Atlantic Water). The model-derived mean velocity of the DWBC leads to tracer concentrations that have to fit the observed F11 and F12 distributions, the F11/F12 ratios, and the tritium distributions. Moreover, the model area is extended from south of the Faroe bank along the continental margin of the American continent to 10°S. The model assumes uniform velocity and uniform turbulent mixing along the flow path of the DWBC, and enhanced turbulent mixing in the vicinity of the current compared to the ocean's interior allows the surrounding waters, which remain motionless, to accumulate tracers. The highest mean velocity of the DWBC, which results in model F12, F11, and 3H distributions as well as F11/F12 ratios, compatible to measurements of these tracers along the western boundary, are 4.8 cm s−1. Variations in the composition of the DWBC as well as changes in the time history of the source water masses do not increase the range of the model velocities.
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  • 9
    Publication Date: 2017-08-23
    Description: Planktic foraminifers Neogloboquadrina pachyderma (sin.) from 87 eastern and central Arctic Ocean surface sediment samples were analyzed for stable oxygen and carbon isotope composition. Additional results from 52 stations were taken from the literature. The lateral distribution of δ18O (Full-size image (〈1 K)) values in the Arctic Ocean reveals a pattern of roughly parallel, W-E stretching zones in the Eurasian Basin, each ∼0.5‰ wide on the δ18O scale. The low horizontal and vertical temperature variability in the Arctic halocline waters (0–100 m) suggests only little influence of temperature on the oxygen isotope distribution of N. pachyderma (sin.). The zone of maximum δ18O values of up to 3.8‰ is situated in the southern Nansen Basin and relates to the tongue of saline (〉 33%.) Atlantic waters entering the Arctic Ocean through the Fram Strait. δ18O values decrease both to the Barents Shelf and to the North Pole, in accordance with the decreasing salinities of the halocline waters. In the Nansen Basin, a strong N-S δ18O gradient is in contrast with a relatively low salinity change and suggests contributions from different freshwater sources, i.e. salinity reduction from sea ice meltwater in the south and from light isotope waters (meteoric precipitation and river-runoff) in the northern part of the basin. North of the Gakkel Ridge, δ18O and salinity gradients are in good accordance and suggest less influence of sea ice melting processes. The δ13C (Full-size image (〈1 K)) values of N. pachyderma (sin.) from Arctic Ocean surface sediment samples are generally high (0.75–0.95‰). Lower values in the southern Eurasian Basin appear to be related to the intrusion of Atlantic waters. The high δ13C values are evidence for well ventilated surface waters. Because the perennial Arctic sea ice cover largely prevents atmosphere-ocean gas exchange, ventilation on the seasonally open shelves must be of major importance. Lack of δ13C gradients along the main routes of the ice drift from the Siberian shelves to the Fram Strait suggests that primary production (i.e. CO2 consumption) does probably not change the CO2 budget of the Arctic Ocean significantly.
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  • 10
    Publication Date: 2016-04-08
    Description: Two major meltwater events are documented in cores from the NW Labrador Sea. One occurred ca. 20,000 14C yr B.P. in association with deposition of a major detrital carbonate unit. Both prior to and after this event, δ18O values of near-surface planktonic foraminifera were 4.5%, indicating fully enriched glacial values. A younger event (ca. 14,000 14 C yr B.P.) is characterized by a dramatic change in δ18O from 4.5 to 2.0% and coincided with the retreat of ice from the outer SE Baffin Shelf, possibly into Hudson Strait. These meltwater events coincide with Heinrich (H) layers 1 and 2 from North Atlantic sediments. The 14,000 14C yr B.P. meltwater event indicates that the eastern margin of the Laurentide Ice Sheet also underwent rapid retreat at approximately the same time as other ice sheet margins around the NE North Atlantic. A third major detrital carbonate event at the base of HU87-033-009, possibly correlative with Heinrich layer 3, occurred ca. 33,960 ± 675 14 C yr B.P.; however, this is older than the accepted date for H-3 of 27,000 14C yr B.P. and may be H-4.
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  • 11
    Publication Date: 2019-09-24
    Description: For over thirty years man has studied “outer space” and installed satellites which watch the surface of the Earth. The great depths of the world ocean are, however, practically unknown and there is an urgent need to put abyssal benthic laboratories into “inner space” in order to study basic phenomena of interest to marine science and climatology as well as man's impact on the oceans. In view of the numerous problems related to global change, as a first step emphasis should first be on the role of the oceans and their inherent processes, which are the focus of such international programmes as the World Ocean Circulation Experiment (WOCE) and the Joint Global Ocean Flux Study (JGOFS). Multi-disciplinary registration of key events at selected key sites investigating the variability in time and space are of the utmost importance. The same methods and techniques must be used for the study of human impacts on the deep oceans caused by mining of metalliferous resources and by waste disposal as well as in basic studies. However, the investigation of the inner space of our planet has certain requirements. As long-term and large-scale investigations become more and more important, development of automized systems, largely independent from research vessels will be required. This will demand high capacities of energy for all technical functions as well as high storage capacities for data and samples. As a consequence the needs for two different—although overlapping—functional approaches are defined for future deep-sea deployments. (A) A system for long-term registration of the natural variability and long-term monitoring of human impacts: (B) A system for short-term observations and short-time experimentations. This report summarizes their technological demands. The envisioned interdisciplinary technology should deliver information on physical, biological and geochemical processes and their variabilities in the deep oceans. The prospected systems need to have the ability for real time video observation, data transfer and experimental manipulation, as well as sensing and sampling facilities with large storage capacities for long-term deployments. Prospective costs of the described multipurpose abyssal benthic laboratory will presumably exceed the funds for deep-sea research of a single country. A joint European effort could solve this problem and help to manifest a leading role for European marine science in international deep-sea and global change research.
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  • 12
    Publication Date: 2017-09-26
    Description: Three groups of REE patterns are observed for the sandstones and shales of the Middle Ordovician Austin Glen Member of the Normanskill Formation. One sandstone sample is enriched in middle and light rare earth elements. The majority of samples are light rare earth element (LREE) enriched with negative Eu-anomalies and flat heavy rare earth elements (HREEs), whereas a third group appears to have lost LREEs and middle rare earth element (MREEs). Homogeneous neodymium isotopic compositions for all samples at about the time of deposition, ϵNd (470 Ma) = −8.2 ± 1.1(2SD), indicate that the source of the Austin Glen Member was well mixed and that the neodymium had a long-term enriched history. The differences in the shape and abundances of the REE patterns combined with the neodymium isotope characteristics of the samples lead us to the conclusion that samarium and neodymium were fractionated and that the neodymium isotopic system might have been disturbed at about the time of deposition (470 Ma). Most samples appear to have been affected by this process. The two most altered shales lost about half of their neodymium and their ratios are higher than the ratios of average shales. These two shales give clearly erroneous mantle-extraction ages, but the average TDM of the provenance can still be deduced (1700–1800 Ma) from the least disturbed sandstones with normal upper crustal ratios. Accordingly, this study demonstrates that the REEs may be transported and neodymium isotopes may be reequilibrated under certain sedimentary conditions (e.g., diagenesis). However, in spite of evidence for REE redistribution, provenance information (TDM, original REE patterns) may still be inferred.
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  • 13
    Publication Date: 2019-09-23
    Description: The winter ice-regime of the 〈80 km wide Alaskan Beaufort Sea shelf is characterized by compression and shearing, resulting in the formation of major grounded pressure ridge systems stabilizing the fast ice on the mid-shelf, and essentially no open-water areas. In contrast, the winter ice-regime of the 500-km wide Laptev Sea shelf is controlled by winds blowing from land to sea, and is therefore dilational. A perennial polynya borders the hundreds of kilometers-wide and very smooth fast ice offshore. In this body of open water, rapidly forming ice is continuously advected offshore by the mean wind field, making the Laptev Sea the single major ice factory for the Arctic Ocean and Transpolar Drift. Conversely, with summer warming this dark polynya turns into an area of high heat gain, which results in the retreat of the ice edge to a much higher latitude and greater distance (〉500 km) from the mainland than in the Beaufort Sea. As a result, the annual freeze-up does not incorporate old, deep-draft ice, and with a lack of compression, such deep-draft ice is not generated in situ, as on the Beaufort Sea shelf. The Laptev Sea has as much as 1000 km of fetch at the end of summer, when freezing storms move in and large (6 m) waves can form. Also, for the first three winter months, the polynya lies inshore at a water depth of only 10 m. Turbulence and freezing are excellent conditions for sediment entrainment by frazil and anchor ice, when compared to conditions in the short-fetched Beaufort Sea. We expect entrainment to occur yearly. Different from the intensely ice-gouged Beaufort Sea shelf, hydraulic bedforms probably dominate in the Laptev Sea. Corresponding with the large volume of ice produced, more dense water is generated in the Laptev Sea, possibly accompanied by downslope sediment transport. Thermohaline convection at the midshelf polynya, together with the reduced rate of bottom disruption by ice keels, may enhance benthic productivity and permit establishment of open-shelf benthic communities which in the Beaufort Sea can thrive only in the protection of barrier islands. Indirect evidence for high benthic productivity is found in the presence of walrus, who also require year-round open water. By contrast, lack of a suitable environment restricts walrus from the Beaufort Sea, although over 700 km farther to the south. We could speculate on other consequences of the different ice regimes in the Beaufort and Laptev Seas, but these few examples serve to point out the dangers of exptrapolating from knowledge gained in the North American Arctic to other shallow Arctic shelf settings.
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  • 14
    Publication Date: 2018-01-17
    Description: Biometric analyses on shells of Turborotalita quinqueloba (Natland) reflect the paleoceanographic conditions in the Norwegian-Greenland Sea (NGS). Both median and mean size variations exhibit a steady increase after the Last Glacial Maximum (LGM). After Termination I the size eventually reaches a constant level with only minor fluctuation. In contrast, peak abundances of specimens occur somewhat later, during the Holocene climatic optimum and rapidly decrease again in the youngest sediments. Test sizes are larger at the Vøring Plateau in the vicinity of incoming Atlantic water than in water further to the west. Turborotalita quinqueloba first appeared in the southwestern part of the NGS with a preliminary major peak in abundance and size well below the Younger Dryas. This species was present in sizes 〈 125 μm in this area during almost entire oxygen isotopic Stage 2. This was not observed in the more easterly located cores. It seems likely that size variations as a ‘tool’ for NGS paleoceanographic interpretations are not only valuable for the time since the LGM, but can also be applied to older isotopic stages where abundances of T. quinqueloba are low or absent in the 〉 125 μm size-fractions but are high in the 63–125 μm fraction (e.g. Stages 7, 9 and 11).
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  • 15
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    Elsevier
    In:  Review of Palaeobotany and Palynology, 80 (3-4). pp. 209-234.
    Publication Date: 2016-09-14
    Description: Among living green algae assigned to the order Chlorococcales and order Zygnematales certain species develop resistant outer organic walls and/or cysts during their life cycles: as such they have the potential to become fossils. Based on morphology,comparison between living algae and microfossil remains are made with varying degrees of confidence, and a possible evolutionary pathway for certain chlorococcalean coenobial families is suggested. Twelve genera are reviewed from earliest to latest Triassic palynological assemblages from northwestern Australia; and the following taxa are described as new: Plaesiodictyon mosellanum ssp. symmetricum ssp. nov.; Plaesiodictyon mosellanurn ssp. variabile ssp. nov.; Plaesiodictvon decussatus sp. nov.: Plaesiodico'on decussatus ssp. decussatus ssp. nov.; Plaesiodictyon decussatus ssp. tetracornuta ssp. nov.; Tetraporina protrusa sp. nov.: Crucigeniella? torques sp. nov.; and Paleoraphidia akestra gen. et sp. nov. (type). Their suggested natural affinities are useful in palaeoenvironmental interpretations of mostly freshwater or low-salinity habitats.
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  • 16
    Publication Date: 2017-05-30
    Description: A method is presented to determine the extent of iron complexation by natural organic ligands in seawater. Catalytic cathodic stripping voltammetry (CSV) is used to take advantage of ligand competition between the added ligand, 1-nitroso-2-napthol (NN), and natural ligands present in seawater. The conditional stability constant for the complexation of iron by NN was calibrated for salinities between 1 and 36 using ligand competition with EDTA. The values of log K'(Fe(NN))3 (valid for pH 6.9 seawater) were found to vary linearly with log salinity according to log K'(Fe(NN))3 = - 1.04 +/- 0.08 log(salinity) + 30.12 +/- 0.09. The detection window, defined by the iron complexing ability of NN was altered by varying the concentration of NN. Preliminary measurements of iron complexing ligands in samples from coastal and open oceanic origin revealed the presence of natural complexing ligands at concentrations higher than that of total dissolved iron. The stability constants for the complexes were high, log K'(FeL) falling within the range of 18.8-21.2, indicating that by far the greatest component (99%) of the dissolved iron occurs organically complexed in pH 6.9 seawater. Model calculations showed that it is possible that the organic fraction may be somewhat less at a pH value near 8.
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  • 17
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    Elsevier
    In:  Earth and Planetary Science Letters, 125 (1-4). pp. 105-118.
    Publication Date: 2016-11-14
    Description: To investigate the growth rates and absolute time stratigraphy of marine hydrogenetic ferromanganese encrustations, we performed 10Be profiling and ‘Co chronometry’ of crustal layers, as well as 87Sr86Sr and δ18O analysis of phosphatised limestone (francolite) within a ∼ 9.5 cm thick ferromanganese crust from Schumann Seamount in the Hawaiian Archipelago. Together with microfossil stratigraphy, our results indicate that some seamount crusts greatly exceed the commonly accepted Miocene maximum age, in this case probably approaching the Cretaceous age of the seamount. In addition to the unconformity at the crust-substrate boundary, at least eight major disconformities are indicated in the Schumann Seamount crust which probably represent depositional hiatuses or episodes of crust erosion. Three of the six upper disconformities can be placed at the Plio-Pleistocene, Middle Miocene and Paleocene-Eocene based on 10Be, microfossil and Co chronometer evidence. 87Sr86Sr and δ18O values of purified francolite from an inclusion-rich layer between the depths of 44 and 49 mm suggest apparent ages that approach those of Eocene-Late Paleocene microfossils reported in overlying layers, whereas francolite vein infillings in the lower part of the crust and in the basaltic substrate yield values that, if interpreted as ages of phosphatization, suggest a minimum Oligocene age. Paleotracking suggests the phosphogenesis observed here and on other Central Pacific seamounts could not have resulted from upwelling enhanced productivity associated with equatorial divergence if the Oligocene and Middle Miocene isotopic ages reported here and elsewhere are correct; however, a maximum Late Paleocene age for the phosphogenesis, consistent with the stratigraphy, would place these seamounts within 10°N of the equator. Paleotracking also suggests northeast tradewind transport of aluminosilicates in the Cenozoic, in agreement with other evidence for the antiquity of this ferromanganese crust.
