ALBERT

Description: 〈b〉Paleomagnetic determination of paleolatitude and rotation of Bering Island (Komandorsky Islands) Russia: comparison with rotations in the Aleutian Islands and Kamchatka〈/b〉〈br〉 P. S. Minyuk and D. B. Stone〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 329-348, https://doi.org/10.5194/smsps-4-329-2009, 2009〈br〉 A paleomagnetic study was carried out on Paleogene sedimentary rocks from Bering Island, Komandorsky islands, located at the far western end of the Aleutian Island Arc. The age of these sediments has been debated at length, but the combination of magnetostratigraphy with the fossil record indicates that the base of the section is of early Eocene (approximately 55 Ma) and the top latest Eocene age. Paleomagnetic data were obtained from 260 samples from 60 individual bedding units. The combined data show a clockwise rotation 〈i〉R〈/i〉=26.3°±8.5°, 〈i〉F〈/i〉=8.1°±2.5° with respect to the North American Plate and 〈i〉R〈/i〉=38°±8.8°, 〈i〉F〈/i〉=8.7°±2.7° with respect to the Eurasian Plate. They also show a shallowing of the inclination which yields a paleolatitude of 53°, 12° south of its expected latitude. The shallowing may have a component due to compaction, but the wide variation in sampled lithologies, combined with internal consistency of the data set, would argue against the shallowing being significant. To compare these data with other Aleutian Arc data we compiled a comprehensive survey of all available data sets. Out of these we selected four islands for which the data passed basic reliability criteria, namely Umnak, Amlia, Amchitka and Medny islands. All four showed significant clockwise rotation with respect to both North American and Eurasian polar wander paths. Several mechanisms can generate the observed rotation, ranging from block rotation driven by oblique relative motion of the Pacific plate, through lateral transport along the curve of the arc, to whole-arc rotation about its eastern end. The distribution and age spread of the rotation data are insufficient to discriminate between mechanisms, but it seems likely that different mechanism may have operated at different times and in different locations.

Description: 〈b〉Paleomagnetism of the Cretaceous rocks from Cape Kronotskiy, East Kamchatka and reconstruction of terrane trajectories in the NE Pacific area〈/b〉〈br〉 W. Harbert, N. V. Tsukanov, D. V. Alexeiev, C. Gaedicke, R. Freitag, B. V. Baranov, S. G. Skolotnev, W. Kramer, and W. Seifert〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 313-327, https://doi.org/10.5194/smsps-4-313-2009, 2009〈br〉 The Kamchatka Peninsula of northeastern Russia is located along the northwestern margin of the Bering Sea and consists of zones of complexly deformed accreted terranes. Paleomagnetic samples were collected for study from a Late Cretaceous aged locality at Cape Kronotskiy (λ=54°44.8´ N, φ=162°1.29´ E). Two components of magnetization were observed. During stepwise thermal demagnetization, the B-magnetic component was observed up to 600°C having a direction and associated uncertainty in stratigraphic coordinates of 〈i〉D〈sub〉s〈/sub〉〈/i〉=300.7°, 〈i〉I〈sub〉s〈/sub〉〈/i〉=48.7°, α〈sub〉95〈/sub〉=10.9°, k-value=11.8, n=17. The B component paleolatitude calculated from the Fisher mean in stratigraphic coordinates and associated statistics are λ〈sub〉obs〈/sub〉=30.4° N or S, λ〈sub〉95〈/sub〉=8.9°, n=17 (sites), k-value=11. Our overall study paleolatitude result is similar to a previously reported paleomagnetic study completed within this unit. Terrane trajectories calculated using the finite rotation poles of Engebretson et al. (1985), which are corrected for either Pacific-hotspot drift or True Polar Wander hotspot-spin axis relative motion, show that the sampled unit represents a far traveled tectonostratigraphic terrane and support a model in which accretion (docking) events of this composite or superterrane with the North America plate occur at approximately 40 Ma.

Description: 〈b〉Comparison of Cretaceous granitoids of the Chaun tectonic zone to those of the Taigonos Peninsula, NE Asia: rock chemistry, composition of rock forming minerals, and conditions of formation〈/b〉〈br〉 P. L. Tikhomirov, M. V. Luchitskaya, and I. R. Kravchenko-Berezhnoy〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 289-311, https://doi.org/10.5194/smsps-4-289-2009, 2009〈br〉 The Cretaceous granitoid complexes of the Eastern Taigonos and the Prybrezhny Taigonos belts (southern part of the Taigonos Peninsula), Tanyurer pluton of the Okhotsk-Chukotka volcanic belt, and the Peekiney, Moltykan, and Telekay plutons of the Chaun tectonic zone are discussed in relation to their structural position, petrography, rock and mineral chemistry and physicochemical conditions of melt crystallization. These granitoid plutons were generated through melting of a compositionally heterogeneous crustal source, with direct contribution from mafic melts produced in the mantle wedge above active or extinct Benioff zones. Variations of the trace-element composition of granitoids are controlled to a greater extent by local compositional peculiarities of the source regions than by the geodynamic regime as such. The final crystallization of these plutons occurred at comparatively shallow depths, between 1–2 and 6–7 km, in a temperature interval of 700–770°C. The depth of emplacement of the bodies decreases with increasing distance from the areas with oceanic and transitional type crust, as does the degree of incompatible element enrichment of the mantle and crustal sources of melts. Variations in fo〈sub〉2〈/sub〉 values at the late stages of crystallization of the plutons reach 3–4 orders of magnitude, exceeding the limits of the quartz-fayalite-magnetite (QFM) and nickel-nickel oxide (NNO) buffer equilibria, which likely results from local variations of the source composition.

Description: 〈b〉Thermogeodynamic manifestations in the Caucasus and their genesis〈/b〉〈br〉 G. E. Gugunava, J. K. Kiria, and T. B. Bochorishvili〈br〉 eEarth Discuss., 4, 77-89, doi:10.5194/eed-4-77-2009, 2009〈br〉 〈b〉Publication in eE not foreseen〈/b〉 (discussion: closed, 2 comments)〈br〉 In the work two aspects of thermal character are considered: first of all this is the connection of subduction phenomena with thermal life of the Caucasus on the basis of over interpreted data of magnetotelluric sounding, and secondly, origin of thermostressed condition of the Caucasus and its geological aspects which is manifested in the following: 〈br〉〈br〉 1. in the zones of anomalous thermodisplacements thermofaults should occur (Le Pishon et al., 1977). These thermofaults are in good correlation with deep faults which are distinguished by geological and seismic methods, these thermofaults may be earthquake sources (Spitak, Racha, etc. earthquakes), also may be channels through which magma derivates (giving mineral deposits) may penetrate on surface (Gugunava and Gijeishvili, 1989); 〈br〉〈br〉 2. in the body of sedimentary complex thermostressed seals and seal failures occur, which are apparently traps for oil-gas fluids. Good correlation of thermodense anomalies with oil deposits of the Caucasus is shown (Alexidze et al., 1985; Gugunava, 1980). 〈br〉〈br〉 Everything above mentioned was carried out within frames of stationary thermal model which did not allow us to reveal time characteristics of interconnection of geological medium and thermal field. 〈br〉〈br〉 Now investigations are being carried out within the frames of stationary thermal model and its interconnection with geological environment.

Description: 〈b〉Thermogeodynamic manifestations in the Caucasus and their genesis〈/b〉〈br〉 G. E. Gugunava, J. K. Kiria, and T. B. Bochorishvili〈br〉 eEarth Discuss., 4, 77-89, doi:10.5194/eed-4-77-2009, 2009〈br〉 〈b〉Publication in eE not foreseen〈/b〉 (discussion: closed, 2 comments)〈br〉 In the work two aspects of thermal character are considered: first of all this is the connection of subduction phenomena with thermal life of the Caucasus on the basis of over interpreted data of magnetotelluric sounding, and secondly, origin of thermostressed condition of the Caucasus and its geological aspects which is manifested in the following: 〈br〉〈br〉 1. in the zones of anomalous thermodisplacements thermofaults should occur (Le Pishon et al., 1977). These thermofaults are in good correlation with deep faults which are distinguished by geological and seismic methods, these thermofaults may be earthquake sources (Spitak, Racha, etc. earthquakes), also may be channels through which magma derivates (giving mineral deposits) may penetrate on surface (Gugunava and Gijeishvili, 1989); 〈br〉〈br〉 2. in the body of sedimentary complex thermostressed seals and seal failures occur, which are apparently traps for oil-gas fluids. Good correlation of thermodense anomalies with oil deposits of the Caucasus is shown (Alexidze et al., 1985; Gugunava, 1980). 〈br〉〈br〉 Everything above mentioned was carried out within frames of stationary thermal model which did not allow us to reveal time characteristics of interconnection of geological medium and thermal field. 〈br〉〈br〉 Now investigations are being carried out within the frames of stationary thermal model and its interconnection with geological environment.

Description: 〈b〉Holocene evolution and sedimentation rate of Alikes Lagoon, Zakynthos island, Western Greece: preliminary results〈/b〉〈br〉 P. Avramidis and N. Kontopoulos〈br〉 eEarth, 4, 23-29, doi:10.5194/ee-4-23-2009, 2009〈br〉 In the present study we present preliminary results from Alikes lagoon in Zakynthos island, an area that is one of the most seismically active regions of Greece. In order to estimate – interpret the Holocene evolution of the area and to reconstruct the palaeoenvironmental changes, we based on data derived from a 21 m sediment core. Sediment types, structure, colour, as well as contact depths and bed characteristics were recorded in the field. Standarised sedimentological analysis was carried out, on 46 samples including grain size analysis, calculation of moment measures, and micro- and molluscan fossils of 17 selected samples. Moreover, radiocarbon age determinations have been made on individual 〈i〉Cardium〈/i〉 shells from two horizons and whole – core Magnetic Susceptibility (MS) measurements were taken. The interpretation of depositional environments suggests a coastal environment (restricted-shallow) with reduced salinity such as a lagoon margin and in a tidal flat and/or marsh particularly. The maximum age of the studied sediments is about 8500 BP. The rate of sedimentation between 8280 BP while 5590 BP was 5.3 mm/yr and between 5590 BP and modern times is on the order of 1.03 mm/yr. These sedimentation rates results are similar to other coastal areas of western Greece.

Description: 〈b〉Morphology of the pore space in claystones – evidence from BIB/FIB ion beam sectioning and cryo-SEM observations〈/b〉〈br〉 G. Desbois, J. L. Urai, and P. A. Kukla〈br〉 eEarth, 4, 15-22, doi:10.5194/ee-4-15-2009, 2009〈br〉 The morphology of pore space has a strong effect on mechanical and transport properties of mudrocks and clay-rich fault gouge, but its characterization has been mostly indirect. We report on a study of Boom clay from a proposed disposal site of radioactive waste (Mol site, Belgium) using high resolution SEM at cryogenic temperature, with ion beam cross-sectioning to prepare smooth, damage free surfaces. Pores commonly have crack-like tips, preferred orientation parallel to bedding and power law size distribution. We define a number of pore types depending on shape and location in the microstructure: large jagged pores in strain shadows of clastic grains, high aspect ratio pores between similarly oriented phyllosilicate grains and crescent-shaped pores in saddle reefs of folded phyllosilicates. 3-D reconstruction by serial cross-sectioning shows 3-D connectivity of the pore space. These findings offer a new insight into the morphology of pores down to nano-scale in comparison to traditional pore size distributions calculated from mercury Injection experiments, explain slaking of clays by successive wetting and drying and provide the basis for microstructure-based models of transport in clays.

Description: 〈b〉Foraminiferal response to environmental changes in Kiel Fjord, SW Baltic Sea〈/b〉〈br〉 A. Nikulina, I. Polovodova, and J. Schönfeld〈br〉 eEarth, 3, 37-49, doi:10.5194/ee-3-37-2008, 2008〈br〉 The living benthic foraminiferal assemblages in Kiel Fjord (SW Baltic Sea) were investigated in the years 2005 and 2006. The faunal studies were accomplished by geochemical analyses of surface sediments. In general, sediment pollution by copper, zinc, tin and lead is assessed as moderate in comparison with levels reported from other areas of the Baltic Sea. However, the inner Kiel Fjord is still exposed to a high load of metals and organic matter due to enhanced accumulation of fine-grained sediments in conjunction with potential pollution sources as shipyards, harbours and intensive traffic. The results of our survey show that the dominant environmental forcing of benthic foraminifera is nutrients availability coupled with human impact. A comparison with faunal data from the 1960s reveals apparent changes in species composition and population densities. The stress-tolerant species 〈i〉Ammonia beccarii〈/i〉 invaded Kiel Fjord. 〈i〉Ammotium cassis〈/i〉 had disappeared that reflects apparently the changes in salinity over the last 10 years. These changes in foraminiferal community and a significant increase of test abnormalities indicate an intensified environmental stress since the 1960s.

Description: 〈b〉Holocene evolution and sedimentation rate of Alikes Lagoon, Zakynthos island, Western Greece: preliminary results〈/b〉〈br〉 P. Avramidis and N. Kontopoulos〈br〉 eEarth, 4, 23-29, doi:10.5194/ee-4-23-2009, 2009〈br〉 In the present study we present preliminary results from Alikes lagoon in Zakynthos island, an area that is one of the most seismically active regions of Greece. In order to estimate – interpret the Holocene evolution of the area and to reconstruct the palaeoenvironmental changes, we based on data derived from a 21 m sediment core. Sediment types, structure, colour, as well as contact depths and bed characteristics were recorded in the field. Standarised sedimentological analysis was carried out, on 46 samples including grain size analysis, calculation of moment measures, and micro- and molluscan fossils of 17 selected samples. Moreover, radiocarbon age determinations have been made on individual 〈i〉Cardium〈/i〉 shells from two horizons and whole – core Magnetic Susceptibility (MS) measurements were taken. The interpretation of depositional environments suggests a coastal environment (restricted-shallow) with reduced salinity such as a lagoon margin and in a tidal flat and/or marsh particularly. The maximum age of the studied sediments is about 8500 BP. The rate of sedimentation between 8280 BP while 5590 BP was 5.3 mm/yr and between 5590 BP and modern times is on the order of 1.03 mm/yr. These sedimentation rates results are similar to other coastal areas of western Greece.

Description: 〈b〉Foraminiferal response to environmental changes in Kiel Fjord, SW Baltic Sea〈/b〉〈br〉 A. Nikulina, I. Polovodova, and J. Schönfeld〈br〉 eEarth, 3, 37-49, doi:10.5194/ee-3-37-2008, 2008〈br〉 The living benthic foraminiferal assemblages in Kiel Fjord (SW Baltic Sea) were investigated in the years 2005 and 2006. The faunal studies were accomplished by geochemical analyses of surface sediments. In general, sediment pollution by copper, zinc, tin and lead is assessed as moderate in comparison with levels reported from other areas of the Baltic Sea. However, the inner Kiel Fjord is still exposed to a high load of metals and organic matter due to enhanced accumulation of fine-grained sediments in conjunction with potential pollution sources as shipyards, harbours and intensive traffic. The results of our survey show that the dominant environmental forcing of benthic foraminifera is nutrients availability coupled with human impact. A comparison with faunal data from the 1960s reveals apparent changes in species composition and population densities. The stress-tolerant species 〈i〉Ammonia beccarii〈/i〉 invaded Kiel Fjord. 〈i〉Ammotium cassis〈/i〉 had disappeared that reflects apparently the changes in salinity over the last 10 years. These changes in foraminiferal community and a significant increase of test abnormalities indicate an intensified environmental stress since the 1960s.

Description: 〈b〉Decline of coral reefs during late Paleocene to early Eocene global warming〈/b〉〈br〉 C. Scheibner and R. P. Speijer〈br〉 eEarth, 3, 19-26, doi:10.5194/ee-3-19-2008, 2008〈br〉 Since the 1980s the frequency of warming events has intensified and simultaneously widespread coral bleaching, and enhanced coral mortality have been observed. Yet, it remains unpredictable how tropical coral reef communities will react to prolonged adverse conditions. Possibly, coral reef systems are sufficiently robust to withstand continued environmental pressures. But if coral mortality increases, what will platform communities of the future look like? The co-evolution of early Paleogene carbonate platforms and palaeoclimate may provide insight. Here we document the impact of early Paleogene global warming on shallow-water carbonate platforms in the Tethys. Between 59 and 55 Ma, three discrete stages in platform development can be identified Tethys-wide: during the first stage carbonate platforms mainly consisted of coralgal reefs; during the second – transitional – stage coralgal reefs thrived only at middle latitudes and gave way to larger foraminifera as dominant carbonate producer in low latitudes; finally, during the third stage, newly developing larger foraminifera lineages completely took over the role as main carbonate-producing organisms in low to middle latitudes. We postulate that rising temperatures led to a stepwise demise of Paleocene coral reefs, giving way to an unprecedented expansion of larger foraminifera, dominating Tethyan platforms during the early Eocene.

Description: 〈b〉Palaeomagnetic investigations of sediments cores from Axios zone (N. Greece): implications of low inclinations in the Aegean〈/b〉〈br〉 E. Aidona, D. Kondopoulou, R. Scholger, A. Georgakopoulos, and A. Vafeidis〈br〉 eEarth, 3, 7-18, doi:10.5194/ee-3-7-2008, 2008〈br〉 Sediment cores from 13 deep boreholes (1–4.1 km) distributed within Axios zone in Northern Greece have been studied by means of palaeomagnetism. Both low field magnetic susceptibility and intensity of the natural remanent magnetization (NRM) indicate rather weakly magnetised materials. A set of 390 samples have been subjected to thermal and alternative field demagnetization. Isothermal remanent magnetization (IRM) acquisition curves and thermomagnetic analysis suggest the dominance of magnetite. Thin sections from 30 selected samples were studied in order to more precisely characterise their magnetic mineralogy. This investigation also reveals the presence of magnetite and pyrite in framboidal form. An attempt to re-orient some of the samples was partially successful by using the viscous component and the anisotropy method. These techniques were applied in order to correct the palaeomagnetic directions due to the orientation ambiguity of the core samples. The corrected mean direction converges towards an eastward value, in agreement with the overall pattern of the onshore results from previous investigations in the study area. 〈br〉〈br〉 Finally, the observed inclinations of characteristic remanences in these rocks are much lower than the expected ones but converge with those obtained from formations on land.

