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  • Nature Publishing Group  (363,432)
  • American Association of Petroleum Geologists (AAPG)
Collection
Publisher
Years
  • 1
    Journal cover
    Unknown
    American Association of Petroleum Geologists (AAPG) | GeoScienceWorld
    Online: 1.1917 – (GFZ only)
    Print: 34(12).1950 – 93(4).2009 (Location: A17, Kompaktmagazin, 9/7 - 10/6)
    Formerly as: The American Association of Petroleum Geologists Bulletin; Bulletin of the American Association of Petroleum Geologists; Bulletin of the Southwestern Association of Petroleum Geologists  (1917–1980)
    Publisher: American Association of Petroleum Geologists (AAPG) , GeoScienceWorld
    Print ISSN: 0016-7606 , 0149-1423
    Electronic ISSN: 1943-2674
    Topics: Geosciences
    Keywords: GeoScienceWorld ; petrology ; Erdöl ; Erdölgeologie ; Erdölgewinnung ; Erdgas ; Erdgasgeologie
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  • 2
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    Nature Publishing Group
    Online: 1.1998 –
    Publisher: Nature Publishing Group
    Print ISSN: 1018-4813
    Electronic ISSN: 1476-5438
    Topics: Biology , Medicine
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  • 3
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    American Association of Petroleum Geologists (AAPG) | GeoScienceWorld | formerly Blackwell Publishing
    Online: 4.1997 – (GFZ only)
    Publisher: American Association of Petroleum Geologists (AAPG) , GeoScienceWorld , formerly Blackwell Publishing
    Print ISSN: 1075-9565
    Electronic ISSN: 1526-0984
    Topics: Geography , Geosciences
    Keywords: GeoScienceWorld
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  • 4
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    Nature Publishing Group | PubMed Central
    Online: 1.1993 – (older than 12 months)
    Publisher: Nature Publishing Group , PubMed Central
    Print ISSN: 1018-4813
    Electronic ISSN: 1476-5438
    Topics: Biology , Medicine
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  • 5
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    Shanghai Institute of Materia Medica, Chinese Academy of Sciences | Nature Publishing Group
    Online: 1.1980 – (older than 12 months)
    Publisher: Shanghai Institute of Materia Medica, Chinese Academy of Sciences , Nature Publishing Group
    Print ISSN: 1671-4083
    Electronic ISSN: 0253-9756
    Topics: Chemistry and Pharmacology , Medicine
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  • 6
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    Nature Publishing Group | Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences
    Online: 2015 –
    Publisher: Nature Publishing Group , Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences
    Electronic ISSN: 2056-5968
    Topics: Biology , Medicine
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  • 7
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    Nature Publishing Group
    Online: 4(1).1997 –
    Publisher: Nature Publishing Group
    Print ISSN: 1350-9047
    Electronic ISSN: 1476-5403
    Topics: Biology , Medicine
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  • 8
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    Nature Publishing Group
    Online: 1.2010 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 2041-4889
    Topics: Biology , Medicine
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  • 9
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    Nature Publishing Group | Cell Death Differentiation Association
    Online: 2015 –
    Publisher: Nature Publishing Group , Cell Death Differentiation Association
    Electronic ISSN: 2058-7716
    Topics: Biology , Medicine
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  • 10
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    Nature Publishing Group | JSTOR
    Online: 1(1).1845 –
    Print: 268.1993 – 303(5).2010 (Location: A17, Kompaktmagazin, 64/5-6)
    Print: 270.1994 – 282.2000 (Location: A17, Kompaktmagazin, 64/5-6)
    Publisher: Nature Publishing Group , JSTOR
    Print ISSN: 0036-8733
    Electronic ISSN: 1946-7087
    Topics: Biology , Natural Sciences in General , Physics
    Abbreviation: Sci Am
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  • 11
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    Nature Publishing Group | ChangChun Institute of Optics, Fine Mechanics, and Physics (CIOMP)
    Online: 1.2012 –
    Publisher: Nature Publishing Group , ChangChun Institute of Optics, Fine Mechanics, and Physics (CIOMP)
    Electronic ISSN: 2047-7538
    Topics: Physics
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  • 12
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    Nature Publishing Group | Biocentury
    Online: 1.2008 – 7.2014
    Publisher: Nature Publishing Group , Biocentury
    Electronic ISSN: 1945-3477
    Topics: Natural Sciences in General
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  • 13
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    Springer Nature | Nature Publishing Group | PubMed Central
    Online: 1.2011 –
    Publisher: Springer Nature , Nature Publishing Group , PubMed Central
    Electronic ISSN: 2045-2322
    Topics: Natural Sciences in General
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  • 14
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    Shanghai Institute of Cell Biology | Nature Publishing Group
    Online: 1(1).1990 –
    Publisher: Shanghai Institute of Cell Biology , Nature Publishing Group
    Print ISSN: 1001-0602
    Electronic ISSN: 1748-7838
    Topics: Biology , Medicine
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  • 15
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    Shanghai Institute of Cell Biology | Nature Publishing Group
    Online: 1.1990 – (older than 12 months)
    Publisher: Shanghai Institute of Cell Biology , Nature Publishing Group
    Print ISSN: 1001-0602
    Electronic ISSN: 1748-7838
    Topics: Biology , Medicine
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  • 16
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    Nature Publishing Group
    Online: 22(1).1977 –
    Publisher: Nature Publishing Group
    Print ISSN: 1434-5161
    Electronic ISSN: 1435-232X
    Topics: Biology , Medicine
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  • 17
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    Nature Publishing Group
    Online: 1(1).1970 –
    Publisher: Nature Publishing Group
    Print ISSN: 0032-3896
    Electronic ISSN: 1349-0540
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 18
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    Nature Publishing Group | ISME (International Society for Microbial Ecology)
    Online: 1.2007 –
    Publisher: Nature Publishing Group , ISME (International Society for Microbial Ecology)
    Corporation: International Society for Microbial Ecology, ISME
    Print ISSN: 1751-7362
    Electronic ISSN: 1751-7370
    Topics: Biology
    Keywords: Mikrobiologie
    Parallel titles: The ISME Journal
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  • 19
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    Nanjing Agricultural University | Nature Publishing Group
    Online: 1.2014 –
    Publisher: Nanjing Agricultural University , Nature Publishing Group
    Print ISSN: 2662-6810
    Electronic ISSN: 2052-7276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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  • 20
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    Nature Publishing Group | ISME (International Society for Microbial Ecology), PubMed Central
    Online: 1.2007 – (older than 12 months)
    Publisher: Nature Publishing Group , ISME (International Society for Microbial Ecology), PubMed Central
    Corporation: International Society for Microbial Ecology, ISME
    Print ISSN: 1751-7362
    Electronic ISSN: 1751-7370
    Topics: Biology
    Keywords: Mikrobiologie
    Parallel titles: The ISME Journal
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  • 21
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    Nature Publishing Group
    Online: 22.1977 – (older than 5 years)
    Publisher: Nature Publishing Group
    Print ISSN: 1434-5161
    Electronic ISSN: 1435-232X
    Topics: Biology , Medicine
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  • 22
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    Nature Publishing Group
    Online: 4.1997 – (older than 5 years)
    Publisher: Nature Publishing Group
    Print ISSN: 0969-7128
    Electronic ISSN: 1476-5462
    Topics: Biology , Medicine
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  • 23
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    Nature Publishing Group
    Online: 1.1999 – (older than 5 years)
    Publisher: Nature Publishing Group
    Print ISSN: 1466-4879
    Electronic ISSN: 1476-5470
    Topics: Biology , Medicine
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  • 24
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    Nature Publishing Group
    Online: 1.1992 – 41.2009
    Online: 53(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1061-4036
    Electronic ISSN: 1546-1718
    Topics: Biology , Medicine
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  • 25
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    Nature Publishing Group
    Online: 229(1).1971 – 246(155).1973
    Publisher: Nature Publishing Group
    Print ISSN: 0090-0028 , 0369-4887
    Topics: Biology
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  • 26
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    Nature Publishing Group
    Online: 1998 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 1744-7933
    Topics: Natural Sciences in General
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  • 27
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    Nature Publishing Group
    Online: 229.1971 – 246.1973
    Publisher: Nature Publishing Group
    Print ISSN: 0300-8746
    Topics: Physics
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  • 28
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    Nature Publishing Group
    Online: 19(1).2021 –
    Online: 19(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1740-1526
    Electronic ISSN: 1740-1534
    Topics: Biology , Medicine
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  • 29
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    Nature Publishing Group
    Online: 22(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1471-0072
    Electronic ISSN: 1471-0080
    Topics: Biology
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  • 30
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    Nature Publishing Group
    Online: 2(1).2021 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 2662-1355
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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  • 31
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    Nature Publishing Group
    Online: 27(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1078-8956
    Electronic ISSN: 1546-170X
    Topics: Biology , Medicine
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  • 32
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    Nature Publishing Group
    Online: 1.2015 –
    Publisher: Nature Publishing Group
    Print ISSN: 2055-026X
    Electronic ISSN: 2055-0278
    Topics: Biology
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  • 33
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    Nature Publishing Group
    Online: 1.2007 – 4(5).2010
    Publisher: Nature Publishing Group
    Electronic ISSN: 1753-9315
    Topics: Geosciences
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  • 34
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    Nature Publishing Group
    Online: 2006 – 2012
    Publisher: Nature Publishing Group
    Electronic ISSN: 1756-0357
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Medicine , Natural Sciences in General , Physics
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  • 35
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    Nature Publishing Group
    Online: 16(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1754-2189
    Electronic ISSN: 1750-2799
    Topics: Natural Sciences in General
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  • 36
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    Nature Publishing Group
    Online: 1.1999 – 11.2009
    Online: 23(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1465-7392
    Electronic ISSN: 1476-4679
    Topics: Biology , Medicine
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  • 37
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    Nature Publishing Group
    Online: 18(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1548-7091
    Electronic ISSN: 1548-7105
    Topics: Biology , Medicine
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  • 38