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  • 18
    Publication Date: 2017-12-06
    Description: We present comprehensive geochemical analyses on samples from the active volcanoes of the Society and Austral hotspot chains, including data for major, trace and rare-earth elements, and Sr, Nd, Pb and Th isotopes. The latter can be used to determine the Th/U in the source at the time of melting, and so give a constraint on the absolute amount of incompatible-element fractionation occurring during melting. SiO2 vs. MgO variations show evidence for variable amounts of a nephelinitic melt component (low SiO2, low MgO) in all the magmas studied. The nephelinite is probably produced in the presence of CO2 during melting. Correlations between SiO2 and the degree of ThU fractionation (derived from Th isotope measurements) imply that the CO2-driven, nephelinitic melting is also responsible for fractionating the Th/U ratio. Comparing the Th isotopes with Sr, Nd and Pb isotopes, it is possible to place limits on the Th/U ratios in the EM II (Societies) and HIMU (Australs) sources. These are ∼ 3.4 and ⩽ 2.5, respectively. The Nb/U ratio, which was previously thought to be relatively constant in all oceanic volcanics (47 ± 10), is shown to be anomalously low (25 ± 5) in some of the Society Seamounts and high (60) in some of the Australs. This confirms the presence of continent-derived material in the Society source and suggests that HIMU volcanics may have elevated Nb/U ratios. The change in Pb isotope compositions in the Australs, from HIMU (e.g., Tubuai) before 6 Ma to the more recent, less extreme compositions seen for example at Macdonald, is the result of a small amount of subducted sediment contaminating the pure old recycled oceanic crust component which, before 6 Ma, yielded HIMU.
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  • 19
    Publication Date: 2016-09-20
    Description: About 73% of the water exchange between the Baltic and the North Seas is via the Darss Sill. Joint Danish and German marine geological investigations, including shallow seismic surveys and sediment sampling, have been carried out in the Darss Sill area between 1989 and 1991. Results from these studies and unpublished archive data from the Institute of Baltic Sea Research, Warnemünde, are presented. These show that the entire Quaternary sedimentary sequence in most of the area is at least 40 m thick. A zone of glacial till outcropping between Denmark and Germany belongs to the Late Weichselian ice marginal line G (“Velgaster Staffel”). The formation of this line caused the damming of a pre-existing (sub)glacial meltwater discharge system. At the beginning of the Baltic Ice Lake formation, a deep and presently buried channel incised in this ice marginal line was part of a (glacio)fluvial drainage system with discharge towards the northeast, i.e. into the Baltic Ice Lake. During the Baltic Ice Lake transgression damming of the Darss Sill occurred due to accumulation of sandy sediments within this channel. On the other hand, the recent Kadet Channel was only occasionally overflown during the Baltic Ice Lake highstand maximum, which was 18 m BSL (below present sea level) in the Darss Sill area. The main erosion and deepening of the Kadet Channel began during the Ancylus Lake highstand maximum. At present, sediment transport on the Darss Sill is governed by northeasterly inflow of saline bottom waters in the entire area from the Kadet Channel to the German coast. Baltic outflow affects the seabed at shallower depth in the Danish sector. Large-scale current-induced bedforms in the area include, amongst others, sandwaves with a height of 5 m. Changes of the bedforms observed indicate a maximum bottom flow speed of 70–100 cm s−1, both for inflow and for outflow.
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  • 20
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    Elsevier
    In:  Deep-Sea Research Part II-Topical Studies in Oceanography, 41 . pp. 307-324.
    Publication Date: 2016-10-10
    Description: Measurements of the chlorofluorocarbons (CFCs), F11 (CCl3F) and F12 (CCl2F2) were made during the Shelf Edge Exchange Processes II (SEEP-II) experiment in the Middle Atlantic Bight during 1988–1989. These compounds undergo large seasonal variations in surface water concentration as a result of temperature-induced solubility changes. Outgassing in summer produces vertical concentration gradients that can be exploited to estimate a cross-pycnocline vertical eddy-diffusivity suitable for biogeochemical flux calculations. Model results based on an exploratory study suggest an average Kz of 1 × 10−5 m2 s−1 for this region during the stratified period. CFCs have advantages over other budget approaches for studying mixing processes, including heat budgets, as there are no internal sources or sinks other than air-sea gas exchange. In order to exploit further the CFC budget of sub-pycnocline shelf waters, regular cruises through the summer months and characterization of CFC levels at the time of stratification are required.
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  • 21
    Publication Date: 2016-10-10
    Description: The Shelf Edge Exchange Processes II (SEEP-II) program was designed to examine the potential for export of organic carbon from the continental shelf to the deeper ocean. In the Middle Atlantic Bight of the east coast, U.S.A., a “cold pool” of relict winter water is isolated by the development of a strong seasonal thermocline on the shelf. Oxygen concentrations were monitored in and above the cold pool from March 1988 to May 1989, with electrodes moored at 19 and 38 m at a 42-m station off the Delmarva Peninsula, eastern U.S.A. An oxygen-flux simulation model was constructed to describe long-term changes in oxygen concentration and saturation. The model utilized biological rate and biomass measurements obtained at the mooring location during cruises. Vertical eddy diffusion was constrained by comparison with the redistribution of chlorofluorocarbons and heat after stratification, and by sensitivity analyses. Model predictions of the average daily change in oxygen concentration and saturation at 38 m were in good agreement with average changes recorded by moored oxygen sensors, when biological generation of oxygen was approximately equal to the thermotrophic consumption. Strong, but transient, fluctuations concentration and saturation were clearly associated with specific advective events, and had little lasting impact on the overall long-term trends. Consequently, model parameters derived from intermittent, cruise-based observations yielded satisfactory predictions of long-term trends. A carbon budget was constructed for the stratified summer period from data that largely overlapped with those used for the oxygen model. The continental shelf ecosystem operates in approximate balance during the summer, with a potential export of no more than 4% of primary production.
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  • 22
    Publication Date: 2019-09-23
    Description: Despite the Arctic sea ice cover's recognized sensitivity to environmental change, the role of sediment inclusions in lowering ice albedo and affecting ice ablation is poorly understood. Sea ice sediment inclusions were studied in the central Arctic Ocean during the Arctic 91 expedition and in the Laptev Sea (East Siberian Arctic Region Expedition 1992). Results from these investigations are here combined with previous studies performed in major areas of ice ablation and the southern central Arctic Ocean. This study documents the regional distribution and composition of particle-laden ice, investigates and evaluates processes by which sediment is incorporated into the ice cover, and identifies transport paths and probable depositional centers for the released sediment. In April 1992, sea ice in the Laptev Sea was relatively clean. The sediment occasionally observed was distributed diffusely over the entire ice column, forming turbid ice. Observations indicate that frazil and anchor ice formation occurring in a large coastal polynya provide a main mechanism for sediment entrainment. In the central Arctic Ocean sediments are concentrated in layers within or at the surface of ice floes due to melting and refreezing processes. The surface sediment accumulation in central Arctic multi-year sea ice exceeds by far the amounts observed in first-year ice from the Laptev Sea in April 1992. Sea ice sediments are generally fine grained, although coarse sediments and stones up to 5 cm in diameter are observed. Component analysis indicates that quartz and clay minerals are the main terrigenous sediment particles. The biogenous components, namely shells of pelecypods and benthic foraminiferal tests, point to a shallow, benthic, marine source area. Apparently, sediment inclusions were resuspended from shelf areas before and incorporated into the sea ice by suspension freezing. Clay mineralogy of ice-rafted sediments provides information on potential source areas. A smectite maximum in sea ice sediment samples repeatedly occurred between 81°N and 83°N along the Arctic 91 transect, indicating a rather stable and narrow smectite rich ice drift stream of the Transpolar Drift. The smectite concentrations are comparable to those found in both Laptev Sea shelf sediments and anchor ice sediments, pointing to this sea as a potential source area for sea ice sediments. In the central Arctic Ocean sea ice clay mineralogy is significantly different from deep-sea clay mineral distribution patterns. The contribution of sea ice sediments to the deep sea is apparently diluted by sedimentary material provided by other transport mechanisms.
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  • 23
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    Elsevier
    In:  Journal of Marine Systems, 5 (6). pp. 411-423.
    Publication Date: 2017-06-26
    Description: Vertical flux of particulate material was recorded with moored sediment traps during 1988/1989 in the Greenland Sea at 72 degrees N, 10 degrees W. This region exhibits pronounced seasonal variability in ice cover. Annual fluxes at 500 m water depth were 22.79, 8.55, 2.39, 3.81 and 0.51 g m(-2) for total flux (dry weight), carbonate, particulate biogenic silicate, particulate organic carbon and nitrogen, respectively. Fluxes increased in April, maximum rates of all compounds occurred in May-June, and consistently high total flux rates of around 100 mg m(-2)d(-1) prevailed during the summer. The increasing flux of biogenic particles measured in April is indicative of an early onset of algal growth in spring. Small pennate diatoms dominated in the trap collections during April, and were still numerous during the high flux period when Thalassiosira species were the most abundant diatoms. During May-June, up to 22% of the Thalassiosira cells collected were viable-looking cells. The faecal pellet flux increased after the May-June event. Therefore we conclude that the diatoms settled as phytodetritus, most likely in rapidly sinking aggregates. From seasonal nutrient profiles it is concluded that diatoms contribute 25% to new production during spring and 50% on an annual basis. More than 50% of newly produced silicate particles are dissolved above the 500 m horizon. High new production during spring does not lead to a pronounced sedimentation pulse of organic matter during spring but elavated vertical export is observed during the entire growth period
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  • 24
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 41 (7). pp. 1053-1068.
    Publication Date: 2018-01-17
    Description: The mean residence time of river-runoff on the shelves and in the halocline of the Arctic Ocean is estimated from salinity and tracer data (tritium, 3He and the 18O/16O ratio). These estimates are derived from comparison of apparent tracer ages of the halocline waters using a combination of tracers that yield different information: (1) the tritium “vintage” age, which records the time that has passed since the river-runoff entered the shelf; and (2) the tritium/3He age, which reflects the time since the shelf waters left the shelf. The difference between the ages determined by these two methods is about 3–6 years. Correction for the initial tritium/3He age of the shelf waters (about 0.5–1.5 years) yields a mean residence time of the river-runoff on the shelves of the Siberian Seas of about 3.5 ± 2 years.
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  • 25
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    Elsevier
    In:  Marine Geology, 121 (1-2). pp. 121-128.
    Publication Date: 2016-06-23
    Description: Two cores recovered in the Greenland Sea contain aggregates (up to 5 cm in diameter) of poorly sorted coarse-grained material. Their lithologic and biogenic content, in addition to the grain size and grain shape, indicate that they are related to till balls. It is possible that they formed in a fluvial or nearshore environment (perhaps in Greenland or Siberia), were frozen into fast ice, and were then transported by sea ice-rafting to their present location. Since the balls were still partly frozen, they could survive the 2000 m drop through the water column to the seafloor.
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  • 26
    Publication Date: 2019-05-14
    Description: A combined high resolution seismic, sub-bottom profiling, and multi-beam echo-sounding survey in the Skagerrak (Danish sector of the North Sea) together with gas analyses at a station along the profile exhibit the expulsion of gas (mainly methane) and the presence of gas-charged sediments at shallow depth. The echo-soundings yield detailed insight into the distribution and shape of typical sea-floor features associated with gas seepage, such as pockmarks. The pockmarks reach dimensions of 800 m in length, 300 m in width, and 15 m in depth, with the long axis running parallel to the slope of the Norwegian Trench. Processing of the multi-channel high resolution seismic data and the digitally recorded sub-bottom profiler signals indicate an internal compressional velocity of about 1050 m s-1 within the gas-charged sediments reaching from the sea-floor to a sub-bottom depth of about 23 m. Using the lateral distribution and thickness of the gas-charged sediments in conjunction with a mean concentration of gas of 3000 ppb, the present amount of trapped gas is estimated to be 6·45 × 1011 g CH4. The flux of methane through the sea-bed into the water column appears to be 7·2 × 1010 g CH4 per year. To explain the small difference in size between the methane pool in near-surface sediments and the annual flux through the sea-bed, a constantly high supply of methane from leaking hydrocarbon reservoirs at greater depths has to be active.
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  • 27
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    Elsevier
    In:  Analytica Chimica Acta, 284 (3). pp. 463-471.
    Publication Date: 2020-06-03
    Description: An automated and semi-intelligent voltammetric system is described for trace metal analysis. The system consists of a voltammeter interfaced with a personal computer, a sample changer, 2 peristaltic pumps, a motor burette and a hanging mercury drop electrode. The system carries out fully automatically approximately 5 metal determinations per hour (including at least 3 repetitive scans and calibration by standard addition) at trace levels encountered in clean sea water. The computer program decides what level of standard addition to use and evaluates the data prior to switching to the next sample. Alternatively, the system can be used to carry out complexing ligand titrations with copper whilst recording the labile copper concentration; in this mode up to 8 full titrations are carried out per day. Depth profiles for chromium speciation in the Mediterranean Sea and a profile for copper complexing ligand concentrations in the North Atlantic Ocean measured on board-ship with the system are presented. The chromium speciation was determined using a new method to differentiate between Cr(III) and Cr(VI) utilizing adsorption of Cr(III) on silica particles.
