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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (25)
  • American Geophysical Union  (23)
  • Elsevier Inc NY Journals  (2)
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  • 1
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    Intense magmatic degassing through the lake of Copahue volcano, 2013-2014 (2016)
    American Geophysical Union
    Details
    Publication Date: 2024-05-09
    Description: Here we report on the first assessment of volatile fluxes from the hyperacid crater lake hosted within the summit crater of Copahue, a very active volcano on the Argentina-Chile border. Our observations were performed using a variety of in situ and remote sensing techniques during field campaigns in March 2013, when the crater hosted an active fumarole field, and in March 2014, when an acidic volcanic lake covered the fumarole field. In the latter campaign, we found that 566 to 1373 t d−1 of SO2 were being emitted from the lake in a plume that appeared largely invisible. This, combined with our derived bulk plume composition, was converted into flux of other volcanic species (H2O ~ 10989 t d−1, CO2 ~ 638 t d−1, HCl ~ 66 t d−1, H2 ~ 3.3 t d−1, and HBr ~ 0.05 t d−1). These levels of degassing, comparable to those seen at many open-vent degassing arc volcanoes, were surprisingly high for a volcano hosting a crater lake. Copahue's unusual degassing regime was also confirmed by the chemical composition of the plume that, although issuing from a hot (65°C) lake, preserves a close-to-magmatic signature. EQ3/6 models of gas-water-rock interaction in the lake were able to match observed compositions and demonstrated that magmatic gases emitted to the atmosphere were virtually unaffected by scrubbing of soluble (S and Cl) species. Finally, the derived large H2O flux (10,988 t d−1) suggested a mechanism in which magmatic gas stripping drove enhanced lake water evaporation, a process likely common to many degassing volcanic lakes worldwide.
    Description: Published
    Description: 6071–6084
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: water/rock interaction ; volcanic lakes ; volcanic/hydrothermal gases ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Fluid Expulsion in Terrestrial Sedimentary Basins: A process providing potential analogs for giant polygons and mounds in the martian lowlands (2015)
    Elsevier Inc NY Journals
    Details
    Publication Date: 2022-02-16
    Description: On Earth, burial of fine-grained sediments in offshore passive margins (e.g., underwater fans and deltas) commonly results in fluid expulsion features including large-scale polygonal fractures, mud volcanoes, and pockmarks. Comparison of resulting offshore polygons and mud volcanoes with giant polygons and high-albedo mounds in the Chryse–Acidalia region of Mars shows the terrestrial and martian features to be similar in size, morphology, geologic context, and general co-occurrence within the same basin. These similarities suggest that the process of terrestrial fluid expulsion may provide an analog that could link the giant polygons and mounds in Chryse and Acidalia to a single process. Moreover, while the terrestrial offshore polygons and mud volcanoes commonly develop in the same basins, these features do not necessarily occur in exactly the same locations within those basins, as they are independent responses to compaction and dewatering. Thus, the fluid expulsion analog does not require that the martian giant polygons and mounds have identical distributions. This is the situation in Chryse and Acidalia where the giant polygons and mounds are extensively developed and generally have overlapping distributions, but where each set of features may occur in places without the other. This fluid expulsion analog is enhanced by the fact that giant polygons and mounds in Chryse and Acidalia cooccur in a regional sense and in a geologic setting that is consistent with a fluid expulsion model of formation. Implications of this analog may impact our view of the role of water in the depositional history of the martian lowlands.
    Description: Published
    Description: 424-432
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Mars, seepage, gas ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Mercury Degassing on Africa-Adriatic Tectonic Plate Margin (2015)
    American Geophysical Union
    Details
    Publication Date: 2021-06-25
    Description: Beside anthropogenic influences, mercury in the environment can also be of natural origin. Among geologic sources, volcanic activity has been of main interest so far. Modern estimations of global natural emissions are between 2000 and 5200 tonnes per year. However, these estimates are very uncertain, thus more detailed and systematic research on natural sources of mercury is necessary. Tectonic activity is connected to certain phenomena such as degassing of Hg and other gases from active faults, geothermal activity, volcanoes, etc., especially on tectonic plate margins. Elemental mercury concentrations in air, soil gases and fluxes, as well as its speciation, in connection to tectonic activity, were studied in different environments such are karst cave (Postojna Cave), active volcano areas (Mt. Etna, Italy), and active tectonic areas in the Mediterranean Basin on Africa-Adriatic tectonic plate margin. Postojna Cave is characterized by elevated Hg (up to 150 ng m-3) air concentrations at certain areas in vicinity of active faults; however the concentrations showed also strong seasonal variations. Mt. Etna on Sicily is the largest and most active Mediterranean volcano. Concentrations of mercury in air in the vicinity of the volcano are relatively high (between 4 and 30 ng m-3) and rise towards the summit crater (65 to 130 ng m-3). Concentrations in sulphatare and fumaroles gases on the summit of the volcano can reach very high values (even up to 60 μg m-3). The Mediterranean Basin is characterized by strong tectonic activity as a consequence of subduction of African plate under the Eurasian plate. A possible source of DGM (dissolved gaseous mercury in sea water) in deeper and bottom waters could be intensive tectonic activity of the seafloor, since higher concentrations and portions of DGM were found near the bottom at locations with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea, Ionian Sea). Distribution of different mercury species in sediment and water of the Mediterranean Sea showed that the main source of mercury is geotectonic activity and its accompanying phenomena.