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    Nature Publishing Group
    Online: 16(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1748-3387
    Electronic ISSN: 1748-3395
    Topics: Biology , Chemistry and Pharmacology , Physics
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  • 39
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    Nature Publishing Group
    Online: 24(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1097-6256
    Electronic ISSN: 1546-1726
    Topics: Biology , Medicine
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  • 40
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    Nature Publishing Group
    Online: 2007 – 2009
    Publisher: Nature Publishing Group
    Electronic ISSN: 1754-8705
    Topics: Biology , Medicine
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  • 41
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    Nature Publishing Group
    Online: 6(1).2021 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 2058-8437
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 42
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    Nature Publishing Group
    Online: 1(1).2009 – 1(9).2009
    Online: 13(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1755-4330
    Electronic ISSN: 1755-4349
    Topics: Chemistry and Pharmacology
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  • 43
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    Nature Publishing Group
    Online: 22(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1471-0056
    Electronic ISSN: 1471-0064
    Topics: Biology , Medicine
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  • 44
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    Nature Publishing Group
    Online: 17(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1552-4450
    Electronic ISSN: 1552-4469
    Topics: Biology , Chemistry and Pharmacology
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  • 45
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    Nature Publishing Group
    Online: 22(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1529-2908
    Electronic ISSN: 1529-2916
    Topics: Biology , Medicine
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  • 46
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    Nature Publishing Group
    Online: 22(1).2021 –
    Publisher: Nature Publishing Group
    Print ISSN: 1471-003X
    Electronic ISSN: 1471-0048
    Topics: Biology , Medicine
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  • 47
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    Nature Publishing Group
    Online: 2015 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 2056-6387
    Topics: Physics
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  • 48
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    Nature Publishing Group
    Online: 1.1994 – 16.2009
    Online: 28(1).2021 –
    Formerly as: Nature Structural Biology  (1994–2003)
    Publisher: Nature Publishing Group
    Print ISSN: 1072-8368 , 1545-9993
    Electronic ISSN: 1545-9985
    Topics: Biology , Medicine
    Acronym: NSMB
    Abbreviation: Nat Struct Mol Biol
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  • 49
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    Nature Publishing Group
    Online: 1.1983 – 27.2009
    Online: 39(1).2021 –
    Formerly as: Bio-Technology  (1983–1996)
    Publisher: Nature Publishing Group
    Print ISSN: 0733-222X , 1087-0156
    Electronic ISSN: 1546-1696
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
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  • 50
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    Nature Publishing Group
    Online: 1(1).2010 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 2041-1723
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General , Physics
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  • 51
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    Nature Publishing Group
    Online: 2015 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 2373-8065
    Topics: Physics
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  • 52
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    Nature Publishing Group
    Online: 1.2001 –
    Publisher: Nature Publishing Group
    Print ISSN: 1470-269X
    Electronic ISSN: 1473-1150
    Topics: Chemistry and Pharmacology
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  • 53
    Journal cover
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    Nature Publishing Group
    Online: 1.2001 – (older than 5 years)
    Publisher: Nature Publishing Group
    Print ISSN: 1470-269X
    Electronic ISSN: 1473-1150
    Topics: Chemistry and Pharmacology
    Parallel titles: The Pharmacogenomics Journal
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  • 54
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    Nature Publishing Group | Shanghai Institute of Ceramics of the Chinese Academy of Sciences
    Online: 2015 –
    Publisher: Nature Publishing Group , Shanghai Institute of Ceramics of the Chinese Academy of Sciences
    Electronic ISSN: 2057-3960
    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 55
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    Nature Publishing Group | Tokyo Institute of Technology
    Online: 1(1).2009 –
    Publisher: Nature Publishing Group , Tokyo Institute of Technology
    Print ISSN: 1884-4049
    Electronic ISSN: 1884-4057
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 56
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    Nature Publishing Group
    Online: 2015 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 2055-5008
    Topics: Biology
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  • 57
    Journal cover
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    Nature Publishing Group
    Online: 2015 –
    Publisher: Nature Publishing Group
    Electronic ISSN: 2056-7189
    Topics: Biology
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  • 58
    Publication Date: 2015-08-04
    Print ISSN: 0149-1423
    Electronic ISSN: 0149-1423
    Topics: Geosciences
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  • 59
    Publication Date: 2015-08-04
    Description: New biostratigraphic zonations, core descriptions, sandstone petrography, facies analysis, and seismic information are compared with published detrital and bedrock geo- and thermochronology to build a Cenozoic paleogeographic reconstruction of the Andean retroarc region of Colombia, encompassing the ancestral Central Cordillera, Middle Magdalena Valley, Eastern Cordillera, and Llanos basin. We identify uplifted sediment source areas, provenance domains, depositional environments, and thickness changes to propose a refined paleogeographic evolution of eastern Colombia. We conclude that Cenozoic evolution of the northernmost Andes includes (1) a period of contractional deformation focused in the Central Cordillera and Middle Magdalena Valley that may have started by the Late Cretaceous, although thermochronological data points to maximum shortening and exhumation during the late Paleocene; (2) a period of slower deformation rates or even tectonic quiescence during the middle Eocene; and (3) a renewed phase of contractional deformation from the late Eocene to the Pleistocene/Holocene expressed in provenance, bedrock thermochronology, and increased subsidence rates in the Llanos foreland. The sedimentary response in the Llanos foreland basin is controlled by source area proximity, exhumation and shortening rates, relationships between accommodation and sediment supply, as well as potential paleoclimate forcing. This new reconstruction changes the picture of Cenozoic basin evolution offered by previous reconstructions, providing an updated chronology of deformation, which is tied to a more precise understanding of basin evolution.
    Print ISSN: 0149-1423
    Electronic ISSN: 0149-1423
    Topics: Geosciences
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  • 60
    Publication Date: 2015-08-04
    Description: In Colombia, palynology has been widely used as a biostratigraphic tool in oil exploration over the last two decades and, as a result of these efforts, an understanding of the chronostratigraphic range of thousands of palynomorph species is now available. Furthermore, because of their relative resistance to physical and chemical degradation, palynomorphs can often survive several tectonic-erosive cycles, allowing them to be used as unique tracers of long-term sedimentological changes. In this work, we use the palynological record from wells and outcrops in the Llanos foothills and the Llanos basin of Colombia to establish the intensity of Cenozoic reworking and its relationship to the tectonic evolution of the Colombian Andes. Using this approach, we were able to discern several tectonic episodes associated with the uplift of the Eastern Cordillera. We documented three periods of either faster erosion in the hinterland or more widespread areas being eroded in the catchment areas (late Paleocene–early Eocene, early to mid Miocene and Pliocene) and two periods of tectonic quiescence (mid-Eocene and mid–late Miocene). These periods correlate well with the deposition of different elements of the petroleum systems in the Llanos basin of Colombia (seals and reservoirs).
    Print ISSN: 0149-1423
    Electronic ISSN: 0149-1423
    Topics: Geosciences
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  • 61
    Publication Date: 2015-08-04
    Description: Physical and geochemical characteristics of produced petroleum from the central region of the Llanos basin, Colombia, were analyzed to understand the petroleum charge history and alteration processes. Petroleum properties in the study area are the result of the complex charge history of the oil fields. The amount of gas in fluids is controlled by the migration distance from the late or, possibly, the current generation kitchen located beneath the foothill deformation zone. Gas influx decreases toward the foreland domain, as indicated by lower values of the gas–oil ratio and saturation pressure. The API gravity of the oil samples is mainly controlled by the intensity of biodegradation. Marine-sourced oils accumulated in shallow reservoirs of the foreland prior to the onset of Andean deformation. Those fluids were subjected to different levels of biodegradation, depending on the time they remained at reservoir temperatures lower than 80°C (176°F) and before being buried to their maximum depth. Geochemical data suggest multiple charge pulses from different source kitchens of two main types of source rocks, as well as different biodegradation levels. The proposed petroleum charge and alteration model allows prediction of the temperature history of a reservoir and the most likely physical properties of the petroleum at a specific location. The model can be used as an exploration tool to assess the risk of charge prior to drilling in unexplored areas of the basin.
    Print ISSN: 0149-1423
    Electronic ISSN: 0149-1423
    Topics: Geosciences
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  • 62
    Publication Date: 2015-08-04
    Description: The Llanos basin, located in the eastern region of Colombia, northwestern South America, is an Andean foreland basin between the Eastern Cordillera (Colombian Andes) and the Guyana Precambrian shield. The basin is the latest stage of a complex multiphase evolution that began in the Paleozoic at the latest. A Paleozoic–Pleistocene basin evolution model is presented based on a regional, two-dimensional, industry seismic data set and well-log observations for the southern part of the basin. Five tectono-stratigraphic sequences were identified: (1) lower Paleozoic depocenters preserved along inverted Neoproterozoic basement blocks; (2) an upper Paleozoic marine sequence folded and faulted in the late Paleozoic during assembly of Pangea; (3) Upper Cretaceous–Paleocene shallow marine sediments deposited in a distal foreland basin related to uplift of the Western and Central Cordilleras of Colombia, the sequence pinches out against a Paleozoic hinge or foreland bulge area; (4) an Eocene–Miocene foreland basin related to uplift of the Eastern Cordillera resulting in a wedge geometry; and (5) Pliocene–Pleistocene fluvial deltaic rocks overfilling the foreland basin. Reactivation of Paleozoic structures occurs at the top of this sequence with the development of anticlinal structures. Present-day stress fields indicate that subduction of the Nazca plate beneath South America may be responsible for reactivation of Paleozoic structures. Inversion of north–south structures with the Neoproterozoic basement is interpreted to be responsible for the Paleozoic and Pleistocene deformation, whereas Cenozoic deformation is related to the two main stages of foreland development of the basin. To the east, where the Paleoproterozoic basement is present, no deformation is interpreted.
