ALBERT

Description: A new 21.3m firn core was drilled in 2015 at a coastal Antarctic high-accumulation site in Adélie Land (66.78◦ S; 139.56◦ E, 602 m a.s.l.), named Terre Adélie 192A (TA192A). The mean isotopic values (−19.3 ‰ ± 3.1 ‰ for δ18O and 5.4 ‰±2.2 ‰ for deuterium excess) are consistent with other coastal Antarctic values. No significant isotope–temperature relationship can be evidenced at any timescale. This rules out a simple interpretation in terms of local temperature. An observed asymmetry in the δ18O seasonal cycle may be explained by the precipitation of air masses coming from the eastern and western sectors in autumn and winter, recorded in the d-excess signal showing outstanding values in austral spring versus autumn. Significant positive trends are observed in the annual d-excess record and local sea ice extent (135–145◦ E) over the period 1998–2014. However, process studies focusing on resulting isotopic compositions and particularly the deuterium excess–δ18O relationship, evidenced as a potential fingerprint of moisture origins, as well as the collection of more isotopic measurements in Adélie Land are needed for an accurate interpretation of our signals.

Description: The timing and intensity of snowmelt processes on sea ice are key drivers determining the seasonal sea-ice energy and mass budgets. In the Arctic, satellite passive microwave and radar observations have revealed a trend towards an earlier snowmelt onset during the last decades, which is an important aspect of Arctic amplification and sea ice decline. Around Antarctica, snowmelt on perennial ice is weak and very different than in the Arctic, with most snow surviving the summer. Here we compile time series of snowmelt-onset dates on seasonal and perennial Antarctic sea ice from 1992 to 2014/15 using active microwave observations from European Remote Sensing Satellite (ERS-1/2), Quick Scatterometer (QSCAT) and Advanced Scatterometer (ASCAT) radar scatterometers. We define two snowmelt transition stages: A weak backscatter rise indicating the initial warming and destructive metamorphism of the snowpack (pre-melt), followed by a rapid backscatter rise indicating the onset of thaw-freeze cycles (snowmelt). Results show large interannual variability with an average pre-melt onset date of 29 November and melt onset of 10 December, respectively, on perennial ice, without any significant trends over the study period, consistent with the small trends of Antarctic sea ice extent. There was a latitudinal gradient from early snowmelt onsets in mid-November in the northern Weddell Sea to late (end-December) or even absent snowmelt conditions in the southern Weddell Sea. We show that QSCAT Ku-band (13.4 GHz signal frequency) derived pre-melt and snowmelt onset dates are earlier by 20 and 18 days, respectively, than ERS and ASCAT C-band (5.6 GHz) derived dates. This offset has been considered when constructing the time series. Snowmelt onset dates from passive microwave observations (37 GHz) are later by 14 and 6 days than those from the scatterometers, respectively. Based on these characteristic differences between melt onset dates observed by different microwave wavelengths, we developed a conceptual model which illustrates how the seasonal evolution of snow temperature profiles may affect different microwave bands with different penetration depths. These suggest that future multi-frequency active/passive microwave satellite missions could be used to resolve melt processes throughout the vertical snow column of thick snow on perennial Antarctic sea ice.

Description: Although quantitative isotope data from speleothems has been used to evaluate isotope-enabled model simulations, currently no consensus exists regarding the most appropriate methodology through which to achieve this. A number of modelling groups will be running isotope-enabled palaeoclimate simulations in the framework of the Coupled Model Intercomparison Project Phase 6, so it is timely to evaluate different approaches to using the speleothem data for data–model comparisons. Here, we illustrate this using 456 globally distributed speleothem δ18O records from an updated version of the Speleothem Isotopes Synthesis and Analysis (SISAL) database and palaeoclimate simulations generated using the ECHAM5-wiso isotope-enabled atmospheric circulation model. We show that the SISAL records reproduce the first-order spatial patterns of isotopic variability in the modern day, strongly supporting the application of this dataset for evaluating model-derived isotope variability into the past. However, the discontinuous nature of many speleothem records complicates the process of procuring large numbers of records if data–model comparisons are made using the traditional approach of comparing anomalies between a control period and a given palaeoclimate experiment. To circumvent this issue, we illustrate techniques through which the absolute isotope values during any time period could be used for model evaluation. Specifically, we show that speleothem isotope records allow an assessment of a model’s ability to simulate spatial isotopic trends. Our analyses provide a protocol for using speleothem isotope data for model evaluation, including screening the observations to take into account the impact of speleothem mineralogy on δ18O values, the optimum period for the modern observational baseline and the selection of an appropriate time window for creating means of the isotope data for palaeo-time-slices.

Description: We present here the first results, for the preindustrial and mid-Holocene climatological periods, of the newly developed isotope-enhanced version of the fully coupled Earth system model MPI-ESM, called hereafter MPI-ESM-wiso. The water stable isotopes H16O, H18O and HDO have been implemented into all components of the coupled model setup. The mid-Holocene provides the opportunity to evaluate the model response to changes in the seasonal and latitudinal distribution of insolation induced by different orbital forcing conditions. The results of our equilibrium simulations allow us to evaluate the performance of the isotopic model in simulating the spatial and temporal variations of water isotopes in the different compartments of the hydrological system for warm climates. For the preindustrial climate, MPI-ESM-wiso reproduces very well the observed spatial distribution of the isotopic content in precipitation linked to the spatial variations in temperature and precipitation rate. We also find a good model–data agreement with the observed distribution of isotopic composition in surface seawater but a bias with the presence of surface seawater that is too 18O-depleted in the Arctic Ocean. All these results are improved compared to the previous model version ECHAM5/MPIOM. The spatial relationships of water isotopic composition with temperature, precipitation rate and salinity are consistent with observational data. For the preindustrial climate, the interannual relationships of water isotopes with temperature and salinity are globally lower than the spatial ones, consistent with previous studies. Simulated results under mid-Holocene conditions are in fair agreement with the isotopic measurements from ice cores and continental speleothems. MPI-ESM-wiso simulates a decrease in the isotopic composition of precipitation from North Africa to the Tibetan Plateau via India due to the enhanced monsoons during the mid-Holocene. Over Greenland, our simulation indicates a higher isotopic composition of precipitation linked to higher summer temperature and a reduction in sea ice, shown by positive isotope–temperature gradient. For the Antarctic continent, the model simulates lower isotopic values over the East Antarctic plateau, linked to the lower temperatures during the mid-Holocene period, while similar or higher isotopic values are modeled over the rest of the continent. While variations of isotopic contents in precipitation over West Antarctica between mid-Holocene and preindustrial periods are partly controlled by changes in temperature, the transport of relatively 18O-rich water vapor near the coast to the western ice core sites could play a role in the final isotopic composition. So, more caution has to be taken about the reconstruction of past temperature variations during warm periods over this area. The coupling of such a model with an ice sheet model or the use of a zoomed grid centered on this region could help to better describe the role of the water vapor transport and sea ice around West Antarctica. The reconstruction of past salinity through isotopic content in sea surface waters can be complicated for regions with strong ocean dynamics, variations in sea ice regimes or significant changes in freshwater budget, giving an extremely variable relationship between the isotopic content and salinity of ocean surface waters over small spatial scales. These complicating factors demonstrate the complexity of interpreting water isotopes as past climate signals of warm periods like the mid-Holocene. A systematic isotope model intercomparison study for further insights on the model dependency of these results would be beneficial.

Description: In this study, we present results obtained from modelling the mid-Pliocene warm period using the Community Earth System Models (COSMOS, version: COSMOS-landveg r2413, 2009) with the two different sets of boundary conditions prescribed for the two phases of the Pliocene Model Intercomparison Project (PlioMIP). Boundary conditions, model forcing, and modelling methodology of the two phases of PlioMIP, tagged PlioMIP1 and PlioMIP2,differ considerably in palaeogeography, in particular with regards to the state of ocean gateways, ice-masks, vegetation and topography. Further differences between model setups as suggested for PlioMIP1 and PlioMIP2 consider updates to the concentration of atmospheric carbon dioxide (CO2), that is specified as 405 and 400 parts per million by volume (ppmv) for PlioMIP1 and PlioMIP2, respectively, as well as minor differences in the concentrations of methane (CH4) and nitrous oxide (N2O) due to changes in the protocol of the Paleoclimate Model Intercomparison Project (PMIP) from phase 3 to phase 4. With this manuscript, we bridge the gap between our contributions to PlioMIP1 (Stepanek and Lohmann, 2012) and PlioMIP2 (Stepanek et al., 2019). We highlight some of the effects that differences in the chosen Mid-Pliocene model setup (PlioMIP2 vs. PlioMIP1) have on the climate state as derived with the COSMOS, as this information will be valuable in the framework of the model-model and model-data-comparison within PlioMIP2. We evaluate the model sensitivity to improved mid-Pliocene boundary conditions using PlioMIP’s core mid-Pliocene experiments for PlioMIP1 and PlioMIP2, and present further simulations where we test model sensitivity to variations in palaeogeography, orbit and concentration of CO2. Firstly,we highlight major changes in boundary conditions from PlioMIP1 to PlioMIP2 and also the limitations recorded from the initial effort. The results derived from of our simulations show that COSMOS simulates a mid-Pliocene climate state that is 0.08 K colder in PlioMIP2, if compared to PlioMIP1. On one hand, high-latitude warming,which is supported by proxy evidence of the mid-Pliocene, is underestimated in simulations of both PlioMIP1 andPlioMIP2. On the other hand, spatial variations in surface air temperature (SAT), sea surface temperature (SST) as well as the distribution of sea ice suggest improvement of simulated SAT and SST in PlioMIP2 if employing the updated palaeogeography. The PlioMIP2 Mid-Pliocene simulation produces warmer SSTs in the Arctic and North Atlantic Ocean than derived from the respective PlioMIP1 climate state. The difference in prescribed CO2accountsfor 1.1 K of warming in the Arctic, leading to an ice-free summer in the PlioMIP1 simulation, and a quasi-ice-free summer in PlioMIP2. Furthermore, employing different orbital forcings in simulating the Mid-Pliocene lead to pronounced annual and seasonal variations, which is not accounted for by marine and terrestrial reconstruction of the time-slice.

Description: The Antarctic temperature changes over the past millennia remain more uncertain than in many other continental regions. This has several origins: (1) the number of high-resolution ice cores is small, in particular on the East Antarctic plateau and in some coastal areas in East Antarctica; (2) the short and spatially sparse instrumental records limit the calibration period for reconstructions and the assessment of the methodologies; (3) the link between isotope records from ice cores and local climate is usually complex and dependent on the spatial scales and timescales investigated. Here, we use climate model results, pseudo-proxy experiments and data assimilation experiments to assess the potential for reconstructing the Antarctic temperature over the last 2 millennia based on a new database of stable oxygen isotopes in ice cores compiled in the frame- work of Antarctica2k (Stenni et al., 2017). The well-known covariance between δ18O and temperature is reproduced in the two isotope-enabled models used (ECHAM5/MPI-OM and ECHAM5-wiso), but is generally weak over the different Antarctic regions, limiting the skill of the reconstructions. Furthermore, the strength of the link displays large variations over the past millennium, further affecting the potential skill of temperature reconstructions based on statistical methods which rely on the assumption that the last decades are a good estimate for longer temperature reconstructions. Using a data assimilation technique allows, in theory, for changes in the δ18O–temperature link through time and space to be taken into account. Pseudoproxy experiments confirm the benefits of using data assimilation methods instead of statistical methods that provide reconstructions with unrealistic variances in some Antarctic subregions. They also confirm that the relatively weak link between both variables leads to a limited potential for reconstructing temperature based on δ18O. However, the reconstruction skill is higher and more uniform among reconstruction methods when the reconstruction target is the Antarctic as a whole rather than smaller Antarctic subregions. This consistency between the methods at the large scale is also observed when reconstructing temperature based on the real δ18O regional composites of Stenni et al. (2017). In this case, temperature reconstructions based on data assimilation confirm the long-term cooling over Antarctica during the last millennium, and the later onset of anthropogenic warming compared with the simulations without data assimilation, which is especially visible in West Antarctica. Data assimilation also allows for models and direct observations to be reconciled by reproducing the east–west contrast in the recent temperature trends. This recent warming pattern is likely mostly driven by internal variability given the large spread of individual Paleoclimate Modelling Intercomparison Project (PMIP)/Coupled Model Intercomparison Project (CMIP) model realizations in simulating it. As in the pseudoproxy framework, the reconstruction methods perform differently at the subregional scale, especially in terms of the variance of the time series produced. While the potential benefits of using a data assimilation method instead of a statistical method have been highlighted in a pseudoproxy framework, the instrumental series are too short to confirm this in a realistic setup.