    Description: Published
    Description: San Francisco
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: restricted
    Keywords: Mercury ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 4
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    Sudden deep gas eruption nearby Rome's airport of Fiumicino (2014)
    American Geophysical Union
    Details
    Publication Date: 2021-03-24
    Description: On 24 August 2013 a sudden gas eruption from the ground occurred in the Tiber river delta, nearby Rome's international airport of Fiumicino. We assessed that this gas, analogous to other minor vents in the area, is dominantly composed of deep, partially mantle-derived CO2, as in the geothermal gas of the surrounding Roman Comagmatic Province. Increased amounts of thermogenic CH4 are likely sourced from Meso-Cenozoic petroleum systems, overlying the deep magmatic fluids. We hypothesize that the intersection of NE-SW and N-S fault systems, which at regional scale controls the location of the Roman volcanic edifices, favors gas uprising through the impermeable Pliocene and deltaic Holocene covers. Pressurized gas may temporarily be stored below these covers or within shallower sandy, permeable layers. The eruption, regardless the triggering cause—natural or man-made, reveals the potential hazard of gas-charged sediments in the delta, even at distances far from the volcanic edifices.
    Description: Published
    Description: 5632–5636
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; deep CO2 ; Tiber river delta ; thermogenic CH4 ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Eruptive activity at Turrialba volcano (Costa Rica): Inferences from 3He/4He in fumarole gases and chemistry of the products ejected during 2014 and 2015 (2017)
    American Geophysical Union
    Details
    Publication Date: 2021-03-01
    Description: A new period of eruptive activity started at Turrialba volcano, Costa Rica, in 2010 after almost 150 years of quiescence. This activity has been characterized by sporadic explosions whose frequency clearly increased since October 2014. This study aimed to identify the mechanisms that triggered the resumption of this eruptive activity and characterize the evolution of the phenomena over the past 2 years. We integrate 3He/4He data available on fumarole gases collected in the summit area of Turrialba between 1999 and 2011 with new measurements made on samples collected between September 2014 and February 2016. The results of a petrological investigation of the products that erupted between October 2014 and May 2015 are also presented. We infer that the resumption of eruptive activity in 2010 was triggered by a replenishment of the plumbing system of Turrialba by a new batch of magma. This is supported by the increase in 3He/4He values observed since 2005 at the crater fumaroles and by comparable high values in September 2014, just before the onset of the new eruptive phase. The presence of a number of fresh and juvenile glassy shards in the erupted products increased between October 2014 and May 2015, suggesting the involvement of new magma with a composition similar to that erupted in 1864–1866. We conclude that the increase in 3He/4He at the summit fumaroles since October 2015 represents strong evidence of a new phase of magma replenishment, which implies that the level of activity remains high at the volcano.
    Description: Published
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Turrialba volcano ; eruptive activity ; 3He/4He ; fumarole gases ; glassy shards ; juvenile component ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
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    Real-time measurements of the concentration and isotope composition of atmospheric and volcanic CO2 at Mount Etna (Italy) (2014)
    American Geophysical Union
    Details
    Publication Date: 2020-02-24
    Description: We present unprecedented data of real-time measurements of the concentration and isotope composition of CO2 in air and in fumarole-plume gases collected in 2013 during two campaigns at Mount Etna volcano, which were made using a laser-based isotope ratio infrared spectrometer. We performed approximately 360 measurements/h, which allowed calculation of the δ13C values of volcanic CO2. The fumarole gases of Torre del Filosofo (2900mabove sea level) range from 3.24 ± 0.06‰to 3.71 ± 0.09‰, comparable to isotope ratio mass spectrometry (IRMS) measurements of discrete samples collected on the same dates. Plume gases sampled more than 1 km from the craters show a δ13C= 2.2 ± 0.4‰, in agreement with the crater fumarole gases analyzed by IRMS. Measurements performed along ~17km driving track from Catania to Mount Etna show more negative δ13C values when passing through populated centers due to anthropogenic-derived CO2 inputs (e.g., car exhaust). The reported results demonstrate that this technique may represent an important advancement for volcanic and environmental monitoring.