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  • 28
    Publication Date: 2020-06-03
    Description: The use of in-line UV-digestion for breakdown of dissolved organic matter (DOM), prior to voltammetric determination of trace metals in natural samples, is discussed in this paper. Destruction of DOM is necessary to free trace metals that are organically complexed and to remove interfering organic surfactants. Complete breakdown of DOM in natural water samples is achieved by in-line UV-digestion using a 100 W medium pressure mercury vapour lamp and a silica coil, at a sample digestion time of 4.5 min. The efficiency of the system is tested with destruction of humic acid, conversion of Cr(III) to Cr(VI), and the release of Ni and Cu from organic complexes in sea water. The in-line application of UV is illustrated by automated voltammetry of nanomolar levels of Cu and Ni in samples from oceanic origin.
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  • 29
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    Elsevier
    In:  TrAC - Trends in Analytical Chemistry, 13 (9). pp. 348-352.
    Publication Date: 2020-05-04
    Description: Instrumentation and methods are described for collecting surface sea water using pumping with subsequent in-line analysis by stripping voltammetry or chronopotentiometry. The review is illustrated with data for estuarine copper and nickel, and the distribution of nickel in Liverpool Bay.
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  • 30
    Publication Date: 2019-06-11
    Description: Geochemical and Sr, Pb, O and C isotopic data are reported for carbonatite samples from five locations in southeast Brazil. Elemental abundances and δ13CPDB data (between −5.8 and −7.2‰) prove that all the samples are derived from the mantle. Dupal isotopic characteristics in the all carbonatite samples from five locations in southeast Brazil are found in this study, characteristics that have not previously been recognized in carbonatites. Brazilian carbonatites possess average values of between 101 and 145, average values of between 5.2 and 10.3, and initial Sr isotopic compositions of between 0.7046 and 0.7062. The Brazilian carbonatites comprise two groups: The northern group is coincident with the passage of the Trindade non-Dupal hotspot at ca. 80 Ma, while the southern group mainly corresponds to the passage of the Tristan de Cunha Dupal hotspot at ca. 130 Ma. Although we expected a geochemical correlation between the Brazilian carbonatites and the South Atlantic hotspots, the enriched isotopic signature (EM1) of all the carbonatite samples is similar to that of alkali basalts on Tristan de Cunha. The combined OSr isotopic diagram indicates that the southern group carbonatites have negligible or only slight crustal contamination. The northern group samples show significantly higher δ18OSMOW values of 9–14‰, more radiogenic Pb isotopic ratios, and a value of 0.705. Even if these signatures are derived from the contamination of a lower crustal component with mantle sources, it is clear that the parental magma also has inherent EM1 isotopic characteristics. The interpretation of the origin of EM1 in the Brazilian carbonatites (subcontinental lithospheric mantle vs. asthenosphere) is dependent on the model of Paraná volcanism at ca. 130 Ma, which remains controversial. One possibility is that both the northern and southern carbonatites came from enriched SCLM under a part of Gondwanaland. In this case, a hotspot would provide the thermal energy to melt the lithospheric source region for both the Paraná flood basalts and the alkali carbonatitic volcanism. Another possibility is that the source of the northern carbonatites is also the Tristan plume carbonate-rich material which had once been trapped under the crust and reactivated by the Trindade hotspot, on the assumption that Paraná volcanism at ca. 130 Ma was mainly triggered by the huge Tristan plume activity. If anything, we favour the latter and believe an asthenospheric mantle plume origin for both the ultimate carbonate source and the Dupal anomaly in the Brazilian carbonatites.
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  • 31
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    Elsevier
    In:  Fisheries Research, 21 . pp. 1-15.
    Publication Date: 2021-01-19
    Description: The aims of this project were to improve understanding of the basic life.cycle biology, stock structure, trophic interactions and fisheries exploitation of northeast Atlantic squid, in particular the loliginids Loligo forbesi and Loligo vulgaris. Multivariate analysis of morphometric data and isozyme electrophoresis shows that L. forbesi populations from the coast of mainland Europe are fairly homogeneous, but that those from the Azores are a distinct stock. Loligo forbesi and L. vulgaris are annual species with a peak of breeding in the winter (December-May) throughout the geographical range, and one or more seasonal peaks of recruitment. Loligo are probably batch spawners. Males grow larger than females, mature about 1 month earlier and recruit earlier to the fishery. Sexual maturity occured at two distinct size classes, more obviously in males than females. Fish, including many cimmercially important species, and Crustacea, were the dominant prey of Loligo. The incidence of fish in the diet increases with squid size. Squid of all types are eaten by fish, seals, cetaceans and seabird, although quantitative estimates of consumption by these trophic levels were low. Catches of squid from northeast Atlantic waters increased over the period 1980-1990 but currently supply only a minor component of the European market for squid, the balance being made up by imports. The squid catch in the northern part of the range shows wide fluctuations in abundance by area and by season. The applicability of assessment methods for these stocks is limited by inadequate and inaccurate statistical information, and because nearly all of the catch arises by-catch from finfisheries.
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  • 32
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    Elsevier
    In:  Netherlands Journal of Sea Research, 33 (1). pp. 57-63.
    Publication Date: 2018-08-14
    Description: Studies on dormant resting cysts of the dinoflagellates Scrippsiella lachrymosa Lewis 1991 and S. trifida Lewis 1991 from Recent North Sea sediments suggest that their motile forms, which have not yet been officially recorded in this area till now, are common members of the North Sea plankton community. Cyst surveys offer avenues to overcome problems in spatial and temporal distributions and in taxonomy, and will help the compilation of a phytoplankton inventory in an area.
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  • 33
    Publication Date: 2019-09-23
    Description: The present paper reviews the literature related to the life cycle of the prymnesiophyte Phaeocystis and its controlling factors and proposes novel hypotheses based on unpublished observations in culture and in the field. We chiefly refer to P. globosa Scherffel as most of the observations concern this species. P. globosa exhibits a complex alternation between several types of free-living cells (non-motile, flagellates, microzoopores and possibly macrozoospores) and colonies for which neither forms nor pathways have been completely identified and described. The different types of Phaeocystis cells were reappraised on the basis of existing microscopic descriptions complemented by unpublished flow cytometric investigations. This analysis revealed the existence of at least three different types of free-living cells identified on the basis of a combination of size, motility and ploidy characteristics: non-motile cells, flagellates and microzoospores. Their respective function within Phaeocystis life cycle, and in particular their involvement in colony formation is not completely understood. Observational evidence shows that Phaeocystis colonies are initiated at the early stage of their bloom each by one free-living cell. The mechanisms controlling this cellular transformation are still uncertain due to the lack of information on the overwintering Phaeocystis fomms and on the cell type responsible for colony induction. The existence of haploid microzoospores released from senescent colonies gives however some support to sexuality involvement at some stages of colony formation. Once colonies are formed, at least two mechanisms were identified as responsible of the spreading of colony form: colony multiplication by colonial division or budding and induction of new colony from colonial cells released in the external medium after colony disruption. The latter mechanism was clearly identified, involving at least two successive cell differentiations in the following sequence: motility development, subsequent flagella loss and settlement to a surface, mucus secretion and colony formation, colonial cell division and colony growth. Aggregate formation, cell motility development and subsequent emigration from the colonies, release of non-motile cells after colony lysis on the other hand, were identified as characteristics for termination of Phaeocystis colony development. These pathways were shown to occur similarly in natural environments. In the early stages of the bloom however, many recently-formed colonies were found on the setae of Chaetoceros spp, suggesting this diatom could play a key-rôle in Phaeocystis bloom inception. Analysis of the possible environmental factors regulating the transition between the different phases of the life cycle, suggested that nutrient status and requirement of a substrate for attachment of free-living cells would be essential for initiation of the colonial form. Physical constraints obviously would be important in determining colony shape and fragmentation although autogenic factors cannot be excluded. Some evidence exists that nutrients regulate colony division, while temperature and nutrient stress would stimulate cell emigration from the colonies.
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  • 34
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    Elsevier
    In:  Continental Shelf Research, 14 (4). pp. 385-399.
    Publication Date: 2018-08-17
    Description: The Bass Strait cascade is a wintertime downwelling caused by cooling of the shallow waters of Bass Strait. During winter, a front separates the cold shelf water from the waters of the Tasman Sea. Continuous horizontal bands of downwelled water leading oceanward beneath the front imply that it can be transgressed near the bottom anywhere along its length. However, by far the greatest volume crosses at a breach at the northern end. Measured currents in eastern Bass Strait fit a predictable pattern: eastward toward the front, then as the front is approached, swinging north towards the breach. Flow northwards along the slope after downwelling is quantified using a simple analytic model. Cascade water found in the “far-field” was found only in small patches. One such patch was found to possess motion independent from the mean flow in which it was embedded.
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  • 35
    Publication Date: 2018-03-21
    Description: This chapter throws the attention on the meiobenthos of the deep northeast Atlantic. The main purpose of this chapter is to summarize new results from an area lying between 15°N and 53°N and extending from the continental margin of western Europe and northwest Africa to the Mid-Atlantic Ridge. It considers first the nature and scope of meiofaunal research in the northeast Atlantic and then discuss the environmental parameters, which are believed to influence meiofaunal organisms. This chapter then discusses the various types and scales of pattern observed among meiofaunal populations within the study area, progressing from the large-scale bathymetric and latitudinal trends and then to small-scale horizontal patterns within particular areas. Faunal densities and faunal composition are considered separately and compared with data from other regions. This chapter also deals with the distribution of meiofauna within sediment profiles and the temporal variability of populations. This chapter concludes by discussing the recent review of deep-sea meiofauna, which focused mainly on the abundance and biomass data from different oceans and on the relationship between the biomass of the meiofauna and that of other faunal components
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  • 36
    Publication Date: 2018-03-08
    Description: The 10Be records of four sediment cores forming a transect from the Norwegian Sea at 70°N (core 23059) via the Fram Strait (core 23235) to the Arctic Ocean at 86°N (cores 1533 and 1524) were measured at a high depth resolution. Although the material in all the cores was controlled by different sedimentological regimes, the 10Be records of these cores were superimposed by glacial/interglacial changes in the sedimentary environment. Core sections with high 10Be concentrations ( 〉 1 · 109 at/g) are related to interglacial stages and core sections with low10Be concentrations ( 〈 0.5 · 109 at/g) are related to glacial stages. Climatic transitions (e.g., Termination II, 5/6) are marked by drastic changes in the 10Be concentrations of up to one order of magnitude. The average 10Be concentrations for each climatic stage show an inverse relationship to their corresponding sedimentation rates, indicating that the 10Be records are the result of dilution with more or less terrigenous ice-rafted material. However, there are strong changes in the 10Be fluxes (e.g., Termination II) into the sediments which may also account for the observed oscillations. Most likely, both processes affected the 10Be records equally, amplifying the contrast between lower (glacials) and higher (interglacials) 10Be concentrations. The sharp contrast of high and low 10Be concentrations at climatic stage boundaries are an independent proxy for climatic and sedimentary change in the Nordic Seas and can be applied for stratigraphic dating (10Be stratigraphy) of sediment cores from the northern North Atlantic and the Arctic Ocean
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  • 37
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 41 (4). pp. 721-739.
    Publication Date: 2017-07-21
    Description: In situ measurement of fluid flow rates from active margins is an important parameter in evaluating dissolved mass fluxes and global geochemical balances as well as tectonic dewatering during developments of accretionary prisms. We have constructed and deployed various devices that allow for the direct measurement of this parameter. An open bottom barrel with an exhaust port at the top and equipped with a mechanical flowmeter was initially used to measure flow rates in the Cascadia accretionary margin during an Alvin dive program in 1988. Sequentially activated water bottles inside the barrel sampled the increase of venting methane in the enclosed body of water. Subsequently, a thermistor flowmeter was developed to measure flow velocities from cold seeps. It can be used to measure velocities between 0.01 and 50 cm s−1, with a response time of 200 ms. It was deployed again by the submersible Alvin in visits to the Cascadia margin seeps (1990) and in conjunction with sequentially activated water bottles inside the barrel. We report the values for the flow rates based on the thermistor flowmeter and estimated from methane flux calculations. These results are then compared with the first measurement at Cascadia margin employing the mechanical flowmeter. The similarity between water flow and methane expulsion rates over more than one order of magnitude at these sites suggests that the mass fluxes obtained by our in situ devices may be reasonably realistic values for accretionary margins. These values also indicate an enormous variability in the rates of fluid expulsion within the same accretionary prism. Finally, during a cruise to the active margin off Peru, another version of the same instrument was deployed via a TV-controlled frame within an acoustic transponder net from a surface ship, the R.V. Sonne. The venting rates obtained with the thermistor flowmeter used in this configuration yielded a value of 4411 m−2 day−1 at an active seep on the Peru slope. The ability for deployment of deep-sea instruments capable of measuring fluid flow rates and dissolved mass fluxes from conventional research vessels will allow easier access to these seep sites and a more widespread collection of the data needed to evaluate geochemical processes resulting from venting at cold seeps on a global basis. Comparison of the in situ flow rates from steady-state compactive dewatering models differ by more than 4 orders of magnitude. This implies that only a small area of the margin is venting and that there must be recharge zones associated with venting at convergent margins
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  • 38
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    Elsevier
    In:  Marine Chemistry, 47 . pp. 115-125.
    Publication Date: 2018-03-02
    Description: A widely used degassing method for methane in seawater employing vacuum was tested and subsequently improved. It yielded 62 ± 3.8% of the total dissolved methane, hence a reproducible correction factor was established. The method was then applied to measure CH4 in the sea-air boundary layer and simultaneously in the overlying air along two transects in the eastern Equatorial Pacific off Peru in March of 1992. The results showed surprising small-scale reversals of the methane exchange between ocean and atmosphere in this region. Generally the ocean acted as a source of methane but also methane uptake by the ocean was found. This was mainly a consequence of high CH4 concentrations in the air which deviated considerably from the long-term and large-scale average. If applied to the flux rate calculations, the observed variabilities indicate that both rate and direction of the methane flux through the air-sea interface vary considerably depending on the atmospheric CH4 content. The implications are that even ocean areas with high concentrations of dissolved CH4 can be considerably weaker sources than would be expected on the basis of 1.7 ppmv mean atmospheric methane content. Based on improved simultaneous analyses of both air and water samples, the ocean-atmosphere flux of methane would therefore be more dynamic than previously thought.