Description: 〈b〉Zoogeography of the bottom Foraminifera of the West-African coast〈/b〉〈br〉 V. Mikhalevich〈br〉 eEarth Discuss., 3, 1-9, doi:10.5194/eed-3-1-2008, 2008〈br〉 〈b〉Revised manuscript has not been submitted〈/b〉 (discussion: closed, 8 comments)〈br〉 The sediment samples from the continental shelf of West-Equatorial Africa (from the Strait of Gibraltar to the Niger estuary), depths ranging from 0 to 69 m were found to contain 176 bottom foraminiferal species. For the majority of them (126 species), their areas of occurrences were mapped and the peculiar features of the geographical range and distribution were studied. The species natural habitats were established based on the taxonomical revision of the species in study all over the World Ocean based on the collections of the Zoological Institute RAS and wide literary data. The method of perforated cards was used to mark the geographical locations of all of the species studied. In order to establish the species geographic zonal distribution (together with their depth habitat) the five characteristic groups of the species were separated: 1. pan-oceanic (cosmopolitan), 2. widely spread tropical-boreal, 3. tropical-law boreal, 4. tropical-subtropical, 5. tropical. The percent of the species of each group among the species composition was established for the fauna of each station and for the whole region.

Description: 〈b〉Zoogeography of the bottom Foraminifera of the West-African coast〈/b〉〈br〉 V. Mikhalevich〈br〉 eEarth Discuss., 3, 1-9, doi:10.5194/eed-3-1-2008, 2008〈br〉 〈b〉Revised manuscript has not been submitted〈/b〉 (discussion: closed, 8 comments)〈br〉 The sediment samples from the continental shelf of West-Equatorial Africa (from the Strait of Gibraltar to the Niger estuary), depths ranging from 0 to 69 m were found to contain 176 bottom foraminiferal species. For the majority of them (126 species), their areas of occurrences were mapped and the peculiar features of the geographical range and distribution were studied. The species natural habitats were established based on the taxonomical revision of the species in study all over the World Ocean based on the collections of the Zoological Institute RAS and wide literary data. The method of perforated cards was used to mark the geographical locations of all of the species studied. In order to establish the species geographic zonal distribution (together with their depth habitat) the five characteristic groups of the species were separated: 1. pan-oceanic (cosmopolitan), 2. widely spread tropical-boreal, 3. tropical-law boreal, 4. tropical-subtropical, 5. tropical. The percent of the species of each group among the species composition was established for the fauna of each station and for the whole region.

Description: 〈b〉Map – geographic locations related to the manuscript sequence〈/b〉〈br〉 〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 3-3, https://doi.org/10.5194/smsps-4-3-2009, 2009〈br〉

Description: 〈b〉Age and paleomagnetism of the Okhotsk-Chukotka Volcanic Belt (OCVB) near Lake El'gygytgyn, Chukotka, Russia〈/b〉〈br〉 D. B. Stone, P. W. Layer, and M. I. Raikevich〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 243-260, https://doi.org/10.5194/smsps-4-243-2009, 2009〈br〉 Paleomagnetic results from the upper two thirds of the whole section of the Okhotsk-Chukotka Volcanic Belt (OCVB) volcanics exposed in the area around Lake El'gygytgyn, Chukotka yield stable, consistent magnetic vectors and well-preserved reversed directions. The magnetostratigraphy and 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar geochronologic data reported here indicate that the sampled OCVB volcanics were erupted between about 90 and 67 Ma, and show no significant change in the apparent pole position over that time. The OCVB extends from northeast China, across Northeast Russia to the Bering Straight. This belt is made up of both extrusive and intrusive rocks, with the extrusive rocks and their associated sediments being dominant. The whole belt important in interpreting the paleogeography of the region because it overlies many of the accreted terranes of Northeast Russia. Most importantly, it overlies parts of the Chukotka-Alaska block which is thought to have moved out of the Arctic Ocean region, as well as terranes accreted from the south. These latter terranes have been rafted northwards on the paleo-plates of the Pacific, implying that the present relative paleogeography of all of the terranes overlain by the OCVB were essentially in place by 67 Ma, and possibly as early as 90 Ma. However, comparing our paleomagnetic pole position for the OCVB with those for North America and Eurasia (a proxy for Siberia) shows a statistically significant displacement of the OCVB pole to the south west. This implies that not only the OCVB, but the underlying terranes of northeast Russia, experienced southerly displacement with respect to the Siberian and North American platforms since the Late Cretaceous.

Description: 〈b〉Tectonic reconstruction of Uda-Murgal arc and the Late Jurassic and Early Cretaceous convergent margin of Northeast Asia–Northwest Pacific〈/b〉〈br〉 S. D. Sokolov, G. Ye. Bondarenko, A. K. Khudoley, O. L. Morozov, M. V. Luchitskaya, M. I. Tuchkova, and P. W. Layer〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 273-288, https://doi.org/10.5194/smsps-4-273-2009, 2009〈br〉 A long tectonic zone composed of Upper Jurassic to Lower Cretaceous volcanic and sedimentary rocks is recognized along the Asian continent margin from the Mongol-Okhotsk fold and thrust belt on the south to the Chukotka Peninsula on the north. This belt represents the Uda-Murgal arc, which was developed along the convergent margin between Northeast Asia and Northwest Meso-Pacific. Several segments are identified in this arc based upon the volcanic and sedimentary rock assemblages, their respective compositions and basement structures. The southern and central parts of the Uda-Murgal arc were a continental margin belt with heterogeneous basement represented by metamorphic rocks of the Siberian craton, the Verkhoyansk terrigenous complex of Siberian passive margin and the Koni-Taigonos Late Paleozoic to Early Mesozoic island arc with accreted oceanic terranes. At the present day latitude of the Pekulney and Chukotka segments there was an ensimatic island arc with relicts of the South Anyui oceanic basin in a backarc basin. Accretionary prisms of the Uda-Murgal arc and accreted terranes contain fragments of Permian, Triassic to Jurassic and Jurassic to Cretaceous (Tithonian–Valanginian) oceanic crust and Jurassic ensimatic island arcs. Paleomagnetic and faunal data show significant displacement of these oceanic complexes and the terranes of the Taigonos Peninsula were originally parts of the Izanagi oceanic plate.

Description: 〈b〉Provenance analysis and tectonic setting of the Triassic clastic deposits in Western Chukotka, Northeast Russia〈/b〉〈br〉 M. I. Tuchkova, S. Sokolov, and I. R. Kravchenko-Berezhnoy〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 177-200, https://doi.org/10.5194/smsps-4-177-2009, 2009〈br〉 The study area is part of the Anyui subterrane of the Chukotka microplate, a key element in the evolution of the Amerasia Basin, located in Western Chukotka, Northeast Russia. The subterrane contains variably deformed, folded and cleaved rhythmic Triassic terrigenous deposits which represent the youngest stage of widespread marine deposition which form three different complexes: Lower-Middle Triassic, Upper Triassic (Carnian) and Upper Triassic (Norian). All of the complexes are represented by rhythmic interbeds of sandstone, siltstone and mudstone. Macrofaunas are not numerous, and in some cases deposits are dated by analogy to, or by their relationship with, other units dated with macrofaunas. The deposits are composed of pelagic sediments, low-density flows, high-density flows, and shelf facies associations suggesting that sedimentation was controlled by deltaic progradation on a continental shelf and subsequent submarine fan sedimentation at the base of the continental slope. Petrographic study of the mineral composition indicates that the sandstones are lithic arenites. Although the Triassic sandstones appear similar in outcrop and by classification, the constituent rock fragments are of diverse lithologies, and change in composition from lower grade metamorphic rocks in the Lower-Middle Triassic to higher grade metamorphic rocks in the Upper Triassic. This change suggests that the Triassic deposits represent an unroofing sequence as the source of the clastic material came from more deeply buried rocks with time.

Description: 〈b〉Multi-phase tectonic structures in the collision zone of the Kolyma-Omolon microcontinent and the eastern margin of the North Asian craton, Northeastern Russia〈/b〉〈br〉 A. V. Prokopiev and V. S. Oxman〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 65-70, https://doi.org/10.5194/smsps-4-65-2009, 2009〈br〉 The sequence of formation of structures is established in the zone of junction of the eastern margin of the North Asian craton and the northeastern flank of the Kolyma-Omolon microcontinent, in the area of bend of the Kolyma structural loop. Detailed structural studies revealed two phases in the formation of Mesozoic structures – an early thrust phase and a late strike-slip phase. Structures formed during each of the phases are described. Thrust structures are represented by the Setakchan nappe on which the minimum amount of horizontal displacement is estimated at 13–15 km. Later superposed left-lateral strike-slip faults have a north strike. Formation of these latter structures occurred during the second phase of collision between the Kolyma-Omolon microcontinent and the eastern margin of the North Asian craton.

Description: 〈b〉Geology of the Shelves surrounding the New Siberian Islands, Russian Arctic〈/b〉〈br〉 D. Franke and K. Hinz〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 35-44, https://doi.org/10.5194/smsps-4-35-2009, 2009〈br〉 A total of 11 700 km of multichannel seismic reflection data were acquired during recent reconnaissance surveys of the wide, shallow shelves of the Laptev and western East Siberian Seas around the New Siberian Islands. To the north of the Laptev Sea, the Gakkel Ridge, an active mid-ocean ridge which separates the North American and Eurasian Plates, meets abruptly the steep slope of the continental shelf. Extension has affected the Laptev Shelf since at least the Early Tertiary and has resulted in the formation of three major, generally north-south trending rift basins: the Ust' Lena Rift, the Anisin Basin, and the New Siberian Basin. Our data indicate that the rift basins on the Laptev Shelf are not continuous with those on the East Siberian Shelf. The latter shelf can best be described as an epicontinental platform which has undergone continuous subsidence since the Late Cretaceous. The greatest subsidence occurred in the NE, manifested by a major depocentre filled with inferred (?)Late Cretaceous to Tertiary sediments up to 5 s (twt) thick. On the basis of deep reflection data we revise and adjust Mesozoic domain boundaries around the New Siberian Islands.

Description: 〈b〉Use of remote sensing and GIS in mapping the environmental sensitivity areas for desertification of Egyptian territory〈/b〉〈br〉 A. Gad and I. Lotfy〈br〉 eEarth Discuss., 3, 41-85, doi:10.5194/eed-3-41-2008, 2008〈br〉 〈b〉Revised manuscript has not been submitted〈/b〉 (discussion: closed, 3 comments)〈br〉 Desertification is defined in the first art of the convention to combat desertification as 〈i〉"land degradation in arid, semiarid and dry sub-humid areas resulting from climatic variations and human activities".〈/i〉 Its consequence include a set of important processes which are active in arid and semi arid environment, where water is the main limiting factor of land use performance in such ecosystem . Desertification indicators or the groups of associated indicators should be focused on a single process. They should be based on available reliable information sources, including remotely sensed images, topographic data (maps or DEM'S), climate, soils and geological data. The current work aims to map the Environmental Sensitivity Areas (ESA's) to desertification in whole territory of Egypt at a scale of 1:1 000 000. 〈br〉〈br〉 ETM satellite images, geologic and soil maps were used as main sources for calculating the index of Environmental Sensitivity Areas (ESAI) for desertification. The algorism is adopted from MEDALLUS methodology as follows; 〈br〉〈br〉 ESAI = (SQI * CQI * VQI)〈sup〉1/3〈/sup〉 〈br〉〈br〉 Where SQI is the soil quality index, CQI is the climate quality index and VQI is the vegetation quality index. The SQI is based on rating the parent material, slope, soil texture, and soil depth. The VQI is computed on bases of rating three categories (i.e. erosion protection, drought resistance and plant cover). The CQI is based on the aridity index, derived from values of annual rainfall and potential evapotranspiration. Arc-GIS 9 software was used for the computation and sensitivity maps production. 〈br〉〈br〉 The results show that the soil of the Nile Valley are characterized by a moderate SQI, however the those in the interference zone are low soil quality indexed. The dense vegetation of the valley has raised its VQI to be good, however coastal areas are average and interference zones are low. The maps of ESA's for desertification show that 86.1% of Egyptian territory is classified as very sensitive areas, while 4.3% as Moderately sensitive, and 9.6% as sensitive. 〈br〉〈br〉 It can be concluded that implementing the maps of sensitivity to desertification is rather useful in the arid and semi arid areas as they give more likely quantitative trend for frequency of sensitive areas. The integration of different factors contributing to desertification sensitivity may lead to plan a successful combating. The usage of space data and GIS proved to be suitable tools to rely estimation and to fulfill the needed large computational requirements. They are also useful in visualizing the sensitivity situation of different desertification parameters.

Description: 〈b〉Palaeomagnetic investigations of sediments cores from Axios zone (N. Greece): implications of low inclinations in the Aegean〈/b〉〈br〉 E. Aidona, D. Kondopoulou, R. Scholger, A. Georgakopoulos, and A. Vafeidis〈br〉 eEarth, 3, 7-18, doi:10.5194/ee-3-7-2008, 2008〈br〉 Sediment cores from 13 deep boreholes (1–4.1 km) distributed within Axios zone in Northern Greece have been studied by means of palaeomagnetism. Both low field magnetic susceptibility and intensity of the natural remanent magnetization (NRM) indicate rather weakly magnetised materials. A set of 390 samples have been subjected to thermal and alternative field demagnetization. Isothermal remanent magnetization (IRM) acquisition curves and thermomagnetic analysis suggest the dominance of magnetite. Thin sections from 30 selected samples were studied in order to more precisely characterise their magnetic mineralogy. This investigation also reveals the presence of magnetite and pyrite in framboidal form. An attempt to re-orient some of the samples was partially successful by using the viscous component and the anisotropy method. These techniques were applied in order to correct the palaeomagnetic directions due to the orientation ambiguity of the core samples. The corrected mean direction converges towards an eastward value, in agreement with the overall pattern of the onshore results from previous investigations in the study area. 〈br〉〈br〉 Finally, the observed inclinations of characteristic remanences in these rocks are much lower than the expected ones but converge with those obtained from formations on land.

Description: 〈b〉A seismic swarm near Neshkan, Chukotka, northeastern Russia, and implications for the boundary of the Bering plate〈/b〉〈br〉 K. G. Mackey, K. Fujita, B. M. Sedov, L. V. Gounbina, and S. Kurtkin〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 261-271, https://doi.org/10.5194/smsps-4-261-2009, 2009〈br〉 A seismic swarm lasting over two years occurred near the village of Neshkan, Chukotka, far northeastern Russia, beginning with a 〈i〉M〈sub〉L〈/sub〉〈/i〉, 4.2 (4.1 〈i〉m〈sub〉b〈/sub〉〈/i〉) earthquake on 9 December 2002. The swarm generated considerable anxiety among the local populace and authorities. Two temporary seismic stations were deployed during the latter part of September 2003, and recorded over 150 events with magnitudes up to 3.0. Eighteen locatable events appear to form a northeast striking linear trend, parallel to other seismicity trends in Chukotka, extending 20 km to the southwest from the village. We interpret this trend as a previously unknown fault. A small pond located ~1 km west of the village drained and some apparent surface deformation was observed over the course of the earthquake sequence. Relocation of historic seismicity in the region shows that a magnitude 6.0 in 1996 may have ruptured an adjacent fault segment. Other, less well located but larger, teleseismic events earlier in the 20th century may also have occurred on or near this fault. The seismicity is consistent a proposed region of transtension along the northern boundary of a Bering plate.

Description: 〈b〉South Anyui suture: tectono-stratigraphy, deformations, and principal tectonic events〈/b〉〈br〉 S. D. Sokolov, G. Ye. Bondarenko, P. W. Layer, and I. R. Kravchenko-Berezhnoy〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 201-221, https://doi.org/10.5194/smsps-4-201-2009, 2009〈br〉 Geochronologic and structural data from the terranes of the South Anyui suture zone record a protracted deformational history before, during and after an Early Cretaceous collision of the passive margin of the Chukotka-Arctic Alaska continental block with the active continental margin of the North Asian continent. Preceding this collision, the island arc complexes of the Yarakvaam terrane on the northern margin of the North Asian craton record Early Carboniferous to Neocomian ages in ophiolite, sedimentary, and volcanic rocks. Triassic to Jurassic amphibolites constrain the timing of subduction and intraoceanic deformation along this margin. The protracted (Neocomian to Aptian) collision of the Chukotka passive margin with the North Asian continent is preserved in a range of structural styles including first north verging folding, then south verging folding, and finally late collisional dextral strike slip motions which likely record a change from orthogonal collision to oblique collision. Due to this collision, the southern passive margin of Chukotka was overthrust by tectonic nappes composed of tectono-stratigraphic complexes of the South Anyui terrane. Greenschists with ages of 115–119 Ma are related to the last stages of this collision. The postcollisional orogenic stage (Albian to Cenomanian) is characterized by sinistral strike slip faults and an extensional environment.