    Print ISSN: 0149-1423
    Electronic ISSN: 0149-1423
    Topics: Geosciences
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  • 63
    Publication Date: 2015-08-04
    Description: In the present study, stratigraphic data from cores and outcrop sections are integrated with data on thermal maturity, organic facies, and thermochronometric information to reconstruct the tectonic and associated petroleum system evolution of the eastern foothills thrust belt along the Colombian Eastern Cordillera, one of the most prolific hydrocarbon provinces in northern South America. Sedimentary and tectonic burial of the foreland autochthon caused maturation of the Coniacian to Santonian shallow marine Chipaque Formation, resulting in successive and diachronous episodes of hydrocarbon migration and trapping. One-dimensional and two-dimensional maturation modeling indicates that oil generation from the Chipaque Formation began at the Paleocene-Eocene boundary (55 Ma) in the southern parts of what is now the Eastern Cordillera and progressed to the north. By the late Oligocene, tectonic inversion of the Eastern Cordillera exhumed most of these kitchens, terminating the oil generation from the Chipaque Formation. Kitchens migrated northward and eastward during the Oligocene and early Miocene. Because of the absence or subsequent erosion of traps, it is likely that the southernmost source rocks expelled most of their oil without any appreciable accumulation. Our modeling indicates that there were two important kitchens during the Cenozoic. The larger of the two was located in the present-day Eastern Cordillera, and it was most productive in the late Eocene–early Oligocene. The second kitchen, which generated oil throughout the Neogene, was located in the foredeep of the Llanos basin, adjacent to the mountain front. Considerable amounts of oil from this recent pulse have accumulated in both deep and shallow reservoirs along the eastern foothills. The modeled reservoir charge history also explains the substantial biodegradation of oils in reservoirs that are today much too deep to support the process. Biodegradation must have occurred when the reservoirs were shallower and at cooler temperatures, and they remained active until the reservoirs were buried to depths where temperatures were high enough to prevent further bacterial activity.
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  • 64
    Publication Date: 2015-08-04
    Description: In this paper, we demonstrate a workflow for constructing kinematic restorations in complex foothill areas devoid of growth strata and other indicators for the chronology of deformation. Our initial reconstructions utilize thermochronometric data, a well-documented structural geometry, and a first-order conversion of exhumation rates into tectonic rates. We then utilize models obtained from the new in-house–developed software FetKin to build a first version of the thermokinematic restoration. The FetKin approach is geared primarily toward testing and further calibration and refinement of the kinematic restoration, based on the extent to which the model result agrees with thermochronometric data from the study area in the form of both discrete ages and inverse-modeled time–temperature envelopes. This analysis also provides rates of shortening and time–temperature paths throughout the model space that can be used to make first-order predictions of when different source rocks entered the oil window. These capabilities are demonstrated in a pilot case study along a cross section in the Colombian Eastern Cordillera. The improved confidence in the reconstruction that this technique provides allows us to show increasing shortening rates in this part of the Andes during the Neogene reaching up to 5 mm/yr (0.20 in./yr) by the Pliocene, and constrain the timing of generation from the most important oil kitchens for the Eastern Cordillera-Llanos basin petroleum system. This approach, therefore, proves to be a useful method for creating high-resolution and high-fidelity kinematic restorations.
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  • 65
    Publication Date: 2015-08-04
    Description: FetKin is a C++ program for forward modeling thermochronological ages on a two-dimensional geological cross section. Modeled ages for various thermochronometers are computed from time–temperature histories that result from coupling the modeled kinematics of deformation obtained from commercial software for balanced reconstructions (2DMove) and a finite element computation of temperatures. Additional capabilities include the ability to accommodate (1) a smooth change of topological relief; (2) the influence of variation in rock physical properties; and (3) multikinetic modeling of fission-track ages and length distributions, as well as apatite and zircon (U-Th)/He and muscovite $$^{40}\mathrm{Ar}/^{39}\mathrm{Ar}$$ systems. A joint first-order analysis of the impact of erosion parameters and material properties improves age predictions and allows for a more complete analysis of observed cooling ages based on their modeled thermal histories. Thus, this paper presents a new software tool that has been developed as a basic support for the methodological approach used to build the kinematic restorations shown in this volume, which are the basic input for petroleum systems modeling and prediction in the Colombian Eastern Cordillera and Llanos foothills basin.
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  • 66
    Publication Date: 2015-08-04
    Description: Analysis of fracture systems in subsurface structures is limited by the amount and uncertainty of available data. With the aim of analyzing the distribution of fracture systems, we studied surface structures as analogs for oil fields in the fractured reservoirs of the Llanos foothills of Colombia. Here, we document the presence of four widespread fracture systems whose distribution is related to fold geometry and folding mechanism. At surface, in the Tierranegra and Silbadero anticlines, the principal fracture systems are symmetrical with respect to northeast- and northwest-trending fold axes, showing higher fracture intensities in the forelimbs of the structures. In the Guavio anticline, higher fracture intensities are located in the backlimb, with principal east–west and northwest–southeast directions. In contrast, we document northeast–southwest fractures near the hinge zones in the adjacent synclines. This distribution suggests that in the Guavio anticline, fractures respond to movement of the hanging-wall above a ramp, consistent with a fault-bend-fold model. Whereas, in the Tierranegra and Silbadero anticlines, fractures respond to limb rotation and hinge migration consistent with detachment fold models. Comparing these with subsurface structures, we identified that El Morro anticline has fracture distributions like those in the Tierranegra and Silbadero anticlines, but have higher fracture intensities. In the case of the Cusiana Structure, fracture intensities are higher in the crest but not in the limbs, and intensities differ from the ones found in the Guavio anticline, showing that these structures are not appropriate analogs. The results show how fracture distribution depends on structural position and fold evolution, and is controlled in part by folding mechanism. This suggests that models based on Holocene fold geometry cannot accurately predict the observed fracture distributions and should not be used to construct discrete fracture network models. Instead, the patterns we describe can be used as a guide for similar structures. Our work illustrates the possibility of having different fracture patterns and fracture abundances in adjacent folds in the same fold-thrust belt.
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  • 67
    Publication Date: 2015-09-25
    Description: Electromagnetic (EM) methods were used to characterize (1) the general near-surface geology and stratigraphy and (2) the initial electrical conductivity distribution at a $${\mathrm{CO}}_{2}$$ enhanced oil recovery (EOR) site to assess and monitor possible near-surface environmental impacts of a carbon sequestration experiment. The field study was conducted at Cranfield Field, an EOR site where $${\mathrm{CO}}_{2}$$ is being injected into a depleted oil and gas reservoir in the Cretaceous lower Tuscaloosa Formation in western Mississippi. The study focused on Tertiary and younger strata between the ground surface and maximum depths of approximately 200 m (656 ft) that host groundwater more than 3000 m (9843 ft) above the oil and gas reservoir and injection zone. It included an airborne geophysical survey collecting frequency-domain EM data, time-domain surface EM measurements, borehole logging with EM induction, natural gamma spectra, and water-level measurements. Different approaches of temperature drift corrections for the borehole EM data were compared; good results of consistent and accurate conductivity values were produced by combining both directions of a two-way (uphole and downhole) measurement. The airborne EM provided data over a large area with sufficient detail to give an overview for the subsequent surface and borehole surveys, the surface time-domain data gave insight into greater depths, and the borehole induction data provided the necessary details. These three EM methods complement each other in areal coverage, lateral and vertical resolution, and exploration depth. Together, they can provide a comprehensive near-surface characterization of the study area that is necessary to establish initial-state conditions that support future monitoring of potential $${\mathrm{CO}}_{2}$$ migration to the near-surface environment.
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  • 68
    Publication Date: 2015-06-02
    Description: Forced folds typically develop above the tips of propagating normal faults in rifts that contain thick, prerift salt or mudstone sequences. This structural style is associated with the deposition of wedge-shaped synrift deposits that thin and onlap toward monoclinal growth folds overlying the vertically restricted fault tips. Subtle stratigraphic traps may develop on the flanks of these folds although, because of limited seismic resolution and sparse well data, the architecture, thickness, and distribution of these early synrift reservoirs are difficult to predict. To improve our understanding of early synrift reservoir development on the flanks of forced folds, we focus on seismic-scale outcrop analogs along the Hadahid fault system, Suez rift, Egypt. Our data indicate that forced folding dominated during early rifting and that the onset of folding was diachronous along strike. Fluvial systems incised the rotating monocline limbs, leading to the formation of valley-like erosional relief along the base synrift unconformity. Reservoir-prone fluvial facies are only locally developed along the forced-fold flank, with their distribution related to the degree of sediment bypass downdip into the adjacent basin. Early synrift relief not filled by fluvial strata was backfilled by transgressive, tidally influenced, reservoir-prone facies, with carbonates being locally developed in areas of low clastic sediment supply. Further extension and fault-tip propagation led to amplification of the forced folds, and deposition of shallow marine-to-shelf parasequences that became thinner toward the growing folds. Although displaying greater strike continuity than the underlying fluvial or tidal reservoirs, shoreface sandstone reservoirs amalgamate onto the flanks of the forced folds and may be absent toward the fold crest. This seismic-scale outcrop analog helps us better understand the subseismic stratigraphic architecture and facies distributions of early synrift reservoirs on the flanks of extensional forced folds. Observations from this and other well-exposed outcrop analogs should help reduce subsurface uncertainty and risk when exploring for hitherto under-explored, subtle, early synrift stratigraphic traps.