Description: Ice-wedge polygons are common features of lowland tundra in the continuous permafrost zone and prone to rapid degradation through melting of ground ice. There are many interrelated processes involved in ice-wedge thermokarst and it is a major challenge to quantify their influence on the stability of the permafrost underlying the landscape. In this study we used a numerical modelling approach to investigate the degradation of ice wedges with a focus on the influence of hydrological conditions. Our study area was Samoylov Island in the Lena River delta of northern Siberia, for which we had in situ measurements to evaluate the model. The tailored version of the CryoGrid 3 land surface model was capable of simulating the changing microtopography of polygonal tundra and also regarded lateral fluxes of heat, water, and snow. We demonstrated that the approach is capable of simulating ice-wedge degradation and the associated transition from a low-centred to a high-centred polygonal microtopography. The model simulations showed ice-wedge degradation under recent climatic conditions of the study area, irrespective of hydrological conditions. However, we found that wetter conditions lead to an earlier onset of degradation and cause more rapid ground subsidence. We set our findings in correspondence to observed types of ice-wedge polygons in the study area and hypothesized on remaining discrepancies between modelled and observed ice-wedge thermokarst activity. Our quantitative approach provides a valuable complement to previous, more qualitative and conceptual, descriptions of the possible pathways of ice-wedge polygon evolution. We concluded that our study is a blueprint for investigating thermokarst landforms and marks a step forward in understanding the complex interrelationships between various processes shaping ice-rich permafrost landscapes.

Description: Warming of the Arctic led to an increase in permafrost temperatures by about 0.3 �C during the last decade. Permafrost warming is associated with increasing sediment water content, permeability, and diffusivity and could in the long term alter microbial community composition and abundance even before permafrost thaws. We studied the long-term effect (up to 2500 years) of submarine permafrost warming on microbial communities along an onshore–offshore transect on the Siberian Arctic Shelf displaying a natural temperature gradient of more than 10 �C. We analysed the in situ development of bacterial abundance and community composition through total cell counts (TCCs), quantitative PCR of bacterial gene abundance, and amplicon sequencing and correlated the microbial community data with temperature, pore water chemistry, and sediment physicochemical parameters. On timescales of centuries, permafrost warming coincided with an overall decreasing microbial abundance, whereas millennia after warming microbial abundance was similar to cold onshore permafrost. In addition, the dissolved organic carbon content of all cores was lowest in submarine permafrost after millennial-scale warming. Based on correlation analysis, TCC, unlike bacterial gene abundance, showed a significant rank-based negative correlation with increasing temperature, while bacterial gene copy numbers showed a strong negative correlation with salinity. Bacterial community composition correlated only weakly with temperature but strongly with the pore water stable isotopes �18O and �D, as well as with depth. The bacterial community showed substantial spatial variation and an overall dominance of Actinobacteria, Chloroflexi, Firmicutes, Gemmatimonadetes, and Proteobacteria, which are amongst the microbial taxa that were also found to be active in other frozen permafrost environments. We suggest that, millennia after permafrost warming by over 10 �C, microbial community composition and abundance show some indications for proliferation but mainly reflect the sedimentation history and paleoenvironment and not a direct effect through warming.

Description: The Global Ocean Data Analysis Project (GLODAP) is a synthesis effort providing regular compilations of surface to bottom ocean biogeochemical data, with an emphasis on seawater inorganic carbon chemistry and related variables determined through chemical analysis of water samples. This update of GLODAPv2, v2.2019, adds data from 116 cruises to the previous version, extending its coverage in time from 2013 to 2017, while also adding some data from prior years. GLODAPv2.2019 includes measurements from more than 1.1 million water samples from the global oceans collected on 840 cruises. The data for the 12 GLODAP core variables (salinity, oxygen, nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity, pH, CFC-11, CFC-12, CFC-113, and CCl4) have undergone extensive quality control, especially systematic evaluation of bias. The data are available in two formats: (i) as submitted by the data originator but updated to WOCE exchange format and (ii) as a merged data product with adjustments applied to minimize bias. These adjustments were derived by comparing the data from the 116 new cruises with the data from the 724 quality-controlled cruises of the GLODAPv2 data product. They correct for errors related to measurement, calibration, and data handling practices, taking into account any known or likely time trends or variations. The compiled and adjusted data product is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 µmol kg−1 in dissolved inorganic carbon, 4 µmol kg−1 in total alkalinity, 0.01–0.02 in pH, and 5 % in the halogenated transient tracers. The compilation also includes data for several other variables, such as isotopic tracers. These were not subjected to bias comparison or adjustments. The original data, their documentation and DOI codes are available in the Ocean Carbon Data System of NOAA NCEI (https://www.nodc.noaa.gov/ocads/oceans/GLODAPv2_2019/, last access: 17 September 2019). This site also provides access to the merged data product, which is provided as a single global file and as four regional ones – the Arctic, Atlantic, Indian, and Pacific oceans – under https://doi.org/10.25921/xnme-wr20 (Olsen et al., 2019). The product files also include significant ancillary and approximated data. These were obtained by interpolation of, or calculation from, measured data. This paper documents the GLODAPv2.2019 methods and provides a broad overview of the secondary quality control procedures and results.

Description: We present a Lagrangian convective transport scheme developed for global chemistry and transport models, which considers the variable residence time that an air parcel spends in convection. This is particularly important for accurately simulating the tropospheric chemistry of short-lived species, e.g., for determining the time available for heterogeneous chemical processes on the surface of cloud droplets. In current Lagrangian convective transport schemes air parcels are stochastically redistributed within a fixed time step according to estimated probabilities for convective entrainment as well as the altitude of detrainment. We introduce a new scheme that extends this approach by modeling the variable time that an air parcel spends in convection by estimating vertical updraft velocities. Vertical updraft velocities are obtained by combining convective mass fluxes from meteorological analysis data with a parameterization of convective area fraction profiles. We implement two different parameterizations: a parameterization using an observed constant convective area fraction profile and a parameterization that uses randomly drawn profiles to allow for variability. Our scheme is driven by convective mass fluxes and detrainment rates that originate from an external convective parameterization, which can be obtained from meteorological analysis data or from general circulation models. We study the effect of allowing for a variable time that an air parcel spends in convection by performing simulations in which our scheme is implemented into the trajectory module of the ATLAS chemistry and transport model and is driven by the ECMWF ERA-Interim reanalysis data. In particular, we show that the redistribution of air parcels in our scheme conserves the vertical mass distribution and that the scheme is able to reproduce the convective mass fluxes and detrainment rates of ERA-Interim. We further show that the estimated vertical updraft velocities of our scheme are able to reproduce wind profiler measurements performed in Darwin, Australia, for velocities larger than 0.6 m s−1. SO2 is used as an example to show that there is a significant effect on species mixing ratios when modeling the time spent in convective updrafts compared to a redistribution of air parcels in a fixed time step. Furthermore, we perform long-time global trajectory simulations of radon-222 and compare with aircraft measurements of radon activity.

Description: Holocene permafrost from ice wedge polygons in the vicinity of large seabird breeding colonies in the Thule District, NW Greenland, was drilled to explore the relation between permafrost aggradation and seabird presence. The latter is reliant on the presence of the North Water Polynya (NOW) in the northern Baffin Bay. The onset of peat accumulation associated with the arrival of little auks (Alle alle) in a breeding colony at Annikitisoq, north of Cape York, is radiocarbon-dated to 4400 cal BP. A thick-billed murre (Uria lomvia) colony on Appat (Saunders Island) in the mouth of the Wolstenholme Fjord started 5650 cal BP. Both species provide marine-derived nutrients (MDNs) that fertilize vegetation and promote peat growth. The geochemical signature of organic matter left by the birds is traceable in the frozen Holocene peat. The peat accumulation rates at both sites are highest after the onset, decrease over time, and were about 2-times faster at the little auk site than at the thick-billed murre site. High accumulation rates induce shorter periods of organic matter (OM) decomposition before it enters the perennially frozen state. This is seen in comparably high C=N ratios and less depleted 13C, pointing to a lower degree of OM decomposition at the little auk site, while the opposite pattern can be discerned at the thick-billed murre site. Peat accumulation rates correspond to 15N trends, where decreasing accumulation led to increasing depletion in 15N as seen in the little-auk-related data. In contrast, the more decomposed OM of the thick-billed murre site shows almost stable 15N. Late Holocene wedge ice fed by cold season precipitation was studied at the little auk site and provides the first stable-water isotopic record from Greenland with mean 18O of 8:00:8, mean D of 36:25:7, mean d excess of 7:70:7, and a 18O-D slope of 7.27, which is close to those of the modern Thule meteoric water line. The syngenetic ice wedge polygon development is mirrored in testacean records of the little auk site and delineates polygon low-center, dry-out, and polygon-high-center stages. The syngenetic permafrost formation directly depending on peat growth (controlled by bird activity) falls within the period of neoglacial cooling and the establishment of the NOW, thus indirectly following the Holocene climate trends.

Description: 〈b〉Ensemble forecasts of air quality in eastern China – Part 1: Model description and implementation of the MarcoPolo–Panda prediction system, version 1〈/b〉〈br〉 Guy P. Brasseur, Ying Xie, Anna Katinka Petersen, Idir Bouarar, Johannes Flemming, Michael Gauss, Fei Jiang, Rostislav Kouznetsov, Richard Kranenburg, Bas Mijling, Vincent-Henri Peuch, Matthieu Pommier, Arjo Segers, Mikhail Sofiev, Renske Timmermans, Ronald van der A, Stacy Walters, Jianming Xu, and Guangqiang Zhou〈br〉 Geosci. Model Dev., 12, 33-67, https://doi.org/10.5194/gmd-12-33-2019, 2019〈br〉 An operational multi-model forecasting system for air quality provides daily forecasts of ozone, nitrogen oxides, and particulate matter for 37 urban areas in China. The paper presents an intercomparison of the different forecasts performed during a specific period of time and highlights recurrent differences between the model output. Pathways to improve the forecasts by the multi-model system are suggested.

Description: 〈b〉RandomFront 2.3: a physical parameterisation of fire spotting for operational fire spread models – implementation in WRF-SFIRE and response analysis with LSFire+〈/b〉〈br〉 Andrea Trucchia, Vera Egorova, Anton Butenko, Inderpreet Kaur, and Gianni Pagnini〈br〉 Geosci. Model Dev., 12, 69-87, https://doi.org/10.5194/gmd-12-69-2019, 2019〈br〉 Wildfires are a concrete problem and impact on human life, property and the environment. An extremely dangerous phenomenon is so-called 〈q〉fire spotting〈/q〉, i.e., the generation of secondary ignitions responsible for dangerous flare-ups during wildfires. The aim of this research was to improve the tools used for risk management through the inclusion of fire spotting in operational wildfire simulators used by forest service agencies.

Description: 〈b〉Vertical characterization of aerosol optical properties and brown carbon in winter in urban Beijing, China〈/b〉〈br〉 Conghui Xie, Weiqi Xu, Junfeng Wang, Qingqing Wang, Dantong Liu, Guiqian Tang, Ping Chen, Wei Du, Jian Zhao, Yingjie Zhang, Wei Zhou, Tingting Han, Qingyun Bian, Jie Li, Pingqing Fu, Zifa Wang, Xinlei Ge, James Allan, Hugh Coe, and Yele Sun〈br〉 Atmos. Chem. Phys., 19, 165-179, https://doi.org/10.5194/acp-19-165-2019, 2019〈br〉 We present the first simultaneous real-time online measurements of aerosol optical properties at ground level and at 260 m on a meteorological tower in urban Beijing in winter. The vertical similarities and differences in scattering and absorption coefficients were characterized. The increases in MAC of BC were mainly associated with the coating materials on rBC. Coal combustion was the dominant source contribution of brown carbon followed by biomass burning and SOA in winter in Beijing.