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  • 39
    Publication Date: 2019-05-14
    Description: The Cenozoic sediments sampled in ODP Leg 104 on the Vøring Plateau show a distinct variability of the total organic carbon content (TOC) and the accumulation rates of TOC. Based on the geochemical and organic-petrographic characterization of the sedimentary organic matter (OM), the allochthonous and autochthonous proportion of the OM could be quantified.The results clearly demonstrate that high TOC percentages and TOC accumulation rates in Cenozoic sediment sections display a generally high input of allochthonous organic matter. Oxidized and partly well-rounded organic particles built up the main portion of OM within the Miocene, TOC-rich sediments. The most probable source of this oxidized OM are reworked sediments from the Scandinavian shelf. Changes in the input of these organic particles are to some degree correlative with sea-level changes.The Cenozoic accumulation of autochthonous OM is low and does not reveal a clear variation during the Miocene and early Pliocene. In spite of a high accumulation rate of biogenic opal during the Early Miocene, the accumulation rate of autochthonous TOC is low. The autochthonous particle assemblage is dominated by relatively inert OM, like dinoflagellate cysts. This points to an intensive biological and/or early diagenetic degradation of the marine OM under well oxidized bottom water conditions during the last 23 Myr. Nevertheless, a continuation of marine OM degradation during later stages of diagenesis cannot be excluded.A prominent dominance of allochthonous OM over autochthonous is documented with the beginning of the Pliocene. At 2.45 Ma the episodic occurrence of ice-rafted, thermally mature OM reflects the onset of the glacial erosion of Mesozoic, coal and black shale bearing sediments on the Scandinavian and Barents Sea shelves. The first occurrence of these, in view of the actual burial depth, thermally overmature OM particles is, therefore, a marker for the beginning of the strong Scandinavian glaciation and the advance of the glacial front toward the shelves.
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  • 40
    Publication Date: 2018-03-21
    Description: In order to assess recent submarine volcanic contributions to the sediments from the active Kolbeinsey Ridge, surface samples were analyzed chemically. The contribution of major and trace elements studied differ within the study area. A statistical analysis of the geochemical variables using factor analysis and cluster method allows to distinguish possible sample groups. Cluster method identifies three distinct sediment groups located in different areas of sedimentation. Group 1 is characterized by highest contents of Fe2O3, V, Co, Ni, Cu and Zn demonstrating the input of volcaniclastic material. Group 2 comprises high values of CaCO3, CaO and Sr representing biogenic carbonate. Group 3 is characterized by the elements K, Rb, Cs, La and Pb indicating the terrigenous component. The absolute percentage of the volcanic, biogenic and terrigenous components in the bulk sediments was calculated by using a normative sediment method. The highest volcanic component (〉 60% on a carbonate free basis) is found on the ridge crest. The biogenic component is highest (10–30%) in the eastern part of the Spar Fracture Zone influenced by the East Iceland Current. Samples from the western and southeastern region of the study area contain more than 90% of terrigenous component which appears to be mainly controlled by input of ice-rafted debris.
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  • 41
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 65, no. ALEX(01)-FR-77-01, AFTAC Contract F08606-76-C-0025, pp. 95-104, (ISBN: 0-08-044051-7)
    Publication Date: 1993
    Keywords: Textbook of geophysics ; GeodesyY ; Geothermics ; Planetology ; ConvolutionE
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  • 42
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    Elsevier
    In:  Marine Pollution Bulletin, 26 (3). pp. 152-155.
    Publication Date: 2018-03-22
    Description: Skin and hair samples of harbour seals (Phoca vitulina) found dead along the west coast of northern Germany in 1988 were analysed for total mercury, cadmium and lead. Cadmium and lead concentrations were below the detection limit in most skin samples. The mercury content of the hair (median: 23.1 μg g−1 wet wt) was several magnitudes higher than the mercury content of the skin (0.27 μg g−1 wet wt). Mercury concentrations in hair samples were significantly higher than lead concentrations (0.54 μg g−1 wet wt), which significantly exceeded cadmium levels (0.09 μg g−1 wet wt). Female seals revealed lower cadmium concentrations in the hair than male seals. Accumulations of metals with age were observed for cadmium and lead in hair samples and for mercury in skin samples of male seals. A connection between metal accumulation and pigmentation or rather moult was clearly recognizable.
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  • 43
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (2). pp. 267-291.
    Publication Date: 2018-03-22
    Description: The spreading of Mediterranean Water (MW) released through the Straits of Gibraltar is studied with hydrographic data, oxygen, nutrients and for the first time with chlorofluoromethane (CFM, compounds F11 and F12) distributions along seven sections in the Gulf of Cadiz, and with measurements in the Western Alboran Sea and west of the Gulf. The properties of MW entering the Gulf are deduced from CFM-salinity correlations east and west of the Straits as well as from property-depth profiles in the Western Alboran Sea. At the time of the survey, the outflow originated from depths above the salinity maximum of the Intermediate Water in the Alboran Sea. It turned out that the F11/F12 ratio of the outflow is equal to the ratios found in the Atlantic water in the Gulf of Cadiz; thus the ratio carries no time information in the region. A model is developed to describe mixing of the MW undercurrent with overlying North Atlantic Central Water (NACW) from different depths. The contribution of each layer to the mixing is parameterized by a weighting factor, which has to satisfy the balances of potential temperature (θ), CFMs, oxygen and nutrients in the MW undercurrent. It is shown that entrainment of water from shallower depths into the undercurrent is important near the Iberian Continental Shelf. Farther west and south, the undercurrent mainly mixes with water from near the salinity minimum of the NACW. For regions where the undercurrent has left the bottom, additional mixing with North Atlantic Deep Water (NADW) has to be taken into account. The percentage of MW in the undercurrent decreases from 76% hear the Straits to about 34% at 7°30′W for the lower core (MI) and about 22–24% for the upper core (Mu). Assuming an outflow of undiluted MW through the Straits of 1.0 Sv, the transport of the undercurrent can be calculated by determining an average dilution factor for each section. The undercurrent transports 2.0 Sv just west of the Straits and 3.6 Sv leave the Gulf of Cadiz. At 36°N, 9°54′W, a meddy with unusually high temperatures and salinities below 500 m was found, covering the density range for both cores, Mu and Ml. From the θ−S characteristics and the evaluated mixing scheme of the meddy it appears to have formed near 7°W in the Gulf, a region up to now not proposed in the literature, and moved westward without much further mixing.
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  • 44
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    Elsevier
    In:  International Journal for Parasitology, 23 (6). pp. 749-755.
    Publication Date: 2018-03-23
    Description: In April 1990, 488 marine fish belonging to 30 species from central Phillipine waters were examined for flesh parasitic infections that may affect their consumability. One species of hemirhamphids and 3 species of belonids harboured plerocercoids of Otobothrium penetrans Linton, 1907 (Proceedings of the U.S. National Museum33, 85–126). This is the first record of this parasite from Pacific fish species. The highest intensity of infection found was 8 in Tylosurus crocodilus. Most of the larvae were located between the dorsal spines of the vertebral column, only 32% were found in the fillets. Based on the present material we give a description of the plerocercoid stage of the species using scanning electron microscopy of the armature and morphometrical measurements. Comparison to results from earlier findings of O. penetrons by Linton (1907; 1924, Proceedings of the U.S. National Museum64, 1–114) and to O. kurisi by Shields (1985, International Journal for Parasitology15: 635–643) lead to the conclusion that the latter species is a synonym for O. penetrans.
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  • 45
    Publication Date: 2018-03-21
    Description: Nine large box cores collected in the western Greenland-Iceland-Norwegian (GIN) Sea were analyzed for calcium carbonate content and coarse fraction components. Stratigraphic control is based on oxygen isotope records performed on four of the cores. All cores were correlated using oxygen and carbon isotope data, fluctuations in calcium carbonate content, coarse terrigenous particle content and volcanic ash beds. Glacial and interglacial cycles are documented by a number of terrigenous particle events and differentiated calcium carbonate production which can be correlated to major paleoceanographic and paleoclimatic shifts. In the older core sections, extensive deposition of ice-rafted detritus (IRD) persisted until about oxygen isotope stage 9 and document a relatively stable environment in this area, strongly influenced by cold surface water masses. The following interval was characterized by variations in the general surface water circulation pattern, although high amounts of IRD are still present in Iceland Sea sediments. Pronounced shifts in terrigenous input and pelagic carbonate records were identified close to the oxygen isotope stage Full-size image (〈1 K) and Full-size image (〈1 K) boundaries, indicating massive melting of icebergs in the western GIN Sea. These enormous inputs of debris were followed by an increase in calcium carbonate production caused by maximum intrusion of warm Atlantic surface waters. Relatively high calcium carbonate contents also show that only little dilution by fine-grained material and a minimum of ice melting occurred during these warm phases. During oxygen isotope stage 5, conditions were more uniform indicating a less pronounced westward penetration of Atlantic waters as compared to the Holocene. The last glacial (stages 4-2) is characterized by the occurrence of “Heinrich”-like events, although high IRD contents were present throughout this interval. A distinct contrast between the northernmost cores and the cores in the south is indicative of a rather strong westward penetration of Atlantic water in the north and of an area dominated by cold water east of the Kolbeinsey Ridge during the Holocene. However, conditions west of Jan Mayen seem to have remained constantly dominated by cold surface waters throughout the whole time investigated.
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  • 46
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (3). pp. 783-800.
    Publication Date: 2018-03-05
    Description: Horizontal distribution of myctophid fishes were studied from two transects in the Arabian Sea in 1987. Species numbers exhibited a south-north decline in diversity, with only half of the fish taxa occupying the northeastern region. Diaphus arabicus was the dominant species both in the south and north. All recorded myctophid fish species migrate in a diel pattern, residing during daytime at depths of extremely low oxygen levels (〈0.1 ml O2 1−1) and foraging in the oxygen-rich surface layer at night. Feeding patterns were determined for the six most abundant myctophid species. All species appeared to be opportunistic predators that prey on a comparatively narrow food spectrum consisting principally of small to medium sized copepods. Numerically, non-calanoid copepods (with Oncaea conifera and O. venusta dominating) made up to 70% of the diet of D. arabicus and Bolinichthys longipes. Of the 26 calanoid copepod species identified from the six myctophid taxa, the genera Euchaeta, Pleuromamma and Candacia generally dominated in the stomachs, with P. indica constituting between 21 and 95% (by numbers) of the calanoid copepod prey.
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  • 47
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (6). pp. 1155-1168.
    Publication Date: 2018-03-05
    Description: Particulate fluxes of aluminium, cadmium, cobalt, copper, iron, manganese, nickel, phosphorus, lead, vanadium and zinc in the northeast subtropical Atlantic Ocean have been determined from sediment trap samples collected between 1 December 1986 and 30 April 1987 at 1020 and 4120 m below the ocean surface. The fluxes of most elements (except Cd and P) show small variations between the different layers, and are closely associated with the vertical transport of aluminium. Elemental composition and flux rates suggest that aerosol loadings from northeast trade winds are the major contributor of these elements to depositing material. Extremely low fluxes of copper, lead and zinc also indicate that anthropogenic perturbations are of insignificant importance in this region.
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  • 48
    Publication Date: 2018-03-05
    Description: Within the framework of the JGOFS Pilot Study in 1989 mesozooplankton (0.2–20 mm) was sampled by means of a Hydro-Bios multinet in five depth strata (0–25, 25–50, 50–100, 100–200, 200–500 m) during four Lagrangian drift experiments of 8–14 days' duration at 18, 33, 46 and 58°N, to follow the seasonal progress of the phytoplankton spring bloom development in the northeast Atlantic. Mesozooplankton standing stock, measured as dry weight and ash-free dry weight, increased by a factor of about 6 from 18 to 58°N. Day/night differences amounted to 10–20% of the average and were—with one exception at 18°N—not statistically significant. Using the data on weight-specific respiration rates measured by colleagues on the same cruise, the ingestion rates and potential community grazing of mesozooplankton on phytoplankton within the upper 100 m of the water column were calculated. During all four drift experiments, quasi-steady-state conditions were observed in phyto- and zooplankton standing stock, primary production and daily sedimentation at 100 m depth. The maximum potential grazing rate by mesozooplankton accounted for about half of the daily primary production. Since sedimentation of fresh phytoplankton was negligible, it is concluded that the grazing pressure exercised by mesozooplankton together with micro- and nanozooplankton was responsible for keeping the phytoplankton standing stock at a more or less constant level during the investigated spring bloom in the four areas. Particle flux was thus dominated by zooplankton faecal material.
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  • 49
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    Elsevier
    In:  Journal of Chromatography A, 642 (1-2). pp. 425-434.
    Publication Date: 2019-02-27
    Description: Accurate congener-specific determination of chlorobiphenyl congeners (all 209 congeners) is finally possible with the use of multidimensional gas chromatography-electron-capture detection techniques. The effectiveness of this technique for environmental analyses is enhanced by ultraclean laboratory practices, non-destructive extraction and clean-up steps and the use of low-volume, high-efficiency HPLC separation for various classes of organic contaminants. In the light of these new developments conventional procedures for chlorobiphenyl analysis are evaluated.
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  • 50
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (3). pp. 711-735.
