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  • Solar-induced chlorophyll fluorescence  (2)
  • AVHRR  (1)
  • Humans
  • Inorganic Chemistry
  • LUNAR AND PLANETARY EXPLORATION
  • MDPI AG  (4)
  • 1
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    Confirmation of ENSO-Southern Ocean teleconnections using satellite-derived SST (2018)
    MDPI AG
    Details
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Remote Sensing 10 (2018): 331, doi:10.3390/rs10020331.
    Description: The Southern Ocean is the focus of many physical, chemical, and biological analyses due to its global importance and highly variable climate. This analysis of sea surface temperatures (SST) and global teleconnections shows that SSTs are significantly spatially correlated with both the Antarctic Oscillation and the Southern Oscillation, with spatial correlations between the indices and standardized SST anomalies approaching 1.0. Here, we report that the recent positive patterns in the Antarctic and Southern Oscillations are driving negative (cooling) trends in SST in the high latitude Southern Ocean and positive (warming) trends within the Southern Hemisphere sub-tropics and mid-latitudes. The coefficient of regression over the 35-year period analyzed implies that standardized temperatures have warmed at a rate of 0.0142 per year between 1982 and 2016 with a monthly standard error in the regression of 0.0008. Further regression calculations between the indices and SST indicate strong seasonality in response to changes in atmospheric circulation, with the strongest feedback occurring throughout the austral summer and autumn.
    Description: B.S.F. is supported by the NASA/South Carolina Space-grant Graduate Assistantship. A. Macdonald acknowledges support from NOAA Grant #NA160AR4310172.
    Keywords: Southern Ocean ; Sea surface temperature ; Teleconnections ; Antarctic Oscillation ; El Niño-Southern Oscillation ; AVHRR
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
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    Performance of solar-induced chlorophyll fluorescence in estimating water-use efficiency in a temperate forest (2018)
    MDPI AG
    Details
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Remote Sensing 10 (2018): 796, doi:10.3390/rs10050796.
    Description: Water-use efficiency (WUE) is a critical variable describing the interrelationship between carbon uptake and water loss in land ecosystems. Different WUE formulations (WUEs) including intrinsic water use efficiency (WUEi), inherent water use efficiency (IWUE), and underlying water use efficiency (uWUE) have been proposed. Based on continuous measurements of carbon and water fluxes and solar-induced chlorophyll fluorescence (SIF) at a temperate forest, we analyze the correlations between SIF emission and the different WUEs at the canopy level by using linear regression (LR) and Gaussian processes regression (GPR) models. Overall, we find that SIF emission has a good potential to estimate IWUE and uWUE, especially when a combination of different SIF bands and a GPR model is used. At an hourly time step, canopy-level SIF emission can explain as high as 65% and 61% of the variances in IWUE and uWUE. Specifically, we find that (1) a daily time step by averaging hourly values during daytime can enhance the SIF-IWUE correlations, (2) the SIF-IWUE correlations decrease when photosynthetically active radiation and air temperature exceed their optimal biological thresholds, (3) a low Leaf Area Index (LAI) has a negative effect on the SIF-IWUE correlations due to large evaporation fluxes, (4) a high LAI in summer also reduces the SIF-IWUE correlations most likely due to increasing scattering and (re)absorption of the SIF signal, and (5) the observation time during the day has a strong impact on the SIF-IWUE correlations and SIF measurements in the early morning have the lowest power to estimate IWUE due to the large evaporation of dew. This study provides a new way to evaluate the stomatal regulation of plant-gas exchange without complex parameterizations.
    Description: This research was supported by U.S. Department of Energy Office of Biological and Environmental Research Grant DE-SC0006951, National Science Foundation Grants DBI 959333 and AGS-1005663, and the University of Chicago and the MBL Lillie Research Innovation Award to Jianwu Tang. This study was also supported by the open project grant (LBKF201701) of Key Laboratory of Land Surface Pattern and Simulation, Chinese Academy of Sciences.
    Keywords: Solar-induced chlorophyll fluorescence ; Water use efficiency ; Leaf area index ; Observation time ; Regression analysis
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
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    Concerns about quadrupole ICP-MS lead isotopic data and interpretations in the environment and health fields (2018)
    MDPI AG
    Details
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in International Journal of Environmental Research and Public Health 15 (2018): 723, doi:10.3390/ijerph15040723.