Description: 〈b〉Dynamic changes in optical and chemical properties of tar ball aerosols by atmospheric photochemical aging〈/b〉〈br〉 Chunlin Li, Quanfu He, Julian Schade, Johannes Passig, Ralf Zimmermann, Daphne Meidan, Alexander Laskin, and Yinon Rudich〈br〉 Atmos. Chem. Phys., 19, 139-163, https://doi.org/10.5194/acp-19-139-2019, 2019〈br〉 〈p〉Following wood pyrolysis, tar ball aerosols were laboratory generated from wood tar separated into polar and nonpolar phases. Chemical information of fresh tar balls was obtained from a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and single-particle laser desorption/resonance enhanced multiphoton ionization mass spectrometry (SP-LD-REMPI-MS). Their continuous refractive index (RI) between 365 and 425 nm was retrieved using a broadband cavity enhanced spectroscopy (BBCES). Dynamic changes in the optical and chemical properties for the nonpolar tar ball aerosols in 〈span〉NO〈sub〉〈i〉x〈/i〉〈/sub〉〈/span〉-dependent photochemical process were investigated in an oxidation flow reactor (OFR). Distinct differences in the chemical composition of the fresh polar and nonpolar tar aerosols were identified. Nonpolar tar aerosols contain predominantly high-molecular weight unsubstituted and alkyl-substituted polycylic aromatic hydrocarbons (PAHs), while polar tar aerosols consist of a high number of oxidized aromatic substances (e.g., methoxy-phenols, benzenediol) with higher O : C ratios and carbon oxidation states. Fresh tar balls have light absorption characteristics similar to atmospheric brown carbon (BrC) aerosol with higher absorption efficiency towards the UV wavelengths. The average retrieved RI is 〈span〉1.661+0.020〈i〉i〈/i〉〈/span〉 and 〈span〉1.635+0.003〈i〉i〈/i〉〈/span〉 for the nonpolar and polar tar aerosols, respectively, with an absorption Ångström exponent (AAE) between 5.7 and 7.8 in the detected wavelength range. The RI fits a volume mixing rule for internally mixed nonpolar/polar tar balls. The RI of the tar ball aerosols decreased with increasing wavelength under photochemical oxidation. Photolysis by UV light (254 nm), without strong oxidants in the system, slightly decreased the RI and increased the oxidation state of the tar balls. Oxidation under varying OH exposure levels and in the absence of 〈span〉NO〈sub〉〈i〉x〈/i〉〈/sub〉〈/span〉 diminished the absorption (bleaching) and increased the O : C ratio of the tar balls. The photobleaching via OH radical initiated oxidation is mainly attributed to decomposition of chromophoric aromatics, nitrogen-containing organics, and high-molecular weight components in the aged particles. Photolysis of nitrous oxide (〈span〉N〈sub〉2〈/sub〉O〈/span〉) was used to simulate 〈span〉NO〈sub〉〈i〉x〈/i〉〈/sub〉〈/span〉-dependent photochemical aging of tar balls in the OFR. Under high-〈span〉NO〈sub〉〈i〉x〈/i〉〈/sub〉〈/span〉 conditions with similar OH exposure, photochemical aging led to the formation of organic nitrates, and increased both oxidation degree and light absorption for the aged tar ball aerosols. These observations suggest that secondary organic nitrate formation counteracts the bleaching by OH radical photooxidation to eventually regain some absorption of the aged tar ball aerosols. The atmospheric implication and climate effects from tar balls upon various oxidation processes are briefly discussed.〈/p〉

Description: 〈b〉Atmospheric new particle formation in China〈/b〉〈br〉 Biwu Chu, Veli-Matti Kerminen, Federico Bianchi, Chao Yan, Tuukka Petäjä, and Markku Kulmala〈br〉 Atmos. Chem. Phys., 19, 115-138, https://doi.org/10.5194/acp-19-115-2019, 2019〈br〉 The characteristics of new particle formation (NPF) in China, including frequency, formation rate, and particle growth rate, were summarized comprehensively and were compared among observations in different environments. The interactions between air pollution and NPF are discussed, as well as the possible reasons for more frequent NPF under heavy pollution conditions than in our current understanding. Significant and future research directions for NPF studies in China are also summarized.

Description: 〈b〉Dynamic changes in optical and chemical properties of tar ball aerosols by atmospheric photochemical aging〈/b〉〈br〉 Chunlin Li, Quanfu He, Julian Schade, Johannes Passig, Ralf Zimmermann, Daphne Meidan, Alexander Laskin, and Yinon Rudich〈br〉 Atmos. Chem. Phys., 19, 139-163, https://doi.org/10.5194/acp-19-139-2019, 2019〈br〉 〈p〉Following wood pyrolysis, tar ball aerosols were laboratory generated from wood tar separated into polar and nonpolar phases. Chemical information of fresh tar balls was obtained from a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and single-particle laser desorption/resonance enhanced multiphoton ionization mass spectrometry (SP-LD-REMPI-MS). Their continuous refractive index (RI) between 365 and 425 nm was retrieved using a broadband cavity enhanced spectroscopy (BBCES). Dynamic changes in the optical and chemical properties for the nonpolar tar ball aerosols in 〈span〉NO〈sub〉〈i〉x〈/i〉〈/sub〉〈/span〉-dependent photochemical process were investigated in an oxidation flow reactor (OFR). Distinct differences in the chemical composition of the fresh polar and nonpolar tar aerosols were identified. Nonpolar tar aerosols contain predominantly high-molecular weight unsubstituted and alkyl-substituted polycylic aromatic hydrocarbons (PAHs), while polar tar aerosols consist of a high number of oxidized aromatic substances (e.g., methoxy-phenols, benzenediol) with higher O : C ratios and carbon oxidation states. Fresh tar balls have light absorption characteristics similar to atmospheric brown carbon (BrC) aerosol with higher absorption efficiency towards the UV wavelengths. The average retrieved RI is 〈span〉1.661+0.020〈i〉i〈/i〉〈/span〉 and 〈span〉1.635+0.003〈i〉i〈/i〉〈/span〉 for the nonpolar and polar tar aerosols, respectively, with an absorption Ångström exponent (AAE) between 5.7 and 7.8 in the detected wavelength range. The RI fits a volume mixing rule for internally mixed nonpolar/polar tar balls. The RI of the tar ball aerosols decreased with increasing wavelength under photochemical oxidation. Photolysis by UV light (254 nm), without strong oxidants in the system, slightly decreased the RI and increased the oxidation state of the tar balls. Oxidation under varying OH exposure levels and in the absence of 〈span〉NO〈sub〉〈i〉x〈/i〉〈/sub〉〈/span〉 diminished the absorption (bleaching) and increased the O : C ratio of the tar balls. The photobleaching via OH radical initiated oxidation is mainly attributed to decomposition of chromophoric aromatics, nitrogen-containing organics, and high-molecular weight components in the aged particles. Photolysis of nitrous oxide (〈span〉N〈sub〉2〈/sub〉O〈/span〉) was used to simulate 〈span〉NO〈sub〉〈i〉x〈/i〉〈/sub〉〈/span〉-dependent photochemical aging of tar balls in the OFR. Under high-〈span〉NO〈sub〉〈i〉x〈/i〉〈/sub〉〈/span〉 conditions with similar OH exposure, photochemical aging led to the formation of organic nitrates, and increased both oxidation degree and light absorption for the aged tar ball aerosols. These observations suggest that secondary organic nitrate formation counteracts the bleaching by OH radical photooxidation to eventually regain some absorption of the aged tar ball aerosols. The atmospheric implication and climate effects from tar balls upon various oxidation processes are briefly discussed.〈/p〉

Description: 〈b〉Watershed classification for the Canadian prairie〈/b〉〈br〉 Jared D. Wolfe, Kevin R. Shook, Chris Spence, and Colin J. Whitfield〈br〉 Hydrol. Earth Syst. Sci. Discuss., https//doi.org/10.5194/hess-2018-625,2019〈br〉 〈b〉Manuscript under review for HESS〈/b〉 (discussion: open, 0 comments)〈br〉 Watershed classification can identify regions expected to respond similarly to disturbance. Methods should extend beyond hydrology to include other environmental questions, such as ecology and water quality. We developed a classification for the Canadian Prairie, and identified seven classes defined by watershed characteristics, including elevation, climate, wetland density, and surficial geology. Results provide a basis for evaluating watershed response to land management and climate condition.

Description: 〈b〉Implications of water management representations for watershed hydrologic modeling in the Yakima River basin〈/b〉〈br〉 Jiali Qiu, Qichun Yang, Xuesong Zhang, Maoyi Huang, Jennifer C. Adam, and Keyvan Malek〈br〉 Hydrol. Earth Syst. Sci., 23, 35-49, https://doi.org/10.5194/hess-23-35-2019, 2019〈br〉 Complex water management activities challenge hydrologic modeling. We evaluated how different representations of reservoir operation and agricultural irrigation affect streamflow simulations in the Yakima River basin. Results highlight the importance of the inclusion of reliable reservoir and irrigation information in watershed models for improving watershed hydrology modeling. Models used here are public and hold the promise to benefit water assessment and management in other basins.

Description: 〈b〉Aircraft-based measurements of High Arctic springtime aerosol show evidence for vertically varying sources, transport and composition〈/b〉〈br〉 Megan D. Willis, Heiko Bozem, Daniel Kunkel, Alex K. Y. Lee, Hannes Schulz, Julia Burkart, Amir A. Aliabadi, Andreas B. Herber, W. Richard Leaitch, and Jonathan P. D. Abbatt〈br〉 Atmos. Chem. Phys., 19, 57-76, https://doi.org/10.5194/acp-19-57-2019, 2019〈br〉 The vertical distribution of Arctic aerosol is an important driver of its climate impacts. We present vertically resolved measurements of aerosol composition and properties made in the High Arctic during spring on an aircraft platform. We explore how aerosol properties are related to transport history and show evidence of vertical trends in aerosol sources, transport mechanisms and composition. These results will help us to better understand aerosol–climate interactions in the Arctic.

Description: 〈b〉Estimating the soil N〈sub〉2〈/sub〉O emission intensity of croplands in northwest Europe〈/b〉〈br〉 Vasileios Myrgiotis, Mathew Williams, Robert M. Rees, and Cairistiona F. E. Topp〈br〉 Biogeosciences Discuss., https//doi.org/10.5194/bg-2018-490,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 This study focuses on a northwest European cropland region and shows that the type of crop growing on a soil has notable effects on the emission of nitrous oxide (N〈sub〉2〈/sub〉O – a greenhouse gas) from that soil. It was found that N〈sub〉2〈/sub〉O emissions from soils under oilseed cultivation are significantly higher than soils under cereal cultivation. This variation is mostly explained by the fact that oilseeds require more nitrogen (fertiliser) than cereals especially at early crop growth stages.

Description: 〈b〉A Double ITCZ Phenomenology of Wind Errors in the Equatorial Atlantic in Seasonal Forecasts with ECMWF Models〈/b〉〈br〉 Jonathan K. P. Shonk, Teferi D. Demissie, and Thomas Toniazzo〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1316,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 Modern climate models are affected by systematic biases that harm their ability to produce reliable seasonal forecasts and climate projections. In this study, we investigate causes of biases in wind patterns over the tropical Atlantic during northern spring in three related models. We find that the wind biases are associated with an increase in excess rainfall and convergence in the tropical western Atlantic at the start of April, leading to the redirection of trade winds away from the equator.

Description: 〈b〉Spiky Fluctuations and Scaling in High-Resolution EPICA Ice Core Dust Fluxes〈/b〉〈br〉 Shaun Lovejoy and Fabrice Lambert〈br〉 Clim. Past Discuss., https//doi.org/10.5194/cp-2018-171,2019〈br〉 〈b〉Manuscript under review for CP〈/b〉 (discussion: open, 0 comments)〈br〉 We analyze the statistical properties of the eight past glacial-interglacial cycles as well as subsections of a generic glacial cycle using the high-resolution dust flux dataset from the Antarctic EPICA Dome C ice core. We show that the high southern latitude climate during glacial maxima, interglacial, and glacial inception is generally more stable but more drought-prone than during mid-glacial conditions.

Description: 〈b〉Nutrient distribution and nitrogen and oxygen isotopic composition of nitrate in water masses of the subtropical South Indian Ocean〈/b〉〈br〉 Natalie C. Harms, Niko Lahajnar, Birgit Gaye, Tim Rixen, Kirstin Dähnke, Markus Ankele, Ulrich Schwarz-Schampera, and Kay-Christian Emeis〈br〉 Biogeosciences Discuss., https//doi.org/10.5194/bg-2018-511,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 The Indian Ocean subtropical gyre is a large oligotrophic area that is likely to adjust to continued warming by increasing stratification, reduced nutrient supply, and decreasing biological production. In this study, we investigated concentrations of nutrients and stable isotopes of nitrate. We determine the lateral influence of water masses entering the gyre from the northern Indian Ocean and from the Southern Ocean and quantify the input of nitrogen by N〈sub〉2〈/sub〉-fixation into the surface layer.

Description: 〈b〉New particle formation in the marine atmosphere during seven cruise campaigns〈/b〉〈br〉 Yujiao Zhu, Kai Li, Yanjie Shen, Yang Gao, Xiaohuan Liu, Yang Yu, Huiwang Gao, and Xiaohong Yao〈br〉 Atmos. Chem. Phys., 19, 89-113, https://doi.org/10.5194/acp-19-89-2019, 2019〈br〉 In this paper, we investigate new particle formation (NPF) events during seven cruises. NPF events were observed on 25 days and were most likely associated with the long-range transport of anthropogenic air pollutants. The relationship between the net generated amount of new particles and their apparent formation rate is established and explained in terms of the roles of different vapor precursors. The survival probability of new particles to CCN size is also discussed.

Description: 〈b〉Aircraft-based measurements of High Arctic springtime aerosol show evidence for vertically varying sources, transport and composition〈/b〉〈br〉 Megan D. Willis, Heiko Bozem, Daniel Kunkel, Alex K. Y. Lee, Hannes Schulz, Julia Burkart, Amir A. Aliabadi, Andreas B. Herber, W. Richard Leaitch, and Jonathan P. D. Abbatt〈br〉 Atmos. Chem. Phys., 19, 57-76, https://doi.org/10.5194/acp-19-57-2019, 2019〈br〉 The vertical distribution of Arctic aerosol is an important driver of its climate impacts. We present vertically resolved measurements of aerosol composition and properties made in the High Arctic during spring on an aircraft platform. We explore how aerosol properties are related to transport history and show evidence of vertical trends in aerosol sources, transport mechanisms and composition. These results will help us to better understand aerosol–climate interactions in the Arctic.