    Publication Date: 2018-03-05
    Description: The productivity regime and size structure of phytoplankton are described for three different epipelagic systems in the Arabian Sea during the inter-monsoon period in spring 1987: (1) the coast of Oman; (2) the central Arabian Sea; and (3) the shelf off Pakistan. These results are related to the functioning of the specific ecosystem. Off the coast of Oman, the transition from a surface maximum of autotrophic biomass and production to a more oligotrophic system, with a chlorophyll subsurface maximum, was observed. Concomitantly, the size spectrum changed towards a higher significance of picoplankton. In the central Arabian Sea, a typical oligotrophic system with a pronounced subsurface maximum of autotrophic biomass and primary production was encountered. Here, the epipelagic system could be divided into two distinct sub-systems: the surface layer “regenerated” production, the predominance of picophytoplankton and minor losses due to sedimentation, thus a “closed” system; and the subsurface maximum layer at the nutricline characterized by higher sedimentation losses and more diatoms. Both sub-systems showed about the same productivity, the turnover in the surface layer having been much greater than in the subsurface maximum. The system on the shelf off Pakistan is seen as a decay stage of the open ocean system when water from offshore is transported onto the shelf during the onset of monsoon winds.
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  • 51
    Publication Date: 2018-03-07
    Description: In February 1988, 60 near surface samples were taken on a track between 2°W in the English Channel, the Pentland Firth and the inner German Bight. Determinations were made on filtered and unfiltered samples. Concentrations of dissolved metals in the North Sea normalized to a salinity of 34.5 were Al 31, Cd 0.13, Co 0.13, Cu 3.4, Mn 6.2 and Ni 3.9 nM. In July 1984 the equivalent concentrations were Al 11, Cd 0.15, Co 0.15, Cu 4.3, Mn 12 and Ni 3.6 nM. Distinct regional differences were detectable which can be related to the origin of the water, differing river inputs, and solution-solid phase exchange reactions. The degree of the influence of exchange reactions was investigated through the concept of Kd, the distribution coefficient. A Kd of 105 ml g−1 for Al is consistent with other observations and explains the relatively high concentrations of dissolved Al detected in the English Channel on this cruise. The data suggest a higher Kd for Mn approaching 106 ml g−1. The high Mn Kd coupled to higher suspended sediment loads in winter may be sufficient to explain the lower concentration of dissolved Mn in winter. Comparison of concentrations across the shelf break suggests that for all the metals studied, the European Shelf is a source of dissolved metals to the deep sea. Calculations based on the limited available data indicate that this export is of similar magnitude to the fresh water input of dissolved metals.
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  • 52
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 91-114.
    Publication Date: 2018-03-05
    Description: An overview is given of the multinational investigations carried out at 47°N 20°W for the period 24 April–31 May, with the main emphasis on the succession of plankton communities and the flux of organic carbon through various plankton components. The depth of the upper mixed layer decreased rapidly after 25 April, triggering the start of the spring bloom that developed within a 2-week period. Chlorophyll a stocks integrated to 80 m water depth reached peak concentrations during the first 10 days in May. The observed decline was partly due to the seasonal development, but also may have been influenced by changes in water masses associated with a cyclonic eddy. Primary production ranged from 50 to 150 mmol C m−2 day−1 with highest values in the first half of May. After the first bloom phase, dominated by diatoms, nanophytoplankton gained more importance as primary producers when silicate was depleted. Stocks of bacteria, microzooplankton and mesozooplankton increased in the second half of May. Bacterial production averaged 30% of primary production and probably metabolized a large amount of dissolved organic carbon (DOC) per day, but due to uncertain carbon conversion efficiencies total bacterial carbon consumption is difficult to estimate. Largely daily changes in the DOC standing stock could not be reconciled with the measured primmary production and are probably an expression of spatial rather than temporal variations. Microzooplankton was found to consume around 64% of primary production in the second half of May. Grazing estimates for mesozooplankton varied but seem to be small (〈5% of primary production) for most of the investigation period. The small mesozooplankton size classes (〈1 mm) dominated biomass and grazing. Vertical particulate organnic carbon (POC) flux measured by sediment traps in 150 m depth was around 9.8 mmol C m−2 day−1 representing approximately 11% of primary production. The spring bloom pulse of particle flux reached the deep ocean and benthos 4–6 weeks after the surface water peak.
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  • 53
    Publication Date: 2018-03-22
    Description: Altimetric data from Geosat and some critical hydrographic measurements were used to estimate in real time the mesoscale physical oceanographic environment surrounding the Joint Global Ocean Flux Study (JGOFS) 1989 North Atlantic Bloom Experiment. Three cyclonic eddies, including an exceptionally large one, evolved and interacted over the 10 weeks of observations. Subsequent analysis of all available hydrographic data confirmed the real time estimates and provided further quantitative information concerning the mesoscale and submesoscale structure of the upper ocean. Remotely sensed indicators of near-surface chlorophyll content reveal significant biological variability on these wavelengths. The altimetric and hydrographic data have been assimilated into a dynamical model to produce optimal estimates of physical fields of interest as they evolve in time for use in physical and biological process studies
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  • 54
    Publication Date: 2018-03-22
    Description: The influence of increasing amounts of surfactants on the toxicity of hydrocarbons was determined using the bioluminescence inhibition test (Microtox test). Three biogenic and three synthetic surfactants were tested against the water-soluble fractions (WSF) of crude and weathered Ekofisk oil, phenol, and naphthalene. Surfactant concentrations below 100 mg litre−1 lowered the toxicity of the WSF, indicating an antagonistic interaction reducing the toxicities of surfactants and hydrocarbons. At concentrations greater than 100 mg litre−1 the toxicity rose again and was higher than the untreated WSF. The point of reversal seemed to be the critical micelle concentration, at which the formation of oil/water emulsions is possible.
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  • 55
    Publication Date: 2017-03-30
    Description: Biological and fishery features of the waves of abundance of Illex argentinus in three fishery regions −52°S (shelf with 180–230 m depths in exclusive economic zone of Argentina—EEZA), 46° and 42°S (continental slope with 600–800 m depths off the EEZA) in April–June 1990 were studied. According to age analysis of 629 statoliths made aboard, age-length structure of each wave of abundance were determined. In April–June active spawning migrations of I. argentinus were observed from feeding grounds located in limits 50–52°S along the continental slope northwards through 46° and 42° fishery regions. Only winter-hatched squids (hatched from June to September of the previous year) took part in migrations which were observed as waves of abundance in all three regions. Each migratory wave of abundance consisted of 2–4 successive monthly generations. The start of spawning movement was corresponded with the age and maturity state of the squid. Squid of all monthly generations began migrating from the 52°S region at a mean age of approximately 250 days, passed through 46°S at mean age 280 days and through 42°S at mean age 295 days. Males migrated 2–3 weeks earlier than females of the same generation. Rates of somatic growth were very low during migrations from 52° to 46°S (RDGR - 0.13% mantle length (ML) in mature males and 0.2% ML in maturing females). During movement from 46° to 42°S and, obviously further, mature squids practically ceased somatic growth. Estimated rate of migrations was 23.2–28.9 km day−1 (including current velocity), or 26–30 cm s−1 (0.47 body length s−1). Spawning was considered to occur on the continental slope of Uruguay and Brazil north of 35°S in July–August. Methodical approaches of efficient determination of squid age, growth and stock structure by means of investigation of squid biological features and statolith microstructure in each distinguished wave of abundance were elaborated.
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  • 56
    Publication Date: 2017-05-04
    Description: The effects of feeding a prepared surimi diet (fish-based) and a prepared pelleted diet (shrimpbased) on the survival, growth and feeding rate of the cuttlefish Sepia officinalis L. were evaluated during a 45-day experiment. One hundred and twenty juveniles of laboratory cultured cuttlefish (74.5 ± 12.36 g) were divided into three treatments and were fed thawed shrimp (control), pellets or surimi. Survival rates on these diets were 95.0%, 67.5% and 22.5%, respectively. Preliminary data indicated that the low survival of cuttlefish fed surimi may have been caused by low levels of copper in their blood (131 vs 244 μg/ml) since copper is required for their respiratory blood pigment, hemocyanin. Instantaneous growth rates were 2.71 % body weight BW/day for cuttlefish fed raw shrimp, 0.33% BW/day for cuttlefish fed pellets, and 0.54% BW/day for cuttlefish fed surimi. The feeding rate of cuttlefish fed shrimp was high (6–8% BW/day). The feeding rate on pellets increased with time (from 〈 1 to 3% BW/day) but never reached the level for raw shrimp. The feeding rate on surimi increased to equal the rate for raw shrimp during days 1–30 (8 to 9% BW/day) and thereafter decreased (〈4% BW/day). In conclusion, there was a major distinction between the palatability of a prepared diet and the ability of that diet to support growth. Surimi was highly palatable but resulted in poor survival, suggesting low nutritional quality. In contrast, pellets were less palatable but produced maintenance growth. Development of practical surimi diets will require supplementation of the surimi with soluble micro- and macronutrients.
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  • 57
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    Elsevier
    In:  Acta Oecologica - International Journal of Ecology, 14 (3). pp. 463-470.
    Publication Date: 2020-04-23
    Description: Changes in marine ecosystems can be manifested in many different ways, on different temporal and spatial scales. Seabirds are top consumers in marine foodwebs and offer opportunities to detect and assess the biological effects of changes in physical parameters (sea-surface temperature [SST], salinity, depth of thermocline etc.) of the marine ecosystem. We compare six-eight years' of data on the biology (diet, and breeding success) of four species of seabird (arctic tern Sterna paradisaea and common tern S. hirundo, which feed at the sea surface; and Atlantic puffin Fratercula antica and razorbill Alca torda, which dive 30-60 m for their prey) breeding on Machias Seal Island (MSI) in the Bay of Fundy with both our own meteorological and oceanographic measurements, and with standard measurements from conventional sources. These are compared with fisheries data on changes in the main prey of all the seabirds concerned (juvenile or '0-group' herring Clupea harengus) which are the most direct link between the seabirds and the physical properties of the marine system. We explore relationships between seabird productivity and diet, and other aspects of both herring biology (larval surveys, and fat content) and oceanography (SST data from the island, and remotely sensed data from the entrance to the Bay of Fundy). Timing of laying by puffins followed SST variation at neither the local (MSI) nor regional scales, but at the scale of the North Atlantic, following the trend of populations breeding off northern Norway. The proportion of herring in the diet of terns over 6 years varied inversely with herring larval abundance the previous fall; this relationship was not statistically significant in the puffin and razorbill. A major new finding is the considerable (approximately 50%) inter-annual variation in the energy density (fat content) of juvenile herring that are the main seabird prey; breeding success of both species of tern varied in parallel with the energy density of juvenile herring in the diet until the last two years of the study, when sandlance (Ammodytes sp.) and euphausid shrimp predominated in the diet. Our long-term research approach combines traditional population monitoring (of numbers of breeding birds) with demographic, behavioural and environmental monitoring, to provide new understanding of the marine ecosystem as well as of seabirds.
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  • 58
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 495-519.
    Publication Date: 2018-03-05
    Description: Productivity regime and phytoplankton size structure are described for two different epipelagic systems in the tropical/subtropical Northeast Atlantic Ocean investigated during 9–11 day drift studies in spring 1989 in the JGOFS North Atlantic Bloom Experiment, 18°N, 30°W and 33°N, 20°W. At the 18°N study site, an oligotrophic system was encountered. The water column above the main pycnocline at about 50–60 m depth was nutrient-depleted, and both chlorophyll and primary production displayed subsurface maxima at the nutricline. Picoplankton was the dominant size fraction, accounting for 78–90% of chlorophyll and 83–98% of primary production. Synechococcus-type coccoid cyanobacteria were the dominant picoplankters. The hydrographic situation was characterized by high small-scale variability; the most interesting feature was the intrusion of nutrient-depleted Subtropical Salinity Maximum Water into the euphotic zone, whose impacts on the productivity regime are discussed. At 33°N study site, a post-bloom situation was encountered. Although the euphotic zone was nutrient-depleted, higher amounts of larger phytoplankton were present, the contribution of picoplankton being 42–53% of chlorophyll and 42–86% of primary production. Over the course of the drift study, subsurface maxima of chlorophyll and productivity evolved, the contribution of picoplankton having increased. Picocyanobacteria again were the dominant picoplankters. At both study sites the profiles of abundance ratios of picocyanobacteria to picoeucaryotes cell numbers proved to be a useful tool to characterize water masses.
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  • 59
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (11-12). pp. 2167-2177.
    Publication Date: 2018-03-07
    Description: The origin and the spreading of the shallow Mediterranean water core (Ms) in the Iberian basin is discussed with a quasi-synoptic hydrographic data set enhanced by chlorofluoromethane (CFM) measurements. Its characteristic density level is found to be σt = 27.4. Characterized by high temperature and CFM values, Ms enters the Iberian basin in the region of Cape St Vincent between depths of 500–750 dbar. A heat anomaly of 〉11.8 × 109 J m−2 is chosen as the boundary between the presence of Ms and the background field. The core is found in a tongue-like shape as well as in separate isolated eddies of both cyclonic and anticyclonic circulation. Using the optimum multiparameter analysis (Tomczak and Large, 1989, Journal of Geophysical Research, 94, 16141–16149), the North Atlantic Central Water (NACW), which mixes with the Mediterranean outflow to form Ms, turned out to be in the mean 1°C warmer and 0.11 saltier than in regions with minor Mediterranean influence. This points to the Gulf of Cadiz as the origin of Ms, where the Mediterranean oufflows is in contact with NACW of the appropriate characteristics.
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  • 60
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    In:  Journal of Marine Systems, 4 (2-3). pp. 231-233.
    Publication Date: 2018-03-07
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  • 61
    Publication Date: 2018-03-07
    Description: Gas chromatography-mass spectrometry (GC-MS) analyses of organic concentrates from eastern Mediterranean surface water show that dissolved fossil fuel residues are dominated by unsubstituted aromatic hydrocarbons and heterocyclic aromatics and thus resemble products of incomplete combustion. Deviating from this interpretation, preferential photochemical oxidation of alkyl-substituted aromatics is suggested as the principal causative mechanism, although, especially near land-based sources. the influence of combustion-derived unsubstituted aromatics is not defined. Total concentrations of dissolved aromatics as determined by GC-FID (flame ionization detection) and GC-MS from a limited data subset were in reasonable agreement with UV fluorescence measurements of dissolved/dispersed oil residues. The same preponderance of unsubstituted aromatics over their alkyl derivatives was found in extracts of the particulate phase, but concentrations were small relative to alkanes and/or alkenes of recent marine biosynthetic origin. CPI (carbon preference index) values of higher molecular weight n-alkanes indicated varying contributions of plant waxes to the particulate hydrocarbon pool. CPI values of corresponding dissolved n-alkanes were found to be near unity, indicating fossil fuel origin. Despite differences in higher molecular weight n-alkane CPI values and the predominance of recent biosynthetic aliphatics, the similarity of dissolved and particulate aromatic fractions suggests limited adsorption by particles of fossil fuel derived hydrocarbons and heterocyclics.