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  • 69
    Publication Date: 2015-06-02
    Description: Clinoform surfaces control aspects of facies architecture within shallow-marine parasequences and can also act as barriers or baffles to flow where they are lined by low-permeability lithologies, such as cements or mudstones. Current reservoir modeling techniques are not well suited to capturing clinoforms, particularly if they are numerous, below seismic resolution, and/or difficult to correlate between wells. At present, there are no modeling tools available to automate the generation of multiple three-dimensional clinoform surfaces using a small number of input parameters. Consequently, clinoforms are rarely incorporated in models of shallow-marine reservoirs, even when their potential impact on fluid flow is recognized. A numerical algorithm that generates multiple clinoforms within a volume defined by two bounding surfaces, such as a delta-lobe deposit or shoreface parasequence, is developed. A geometric approach is taken to construct the shape of a clinoform, combining its height relative to the bounding surfaces with a mathematical function that describes clinoform geometry. The method is flexible, allowing the user to define the progradation direction and the parameters that control the geometry and distribution of individual clinoforms. The algorithm is validated via construction of surface-based three-dimensional reservoir models of (1) fluvial-dominated delta-lobe deposits exposed at the outcrop (Cretaceous Ferron Sandstone Member, Utah), and (2) a sparse subsurface data set from a deltaic reservoir (Jurassic Sognefjord Formation, Troll Field, Norwegian North Sea). Resulting flow simulation results demonstrate the value of including algorithm-generated clinoforms in reservoir models, because they may significantly impact hydrocarbon recovery when associated with areally extensive barriers to flow.
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  • 70
    Publication Date: 2015-06-02
    Description: Permeability contrasts associated with clinoforms have been identified as an important control on fluid flow and hydrocarbon recovery in fluvial-dominated deltaic parasequences. However, they are typically neglected in subsurface reservoir models or considered in isolation in reservoir simulation experiments because clinoforms are difficult to capture using current modeling tools. A suite of three-dimensional reservoir models constructed with a novel, stochastic, surface-based clinoform-modeling algorithm and outcrop analog data (Upper Cretaceous Ferron Sandstone Member, Utah) have been used here to quantify the impact of clinoforms on fluid flow in the context of (1) uncertainties in reservoir characterization, such as the presence of channelized fluvial sandbodies and the impact of bed-scale heterogeneity on vertical permeability, and (2) reservoir engineering decisions, including oil production rate. The proportion and distribution of barriers to flow along clinoforms exert the greatest influence on hydrocarbon recovery; equivalent models that neglect these barriers overpredict recovery by up to 35%. Continuity of channelized sandbodies that cut across clinoform tops and vertical permeability within distal delta-front facies influence sweep within clinothems bounded by barriers. Sweep efficiency is reduced when producing at higher rates over shorter periods, because oil is bypassed at the toe of each clinothem. Clinoforms are difficult to detect using production data, but our results indicate that they significantly influence hydrocarbon recovery and their impact is typically larger than that of other geologic heterogeneities regardless of reservoir engineering decisions. Clinoforms should therefore be included in models of fluvial-dominated deltaic reservoirs to accurately predict hydrocarbon recovery and drainage patterns.
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  • 71
    Publication Date: 2015-06-02
    Description: Raman spectroscopy has been used extensively in thermal maturation studies of kerogen, but has not been used to examine the maturation of organic cements in agglutinated foraminifera. Here, we use Raman spectroscopy to document the existence of carbonaceous matter and silica in recent and fossil agglutinated foraminifera, and to measure thermal alteration effects in fossil foraminifera. The distribution of carbonaceous matter through the test (shell) walls of agglutinated foraminifera suggests that this carbonaceous material is derived from primary organic cement and not from random contamination. Fossil specimens exhibit three broad stages of maturation: (1) Immature specimens are characterized by moderately strong fluorescence, broad, low intensity Raman peaks (relative to fluorescence), and a tendency for the G-band to occur at lower wave numbers. These attributes are consistent with the presence of amorphous carbonaceous matter and minor organic degradation. (2) Mature samples (oil window) exhibit high fluorescence, increased relative D- and G-band intensities, and a decreased width of the D-band. (3) Postmature samples exhibit low levels of fluorescence and high relative D- and G-band intensities, a tendency for the G-band to be located at higher wave numbers, an increase in the D:G band ratio, and an increase of the relative intensity of the silica peak. This stage is consistent with the presence of highly ordered carbonaceous matter and diagenetic quartz. These findings indicate that Raman spectroscopic analysis of fossil agglutinated foraminifera can be used as a quick and easy tool to assess thermal maturity and estimate optimal temperatures for hydrocarbon generation.
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  • 72
    Publication Date: 2015-06-02
    Description: Although numerous case studies exist to illustrate the large-scale stratigraphic architecture of salt-withdrawal minibasins, there is no clear understanding of how stratal patterns emerge as a function of the interplay between basin subsidence and sedimentation. Here we present a simple model of mass balance in minibasin sedimentation that focuses on the interaction between long-term sediment supply and basin-wide subsidence rate. The model calculates the sediment flux in three dimensions assuming a simplified basin and deposit geometry. The main model output is a cross section that captures the large-scale stratigraphic patterns. This architecture is determined by the relative movement of the stratal terminations along the basin margin: consecutive pinchout points can (1) be stationary, (2) move toward the basin edge (onlap), or (3) move toward the basin center (offlap). The direction and magnitude of this movement depend on the balance between the volume made available through subsidence, calculated only over the area of the previous deposit, and the volume needed to accommodate all the sediment that comes into the basin. Cycles of increasing-to-decreasing sediment supply result in stratigraphic sequences with an onlapping lower part and offlapping upper part. If the sediment input curve is more similar to a step function, stratigraphic sequences only consist of an onlapping sediment package, with no offlap at the top. Modeling two linked basins in which deposition takes place during ongoing subsidence shows that conventional static fill-and-spill models cannot correctly capture the age relationships between basin fills. In general, lower sediment input rates and periods of sediment bypass result in sand-poor convergent stratal patterns, and episodic but high volumetric sedimentation rates lead to well-defined onlap with an increased probability of high sand content.
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  • 73
    Publication Date: 2016-07-16
    Description: Modeling of fluid flow in naturally fractured reservoirs is often done through modeling and upscaling of discrete fracture networks (DFNs). The two-dimensional fracture geometry required for DFNs is obtained from subsurface and outcropping analog data. However, these data provide little information on subsurface fracture aperture, which is essential for quantifying porosity and permeability. Apertures are difficult to obtain from either outcropping or subsurface data and are therefore often based on fracture size or scaling relationships, but these do not consider the orientation and spatial distribution of fractures with respect to the in situ stress field. Using finite-element simulations, mechanical aperture can be modeled explicitly, but because changes in fracture geometry require renewed meshing and simulating, this approach is not easily integrated into subsurface DFN modeling workflows. We present a geometrically based method for calculating the shear-induced hydraulic aperture, that is, an aperture of up to 0.5 mm (0.02 in.) that can result from shear displacement along irregular fracture walls. The geometrically based method does not require numerical simulations, but it can instead be directly applied to DFNs using the fracture orientation and spacing distributions in combination with an estimate of the regional stress tensor and orientation. The frequency distribution of hydraulic aperture from the geometrically based method is compared with finite-element models constructed from five real fracture networks, digitized from outcropping pavements. These networks cover a wide range of possible geometries and spatial distributions. The geometrically based method predicts the average hydraulic aperture and equivalent permeability of fractured porous media with error margins of less than 5%.
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  • 74
    Publication Date: 2016-07-21
    Description: Numerical geochemical modeling was used to study the effects on pore-water composition and mineralogy from carbon dioxide (CO 2 ) injection into the Pennsylvanian Morrow B Sandstone in the Farnsworth Unit in northern Texas to evaluate its potential for long-term CO 2 sequestration. Speciation modeling showed the present Morrow B formation water to be supersaturated with respect to an assemblage of zeolite, clay, carbonate, mica, and aluminum hydroxide minerals and quartz. The principal accessory minerals in the Morrow B, feldspars and chlorite, were predicted to dissolve. A reaction-path model in which CO 2 was progressively added up to its solubility limit into the Morrow B formation water showed a decrease in pH from its initial value of 7 to approximately 4.1 to 4.2, accompanied by the precipitation of small amounts of quartz, diaspore, and witherite. As the resultant CO 2 -charged fluid reacted with more of the Morrow B mineral matrix, the model predicted a rise in pH, reaching a maximum of 5.1 to 5.2 at a water–rock ratio of 10:1. At a higher water–rock ratio of 100:1, the pH rose to only 4.6 to 4.7. Diaspore, quartz, and nontronite precipitated consistently regardless of the water–rock ratio, but the carbonate minerals siderite, witherite, dolomite, and calcite precipitated at higher pH values only. As a result, CO 2 sequestration by mineral trapping was predicted to be important only at low water–rock ratios, accounting for a maximum of 2% of the added CO 2 at the lowest water–rock ratio investigated of 10:1, which corresponds to a small porosity increase of approximately 0.14% to 0.15%.
