ALBERT

Description: The difference in heating or cooling to power ratio between required demands for district networks and the proposed tri-generation system is the most challenging issue of the system configuration and design. In this work, an adjustable, novel tri-generation system driven by geothermal resources is proposed to supply the thermal energies of a specific district network depending on ambient temperature in Germany. The tri-generation system is a combination of a modified absorption refrigeration cycle and a Kalina cycle using NH3-H2O mixture as a working fluid for the whole tri-generation system. A sensitive analysis of off-design conditions is carried out to study the effect of operational parameters on the system performances prior to optimizing its performance. The simulation show that the system is able to cover required heating and cooling demands. The optimization is applied considering the maximum exergy efficiency (scenario 1) and minimum total exergy destruction rate (scenario 2). The optimization results show that the maximum mean exergy efficiency in scenario 1 is achieved as 44.67% at the expense of 14.52% increase in the total exergy destruction rate in scenario 2. The minimum mean total exergy destruction rate in scenario 2 is calculated as 2980 kW at the expense of 8.32% decrease in the exergy efficiency in scenario 1.

Description: Fluoride is a halogen found in soil and water from natural and anthropogenic sources. Foods, such as cereals, fruits, and vegetables, among others, absorb and accumulate fluoride. High intakes of this element produce toxic effects such as dental or skeletal fluorosis. Fluoride content was determined in a total of 144 samples from different food groups (cereals and derivatives, fruits, tree nuts, dry fruits, mushrooms, vegetables, and legumes) using selective fluoride ion potentiometry. The fluoride concentration stood out in almonds (3.70 ± 0.96 mg/kg), walnuts (3.53 ± 0.62 mg/kg), bread (2.54 ± 0.85 mg/kg), and rice (2.28 ± 0.93 mg/kg). Consumption of 236 g/day of bread or 263 g/day of rice represents 100% of the recommended daily intake (DRI) set at 0.6 mg/day for children aged 1–3 years. In the case of rice consumption by children of these ages, it is recommended to use bottled water for rice preparation. The consumption of the analyzed foods by teenagers and adults does not pose a health risk.

Description: The study shows an analysis of a 7-year data set measuring Ultraviolet-B (UVB) irradiance values and ultraviolet index TABLEUVI) values derived from ground-based broadband irradiance measurements, satellite-derived total ozone, and UVB solar irradiance recorded in Valladolid (Central Spain). Ultraviolet-B (UVB) solar irradiance measurements in the range (280–315 nm) carried out during the period 2013–2019 at a continental Mediterranean solar station, located in Valladolid (Spain), were analyzed. UVB data recorded using a YES UVB-1 pyranometer were used to estimate erythemal irradiance, ultraviolet erythemal irradiance (UVER), UVI, cumulative dose, and sun protection. Hourly UVER data in January (minimum values) and June (maximum values) were analyzed as an average year for the measurement station. Differences between UVI values at solar noon and the maximum daily value were minimal. It was found that on certain summer days, maximum daily UVI and SED (cumulative daily dose) could be over 12 and 60, respectively. The cumulative dose on the horizontal surface was calculated at the station for different skin types. It was observed that over 45% of the annual dose is received in summer, about 30% in spring, over 15% in autumn, and less than 10% in winter. In addition, the relationship between the maximum daily UVI and the annual accumulated dose in SEDs was studied to provide information on sun protection under low UVI conditions.

Description: Accurately forecasting how crowds of people are distributed in urban areas during daily activities is of key importance for the smart city vision and related applications. In this work we forecast the crowd density and distribution in an urban area by analyzing an aggregated mobile phone dataset. By comparing the forecasting performance of statistical and deep learning methods on the aggregated mobile data we show that each class of methods has its advantages and disadvantages depending on the forecasting scenario. However, for our time-series forecasting problem, deep learning methods are preferable when it comes to simplicity and immediacy of use, since they do not require a time-consuming model selection for each different cell. Deep learning approaches are also appropriate when aiming to reduce the maximum forecasting error. Statistical methods instead show their superiority in providing more precise forecasting results, but they require data domain knowledge and computationally expensive techniques in order to select the best parameters.

Description: In the present work, an assessment of the corrosion behavior of mild steel in the presence of an organic corrosion inhibitor loaded into hybrid composite materials is performed. Hybrid organic–inorganic nanocontainers based on cerium and titanium oxides were fabricated via a combination of radical polymerization together with the coprecipitation method and sol-gel technique. The corrosion inhibition role of these hybrid materials loaded with an inhibitor is considered. A set of characterization assays addressing morphology, composition and structural aspects of the exposed steels is illustrated, along with electrochemical evaluations. The results reveal enhanced stimuli responsive anticorrosion ability of the produced hybrid materials. Furthermore, upon corrosion, new compounds are formed onto the exposed areas of the treated metals. The conducted experiments shed light on the corrosion mechanisms for steel alloys as well as the actuation of the fabricated composite materials, paving the way for future developments in this area.