    Description: Published
    Description: 2382–2389
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Real-time data of CO2 content and δ13C in atmospheric/volcanic gases ; This study opens new perspective for the community for volcanic surveillance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Low temperature production and exhalation of methane from serpentinized rocks on Earth: a potential analog for methane production on Mars (2015)
    Elsevier Inc NY Journals
    Details
    Publication Date: 2020-02-24
    Description: We evaluate, based on terrestrial analogs, the potential flux, origin and isotopic signature of methane (CH4) from serpentinized or serpentinizing rocks on Mars. The Tekirova ophiolites, in Turkey, have been shown to release, either via focused vents or through diffuse microseepage, substantial amounts of CH4 which could be produced via catalyzed abiotic methanation (Sabatier reaction) at low temperatures (〈50 C). Serpentinized ultramafic rocks on Mars are likely to have necessary chemical constituents for methane production and fractures for release of gas to the atmosphere, similar to those on Earth. A simple, first-order estimation gas-advection model suggests that methane fluxes on the order of several mg m 2 d 1, similar to microseepage observed in terrestrial ophiolites, could occur in martian rocks. High temperature, hydrothermal conditions may not be necessary for abiotic CH4 synthesis on Mars: low temperature (〈50 C) methanation is possible in the presence of catalysts like ruthenium, rhodium or, more commonly, chromium minerals, which occur in terrestrial ophiolites as in martian mantle meteorites. The terrestrial analog environment of abiotic microseepage may thus explain production of methane on Mars in the ancient past or at present. The wide range of martian 12C/13C and D/H ratios and the potential secondary alteration of CH4 by abiotic oxidation, as observed on Earth, could result in large isotope variations of methane on Mars. CH4 isotopic composition alone may not allow definitive determination of biotic vs. abiotic gas origin. Using our terrestrial vs. martian analysis as guide to future Mars exploration we propose that direct methane and ethane gas detection and isotopic measurements on the ground over serpentinized/serpentinizing rocks should be considered in developing future strategies for unraveling the source and origin of methane on Mars.
    Description: Published
    Description: 276-285
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: methane, Mars, serpentinization ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    S, Cl and F degassing as an indicator of volcanic dynamics: The 2001 eruption of Mount Etna (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The recent eruption of Mount Etna (July 2001) offered the opportunity to analyze magma-derived volatiles emitted during preand syn-eruptive phases, and to verify whether their composition is affected by changes in volcanic dynamics. This paper presents the results of analyses of F, Cl and S in the volcanic plume collected by filter-packs, and interprets variations in the composition based on contrasting solubility in magmas. A Rayleigh-type degassing mechanism was used to fit the acquired data and to estimate Henryâ s solubility constant ratios in Etnean basalt. This model provided insights into the dynamics of the volcano. Abundances of sulfur and halogens in eruptive plumes may help predict the temporal evolution of an ongoing effusive eruption.
    Description: -Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 1559
    Description: partially_open
    Keywords: magmatic degassing ; acidic gases ; plume chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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    Format: 275912 bytes
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  • 9
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    Continuous monitoring of soil CO2 flux on Mt. Etna:The 2004–2005 eruption and the role of regional tectonics and volcano tectonics. (2008)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The soil CO2 flux on Mt. Etna as recorded by the ETNAGAS network (an automatic system for measuring soil CO2 flux and meteorological parameters) started to increase strongly about 5 months prior to the onset of the 2004–2005 eruption and decreased a few months before the end of the eruption. Time delays in the occurrences of anomalies in soil CO2 flux at different sites in the geochemical network constrain the relationship between soil CO2 flux distributions and the tectonic framework of Etna volcano. The anomalies observed before the 2004–2005 eruption support the intrusion of new undegassed magma into the upper feeding system of the volcano (〈20 km below sea level). Magma subsequently rose slowly in the volcano conduits, thereby triggering the onset of the 2004–2005 eruption. The time delays in the occurrences of anomalies in combination with spectral analysis indicate the importance of tectonic and volcanotectonic structures in driving the ascent of deep gases within the crust. Moreover, greatest amplitude pulsations of the low-frequency components of the CO2 flux signals were correlated with the paroxystic activities of the 2004–2005 eruption. This study confirms that CO2 flux variation is a useful indicator for volcanic activity in the surveillance of the Mt. Etna and similar basaltic volcanoes.
    Description: Dipartimento Protezione Civile Ministero degli Interni
    Description: Published
    Description: B09206
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 flux ; Continuous monitoring of soil CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    A PTFE membrane for the in situ extraction of dissolved gases in natural waters: Theory and applications (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: A new method for extracting dissolved gases in natural waters has been developed and tested, both in the laboratory and in the field. The sampling device consists of a polytetrafluroethylene (PTFE) tube (waterproof and gas permeable) sealed at one end and connected to a glass sample holder at the other end. The device is pre-evacuated and subsequently dipped in water, where the dissolved gases permeate through the PTFE tube until the pressure inside the system reaches equilibrium. A theoretical model describing the time variation in partial gas pressure inside a sampling device has been elaborated, combining the mass balance and ‘‘Solution-Diffusion Model’’ which describes the gas permeation process through a PTFE membrane). This theoretical model was used to predict the temporal evolution of the partial pressure of each gas species in the sampling device. The model was validated by numerous laboratory tests. The method was applied to the groundwater of Vulcano Island (southern Italy). The results suggest that the new sampling device could easily extract the dissolved gases from water in order to determine their chemical and isotopic composition.
    Description: - European Social Fund.
    Description: Published
    Description: Q09005
    Description: partially_open
    Keywords: dissolved gases ; helium isotope ; PTFE membrane ; Vulcano Island ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 503 bytes
    Format: 446781 bytes
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