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  • 75
    Publication Date: 2016-07-21
    Description: Substrate relief is a common characteristic of hard-bottom offshore banks and is associated with benthic biodiversity. Earlier studies revealed varying relief associated with offshore mesophotic communities. Correlations may exist between relief and benthic biodiversity, which in turn may be useful in determining drill sites. Such drill site determination requires obtaining an estimate of variability in relief on these banks and its associated geographic patterns. We performed fine-scale surveys of relief on 14 banks in the Gulf of Mexico to examine variation between them, geographic patterns, and possible processes influencing them: 28 Fathom, 29 Fathom, Alderdice, Bouma, Bright, Elvers, Geyer, Horseshoe, McGrail, Parker, Rankin, Rezak, Sidner, and Sonnier Banks. We used a multibeam sensor on a remotely operated vehicle, with resolution of approximately 0.5 m (2 ft). Average and standard deviation of relief were calculated at the transect, drop site, and bank levels of resolution. Sidner and McGrail Banks had the highest relief, and 29 Fathom and Sonnier had the lowest. Sidner Bank had relief averaging up to 11 m (36 ft) in height, whereas 29 Fathom Bank exhibited the lowest relief (range 1 to 2 m [3 to 7 ft]). Bright Bank and all others exhibited intermediate and variable relief at both the transect and drop site levels. Relief is not predictable on many banks because of high variability between drop sites. Some low-relief banks are predictable in their relief, lending themselves to predictions of benthic diversity and suitable drill sites. Relief decreased significantly as one moved northward in the study region. Relief exhibited a significant sinusoidal pattern from west to east. Banks with low relief occurred off Lake Calcasieu and Lafayette, Louisiana.
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  • 76
    Publication Date: 2016-07-16
    Description: The Lower Cretaceous presalt section in the Kwanza Basin contains an excellent petroleum system that includes "synrift" strata (Barremian) overlain by a "sag" interval (Aptian) and capped by the Loeme Salt. The upper synrift is generally limestone with widespread mollusk packstones and grainstones (coquinas) deposited in a fresh-to–moderately saline (alkaline) lake. The sag interval is characterized by carbonate platforms and silica-rich isolated buildups formed in highly evaporated, highly alkaline lakes. Shrubby (dendritic), microbially influenced boundstones and intraclast–spherulite grainstones accumulated in shallow water on platform tops. Microbial cherts were deposited as organic buildups on large, isolated structural highs basinward (west) of platforms, and they apparently formed at low temperatures in very alkaline lake water. Shrubby boundstones and microbial cherts have vuggy pores that are primary and result in high permeability. Wackestones and packstones with calcitic grains (mainly spherulites) in dolomite or argillaceous dolomite were deposited in slightly deeper, low-energy sag environments. In addition, clays (especially stevensite) precipitated out of the silica-rich, highly alkaline lake waters. During sag deposition, calcite precipitated on the shallow lake floor with morphologies that ranged from spherulites to shrubs and included a continuum of intermediate forms. Spherulites probably precipitated just below the sediment–water interface. Spherulites and shrubby calcites are commonly recrystallized. Spherulites floating in stevensite probably formed in deeper lacustrine environments. Organic-rich mudstones were deposited in even deeper lacustrine environments in synrift and sag intervals, and they are likely the source of most hydrocarbons in this system. These interpretations are supported by seismic, core, petrographic, and stable isotope data.
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  • 77
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    American Association of Petroleum Geologists (AAPG)
    Publication Date: 2016-07-16
    Description: The natural fracture system developed in the Cardium sandstone is examined in four outcropping structures that represent different stages of fold development. At the incipient stage of folding, the fracture system is dominated by large, widely spaced hybrid fractures that have very small displacements and are aligned in the regional shortening direction (type I orientation). These fractures are naturally propped open by asperities along the fracture surfaces. A lesser number of small thrust faults (type III orientation) are also developed. Extension fractures aligned parallel to the fold axis (type II orientation) begin to develop in the early stage of folding. Through the intermediate stage of folding, there is a progressive increase in the intensity of both type I and type II orientation fractures. Incremental increases in shear displacement on new or reactivated fractures create a gouge of comminuted sandstone grains along the fracture interface. As folding progresses to an advanced stage, there is major increase in the amount of shear displacement on both type I and type II orientation fractures. Many existing fractures coalesce into connected fracture zones and small faults that have shear offsets ranging from several centimeters to several meters. A breccia can result from intense fracturing in the rock within and marginal to these shear features. Slickensides on type I orientation features consistently indicate slip in a subhorizontal direction, even as bed dip increases. Multiple slickenside patterns record reactivation of these features. Type II orientation fractures and small faults consistently undergo bed-perpendicular slip. Type I and type II features both serve to stretch the Cardium sandstone beds but in different directions. Only type III features, which are a minor component of the fracture population, result in bed thickening.
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  • 78
    Publication Date: 2013-09-14
    Description: We describe the structure, microstructure, and petrophysical properties of fault rocks from two normal fault zones formed in low-porosity turbiditic arkosic sandstones, in deep diagenesis conditions similar to those of deeply buried reservoirs. These fault rocks are characterized by a foliated fabric and quartz-calcite sealed veins, which formation resulted from the combination of the (1) pressure solution of quartz, (2) intense fracturing sealed by quartz and calcite cements, and (3) neoformation of synkinematic white micas derived from the alteration of feldspars and chlorite. Fluid inclusion microthermometry in quartz and calcite cements demonstrates fault activity at temperatures of 195°C to 268°C. Permeability measurements on plugs oriented parallel with the principal axes of the finite strain ellipsoid show that the Y axis (parallel with the foliation and veins) is the direction of highest permeability in the foliated sandstone (10 •2 md for Y against 10 •3 md for X, Z, and the protolith, measured at a confining pressure of 20 bars). Microstructural observations document the localization of the preferential fluid path between the phyllosilicate particles forming the foliation. Hence, the direction of highest permeability in these fault rocks would be parallel with the fault and subhorizontal, that is, perpendicular to the slickenlines representing the local slip direction on the fault surface. We suggest that a similar relationship between kinematic markers and fault rock permeability anisotropy may be found in other fault zone types (reverse or strike-slip) affecting feldspar-rich lithologies in deep diagenesis conditions.
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  • 79
    Publication Date: 2013-09-14
    Description: This work discusses concepts related to the occurrence of salt along weakness planes, such as faults and fractures, which resemble igneous intrusions and may result in peculiar seismic features. We suggest that mechanisms for the formation of these structures basically involve the creation of extensional faults (commonly associated with crestal collapse grabens), which are rotated and migrated to structural flanks by domation, creating interesting seismic features here referred to as halokinetic rotating faults. At the time of their formation, some of these faults may be incipiently intruded by salt as a way of relieving sporadic intense internal overpressure episodes in the salt body, by regional compression, and/or by buoyancy effects compensating the density difference between salt and surrounding sediments. The relatively low overburden pressure at the crest of the diapir and the original high dip angles of these fault planes favor salt intrusions near the diapir apex. The process may occur in several cycles along the salt dome evolution, creating several generations of salt apophyses positioned in the diapir apex and flanks, resulting in different dips and areas of extension. These intrusions sometimes resemble the branches of Christmas tree structures, which are commonly formed by extrusive mechanisms. Although well and seismic data point to the occurrence of salt along fault planes, we recognize that salt is not a low-viscosity fluid, and the mechanisms to allow its penetration along fault planes remain unknown. Some of the possible mechanisms, which are commonly associated with a later phase of regional compression, are discussed in this work. The implications for petroleum exploration may have been overlooked in the recent exploration campaigns in the deep-water regions of the Brazilian margin. Halokinetic rotating faults, when partially filled with salt, are sometimes responsible for common pitfalls observed in seismic and well data interpretation. When fault planes present subhorizontal dips and high reflectivity, caused by the presence of salt, they have been mistakenly interpreted as flatspots, a well-known seismic hydrocarbon indicator. When drilled and proved to correspond to thin evaporite intervals in well data, these salt apophyses have also been misinterpreted as younger localized evaporitic events overlying the main salt body.
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  • 80
    Publication Date: 2013-09-20
    Description: The Cretaceous rocks of Florida have been recognized as potentially suitable reservoirs for geologic carbon dioxide (CO 2 ) sequestration. Specifically, the upper member of the Upper Cretaceous Lawson Formation, together with the lower part of the Paleocene Cedar Keys Formation, is presented here as a potential composite CO 2 storage reservoir that is mainly composed of porous dolostone sealed by thick anhydrites of the overlying middle Cedar Keys Formation. Many of the porous intervals within the Cedar Keys-Lawson storage reservoir display lateral continuity and have an average porosity range of 20%–30%. The estimated CO 2 storage capacity for the reservoir is approximately 97 billion t of CO 2 , which means the Lawson and Cedar Keys Formations composite reservoir could potentially support CO 2 sequestration for hundreds of large-scale power plants in the southeastern United States for their entire 40-yr lifespan. Because most of the previous research on the Lawson Formation is concentrated in north-central and northeastern Florida and southern Georgia, this study further characterizes the formation and its CO 2 sequestration potential in south-central and southern Florida.
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  • 81
    Publication Date: 2013-09-20
    Description: Geochemical reactions that may occur on CO 2 injection into a sandstone formation in Missouri (MO) were investigated by means of geochemical modeling. Five possible injection sites were considered: two in the northwestern part of the state, two in the northeastearn part, and one in the southwestern part. The Geochemist Workbench software was used to investigate solubility trapping and mineral precipitation. Modeling was performed for two periods: an injection period of 10 yr and a postinjection period where the reactions proceeded to equilibrium. The work presented substantial challenges. Among them are uncertainty in kinetic constants for the dissolution and precipitation of minerals on CO 2 injection. Model results include equilibrium values for CO 2 stored via solubility trapping ranging from 49-g CO 2 /kg free formation water in Northeast MO to 78-g CO 2 /kg free formation water for Southwest MO. Mineral trapping is significantly lower, between 2.6- and 18.4-g CO 2 /kg free formation water. The model shows siderite and dawsonite as the major carbonate minerals formed, in this order. On a volumetric basis, northwest MO sequestration values were slightly greater than those obtained for northeast MO because of the somewhat greater depth and higher injection pressure at the injection target (Lamotte Sandstone) at the northwestern sites. However, the greater thickness of the aquifer for the northeastern sites provided overall greater sequestration capacity. Greene County was altogether unfit for sequestration because of the low total dissolved solids value of the formation water.
