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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases  (11)
  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (8)
  • Elsevier Ltd.  (9)
  • Blackwell Publishing Ltd  (6)
  • Chinese Geoscience Union  (2)
  • American Chemical Society (ACS)
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Publisher
Years
  • 1
    Publication Date: 2017-04-04
    Description: A global database of gas composition and methane stable isotopes of 143 terrestrial mud volcanoes from 12 countries and 60 seeps independent from mud volcanism from eight countries, was compiled and examined in order to provide the first worldwide statistics on the origin of methane seeping at the earth’s surface. Sixteen seep data were coupled with their associated subsurface reservoirs. The surface seepage data indicate that at least 76% of the mud volcanoes release thermogenic gas, with only 4% biogenic and 20% with mixed character. The average (201 data) of methane concentration and methane carbon isotope ratios (δ to the power of 13 C1) of mud volcanoes are 90% v/v and -46.4‰, respectively. The other types of seeps, which are independent from mud volcanism, have an average δ to the power of 13 C1 value that is slightly higher (-42.9‰). Gases from mud volcanoes are generally lighter (more methane, less ethane and propane) than their associated reservoir gases, suggesting a molecular fractionation during advective fluid migration. Other types of seeps, especially "dry" seeps, maintain the reservoir C1/(C2 + C3) "Bernard" ratio. Mud volcanoes behave like a "natural refinery" and the origin of gas more isotopically enriched than -50% and with C1/(C2 + C3) 〉500 should be attributed to a thermogenic source, rather than partial oxidation of biogenic gas. Some data that appear biogenic in the "Bernard diagram" can be explained by molecular fractionation of mixed gas. Consequently, the "Bernard" parameter may be misleading when applied to mud volcanoes since it does not always reflect the original gas composition. The mechanisms of the molecular advective segregation should be studied quantitatively by specific models and experiments.
    Description: Published
    Description: 333-344
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: Mud volcanoes ; Seeps ; Methane ; Isotopes ; Organic geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Between 140 and 170 m water depth, more than 100 small-scale domes and peculiar ridges were mapped a few miles offshore of south-eastern Sicily along the Malta plateau (eastern Mediterranean Sea), Swath bathymetric data along with a dense grid of side scan sonar and seismic profiles were acquired in an area extending over 100 km2. Gravity cores, water samples and video observations were also collected at selected sites. Mapped domes were found from 50 to 200 m wide and no more than 5 m high occurring on the seafloor, isolated or arranged in clusters. Ridges consisted of large tabular sub-elongated structures, elevated from 5 to 10 m from the surrounding seafloor, and had flat tops on which numerous closeset, small cones occurred, appearing in video observation as carbonate buildings strongly colonized by gorgonians. Characteristic acoustic signatures (i.e. blank areas and/or turbidity zones and enhanced reflections in seismic records), measured gas anomalies in seawater samples and detected plumes on echosounder profiles suggest that both the domes and ridges are influenced by active seeps. In addition, their spatial distribution reflected patterns of tectonic lineaments produced by the late Miocene to present-day geo-dynamic evolution of the Malta plateau, which is also an important hydrocarbon province. Results from gravity cores suggest that mud extrusion seems to be the main process responsible for the origin of the domes, which are formed by gray mud with only a few centimeters of biogenic sand at the top, indicating that recent bioclastic material is not a major contributor to mound building. However, at present, active degassing appears to be the main process that controls the morphological and sedimentological expression of both the domes and ridges. Therefore, a quiescent or intermittent active stage for mud extrusion is considered.
    Description: Published
    Description: 1831-1848
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Methane seeps ; Mud extrusion ; Seismic ; Backscattering ; Seafloor morphology ; Malta plateau ; Sicily channel ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-03
    Description: Several types of natural gas emissions (soil gas, low temperature fumaroles, gas bubbling in mud pools) were collected monthly on Mt. Etna volcano between July 2000 and July 2003 both from its summit and its flanks. Samples were analysed for the determination of the concentrations of CO2, CH4, He, H2, CO as well as the isotopic ratios of 13 14 C/ C of CO2 (δ13C) and He (R/Ra). The analysed gases were chemically divided into two groups: air-contaminated (from sites closer to the summit vents of Mt. Etna) and CO2 - rich. Among the latter, samples from the lower SW flank of the volcano showed high contents of biogenic thermogenic and/or microbial CH4. Isotopic shift in the δ13C values is caused by input of organic CO2 and/or by interaction between magmatic CO2 and shallow ground water as a function of water temperature and CO2 flux from depth. Based on a graphic method applied to δ13 TDIC C of some ground water, the inferred isotopic composition of the pristine magmatic gas at Mt. Etna is characterised by δ13C values ranging from -2 to -1 0 00 . During the period July 2000 - July 2003 significant variations were observed in many of the investigated parameters almost at all monitored sites. Seasonal influences were generally found to be negligible, with only a limited effect of air temperature changes on soil CO2 and ground temperature in only two of the air-contaminated sites. The largest chemical anomalies were observed in the air-contaminated sites, probably because of the strong buffering power of local ground water on gases released through the most peripheral areas where the CO2-rich sites are located. The anomalous changes observed during the study period can be explained in terms of progressive gas release from separate batches of magma that ascend towards the surface in a step-wise manner. Data relevant to the period following the 2002-03 eruption suggest that magma kept accumulating beneath the volcano, thus increasing the probability of a new large eruption at Mt. Etna.