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  • 62
    Publication Date: 2018-03-07
    Description: Saudi Arabian coastal waters near sandy beaches, severely contaminated with crude oil released in Kuwait during the 1991 Gulf War, as well as underlying sediments and a few bivalves, were analysed to assess concentrations and composition of petrogenic hydrocarbon mixtures and structurally related oxidation products. Concentrations of dissolved oil residues determined by UV spectrofluorometry (UVF) near oil deposits on beaches did not exceed 3.5 μg l−1; concentrations dropped to approximately 1/10th of this value a few miles offshore. Gravimetric concentrations of unfractionated lipophilic material extracted from large volumes of seawater at the same stations were up to 10 times those determined by UVF. After chromatography on silica gel, individual petroleum hydrocarbons in the low polarity fractions and oxidation products in the polar fractions were characterized by their spectra (GC/MS) and quantitated by Selected Ion Monitoring (SIM) GC/MS. Concentrations of oxidation products (ketones, aldehydes, alcohols) of aromatic hydrocarbons exceeded those of their parent compounds by more than an order of magnitude. Significant concentrations were also found of the presumably pyrogenic triplett sensitizer anthraquinone. Contributions to polar fractions of water extracts by biosynthesized lipids were negligible. UVF determinations appear to underestimate concentrations of dissolved oil residues, because many oxidation products have lower fluorescence quantum yields than the respective parent hydrocarbons. Their ecotoxicological properties are unknown. Concentrations measured in sediments by UVF ranged from 13 to 540 μg g−1 dry wt and 0.5 to 103 μg g−1 as measured by gas chromatography with flame ionization detection (FID GC). Bivalves ranged from 0.8 to 1.5 μg mg−1 extractable organic matter (EOM) by UVF, and 0.1 to 0.3 μg mg−1 EOM by GC analysis. PAHs were identified in sediment and bivalve extracts by GC/MS and quantitated by SIM GC/MS. None of the relatively water soluble alkylbenzene photo-oxidation products found in water samples nor any higher molecular weight quinones could be detected in sediment extracts. However, ion chromatograms strongly suggest the presence of numerous high molecular weight aromatics in that matrix.
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  • 63
    Publication Date: 2018-03-07
    Description: As part of the NOAA/ROPME/MSRC sponsored assessment of the coast of Saudi Arabia, heavily impacted by the large oil spills of the 1991 Gulf War, we measured benthic community respiration (R) and primary production (P) rates in shallow subtidal basins near heavily oiled coastlines. Study sites were located in zones predicted to be basins of maximum deposition of any oiled sediments likely to wash off the adjacent coast and in reference bays predicted to be clean and unaffected. We measured oxygen exchange using in situ benthic respirometers and analysed petroleum hydrocarbon (PHC) levels in the near surface sediments at five stations. We concentrated our efforts in mud habitats to complement related studies in seagrass habitats. Measured community R rates ranged from a low of 700 μM m2 h−1 in coarse sand sediments with total organic carbon content (TOC) of only 0.16% of dry wt to the highest rate of 2184 μm m−2 h−1 in finer mud-sand habitats with 0.39% TOC. All measured rates were in the range of literature values for shallow marine sediments at temperatures of 17 to 19°C. Sediment oil content was 13–540 μg g−1 dry wt by ultraviolet fluorescence (UVF) analysis and 0.5–103 μg g−1 by gas chromatography (GC). Benthic P rates, calculated as light minus dark changes in dissolved oxygen, ranged from a low of 1162 μm m−2 h−1 at the most heavily oiled site to a high of 5216 μm m−2 h−1 at less oiled sites. While a weak inverse relationship between benthic P and sediment oil content was not significant statistically due to the small number of samples, a significant inverse relationship was found between the ratio of production to respiration (P/R) and the total petroleum content of the sediments by UVF. The effect appears to be driven more by differences in production than an effect on respiration which showed little relationship with either oil content or productivity. We conclude that within 1 year after the oil grounded on the intertidal sands of Saudi Arabia, the levels of oil in subtidal benthic sediments had decreased in most habitats to levels that did not show community stress by our oxygen measurements. Rather, long term damage to benthic subtidal habitats was limited only to enclosed bays adjacent to the most heavily oiled coastlines. Preliminary estimates of yearly P converted to carbon units indicates that the shallow mud sediments of the Gulf are at least as productive as most oligotrophic water columns. Since benthic habitats covered by seagrass, algae beds or coral reefs are likely to have even higher production rates, we conclude that benthic processes contribute significantly to the overall carbon flux in the Gulf ecosystem.
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  • 64
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (2). pp. 257-266.
    Publication Date: 2018-03-21
    Description: A method for the collection of large-volume samples of oceanic particles is described. Near-surface seawater is pumped from below the ship to a continuous-flow centrifuge at rates of up to 1.2 m3 h−1. The seawater is in contact with polyethylene, polypropylene, Teflon and titanium materials only. The retention efficiency of the centrifuge for marine particles is the same as for standard membrane filters, as shown by comparisons with separate samples from Go-Flo bottles. The pumping system is non-contaminating with respect to both particulate and dissolved species. Several subsampling facilities for additional chemical constituents and other parameters can be supplied simultaneously due to the modular design of the system and the high flow rates
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  • 65
    Publication Date: 2018-03-02
    Description: Sediments of 13 piston cores from opposite continental slopes of the South China Sea, off southern China and Sabah (northern Borneo), were analyzed by sedimentological methods and dated by oxygen isotope stratigraphy. Sediments mostly consist of hemipelagic clay with 20% carbonate off Sabah and 40% off China. We calculated terrigenous and carbonate accumulation rates for up to 11 time-slices from the Holocene to oxygen-isotope stage 6. Terrigenous accumulation rates generally increase with water depth and reach a maximum at the middle slope off Sabah and at the lower continental slope off China. During glacial and interglacial times this distribution pattern did not markedly change, despite an increase of accumulation rates for glacial periods by a factor of 2 to 5 compared to interglacial periods. Rates are negatively correlated with positions of sea level, which controls the partition of fluviatile terrigenous material for deposition on shelf, slope, and abyssal plain. Carbonate accumulation rates are higher off China by a factor of 2 compared to Sabah, probably indicating higher calcareous plankton productivity.
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  • 66
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (9). pp. 1925-1933.
    Publication Date: 2018-03-02
    Description: The Vema Channel represents a prominent location for the nortward flow of bottom water in the subtropical western South Atlantic. A recent multibeam echo-sounding survey of the Vema Sill on board F.S. Meteor revealed a narrow and shallow portion of the Vema Channel at 31°12′S, 39°24′W, the Vema Sill. The survey also showed the remarkably asymmetric shape of the sill region, suggesting an interaction between the bottom flow and the shape of the channel.
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  • 67
    Publication Date: 2017-07-21
    Description: Live observations, cytological characteristics and biometrical measurements on Miliolinella subrotunda (Montagu, 1803) sampled from the northern and southern Atlantic Ocean are presented.M. subrotunda facultatively constructs a long, detritic tube lifting the test several millimeters above the sediment surface. A thickened conical base anchors the construction on the sediment surface and a long, flexible tube protrudes into the velocity profile of the bottom currents. The miliolid test is placed on top, surrounded by the uppermost part of the tube. This construction allows the organisms to feed in the particle stream above the sediment surface. In comparison to species living in and on the surface sediments,M. subrotunda apparently shows higher nutritional values in food ingested and larger amounts of reserve substances. Characteristics of the shape and structure that reduce drag on the tubes include a broadened conical base, a flexible tube, and a rounded top. From biometrical measurements it is concluded, that the tubes are constructed over a short period of their ontogeny.
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  • 68
    Publication Date: 2016-11-14
    Description: The Houtman Abrolhos Islands, situated at the western passive margin of the Australian continent, consist of a series of shelf-edge coral reefs. The central platforms of the reefs are Late Pleistocene in age and are generally some 3–5 m above present sea level. The uppermost part of the Last Interglacial reefs normally has an upward-shallowing sequence, consisting of coral framestone, coralline algal bindstone and skeletal grainstone to rudstone. This sequence represents deposition in water depths of less than 2 m, and provides a good indicator of sea level. High-precision mass-spectrometric dates of corals from the Abrolhos reefs, including dates obtained from drill cores, arological, isotopic and stratigraphic criteria are established for the selection of suitable samples for dating and for assessing the reliability of dates. Using the screened dates and the stratigraphic evidence, the timing and character of the sea level variations of the Last Interglacial in the Abrolhos region are examined. The data show that sea level of the Last Interglacial in the Abrolhos was 4 m below its present height by ca. 134 ka BP and probably reached about 2 m above present height at ca. 133 ka BP. The exact time at which sea level reached its peak (6 m above present sea level) cannot be determined from our data. But it is clear that the sea level high stand of the Last Interglacial lasted until ca. 116 ka BP and that for much of the Last Interglacial sea level at the Abrolhos was at a height of about 4 m above its present level
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  • 69
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    Elsevier
    In:  Chemical Geology, 103 (1-4). pp. 271-281.
    Publication Date: 2015-11-24
    Description: Accurately weighed aliquots of the ∼ 500-Ma-old interlaboratory standard hornblende MMHb-1 were mixed with known quantities of a ∼ 100 Ma-old Himalayan biotite and subjected to normal Full-size image (〈1 K) incremental heating analysis. The addition of the biotite created monotonically increasing apparent ages, similar to profiles interpreted as showing Ar diffusive loss in the literature. The release of Ar from biotite dominates the low-temperature portion of the spectra and lowers the observed age. Lower Ca/K ratios in the first increments are consistent with contamination, but do not distinguish the composition of the contaminant phase. A large number of published amphibole “diffusive loss” profiles may, in fact, be due to contamination by biotite or other phases which release Ar at low extraction temperatures.
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  • 70
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (8). pp. 1547-1557.
    Publication Date: 2016-10-19
    Description: Moored Acoustic Doppler Current Profilers (ADCPs) were used to analyse the daily vertical zooplankton migration and its seasonality. One-year records of vertical velocity and acoustic backscatter were obtained at four stations in the Greenland Sea. Both parameters exhibited a diurnal cycle typical for vertically migrating zooplankton. Upward and downward migration occured in short periods approximately 5 h long, and peak migration velocities were around 1.5 cm s−1. Similar structures were observed at all four mooring sites in the 200–300 m depth range. Farther down, between 1000 and 1400 m, no daily migration was observed. Strong seasonal variations are evident, and both the phase and intensity of the migration pattern change with daylight as the season progresses. In summer and during the polar night the migration became very weak and was only detectable in the displacement of scattering layers. When the day/ night contrast was large, intense upward or downward motion was accompanied by sloping backscatter isopleths. We observed two main scattering layers, a deep layer that varies in depth with season and an almost invariable shallow scattering layer at about 150 m depth. The deep layer was interpreted as the “resting depth” of the migrating plankter, and the latter as their “feeding horizon”. Changes in the “resting depth” from about 400 m in autumn and spring to about 200 m in winter lead to seasonal variations in the migration distance. This behaviour is discussed with respect to environmental conditions.
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  • 71
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    Elsevier
    In:  Sedimentary Geology, 82 (1-4). pp. 145-155.
    Publication Date: 2016-09-07
    Description: 50 m of Middle Eocene pure radiolarian ooze were drilled at ODP Site 660 in the equatorial East Atlantic, 80 km northeast of the Kane Gap. The oozes comprise a 10 m high and 2 km broad mound of seismic reverberations, covered by manganese-rich sediment, and contain trace amounts of sponge spicules and diatoms, negligible organic carbon (0.15%), clay, and variable amounts of pyrite. The yellow to pale brown silty sediments are relatively coarse-grained (30–45% coarser than 6 μm), little bioturbated, and commonly massive or laminated on a cm-scale. The unlithified radiolarian ooze may indicate an interval of high oceanic productivity, probably linked to a palaeoposition of Site 660 close to the equatorial upwelling belt during Middle Eocene time. The absence of organic matter, however, and both the laminated bedding and the mound-like structure of the deposit on the lower slope of a continental rise indicate deposition by relatively intense contour currents of oxygen-rich deep water, which passed through the Kane Gap, winnowed the fine clay fraction, and prevented the preservation of organic carbon. The ooze may be either a contourite-lag deposit, or a contourite accumulation of displaced radiolarians, originating south of the Kane Gap and being deposited in its northern lee, thus documenting the passage of a strong cross-equatorial bottom-water current formed near Antarctica. These Eocene contourites may be an analogue for ancient radiolarites in the Tethyan Ocean.
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  • 72
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    Elsevier
    In:  Marine Micropaleontology, 20 . pp. 215-234.
    Publication Date: 2017-07-21
    Description: In situ observations of microhabitat preferences of living benthic foraminifera are presented from sediments of the Norwegian-Greenland Sea, the upwelling area off northwestern Africa and the shallow-water Kiel Bight (Baltic Sea). Certain foraminiferal species (e.g.Cibicidoides wuellerstorfi andRupertina stabilis) can be regarded as strictly epibenthic species, colonizing elevated habitats that are strongly affected by bottom water hydrodynamics. Large epibenthic foraminifera (e.g.Rhabdammina abyssorum andHyperammina crassatina) colonize the sediment surface in areas where strong bottom currents occur and might have by virtue of their own size an impact on the small-scale circulation patterns of the bottom water. Motile species changing from epifaunal to infaunal habitats (e.g.Pyrgo rotalaria, Melonis barleeanum, Elphidium excavatum clavatum, Elphidium incertum, Ammotium cassis andSphaeroidina bulloides) are regarded here as highly adaptable to changes in food availability and/or changing environmental conditions. This flexible behaviour is regarded as a dynamic adaptation to optimize food acquisition, rather than a static concept leading to habitat classification of these ubiquitous rhizopods.