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  • 82
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    American Association of Petroleum Geologists (AAPG)
    Publication Date: 2013-10-04
    Description: We present a new hypothesis for the Jurassic plate-tectonic evolution of the Gulf of Mexico basin and discuss how this evolution influenced Jurassic salt tectonics. Four interpretations, some based on new data, constrain the hypothesis. First, the limit of normal oceanic crust coincides with a landward-dipping basement ramp near the seaward end of the salt basin, which has been mapped on seismic data. Second, the deep salt in the deep-water Gulf of Mexico can be separated into provinces on the basis of position with respect to this ramp. Third, paleodepths in the postsalt sequence indicate that salt filled the Gulf of Mexico salt basin to near sea level. Fourth, seismic data show that postsalt sediments in the central Louann and the Yucatan salt basins exhibit large magnitudes of Late Jurassic salt-detached extension not balanced by equivalent salt-detached shortening. In our hypothesis, Callovian salt was deposited in preexisting crustal depressions on hyperextended continental and transitional crust. After salt deposition ended, rifting continued for another 7 to 12 m.y. before sea-floor spreading began. During this phase of postsalt crustal stretching, the salt and its overburden were extended by 100 to 250 km (62–155 mi), depending on location. Sea-floor spreading divided the northern Gulf of Mexico into two segments, separated by the northwest-trending Brazos transform. The eastern segment opened from east to west, leaving the Walker Ridge salient in the center of the basin as the final area to break apart. In some areas, salt flowed seaward onto new oceanic crust, first concordantly over the basement as a parautochthonous province, then climbing up over stratigraphically younger strata as an allochthonous province.
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  • 83
    Publication Date: 2013-10-04
    Description: Three aspects of basement structure and rift-related salt distribution have especially influenced the evolution of the deep-water northern Gulf of Mexico: (1) creation of a basement high (Toledo Bend flexure), separating a chain of interior basins from the central Louann salt basin, (2) segmentation of the central Louann salt basin by the Brazos transfer fault into eastern and central domains, and (3) salt provinces formed during basin opening. The Toledo Bend flexure was reactivated as a hinge during the Cenozoic uplift of the North American craton. This uplift triggered gravity gliding, forming fold belts in the seaward parts of the continental margin. The geometry of the Toledo Bend flexure influenced the position of these fold belts. The Brazos transfer fault separates the west sector of the study area from the central and east sectors. Most of the salt in the deep-water northern Gulf of Mexico lay in the central sector, which sourced most of the Sigsbee salt canopy. The western sector was narrower and was subdivided by the East Breaks basement high. Splitting the Callovian salt basin in two as the gulf opened created a southward-thinning wedge of salt at the seaward end of the northern Gulf of Mexico. We divide this wedge into a series of provinces on the basis of the geometry of the base of the deep salt. Original salt thickness influenced diapir location, the geometry of the Sigsbee canopy, the geometry and style of later compressional fold belts, and petroleum systems.
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  • 84
    Publication Date: 2013-10-04
    Description: Recent ultradeep exploration in the northern Gulf of Mexico has revealed a broad diffuse zone of salt-cored folding beneath the present continental shelf. This zone is a pillow fold belt, where salt pillows grew halokinetically and were then mildly shortened. Below the Louisiana shelf, a contractional early-to-late Miocene pillow fold belt is separated by a partly welded canopy from an overlying early Miocene–to–Pliocene extensional system. This anomalous juxtaposition raises two paradoxes: (1) Why was mid-Miocene shortening close to the Miocene shelf break, where extension is expected? and (2) Why did shortening below the canopy overlap in time with extension above the canopy? Coastal uplift can explain both paradoxes. Cenozoic uplift and exhumation of the north rim of the Gulf of Mexico created the observed coastal offlap and truncation around the rim. Uplift tilted the continental margin and overpowered the influence of the paleoshelf break, causing shortening much farther updip than before uplift. Physical models confirm that this hypothesis is mechanically sound. Our other models had two stacked detachments, each pinned in different locations. Because of this, deep shortening below the canopy was coeval with shallow extension above the canopy. The deep detachment was pinned far inland, equivalent to the uplifted continental interior. Extension above this deep detachment was partly balanced by shortening far downdip to form a pillow fold belt where a network of thrusts linked the squeezed pillows. In contrast, the shallow extensional system above the canopy was pinned farther seaward, equivalent to the upper continental slope.
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  • 85
    Publication Date: 2013-10-04
    Description: The process and mechanisms of secondary hydrocarbon migration in the Tazhong uplift, Tarim Basin, were investigated based on the analysis of the regional structure and by integrating geologic, hydrodynamic, and geochemical parameters. Parameters successfully analyzed included the fluid potential, fluid properties, production outputs, and diamantane index. The results indicated that hydrocarbons migrated into the Tazhong uplift from the northern part of the Manjiaer depression through a series of injection points (IPs) during four orogenies, that is, the early Caledonian (510 Ma), the late Caledonian (439 Ma), the late Hercynian–Indosinian (290 Ma), and the Yanshanian–Himalayan (208 Ma). A total of six IPs were identified at the intersections of the northeast-trending faults and the northwest-trending flower strike faults. The hydrocarbons migrated from the IPs into traps along regional trends from northwest to southeast and from northeast to southwest. The hydrocarbon migration process and patterns determined the distribution of hydrocarbon properties and production rates in the Tazhong uplift. With increasing distance from the IPs, daily hydrocarbon production decreases, and the hydrocarbons become progressively heavier and display lower gas:oil ratios.
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  • 86
    Publication Date: 2013-10-04
    Description: Determination of turbidite event magnitude and frequency remains subjective and difficult to define. This is because turbidite sedimentation events commonly include both sand and mud, with the mud component commonly excluded from bed thickness studies because of the inability to establish a genetic link to the turbidity current. Pelagic mudrock is defined as fine-grained marine sediment derived primarily from biogenic particles, whereas hemipelagic mudrock includes both biogenic and terrigenous particles. Unfortunately, these compositional definitions do not account for differences in depositional process. Scanning electron microscopy, field emission scanning electron microscopy, and x-ray diffraction analyses of 70 samples from El Rosario Formation outcrops (Baja California, Mexico) and core from the Woodford Shale (Oklahoma) illustrate this distinction. Furthermore, these laboratory measurements are calibrated to 192 outcrop samples to provide a robust method for field identification of clay fabric and mineralogy to define turbidite sedimentation units. Pelagites show organized layering of clay platelets, few flocculates, and a lower proportion of high-density minerals. Hemipelagites have disorganized and chaotic clay fabrics characterized by visible flocculates and contain a higher proportion of denser particles. There may also be a corresponding change in clay mineralogy, for example, smectite in pelagites versus kaolinite in hemipelagites. These results indicate a settling velocity greater than shear velocity in pelagites, whereas hemipelagites record the opposite condition. Turbidity currents support and suspend denser grains, generate disorganized and chaotic clay fabrics, and provide more time for flocculation. Discrimination between pelagites and hemipelagites has important implications in the determination of turbidite event frequency and magnitude, which affects vertical connectivity and continuity of sand, deposited from multipartite turbidity currents. In addition, distinction between pelagites and hemipelagites provides a better understanding of mudrock reservoir architecture.
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  • 87
    Publication Date: 2013-10-04
    Description: The Molasse deposits of the Central Eastern Alps are partly incorporated into a fold and thrust belt that recently has come into exploration focus. The structural style and timing of deformation varies significantly alongstrike. Regional three-dimensional seismic and well data interpretation indicate three different structural segments from east to west: (1) The Sierning imbricates have a decollement close to the base of the Molasse sequence and consist of varying numbers of thrust sheets alongstrike. Early Miocene shortening of the Molasse is at least 6.2 km (3.9 mi). Overthrusting of the internal Penninic and Helvetic wedge since the Oligocene accommodated at least 25 km (15.5 mi) of additional shortening. (2) The Regau segment is dominated by one to two small thrust sheets above a shallow detachment. This segment is dominated by overthrusting of the Alpine wedge. (3) The Perwang imbricates consist of an Oligocene wedge with complex deformed thrust sheets above a detachment horizon in Upper Cretaceous marls. Minimum shortening in the imbricates is 18.5 km (11.5 mi) with overthrusting 33.3 km (20.7 mi). All shortening estimates have an uncertainty of approximately 20% to 35%. The laterally varying thrust-belt architecture results from predeformational conditions (e.g., sediment thickness, mechanical stratigraphy, and basement dip). In the Sierning imbricates, hydrocarbon trap definition and charge issues are exploration risks. In the Regau segment, exploration is focused on the subthrust play. The Perwang imbricates have hydrocarbon shows but no economic discoveries. Charge and seal issues are the main risks. The petroleum systems in the context of the structural evolution are not yet fully understood.