Description: 〈b〉Simulated single-layer forest canopies delay Northern Hemisphere snowmelt〈/b〉〈br〉 Markus Todt, Nick Rutter, Christopher G. Fletcher, and Leanne M. Wake〈br〉 The Cryosphere Discuss., https//doi.org/10.5194/tc-2018-270,2019〈br〉 〈b〉Manuscript under review for TC〈/b〉 (discussion: open, 0 comments)〈br〉 Vegetation is often represented by a single layer in global land models. Studies have found deficient simulation of thermal radiation beneath forest canopies when represented by single-layer vegetation. This study corrects thermal radiation in forests for a global land model using single-layer vegetation in order to assess the effect of deficient thermal radiation on snow cover and snowmelt. Results indicate that single-layer vegetation causes snow in forests being too cold and melting too late.

Description: 〈b〉Brief Communication: Early season snowpack loss and implications for oversnow vehicle recreation travel planning〈/b〉〈br〉 Benjamin J. Hatchett and Hilary G. Eisen〈br〉 The Cryosphere, 13, 21-28, https://doi.org/10.5194/tc-13-21-2019, 2019〈br〉 We examine the timing of early season snowpack relevant to oversnow vehicle (OSV) recreation over the past 3 decades in the Lake Tahoe region (USA). Data from two independent data sources suggest that the timing of achieving sufficient snowpack has shifted later by 2 weeks. Increasing rainfall and more dry days play a role in the later onset. Adaptation strategies are provided for winter travel management planning to address negative impacts of loss of early season snowpack for OSV usage.

Description: 〈b〉Aerosol radiative effects with MACv2〈/b〉〈br〉 Stefan Kinne〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-949,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 〈p〉onthly global maps for aerosol properties of the MACv2 climatology are applied in an off-line radiative transfer model to determine aerosol radiative effects. For details beyond global averages in most cases global maps are presented to visualize regional and seasonal details. Aside from the direct radiative (aerosol presence) effect, including those for aerosol components as extracted from MACv2 aerosol optics, also the major aerosol indirect radiative effect is covered. Hereby, the impact of smaller drops in water clouds due to added anthropogenic aerosol was simulated by applying a satellite retrieval based fit from locally associations between aerosol and drop concentrations over oceans. Present-day anthropogenic aerosols of MACv2 – on a global average basis – reduce the radiative net-fluxes at the top of the atmosphere (TOA) by −1.0 W/m〈sup〉2〈/sup〉 and at the surface by −2.1 W/m〈sup〉2〈/sup〉. Direct cooling contributions are only about half of indirect contributions (−.35 vs −.65) at TOA, but about twice at the surface (−1.45 vs −.65), as solar absorption of the direct effect warms the atmosphere by +1.1 W/m〈sup〉2〈/sup〉. Natural aerosols are on average less absorbing (for a relatively larger solar TOA cooling) and larger in size (now contributing with IR greenhouse warming). Thus, average TOA direct forcing efficiencies for total and anthropogenic aerosol happen to be similar: −11 W/m〈sup〉2〈/sup〉/AOD at all-sky and −24 W/m〈sup〉2〈/sup〉/AOD at clear-sky conditions. The present-day direct impact by all soot (BC) is globally averaged +0.55W/m〈sup〉2〈/sup〉 and at least half of it should be attributed to anthropogenic sources. Hereby any accuracy of anthropogenic impacts, not just for soot, suffers from the limited access to a pre-industrial reference. Anthropogenic uncertainty has a particular strong impact on aerosol indirect effects, which dominate the (TOA) forcing. Accounting for uncertainties in the anthropogenic definition, present-day aerosol forcing is estimated to stay within the −0.7 to −1.6 W/m〈sup〉2〈/sup〉 range, with a best estimate at −1 W/m〈sup〉2〈/sup〉. Calculations with model predicted temporal changes to anthropogenic AOD indicate that qualitatively the anthropogenic aerosol forcing has not changed much over the last decades and is not likely to increase over the next decades, despite strong regional shifts. These regional shifts explain most solar insolation (brightening or dimming) trends that have been observed by ground-based radiation data.〈/p〉

Description: 〈b〉Thermal structure of the mesopause region during the WADIS-2 rocket campaign〈/b〉〈br〉 Raimund Wörl, Boris Strelnikov, Timo P. Viehl, Josef Höffner, Pierre-Dominique Pautet, Michael J. Taylor, Yucheng Zhao, and Franz-Josef Lübken〈br〉 Atmos. Chem. Phys., 19, 77-88, https://doi.org/10.5194/acp-19-77-2019, 2019〈br〉 Simultaneous temperature measurements during the WADIS-2 rocket campaign are used to investigate the thermal structure of the mesopause region. Vertically and horizontally resolved in situ and remote measurements are in good agreement and show dominating long-term and large-scale waves with periods of 24 h and higher tidal harmonics. Only a few gravity waves with periods shorter than 6 h and small amplitudes are there.

Description: 〈b〉Verification of anthropogenic VOC emission inventory through ambient measurements and satellite retrievals〈/b〉〈br〉 Jing Li, Yufang Hao, Maimaiti Simayi, Yuqi Shi, Ziyan Xi, and Shaodong Xie〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1133,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 We established an emission inventory of anthropogenic VOCs in the Beijing–Tianjin–Hebei region of China. The developed emission inventory was evaluated through ambient measurements and satellite retrieval results. To obtain a more accurate emission inventory, we propose the investigation of the household coal consumption, the adjustment of EFs based on the latest pollution control policies, and the verification of the source profiles of OVOCs and halocarbons.

Description: 〈b〉Classification of aerosol population type and cloud condensation nuclei properties in a coastal California littoral environment using an unsupervised cluster model〈/b〉〈br〉 Samuel A. Atwood, Sonia M. Kreidenweis, Paul J. DeMott, Markus D. Petters, Gavin C. Cornwell, Andrew C. Martin, and Kathryn A. Moore〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1297,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 This paper presents measurements of aerosol particles at a coastal location. The particles were classified into distinct aerosol types using both microphysical measurements and meteorological information, allowing rapid changes between the aerosol types to be reliably identified. These particles can alter cloud and precipitation processes, and inclusion of the differences between types can improve atmospheric models and remote sensing retrievals in littoral zones.

Description: 〈b〉Development of a balloon-borne instrument for CO〈sub〉2〈/sub〉 vertical profile observations in the troposphere〈/b〉〈br〉 Mai Ouchi, Yutaka Matsumi, Tomoki Nakayama, Kensaku Shimizu, Takehiko Sawada, Toshinobu Machida, Hidekazu Matsueda, Yousuke Sawa, Isamu Morino, Osamu Uchino, Tomoaki Tanaka, and Ryoichi Imasu〈br〉 Atmos. Meas. Tech. Discuss., https//doi.org/10.5194/amt-2018-376,2019〈br〉 〈b〉Manuscript under review for AMT〈/b〉 (discussion: open, 0 comments)〈br〉 A novel, practical observation system for measuring tropospheric carbon dioxide (CO〈sub〉2〈/sub〉) concentrations carried by a small helium-filled balloon (CO〈sub〉2〈/sub〉 sonde), has been developed for the first time. The low-cost CO〈sub〉2〈/sub〉 sondes can potentially be used for frequently measurements of vertical profiles of CO〈sub〉2〈/sub〉 in any parts of the world providing as useful information to understand the global and regional carbon budgets by replenishing the present sparse observation coverage.

Description: 〈b〉Comparison of Different Sequential Assimilation Algorithms for Satellite-derived Leaf Area Index Using the Data Assimilation Research Testbed (lanai)〈/b〉〈br〉 Xiao-Lu Ling, Cong-Bin Fu, Zong-Liang Yang, and Wei-Dong Guo〈br〉 Geosci. Model Dev. Discuss., https//doi.org/10.5194/gmd-2018-232,2019〈br〉 〈b〉Manuscript under review for GMD〈/b〉 (discussion: open, 0 comments)〈br〉 Both observation and simulation can provide the temporal and spatial variation of vegetation characteristic, while they are not satisfactory for understanding the mechanism of the exchange between ecosystems and atmosphere. Data assimilation (DA) can combine the observation and models via mathematical statistical analysis.The results show that the Ensemble Adjust Kalman Filter (EAKF) is the optical algorithm. In addition, models perform better when the DA accept more proportion of observation.

Description: 〈b〉The importance of crystalline phases in ice nucleation by volcanic ash〈/b〉〈br〉 Elena C. Maters, Donald B. Dingwell, Corrado Cimarelli, Dirk Müller, Thomas F. Whale, and Benjamin J. Murray〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1326,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 This experimental study investigates the influence of volcanic ash chemical composition, crystallinity, and mineralogy on its ability to promote freezing of supercooled water. The results indicate that crystals in ash play a key role in this process, and suggest that alkali and plagioclase feldspars in ash may be highly ice-active. These findings contribute to improving understanding of the potential of ash emissions from different explosive eruptions to impact ice formation in the atmosphere.

Description: 〈b〉Large increases in N〈sub〉cn〈/sub〉 and N〈sub〉ccn〈/sub〉 together with a nucleation-modeparticle pool over the northwestern Pacific Ocean in the spring of 2014〈/b〉〈br〉 Juntao Wang, Yanjie Shen, Kai Li, Yang Gao, Huiwang Gao, and Xiaohong Yao〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1089,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 In this paper, we studied the spatiotemporal variability of N〈sub〉cn〈/sub〉 and particle number size distributions, as well as N〈sub〉ccn〈/sub〉 and CCN activities over the NWPO in the spring of 2014. Several new findings have been revealed and discussed, e.g., large increases of N〈sub〉cn〈/sub〉 and N〈sub〉ccn〈/sub〉, against historical data and small contributions of dust and BB aerosols to N〈sub〉cn〈/sub〉 and N〈sub〉ccn〈/sub〉 on the monthly time scale, etc. This work may help understand the influence of the current outflow from the Asian continent on the climate.

Description: 〈b〉Analyses of temperature and precipitation in the Indian Jammu and Kashmir region for the 1980–2016 period: implications for remote influence and extreme events〈/b〉〈br〉 Sumira Nazir Zaz, Shakil Ahmad Romshoo, Ramkumar Thokuluwa Krishnamoorthy, and Yesubabu Viswanadhapalli〈br〉 Atmos. Chem. Phys., 19, 15-37, https://doi.org/10.5194/acp-19-15-2019, 2019〈br〉 This paper is of first of its kind for the Jammu and Kashmir (western Himalayas) region, India. It shows the clear relation between the upper tropospheric Rossby wave activity (potential vorticity at the 350 K potential temperature and 200 mb level surface pressure) and the surface weather parameters (e.g., precipitation) over a period of 3 decades during 1980–2016. This indicates that the climatic weather pattern over the Kashmir region is influenced mostly by global climate change processes.

Description: 〈b〉Secondary organic aerosol formation from smoldering and flaming combustion of biomass: a box model parametrization based on volatility basis set〈/b〉〈br〉 Giulia Stefenelli, Jianhui Jiang, Amelie Bertrand, Emily A. Bruns, Simone M. Pieber, Urs Baltensperger, Nicolas Marchand, Sebnem Aksoyoglu, André S. H. Prévôt, Jay G. Slowik, and Imad El Haddad〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1308,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 Box model simulations, based on the volatility basis set (VBS) approach, of smog chamber wood combustion experiments conducted at different temperatures (−10 °C, 2 °C, 15 °C), emission loads, combustion conditions (flaming and smoldering) and residential stoves fabricated in the last two decades. Novel parameterization methods based on a genetic algorithm approach allowed estimation of precursor class contributions to SOA and evaluation of the effect of emission variability on SOA yield predictions.

Description: 〈b〉Impacts of Horizontal Resolution and Air–Sea Flux Parameterization on the Intensity and Structure of simulated Typhoon Haiyan (2013)〈/b〉〈br〉 Mien-Tze Kueh, Wen-Mei Chen, Yang-Fan Sheng, Simon C. Lin, Tso-Ren Wu, Eric Yen, Yu-Lin Tsai, and Chuan-Yao Lin〈br〉 Nat. Hazards Earth Syst. Sci. Discuss., https//doi.org/10.5194/nhess-2018-333,2019〈br〉 〈b〉Manuscript under review for NHESS〈/b〉 (discussion: open, 0 comments)〈br〉 In this study, we show that both the model horizontal resolution and air-sea flux parameterization can exert large influence on tropical cyclone intensity simulation but with different impacts on wind structures. We highlight the intensification and contraction of TC eyewall in response to the reduction of grid spacing. We also suggest that a well-developed eyewall is more conducive to the positive effect of flux formulas on TC development.

Description: 〈b〉Primary and secondary sources of ambient formaldehyde in the Yangtze River Delta based on OMPS observation〈/b〉〈br〉 Wenjing Su, Cheng Liu, Qihou Hu, Shaohua Zhao, Youwen Sun, Wei Wang, Yizhi Zhu, Jianguo Liu, and Jhoon Kim〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1192,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 For a better understanding of the pollution and atmospheric chemistry of HCHO, we evaluated its primary and secondary sources in the Yangtze River Delta based on HCHO column density from Ozone Mapping and Profiler Suite (OMPS) and combining with surface in-situ measurements. We found that secondary formation contributed most to ambient HCHO for a long time, but primary emission could be dominant in the winter. The usability of total HCHO as the proxy of VOCs reactivity depends on time scale.