Description: 〈b〉Deformation of the Northwestern Okhotsk Plate: How is it happening?〈/b〉〈br〉 D. Hindle, K. Fujita, and K. Mackey〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 147-156, https://doi.org/10.5194/smsps-4-147-2009, 2009〈br〉 The Eurasia (EU) – North America (NA) plate boundary zone across Northeast Asia still presents many open questions within the plate tectonic paradigm. Constraining the geometry and number of plates or microplates present in the plate boundary zone is especially difficult because of the location of the EU-NA euler pole close to or even upon the EU-NA boundary. One of the major challenges remains the geometry of the Okhotsk plate (OK). whose northwestern portion terminates on the EU-OK-NA triple junction and is thus caught and compressed between converging EU and NA. We suggest that this leads to a coherent and understandable large scale deformation pattern of mostly northwest-southeast trending strike-slip faults which split Northwest OK into several extruding slivers. When the fault geometry is analysed together with space geodetic and focal mechanism data it suggests a central block which is extruding faster bordered east and west by progressively slower extruding blocks until the OK plate boundary faults are encountered. Taking into account elastic loading from both the intra-OK faults and the OK-Pacific (PA) boundary reconciles geodetic motions with geologic slip rates on at least the OK-NA boundary which corresponds to the Ulakhan fault.

Description: 〈b〉The Tommot pluton: a Middle Paleozoic rift-related alkaline gabbro and syenite complex, Yakutia, northeast Russia〈/b〉〈br〉 V. A. Trunilina, P. W. Layer, L. M. Parfenov, A. I. Zaitsev, and Y. S. Orlov〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 97-109, https://doi.org/10.5194/smsps-4-97-2009, 2009〈br〉 The Tommot pluton is located within the continental Omulevka terrane of the inner zone of the Verkhoyansk-Kolyma Mesozoic orogen. It is a small complex (~12 km〈sup〉2〈/sup〉) composed of alkaline-ultramafic rocks, alkaline and subalkaline gabbroids, and alkaline and quartz syenites. The pluton is unique both in the composition and age of its constituent rocks. Mineralogical-petrographical and geochemical studies of the rocks indicate that the alkaline rocks resulted from the melting of depleted mantle horizons. K-Ar, Rb-Sr, and 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar age determinations confirm a Paleozoic age of the rocks. Formation of the alkaline rocks is related to Middle Paleozoic rifting which occurred as two discrete events: a Late Devonian event, which affected the marginal part of the Siberian continent, and a Late Carboniferous event that reflects internal deformation of the Omulevka terrane or late-stage extension. A spatially associated alkali granite, the Somnitel'nyy pluton, is Late Jurassic–Early Cretaceous in age and is synchronous with accretion of the Kolyma-Omolon Superterrane to Siberia in the Mesozoic.

Description: 〈b〉Biography – Leonid M. Parfenov (1937–2002)〈/b〉〈br〉 K. Fujita, A. V. Prokopiev, and D. B. Stone〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 5-9, https://doi.org/10.5194/smsps-4-5-2009, 2009〈br〉

Description: 〈b〉Geochronology and thermochronology of Cretaceous plutons and metamorphic country rocks, Anyui-Chukotka fold belt, North East Arctic Russia〈/b〉〈br〉 E. L. Miller, S. M. Katkov, A. Strickland, J. Toro, V. V. Akinin, and T. A. Dumitru〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 157-175, https://doi.org/10.5194/smsps-4-157-2009, 2009〈br〉 U-Pb isotopic dating of seven granitoid plutons and associated intrusions from the Bilibino region (Arctic Chukotka, Russia) was carried out using the SHRIMP-RG. The crystallization ages of these granitoids, which range from approximately 116.9±2.5 to 108.5±2.7 Ma, bracket two regionally significant deformational events. The plutons cut folds, steep foliations and thrust-related structures related to sub-horizontal shortening at lower greenschist facies conditions (〈i〉D〈/i〉〈sub〉1〈/sub〉), believed to be the result of the collision of the Arctic Alaska-Chukotka microplate with Eurasia along the South Anyui Zone (SAZ). Deformation began in the Late Jurassic, based on fossil ages of syn-orogenic clastic strata, and involves strata as young as early Cretaceous (Valanginian) north of Bilibino and as young as Hauterivian-Barremian, in the SAZ. The second phase of deformation (〈i〉D〈/i〉〈sub〉2〈/sub〉) is developed across a broad region around and to the east of the Lupveem batholith of the Alarmaut massif and is interpreted to be coeval with magmatism. 〈i〉D〈/i〉〈sub〉2〈/sub〉 formed gently-dipping, high-strain foliations (〈i〉S〈/i〉〈sub〉2〈/sub〉). Growth of biotite, muscovite and actinolite define 〈i〉S〈/i〉〈sub〉2〈/sub〉 adjacent to the batholith, while chlorite and white mica define 〈i〉S〈/i〉〈sub〉2〈/sub〉 away from the batholith. Sillimanite (± andalusite) at the southeastern edge the Lupveem batholith represent the highest grade metamorphic minerals associated with 〈i〉D〈/i〉〈sub〉2〈/sub〉. 〈i〉D〈/i〉〈sub〉2〈/sub〉 is interpreted to have developed during regional extension and crustal thinning. Extension directions as measured by stretching lineations, quartz veins, boudinaged quartz veins is NE-SW to NW-SE. Mapped dikes associated with the plutons trend mostly NW-SE and indicate NE-SW directed extension. 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar ages from 〈i〉S〈/i〉〈sub〉2〈/sub〉 micas range from 109.3±1.2 to 103.0±1.8 Ma and are interpreted as post-crystallization cooling ages following a protracted period of magmatism and high heat flow. Regional uplift and erosion of many kilometers of cover produced a subdued erosional surface prior to the eruption of volcanic rocks of the Okhotsk-Chukotka volcanic belt (OCVB) whose basal units (~87 Ma) overlie this profound regional unconformity. A single fission track age on apatite from granite in the Alarmaut massif yielded an age of 90±11 Ma, in good agreement with this inference.

Description: 〈b〉Summary of Northeast Asia geodynamics and tectonics*〈/b〉〈br〉 L. M. Parfenov, G. Badarch, N. A. Berzin, A. I. Khanchuk, M. I. Kuzmin, W. J. Nokleberg, A. V. Prokopiev, M. Ogasawara, and H. Yan〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 11-33, https://doi.org/10.5194/smsps-4-11-2009, 2009〈br〉 The compilation, synthesis, description, and interpretation of regional geology and tectonics of major regions, such as Northeast Asia (Eastern Russia, Mongolia, Northern China, South Korea, and Japan) and the Circum-North Pacific (the Russian Far East, Alaska, and Canadian Cordillera), requires a complex methodology that includes: (1) definitions of key terms; (2) compilation of a regional geodynamics map that can be constructed according to modern tectonic concepts and definitions; and (3) formulation of a comprehensive tectonic model. This article presents a summary of the regional dynamics and tectonics of Northeast Asia as developed for a new summary geodynamics map of the region. This article also describes how a high-quality summary geodynamics map and companion tectonic analysis substantially aids in the understanding of the origin of major rock units, major structures, and contained mineral and fuel resources, and provides important guidelines for new research. 〈br〉〈br〉 * Prepared in memory of Leonid M. Parfenov, the leader of the geodynamics map team for the International collaborative project on NE Asia tectonics and metallogenesis.

Description: 〈b〉Detrital zircon geochronologic tests of the SE Siberia-SW Laurentia paleocontinental connection〈/b〉〈br〉 J. S. MacLean, J. W. Sears, K. R. Chamberlain, A. K. Khudoley, A. V. Prokopiev, A. P. Kropachev, and G. G. Serkina〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 111-116, https://doi.org/10.5194/smsps-4-111-2009, 2009〈br〉 Strikingly similar Late Mesoproterozoic stratigraphic sequences and correlative U-Pb detrital-zircon ages may indicate that the Sette Daban region of southeastern Siberia and the Death Valley region of southwestern North America were formerly contiguous parts of a Grenville foreland basin. The Siberian section contains large numbers of detrital zircons that correlate with Grenville, Granite-Rhyolite, and Yavapai basement provinces of North America. The sections in both Siberia and Death Valley exhibit west-directed thrust faults that may represent remnants of a Grenville foreland thrust belt. North American detrital-zircon components do not occur in Siberian samples above a ~600 Ma breakup unconformity, suggesting that rifting and continental separation blocked transfer of clastic sediment between the cratons by 600 Ma. Faunal similarities suggest, however, that the two cratons remained within the breeding ranges of Early Cambrian trilobites and archeocyathans.

Description: 〈b〉Seismotectonics of the Chersky Seismic Belt, eastern Sakha Republic (Yakutia) and Magadan District, Russia〈/b〉〈br〉 K. Fujita, B. M. Koz'min, K. G. Mackey, S. A. Riegel, M. S. McLean, and V. S. Imaev〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 117-145, https://doi.org/10.5194/smsps-4-117-2009, 2009〈br〉 The Chersky seismic belt represents a zone of deformation between the North American and Eurasian plates in northeast Russia. The belt extends from the Laptev Sea into the Chersky Range where it splits into two branches. One branch extends to Kamchatka and the Aleutian-Kurile Junction, while the other branch extends south towards Sakhalin Island. Focal mechanisms indicate a change from extension to transpression in the northern Verkhoyansk Range and generally left-lateral transpression in the Chersky Range extending to northern Kamchatka. The few focal mechanisms on the second branch suggest right-lateral transpression. A large number of faults, sub-parallel to the seismicity and presumed to be strike-slip, are visible in satellite imagery and topographic maps and are also associated with seismically generated landslides. 〈br〉〈br〉 These data support a model in which the Sea of Okhotsk forms the core of a separate Okhotsk microplate surrounded by diffuse boundaries on the north and west. Microseismicity in continental northeast Russia is most heavily concentrated within and between the fault systems along the northern boundary of the proposed Okhotsk plate and indicates a high level of deformation. The sense of slip on the faults (both from focal mechanisms and geology) are also generally consistent with the extrusion of the Okhotsk plate to the southeast as it is compressed between its larger neighbors. The northernmost part of the Okhotsk plate may be decoupled to some degree from the more stable central Sea of Okhotsk.

Description: 〈b〉Review of geology of the New Siberian Islands between the Laptev and the East Siberian Seas, North East Russia〈/b〉〈br〉 M. Kos'ko and E. Korago〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 45-64, https://doi.org/10.5194/smsps-4-45-2009, 2009〈br〉 The New Siberian Islands comprise De Long Islands, Anjou Islands, and Lyakhov Islands. Early Paleozoic, Mesozoic and Cenozoic sediments and igneous rocks are known on the De Long Islands. Cambrian slate, siltstone, mudstone and silicified limestone occur on Bennett Island. Ordovician volcanogenic turbidites, lavas, and small intrusions of andesite-basalt, basalt, dolerite, and porphyritic diorite were mapped on Henrietta Island. The igneous rocks are of calc-alkaline island arc series. The Ordovician age of the sequence was defined radiometrically. Early Paleozoic strata were faulted and folded presumably in the Caledonian time. Early Cretaceous sandstone and mudstone are known on Bennett Island. They are overlain by a 106–124 Ma basalt unit. Cenozoic volcanics are widespread on the De Long Islands. Zhokhov Island is an eroded stratovolcano. The volcanics are mostly of picrite-olivine type and limburgite. Radiometric dating indicates Miocene to Recent ages for Cenozoic volcanism. 〈br〉〈br〉 On the Anjou islands Lower-Middle Paleozoic strata consist of carbonates, siliciclastics, and clay. A Northwest-southeast syn-sedimentary facies zonation has been reconstructed. Upper Paleozoic strata are marine carbonate, clay and siliciclastic facies. Mudstone and clay predominate in the Triassic to Upper Jurassic section. Aptian-Albian coal bearing deposits uconformably overlap lower strata indicating Early Cretaceous tectonism. Upper Cretaceous units are mostly clay and siltstone with brown coal strata resting on Early Cretaceous weathered rhyolite. Cenozoic marine and nonmarine silisiclastics and clay rest upon the older units with a transgressive unconformity including a weathering profile in the older rocks. 〈br〉〈br〉 Manifestations of Paleozoic and Triassic mafic and Cretaceous acidic magmatism are also found on these islands. The pre-Cretaceous structure of the Anjou islands is of a block and fold type Late Cimmerian in age followed by faulting in Cenozoic time. 〈br〉〈br〉 The Lyakhov islands are located at the western end of the Late Cimmerian South Anyui suture. Sequences of variable age, composition, and structural styles are known on the Lyakhov Islands. These include an ancient metamorphic sequence, Late Paleozoic ophiolitic sequence, Late Mesozoic turbidite sequence, Cretaceous granites, and Cenozoic sediments. Fold and thrust imbricate structures have been mapped on southern Bol'shoi Lyakhov Island. North-northwestern vergent thrusts transect the Island and project offshore. Open folds of Jurassic–Early Cretaceous strata are characteristic of Stolbovoi and Malyi Lyakhov islands. 〈br〉〈br〉 Geology of the New Siberian Islands supports the concept of a circum Arctic Phanerozoic fold belt. The belt is comprised of Caledonian, Ellesmerian, Early Cimmerian and Late Cimmerian fold systems, manifested in many places on the mainland and on islands around the Arctic Ocean. Knowledge of the geology of the New Siberian Islands has been used to interpret anomalous gravity and magnetic field maps and Multi Channel Seismic (MCS) lines. Two distinguishing structural stages are universally recognized within the offshore sedimentary cover which correlate with the onshore geology of the New Siberian Islands. Dating of the upper structural stage and constituent seismic units is based on structural and stratigraphic relationships between Late Mesozoic and Cenozoic units in the archipelago. The Laptev Sea–western East Siberian Sea seismostratigraphic model for the upper structural stage has much in common with the seismostratigraphic model in the American Chukchi Sea.

Description: 〈b〉Editors and Acknowledgement〈/b〉〈br〉 〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 1-1, https://doi.org/10.5194/smsps-4-1-2009, 2009〈br〉

Description: 〈b〉Morphology of the pore space in claystones – evidence from BIB/FIB ion beam sectioning and cryo-SEM observations〈/b〉〈br〉 G. Desbois, J. L. Urai, and P. A. Kukla〈br〉 eEarth, 4, 15-22, doi:10.5194/ee-4-15-2009, 2009〈br〉 The morphology of pore space has a strong effect on mechanical and transport properties of mudrocks and clay-rich fault gouge, but its characterization has been mostly indirect. We report on a study of Boom clay from a proposed disposal site of radioactive waste (Mol site, Belgium) using high resolution SEM at cryogenic temperature, with ion beam cross-sectioning to prepare smooth, damage free surfaces. Pores commonly have crack-like tips, preferred orientation parallel to bedding and power law size distribution. We define a number of pore types depending on shape and location in the microstructure: large jagged pores in strain shadows of clastic grains, high aspect ratio pores between similarly oriented phyllosilicate grains and crescent-shaped pores in saddle reefs of folded phyllosilicates. 3-D reconstruction by serial cross-sectioning shows 3-D connectivity of the pore space. These findings offer a new insight into the morphology of pores down to nano-scale in comparison to traditional pore size distributions calculated from mercury Injection experiments, explain slaking of clays by successive wetting and drying and provide the basis for microstructure-based models of transport in clays.

Description: 〈b〉Geometry of the Turkey-Arabia and Africa-Arabia plate boundaries in the latest Miocene to Mid-Pliocene: the role of the Malatya-Ovacık Fault Zone in eastern Turkey〈/b〉〈br〉 R. Westaway, T. Demir, and A. Seyrek〈br〉 eEarth, 3, 27-35, doi:10.5194/ee-3-27-2008, 2008〈br〉 We suggest a working hypothesis for the geometry of the strike-slip faults that formed the boundaries between the Turkish, African and Arabian plates in the latest Miocene to Mid-Pliocene (LMMP), between ~7–6 Ma and ~3.5 Ma. This geometry differed significantly from the modern geometry; the northern Dead Sea Fault Zone (DSFZ) was located east of its present line and the TR-AR boundary was formed by the Malatya-Ovacık Fault Zone (MOFZ), located well north of the modern East Anatolian Fault Zone (EAFZ). The MOFZ is potentially the most problematic aspect of such a scheme, given the dramatically different interpretations of it that have been proposed. However, the presently-available evidence, albeit limited, is consistent with our proposed interpretation. Significant differences between the proposed LMMP fault geometry and the modern geometry include, first, the transtensional geometry of the MOFZ, the modern EAFZ being typically a left-lateral transform fault zone but with localized transpression. Second, the MOFZ slip rate was much lower than the ~9–10 mm a〈sup〉−1〈/sup〉 EAFZ slip rate; it is estimated as ~2–3 mm a〈sup〉−1〈/sup〉, having produced no more than ~8 km of slip during its approximately three million year long activity. The Euler vector is tentatively inferred to have involved relative rotation between the Turkish and Arabian Plates at ~0.85±0.15° Ma〈sup〉−1〈/sup〉 about a pole at ~37.75±0.15° N, ~38.8±0.3° E. Third, unlike at present, there was no throughgoing linkage of left-lateral faulting between the LMMP DSFZ and the MOFZ; instead, the DSFZ terminated northward, and the MOFZ terminated southward, in a zone of localised crustal shortening adjoining the suture of the former Neotethys Ocean in the Kahramanmaraş-Pazarcık region of SE Turkey. The different motion of the Turkish plate relative to Arabia, and, thus, relative to Eurasia, means that senses and rates of crustal deformation can be expected to have been different during the LMMP phase from at present, throughout the eastern Mediterranean region.