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  • 88
    Publication Date: 2013-09-14
    Description: Quartz is the principal framework mineral in clastic sediment reservoirs. In a frontier basin with sparse wells, the source of quartz in sandstones may be a predictor of the availability of medium- to coarse-grained quartz sand from plutonic sources, likely to provide good reservoirs. The Scotian Basin, offshore eastern Canada, was used to test this hypothesis because of its well-understood provenance history and geographic variability in known medium- to coarse-grained reservoir sandstones. The sources of detrital quartz in fine-grained sandstones were determined using hot-cathode cathodoluminescence (CL), supplemented by other petrographic techniques. The CL color shift for different quartz types was calibrated against the CL properties of representative source rocks in the hinterland, because generalizations in the literature do not precisely match our basin-specific observations. Grain size of sandstone exerts a strong control over quartz type, with plutonic-hypabyssal quartz and high-grade metamorphic quartz more abundant in coarse-grained sandstones and low-grade metamorphic quartz more abundant in fine-grained sandstones. Nevertheless, the analysis of fine-grained sandstones shows that plutonic-hypabyssal quartz is more abundant in fine-grained sandstones of the Sable subbasin than in those of the Abenaki subbasin. The abundance of plutonic-hypabyssal quartz correlates with the abundance of medium- to coarse-grained sandstone reservoirs in the Sable subbasin. This study suggests that, in frontier basins, the abundance of plutonic-hypabyssal quartz in fine-grained sandstones can be used as an indicator of available medium- to coarse-grained sandstone reservoir.
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  • 89
    Publication Date: 2013-09-14
    Description: The three-dimensional (3-D) geometry of fractures and fault-related dolomite is difficult to access with classical subsurface prospection tools. Therefore, we have investigated an outcrop to improve the subsurface prediction for complex dolomite bodies. This outcrop is located in the Etoile massif (southeastern France) within a fault-bend anticline. The sedimentary units are of Upper Triassic to lower Barremian age. The fold results from the Pyreneo-Provençal shortening during the Late Cretaceous to the Eocene. The anticline hosts three types of dolomite bodies: (1a) massive dolomite of middle to late Oxfordian age, (1b) syndepositional stratabound dolomite of Tithonian age, and (2) isolated dolomite bodies associated with fractures and faults. Large-scale geometries of fault-related dolomite bodies have been modeled in 3-D. The 3-D geometries of these bodies show diapir-, finger- and wall-like structures. These bodies are located close to the main thrusts, in strata of middle Oxfordian to early Barremian age and are linked to the compressive fold-bending phase during the Late Cretaceous. Fault-related dolomitization occurred because of magnesium removal from the hydraulic brecciation and the pressure solution of type 1 dolomite with overpressured fluids. These fluids flushed upward along the main thrust and laterally by following the reservoir property contrasts in the host rocks. Fault-related dolomite bodies are either spread far apart from faults in grainy limestones with good initial reservoir properties or are restricted to fault vicinity in muddy limestones with poor initial reservoir properties. The study of the structural and stratigraphic framework was essential in the understanding of the dolomitization process.
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  • 90
    Publication Date: 2013-10-04
    Description: An interpretation of geologic structure at King Sound in the Canning Basin was completed using airborne gravity gradient, magnetic, and seismic data. During the Late Devonian and Mississippian periods, the elevated part of the basement in the north was rimmed by carbonate reefs and redeposited carbonate debris, whereas in the south, siliciclastic submarine fans and turbidites were deposited along the margin of the basement in a deep-marine environment. Three principal lithologic units were identified from the vertical gravity gradient ( G DD ) in the basin: (1) the Fairfield Group carbonates of high density are interpreted to be the source of prominent positive gravity anomalies; (2) forereef debris and carbonate clastics reworked from carbonates higher up the slope or from the carbonate platform are interpreted to be the source of medium-density responses; and (3) turbidites, debris flows, and associated clastic basinal sequences of low density are interpreted to be the source of prominent negative gravity anomalies. Depth slices of G DD indicate the channelized nature of turbidite flows. In the lower section of the basin, intrasedimentary intrusives were identified from magnetic, G DD , seismic, and well data. Depth to magnetic basement calculation indicates that the surface of the Archean to Paleoproterozoic basement ranges from 3200 to 130 m (10,499–427 ft) below sea level. The northwest- and northeast-oriented south-dipping faults cut the basement and propagate upward into the sediments. A three-dimensional geologic model constructed for King Sound satisfies all known geologic constraints and is consistent with the gravity, magnetic, seismic, and well data.
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  • 91
    Publication Date: 2013-10-04
    Description: The evolution of porosity in shales with increasing maturity was examined in a suite of five New Albany Shale samples spanning a maturity range from immature (vitrinite reflectance, R o 0.35%) to postmature (R o 1.41%). Devonian to lower Mississippian New Albany Shale samples from the Illinois Basin used in this study contain marine type II kerogen having total organic carbon contents from 1.2 to 13.0 wt. %. Organic petrology, CO 2 and N 2 low-pressure adsorption, and mercury intrusion capillary pressure techniques were used to quantify pore volumes, pore sizes, and pore-size distributions. Increasing maturity of the New Albany Shale is paralleled by many changes in the characteristics of porosity. The total porosity of 9.1 vol. % in immature New Albany Shale decreases to 1.5 vol. % in the late mature sample, whereas total pore volumes decrease from 0.0365 to 0.0059 cm 3 /g in the same sequence. Reversing the trend at even higher maturity, the postmature New Albany Shale exhibits higher porosity and larger total pore volumes compared to the late mature sample. With increasing maturity, changes in total porosity and total pore volumes are accompanied by changes in pore-size distributions and relative proportions of micropores, mesopores, and macropores. Porosity-related variances are directly related to differences in the amount and character of the organic matter and mineralogical composition, but maturity exerts the dominant control upon these characteristics. We conclude that organic matter transformation due to hydrocarbon generation and migration is a pivotal cause of the observed porosity differences.
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  • 92
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    Unknown
    American Association of Petroleum Geologists (AAPG)
    Publication Date: 2013-10-04
    Description: In this case study, we used simulated seismic data from outcrops on Svalbard to analyze what seismic facies are composed of, what the dominating factors in forming the facies are, and which consequences this has for the interpretation results. Seismic facies analyses can be used to interpret environmental setting, depositional processes, and lithology. Here, we found that noise is the most important factor in forming the seismic facies. Noise is defined as all reflections that cannot be ascribed directly to the reservoir model. Effects from overburden and processing dominated, and the low-frequency content of the seismic section complicated the seismic facies analyses. The main reason for this is that the analysis relies heavily on identified internal patterns and low-angle terminations. Such patterns and terminations are easily created by the seismic method itself, by overburden effects, and by artifacts generated when processing the data. External form, strong amplitudes, and continuous reflections are robust seismic observations, whereas the internal pattern and terminations are commonly deceptive. Identification of boundaries based on predefined patterns of terminations does not work here, and uncritical use of seismic facies analysis in this interpretation case will create wrong reservoir models. Because of the size of the outcrops, the results from this analysis are relevant for reservoir-scale seismic interpretation and detailed interpretation for prospect evaluation in mature basins. For seismic interpretation at a more regional scale, it is probably less relevant.
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  • 93
    Publication Date: 2013-10-04
    Description: The Ordovician carbonate platform at the Yijianfang outcrop of the Bachu uplift region in the western Tarim Basin contains four types of genetic facies associations developed in the calciclastic slope-fan depositional system: an olistostrome zone, fan channels, lobes, and a marginal slope. The olistostrome zone is characterized by olistoliths and slump fans, whereas the fan channels and lobes are further divided into proximal and distal facies. The marginal slope deposits constitute the background sedimentation in which the calciclastic slope fans are intercalated. From proximal to distal parts of the fan channels and lobes, their scale gradually becomes smaller, and the size and sorting of grains become finer and better, respectively. Analysis of the stratigraphic framework indicates that the fans formed in the lower strata of the Upper Ordovician Lianglitage Formation in four high-frequency sequences (i.e., Pss1–Pss4). Field paleocurrent measurements indicate northeast-southwest depositional strike for the early platform margin of the Lianglitage Formation. Sediments in the calciclastic slope fans were derived from the platform margin, and evolution of the calciclastic slope fans was generally progradational from Pss1 to Pss2 and then continuously retrogradational from Pss2 to Pss4. The calciclastic slope fans in the outcrop area are not reservoir-prone rocks, but interpretation on these fans can provide useful information about potential hydrocarbon reservoirs along the platform margin. The P -wave velocity, S -wave velocity, and density variations in each genetic facies may be used to identify the subsurface calciclastic slope-fan depositional system.
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  • 94
    Publication Date: 2013-04-04
    Description: Reservoir properties of Upper Triassic–Middle Jurassic sandstones, Spitsbergen, are studied as part of a CO 2 storage pilot project in Longyearbyen. The reservoir formations show large contrasts in sandstone compositions, with unexpected low permeability despite moderate porosity values. Petrographic analyses were performed to investigate the influence and distribution of diagenesis. It is concluded that, because of various compaction, cementation, and dissolution processes, the sandstone porosity is mainly isolated molds and micropores and associated with fibrous illite and chamosite, explaining the low permeability. Diagenesis and the distribution of quartz cement is influenced by lithofacies and detrital compositions. Mineralogically immature sandstones (De Geerdalen Formation) show a homogeneous distribution of quartz cement overgrowths on quartz grains, distributed interstitial to labile grains and other cements (e.g., late calcite). The main silica source was from the dissolution of adjacent feldspar and labile grains as part of the chemical compaction. In contrast, quartz-dominated sandstones (Knorringfjellet Formation) show a heterogeneous patchy distribution of quartz cement influenced by the sedimentary bioturbation pattern, with silica sourced also from dissolution at clay-rich microstylolites. Phosphatic beds at the base and top of the formation are strongly influenced by marine eogenesis and reworking processes and associated with concentration of iron-rich authigenic minerals. The highest porosity appears in sand-supported conglomerate where moldic clay-mineral ooids contributed to reduce quartz cementation. The stratigraphic change from mineralogical immature (Triassic) to mature (uppermost Triassic–Jurassic) sandstone compositions is detected in wide areas of the Barents Shelf and has considerable implications for the distribution of sandstone reservoir properties.