Description: 〈b〉Local and regional contributions to fine particulate matter in the 18 cities of Sichuan Basin, southwestern China〈/b〉〈br〉 Xue Qiao, Hao Guo, Ya Tang, Pengfei Wang, Wenye Deng, Xing Zhao, Jianlin Hu, Qi Ying, and Hongliang Zhang〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1214,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 A source-oriented version of the CMAQ model was used to quantify contributions from nine regions to PM〈sub〉2.5〈/sub〉 and its components in the 18 cities within the Sichuan Basin. Non-local emissions contribute to 39~66 % and 25~52 % to the citywide average PM〈sub〉2.5〈/sub〉 concentrations of 45~126 and 14~31 μg m〈sup〉−3〈/sup〉 in the winter and summer, respectively. This study demonstrates the importance of joint emission control efforts among cities within the SCB and neighbor regions to the east.

Description: 〈b〉MAX-DOAS measurements of tropospheric NO〈sub〉2〈/sub〉 and HCHO in Nanjing and the comparison to OMI observations〈/b〉〈br〉 Ka Lok Chan, Zhuoru Wang, Aijun Ding, Klaus-Peter Heue, Yicheng Shen, Jing Wang, Feng Zhang, Nan Hao, and Mark Wenig〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1266,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 The manuscript presents long term observations of atmospheric nitrogen dioxide (NO〈sub〉2〈/sub〉) and formaldehyde (HCHO) in Nanjing using a MAX-DOAS instrument. The measurements were performed from April 2013 to February 2017. The MAX-DOAS measurements of NO〈sub〉2〈/sub〉 and HCHO are used to validate OMI satellite observations and to investigate the influences of region transport of air pollutants on the air quality in Nanjing.

Description: 〈b〉Detection of Outflow of Formaldehyde and Glyoxal from the African continent to the Atlantic Ocean with a MAX-DOAS Instrument〈/b〉〈br〉 Lisa K. Behrens, Andreas Hilboll, Andreas Richter, Enno Peters, Leonardo M. A. Alvarado, Anna B. Kalisz Hedegaard, Folkard Wittrock, John P. Burrows, and Mihalis Vrekoussis〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1286,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 MAX-DOAS measurements were conducted on the research vessel Maria S. Merian during a cruise from the Azores to South Africa in October 2016. The measurements indicate enhanced levels of HCHO and CHOCHO over the remote Atlantic Ocean, which is unexpected due to their short lifetime. Precursors of these gases or gas-aerosol combinations might be transported. Model simulations indicate potential source regions over the African continent, probably related to biomass burning or biogenic emissions.

Description: 〈b〉Develop a coupled agent-based modeling approach for uncertain water management decisions〈/b〉〈br〉 Jin-Young Hyun, Shih-Yu Huang, Y. C. Ethan Yang, Vincent Tidwell, and Jordan Macknick〈br〉 Hydrol. Earth Syst. Sci. Discuss., https//doi.org/10.5194/hess-2018-555,2019〈br〉 〈b〉Manuscript under review for HESS〈/b〉 (discussion: open, 0 comments)〈br〉 This study applies a 〈q〉two-way〈/q〉 coupled agent-based model (ABM) with a River-Reservoir management model (RiverWare) to address the interaction between human and natural systems using Bayesian Inference (BI) mapping joined with Cost-Loss (CL). The calibration results show that this methodology can capture the historical pattern of both human activities and natural dynamics and outperforms those without using BI and CL.

Description: 〈b〉Potentials and pitfalls of permafrost active layer monitoring using the HVSR method: a case study in Svalbard〈/b〉〈br〉 Andreas Köhler and Christian Weidle〈br〉 Earth Surf. Dynam., 7, 1-16, https://doi.org/10.5194/esurf-7-1-2019, 2019〈br〉 The uppermost part of permanently frozen ground can thaw during summer and refreeze during winter. We use a method based on naturally generated seismic waves to continuously monitor these changes close to the research settlement of Ny-Ålesund in Svalbard between April and August 2016. Our results reveal some potential pitfalls when interpreting temporal variations in the data. However, we show that a careful data analysis makes this method a very useful tool for long-term permafrost monitoring.

Description: 〈b〉Long-profile evolution of transport-limited gravel-bed rivers〈/b〉〈br〉 Andrew D. Wickert and Taylor F. Schildgen〈br〉 Earth Surf. Dynam., 7, 17-43, https://doi.org/10.5194/esurf-7-17-2019, 2019〈br〉 Rivers can raise or lower their beds by depositing or eroding sediments. We combine equations for flow, channel/valley geometry, and gravel transport to learn how climate and tectonics shape down-valley profiles of river-bed elevation. Rivers steepen when they receive more sediment (relative to water) and become straighter with tectonic uplift. Weathering and breakdown of gravel is needed to produce gradually widening river channels with concave-up profiles that are often observed in the field.

Description: 〈b〉Definition differences and internal variability affect the simulated Arctic sea ice melt season〈/b〉〈br〉 Abigail Smith and Alexandra Jahn〈br〉 The Cryosphere, 13, 1-20, https://doi.org/10.5194/tc-13-1-2019, 2019〈br〉 Here we assessed how natural climate variations and different definitions impact the diagnosed and projected Arctic sea ice melt season length using model simulations. Irrespective of the definition or natural variability, the sea ice melt season is projected to lengthen, potentially by as much as 4–5 months by 2100 under the business as usual scenario. We also find that different definitions have a bigger impact on melt onset, while natural variations have a bigger impact on freeze onset.

Description: 〈b〉Three decades of simulated global terrestrial carbon fluxes from a data assimilation system confronted to different periods of observations〈/b〉〈br〉 Karel Castro-Morales, Gregor Schürmann, Christoph Köstler, Christian Rödenbeck, Martin Heimann, and Sönke Zaehle〈br〉 Biogeosciences Discuss., doi:10.5194/bg-2018-517,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 To obtain nearly thirty years of global terrestrial carbon fluxes, we simultaneously incorporated in a land surface model three different time periods of two observational data sets: absorbed photosynthetic active radiation and atmospheric CO〈sub〉2〈/sub〉 concentrations. One decade of data is enough to improve the modeled long-term trends and seasonal amplitudes of the assimilated variables, particularly in boreal regions. This model has the potential to provide short-term predictions of land carbon fluxes.

Description: 〈b〉Ostracods as ecological and isotopic indicators of lake water salinity changes: The Lake Van example〈/b〉〈br〉 Jeremy McCormack, Finn Viehberg, Derya Akdemir, Adrian Immenhauser, and Ola Kwiecien〈br〉 Biogeosciences Discuss., doi:10.5194/bg-2018-476,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 We juxtapose changes in ostracod taxonomy, morphology (noding) and oxygen (δ〈sup〉18〈/sup〉O) and carbon (δ〈sup〉13〈/sup〉C) isotopic composition for the last 150 kyr with independent low-resolution salinity proxies. We demonstrate that for Lake Van, salinity is the most important factor influencing the composition of the ostracod assemblage and the formation of nodes on the valves of limnocytherinae species. Ostracod δ〈sup〉18〈/sup〉O shows a higher sensibility towards climatic and hydrological variations than the bulk isotopy.

Description: 〈b〉Organic signatures in Pleistocene cherts from Lake Magadi (Kenya), analogs for early Earth hydrothermal deposits〈/b〉〈br〉 Manuel Reinhardt, Walter Goetz, Jan-Peter Duda, Christine Heim, Joachim Reitner, and Volker Thiel〈br〉 Biogeosciences Discuss., https//doi.org/10.5194/bg-2018-513,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 Organic matter in Archean hydrothermal cherts may contain molecular traces of early life. Alteration processes during and after deposition, however, may have obliterated potential biosignatures. Our results from modern analog samples (Pleistocene cherts from Lake Magadi, Kenya) show that biomolecules can survive early hydrothermal destruction in the macromolecular fraction of the organic matter. A conservation of molecular biosignatures in Archean hydrothermal cherts therefore seems possible.

Description: 〈b〉Detection of Outflow of Formaldehyde and Glyoxal from the African continent to the Atlantic Ocean with a MAX-DOAS Instrument〈/b〉〈br〉 Lisa K. Behrens, Andreas Hilboll, Andreas Richter, Enno Peters, Leonardo M. A. Alvarado, Anna B. Kalisz Hedegaard, Folkard Wittrock, John P. Burrows, and Mihalis Vrekoussis〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1286,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 MAX-DOAS measurements were conducted on the research vessel Maria S. Merian during a cruise from the Azores to South Africa in October 2016. The measurements indicate enhanced levels of HCHO and CHOCHO over the remote Atlantic Ocean, which is unexpected due to their short lifetime. Precursors of these gases or gas-aerosol combinations might be transported. Model simulations indicate potential source regions over the African continent, probably related to biomass burning or biogenic emissions.

Description: 〈b〉Primary and secondary sources of ambient formaldehyde in the Yangtze River Delta based on OMPS observation〈/b〉〈br〉 Wenjing Su, Cheng Liu, Qihou Hu, Shaohua Zhao, Youwen Sun, Wei Wang, Yizhi Zhu, Jianguo Liu, and Jhoon Kim〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1192,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 For a better understanding of the pollution and atmospheric chemistry of HCHO, we evaluated its primary and secondary sources in the Yangtze River Delta based on HCHO column density from Ozone Mapping and Profiler Suite (OMPS) and combining with surface in-situ measurements. We found that secondary formation contributed most to ambient HCHO for a long time, but primary emission could be dominant in the winter. The usability of total HCHO as the proxy of VOCs reactivity depends on time scale.

Description: 〈b〉Greenland Ice Sheet late-season melt: Investigating multi-scale drivers of K-transect events〈/b〉〈br〉 Thomas J. Ballinger, Thomas L. Mote, Kyle Mattingly, Angela C. Bliss, Edward Hanna, Dirk van As, Melissa Prieto, Saeideh Gharehchahi, Xavier Fettweis, Brice Noël, Paul C. J. P. Smeets, Mads H. Ribergaard, and John Cappelen〈br〉 The Cryosphere Discuss., https//doi.org/10.5194/tc-2018-285,2019〈br〉 〈b〉Manuscript under review for TC〈/b〉 (discussion: open, 0 comments)〈br〉 Studies have questioned links between Arctic marginal sea open water duration and Greenland Ice Sheet (GrIS) surface balance changes, namely melt events. Through analyses involving observations and climate models, we show that late summer through autumn “unseasonal” melt events are primarily driven by the northward movement of warm, moist air masses across the western ice sheet edge, while near-surface, off-ice winds block heat transfer off nearby Baffin Bay.

Description: 〈b〉Snow cover variability across glaciers in Nordenskiöldland (Svalbard) from point measurements in 2014–2016〈/b〉〈br〉 Marco Möller and Rebecca Möller〈br〉 Earth Syst. Sci. Data Discuss., https//doi.org/10.5194/essd-2018-158,2019〈br〉 〈b〉Manuscript under review for ESSD〈/b〉 (discussion: open, 0 comments)〈br〉 Snow water equivalents (SWE) are useful for calibration and validation of different snow cover-related modeling efforts (e.g. glacier mass balance or snow drift). They form a measure of snow accumulation better than snow depth as they are independent of density differences and thus comparable. A dataset is presented which provides point data of snow depth and density measurements as well as of calculated SWE from 109 locations on glaciers in the central region of the Arctic archipelago Svalbard.

Description: 〈b〉Fifty years of recorded hillslope runoff on seasonally-frozen ground: The Swift Current, Saskatchewan, Canada dataset〈/b〉〈br〉 Anna E. Coles, Jeffrey J. McDonnell, and Brian G. McConkey〈br〉 Earth Syst. Sci. Data Discuss., https//doi.org/10.5194/essd-2018-126,2019〈br〉 〈b〉Manuscript under review for ESSD〈/b〉 (discussion: open, 1 comment)〈br〉 〈p〉Long records of hillslope runoff and nutrients are rare – on seasonally frozen ground they are almost non-existent. The Swift Current hillslopes at the Swift Current Research and Development Centre on the Canadian Prairies provide such a long-term hydrological record. Runoff, runoff nutrient concentration, snowpack, soil moisture, and soil nutrient concentration were monitored on the three 5 ha hillslopes over a 50-year period (1962–2011). Runoff from the hillslopes was generated episodically during snowmelt and occasional rainfall events. Edge-of-field runoff was measured with a 0.61 m H-flume. Daily runoff nutrient concentration data are available for nitrate (March 1971–April 2011), ammonium (February 1996–April 2011), and orthophosphate (March–April 1971; June 1991–April 2011). Snowpack data (snowpack depth, density and water equivalent) were determined via manual snow surveys carried out several times each winter, between January and March, between 1965 and 2011 Gravimetric soil moisture content was measured in October and April each year between 1971 and 2011 at five depth intervals (0–15, 15–30, 30–60, 60–90, and 90–120 cm) at nine points on each hillslope. We summarize these hillslope data in two publically-available repositories: 1) 1962–2011 data on runoff, runoff nutrients, snowpack, soil moisture, soil nutrients, and crop and tillage practices at 〈a href="https://doi.org/10.23684/hhn5-rz52" target="_blank"〉https://doi.org/10.23684/hhn5-rz52〈/a〉; and 2) digital elevation data at 〈a href="https://doi.org/10.20383/101.011" target="_blank"〉https://doi.org/10.20383/101.011〈/a〉. Complete climate data recorded at a Environment and Climate Change Canada meteorological station located 390 m from the three hillslopes are publically-available at 〈a href="http://climate.weather.gc.ca/" target="_blank"〉http://climate.weather.gc.ca/〈/a〉.〈/p〉

Description: 〈b〉GemPy 1.0: open-source stochastic geological modeling and inversion〈/b〉〈br〉 Miguel de la Varga, Alexander Schaaf, and Florian Wellmann〈br〉 Geosci. Model Dev., 12, 1-32, https://doi.org/10.5194/gmd-12-1-2019, 2019〈br〉 〈i〉GemPy〈/i〉 is an open-source Python-based 3-D structural geological modeling software, which allows the implicit (i.e. automatic) creation of complex geological models from interface and orientation data. 〈i〉GemPy〈/i〉 is implemented in the programming language Python, making use of a highly efficient underlying library, Theano, for efficient code generation that performs automatic differentiation. This enables the link to probabilistic machine-learning and Bayesian inference frameworks.