Description: 〈b〉Late Pleistocene palaeoproductivity patterns during the last climatic cycle in the Guyana Basin as revealed by calcareous nannoplankton〈/b〉〈br〉 G.-E. López-Otálvaro, J. A. Flores, F. J. Sierro, I. Cacho, J.-O. Grimalt, E. Michel, E. Cortijo, and L. Labeyrie〈br〉 eEarth, 4, 1-13, doi:10.5194/ee-4-1-2009, 2009〈br〉 Variations in the assemblage and abundance of coccoliths reveal changes in oceanic and atmospheric dynamics in the Guyana Basin over the last climatic cycle, mainly linked to latitudinal variations in the ITCZ (Intertropical Convergence Zone). Records of the N ratio (a palaeoproductivity index of coccolithophores) allowed us to monitor nutri-thermocline fluctuations. Nannofossil accumulation rates (NAR) vary closely with the N ratio, indicating a strong correlation between these two palaeoproductivity proxies. Decreases in the N ratio and NAR values suggest lower palaeoproductivity during glacial substages, indicating a deep nutri-thermocline (deep stratification of the mixed layer) as a consequence of the piling up of warm water dragged by the NEC. This setting was favoured by the southern shift of the ITCZ and Trade winds which blew perpendicular to the Guyana coast. By contrast, increases in the N ratio and NAR values revealed higher palaeoproductivity during interglacial substages, suggesting a shoaling of the nutri-thermocline. This scenario is favoured by a northward displacement of the ITCZ with the southeast Trade winds blowing alongshore. Additionally, palaeoproductivity changes during substages of Marine Isotope Stage (MIS) 6-5 are of much higher amplitude than those recorded in substages of MIS 4-2 and the early Holocene. Similarities between the palaeoproductivity and the 65° N summer insolation records, suggest a link between the depth of nutri-thermocline, the latitudinal migration of the ITCZ and ice-sheet changes in the Northern Hemisphere.

Description: 〈b〉Decline of coral reefs during late Paleocene to early Eocene global warming〈/b〉〈br〉 C. Scheibner and R. P. Speijer〈br〉 eEarth, 3, 19-26, doi:10.5194/ee-3-19-2008, 2008〈br〉 Since the 1980s the frequency of warming events has intensified and simultaneously widespread coral bleaching, and enhanced coral mortality have been observed. Yet, it remains unpredictable how tropical coral reef communities will react to prolonged adverse conditions. Possibly, coral reef systems are sufficiently robust to withstand continued environmental pressures. But if coral mortality increases, what will platform communities of the future look like? The co-evolution of early Paleogene carbonate platforms and palaeoclimate may provide insight. Here we document the impact of early Paleogene global warming on shallow-water carbonate platforms in the Tethys. Between 59 and 55 Ma, three discrete stages in platform development can be identified Tethys-wide: during the first stage carbonate platforms mainly consisted of coralgal reefs; during the second – transitional – stage coralgal reefs thrived only at middle latitudes and gave way to larger foraminifera as dominant carbonate producer in low latitudes; finally, during the third stage, newly developing larger foraminifera lineages completely took over the role as main carbonate-producing organisms in low to middle latitudes. We postulate that rising temperatures led to a stepwise demise of Paleocene coral reefs, giving way to an unprecedented expansion of larger foraminifera, dominating Tethyan platforms during the early Eocene.

Description: 〈b〉Characteristics of chlorites in seismogenic fault zones: the Taiwan Chelungpu Fault Drilling Project (TCDP) core sample〈/b〉〈br〉 Y. Hashimoto, O. Tadai, M. Tanimizu, W. Tanikawa, T. Hirono, W. Lin, T. Mishima, M. Sakaguchi, W. Soh, S. R. Song, K. Aoike, T. Ishikawa, M. Murayama, K. Fujimoto, T. Fukuchi, M. Ikehara, H. Ito, H. Kikuta, M. Kinoshita, K. Masuda, T. Matsubara, O. Matsubayashi, K. Mizoguchi, N. Nakamura, K. Otsuki, T. Shimamoto, H. Sone, and M. Takahashi〈br〉 eEarth, 3, 1-6, doi:10.5194/ee-3-1-2008, 2008〈br〉 The iron content and the asymmetry of iron and magnesium ions in chlorites are examined for the Chelungpu Fault in Taiwan, which is a seismogenic fault. The samples are collected from the cores drilled for the Taiwan Chelungpu Fault Drilling Project (TCDP, borehole B). Three fault zones are recognized as candidates for the source of seismogenic materials. The fault zones are composed of fractured-damaged rocks, breccia, gray gouge, black gouge, and black material. Chlorite from each type of rock was analyzed by using X-ray diffraction (XRD). The iron content and asymmetry of the iron and magnesium ions in the chlorites were estimated from the XRD peak ratios. The hydroxide and silicate layers of chlorite in the black gouge and black material have low iron contents. Many studies have suggested that a temperature rise occurred at the fault zones. In addition, the temperature rise can result in the production of iron oxides such as magnetite or maghemite, as reported by other studies. However, the temperature rise cannot explain the low value of iron content in the chlorites. Another reason for the low value of iron content is the variation in the pH of the fluid, which can be controlled by radical reactions. Therefore, on the basis of chlorite characteristics, the reactions at the seismogenic fault are due not only to the thermal decomposition resulting from the temperature rise and but also to rock-fluid interactions.

Description: 〈b〉Characteristics of chlorites in seismogenic fault zones: the Taiwan Chelungpu Fault Drilling Project (TCDP) core sample〈/b〉〈br〉 Y. Hashimoto, O. Tadai, M. Tanimizu, W. Tanikawa, T. Hirono, W. Lin, T. Mishima, M. Sakaguchi, W. Soh, S. R. Song, K. Aoike, T. Ishikawa, M. Murayama, K. Fujimoto, T. Fukuchi, M. Ikehara, H. Ito, H. Kikuta, M. Kinoshita, K. Masuda, T. Matsubara, O. Matsubayashi, K. Mizoguchi, N. Nakamura, K. Otsuki, T. Shimamoto, H. Sone, and M. Takahashi〈br〉 eEarth, 3, 1-6, doi:10.5194/ee-3-1-2008, 2008〈br〉 The iron content and the asymmetry of iron and magnesium ions in chlorites are examined for the Chelungpu Fault in Taiwan, which is a seismogenic fault. The samples are collected from the cores drilled for the Taiwan Chelungpu Fault Drilling Project (TCDP, borehole B). Three fault zones are recognized as candidates for the source of seismogenic materials. The fault zones are composed of fractured-damaged rocks, breccia, gray gouge, black gouge, and black material. Chlorite from each type of rock was analyzed by using X-ray diffraction (XRD). The iron content and asymmetry of the iron and magnesium ions in the chlorites were estimated from the XRD peak ratios. The hydroxide and silicate layers of chlorite in the black gouge and black material have low iron contents. Many studies have suggested that a temperature rise occurred at the fault zones. In addition, the temperature rise can result in the production of iron oxides such as magnetite or maghemite, as reported by other studies. However, the temperature rise cannot explain the low value of iron content in the chlorites. Another reason for the low value of iron content is the variation in the pH of the fluid, which can be controlled by radical reactions. Therefore, on the basis of chlorite characteristics, the reactions at the seismogenic fault are due not only to the thermal decomposition resulting from the temperature rise and but also to rock-fluid interactions.

Description: 〈b〉Syn- and post-orogenic exhumation of metamorphic rocks in North Aegean〈/b〉〈br〉 R. Lacassin, N. Arnaud, P. H. Leloup, R. Armijo, and B. Meyer〈br〉 eEarth, 2, 51-63, doi:10.5194/ee-2-51-2007, 2007〈br〉 The Olympos-Ossa-Pelion (OOP) ranges, in NW Aegean, encompass Greece highest summit and are located near the extremity of the North Anatolian Fault (NAF). Structural and thermochronological data gathered in the OOP ranges show that the main exhumation of metamorphic nappes occurred in the Eocene, at ca. 43–39 Ma. This early exhumation, associated with ductile, then brittle-ductile normal faulting with northeastward transport, is coeval with orogenic shortening in the close area. Cooling rates, and likely exhumation, have been low between ~40 Ma and ~20 Ma. 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar crystallization ages (between 20 and 15 Ma) appears related to brittle-ductile normal faulting and likely associated with Neogene Aegean back-arc extension. The dating of a diabase dyke, and the geometry of associated brittle jointing, of onshore and offshore active normal faults suggest a shift in extension direction after 4Ma, possibly in relation with the propagation of the NAF in northern Aegean.

Description: 〈b〉Syn- and post-orogenic exhumation of metamorphic rocks in North Aegean〈/b〉〈br〉 R. Lacassin, N. Arnaud, P. H. Leloup, R. Armijo, and B. Meyer〈br〉 eEarth, 2, 51-63, doi:10.5194/ee-2-51-2007, 2007〈br〉 The Olympos-Ossa-Pelion (OOP) ranges, in NW Aegean, encompass Greece highest summit and are located near the extremity of the North Anatolian Fault (NAF). Structural and thermochronological data gathered in the OOP ranges show that the main exhumation of metamorphic nappes occurred in the Eocene, at ca. 43–39 Ma. This early exhumation, associated with ductile, then brittle-ductile normal faulting with northeastward transport, is coeval with orogenic shortening in the close area. Cooling rates, and likely exhumation, have been low between ~40 Ma and ~20 Ma. 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar crystallization ages (between 20 and 15 Ma) appears related to brittle-ductile normal faulting and likely associated with Neogene Aegean back-arc extension. The dating of a diabase dyke, and the geometry of associated brittle jointing, of onshore and offshore active normal faults suggest a shift in extension direction after 4Ma, possibly in relation with the propagation of the NAF in northern Aegean.

Description: 〈b〉Impact vesiculation – a new trigger for volcanic bubble growth and degassing〈/b〉〈br〉 D. A. Rothery, J. M. Sumner, O. Spieler, and D. B. Dingwell〈br〉 eEarth Discuss., 2, 151-167, doi:10.5194/eed-2-151-2007, 2007〈br〉 〈b〉Revised manuscript has not been submitted〈/b〉 (discussion: closed, 3 comments)〈br〉 We highlight a potentially important trigger for bubble growth and degassing in volcanic bombs. We have successfully triggered bubble growth in previously unvesiculated samples of silicate melt during experiments to simulate volcanic bomb impact, by firing pellets at, and dropping weights onto, melt samples. We call this phenomenon "impact vesiculation". Further work is required on real volcanic bombs to establish the extent to which impact vesiculation occurs in nature. However, our experiments are sufficient to demonstrate that impact vesiculation is a viable processes and should be borne in mind in analysis of bubble populations and degassing histories of bombs and spatter-fed lava flows. Degassing caused by impact vesiculation can occur only at ground-level, so any attempt to calculate the amount of erupted gas available for transport high into the atmosphere by convection above the source of a fountain-fed lava flow that is based on subtracting the volatile content of fluid inclusions from the volatile content of the resulting lava flow would be an overestimate if significant impact vesiculation has occurred.

Description: 〈b〉Impact vesiculation – a new trigger for volcanic bubble growth and degassing〈/b〉〈br〉 D. A. Rothery, J. M. Sumner, O. Spieler, and D. B. Dingwell〈br〉 eEarth Discuss., 2, 151-167, doi:10.5194/eed-2-151-2007, 2007〈br〉 〈b〉Revised manuscript has not been submitted〈/b〉 (discussion: closed, 3 comments)〈br〉 We highlight a potentially important trigger for bubble growth and degassing in volcanic bombs. We have successfully triggered bubble growth in previously unvesiculated samples of silicate melt during experiments to simulate volcanic bomb impact, by firing pellets at, and dropping weights onto, melt samples. We call this phenomenon "impact vesiculation". Further work is required on real volcanic bombs to establish the extent to which impact vesiculation occurs in nature. However, our experiments are sufficient to demonstrate that impact vesiculation is a viable processes and should be borne in mind in analysis of bubble populations and degassing histories of bombs and spatter-fed lava flows. Degassing caused by impact vesiculation can occur only at ground-level, so any attempt to calculate the amount of erupted gas available for transport high into the atmosphere by convection above the source of a fountain-fed lava flow that is based on subtracting the volatile content of fluid inclusions from the volatile content of the resulting lava flow would be an overestimate if significant impact vesiculation has occurred.

Description: 〈b〉Geometry of the Turkey-Arabia and Africa-Arabia plate boundaries in the latest Miocene to Mid-Pliocene: the role of the Malatya-Ovacık Fault Zone in eastern Turkey〈/b〉〈br〉 R. Westaway, T. Demir, and A. Seyrek〈br〉 eEarth, 3, 27-35, doi:10.5194/ee-3-27-2008, 2008〈br〉 We suggest a working hypothesis for the geometry of the strike-slip faults that formed the boundaries between the Turkish, African and Arabian plates in the latest Miocene to Mid-Pliocene (LMMP), between ~7–6 Ma and ~3.5 Ma. This geometry differed significantly from the modern geometry; the northern Dead Sea Fault Zone (DSFZ) was located east of its present line and the TR-AR boundary was formed by the Malatya-Ovacık Fault Zone (MOFZ), located well north of the modern East Anatolian Fault Zone (EAFZ). The MOFZ is potentially the most problematic aspect of such a scheme, given the dramatically different interpretations of it that have been proposed. However, the presently-available evidence, albeit limited, is consistent with our proposed interpretation. Significant differences between the proposed LMMP fault geometry and the modern geometry include, first, the transtensional geometry of the MOFZ, the modern EAFZ being typically a left-lateral transform fault zone but with localized transpression. Second, the MOFZ slip rate was much lower than the ~9–10 mm a〈sup〉−1〈/sup〉 EAFZ slip rate; it is estimated as ~2–3 mm a〈sup〉−1〈/sup〉, having produced no more than ~8 km of slip during its approximately three million year long activity. The Euler vector is tentatively inferred to have involved relative rotation between the Turkish and Arabian Plates at ~0.85±0.15° Ma〈sup〉−1〈/sup〉 about a pole at ~37.75±0.15° N, ~38.8±0.3° E. Third, unlike at present, there was no throughgoing linkage of left-lateral faulting between the LMMP DSFZ and the MOFZ; instead, the DSFZ terminated northward, and the MOFZ terminated southward, in a zone of localised crustal shortening adjoining the suture of the former Neotethys Ocean in the Kahramanmaraş-Pazarcık region of SE Turkey. The different motion of the Turkish plate relative to Arabia, and, thus, relative to Eurasia, means that senses and rates of crustal deformation can be expected to have been different during the LMMP phase from at present, throughout the eastern Mediterranean region.

Description: 〈b〉Late Pleistocene palaeoproductivity patterns during the last climatic cycle in the Guyana Basin as revealed by calcareous nannoplankton〈/b〉〈br〉 G.-E. López-Otálvaro, J. A. Flores, F. J. Sierro, I. Cacho, J.-O. Grimalt, E. Michel, E. Cortijo, and L. Labeyrie〈br〉 eEarth, 4, 1-13, doi:10.5194/ee-4-1-2009, 2009〈br〉 Variations in the assemblage and abundance of coccoliths reveal changes in oceanic and atmospheric dynamics in the Guyana Basin over the last climatic cycle, mainly linked to latitudinal variations in the ITCZ (Intertropical Convergence Zone). Records of the N ratio (a palaeoproductivity index of coccolithophores) allowed us to monitor nutri-thermocline fluctuations. Nannofossil accumulation rates (NAR) vary closely with the N ratio, indicating a strong correlation between these two palaeoproductivity proxies. Decreases in the N ratio and NAR values suggest lower palaeoproductivity during glacial substages, indicating a deep nutri-thermocline (deep stratification of the mixed layer) as a consequence of the piling up of warm water dragged by the NEC. This setting was favoured by the southern shift of the ITCZ and Trade winds which blew perpendicular to the Guyana coast. By contrast, increases in the N ratio and NAR values revealed higher palaeoproductivity during interglacial substages, suggesting a shoaling of the nutri-thermocline. This scenario is favoured by a northward displacement of the ITCZ with the southeast Trade winds blowing alongshore. Additionally, palaeoproductivity changes during substages of Marine Isotope Stage (MIS) 6-5 are of much higher amplitude than those recorded in substages of MIS 4-2 and the early Holocene. Similarities between the palaeoproductivity and the 65° N summer insolation records, suggest a link between the depth of nutri-thermocline, the latitudinal migration of the ITCZ and ice-sheet changes in the Northern Hemisphere.