Description: The importance of a reliable blade root connection has grown due to the higher-gravity-induced edgewise loads on the blade root that resulted from the recent increased size and weight of a wind turbine rotor blade. To avoid the loosening of a bolt joint connection or even consecutive blade failures, the stress concentration factor (SCF) at the bolt thread root that is sensitive to fatigue should be understood comprehensively. In this work, two-dimensional and three-dimensional finite element (FE) analysis methods were used to determine the SCF at the bolt threads both between an insert and a M42 bolt used for a large offshore blade, and between a M42 bolt and a nut. The effect of various geometric parameters on the SCF were also investigated, which included shank diameter, nut height, nut type, and relief cone. Results showed that the decreased diameter of a M42 bolt shank diameter was the dominant design driver in reducing the stress concentration factor by 40%, from 3.94 to 2.32. The round nut type was also a recommended factor to be implemented to connect bolts and inner pitch bearing with an additional 10% SCF reduction. The relief cones applied to bolt threads and insert threads also contributed to the reduction of SCF to 2.01, a 49% reduction in total. This work not only provides guidelines by which to choose the proper geometry of the bolt and nut for a large blade, but also could be beneficial in designing bolted joint connections of segment or modular blades.

Description: Acrylic bone cement (ABC) is one of the most used materials in orthopedic surgery, mainly for the fixation of orthopedic implants to the bone. However, ABCs usually present lack of biological activity and osseointegration capacity that leads to loosening of the prosthesis. This work reports the effect of introducing graphene oxide (GO) and chitosan (CS), separately or together, in the ABC formulation on setting performance, mechanical behavior, and biological properties. Introduction of both CS and GO to the ABC decreased the maximum temperature by 21% and increased the antibacterial activity against Escherichia coli by 87%, while introduction of only CS decreased bending strength by 32%. The results of cell viability and cell adhesion tests showed in vitro biocompatibility. The in vivo response was investigated using both subdermal and bone parietal implantations in Wistar rats. Modified ABCs showed absence of immune response, as confirmed by a normal inflammatory response in Wistar rat subdermal implantation. The results of the parietal bone implantation showed that the addition of CS and GO together allowed a near total healing bone–cement interface, as observed in the micrographic analysis. The overall results support the great potential of the modified ABCs for application in orthopedic surgery mainly in those cases where osseointegration is required.

Description: The phytochemical characteristic analysis of a group of 30 haskap berry genotypes was carried out bearing in mind the concern for the consumption of food with high nutraceutical value that helps maintain good health. Phytochemical fruit composition and antioxidant activity were assessed by the Folin–Ciocalteau, spectrophotometric, DPPH (1,1-diphenyl-2-picrylhydrazyl) as well as ABTS (2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) method. Evaluation of antioxidant activity was referred to as the Trolox equivalent. The observed differences in the content of phenolics, flavonoids, vitamin C and antioxidant activity allowed us to select genotypes which, due to the high level of the analyzed compounds, are particularly recommended in everyone’s diet. In addition, the analysis of the prospects of increasing the analyzed phytochemical properties, estimated by parameters such as heritability and genetic progress, indicates the effectiveness of breeding in relation to each of the analyzed traits. The results of the presented research can be used in the implementation of future breeding programs for this valuable species.

Description: The purpose of this study was to analyze the contribution of anthropometric and strength determinants of 2000 m ergometer performance in traditional rowing. Nineteen rowers competing at national level participated in this study. Anthropometric characteristics, vertical jumps and bench pull tests were assessed to determine conditional factors, whereas the 2000 m test was used to set rowing performance. Pearson correlation coefficient, linear stepwise and allometric regression analyses were used to predict rowing performance (R2 〉 50%). Height, body mass and body muscle correlated with rowing performance in male and female rowers. Similarly, power output for squat jump and countermovement jump power correlated with performance. Finally, mean propulsive velocity, mean power and maximum power in bench pull also correlated with the test. Stepwise multiple regression analysis identified body mass (R2 = 0.69, p 〈 0.001) and mean propulsive velocity in bench pull (R2 = 0.76, p 〈 0.001) for male rowers and body muscle (R2 = 0.89, p = 0.002) and maximum power in bench pull (R2 = 0.62, p = 0.036) for female rowers as the best predictors of rowing performance. These results determine the relevance of anthropometric characteristics and, in contrast to Olympic rowing, support the greatest importance of upper body power in traditional rowing training.

Description: Self-tapping screws (STSs) can be efficiently used in various fastening solutions for timber constructions and are notoriously able to offer high stiffness and load-carrying capacity, compared to other timber-to-timber composite (TTC) joint typologies. The geometrical and mechanical characterization of TTC joints, however, is often hard and uncertain, due to a combination of various influencing parameters and mechanical aspects. Among others, the effects of friction phenomena between the system components and their reciprocal interaction under the imposed design loads can remarkably influence the final estimates on structural capacity, in the same way of possible variations in the boundary conditions. The use of Finite Element (FE) numerical models is well-known to represent a robust tool and a valid alternative to costly and time consuming experiments and allows one to further explore the selected load-bearing components at a more refined level. Based on previous research efforts, this paper presents an extended FE investigation based on full three-dimensional (3D) brick models and surface-based cohesive zone modelling (CZM) techniques. The attention is focused on the mechanical characterization of small-scale TTC specimens with inclined STSs having variable configurations, under a standard push-out (PO) setup. Based on experimental data and analytical models of literature, an extended parametric investigation is presented and correlation formulae are proposed for the analysis of maximum resistance and stiffness variations. The attention is then focused on the load-bearing role of the steel screws, as an active component of TTC joints, based on the analysis of sustained resultant force contributions. The sensitivity of PO numerical estimates to few key input parameters of technical interest, including boundaries, friction and basic damage parameters, is thus discussed in the paper.