Description: 〈b〉Comparison of the GRUAN data products for Meisei RS-11G and Vaisala RS92-SGP radiosondes at Tateno (36.06° N, 140.13° E), Japan〈/b〉〈br〉 Eriko Kobayashi, Shunsuke Hoshino, Masami Iwabuchi, Takuji Sugidachi, Kensaku Shimizu, and Masatomo Fujiwara〈br〉 Atmos. Meas. Tech. Discuss., https//doi.org/10.5194/amt-2018-416,2019〈br〉 〈b〉Manuscript under review for AMT〈/b〉 (discussion: open, 0 comments)〈br〉 The authors carried out dual flights of RS-11G and RS92-SGP radiosondes and investigated the differences in the performance of the radiosondes to help characterize GRUAN data products. A novel aspect of GRUAN data products is that vertically resolved uncertainty estimates and metadata are provided for each sounding and comparison of GRUAN data products is important in securing the temporal homogeneity of climate data records.

Description: 〈b〉WHU-SGCC: A novel approach for blending daily satellite (CHIRP) and precipitation observations over Jinsha River Basin〈/b〉〈br〉 Gaoyun Shen, Nengcheng Chen, Wei Wang, and Zeqiang Chen〈br〉 Earth Syst. Sci. Data Discuss., https//doi.org/10.5194/essd-2018-150,2019〈br〉 〈b〉Manuscript under review for ESSD〈/b〉 (discussion: open, 0 comments)〈br〉 The development of effective methods for high-accuracy precipitation estimates over complex terrain and on a daily scale is important for mountainous hydrological applications. This study offers a novel approach called WHU-SGCC by blending rain gauged and satellite data, to estimate daily precipitation at 0.05° resolution over Jinsha River Basin, the complicated mountainous terrain with sparse rain gauge data, considering the spatial correlation and the historical precipitation characteristics.

Description: 〈b〉GemPy 1.0: open-source stochastic geological modeling and inversion〈/b〉〈br〉 Miguel de la Varga, Alexander Schaaf, and Florian Wellmann〈br〉 Geosci. Model Dev., 12, 1-32, https://doi.org/10.5194/gmd-12-1-2019, 2019〈br〉 〈i〉GemPy〈/i〉 is an open-source Python-based 3-D structural geological modeling software, which allows the implicit (i.e. automatic) creation of complex geological models from interface and orientation data. 〈i〉GemPy〈/i〉 is implemented in the programming language Python, making use of a highly efficient underlying library, Theano, for efficient code generation that performs automatic differentiation. This enables the link to probabilistic machine-learning and Bayesian inference frameworks.

Description: 〈b〉Merits of novel high-resolution estimates and existing long-term estimates of humidity and incident radiation in a complex domain〈/b〉〈br〉 Helene Birkelund Erlandsen, Lena Merete Tallaksen, and Jørn Kristiansen〈br〉 Earth Syst. Sci. Data Discuss., https//doi.org/10.5194/essd-2018-121,2019〈br〉 〈b〉Manuscript under review for ESSD〈/b〉 (discussion: open, 0 comments)〈br〉 Robust estimates of runoff, snow, and evaporation rely on high quality estimates of incoming solar and thermal radiation at the surface, and near surface humidity. Taking advantage of the physical soundness of a numerical weather reanalyisis and the preciseness and spatial resolution of a national gridded temperature data set, new estimates of these variables are presented for Norway. Further, existing data sets and observations are compared, emphasising daily correlation, trends, and gradients.

Description: 〈b〉Fifty years of recorded hillslope runoff on seasonally-frozen ground: The Swift Current, Saskatchewan, Canada dataset〈/b〉〈br〉 Anna E. Coles, Jeffrey J. McDonnell, and Brian G. McConkey〈br〉 Earth Syst. Sci. Data Discuss., https//doi.org/10.5194/essd-2018-126,2019〈br〉 〈b〉Manuscript under review for ESSD〈/b〉 (discussion: open, 1 comment)〈br〉 〈p〉Long records of hillslope runoff and nutrients are rare – on seasonally frozen ground they are almost non-existent. The Swift Current hillslopes at the Swift Current Research and Development Centre on the Canadian Prairies provide such a long-term hydrological record. Runoff, runoff nutrient concentration, snowpack, soil moisture, and soil nutrient concentration were monitored on the three 5 ha hillslopes over a 50-year period (1962–2011). Runoff from the hillslopes was generated episodically during snowmelt and occasional rainfall events. Edge-of-field runoff was measured with a 0.61 m H-flume. Daily runoff nutrient concentration data are available for nitrate (March 1971–April 2011), ammonium (February 1996–April 2011), and orthophosphate (March–April 1971; June 1991–April 2011). Snowpack data (snowpack depth, density and water equivalent) were determined via manual snow surveys carried out several times each winter, between January and March, between 1965 and 2011 Gravimetric soil moisture content was measured in October and April each year between 1971 and 2011 at five depth intervals (0–15, 15–30, 30–60, 60–90, and 90–120 cm) at nine points on each hillslope. We summarize these hillslope data in two publically-available repositories: 1) 1962–2011 data on runoff, runoff nutrients, snowpack, soil moisture, soil nutrients, and crop and tillage practices at 〈a href="https://doi.org/10.23684/hhn5-rz52" target="_blank"〉https://doi.org/10.23684/hhn5-rz52〈/a〉; and 2) digital elevation data at 〈a href="https://doi.org/10.20383/101.011" target="_blank"〉https://doi.org/10.20383/101.011〈/a〉. Complete climate data recorded at a Environment and Climate Change Canada meteorological station located 390 m from the three hillslopes are publically-available at 〈a href="http://climate.weather.gc.ca/" target="_blank"〉http://climate.weather.gc.ca/〈/a〉.〈/p〉

Description: 〈b〉Calibration and analysis of the uncertainty in downscaling global land use and land cover projections from GCAM〈/b〉〈br〉 Min Chen, Chris R. Vernon, Maoyi Huang, Katherine V. Calvin, and Ian P. Kraucunas〈br〉 Geosci. Model Dev. Discuss., https//doi.org/10.5194/gmd-2018-248,2019〈br〉 〈b〉Manuscript under review for GMD〈/b〉 (discussion: open, 0 comments)〈br〉 Demeter is a community spatial downscaling model that disaggregates land use and land cover changes projected by integrated human-Earth system models. However, Demeter has not been intensively calibrated, and we still lack a good knowledge about its sensitivity to key parameters and the parameter uncertainties. This paper aims to solve this problem.

Description: 〈b〉WHU-SGCC: A novel approach for blending daily satellite (CHIRP) and precipitation observations over Jinsha River Basin〈/b〉〈br〉 Gaoyun Shen, Nengcheng Chen, Wei Wang, and Zeqiang Chen〈br〉 Earth Syst. Sci. Data Discuss., https//doi.org/10.5194/essd-2018-150,2019〈br〉 〈b〉Manuscript under review for ESSD〈/b〉 (discussion: open, 0 comments)〈br〉 The development of effective methods for high-accuracy precipitation estimates over complex terrain and on a daily scale is important for mountainous hydrological applications. This study offers a novel approach called WHU-SGCC by blending rain gauged and satellite data, to estimate daily precipitation at 0.05° resolution over Jinsha River Basin, the complicated mountainous terrain with sparse rain gauge data, considering the spatial correlation and the historical precipitation characteristics.

Description: 〈b〉On the fine vertical structure of the low troposphere over the coastal margins of East Antarctica〈/b〉〈br〉 Étienne Vignon, Olivier Traullé, and Alexis Berne〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1197,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 The sea-level rise associated to climate change will depend on how much the Antarctic ice sheet gain – viz precipitation – or loose mass. The precipitation simulation by climate models used for projections depends on the representation of the atmospheric circulation over and around Antarctica. Using daily measurements from balloon soundings at nine stations, this study characterizes the structure of the atmosphere over the Antarctic coast and assess its representation in a climate model.

Description: 〈b〉Insights into the O : C dependent mechanisms controlling the evaporation of α-pinene secondary organic aerosol particles〈/b〉〈br〉 Angela Buchholz, Andrew T. Lambe, Arttu Ylisirniö, Zijun Li, Olli-Pekka Tikkanen, Celia Faiola, Eetu Kari, Liqing Hao, Olli Luoma, Wei Huang, Claudia Mohr, Douglas R. Worsnop, Sergey A. Nizkorodov, Taina Yli-Juuti, Siegfried Schobesberger, and Annele Virtanen〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1305,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 We studied the evaporation of α-pinene secondary organic aerosol particles in clean air to derive their volatility from the observed size changes. We found that the particles became more resilient to evaporation with increased oxidative age, possibly increasing their lifetime in the atmosphere. Also, increased relative humidity increased the particle evaporation. Mass spectrometry measurements of the particles at different stages of evaporation revealed some water-induced composition changes.

Description: 〈b〉Insights into the O : C dependent mechanisms controlling the evaporation of α-pinene secondary organic aerosol particles〈/b〉〈br〉 Angela Buchholz, Andrew T. Lambe, Arttu Ylisirniö, Zijun Li, Olli-Pekka Tikkanen, Celia Faiola, Eetu Kari, Liqing Hao, Olli Luoma, Wei Huang, Claudia Mohr, Douglas R. Worsnop, Sergey A. Nizkorodov, Taina Yli-Juuti, Siegfried Schobesberger, and Annele Virtanen〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1305,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 We studied the evaporation of α-pinene secondary organic aerosol particles in clean air to derive their volatility from the observed size changes. We found that the particles became more resilient to evaporation with increased oxidative age, possibly increasing their lifetime in the atmosphere. Also, increased relative humidity increased the particle evaporation. Mass spectrometry measurements of the particles at different stages of evaporation revealed some water-induced composition changes.

Description: 〈b〉Quantitative precipitation estimation with weather radar using a data- and information-based approach〈/b〉〈br〉 Malte Neuper and Uwe Ehret〈br〉 Hydrol. Earth Syst. Sci. Discuss., https//doi.org/10.5194/hess-2018-606,2019〈br〉 〈b〉Manuscript under review for HESS〈/b〉 (discussion: open, 0 comments)〈br〉 In our study we apply a data-driven approach to estimate precipitation quantitatively with the use of weather radar data. The method is based on Information theory concepts. It uses predictive relations expressed by empirical discrete probability distributions directly derived from data rather than the standard deterministic functions.

Description: 〈b〉Develop a coupled agent-based modeling approach for uncertain water management decisions〈/b〉〈br〉 Jin-Young Hyun, Shih-Yu Huang, Y. C. Ethan Yang, Vincent Tidwell, and Jordan Macknick〈br〉 Hydrol. Earth Syst. Sci. Discuss., https//doi.org/10.5194/hess-2018-555,2019〈br〉 〈b〉Manuscript under review for HESS〈/b〉 (discussion: open, 0 comments)〈br〉 This study applies a 〈q〉two-way〈/q〉 coupled agent-based model (ABM) with a River-Reservoir management model (RiverWare) to address the interaction between human and natural systems using Bayesian Inference (BI) mapping joined with Cost-Loss (CL). The calibration results show that this methodology can capture the historical pattern of both human activities and natural dynamics and outperforms those without using BI and CL.

Description: 〈b〉Stochastic modeling of flow and conservative transport in three-dimensional discrete fracture networks〈/b〉〈br〉 I-Hsien Lee, Chuen-Fa Ni, Fang-Pang Lin, Chi-Ping Lin, and Chien-Chung Ke〈br〉 Hydrol. Earth Syst. Sci., 23, 19-34, https://doi.org/10.5194/hess-23-19-2019, 2019〈br〉 Few studies focused on the direct solution of the ADE for 3-D DFNs. The study is the first to solve the ADE and focus on assessing the velocity uncertainty in 3-D DFNs. The velocity uncertainty shows a limited range of influence close to the mean diameter of a fracture. The information is useful for engineering designs at sites with fractured rocks. We quantified that the tracer test in wells might lead to the overestimation of mean concentration and induce high uncertainty in fractured media.