Description: 〈b〉Use of remote sensing and GIS in mapping the environmental sensitivity areas for desertification of Egyptian territory〈/b〉〈br〉 A. Gad and I. Lotfy〈br〉 eEarth Discuss., 3, 41-85, doi:10.5194/eed-3-41-2008, 2008〈br〉 〈b〉Revised manuscript has not been submitted〈/b〉 (discussion: closed, 3 comments)〈br〉 Desertification is defined in the first art of the convention to combat desertification as 〈i〉"land degradation in arid, semiarid and dry sub-humid areas resulting from climatic variations and human activities".〈/i〉 Its consequence include a set of important processes which are active in arid and semi arid environment, where water is the main limiting factor of land use performance in such ecosystem . Desertification indicators or the groups of associated indicators should be focused on a single process. They should be based on available reliable information sources, including remotely sensed images, topographic data (maps or DEM'S), climate, soils and geological data. The current work aims to map the Environmental Sensitivity Areas (ESA's) to desertification in whole territory of Egypt at a scale of 1:1 000 000. 〈br〉〈br〉 ETM satellite images, geologic and soil maps were used as main sources for calculating the index of Environmental Sensitivity Areas (ESAI) for desertification. The algorism is adopted from MEDALLUS methodology as follows; 〈br〉〈br〉 ESAI = (SQI * CQI * VQI)〈sup〉1/3〈/sup〉 〈br〉〈br〉 Where SQI is the soil quality index, CQI is the climate quality index and VQI is the vegetation quality index. The SQI is based on rating the parent material, slope, soil texture, and soil depth. The VQI is computed on bases of rating three categories (i.e. erosion protection, drought resistance and plant cover). The CQI is based on the aridity index, derived from values of annual rainfall and potential evapotranspiration. Arc-GIS 9 software was used for the computation and sensitivity maps production. 〈br〉〈br〉 The results show that the soil of the Nile Valley are characterized by a moderate SQI, however the those in the interference zone are low soil quality indexed. The dense vegetation of the valley has raised its VQI to be good, however coastal areas are average and interference zones are low. The maps of ESA's for desertification show that 86.1% of Egyptian territory is classified as very sensitive areas, while 4.3% as Moderately sensitive, and 9.6% as sensitive. 〈br〉〈br〉 It can be concluded that implementing the maps of sensitivity to desertification is rather useful in the arid and semi arid areas as they give more likely quantitative trend for frequency of sensitive areas. The integration of different factors contributing to desertification sensitivity may lead to plan a successful combating. The usage of space data and GIS proved to be suitable tools to rely estimation and to fulfill the needed large computational requirements. They are also useful in visualizing the sensitivity situation of different desertification parameters.

Description: 〈b〉Geotectonic setting of the Tertiary Uyandina and Indigirka-Zyryanka basins, Republic Sakha (Yakutia), Northeast Russia, using coal rank data〈/b〉〈br〉 H.-J. Paech〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 85-96, https://doi.org/10.5194/smsps-4-85-2009, 2009〈br〉 Outcrops along the Inach River in the Uyandina basin and those along the Myatis' River in the Indigirka-Zyryanka basin were studied in detail and sampled for coal rank determinations. The Uyandina basin is an intramontane pull-apart basin characterized by extensional structures within the Moma rift system. The coal rank is below 0.3% vitrinite reflectance (〈i〉R〈sub〉r〈/sub〉〈/i〉), which indicates shallow, immature conditions of basin formation and very low subsidence. The Myatis' River coal-bearing outcrops in the Indigirka-Zyryanka basin reveal compression induced by continent collision. The compressive deformation includes also lowermost Pliocene strata. Due to the position in the Verkhoyansk-Chersky fold belt adjacent to the Kolyma-Omolon microcontinent the Indigirka-Zyryanka basin has much in common with a foredeep, i.e. the asymmetry in thickness and tectonic structure. The vitrinite reflectance data (〈i〉R〈sub〉r〈/sub〉〈/i〉) which range from 0.25% to more than 5% reinforce the accepted models that describe basin subsidence and geothermal history and the tectonic deformation.

Description: 〈b〉Structural studies near Pevek, Russia: implications for formation of the East Siberian Shelf and Makarov Basin of the Arctic Ocean〈/b〉〈br〉 E. L. Miller and V. E. Verzhbitsky〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 223-241, https://doi.org/10.5194/smsps-4-223-2009, 2009〈br〉 The Pevek region of Arctic Russia provides excellent beach cliff exposure of sedimentary and igneous rocks that yield detailed information on the nature, progression and timing of structural events in this region. Regional folding and thrust faulting, with the development of a south-dipping axial plane cleavage/foliation developed during N-S to NE-SW directed shortening and formation of the Chukotka-Anyui fold belt. This deformation involves strata as young as Valanginian (136–140 Ma, Gradstein et al., 2004). Fold-related structures are cut by intermediate to silicic batholiths, plutons and dikes of Cretaceous age. Reported K-Ar whole rock and mineral ages on the granitoids range from 144 to 85 Ma, but to the south, more reliable U-Pb zircon ages on compositionally similar plutons yield a much narrower age range of ~120–105 Ma (Miller et al., this volume) and a pluton in Pevek yields a U-Pb age on zircon of 108.1±1.1 Ma with evidence for inheritance of slightly older 115 Ma zircons. Magmas were intruded during an episode of E-W to ENE-WSW directed regional extension based on the consistent N-S to NNW-SSE orientation of over 800 mapped dikes and quartz veins. Analysis of small-offset faults and slickensides yield results compatible with those inferred from the dikes. Younger tectonic activity across this region is minor and the locus of magmatic activity moved southward towards the Pacific margin as represented by the 〈90 Ma Okhotsk-Chukotsk volcanic belt (OCVB). A lengthy period of uplift and erosion occurred after emplacement of Cretaceous plutons and produced the peneplain beneath the younger OCVB. 〈br〉〈br〉 Based on our studies, we speculate that ~120–105 Ma magmatism, which heralds a change in tectonic regime from compression to extension, could represent one of the consequences of the inception of rifting in the Amerasian Basin of the Arctic, forming the Makarov Basin north of the Siberian shelf at this longitude. A synthesis of available seismic reflection, gravity and magnetic data for the offshore Siberian Shelf reveals a widespread, seismically mappable basement-sedimentary cover contact that deepens northward towards the edge of the shelf with few other significant basins. Various ages have been assigned to the oldest strata above the unconformity, ranging from Cretaceous (Albian – 112–100 Ma) to Tertiary (Paleocene–Eocene – ~60–50 Ma). The period of uplift and erosion documented along the Arctic coast of Russia at this longitude could represent the landward equivalent of the (yet undrilled) offshore basement-sedimentary cover contact, thus overlying sedimentary sequences could be as old as early Late Cretaceous. Although quite speculative, these conclusions suggest that land-based geologic, structural, petrologic and geochronologic studies could provide useful constraints to help resolve the plate tectonic history of the Arctic Ocean.

Description: 〈b〉Middle Paleozoic-Mesozoic boundary of the North Asian craton and the Okhotsk terrane: new geochemical and geochronological data and their geodynamic interpretation〈/b〉〈br〉 A. V. Prokopiev, J. Toro, J. K. Hourigan, A. G. Bakharev, and E. L. Miller〈br〉 Stephan Mueller Spec. Publ. Ser., 4, 71-84, https://doi.org/10.5194/smsps-4-71-2009, 2009〈br〉 The Okhotsk terrane, located east of the South Verkhoyansk sector of the Verkhoyansk fold-and-thrust belt, has Archean crystalline basement and Riphean to Early Paleozoic sedimentary cover similar to that of the adjacent the North Asian craton. However, 2.6 Ga biotite orthogneisses of the Upper Maya uplift of the Okhotsk terrane yielded Early Devonian 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar cooling ages, evidence of a Mid-Paleozoic metamorphic event not previously known. These gneisses are also intruded by 375±2 Ma (Late Devonian) calc-alkaline granodiorite plutons that we interpret as part of a continental margin volcanic arc. Therefore, Late Devonian rifting, which affected the entire eastern margin of North Asia separating the Okhotsk terrane from the North Asian craton, was probably a back-arc event. 〈br〉〈br〉 Our limited 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar data from the South Verkhoyansk metamorphic belt suggests that low grade metamorphism and deformation started in the Late Jurassic due to accretion of the Okhotsk terrane to the North Asia margin along the Bilyakchan fault. Shortening and ductile strain continued in the core of the South Verkhoyansk metamorphic belt until about 120 Ma due to paleo-Pacific subduction along the Uda-Murgal continental margin arc.

Description: The early Carboniferous (Mississippian) sedimentary succession of the Montagne Noire is subdivided into three major lithostratigraphic units, in ascending order the Montagne Noire Griotte Group (Devonian to Early Tournaisian), the Tournaisian to Viséan Saint-Nazaire Group (with the Lydiennes, Faugères, Colonnes, and Puech Capel Formations, the latter new), and the Laurens Flysch Group (late Viséan). The ammonoid assemblages in these rock units are reviewed. A total of 29 Early Carboniferous ammonoid taxa at species level are determined. The new genus Nigrocyclus n. gen., and the new species Gattendorfia nazairensis n. sp., Globimitoceras albaillei n. sp., and Neogoniatites canovasi n. sp. are described. Die unterkarbonische Abfolge von Sedimentgesteinen in der Montagne Noire wird in drei lithostratigraphische Einheiten untergliedert, von unten nach oben die Montagne Noire Griotte Gruppe (Oberdevon bis Untertournai), die Saint-Nazaire Gruppe des Tournaisium und Viséum (mit den Lydiennes Faugères, Colonnes und Puech Capel Formationen, von denen die letzte neu ist), und der Laurens Flysch Gruppe (Oberviséum). Die Ammonoideen-Vergesellschaftungen in diesen Gesteinen werden revidiert. Insgesamt werden 29 unterkarbonische Ammonoideen-Taxa auf Artebene aufgeführt; neu beschrieben werden die Gattung Nigrocyclus n. gen. sowie die Arten Gattendorfia nazairensis n. sp., Globimitoceras albaillei n. sp. und Neogoniatites canovasi n. sp. doi:10.1002/mmng.200700002

Description: The occurrence of Triodus teberdaensis n. sp. teeth from the Pennsylvanian Tolstiy Bugor Formation (Moscovian) of Karachay-Cherkess Republic is the first evidence of xenacanthid remains from the Caucasus. The new species was found in carbonate sediments interpreted as resulting from short-term transgressions during the Pennsylvanian regressive phase – further evidence that xenacanthids, predominantly adapted to freshwater, have also lived in marine environments. Das Auftreten von Zähnen des Triodus teberdaensis n. sp. in der oberkarbonischen Tolstiy Bugor Formation (Moscovium) von Karatschai-Tscherkessien ist der erste Nachweis xenacanthider Überreste aus dem Kaukasus. Die neue Art wurde in karbonatischen Sedimenten, die als Transgressions-Intervalle innerhalb der globalen Oberkarbon-Regression interpretiert werden, abgelagert – ein Beleg dafür, dass die überwiegend aus Süßwasserablagerungen bekannten Xenacanthiden auch im marinen Milieu lebten. doi:10.1002/mmng.200700004

Description: Elemental carbon (EC), as one of the primary light-absorbing components in the atmosphere, has a significant impact on both regional and global climate. The environmental impacts of EC are strongly dependent on its particle size. Little is known about the size distribution characteristics of EC particles in the ambient environments of China. We here report size distributions of EC in the urban area of Shenzhen in South China. EC consistently exhibited two modes, a fine and a coarse mode. The majority of EC (~80%) in this coastal metropolitan city resided in particles smaller than 3.2 μm in diameter. The fine mode peaked at around either 0.42 μm or 0.75 μm. While the mode at 0.42 μm could be ascribed to fresh vehicular emissions in this region, the mode at 0.75 μm had to be a result of particle growth from smaller EC particles. We made a theoretical investigation of the particle growth processes that were responsible for EC particles to grow from 0.42 μm to 0.75 μm in the atmosphere. Our calculations indicate that the EC peak at 0.75 μm could not be produced through either coagulation or H2SO4 condensation; both were too slow to lead to significant EC growth. Hygroscopic growth was also calculated to be impossible. Instead, addition of sulfate through in-cloud processing was found to be able to significantly grow EC particles to explain the EC peak at 0.75 μm. We also estimated from the EC size distributions the mixing state of EC. In the droplet size, at least 45–60% of EC mass in the summer samples and 68% of EC mass in the winter samples was internally mixed with sulfate as a result of in-cloud processing. Such information on EC needs to be considered in modeling aerosol optical properties in this region. Our results also suggest that the in-cloud processing of primary EC particles could enhance light absorbing capacities through mixing EC and sulfate.

Description: An integrated sand and dust storm (SDS) forecasting system – CUACE/Dust (the Chinese Unified Atmospheric Chemistry Environment for Dust) has been developed, which consists of a comprehensive dust aerosol module with emission, dry/wet depositions and other atmospheric dynamic processes, and a data assimilation system (DAS) using observational data from the CMA (China Meteorological Administration) ground dust monitoring network and retrieved dust information from a Chinese geostationary satellite – FY-2C. This is the first time that a combination of surface network observations and satellite retrievals of the dust aerosol has been successfully used in the real time operational forecasts in East Asia through a DAS. During its application for the operational SDS forecasts in East Asia for spring 2006, this system captured the major 31 SDS episodes observed by both surface and satellite observations. Analysis shows that the seasonal mean threat score (TS) for 0–24 h forecast over the East Asia in spring 2006 increased from 0.22 to 0.31 by using the DAS, a 41% enhancement. The time series of the forecasted dust concentrations for a number of representative stations for the whole spring 2006 were also evaluated against the surface PM10 monitoring data, showing a very good agreement in terms of the SDS timing and magnitudes near source regions where dust aerosols dominate. This is a summary paper for a special issue of ACP featuring the development and results of the forecasting system.

Description: Chemical and physical processes, such as heterogeneous chemical reactions, light scattering, and metamorphism occur in the natural snowpack. To model these processes in the snowpack, the specific surface area (SSA) is a key parameter. In this study, two methods, computed tomography and methane adsorption, which have intrinsically different spatial resolutions –molecular and 30 μm, respectively – were used to determine the SSA of identical natural snow samples. The two methods give identical results, with an uncertainty of 3%. This implies that the surface of natural snow is smooth up to a scale of about 30 μm and that for optical methods a voxel size of 10 μm is sufficient to capture all structural features of natural snow. This smoothness can be physically explained by calculating sublimation and surface diffusion on the snow particles. The methane adsorption method is superior to computed tomography for very fresh snow, but thin layers typical for natural snowpacks can not be resolved. Computed tomography can measure SSA in layers of less than 1 mm thickness, and is therefore advantageous in layered snowpacks.

Description: Secondary organic aerosol (SOA) formation from the photooxidation of one monoterpene (α-pinene) and two sesquiterpenes (longifolene and aromadendrene) is investigated in the Caltech environmental chambers. The effect of NOx on SOA formation for these biogenic hydrocarbons is evaluated by performing photooxidation experiments under varying NOx conditions. The NOx dependence of α-pinene SOA formation follows the same trend as that observed previously for a number of SOA precursors, including isoprene, in which SOA yield (defined as the ratio of the mass of organic aerosol formed to the mass of parent hydrocarbon reacted) decreases as NOx level increases. The NOx dependence of SOA yield for the sesquiterpenes, longifolene and aromadendrene, however, differs from that determined for isoprene and α-pinene; the aerosol yield under high-NOx conditions substantially exceeds that under low-NOx conditions. The reversal of the NOx dependence of SOA formation for the sesquiterpenes is consistent with formation of relatively low-volatility organic nitrates, and/or the isomerization of large alkoxy radicals leading to less volatile products. Analysis of the aerosol chemical composition for longifolene confirms the presence of organic nitrates under high-NOx conditions. Consequently the formation of SOA from certain biogenic hydrocarbons such as sesquiterpenes (and possibly large anthropogenic hydrocarbons as well) may be more efficient in polluted air.

Description: The species and chemistry responsible for secondary organic aerosol (SOA) formation remain highly uncertain. Laboratory studies of the oxidation of individual, high-flux SOA precursors do not lead to particles with mass spectra (MS) matching those of ambient aged organic material. And, the complexity of real organic particles challenges efforts to identify their chemical origins. We have previously hypothesized that SOA can form from the atmospheric oxidation of a large suite of precursors with varying vapor pressures. Here, we support this hypothesis by using an aerosol mass spectrometer to track the chemical evolution of diesel exhaust as it is photochemically oxidized in an environmental chamber. With explicit knowledge of the condensed-phase MS of the primary emissions from our engine, we are able to decompose each recorded MS into contributing primary and secondary spectra throughout the experiment. We find that the SOA MS becomes increasingly oxidized as a function of time, eventually reaching a final MS that closely resembles that of ambient aged organic particulate matter. This observation is consistent with the idea that lower vapor pressure, semi-volatile organic emissions can form condensable products with fewer generations of oxidation, and therefore, they form relatively less oxidized SOA very quickly.

Description: The formation of formaldehyde via hydrogen atom transfer from the methoxy radical to molecular oxygen is a key step in the atmospheric photochemical oxidation of methane, and in the propagation of deuterium from methane to molecular hydrogen. We report the results of the first investigation of the branching ratio for HCHO and HCDO formation in the CH2DO+O2 reaction. Labeled methoxy radicals (CH2DO) were generated in a photochemical reactor by photolysis of CH2DONO. HCHO and HCDO concentrations were measured using FTIR spectroscopy. Significant deuterium enrichment was seen in the formaldehyde product, from which we derive a branching ratio of 88.2±1.1% for HCDO and 11.8±1.1% for HCHO. The implications of this fractionation on the propagation of deuterium in the atmosphere are discussed.

Description: The chemistry climate model ECHAM5/MESSy1 (E5/M1) in a setup extending from the surface to 80 km with a vertical resolution of about 600 m near the tropopause with nudged tropospheric meteorology allows a direct comparison with satellite data of chemical species at the same time and location. Here we present results out of a transient 10 years simulation for the period of the Antarctic vortex split in September 2002, where data of MIPAS on the ENVISAT-satellite are available. For the first time this satellite instrument opens the opportunity, to evaluate all stratospheric nitrogen containing species simultaneously with a good global coverage, including the source gas N2O which allows an estimate for NOx-production in the stratosphere. We show correlations between simulated and observed species in the altitude region between 10 and 50 hpa for different latitude belts, together with the Probability Density Functions (PDFs) of model results and observations. This is supplemented by global charts on pressure levels showing the satellite data and the simulated data sampled at the same time and location. We demonstrate that the model in most cases captures the partitioning in the nitrogen family, the diurnal cycles and the spatial distribution within experimental uncertainty. There appears to be, however, a problem to reproduce the observed nighttime partitioning between N2O5 and NO2 in the middle stratosphere.