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  • 73
    Publication Date: 2017-06-23
    Description: The Houtman Abrolhos reefs, situated on the western continental margin of Australia, occupy a transitional position between cool-water shelf carbonate sediments to the south and more tropical environments to the north. Their existence at the outer limits of the geographical range for coral reef growth is a result of the warm, poleward-flowing Leeuwin Current. Though the modern reefs differ ecologically from tropical reefs, their geological characteristics have been little known until recently. Each of the three island groups in the Abrolhos consists of a central platform of Last Interglacial reefs, about which windward and leeward Holocene reefs have developed asymmetrically. In the Easter Group the subtidal windward reef in the west is ca. 10 m thick and is backed by a leeward-prograding, lagoon sand sheet which is 0–3 m thick. The emergent parts of the leeward reefs in the east consist of an upward-shallowing sequence comprising reef facies, peritidal rudstone facies, and coral rubble storm ridges. This is underlain by over 26 m of Holocene reef facies. Coring and dating of the Holocene reefs (using both TIMS and 14C methods) in the Easter Group has shown significantly different lithofacies in the windward and leeward reefs, and has allowed reconstruction of Holocene reef growth and sea-level history. Coralline algal bindstones and interbedded coral framestone facies characterise the relatively slow-growing windward Holocene reefs, whereas the fast-growing leeward reefs consist of coral framestone facies which are dominated by Acropora. The leeward reefs commenced growth about 10,000 years ago and the Morley reef grew to 0.3 m above present sea level by 6400 years B.P., recording a relative high sea-level event. This generated Holocene constructional topography characterised by “blue-hole” terrain. Windward Holocene reef growth commenced after 8200 years B.P. following erosion of the windward part of the Last Interglacial platform. High wave energy and competition with macroalgae limited coral growth, and the coralline algal-dominated windward reefs grew more slowly to sea level. The Holocene sea-level record provided by dates from the 26 m core of the Morley reef (a “keep-up” reef) is the first such record from the western continental margin of Australia.
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  • 74
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 521-536.
    Publication Date: 2019-01-21
    Description: During a R.V. Meteor JGOFS-NABE cruise to a tropical site in the northeast Atlantic in spring 1989, three different vertical regimes with respect to nitrate distribution and availability within the euphotic zone were observed. Besides dramatic variations in the depth of the nitracline, a previously undescribed nose-like nitrate maximum within the euphotic zone was the most prominent feature during this study. Both the vertical structure of phytoplankton biomass and the degree of absolute and relative new production were related to the depth of the nitracline, which in turn was dependent on the occurrence/non-occurrence of the subsurface subtropical salinity maximum (S(max)). The mesoscale variability of the nitracline depth, as indicated from a pre-survey grid, and published data on the frequent occurrence of the S(max) in tropical waters suggest higher variability of new production and F-ratio than usually expected for oligotrophic oceans. The importance of salt fingering and double diffusion for nitrate transport into the euphotic zone is discussed.
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  • 75
    Publication Date: 2016-05-17
    Description: Al- and Ti-rich smectites associated with alkaline volcanic rocks were dredged during several cruises of the German research vessel “SONNE” as part of an extensive survey of manganese crusts in the Central Pacific seamount region. X-ray diffraction, chemical composition and infrared spectroscopy suggest that the smectites are constituents of the nontronite-beidellite solid solution series. X-ray fluorescence analyses yield considerable amounts of Al2O3 and Fe2O3 averaging 14.5 and 12.4 wt%, respectively. According to ASTM data the smectites are Al-rich nontronites rather than Fe-rich beidellites. A TiO2 content of up to 4.9 wt% is thought to be due to anatase impurities. δ18O-values in the range of +23.8 to +21.0‰ vs. SMOV indicate formation temperatures of 32–48°C. The rare-earth element patterns of the nontronitic smectites and associated alkaline volcanics are almost identical, showing a relative enrichment of light and a depletion of heavy rare-earth elements. It is concluded that the smectites formed as low-temperature alteration products during interaction of seawater with cooling basaltic/alkaline rocks rather than by mixing of hydrothermal fluids with seawater.
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  • 76
    Publication Date: 2016-07-19
    Description: Dissolved silica (Si) and inorganic germanium (Ge) concentrations were measured in hydrothermal fluids from black smoker vents on the East Pacific Rise (21°N EPR) and the Southern Juan de Fuca Ridge (45°N SJdFR: North and South Cleft Sites, Axial Volcano). These typically display end-member concentrations ranging from 16 to 23 mM (Si) and 150 to 280 nM (Ge), and end-member Ge/Si ratios clustering between 8 and 14 × 10−6, more than 10-fold greater than the ratio entering the ocean via rivers (0.54 × 10−6) and being recycled in seawater (0.7 × 10−6). ‘Excess’ concentrations of dissolved Si and Ge above oceanic background are observed in mid-water hydrothermal plumes over mid-ocean ridge (MOR) spreading centers on the Southern EPR (SEPR) (10°–20°S) and the SJdFR. The largest Si and Ge concentration anomalies occur over the North Cleft Segment of the SJdFR. These are a factor of three greater than anomalies over the SEPR (10°–20°S). Excess Ge correlates with excess3He in plumes at a Ge/3He molar ratio of about 1 × 104, approximately the same ratio as in black smokers. These observations, combined with low abundances of Ge in Fesingle bondMn-rich metalliferous sediments, suggest that Ge (and Si) behave conservatively in mid-ocean ridge hydrothermal plumes. A simple ocean Si and Ge balance, constrained by the global river silica flux and Ge/Si ratios in hydrothermal vents, rivers and biogenic silica, suggests that the global hydrothermal silica flux is about 1–4 × 1011 mole yr−1, much lower than that estimated from3He. Either (1) 70–80% of the Ge flux to the ocean is removed in as-yet undiscovered sinks (not opal), or (2) only 10% of the mantle to ocean3He and heat fluxes is associated with MOR hydrothermal convection through the 350°C isotherm (90% is off-ridge), or (3) the oceanic Ge/Si,3He/ (and87Sr86Sr) balances today are far from steady-state.
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  • 77
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    Elsevier
    In:  Global and Planetary Change, 8 . pp. 1-8.
    Publication Date: 2018-03-08
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  • 78
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    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 167 (1). pp. 91-108.
    Publication Date: 2019-03-13
    Description: A mechanistic account of skeletal density band formation in massive colonies of Porites is developed by linking observations from vital staining of growing skeletons with measurements of density band characteristics, dissepiment spacing and the depth to which skeleton was occupied by tissue. Three growth processes contribute to density band formation. First, addition of new skeleton at the outer surface of the colony. Second, thickening of existing skeleton through the depth of the tissue layer (tissue usually occupies skeleton formed over the last 4–13 months). Third, the density pattern is then modified by periodic and abrupt uplift of the lower margin of the tissue layer which occurs about every 30 days. Uplift is associated with formation of new dissepiments and produces a fine density band at the lower margin of the tissue layer. Less regular, fine bands are formed within the tissue layer probably as a result of variations in calcification at the colonial surface. X-radiography of skeletal slices compresses and combines the results of these mechanisms making it difficult to distinguish the contribution of individual mechanisms to the overall X-ray image. The relative importance of the three mechanisms — extension, thickening and tissue uplift — to overall skeletal growth may differ between individual colonies. Variability in the way the mechanisms operate and combine may account for widely differing reports of coral density banding.
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  • 79
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    In:  Comparative Biochemistry and Physiology Part B: Biochemistry and Molecular Biology, 105 (1). pp. 183-192.
    Publication Date: 2021-01-19
    Description: 1. The salivary enzymes of the octopus Eledone cirrhosa were separated using isoelectric focusing techniques (IEF) and HPLC. 2. The use of casein zymograms allowed the detection of at least 10 caseinolytic bands in analytical IEF gels and a preliminary, based on pI values, is described. 3. There appear to be two salivary chitinases. 4. Using HPLC, it was possible to separate the most cationic of these from the proteolytic enzymes of similar pI.
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  • 80
    Publication Date: 2021-02-25
    Description: The Hg concentration in horned octopus was studied in relation to its biological cycle. The metal was measured in the muscle tissue of specimens of different size, sex and maturity. This species proved to be a strong accumulator of mercury, whose concentration was found to be correlated with length independently of the sex. The relationship with size was found also for the organic form. Consideration was given to the danger of frequent consumption of this cephalopod and to its use as a biomonitor of environmental mercury impact.
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  • 81
    Publication Date: 2016-11-14
    Description: U/Th (TIMS) and 14C (AMS) measurements are presented from two coral cores from the Easter group of the Houtman Abrolhos Islands between 28°S and 29°S on the western continental margin of Australia. The U/Th measurements on the Morley core from Morley Island cover a depth interval from 0.2 m above present sea level to 24.4 m below present sea level and comprise eleven samples. The ages vary between 6320 ± 50 a, at 0.2 m above sea level, and 9809 ± 95 a, at 24.4 m below sea level (all errors are 2σ). The mean growth rate is 7.1 ± 0.9 m/ka. The 14C dates of selected Morley core corals show that the 14C ages are ∼ 1000 a younger than their corresponding U/Th ages, which agrees with previous results. The main purpose of our 14C measurements is to be able to compare them precisely with other coral cores where no U/Th measurements are available. The U/Th measurements of the Suomi core from Suomi Island cover a depth interval from 0.05 m to 14.2 m below present sea level and consist of four samples. The ages vary between 4671 ± 40 a, at 0.05 m below sea level, and 7102 ± 82 a, at 14.2 m below sea level, with a mean growth rate of 5.8 ± 0.2 m/ka. The growth history of both cores is explained by a simple model in which the growth rates of the Morley core can be interpreted as reflecting local rates of sea level rise, whereas the Suomi core is interpreted as reflecting lateral growth during the past ∼ 6000 a. Our results indicate that sea level relative to the western margins of the Australian continent was about 24 m lower than present at about 9800 a B.P. (14C gives a date of 8500 a B.P.). Sea level then rose and reached a highstand, slightly higher than the present position at about 6300 a B.P (14C date: 5500 a). This highstand declined but was still higher than present at 4600 a B.P. This is in agreement with previous observations along the Australian coastal margins and with observations from the Huon peninsula (Papua New Guinea). Our results are very similar to theoretical numerical models, which take into consideration water loading and isostatic compensation and viscous mantle flow. In contrast, coral cores from Barbados show that corals with a 14C age of ∼ 5500 a B.P. are some ∼ 10 m b.p.s.l. We interpret the difference between the Barbados core and the Morley core as resulting from additional “flooding” of Barbados by water redistribution, due to changes in the Earth's geoid but not reflecting global sea level rise or major addition of melt waters over the past ∼ 6000 a. The difference in the geoid at Barbados between ∼ 6000 a B.P. and the present will require a refinement in the geophysical models. Precise230Th (TIMS) measurements on continental coasts will be required to provide an adequate data base for modelling deformation, flow of mantle material and sea-level height
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  • 82
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (4). pp. 727-737.
    Publication Date: 2019-09-23
    Description: Coupling between surface water plankton and abyssal benthos was investigated during a mass development of salps (Salpa fusiformis) in the Northeast Atlantic. Cyanobacteria numbers and composition of photosynthetic pigments were determined in faeces of captured salps from surface waters, sediment trap material, detritus from plankton hauls, surface sediments from 4500–4800 m depth and Holothurian gut contents. Cyanobacteria were found in all samples containing salp faeces and also in the guts of deep-sea Holothuria. The ratio between zeaxanthin (typical of cyanobacteria) and sum of chlorophyll a pigments was higher in samples from the deep sea when compared to fresh salp faeces, indicating that this carotenoid persisted longer in the sedimenting material than total chlorophyll a pigments. The microscopic and chemical observations allowed us to trace sedimenting salp faeces from the epipelagial to the abyssal benthos, and demonstrated their role as a fast and direct link between both systems. Cyanobacteria may provide a simple tracer for sedimenting phytodetritus.
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  • 83
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    In:  Earth and Planetary Science Letters, 116 (1-4). pp. 81-99.
    Publication Date: 2016-11-14
    Description: Seabeam mapping in the central Pacific Ocean, southeast of Pitcairn Island, has revealed a number of large volcanic edifices, some of which appear to be currently active. Here we document the first isotope and trace element data obtained for dredge samples from these volcanoes which are believed to represent the present-day surface expression of the Pitcairn mantle plume. Striking linear trends in multi-isotope plots suggest the operation of a simple two-component mixing process in the genesis of these lavas with end-members of extreme EM-I and isotopically more depleted type. Isotope-trace element covariations allow limits to be placed upon the composition of the Pitcairn plume source, which is then compared with other EM-type oceanic islands. Current hypotheses for the generation of EM components are then evaluated in the light of these data. Temporal trends, similar to those seen on Pitcairn Island, are present within the seamount data, although samples equivalent to the post-shield formations on Pitcairn Island are not observed. These evolutionary trends suggest a high level origin for the depleted component rather than entrainment of asthenospheric material into a rising diapir. Three of the Pitcairn seamounts are much older, in the region of 20–25 Ma, and were probably formed in a near-ridge environment.
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  • 84
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    In:  Earth and Planetary Science Letters, 120 (3-4). pp. 103-109.