    Description: There has been a massive increase in recent years of the use of lead (Pb) isotopes in attempts to better understand sources and pathways of Pb in the environment and in man or experimental animals. Unfortunately, there have been many cases where the quality of the isotopic data, especially that obtained by quadrupole inductively coupled plasma mass spectrometry (Q-ICP-MS), are questionable, resulting in questionable identification of potential sources, which, in turn, impacts study interpretation and conclusions. We present several cases where the isotopic data have compromised interpretation because of the use of only the major isotopes 208Pb/206Pb and 207Pb/206Pb, or their graphing in other combinations. We also present some examples comparing high precision data from thermal ionization (TIMS) or multi-collector plasma mass spectrometry (MC-ICP-MS) to illustrate the deficiency in the Q-ICP-MS data. In addition, we present cases where Pb isotopic ratios measured on Q-ICP-MS are virtually impossible for terrestrial samples. We also evaluate the Pb isotopic data for rat studies, which had concluded that Pb isotopic fractionation occurs between different organs and suggest that this notion of biological fractionation of Pb as an explanation for isotopic differences is not valid. Overall, the brief review of these case studies shows that Q-ICP-MS as commonly practiced is not a suitable technique for precise and accurate Pb isotopic analysis in the environment and health fields
    Keywords: Lead isotopes ; ICP-MS ; TIMS ; MC-ICP-MS ; Environment ; Humans ; Rats ; Fractionation
    Repository Name: Woods Hole Open Access Server
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  • 4
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    Comparison of phenology estimated from reflectance-based indices and solar-induced chlorophyll fluorescence (SIF) observations in a temperate forest using GPP-based phenology as the standard (2018)
    MDPI AG
    Details
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Remote Sensing 10 (2018): 932, doi:10.3390/rs10060932.
    Description: We assessed the performance of reflectance-based vegetation indices and solar-induced chlorophyll fluorescence (SIF) datasets with various spatial and temporal resolutions in monitoring the Gross Primary Production (GPP)-based phenology in a temperate deciduous forest. The reflectance-based indices include the green chromatic coordinate (GCC), field measured and satellite remotely sensed Normalized Difference Vegetation Index (NDVI); and the SIF datasets include ground-based measurement and satellite-based products. We found that, if negative impacts due to coarse spatial and temporal resolutions are effectively reduced, all these data can serve as good indicators of phenological metrics for spring. However, the autumn phenological metrics derived from all reflectance-based datasets are later than the those derived from ground-based GPP estimates (flux sites). This is because the reflectance-based observations estimate phenology by tracking physiological properties including leaf area index (LAI) and leaf chlorophyll content (Chl), which does not reflect instantaneous changes in phenophase transitions, and thus the estimated fall phenological events may be later than GPP-based phenology. In contrast, we found that SIF has a good potential to track seasonal transition of photosynthetic activities in both spring and fall seasons. The advantage of SIF in estimating the GPP-based phenology lies in its inherent link to photosynthesis activities such that SIF can respond quickly to all factors regulating phenological events. Despite uncertainties in phenological metrics estimated from current spaceborne SIF observations due to their coarse spatial and temporal resolutions, dates in middle spring and autumn—the two most important metrics—can still be reasonably estimated from satellite SIF. Our study reveals that SIF provides a better way to monitor GPP-based phenological metrics.
    Description: This research was supported by U. S. Department of Energy Office of Biological and Environmental Research Grant DE-SC0006951, National Science Foundation Grants DBI 959333 and AGS-1005663, and the University of Chicago and the MBL Lillie Research Innovation Award to Jianwu Tang and China Scholarship Council No. 201506190095 to Z. Liu. Xiaoliang Lu was also supported by the open project grant (LBKF201701) of Key Laboratory of Land Surface Pattern and Simulation, Chinese Academy of Sciences.
    Keywords: Solar-induced chlorophyll fluorescence ; Reflectance ; Phenology ; Fall phenological events
    Repository Name: Woods Hole Open Access Server
    Type: Article
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