Description: We investigate the extent to which commonly considered quantities, based on total column ozone observations and simulations, are applicable as measures of ozone loss in the polar vortices. Such quantities have been used frequently in ozone assessments by the World Meteorological Organization (WMO) and to assess the performance of chemistry-climate models. The most commonly considered quantity is monthly mean column ozone poleward of a latitude of 63° in spring. For the Arctic, these monthly means were found to be insensitive to the exact choice of the latitude threshold, unlike the Antarctic where greater sensitivity was found. Choosing a threshold based on the location of the transport barrier at the vortex boundary instead of geometric latitude led to a roughly similar year-to-year variability of the monthly means, but in particular years deviations of several tens of Dobson units occurred. Moreover, the minimum of daily total ozone minima poleward of a particular latitude, another popular measure, is debatable, insofar as it relies on one single measurement or model grid point. For Arctic conditions, this minimum value occurred often in air outside polar vortex, both in the observations and in a chemistry-climate model. As a result, we recommend that the minimum of daily minima no longer be used when comparing polar ozone loss in observations and models. As a possible alternative, we suggest considering the minimum of daily average total ozone poleward of a particular equivalent latitude (or in the vortex) in spring. This definition both obviates relying on one single data point and reduces the impact of year-to-year variability in the Arctic vortex breakup on ozone loss measures. However, compact relations of such simple measures with meteorological quantities that describe the potential for polar heterogeneous chlorine activation and thus ozone loss were not found. Therefore, we argue that where possible, more sophisticated measures of chemical polar ozone loss that include additional information to disentangle the impact of transport and chemistry on ozone, should be employed.

Description: Ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements were performed at Tsukuba, Japan (36.1° N, 140.1° E), in November–December 2006. The measured spectra of scattered sunlight are analyzed by DOAS and optimal estimation methods to retrieve the aerosol optical depth (τ) and the vertical profile of the aerosol extinction coefficient (σ) at 476 nm in the lower troposphere. We characterize these retrieved quantities through comparisons with coincident lidar and sky radiometer measurements. The retrieved σ values for layers of 0–1 and 1–2 km agree with lidar data to within 30% and 60%, respectively, for most cases, including partly cloudy conditions. Results similar to σ at 0–1 km are obtained for the retrieved τ values, demonstrating that MAX-DOAS provides the new, unique aerosol dataset in the lower troposphere.

Description: Ozone (O3) profiles recorded over Beijing from 1995 to 2005 by the Measurement of Ozone and Water Vapor by Airbus In-Service Aircraft (MOZAIC) program were analyzed to provide a first climatology of tropospheric O3 over Beijing and the North China Plains (NCPs), one of the most populated and polluted regions in China. A pooled method was adopted in the data analysis to reduce the influence of irregular sampling frequency. The tropospheric O3 over Beijing shows a seasonal and vertical distribution typical of mid-latitude locations in the Northern Hemisphere, but has higher daytime concentrations in the lower troposphere, when compared to New York City, Tokyo, and Paris at similar latitude. The tropospheric O3 over Beijing exhibits a common summer maximum and a winter minimum, with a broad summer maximum in the middle troposphere and a narrower early summer (June) peak in the lower troposphere. Examination of meteorological and satellite data suggests that the lower tropospheric O3 maximum in June is a result of strong photochemical production, transport of regional pollution, and possibly also more intense burnings of biomass in Central-Eastern China. Trajectory analysis indicates that in summer the regional pollution sources from the NCPs, maybe mixed with urban plumes from Beijing, played important roles on the high O3 concentrations in the boundary layer, but had limited impact on the O3 concentrations in the middle troposphere. A comparison of the data recorded before and after 2000 reveals that O3 in the lower troposphere over Beijing had a strong positive trend (approximately 2% per year from 1995 to 2005) in contrast to a flat or a decreasing trend over Tokyo, New York City, and Paris, indicating worsening photochemical pollution in Beijing and the NCPs.

Description: Organic carbon (OC) comprises a large fraction of fine particulate matter (PM2.5) in Mexico City. Daily and select 12-h PM2.5 samples were collected in urban and peripheral sites in Mexico City from 17–30 March 2006. Samples were analyzed for OC and elemental carbon (EC) using thermal-optical filter-based methods. Real-time water-soluble organic carbon (WSOC) was collected at the peripheral site. Organic compounds, particularly molecular markers, were quantified by soxhlet extraction with methanol and dichloromethane, derivitization, and gas chromatography with mass spectrometric detection (GCMS). A chemical mass balance model (CMB) based on molecular marker species was used to determine the relative contribution of major sources to ambient OC. Motor vehicles, including diesel and gasoline, consistently accounted for 47% of OC in the urban area and 31% on the periphery. The daily contribution of biomass burning to OC was highly variable, and ranged from 5–30% at the urban site and 11–50% at the peripheral site. The remaining OC unapportioned to primary sources showed a strong correlation with WSOC and was considered to be secondary in nature. Comparison of temporally resolved OC showed that contributions from primary aerosol sources during daylight hours were not significantly different from nighttime. This study provides quantitative understanding of the important sources of OC during the MILAGRO 2006 field campaign.

Description: Reliable reference profiles and estimates of variability are a necessity for a variety of processes relating to ENVISAT including the development of key aspects and inputs for the operational processor for the Michelson Interferometer for Passive Atmospheric Sounding. MIPAS reference atmospheres have therefore been produced in two forms, namely standard atmospheres for modelling and error analysis for typical atmospheric situations and the IG2 seasonal climatologies for initial guess profiles used as part of the operational processing. The reference states cover 36 species on a common altitude, pressure, and temperature grid from 0 to 120 km, and include both means and estimates of variability (maximum, minimum and one sigma values). This paper describes V3.1 of the standard atmospheres and V4.0 of the IG2 atmospheres which are the current versions of the reference atmospheres. Particular attention is paid to the MIPAS operational geophysical products (pressure/temperature, H2O, O3, CH4, N2O, HNO3 and NO2) and to CO2 whose mixing ratio is required for the retrieval of pressure and temperature. A dynamic representation of CO2 is presented which shows the presence of CO2 gradients in the troposphere and the lower stratosphere. Since these atmospheres have been produced independently of MIPAS data, it is also possible to compare the data to the MIPAS operational products and derive valuable information on both the reference atmospheres and on MIPAS data products themselves. This process has been performed for V4.61/V4.62 data from the year 2003 as part of the MIPAS validation activity. It is demonstrated that the agreement between the MIPAS mean data and the reference atmospheres is very good in mid-latitudes and the tropics, verifying these data to first order. There is also reasonable agreement in standard deviations between the IG2 atmospheres and the corresponding sigmas calculated from the MIPAS data. Knowledge of tropospheric concentrations of CH4 and N2O is used to examine the accuracy of the MIPAS data and their susceptibility to cloud effects. It is shown that for the highest accuracy, MIPAS data should be filtered with cloud index values of 2.5 for N2O and 3.5 for CH4. Once such filtering has been performed, the MIPAS data for these species appear to be accurate to within 10% in the upper troposphere. The use of cloud index data in combination with MIPAS data is recommended for studies of the polar winter stratosphere and the upper troposphere/lower stratosphere.

Description: A differential scanning calorimeter (DSC) was used to explore heterogeneous ice nucleation of emulsified aqueous suspensions of two Arizona test dust (ATD) samples with particle diameters of nominally 0–3 and 0–7 μm, respectively. Aqueous suspensions with ATD concentrations of 0.01–20 wt% have been investigated. The DSC thermograms exhibit a homogeneous and a heterogeneous freezing peak whose intensity ratios vary with the ATD concentration in the aqueous suspensions. Homogeneous freezing temperatures are in good agreement with recent measurements by other techniques. Depending on ATD concentration, heterogeneous ice nucleation occurred at temperatures as high as 256 K or down to the onset of homogeneous ice nucleation (237 K). For ATD-induced ice formation Classical Nucleation Theory (CNT) offers a suitable framework to parameterize nucleation rates as a function of temperature, experimentally determined ATD size, and emulsion droplet volume distributions. The latter two quantities serve to estimate the total heterogeneous surface area present in a droplet, whereas the suitability of an individual heterogeneous site to trigger nucleation is described by the compatibility function (or contact angle) in heterogeneous CNT. The intensity ratio of homogeneous to heterogeneous freezing peaks is in good agreement with the assumption that the ATD particles are randomly distributed amongst the emulsion droplets. The observed dependence of the heterogeneous freezing temperatures on ATD concentrations cannot be described by assuming a constant contact angle for all ATD particles, but requires the ice nucleation efficiency of ATD particles to be (log)normally distributed amongst the particles. Best quantitative agreement is reached when explicitly assuming that high-compatibility sites are rare and that therefore larger particles have on average more and better active sites than smaller ones. This analysis suggests that a particle has to have a diameter of at least 0.1 μm to exhibit on average one active site.

Description: The data assimilation of stratospheric constituents is reviewed. The data assimilation method is introduced, with particular consideration to its application to stratospheric constituent measurements. Differences from meteorological data assimilation are outlined. Historically, two approaches have been used to carry out constituent assimilation. One approach has carried constituent assimilation out as part of a numerical weather prediction system; the other has carried it out in a standalone chemical model, often with a more sophisticated representation of chemical processes. Whereas the aim of the numerical weather prediction approach has been to improve weather forecasts, the aims of the chemical model approach have included providing chemical forecasts and analyses of chemical constituents. A range of constituent assimilation systems developed in these two areas is presented and strengths and weaknesses discussed. The use of stratospheric constituent data assimilation to evaluate models, observations and analyses, and to provide analyses of constituents, monitor ozone, and make ozone forecasts is discussed. Finally, the current state of affairs is assessed, future directions are discussed, and potential key drivers identified.

Description: Elastic and polarization lidar was used to measure the vertical profiles of aerosol backscattering coefficients at wavelengths of 355, 532, 735, and 1064 nm, and the depolarization ratio at 532 nm in order to study the aerosol properties in the free troposphere over Tsukuba, Japan, in 2006. An elevated dust layer was observed at altitudes between 3 and 8.5 km on 1 April during the Asian dust period. The wavelength exponents of the aerosol backscattering coefficient (k) were –0.1 to 0.5, and the depolarization ratio (δp) was 25% for the dust layer, suggesting the predominance of supermicrometer-sized (coarse mode) nonspherical particles. An aerosol layer observed at altitudes between 1.5 and 5 km on 19 October during the less-dust period exhibited the values of k=1.0 to 1.6 and δp=1 to 13%, suggesting the predominance of submicrometer-sized (fine mode) particles. In those layers, the values of k and δp varied with height; they were also negatively correlated, suggesting that the proportion of the coarse nonspherical particles to total particles varied. The particle size distributions estimated from the observed values and the theoretical computation revealed number mode radii of 0.3 &mum; for the coarse mode and 0.1 &mum; for the fine mode, assuming bimodal distribution. These results were consistent with those obtained from the sky-radiometer measurements, although they revealed another mode in the larger radius. The column volume concentration derived from the lidar was 48% lower than that derived from the sky-radiometer on 1 April and 16% lower on 19 October. The optical thickness derived from the lidar was 12% lower than that obtained from the sky-radiometer on 1 April and 29% higher on 19 October. Further case study is necessary to validate the method for estimating aerosol properties based on the lidar measurement.

Description: Using three meteorological reanalyses and three outgoing long-wave radiation (OLR) datasets, we show that the Hadley circulation has a significant poleward expansion of about 2 to 4.5 degrees of latitude since 1979. The three reanalyses along with the MSU data all indicate that the poleward expansion of the Hadley circulation in each hemisphere occurs during its spring and fall seasons. Results from the OLR datasets do not have such seasonality. The expansion of the Hadley circulation implies a poleward expansion of the band of subtropical subsidence, leading to enhanced mid-latitude tropospheric warming and poleward shifts of the subtropical dry zone. This would contribute to an increased frequency of midlatitude droughts in both hemispheres.

Description: In spring 2006 a special meteorological situation occurred in the European Arctic region giving record high levels of air pollution. The synoptic situation resulted in extensive transport of pollution predominantly from agricultural fires in Eastern Europe into the Arctic region and record high air-pollution levels were measured at the Zeppelin observatory at Ny-Ålesund (78°54' N, 11°53' E) in the period from 25 April to 12 May. In the present study we investigate the optical properties of the aerosols from this extreme event and we estimate the radiative forcing of this episode. We examine the aerosol optical properties from the source region and into the European Arctic and explore the evolution of the episode and the changes in the optical properties. A number of sites in Eastern Europe, Northern Scandinavia and Svalbard are included in the study. In addition to AOD measurements, we explored lidar measurements from Minsk, ALOMAR (Arctic Lidar Observatory for Middle Atmosphere Research at Andenes) and Ny-Ålesund. For the AERONET sites included (Minsk, Toravere, Hornsund) we have further studied the evolution of the aerosol size. Importantly, at Svalbard it is consistency between the AERONET measurements and calculations of single scattering albedo based on aerosol chemical composition. We have found strong agreement between the satellite daily MODIS AOD and the ground-based AOD observations. This agreement is crucial for the radiative forcing calculations. We calculate a strong negative radiative forcing for the most polluted days employing the analysed ground based data, MODIS AOD and a multi-stream model for radiative transfer of solar radiation.

Description: A one-dimensional chemical transport model has been developed to investigate the vertical gradients of bromine and iodine compounds in the Antarctic coastal boundary layer. The model has been applied to interpret recent year-round observations of iodine and bromine monoxides (IO and BrO) at Halley Station, Antarctica. The model requires an equivalent I atom flux of ~109 molecule cm−2 s−1 from the snowpack in order to account for the measured IO levels, which are up to 20 ppt during spring. Using the current knowledge of gas-phase iodine chemistry, the model predicts significant gradients in the vertical distribution of iodine species. However, recent ground-based and satellite observations of IO imply that the radical is well-mixed in the boundary layer, indicating a longer than expected atmospheric lifetime for the radical. This can be modelled by including photolysis of the higher iodine oxides (I2O2, I2O3, I2O4 and I2O5), and rapid recycling of HOI and INO3 through sea-salt aerosol. The model also predicts significant concentrations (up to 25 ppt) of I2O5 in the lowest 10 m of the boundary layer, which could lead to the formation of ultrafine iodine oxide aerosols. Heterogeneous chemistry involving sea-salt aerosol is also necessary to account for the vertical profile of BrO. Iodine chemistry causes a large increase (typically more than 3-fold) in the rate of O3 depletion in the BL, compared with bromine chemistry alone. Rapid entrainment of O3 from the free troposphere is required to account for the observation that on occasion there is little O3 depletion at the surface in the presence of high concentrations of IO and BrO. The halogens also cause significant changes to the vertical profiles of HO and HO2 and the NO2/NO ratio. The average Hg0 lifetime against oxidation is also predicted to be about 10 h during springtime. Overall, our results show that halogens profoundly influence the oxidizing capacity of the Antarctic troposphere.

Description: Fast measurements of aerosol and gas-phase constituents coupled with the ISORROPIA-II thermodynamic equilibrium model are used to study the partitioning of semivolatile inorganic species and phase state of Mexico City aerosol sampled at the T1 site during the MILAGRO 2006 campaign. Overall, predicted semivolatile partitioning agrees well with measurements. PM2.5 is insensitive to changes in ammonia but is to acidic semivolatile species. Semi-volatile partitioning equilibrates on a timescale between 6 and 20 min. When the aerosol sulfate-to-nitrate molar ratio is less than 1, predictions improve substantially if the aerosol is assumed to follow the deliquescent phase diagram. Treating crustal species as "equivalent sodium" (rather than explicitly) in the thermodynamic equilibrium calculations introduces important biases in predicted aerosol water uptake, nitrate and ammonium; neglecting crustals further increases errors dramatically. This suggests that explicitly considering crustals in the thermodynamic calculations are required to accurately predict the partitioning and phase state of aerosols.

Description: We present month-long observations of speciated acyl peroxy nitrates (APNs), including PAN, PPN, MPAN, APAN, and the sum of PiBN and PnBN, measured at the Mount Bachelor Observatory (MBO) as part of the INTEX-B collaborative field campaign during spring 2006. APN abundances, measured by thermal dissociation-chemical ionization mass spectrometry (TD-CIMS), are discussed in terms of differing contributions from the boundary layer and the free troposphere and in the context of previous APN measurements in the NE Pacific region. PAN mixing ratios range from 11 to 3955 pptv, with a mean value of 334 pptv for the full measurement period. PPN is linearly correlated with PAN (r2=0.96), with an average abundance of 6.5% relative to PAN; other APNs are generally

Description: We examined the response of surface ozone to future climate change over the eastern United States by performing simulations corresponding to present (1990s) and future (2050s) climates using an integrated model of global climate, tropospheric gas-phase chemistry, and aerosols. A future climate has been imposed using ocean boundary conditions corresponding to the IPCC SRES A2 scenario for the 2050 s decade, resulting in an increase in the global annual-average surface air temperature by 1.7°C, with a 1.4°C increase over the surface layer of the eastern United States. Present-day anthropogenic emissions and CO2/CH4 mixing ratios have been used in both simulations while climate-sensitive natural emissions were allowed to vary with the simulated climate. There is practically zero change in the spatiotemporally averaged ozone mixing ratios predicted over the eastern United States. However, the severity and frequency of ozone episodes over the eastern United States increased due to future climate change, primarily as a result of increased ozone chemical production due to increased natural isoprene emissions. The 95th percentile ozone mixing ratio increased by 5 ppbv and the largest frequency increase occured in the 80–90 ppbv range. The most substantial and statistically significant (p-value

Description: The global chemical transport model Oslo CTM2 has been extended to include the formation, transport and deposition of secondary organic aerosol (SOA). Precursor hydrocarbons which are oxidised to form condensible species include both biogenic species such as terpenes and isoprene, as well as species emitted predominantly by anthropogenic activities (toluene, m-xylene, methylbenzene and other aromatics). A model simulation for 2004 gives an annual global SOA production of approximately 55 Tg. Of this total, 2.5 Tg is found to consist of the oxidation products of anthropogenically emitted hydrocarbons, and about 15 Tg is formed by the oxidation products of isoprene. The global production of SOA is increased to about 76 Tg yr−1 by allowing semi-volatile species to condense on ammonium sulphate aerosol. This brings modelled organic aerosol values closer to those observed, however observations in Europe remain significantly underestimated, raising the possibility of an unaccounted for SOA source. Allowing SOA to form on ammonium sulphate aerosol increases the contribution of anthropogenic SOA from about 4.5% to almost 9% of the total production. The importance of NO3 as an oxidant of SOA precursors is found to vary regionally, causing up to 50%–60% of the total amount of SOA near the surface in polluted regions and less than 25% in more remote areas. This study underscores the need for SOA to be represented in a more realistic way in global aerosol models in order to better reproduce observations of organic aerosol burdens in industrialised and biomass burning regions.