Description: 〈b〉Time-variability of the fraction of young water in a small headwater catchment〈/b〉〈br〉 Michael P. Stockinger, Heye R. Bogena, Andreas Lücke, Christine Stumpp, and Harry Vereecken〈br〉 Hydrol. Earth Syst. Sci. Discuss., https//doi.org/10.5194/hess-2018-604,2019〈br〉 〈b〉Manuscript under review for HESS〈/b〉 (discussion: open, 0 comments)〈br〉 Precipitation moves through the soil to become streamwater. The fraction of precipitation that became streamwater after 3 months (Fyw) can be calculated with the stable isotopes of water. Previously this was done for all the isotope data available, e.g., for several years. We used one year of data to calculate Fyw and moved this calculation time window over the time series. Results highlight that Fyw varies in time. Comparison studies of different regions should take this into account.

Description: 〈b〉The significant contribution of HONO to secondary pollutants during a severe winter pollution event in southern China〈/b〉〈br〉 Xiao Fu, Tao Wang, Li Zhang, Qinyi Li, Zhe Wang, Men Xia, Hui Yun, Weihao Wang, Chuan Yu, Dingli Yue, Yan Zhou, Junyun Zheng, and Rui Han〈br〉 Atmos. Chem. Phys., 19, 1-14, https://doi.org/10.5194/acp-19-1-2019, 2019〈br〉 This study has identified the major contributors to the observed high HONO levels during a severe winter pollution episode and highlighted the importance of HONO chemistry in the combined photochemical and haze pollution in a subtropical region. It also highlighted the critical need to include and update HONO sources in regional air quality models in order to predict ozone and other secondary pollutants better during heavy pollution events in southern China and similar regions.

Description: 〈b〉A reconstruction of warm water inflow to Upernavik Isstrøm since AD 1925 and its relation to glacier retreat〈/b〉〈br〉 Flor Vermassen, Nanna Andreasen, David J. Wangner, Nicolas Thibault, Marit-Solveig Seidenkrantz, Rebecca Jackson, Sabine M. Schmidt, Kurt H. Kjær, and Camilla S. Andresen〈br〉 Clim. Past Discuss., https//doi.org/10.5194/cp-2018-174,2019〈br〉 〈b〉Manuscript under review for CP〈/b〉 (discussion: open, 0 comments)〈br〉 This study shows that warming of ocean waters is related to the retreat of Upernavik Isstrøm, a glacier in Northwest Greenland. We show that in the 1930s and after 2000 the waters in the fjord warmed and the glacier retreated. We found this by investigating microfossils from sediments in Upernavik Fjord; different species occur in response to warmer waters.

Description: 〈b〉The CMEMS GlobColour 〈i〉Chlorophyll-a〈/i〉 Product Based on Satellite Observation〈/b〉〈br〉 Philippe Garnesson, Antoine Mangin, Odile Fanton d'Andon, Julien Demaria, and Marine Bretagnon〈br〉 Ocean Sci. Discuss., https//doi.org/10.5194/os-2018-155,2019〈br〉 〈b〉Manuscript under review for OS〈/b〉 (discussion: open, 0 comments)〈br〉 〈p〉This work concerns the chlorophyll products based on Satellite Observation and disseminated in the frame of the Copernicus Marine Environmental Monitoring Service (CMEMS).〈/p〉 〈p〉 This work highlights the main advantages provided by the Copernicus Globcolour processor which is used to serve the CMEMS with a long time series from 1997 to present with level 3 & 4 products at Global level (4 km of spatial resolution) and for the Atlantic level 4 product (1 km).〈/p〉 〈p〉 It discusses the different ways to merge data coming from different sensors and it is shown that the GlobColour processor approach provide a better flexibility. At present, it is the only one CMEMS processor able to ingest the OLCI-S3A in the merged product (OLCI-S3A data are ingested in the operational CMEMS products since the April 2018 release).〈/p〉 〈p〉 Behind the merging, the flagging strategy to go from level 2 provided by spatial agencies to the level 3 CMEMS products is also discussed. A better spatial coverage is demonstrated, including the coastal area which is of particular interest for many users involved in the EU Water Framework and Marine Strategy Framework Directive.〈/p〉

Description: 〈b〉Induced seismicity in geologic carbon storage〈/b〉〈br〉 Víctor Vilarrasa, Jesus Carrera, Sebastià Olivella, Jonny Rutqvist, and Lyesse Laloui〈br〉 Solid Earth Discuss., https//doi.org/10.5194/se-2018-129,2019〈br〉 〈b〉Manuscript under review for SE〈/b〉 (discussion: open, 0 comments)〈br〉 To meet the goal of the Paris Agreement to limit temperature increase below 2 ºC, Geologic Carbon Storage (GCS) will be necessary at the gigatone scale. But to successfully deploy GCS, seismicity induced by CO〈sub〉2〈/sub〉 injection should be controlled and maintained below a threshold that does not generate nuisances to the population. We conclude that felt induced seismicity can be minimized provided that a proper site characterization, monitoring and pressure management are performed.

Description: 〈b〉Improved aerosol correction for OMI tropospheric NO〈sub〉2〈/sub〉 retrieval over East Asia: constraint from CALIOP aerosol vertical profile〈/b〉〈br〉 Mengyao Liu, Jintai Lin, K. Folkert Boersma, Gaia Pinardi, Yang Wang, Julien Chimot, Thomas Wagner, Pinhua Xie, Henk Eskes, Michel Van Roozendael, François Hendrick, Pucai Wang, Ting Wang, Yingying Yan, Lulu Chen, and Ruijing Ni〈br〉 Atmos. Meas. Tech., 12, 1-21, https://doi.org/10.5194/amt-12-1-2019, 2019〈br〉 China has become the world’s largest emitter of NO〈sub〉〈i〉x〈/i〉〈/sub〉, which mainly comes from vehicle exhaust, power plants, etc. However, there are no official ground-based measurements before 2013, so satellites have been widely used to monitor and analyze NO〈sub〉〈i〉x〈/i〉〈/sub〉 pollution here. Aerosol is the key factor influencing the accuracy of the satellite NO〈sub〉〈i〉x〈/i〉〈/sub〉 product. Our study provides a more accurate way to account for aerosol's influence compared to current widely used products.

Description: 〈b〉Comparison of the GRUAN data products for Meisei RS-11G and Vaisala RS92-SGP radiosondes at Tateno (36.06° N, 140.13° E), Japan〈/b〉〈br〉 Eriko Kobayashi, Shunsuke Hoshino, Masami Iwabuchi, Takuji Sugidachi, Kensaku Shimizu, and Masatomo Fujiwara〈br〉 Atmos. Meas. Tech. Discuss., https//doi.org/10.5194/amt-2018-416,2019〈br〉 〈b〉Manuscript under review for AMT〈/b〉 (discussion: open, 0 comments)〈br〉 The authors carried out dual flights of RS-11G and RS92-SGP radiosondes and investigated the differences in the performance of the radiosondes to help characterize GRUAN data products. A novel aspect of GRUAN data products is that vertically resolved uncertainty estimates and metadata are provided for each sounding and comparison of GRUAN data products is important in securing the temporal homogeneity of climate data records.

Description: 〈b〉Snow cover variability across glaciers in Nordenskiöldland (Svalbard) from point measurements in 2014–2016〈/b〉〈br〉 Marco Möller and Rebecca Möller〈br〉 Earth Syst. Sci. Data Discuss., https//doi.org/10.5194/essd-2018-158,2019〈br〉 〈b〉Manuscript under review for ESSD〈/b〉 (discussion: open, 0 comments)〈br〉 Snow water equivalents (SWE) are useful for calibration and validation of different snow cover-related modeling efforts (e.g. glacier mass balance or snow drift). They form a measure of snow accumulation better than snow depth as they are independent of density differences and thus comparable. A dataset is presented which provides point data of snow depth and density measurements as well as of calculated SWE from 109 locations on glaciers in the central region of the Arctic archipelago Svalbard.

Description: 〈b〉Analyses of temperature and precipitation in the Indian Jammu and Kashmir region for the 1980–2016 period: implications for remote influence and extreme events〈/b〉〈br〉 Sumira Nazir Zaz, Shakil Ahmad Romshoo, Ramkumar Thokuluwa Krishnamoorthy, and Yesubabu Viswanadhapalli〈br〉 Atmos. Chem. Phys., 19, 15-37, https://doi.org/10.5194/acp-19-15-2019, 2019〈br〉 This paper is of first of its kind for the Jammu and Kashmir (western Himalayas) region, India. It shows the clear relation between the upper tropospheric Rossby wave activity (potential vorticity at the 350 K potential temperature and 200 mb level surface pressure) and the surface weather parameters (e.g., precipitation) over a period of 3 decades during 1980–2016. This indicates that the climatic weather pattern over the Kashmir region is influenced mostly by global climate change processes.

Description: 〈b〉Distributed Temperature Profiling System Provides Spatially Dense Measurements and Insights about Permafrost Distribution in an Arctic Watershed〈/b〉〈br〉 Emmanuel Léger, Baptiste Dafflon, Yves Robert, Craig Ulrich, John E. Peterson, Sébastien Biraud, Vladimir E. Romanovsky, and Susan S. Hubbard〈br〉 The Cryosphere Discuss., https//doi.org/10.5194/tc-2018-264,2019〈br〉 〈b〉Manuscript under review for TC〈/b〉 (discussion: open, 0 comments)〈br〉 〈p〉Soil temperature has been recognized as a property that strongly influences a myriad of hydro-biogeochemical processes, as well as containing important information on the properties modulating the soil thermal flux. In spite of its importance, our ability to acquire soil temperature data with high spatial and temporal resolution and coverage is limited, because of the high cost of equipment, the difficulties of deployment, and the complexities of data management. Here we propose a new strategy that we call Distributed Temperature Profiling (DTP), which consists of cheap, low-impact, low-power, vertically resolved temperature probes that independently and autonomously record soil temperature. We developed a prototype DTP system for characterizing and monitoring near-surface thermal properties, using an unprecedented number of laterally and vertically distributed temperature measurements. The DTP system was tested in an Arctic ecosystem near Nome, AK, to identify near-surface permafrost distribution and various thermal regimes in a discontinuous permafrost environment during the summer time. Results show that the DTP system enabled successful acquisition of vertically resolved profiles of summer soil temperature over the top 0.8 m at numerous locations. DTP also enabled high resolution identification and lateral delineation of near-surface permafrost locations from surrounding zones with no permafrost or deep permafrost table locations overlain by a perennially thawed layer. The DTP strategy overcomes some of the limitations associated with – and complements the strengths of – borehole-based soil temperature sensing as well as Fiber-Optic Distributed Temperature Sensing (FO-DTS) approaches. Combining DTP data with co-located topographic and vegetation maps obtained using Unmanned Aerial Vehicle (UAV) and Electrical Resistivity Tomography (ERT) data allowed us to identify correspondences between surface and subsurface property distribution, and in particular between topography, vegetation, shallow soil properties, and near-surface permafrost. Finally, the results highlight the considerable value of the newly developed DTP strategy for investigating the significant variability and complexity of subsurface thermal and hydrological regimes in discontinuous permafrost regions.〈/p〉

Description: 〈b〉Large increases in N〈sub〉cn〈/sub〉 and N〈sub〉ccn〈/sub〉 together with a nucleation-modeparticle pool over the northwestern Pacific Ocean in the spring of 2014〈/b〉〈br〉 Juntao Wang, Yanjie Shen, Kai Li, Yang Gao, Huiwang Gao, and Xiaohong Yao〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1089,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 In this paper, we studied the spatiotemporal variability of N〈sub〉cn〈/sub〉 and particle number size distributions, as well as N〈sub〉ccn〈/sub〉 and CCN activities over the NWPO in the spring of 2014. Several new findings have been revealed and discussed, e.g., large increases of N〈sub〉cn〈/sub〉 and N〈sub〉ccn〈/sub〉, against historical data and small contributions of dust and BB aerosols to N〈sub〉cn〈/sub〉 and N〈sub〉ccn〈/sub〉 on the monthly time scale, etc. This work may help understand the influence of the current outflow from the Asian continent on the climate.

Description: 〈b〉Calibration and analysis of the uncertainty in downscaling global land use and land cover projections from GCAM〈/b〉〈br〉 Min Chen, Chris R. Vernon, Maoyi Huang, Katherine V. Calvin, and Ian P. Kraucunas〈br〉 Geosci. Model Dev. Discuss., https//doi.org/10.5194/gmd-2018-248,2019〈br〉 〈b〉Manuscript under review for GMD〈/b〉 (discussion: open, 0 comments)〈br〉 Demeter is a community spatial downscaling model that disaggregates land use and land cover changes projected by integrated human-Earth system models. However, Demeter has not been intensively calibrated, and we still lack a good knowledge about its sensitivity to key parameters and the parameter uncertainties. This paper aims to solve this problem.