    Publication Date: 2016-11-14
    Description: The geochemistry of mid-oceanic ridge basalts from 86°N (Arctic Ocean) provides, for the first time, an insight into the composition of the mantle around the North Pole. Our data show the source region of the Arctic basalts to possess traces of an enrichment similar to the DUPAL signature. This is remarkable since up to now the DUPAL signature has been believed to be present only in Indian but not in Atlantic or Pacific MORB. These results also argue against a model of whole-mantle convection, in which upwelling of enriched material at the equator is balanced by downwelling of depleted material at the poles
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  • 85
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    In:  Dry coastal ecosystems in the Northern Baltic Sea | Dry coastal ecosystems. Polar regions and Europe, 2
    Publication Date: 2022-03-21
    Type: info:eu-repo/semantics/bookPart
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  • 86
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    Elsevier
    In:  Methodological Requirements for Regional Models | Eurosim 92 Simulation Congress
    Publication Date: 2022-03-21
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  • 87
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 54, no. XVI:, pp. 9-66, (ISBN: 3486274473, 2. Auflage 2004, xxiv, 244 Seiten)
    Publication Date: 1992
    Keywords: FractureT ; Geol. aspects ; Seismicity ; Statistical investigations
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  • 88
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    Elsevier
    In:  Bull., Polar Proj. OP-O3A4, Continental Lower Crust, Amsterdam, Elsevier, vol. 4, no. Subvol. b, pp. 45, (ISBN 0080419208)
    Publication Date: 1992
    Keywords: Reflectivity ; Review article ; Reflection seismics ; CRUST ; Meissner
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  • 89
    Publication Date: 2020-07-31
    Description: Distribution and abundance of the horned octopus Eledone cirrhosa in the Tyrrhenian Sea are described on the basis of stratified-random bottom trawl surveys in spring and summer of the years 1985–1987. Specimens were caught between 25 and 630 m depth (higher densities between 50 and 200 m depth); mature males were found to prefer deeper bottoms than mature females. Young specimens occurred in spring samples from the Western Ligurian Sea and in summer samples from the Lower Tyrrhenian Sea, but were scarcely represented in the Higher Tyrrhenian Sea. Thus recruitment seems to be progressively delayed later in the season from north to south. The greatest abundance was recorded in the Higher Tyrrhenian Sea; wide seasonal variations of minimum stock biomass estimates have been observed and total biomass decreased from 1985 to 1987 in the surveyed areas.
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  • 90
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    Unknown
    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 163 (2). pp. 261-276.
    Publication Date: 2017-03-29
    Description: An investigation was carried out on the morphology, growth and microstructure of statoliths of 833 specimens of Sthenoteuthis pteropus (Steenstrup) mantle length (ML): 2–548 mm collected in the open waters of the Gulf of Guinea in 1984–1988. Statolith morphology is similar to that of other species of the subfamily Ommastrephinae and is similar to the sibling species S. oulaniensis. Statolith development includes five stages resembling those of Illex illecebrosus and other ommastrephids. Statolith growth is characterized by negative allometry. Increments visible in ground sections of statoliths can be grouped into four main growth zones, differing mainly in colour and increment width. Age and growth rates of S. pteropus were calculated using increment counts. The life span of females of all size groups does not exceed 1 yr, that of males is 1–2 months shorter, probably due to preliminary mating. Instantaneous relative growth rage (G) of paralarvae is high (up to 16% of body weight (BW)). G values for juveniles decline, but remain relatively high (7–8% BW). Juveniles attain 100–110 mm ML by age 100–110 days. G values for adults are the lowest (1.8–2% BW), but daily growth rates reach maximum values (40–70 g per day in large females of 450–500 mm ML). Each ontogenetic phase of S. pteropus corresponds to features of morphology, growth and microstructure of the statolith.
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  • 91
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    Unknown
    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 162 (2). pp. 229-241.
    Publication Date: 2018-03-16
    Description: The presented data on indirect and direct calorimetry in Halicryptus spinulosus, a species with prominent ecological significance in parts of the Baltic Sea, provide a basis for a better understanding of the metabolic adaptation of these animals to low oxygen availability in their environment. Metabolic rates in H. spinulosus were measured respirometrically as oxygen consumption and calorimetrically as heat dissipation. Oxygen uptake rates are in the range of M O2 = 3.81 ± 1.37 μmol O2·g−1 dry mass·h−1. Upon reimmersion into normoxic seawater after an anoxic incubation of 7 days, the animals exhibit an overshoot of oxygen consumption by a factor of 2.4. It takes at least 2 days for the animals to balance their oxygen consumption to previously measured rates. Direct calorimetry exhibits different strategies of H. spinulosus to cope with declining oxygen and anoxia. During the first 2 transitional days to anoxia in the calorimeter, the animals decreased heat dissipation moderately down to 53.4 and 26%, respectively, of aerobic values. The animals are not necessarily quiescent at the beginning of anoxia, but at the end of the experiments after 14 days metabolic rates have dropped substantially down to ≈2% of normoxic values. These findings are discussed with regard to an effective adaption to frequently changing oxygen regimes in deeper parts of the Baltic Sea.
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  • 92
    Publication Date: 2018-03-15
    Description: CO2 partial pressure in surface water was measured in the Northeast Atlantic and in the Hebride Shelf/North Sea area during a cruise with R.V. Poseidon in June 1991. A mean pCO2 of 303 μatm was found in the Atlantic between 50°N and 60°N. For an atmospheric CO2 content of 357.5 ppm(v) this corresponds to a partial pressure difference of −55 μatm. This supports the view that the subarctic Atlantic is a significant sink within the CO2 cycle between the ocean and the atmosphere. A comparison of our measurements with other data reveals that the pCO2 distribution changes significantly during May/June. This explained by seasonal warming, CO2 exchange with the atmosphere and biomass production. The contribution by each of these processes to the seasonal variations is calculated. It was found that during a plankton bloom the production of biomass is the dominating factor and may lower seawater pCO2 by almost 100 μatm. The shelf areas are charactrized by strong pCO2 gradients which are explained by water exchange with the Atlantic, temperature effects and biomass production.
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  • 93
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    Unknown
    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 158 (1). pp. 105-121.
    Publication Date: 2017-01-23
    Description: Sixteen samples (588 individuals) of the Argentine shortfin squid Illex argentinus were collected by commercial vessels from Falkland and surrounding waters (42°06–51°17S) between February and May 1990 and subjected to starch gel electrophoresis. Levels of electrophoretically detectable generic variability and the extent of population differentiation were determined from allele frequencies at 25 enzyme-coding loci. Low levels of genetic variability were detected, with the overall proportion of polymorphic loci, P = 0.28, mean heterozygosities per locus, H1 = 0.011, and the average effective number of alleles, Nc = 1.23. Marked population differentiation was indicated by significant differences in allele frequency among samples, and unbalanced genotypic distributions with heterozygote deficits at most loci. Nei's mean genetic distances (D) and identities (I) ranged from 0.000 to 0.130 and 1.000 to 0.878, respectively, underlining the marked genetic divergence detected. Some evidence of microgeographic differentiation (between replicates within sites) was observed. Individuals collected from northerly limits of the sampled area (42: 06 S, 58:09 W) were most genetically distinct (I = 0.878−0.904), suggesting the existence of a hitherto unrecognised subspecies or species of Illex. Emphasis is placed on the need to delimit putative stock boundaries, and develop appropriate population models to ensure conservation of genetic resources.
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  • 94
    Publication Date: 2017-06-23
    Description: Coccolith and dinoflagellate cyst assemblages have been investigated in five sediment cores from the Norwegian Sea and Fram Strait. Both fossil groups are characterized by similar patterns of composition. The assemblages contain high proportions of single species. The coccolith flora is of low diversity and consists almost entirely of Coccolithus pelagicus and Emiliania huxleyi. The dinoflagellate cysts are generally dominated by Operculodinium centrocarpum and Nematosphaeropsis labyrinthus. Other species, especially Bitectatodinium tepikiense, Peridinium faeroense and Impagidinium pallidum, sometimes contribute considerably to the assemblages. Based on the abundance of the assemblages and the ratio change between the dominating species it has been possible to establish three intervals of distinct major changes in surface water mass conditions. Sparse occurrences of coccoliths and dinoflagellate cysts have been observed before 10,000 yrs. B.P., indicating harsh environmental conditions with a distinct influence of meltwater and temporarily very slight inflow of Atlantic water. The modern surface-water circulation pattern was reinitiated during Termination IB. The assemblages suggest slightly cooler and probably less saline surface water conditions than are present today until 7500 yrs B.P. Solar insolation may have caused a first temperature peak which is responsible for the early Holocene productivity maximum. A considerable change in the composition of dinocyst and coccolith assemblages occurs corresponding approximately to the onset of the Holocene climatic optimum. This change was most probably linked to an almost synchronous reorganization of the hydrographic properties in the entire North Atlantic realm after the ice sheets had vanished. Since 6000 yrs B.P. the Norwegian Current with its modern oceanographic and ecological properties has been fully established.
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  • 95
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    Unknown
    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 156 (2). pp. 161-178.
    Publication Date: 2017-01-27
    Description: The alimentary tracts of 12 species of Antarctic squid were examined visually and serologically for the presence of Euphausia superba. Only four species, Alluroteuthis antarcticus, Galiteuthis glacialis, Martialia hyadesi and Psychroteuthis glacialis, contained material which was identifiable to species visually. Myctophid fish and euphausiids were the most common prey item. Serology showed that specimens of six species had eaten euphausiids. Where antisera showed cross-reactions with other potential prey species, biogeographical and haul data was used to determine the species of Euphausia consumed. P. glacialis (n=19) had consumed E. superba. Mastigoteuthis psychrophila (n=10) had eaten E. superba and/or E. triacantha. Brachioteuthis picta (n=6), M. hyadesi (n=27), and two Moroteuthis spp. (n=2) had consumed unidentified euphausiids. Bathyteuthis abyssicola (n=13) and Histioteuthis eltaninae (n=13) had not preyed on euphausiids. B. picta appeared to have fed in the net.
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  • 96
    Publication Date: 2019-02-15
    Description: Analysis of growth by year of hatching was estimated from the statolith growth increments of the oceanic squid Todarodes angolensis in three consecutive years. Samples were taken between November 1987 and February 1990 in the northern Benguela upwelling system. Growth increments suggested that hatching took place throughout the year and that the life cycle was ≈ 1 yr. From the onset of sexual maturity in the final third of the life cycle, growth rates were subject to considerable individual variation. Growth rate was significant highest in the 1987 year class, presumably because of exceptionally cool environmental conditions in the Benguela region. The response of T. angolensis to interannual environmental variability in the northern Benguela system is discussed. The results from this study suggest that it will be important to consider variability in growth rate in relation to environmental conditions, in future studies of squid age and growth.
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  • 97
    Publication Date: 2020-06-10
    Description: A central tenet of Antarctic ecology suggests that increases in Chinstrap Penguin (Pygoscelis antarctica) populations during the last four decades resulted from an increase in prey availability brought on by the decrease in baleen whale stocks. We question this tenet and present evidence to support the hypothesis that these increases are due to a gradual decrease in the frequency of cold years with extensive winter sea ice cover resulting from environmental warming. Supporting data were derived from one of the first, major multidisciplinary winter expedition to the Scotia and Weddell seas; recent satellite images of ocean ice cover; and the analysis of long-term surface temperature records and penguin demography. Our observations indicate there is a need to pay close attention to environmental data in the management of Southern Ocean resources given the complexity of relating biological changes to ecological perturbations.
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  • 98
    facet.materialart.
    Unknown
    Elsevier
    In:  Polar Biology, 12 (6-7). pp. 659-665.
    Publication Date: 2020-06-10
    Description: The seabird and seal community at Heard Island and the McDonald Islands comprised an estimated total biomass of 27893 tonnes of which the 15 breeding species of seabirds made up 70%. The total annual consumption of marine resources was estimated to be approximately 521 000 t, of which 81% was consumed by seabirds Approximately 165 000 t of fish, 41 600 t of squid and 312 000 t of crustaceans are consumed annually by this seabird and seal community. The annual energy flux to this community was estimated to be 2.17·1012 kJ and approximately 56 000 t of carbon are consumed annually. Breeding populations of King Penguins and Antarctic Fur Seals are increasing, that of the Southern Elephant Seal is decreasing; there are no data on the population trend for Macaroni Penguins, the predominant consumer species. Commercial fisheries are presently operating at the nearby Iles Kerguelen, and similar activities may prove to be commercially viable at Heard Island. The fishery is for Champsocephalus gunnari, a major prey species of penguins and Antarctic Fur Seals at Heard Island during the summer breeding season.
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  • 99
    Publication Date: 2018-03-20
    Description: Oil released into the sea undergoes immediate compositional changes as a result of processes of volatilization, dissolution, particle adsorption, and microbial and photochemical decomposition. Based on our observation of the molecular composition of oil residues dissolved in subtropical ocean waters, we hypothesized photo-oxidation of alkyl-substituted polycyclic aromatic hydrocarbons (PAH) and heterocyclic aromatics in preference to their unsubstituted parent compounds. As the ratios of alkyl to parent PAH are used to assign sources to contaminant residues in environmental samples, we tested the hypothesis in a controlled experiment: membrane-filtered seawater collected near the island of Bermuda was saturated with a Nigerian crude oil and exposed to natural sunlight in a quartz flask. Comparison with a dark control under otherwise identical conditions served to differentiate between sunlight-induced and microbially mediated decreases in concentration and changes in composition. We conclude on the basis of UV fluorescence, GC-MS, and microbiological data that sunlight-induced oxidation is responsible for the rapid loss of the UV fluorescence signal for total aromatic hydrocarbons and for the preferential depletion of the alkyl-substituted PAH and heterocyclic aromatics. Structure-dependent selectivity in the photo-oxidation of dissolved oil residues may thus result in residual hydrocarbon blends which could be mistaken as originating from incomplete combustion processes.
    Type: Article , PeerReviewed
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  • 100
    Publication Date: 2017-06-22
    Description: The Neogene Bolboforma zones established in the North Atlantic have been correlated with the calcareous nannoplankton stratigraphy obtained by investigation of the same samples from DSDP Sites 12–116 (44 samples), 49–408 (76 samples), 81–555 (43 samples) and 94–608 (103 samples). The absolute ages for the zonal boundaries were determined by the paleomagmetic record of Site 94–608. This correlation and the age determinations are additional useful tools to develop a precise biostratigraphy of Neogene sediments in the Northern Atlantic.
    Type: Article , PeerReviewed
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