Description: The CCN properties, surfactant characteristics, and droplet growth kinetics of secondary organic aerosol (SOA) formed from the ozonolysis of three parent alkene hydrocarbons (terpinolene, 1-methlycycloheptene and cycloheptene) are explored. Based on measurements of CCN activity, total carbon and inorganic ion concentrations, we estimate the average molar volume of the water-soluble organic component using Köhler Theory Analysis (KTA). The results suggest that the water-soluble organics in the SOA are composed of relatively low molecular weight species, with an effective molar mass less than 200 g mol−1. This finding is consistent with the speciated fraction for some of the SOA, and suggests that KTA can be applied to complex organic aerosol, such as that found in the atmosphere. From measurements of CCN activity and Köhler Theory, we apply a novel method to infer the surface tension at the point of activation; this is used to infer the presence of surface-active organics. It is found that the water-soluble carbon can be surface-active, depressing surface tension 10–15% from that of pure water at concentrations relevant for CCN activation. Although important, this level of surface tension depression is lower than expected for HULIS, which suggest that they are not likely in the SOA examined. In all cases, the CCN exhibit droplet growth kinetics similar to (NH4)2SO4.

Description: Solar irradiance spectral measurements were performed during a total solar eclipse. The spectral effect of the limb darkening to the global, direct irradiance and actinic flux measurements was investigated. This effect leads to wavelength dependent changes in the measured solar spectra showing a much more pronounced decrease in the radiation at the lower wavelengths. Radiative transfer model results were used for the computation of a correction for the total ozone measurements due to the limb darkening. This correction was found too small to explain the large decrease in total ozone column derived from the standard Brewer measurements, which is an artifact in the measured irradiance due to the increasing contribution of diffuse radiation against the decreasing direct irradiance caused by the eclipse. Calculations of the Extraterrestrial spectrum and the effective sun's temperatures, as measured from ground based direct irradiance measurements, showed an artificial change in the calculations of both quantities due to the fact that radiation coming from the visible part of the sun during the eclipse phases differs from the back body radiation described by the Planck's law.

Description: Correctly modeling stratospheric inorganic chlorine (Cly) is crucial for modeling the past and future evolution of stratospheric ozone. However, comparisons of the chemistry climate models used in the latest international assessment of stratospheric ozone depletion have shown large differences in the modeled Cly, with these differences explaining differences in the simulated evolution of ozone over the next century. Here in, we examine the role of transport in determining the simulated Cly using three simulations from the same off-line chemical transport model that have the same lower tropospheric boundary conditions and the same chemical solver, but differing resolution and/or meteorological fields. These simulations show that transport plays a key role in determining the Cly distribution, and that Cly depends on both the time scales and pathways of transport. The time air spends in the stratosphere (e.g., the mean age) is an important transport factor determining stratospheric Cly, but the relationship between mean age and Cly is not simple. Lower stratospheric Cly depends on the fraction of air that has been in the upper stratosphere, and transport differences between models having the same mean age can result in differences in the fraction of organic chlorine converted into Cly. Differences in transport pathways result in differences in vertical profiles of CFCs, and comparisons of observed and modeled CFC profiles provides a stringent test of transport pathways in models.

Description: We describe an estimation technique for biomass burning emissions in South America based on a combination of remote sensing fire products and field observations. For each fire pixel detected by remote sensing, the mass of the emitted tracer is calculated based on field observations of fire properties related to the type of vegetation burning. The burnt area is estimated from the instantaneous fire size retrieved by remote sensing, when available, or from statistical properties of the burn scars. The sources are then spatially and temporally distributed and assimilated daily by the Coupled Aerosol and Tracer Transport model to the Brazilian developments on the Regional Atmospheric Modeling System (CATT-BRAMS) in order to perform the prognostic of related tracer concentrations. Two other biomass burning inventories are simultaneously used to compare the emission strength in terms of the resultant tracer distribution. Several evaluations of the model with the three emission estimations were performed, comparing results with direct measurements of carbon monoxide both near-surface and airborne, as well as remote sensing derived products. Model results with the methodology of estimation introduced in this paper show a relatively good agreement with the direct measurements and MOPITT data product; pointing out the reliability of the model from local to regional scales.

Description: In radiative transfer simulations the simplification of cloud top structure by homogenous assumptions can breed to mistakes in comparison to realistic heterogeneous cloud top structures. This paper examines the influence of cloud top heterogeneity on the radiation at the top of the atmosphere. The use of cloud top measurements with a high temporal resolution allows to analyse small spatial cloud top heterogeneities by using the frozen turbulence assumption for the time – space conversion. Radiative observations are often based on satellite measurements, whereas small spatial structures are not considered in such treatments. A spectral analysis of the cloud top measurements showed slopes of power spectra between –1.8 and –2.0, this values are larger then the spectra of –5/3 which is often applied to generate cloud field variability. The comparison of 3-D radiative transfer results from cloud fields with homogenous and heterogeneous tops have been done for a single wavelength of 0.6 μm. The radiative transfer calculations result in lower albedos for heterogeneous cloud tops. The differences of albedos between heterogeneous and homogeneous cloud top decrease with increasing solar zenith angle. The influence of cloud top variability on radiances is shown. Explicitly in forward direction the reflectances for heterogeneous tops are larger, in backward direction lower. The largest difference of the mean reflectances (mean over cloud field) between homogeneous and heterogeneous cloud top is approximately 0.3, which is 30% of illumination.

Description: In the course of our study of the upper tropospheric composition with the infrared Atmospheric Chemistry Experiment – Fourier Transform Spectrometer (ACE–FTS), we found an occultation sequence that on 8 October 2005, sampled a remarkable plume near the east coast of Tanzania. Model simulations of the CO distribution in the Southern hemisphere are performed for this period and they demonstrate that the emissions for this event originated from a nearby forest fire, after which the plume was transported from the source region to the upper troposphere. Taking advantage of the very high signal-to-noise ratio of the ACE–FTS spectra over a wide wavenumber range (750–4400 cm−1), we present in-depth analyses of the chemical composition of this plume in the middle and upper troposphere, focusing on the measurements of weakly absorbing pollutants. For this specific biomass burning event, we report simultaneous observations of an unprecedented number of organic species. Measurements of C2H4 (ethene), C3H4 (propyne), H2CO (formaldehyde), C3H6O (acetone) and CH3COO2NO2 (peroxyacetylnitrate, abbreviated as PAN) are the first reported detections using infrared occultation spectroscopy from satellites. Based on the lifetime of the emitted species, we discuss the photochemical age of the plume and also report, whenever possible, the enhancement ratios relative to CO.

Description: Cirrus cloud formation is believed to be domi-nated by homogeneous freezing of supercooled liquid aerosols in many instances. Heterogeneous ice nuclei such as mineral dust, metallic, and soot particles, and some crystalline solids within partially soluble aerosols are suspected to modulate cirrus properties. Among those, the role of ubiqui-tous soot particles is perhaps the least understood. Because aviation is a major source of upper tropospheric soot particles, we put emphasis on ice formation in dispersing aircraft plumes. The effect of aircraft soot on cirrus formation in the absence of contrails is highly complex and depends on a wide array of emission and environmental parameters. We use a microphysical-chemical model predicting the formation of internally mixed, soot-containing particles up to two days after emission, and suggest two principal scenarios, both assuming soot particles to be moderate ice nuclei relative to cirrus formation by homogeneous freezing in the presence of few efficient dust ice nuclei: high concentrations of original soot emissions could slightly increase the number of ice crystals; low concentrations of particles originating from coagulation of emitted soot with background aerosols could lead to a significant reduction in ice crystal number. A critical discussion of laboratory experiments reveals that the ice nucleation efficiency of soot particles depends strongly on their source, and, by inference, on atmospheric aging processes. Mass and chemistry of soluble surface coatings appear to be crucial factors. Immersed soot particles tend to be poor ice nuclei, some bare ones nucleate ice at low supersaturations. However, a fundamental understanding of these studies is lacking, rendering extrapolations to atmospheric conditions speculative. In particular, we cannot yet decide which indirect aircraft effect scenario is more plausible, and options suggested to mitigate the problem remain uncertain.

Description: Transport and scavenging of chemical constituents in deep convection is important to understanding the composition of the troposphere and therefore chemistry-climate and air quality issues. High resolution cloud chemistry models have been shown to represent convective processing of trace gases quite well. To improve the representation of sub-grid convective transport and wet deposition in large-scale models, general characteristics, such as species mass flux, from the high resolution cloud chemistry models can be used. However, it is important to understand how these models behave when simulating the same storm. The intercomparison described here examines transport of six species. CO and O3, which are primarily transported, show good agreement among models and compare well with observations. Models that included lightning production of NOx reasonably predict NOx mixing ratios in the anvil compared with observations, but the NOx variability is much larger than that seen for CO and O3. Predicted anvil mixing ratios of the soluble species, HNO3, H2O2, and CH2O, exhibit significant differences among models, attributed to different schemes in these models of cloud processing including the role of the ice phase, the impact of cloud-modified photolysis rates on the chemistry, and the representation of the species chemical reactivity. The lack of measurements of these species in the convective outflow region does not allow us to evaluate the model results with observations.

Description: Within the project EUropean Studies on Trace gases and Atmospheric CHemistry as a contribution to Large-scale Biosphere–atmosphere experiment in Amazonia (LBA-EUSTACH), we performed tower-based eddy covariance measurements of O3 flux above an Amazonian primary rain forest at the end of the wet and dry seasons. Ozone deposition revealed distinct seasonal differences in the magnitude and diel variation. In the wet season, the rain forest was an effective O3 sink with a mean daytime (midday) maximum deposition velocity of 2.3 cm s−1, and a corresponding O3 flux of –11 nmol m−2 s−1. At the end of the dry season, the ozone mixing ratio was about four times higher (up to maximum values of 80 ppb) than in the wet season, as a consequence of strong regional biomass burning activity. However, the typical maximum daytime deposition flux was very similar to the wet season. This results from a strong limitation of daytime O3 deposition due to reduced plant stomatal aperture as a response to large values of the specific humidity deficit. As a result, the average midday deposition velocity in the dry burning season was only 0.5 cm s−1. The large diel ozone variation caused large canopy storage effects that masked the true diel variation of ozone deposition mechanisms in the measured eddy covariance flux, and for which corrections had to be made. In general, stomatal aperture was sufficient to explain the largest part of daytime ozone deposition. However, during nighttime, chemical reaction with nitrogen monoxide (NO) was found to contribute substantially to the O3 sink in the rain forest canopy. Further contributions were from non-stomatal plant uptake and other processes that could not be clearly identified. Measurements, made simultaneously on a 22 years old cattle pasture enabled the spatially and temporally direct comparison of O3 dry deposition values from this site with typical vegetation cover of deforested land in southwest Amazonia to the results from the primary rain forest. The mean ozone deposition to the pasture was found to be systematically lower than that to the forest by 30% in the wet and 18% in the dry season.

Description: The role of polar stratospheric clouds in polar ozone loss has been well documented. The CALIPSO satellite mission offers a new opportunity to characterize PSCs on spatial and temporal scales previously impossible. A PSC detection algorithm based on a single wavelength threshold approach has been developed for CALIPSO. The method appears to accurately detect PSCs of all opacities, including tenuous clouds, with a very low rate of false positives and few missed clouds. We applied the algorithm to CALIOP data acquired during the 2006 Antarctic winter season from 13 June through 31 October. The spatial and temporal distribution of CALIPSO PSC observations is illustrated with weekly maps of PSC occurrence. The evolution of the 2006 PSC season is depicted by time series of daily PSC frequency as a function of altitude. Comparisons with "virtual" solar occultation data indicate that CALIPSO provides a different view of the PSC season than attained with previous solar occultation satellites. Measurement-based time series of PSC areal coverage and vertically-integrated PSC volume are computed from the CALIOP data. The observed area covered with PSCs is significantly smaller than would be inferred from the commonly used temperature-based proxy TNAT but is similar in magnitude to that inferred from TSTS . The potential of CALIOP measurements for investigating PSC composition is illustrated using combinations of lidar backscatter and volume depolarization for two CALIPSO PSC scenes.

Description: Mineral aerosol is of interest due to its physiochemical impacts on the Earth's atmosphere. However, adsorbed organics could influence the chemical and physical properties of atmospheric mineral particles and alter their impact on the biosphere and climate. In this work, the heterogeneous uptake of a series of small organic acids on the swelling clay, Na-montmorillonite, was studied at 212 K as a function of relative humidity (RH), organic acid pressure and clay mass. A high vacuum chamber equipped with a quadrupole mass spectrometer and a transmission Fourier transform infrared spectrometer was used to detect the gas and condensed phases, respectively. Sub-monolayer coverage of organic acid on montmorillonite was observed under dry conditions and relevant organic acid pressures. However, the organic acid content increased significantly with increasing humidity. Additionally, while the initial uptake efficiency was found to be independent of organic acid pressure, it increased linearly with increasing clay mass. Thus, the small masses studied allow access to the entire surface area of the clay sample with minimal effects due to surface saturation. Results from this study show that the initial uptake efficiency for n-butyric acid on the clay increases by an order of magnitude as the RH is raised from 0% to 45% RH at 212 K while the uptake of formic, acetic and propionic acids increase only slightly at higher humidities. Additionally, the presence of organic acids was found to slightly enhance the water content of the clay above 45% RH. Our results indicate that heterogeneous uptake of organic acids on swelling clay minerals provides an important heterogeneous sink for these species and may modify the cloud forming potential of the clay particles.

Description: We developed a new emission inventory for Asia (Regional Emission inventory in ASia (REAS) Version 1.1) for the period 1980–2020. REAS is the first inventory to integrate historical, present, and future emissions in Asia on the basis of a consistent methodology. We present here emissions in 2000, historical emissions for 1980–2003, and projected emissions for 2010 and 2020 of SO2, NOx, CO, NMVOC, black carbon (BC), and organic carbon (OC) from fuel combustion and industrial sources. Total energy consumption in Asia more than doubled between 1980 and 2003, causing a rapid growth in Asian emissions, by 28% for BC, 30% for OC, 64% for CO, 108% for NMVOC, 119% for SO2, and 176% for NOx. In particular, Chinese NOx emissions showed a marked increase of 280% over 1980 levels, and growth in emissions since 2000 has been extremely high. These increases in China were mainly caused by increases in coal combustion in the power plants and industrial sectors. NMVOC emissions also rapidly increased because of growth in the use of automobiles, solvents, and paints. By contrast, BC, OC, and CO emissions in China showed decreasing trends from 1996 to 2000 because of a reduction in the use of biofuels and coal in the domestic and industry sectors. However, since 2000, Chinese emissions of these species have begun to increase. Thus, the emissions of air pollutants in Asian countries (especially China) showed large temporal variations from 1980–2003. Future emissions in 2010 and 2020 in Asian countries were projected by emission scenarios and from emissions in 2000. For China, we developed three emission scenarios: PSC (policy success case), REF (reference case), and PFC (policy failure case). In the 2020 REF scenario, Asian total emissions of SO2, NOx, and NMVOC were projected to increase substantially by 22%, 44%, and 99%, respectively, over 2000 levels. The 2020 REF scenario showed a modest increase in CO (12%), a lesser increase in BC (1%), and a slight decrease in OC (–5%) compared with 2000 levels. However, it should be noted that Asian total emissions are strongly influenced by the emission scenarios for China.

Description: The paper presents a cloud filtering method for upper tropospheric humidity (UTH) measurements at 183.31±1.00 GHz. The method uses two criteria: The difference between the brightness temperatures at 183.31±7.00 and 183.31±1.00 GHz, and a threshold for the brightness temperature at 183.31±1.00 GHz. The robustness of this cloud filter is demonstrated by a mid-latitudes winter case-study. The paper then studies different biases on UTH climatologies. Clouds are associated with high humidity, therefore the dry bias introduced by cloud filtering is discussed and compared to the wet biases introduced by the clouds radiative effect if no filtering is done. This is done by means of a case study, and by means of a stochastic cloud database with representative statistics for midlatitude conditions. The consistent result is that both cloud wet bias (0.8% RH) and cloud filtering dry bias (–2.4% RH) are modest for microwave data, where the numbers given are for the stochastic cloud dataset. This indicates that for microwave data cloud-filtered UTH and unfiltered UTH can be taken as error bounds for errors due to clouds. This is not possible for the more traditional infrared data, since the radiative effect of clouds is much stronger there. The focus of the paper is on midlatitude data, since atmospheric data to test the filter for that case were readily available. The filter is expected to be applicable also to subtropical and tropical data, but should be further validated with case studies similar to the one presented here for those cases.