Description: 〈b〉Determining the Optimal Grid Resolution for Topographic Analysis on an Airborne Lidar Dataset〈/b〉〈br〉 Taylor Smith, Aljoscha Rheinwalt, and Bodo Bookhagen〈br〉 Earth Surf. Dynam. Discuss., https//doi.org/10.5194/esurf-2018-96,2019〈br〉 〈b〉Manuscript under review for ESurf〈/b〉 (discussion: open, 1 comment)〈br〉 Representing the surface of the earth on an equally spaced grid leads to errors and uncertainties in derived slope and aspect. Using synthetic data, we develop a quality metric that can be used to compare the uncertainties in different datasets. We then apply this method to a real-world lidar dataset, and find that one-meter data has larger error bounds than lower resolution data. The highest data resolution is not always the best choice – it is important to consider the quality of the data.

Description: 〈b〉Reviews and syntheses: Dams, water quality and tropical reservoir stratification〈/b〉〈br〉 R. Scott Winton, Elisa Calamita, and Bernhard Wehrli〈br〉 Biogeosciences Discuss., https//doi.org/10.5194/bg-2018-510,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 A global boom in dam construction throughout the world’s tropics motivated us to review and synthesize information on the water quality impacts of dams with a focus on low latitude contexts and scope for mitigation. Sediment trapping and reservoir stratification are key process driving chemical and ecological impacts to tropical rivers. We analyze the 54 most-voluminous low latitude reservoirs and find that stratification seems to be a ubiquitous phenomenon.

Description: 〈b〉On what scales can GOSAT flux inversions constrain anomalies in terrestrial ecosystems?〈/b〉〈br〉 Brendan Byrne, Dylan B. A. Jones, Kimberly Strong, Saroja M. Polavarapu, Anna B. Harper, David F. Baker, and Shamil Maksyutov〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-909,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 Spatial and temporal variations in atmospheric CO〈sub〉2〈/sub〉 are driven by fluxes of CO〈sub〉2〈/sub〉 at Earth's surface. Therefore, measurements of variations in atmospheric CO〈sub〉2〈/sub〉 from satellites, such as the Greenhouse Gases Observing Satellite (GOSAT), inform the spatiotemporal variations in CO〈sub〉2〈/sub〉 fluxes at Earth's surface. In this study, we examine how well interannual variations in CO〈sub〉2〈/sub〉 surface fluxes can be estimated from GOSAT measurements. We show estimated CO〈sub〉2〈/sub〉 anomalies are correlated with temperature anomalies.

Description: 〈b〉Reviews and syntheses: Dams, water quality and tropical reservoir stratification〈/b〉〈br〉 R. Scott Winton, Elisa Calamita, and Bernhard Wehrli〈br〉 Biogeosciences Discuss., doi:10.5194/bg-2018-510,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 A global boom in dam construction throughout the world’s tropics motivated us to review and synthesize information on the water quality impacts of dams with a focus on low latitude contexts and scope for mitigation. Sediment trapping and reservoir stratification are key process driving chemical and ecological impacts to tropical rivers. We analyze the 54 most-voluminous low latitude reservoirs and find that stratification seems to be a ubiquitous phenomenon.

Description: 〈b〉On what scales can GOSAT flux inversions constrain anomalies in terrestrial ecosystems?〈/b〉〈br〉 Brendan Byrne, Dylan B. A. Jones, Kimberly Strong, Saroja M. Polavarapu, Anna B. Harper, David F. Baker, and Shamil Maksyutov〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-909,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 Spatial and temporal variations in atmospheric CO〈sub〉2〈/sub〉 are driven by fluxes of CO〈sub〉2〈/sub〉 at Earth's surface. Therefore, measurements of variations in atmospheric CO〈sub〉2〈/sub〉 from satellites, such as the Greenhouse Gases Observing Satellite (GOSAT), inform the spatiotemporal variations in CO〈sub〉2〈/sub〉 fluxes at Earth's surface. In this study, we examine how well interannual variations in CO〈sub〉2〈/sub〉 surface fluxes can be estimated from GOSAT measurements. We show estimated CO〈sub〉2〈/sub〉 anomalies are correlated with temperature anomalies.

Description: 〈b〉Comparison of Different Sequential Assimilation Algorithms for Satellite-derived Leaf Area Index Using the Data Assimilation Research Testbed (lanai)〈/b〉〈br〉 Xiao-Lu Ling, Cong-Bin Fu, Zong-Liang Yang, and Wei-Dong Guo〈br〉 Geosci. Model Dev. Discuss., https//doi.org/10.5194/gmd-2018-232,2019〈br〉 〈b〉Manuscript under review for GMD〈/b〉 (discussion: open, 0 comments)〈br〉 Both observation and simulation can provide the temporal and spatial variation of vegetation characteristic, while they are not satisfactory for understanding the mechanism of the exchange between ecosystems and atmosphere. Data assimilation (DA) can combine the observation and models via mathematical statistical analysis.The results show that the Ensemble Adjust Kalman Filter (EAKF) is the optical algorithm. In addition, models perform better when the DA accept more proportion of observation.

Description: 〈b〉Floodwater Impact on Galveston Bay Phytoplankton Taxonomy, Pigment Composition and Photo-Physiological State following Hurricane Harvey from Field and Ocean Color (Sentinel-3A OLCI) Observations〈/b〉〈br〉 Bingqing Liu, Eurico J. D'Sa, and Ishan D. Joshi〈br〉 Biogeosciences Discuss., https//doi.org/10.5194/bg-2018-504,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 An approach using bio-optical field and ocean color (Sentinel-3A OLCI) data combined with inversion models allowed for the first time, an assessment of phytoplankton response (changes in taxonomy, pigment composition and physiological state) to a large hurricane-related floodwater perturbation in a turbid estuary. The study revealed the transition in phytoplankton community species as well as the spatiotemporal distributions of phytoplankton diagnostic pigments in the floodwater impacted bay.

Description: 〈b〉Stand age and species composition effects on surface albedo in a mixedwood boreal forest〈/b〉〈br〉 Mohammad Abdul Halim, Han Y. H. Chen, and Sean C. Thomas〈br〉 Biogeosciences Discuss., https//doi.org/10.5194/bg-2018-501,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 Using field data collected over 4 years across a range of stand ages, we investigated how seasonal surface albedo in boreal forest varies with stand age, stand structure, and composition. Our results indicate that successional change in species composition is a key driver of age-related patterns in albedo, with hardwood species associated with higher albedo. The patterns described have important implications for both climate modelling and 〈q〉climate-smart〈/q〉 boreal forest management.

Description: 〈b〉Stand age and species composition effects on surface albedo in a mixedwood boreal forest〈/b〉〈br〉 Mohammad Abdul Halim, Han Y. H. Chen, and Sean C. Thomas〈br〉 Biogeosciences Discuss., doi:10.5194/bg-2018-501,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 Using field data collected over 4 years across a range of stand ages, we investigated how seasonal surface albedo in boreal forest varies with stand age, stand structure, and composition. Our results indicate that successional change in species composition is a key driver of age-related patterns in albedo, with hardwood species associated with higher albedo. The patterns described have important implications for both climate modelling and 〈q〉climate-smart〈/q〉 boreal forest management.

Description: 〈b〉Classification of aerosol population type and cloud condensation nuclei properties in a coastal California littoral environment using an unsupervised cluster model〈/b〉〈br〉 Samuel A. Atwood, Sonia M. Kreidenweis, Paul J. DeMott, Markus D. Petters, Gavin C. Cornwell, Andrew C. Martin, and Kathryn A. Moore〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1297,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 This paper presents measurements of aerosol particles at a coastal location. The particles were classified into distinct aerosol types using both microphysical measurements and meteorological information, allowing rapid changes between the aerosol types to be reliably identified. These particles can alter cloud and precipitation processes, and inclusion of the differences between types can improve atmospheric models and remote sensing retrievals in littoral zones.

Description: 〈b〉Interpretation of particle number size distributions measured across an urban area during the FASTER campaign〈/b〉〈br〉 Roy M. Harrison, David C. S. Beddows, Mohammed S. Alam, Ajit Singh, James Brean, Ruixin Xu, Simone Kotthaus, and Sue Grimmond〈br〉 Atmos. Chem. Phys., 19, 39-55, https://doi.org/10.5194/acp-19-39-2019, 2019〈br〉 Particle number size distributions were measured simultaneously at five sites in London during a campaign. Observations are interpreted in terms of both evaporative shrinkage of traffic-generated particles and condensational growth, probably of traffic-generated particles under cool nocturnal conditions, as well as the influence of particles emitted from Heathrow Airport at a distance of about 22 km. The work highlights the highly dynamic behaviour of nanoparticles within the urban atmosphere.

Description: 〈b〉Floodwater Impact on Galveston Bay Phytoplankton Taxonomy, Pigment Composition and Photo-Physiological State following Hurricane Harvey from Field and Ocean Color (Sentinel-3A OLCI) Observations〈/b〉〈br〉 Bingqing Liu, Eurico J. D'Sa, and Ishan D. Joshi〈br〉 Biogeosciences Discuss., doi:10.5194/bg-2018-504,2019〈br〉 〈b〉Manuscript under review for BG〈/b〉 (discussion: open, 0 comments)〈br〉 An approach using bio-optical field and ocean color (Sentinel-3A OLCI) data combined with inversion models allowed for the first time, an assessment of phytoplankton response (changes in taxonomy, pigment composition and physiological state) to a large hurricane-related floodwater perturbation in a turbid estuary. The study revealed the transition in phytoplankton community species as well as the spatiotemporal distributions of phytoplankton diagnostic pigments in the floodwater impacted bay.

Description: 〈b〉High-resolution (0.05° × 0.05°) NO〈sub〉〈i〉x〈/i〉〈/sub〉 emissions in the Yangtze River Delta inferred from OMI〈/b〉〈br〉 Hao Kong, Jintai Lin, Ruixiong Zhang, Mengyao Liu, Hongjian Weng, Ruijing Ni, Lulu Chen, Jingxu Wang, and Qiang Zhang〈br〉 Atmos. Chem. Phys. Discuss., https//doi.org/10.5194/acp-2018-1275,2019〈br〉 〈b〉Manuscript under review for ACP〈/b〉 (discussion: open, 0 comments)〈br〉 We develop a computationally efficient space-based top-down method to inverting NO〈sub〉〈i〉x〈/i〉〈/sub〉 emissions in major urban areas at high resolution. The inversion method uses long-term OMI NO〈sub〉2〈/sub〉 data to enhance the horizontal resolution, and it accounts for the nonlinear effects of horizontal transport, chemical loss, and deposition on NO〈sub〉〈i〉x〈/i〉〈/sub〉. The inversion results reveal fine-scale spatial information of emissions which is hardly captured by bottom up inventories.

Description: 〈b〉The CMEMS GlobColour 〈i〉Chlorophyll-a〈/i〉 Product Based on Satellite Observation〈/b〉〈br〉 Philippe Garnesson, Antoine Mangin, Odile Fanton d'Andon, Julien Demaria, and Marine Bretagnon〈br〉 Ocean Sci. Discuss., https//doi.org/10.5194/os-2018-155,2019〈br〉 〈b〉Manuscript under review for OS〈/b〉 (discussion: open, 0 comments)〈br〉 〈p〉This work concerns the chlorophyll products based on Satellite Observation and disseminated in the frame of the Copernicus Marine Environmental Monitoring Service (CMEMS).〈/p〉 〈p〉 This work highlights the main advantages provided by the Copernicus Globcolour processor which is used to serve the CMEMS with a long time series from 1997 to present with level 3 & 4 products at Global level (4 km of spatial resolution) and for the Atlantic level 4 product (1 km).〈/p〉 〈p〉 It discusses the different ways to merge data coming from different sensors and it is shown that the GlobColour processor approach provide a better flexibility. At present, it is the only one CMEMS processor able to ingest the OLCI-S3A in the merged product (OLCI-S3A data are ingested in the operational CMEMS products since the April 2018 release).〈/p〉 〈p〉 Behind the merging, the flagging strategy to go from level 2 provided by spatial agencies to the level 3 CMEMS products is also discussed. A better spatial coverage is demonstrated, including the coastal area which is of particular interest for many users involved in the EU Water Framework and Marine Strategy Framework Directive.〈/p〉

Description: 〈b〉A simple model for local-scale sensible and latent heat advection contributions to snowmelt〈/b〉〈br〉 Phillip Harder, John W. Pomeroy, and Warren D. Helgason〈br〉 Hydrol. Earth Syst. Sci., 23, 1-17, https://doi.org/10.5194/hess-23-1-2019, 2019〈br〉 As snow cover becomes patchy during snowmelt, energy is advected from warm snow-free surfaces to cold snow-covered surfaces. This paper proposes a simple sensible and latent heat advection model for snowmelt situations that can be coupled to one-dimensional energy balance snowmelt models. The model demonstrates that sensible and latent heat advection fluxes can compensate for one another, especially in early melt periods.

Description: 〈b〉Quantitative precipitation estimation with weather radar using a data- and information-based approach〈/b〉〈br〉 Malte Neuper and Uwe Ehret〈br〉 Hydrol. Earth Syst. Sci. Discuss., https//doi.org/10.5194/hess-2018-606,2019〈br〉 〈b〉Manuscript under review for HESS〈/b〉 (discussion: open, 0 comments)〈br〉 In our study we apply a data-driven approach to estimate precipitation quantitatively with the use of weather radar data. The method is based on Information theory concepts. It uses predictive relations expressed by empirical discrete probability distributions directly derived from data rather than the standard deterministic functions.