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  • 95
    Publication Date: 2013-09-14
    Description: Innovative seismic forward modeling is used to illustrate the sensitivity within seismic data, and its application in the interpretation of onlap and pinch-out of terminating deep-water sandstones, two critical components in deep-water exploration and production. Sandstone quality, net-to-gross estimates, volume calculations, vertical connectivity, and stratigraphic trapping are all dependent on the sandstone extent and their seismic characteristics in these settings. However, seismic resolution is commonly insufficient to resolve the critical reservoir parameters. Seismic modeling of termination styles based on integrated outcrop and subsurface properties allows for depth- and resolution-focused predictive models to be built for improved subsurface analysis. This technique is currently underused as a method to better understand the sensitivity of seismic data to the target lithologies and their geometries. The Grès d'Annot Formation is a well-studied sand-prone deep-water system of Paleogene age, deposited in a bathymetrically complex setting. Six end-member termination styles are discussed, including three sand-prone styles—simple onlap (O s ), draping onlap (O d ), and bed thickening (O t )—and three heterolithic styles—advancing pinch-out (P a ), convergent pinch-out (P c ), and convergent thickening and pinch-out (P ct ). Local thickening close to the system margins is common in both sand-prone and heterolithic terminating strata and plays an important function in the appropriate distribution of sandstone. The outcrops are interpreted as potential (process) analogs for the complex sandstone distribution and termination patterns observed in plays like the Paleogene of the Gulf of Mexico and the Jurassic of the northern North Sea.
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  • 96
    Publication Date: 2013-09-14
    Description: Cenozoic rifted lacustrine basins in east China display three main basin types: (1) basins with steeply dipping boundary fault, whose hanging walls tilt along pivot points; (2) basins with listric boundary faults, whose hanging walls bend along flexural bending points; and (3) basins formed by earlier extensional rifting with later strike-slip movement superimposed. The sequence development is intimately linked to the tectonic movements in the area, where second-order sequences are regionally correlatable from basin to basin and relate to the large-scale tectonic movements in the region. Third-order sequences are related to local tectonic activity and are correlatable within basins, between subbasins, and sometimes, between neighboring basins. Detailed sequence-stratigraphic analysis and mapping of depositional systems demonstrate that sand-body distribution patterns are related to sequence-stratigraphic frameworks. For the three kinds of basins, the positions of pivot point zones, flexural bend zones, and strike-slip faults plus the syndepositional faults all control the distribution of depositional systems, systems tract, and sand bodies. These controlling factors can be attributed to different structural and stratigraphic features that change the accommodation. Structural elements include boundary faults, syndepositional faults, and abrupt changes in dip. Stratigraphic controls include preexisting surfaces with local channelization, paleobathymetric lows, and onlap onto clinoform slopes. The lowstand sand bodies deposited at the downdip end of these controlling factors constitute the current and future exploration targets for conventional reservoirs.
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  • 97
    Publication Date: 2013-09-14
    Description: Outcrops provide valuable information for the characterization of fracture networks. Sampling methods such as scanline sampling, window sampling, and circular scanline and window methods are available to measure fracture network characteristics in outcrops and from well cores. These methods vary in their application, the parameters they provide and, therefore, have advantages and limitations. We provide a critical review on the application of these sampling methods and apply them to evaluate two typical natural examples: (1) a large-scale satellite image from the Oman Mountains, Oman (120,000 m 2 [1,291,669 ft 2 ]), and (2) a small-scale outcrop at Craghouse Park, United Kingdom (19 m 2 [205 ft 2 ]). The differences in the results emphasize the importance to (1) systematically investigate the required minimum number of measurements for each sampling method and (2) quantify the influence of censored fractures on the estimation of fracture network parameters. Hence, a program was developed to analyze 1300 sampling areas from 9 artificial fracture networks with power-law length distributions. For the given settings, the lowest minimum number of measurements to adequately capture the statistical properties of fracture networks was found to be approximately 110 for the window sampling method, followed by the scanline sampling method with approximately 225. These numbers may serve as a guideline for the analyses of fracture populations with similar distributions. Furthermore, the window sampling method proved to be the method that is least sensitive to censoring bias. Reevaluating our natural examples with the window sampling method showed that the existing percentage of censored fractures significantly influences the accuracy of inferred fracture network parameters.
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  • 98
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    Unknown
    American Association of Petroleum Geologists (AAPG)
    Publication Date: 2013-09-14
    Description: In western Greece, the Ionian and pre-Apulian zones represent, respectively, the basin and the transitional zone (slope) to the Apulian platform. The Apulian platform constitutes the weakly deformed foreland of the external Hellenides. The pre-Apulian zone appears in the Ionian Islands and the eastern Ionian Sea, whereas the Apulian platform is exclusively found in the Ionian Sea. The Ionian zone consists of Triassic evaporites, Jurassic–upper Eocene (mostly pelagic carbonates, minor cherts, and shales), overlain by the Oligocene flysch. Organic-rich source rocks occur within Triassic evaporites and Jurassic–Cretaceous pelagic argillaceous-siliceous rocks. The pre-Apulian zone consists of Triassic to Miocene deposits, mainly mixed neritic-pelagic carbonates. Hydrocarbon source rocks include pelagic and hemipelagic deposits rich in marine organic material, although terrigenous organic matter is also found in siliciclastic layers. Apulian platform source rocks are mainly the organic-rich shales within the Triassic Burano evaporites. Western Greece contains major petroleum systems, which extend into the Ionian Sea. Ionian, pre-Apulian, and Apulian petroleum systems contribute to the probable hydrocarbon accumulations within the big offshore (Ionian Sea) anticlines. Western Greece contains important oil and gas shale reservoirs with a potential of unconventional exploration. Promising areas for hydrocarbons need systematic and detailed three-dimensional seismic data. Exploration for conventional petroleum reservoirs, through the interpretation of seismic profiles and the abundant surface geologic data, will provide the subsurface geometric characteristics of the unconventional reservoirs. Their exploitation should follow that of conventional hydrocarbons to benefit from the anticipated technological advances, eliminating environmental repercussions.
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  • 99
    Publication Date: 2015-05-05
    Description: Outcrop chalk of late Campanian age (Gulpen Formation) from Liège (Belgium) was flooded with $${\mathrm{MgCl}}_{2}$$ in a triaxial cell for 516 days under reservoir conditions to understand how the non-equilibrium nature of the fluids altered the chalks. The study is motivated by enhanced oil recovery (EOR) processes because dissolution and precipitation change the way in which oils are trapped in chalk reservoirs. Relative to initial composition, the first centimeter of the flooded chalk sample shows an increase in MgO by approximately 100, from a weight percent of 0.33% to 33.03% and a corresponding depletion of CaO by more than 70% from 52.22 to 14.43 wt.%. Except for Sr, other major or trace elements do not show a significant change in concentration. Magnesite was identified as the major newly grown mineral phase. At the same time, porosity was reduced by approximately 20%. The amount of $${\mathrm{Cl}}^{-}$$ in the effluent brine remained unchanged, whereas $${\mathrm{Mg}}^{2+}$$ was depleted and $${\mathrm{Ca}}^{2+}$$ enriched. The loss of $${\mathrm{Ca}}^{2+}$$ and gain in $${\mathrm{Mg}}^{2+}$$ are attributed to precipitation of new minerals and leaching the tested core by approximately 20%, respectively. Dramatic mineralogical and geochemical changes are observed with scanning electron microscopy–energy-dispersive x-ray spectroscopy, nano secondary ion mass spectrometry, x-ray diffraction, and whole-rock geochemistry techniques. The understanding of how fluids interact with rocks is important to, for example, EOR, because textural changes in the pore space affect how water will imbibe and expel oil from the rock. The mechanisms of dissolution and mineralization of fine-grained chalk can be described and quantified and, when understood, offer numerous possibilities in the engineering of carbonate reservoirs.
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  • 100
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    American Association of Petroleum Geologists (AAPG)
    Publication Date: 2015-05-05
    Description: This paper reviews the hydrocarbon-retaining properties of overpressured reservoirs and discusses the mechanisms for petroleum accumulation, preservation and loss in overpressured reservoirs, and the factors controlling hydrocarbon column heights in overpressured traps. Four types of overpressured traps (filled, underfilled, unfilled, and drained) are recognized. The diversities in petroleum-bearing properties reflect the complexities of petroleum accumulation and leakage in overpressured reservoirs. Forced top seal fracturing, frictional failure along preexisting faults, and capillary leakage are the major mechanisms for petroleum loss from overpressured reservoirs. The hydrocarbon retention capacities of overpressured traps are controlled by three groups of factors: (1) factors related to minimum horizontal stress (tectonic extension or compression, stress regimes, and basin scale and localized pressure–stress coupling); (2) factors related to the magnitudes of water-phase pressure relative to seal fracture pressure (the depth to trap crest, vertical and/or lateral overpressure transfer, mechanisms of overpressure generation); and (3) factors related to the geomechanical properties of top seals or sealing faults (the tensile strength and brittleness of the seals, the natures and structures of fault zones). Commercial petroleum accumulations may be preserved in reservoirs with pressure coefficients greater than 2.0 and pore pressure/vertical stress ratios greater than 0.9 (up to 0.97). The widely quoted assumption that the fracture pressure is 80%–90% of the overburden pressure and hydrofracturing occurs when the pore pressure reaches 85% of the overburden pressure significantly underestimates the maximum sustainable overpressures, and thus, potentially the hydrocarbon-retention capacities, especially in deeply buried traps. Lateral and/or vertical water-phase overpressure transfer from deeper successions plays an important role in the formation of unfilled and drained overpressured traps. Traps in hydrocarbon generation-induced overpressured systems have greater exploration potential than traps in disequilibrium compaction-induced overpressured systems with similar overpressure magnitude.
    Print ISSN: 0149-1423
    Electronic ISSN: 0149-1423
    Topics: Geosciences
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