Description: The simulation of convection, lightning and subsequent NOx emissions with global atmospheric chemistry models is associated with large uncertainties since these processes are heavily parameterised. Each parameterisation by itself has deficiencies while the combination substantially increases the uncertainties from the individual parameterisations. In this study several combinations of state-of-the-art convection and lightning parameterisations are used in model simulations with the global atmospheric chemistry model ECHAM5/MESSy and are evaluated against lightning observations. A wide range in the spatial and temporal variability of the simulated flash densities is found, attributed to both types of parameterisations. Some combinations perform well, whereas others are hardly applicable. In addition to resolution dependent rescaling parameters, each combination of lightning and convection schemes requires individual scaling to reproduce the observed flash frequencies. The resulting NOx profiles are inter-compared, but definite conclusions about the most realistic profiles can currently not be provided.

Description: Data from a co-located imaging Doppler interferometer and SuperDARN radar recorded since 1996 have been analysed in a consistent manner to determine daily mean winds and tides in the upper mesosphere. By comparing only days when both techniques were recording good quality data it is shown that the SuperDARN radar winds and tides correlate best with the IDI height bin 90–95 km. On timescales of one hour the winds derived from each technique correlate poorly, whereas the daily mean winds are in much better agreement suggesting that the two radars are sensitive to different parts of the gravity wave spectrum. Regression analysis reveals that the observed SuperDARN daily mean meridional wind strength is approximately 65% that recorded by the IDI while the zonal winds are of similar magnitude, in good quantitative agreement with previous studies which have shown contamination to SuperDARN-derived winds due to the significant back lobe of the radar radiation pattern. Climatologically the two techniques observe similar monthly mean winds with the SuperDARN meridional winds suppressed compared to the IDI which tends to record winds more poleward and eastward than those derived by the SuperDARN radar during the summer months, and to be slightly more equatorward during the winter. The 12-h tidal amplitude and phase in both the zonal and meridional components derived from both techniques are in excellent agreement, whereas the 24-h tides are seen much more strongly in the SuperDARN radar, especially in wintertime, with poor phase agreement. Long term comparison of the two techniques reveals a tendency for the IDI meridional winds to be more poleward during solar maximum especially during summer time; an effect which is not reproduced in the meridional winds derived from the SuperDARN radar. These results are discussed in the context of previous studies to independently determine the veracity of each technique.

Description: Subvisible cirrus (SVC) clouds are often observed within the tropical tropopause layer (TTL) and have been shown to have a significant impact on the earth radiation budget. The Costa Rica Aura Validation Experiment (CR-AVE) sponsored by the National Aeronautics and Space Administration (NASA) took place near San Jose, Costa Rica from 14 January–15 February 2006. The NASA WB-57F sampled SVC in the TTL from −75°C to −90°C with an improved set of cloud particle probes. The first digital images of ice particles in the TTL are compared with replicator images of ice particles collected in 1973 by a WB-57F in the TTL. The newer measurements reveal larger particles, on the order of 100 μm compared with

Description: Continuous ambient measurements with aerosol time-of-flight mass spectrometry (ATOFMS) were carried out in an industrial/residential section in the northern part of Mexico City as part of the Mexico City Metropolitan Area – 2006 campaign (MCMA-2006) between 7–27 March, 2006. Biomass and organic carbon (OC) particle types were found to dominate the accumulation mode both day and night. The concentrations of both organic carbon and biomass particles were roughly equal early in the morning, but biomass became the largest contributor to the accumulation mode mass from the late morning until early evening. The diurnal pattern can be attributed to aging and/or a change in meteorology. Fresh elemental carbon (EC) particles were observed during rush hour. The majority of the EC particles were mixed with nitrate, sulfate, organic carbon and potassium. Submicron particles from industrial sources in the northeast were composed of an internal mixture of Pb, Zn, EC and Cl and peaked early in the morning. A unique nitrogen-containing organic (NOC) particle type was observed, and is hypothesized to be from industrial emissions based on the temporal profile and back trajectory analysis. This study provides unique insights into the real-time changes in single particle mixing state as a function of size and time for aerosols in Mexico City. These new findings indicate that biomass burning and industrial operations make significant contributions to particles in Mexico City. These sources have received relatively little attention in previous intensive field campaigns.

Description: In this paper we present an approach for the statistical analysis of multi-model ensemble results. The models considered here are operational long-range transport and dispersion models, also used for the real-time simulation of pollutant dispersion or the accidental release of radioactive nuclides. We first introduce the theoretical basis (with its roots sinking into the Bayes theorem) and then apply this approach to the analysis of model results obtained during the ETEX-1 exercise. We recover some interesting results, supporting the heuristic approach called "median model", originally introduced in Galmarini et al. (2004a, b). This approach also provides a way to systematically reduce (and quantify) model uncertainties, thus supporting the decision-making process and/or regulatory-purpose activities in a very effective manner.

Description: Snow on the ground is a complex multiphase photochemical reactor that dramatically modifies the chemical composition of the overlying atmosphere. A quantitative description of the emissions of reactive gases by snow requires the knowledge of snow physical properties. This overview details our current understanding of how those physical properties relevant to snow photochemistry vary during snow metamorphism. Properties discussed are density, specific surface area, optical properties, thermal conductivity, permeability and gas diffusivity. Inasmuch as possible, equations to parameterize these properties as a function of climatic variables are proposed, based on field measurements, laboratory experiments and theory. The potential of remote sensing methods to obtain information on some snow physical variables such as grain size, liquid water content and snow depth are discussed. The possibilities for and difficulties of building a snow photochemistry model by adapting current snow physics models are explored. Elaborate snow physics models already exist, and including variables of particular interest to snow photochemistry such as light fluxes and specific surface area appears possible. On the other hand, understanding the nature and location of reactive molecules in snow seems to be the greatest difficulty modelers will have to face for lack of experimental data, and progress on this aspect will require the detailed study of natural snow samples.

Description: The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), on-board the European ENVIronmental SATellite (ENVISAT) launched on 1 March 2002, is a middle infrared Fourier Transform spectrometer measuring the atmospheric emission spectrum in limb sounding geometry. The instrument is capable to retrieve the vertical distribution of temperature and trace gases, aiming at the study of climate and atmospheric chemistry and dynamics, and at applications to data assimilation and weather forecasting. MIPAS operated in its standard observation mode for approximately two years, from July 2002 to March 2004, with scans performed at nominal spectral resolution of 0.025 cm−1 and covering the altitude range from the mesosphere to the upper troposphere with relatively high vertical resolution (about 3 km in the stratosphere). Only reduced spectral resolution measurements have been performed subsequently. MIPAS data were re-processed by ESA using updated versions of the Instrument Processing Facility (IPF v4.61 and v4.62) and provided a complete set of level-2 operational products (geo-located vertical profiles of temperature and volume mixing ratio of H2O,O3, HNO3, CH4, N2O and NO2) with quasi continuous and global coverage in the period of MIPAS full spectral resolution mission. In this paper, we report a detailed description of the validation of MIPAS-ENVISAT operational ozone data, that was based on the comparison between MIPAS v4.61 (and, to a lesser extent, v4.62) O3 VMR profiles and a comprehensive set of correlative data, including observations from ozone sondes,ground-based lidar, FTIR and microwave radiometers, remote-sensing and in situ instruments on-board stratospheric aircraft and balloons, concurrent satellite sensors and ozone fields assimilated by the European Center for Medium-range Weather Forecasting. A coordinated effort was carried out, using common criteria for the selection of individual validation data sets, and similar methods for the comparisons. This enabled merging the individual results from a variety of independent reference measurements of proven quality (i.e., well characterised error budget) into an overall evaluation of MIPAS O3 data quality, having both statistical strength and the widest spatial and temporal coverage. Collocated measurements from ozone sondes and ground-based lidar and microwave radiometers of the Network for Detection Atmospheric Composition Change (NDACC) were selected to carry out comparisons with time series of MIPAS O3 partial columns and to identify groups of stations and time periods with a uniform pattern of ozone differences, that were subsequently used for a vertically resolved statistical analysis. The results of the comparison are classified according to synoptic and regional systems and to altitude intervals, showing a generally good agreement within the comparison error bars in the upper and middle stratosphere. Significant differences emerge in the lower stratosphere and are only partly explained by the larger contributions of horizontal and vertical smoothing differences and of collocation errors to the total uncertainty. Further results obtained from a purely statistical analysis of the same data set from NDACC ground-based lidar stations, as well as from additional ozone soundings at middle latitudes and from NDACC ground-based FTIR measurements, confirm the validity of MIPAS O3 profiles down to the lower stratosphere, with evidence of larger discrepancies at the lowest altitudes. The validation against O3 VMR profiles using collocated observations performed by other satellite sensors (SAGE II, POAM III, ODIN-SMR, ACE-FTS, HALOE, GOME) and ECMWF assimilated ozone fields leads to consistent results, that are to a great extent compatible with those obtained from the comparison with ground-based measurements. Excellent agreement in the full vertical range of the comparison is shown with respect to collocated ozone data from stratospheric aircraft and balloon instruments, that was mostly obtained in very good spatial and temporal coincidence with MIPAS scans. This might suggest that the larger differences observed in the upper troposphere and lowermost stratosphere with respect to collocated ground-based and satellite O3 data are only partly due to a degradation of MIPAS data quality. They should be rather largely ascribed to the natural variability of these altitude regions and to other components of the comparison errors. By combining the results of this large number of validation data sets we derived a general assessment of MIPAS v4.61 and v4.62 ozone data quality. A clear indication of the validity of MIPAS O3 vertical profiles is obtained for most of the stratosphere, where the mean relative difference with the individual correlative data sets is always lower than 10%. Furthermore, these differences always fall within the combined systematic error (from 1 hPa to 50 hPa) and the standard deviation is fully consistent with the random error of the comparison (from 1 hPa to ~30–40 hPa). A degradation in the quality of the agreement is generally observed in the lower stratosphere and upper troposphere, with biases up to 25% at 100 hPa and standard deviation of the global mean differences up to three times larger than the combined random error in the range 50–100 hPa. The larger differences observed at the bottom end of MIPAS retrieved profiles can be associated, as already noticed, to the effects of stronger atmospheric gradients in the UTLS that are perceived differently by the various measurement techniques. However, further components that may degrade the results of the comparison at lower altitudes can be identified as potentially including cloud contamination, which is likely not to have been fully filtered using the current settings of the MIPAS cloud detection algorithm, and in the linear approximation of the forward model that was used for the climatological estimate of systematic error components. The latter, when affecting systematic contributions with a random variability over the spatial and temporal scales of global averages, might result in an underestimation of the random error of the comparison and add up to other error sources, such as the possible underestimates of the p and T error propagation based on the assumption of a 1 K and 2% uncertainties, respectively, on MIPAS temperature and pressure retrievals. At pressure lower than 1 hPa, only a small fraction of the selected validation data set provides correlative ozone data of adequate quality and it is difficult to derive quantitative conclusions about the performance of MIPAS O3 retrieval for the topmost layers.

Description: Optimal estimation theory is used to retrieve the absolute Na density profiles in the mesosphere/lower thermosphere from limb-scanning measurements of the Na radiance at 589 nm in the dayglow. Two years of observations (2003 and 2004), recorded by the OSIRIS spectrometer on the Odin satellite, have been analysed to yield the seasonal and latitudinal variation of the Na layer column abundance, peak height, and peak width. The layer shows little seasonal variation at low latitudes, but the winter/summer ratio increases from a factor of ~3 at mid-latitudes to ~10 in the polar regions. Comparison of the measurements made at about 06:00 and 18:00 LT shows little diurnal variation in the layer, apart from the equatorial region where, during the equinoxes, there is a two-fold increase in Na density below 94 km between morning and evening. This is most likely caused by the strong downward wind produced by the diurnal tide between ~02:00 and 10:00 LT. The dramatic removal of Na below 85 km at latitudes above 50° during summer is explained by the uptake of sodium species on the ice surfaces of polar mesospheric clouds, which were simultaneously observed by the Odin satellite.

Description: The demand for intercontinental transportation is increasing and people are requesting short travel times, which supersonic air transportation would enable. However, besides noise and sonic boom issues, which we are not referring to in this investigation, emissions from supersonic aircraft are known to alter the atmospheric composition, in particular the ozone layer, and hence affect climate significantly more than subsonic aircraft. Here, we suggest a metric to quantitatively assess different options for supersonic transport with regard to the potential destruction of the ozone layer and climate impacts. Options for fleet size, engine technology (nitrogen oxide emission level), cruising speed, range, and cruising altitude, are analyzed, based on SCENIC emissions scenarios for 2050, which underlay the requirements to be as realistic as possible in terms of e.g. economic markets and profitable market penetration. This methodology is based on a number of atmosphere-chemistry and climate models to reduce model dependencies. The model results differ significantly in terms of the response to a replacement of subsonic aircraft by supersonic aircraft. However, model differences are smaller when comparing the different options for a supersonic fleet. The base scenario, where supersonic aircraft get in service in 2015, a first fleet fully operational in 2025 and a second in 2050, lead in our simulations to a near surface temperature increase in 2050 of around 7 mK and with constant emissions afterwards to around 21 mK in 2100. The related total radiative forcing amounts to 22 mWm²in 2050, with an uncertainty between 9 and 29 mWm². A reduced supersonic cruise altitude or speed (from March 2 to Mach 1.6) reduces both, climate impact and ozone destruction, by around 40%. An increase in the range of the supersonic aircraft leads to more emissions at lower latitudes since more routes to SE Asia are taken into account, which increases ozone depletion, but reduces climate impact compared to the base case.

Description: With the global aerosol-climate model ECHAM5-HAM we investigate the potential influence of organic aerosol originating from the ocean on aerosol mass and chemical composition and the droplet concentration and size of marine clouds. We present sensitivity simulations in which the uptake of organic matter in the marine aerosol is prescribed for each aerosol mode with varying organic mass and mixing state, and with a geographical distribution and seasonality similar to the oceanic emission of dimethyl sulfide. Measurements of aerosol mass and chemical composition serve to evaluate the representativity of the model initializations. Good agreement with the measurements is obtained when organic matter is added to the Aitken, accumulation and coarse modes simultaneously. Representing marine organics in the model leads to higher cloud drop number concentrations, smaller cloud drop effective radii, and a better agreement with remote sensing measurements. The mixing state of the organics and the other aerosol matter, i.e., internal or external depending on the formation process of aerosol organics, is an important factor for this. We estimate that globally about 75 Tg C yr−1 of organic matter from marine origin enters the aerosol phase. An approximate 35% of this occurs through formation of secondary organic aerosol and 65% through emission of primary particles.

Description: Nitric acid (HNO3) is one of the key products that are operationally retrieved by the European Space Agency (ESA) from the emission spectra measured by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) onboard ENVISAT. The product version 4.61/4.62 for the observation period between July 2002 and March 2004 is validated by comparisons with a number of independent observations from ground-based stations, aircraft/balloon campaigns, and satellites. Individual HNO3 profiles of the ESA MIPAS level-2 product show good agreement with those of MIPAS-B and MIPAS-STR (the balloon and aircraft version of MIPAS, respectively), and the balloon-borne infrared spectrometers MkIV and SPIRALE, mostly matching the reference data within the combined instrument error bars. In most cases differences between the correlative measurement pairs are less than 1 ppbv (5–10%) throughout the entire altitude range up to about 38 km (~6 hPa), and below 0.5 ppbv (15–20% or more) above 30 km (~17 hPa). However, differences up to 4 ppbv compared to MkIV have been found at high latitudes in December 2002 in the presence of polar stratospheric clouds. The degree of consistency is further largely affected by the temporal and spatial coincidence, and differences of 2 ppbv may be observed between 22 and 26 km (~50 and 30 hPa) at high latitudes near the vortex boundary, due to large horizontal inhomogeneity of HNO3. Similar features are also observed in the mean differences of the MIPAS ESA HNO3 VMRs with respect to the ground-based FTIR measurements at five stations, aircraft-based SAFIRE-A and ASUR, and the balloon campaign IBEX. The mean relative differences between the MIPAS and FTIR HNO3 partial columns are within ±2%, comparable to the MIPAS systematic error of ~2%. %This should be the systematic error without spectroscopy since the ground-based data were retrieved using the same version of the HITRAN database. For the vertical profiles, the biases between the MIPAS and FTIR data are generally below 10% in the altitudes of 10 to 30 km. The MIPAS and SAFIRE chem{HNO_3} data generally match within their total error bars for the mid and high latitude flights, despite the larger atmospheric inhomogeneities that characterize the measurement scenario at higher latitudes. The MIPAS and ASUR comparison reveals generally good agreements better than 10–13% at 20–34 km. The MIPAS and IBEX measurements agree reasonably well (mean relative differences within ±15%) between 17 and 32 km. Statistical comparisons of the MIPAS profiles correlated with those of Odin/SMR, ILAS-II, and ACE-FTS generally show good consistency. The mean differences averaged over individual latitude bands or all bands are within the combined instrument errors, and generally within 1, 0.5, and 0.3 ppbv between 10 and 40 km (~260 and 4.5 hPa) for Odin/SMR, ILAS-II, and ACE-FTS, respectively. The standard deviations of the differences are between 1 to 2 ppbv. The standard deviations for the satellite comparisons and for almost all other comparisons are generally larger than the estimated measurement uncertainty. This is associated with the temporal and spatial coincidence error and the horizontal smoothing error which are not taken into account in our error budget. Both errors become large when the spatial variability of the target molecule is high.