    Description: Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo
    Description: Published
    Description: 805-841
    Description: open
    Keywords: Mt. Etna ; Geochemistry ; Gases ; Eruptive activity ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 67393 bytes
    Format: text/plain
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  • 4
    Publication Date: 2017-04-04
    Description: The geochemical monitoring carried out on fluids released in the Central Apennines (Umbria region) evidenced seismically-induced modifications of the physic-chemical parameters in all the released fluids, including some cold waters circulating in certain carbonate rocks that are exploited for drinking purposes. The results allowed us to recognize the presence of components of diverse origin that changed the chemical composition of the water. These components, potentially dangerous for human consumption, can be considered as being “secondary effects” on local aquifers, induced by crustal deformation. We would also stress the relationship between the circulating fluids and active tectonic structures, as we detected modifications in some springs that were apparently not located anywhere near the local faults. The temporal variations in the geochemical features of the investigated cold waters are related to the local faulting activity that occurs during seismogenesis. The geochemical monitoring that provided information on fault movements during the seismic crisis, is also able to give us information regarding faulting activity in its earlier stages.
    Description: Published
    Description: 709-729
    Description: 3.2. Tettonica attiva
    Description: N/A or not JCR
    Description: reserved
    Keywords: cold waters ; earthquakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: Bonini (2009) has recently written an interesting paper dealing with the structural setting and relationships to seismicity of a CO2(carbon dioxide)-driven mud volcano, called Pieve S. Stefano (PSS), located in the Northern Apennines of Italy.We outline here that PSS is not a mud volcano at all. The author erroneously attributes the term ‘‘mud volcano’’ (also featured in the title of the article) to a CO2-dominant gas manifestation, which should be considered as a ‘‘mofette’’ or more generally a dry CO2-vent (or ‘‘gas pool’’; Minissale et al., 2000; Heinicke et al., 2006). Our comment does not dispute Bonini’s data interpretations and conclusions (for which a first comment has already been made by Collettini, in press), but discusses why misuse of the term ‘‘mud volcano’’ may lead to misquotations in future mud volcano literature.
    Description: Published
    Description: 1270-1271
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Mud volcano ; Mofette ; Carbon dioxide ; Gas manifestation ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: The paper describes a case of a natural emission of methane from soil in an urban development area, generating a significant risk for the local population and buildings, due to gas explosiveness and asphyxiation potential. The site is located on the south-western margin of the East-European Platform in eastern Romania, in a hydrocarbon-prone area crossed by the Pericarpathian lineament and regional faults. Molecular composition of gas and stable isotopic analyses of methane (CH4〉90%, δ to the power of 13 C1: -49.4‰, δD1: -173.4‰) indicate a dominant thermogenic origin, with significant amounts of C2-C5 alkanes (~5%), likely migrating through faults from a deep reservoir. Possible candidates are the Saucesti and Secuieni gas fields, located in the same petroleum system. Two surface geochemical surveys, based on closed-chamber flux measurements, were performed to assess the degassing intensity and the extent of the affected area. Methane fluxes from soil reach orders of 10 to the power of 4 mg m to the power of -2 day to the power of -1. Gas seepage mainly occurs in one zone 30 000 m2 wide, and it is likely controlled by channeling along a fault and gas accumulation in permeable sediments and shallow subsoil. The estimated total CH4 emission is about 40 t year to the power of -1 CH4, of which 8–9 t year to the power of -1 are naturally released from soil and 30–35 t year to the power of -1 are emitted from shallow boreholes. These wells have likely channeled the gas accumulated in shallow alluvial sediment but gas flux from soil is still high and mitigation measures are needed to reduce the risk for humans and buildings.
    Description: Published
    Description: 311-320
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: gas hazard ; methane seepage ; soil degassing ; thermogenic gas ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2017-04-04
    Description: Three different methodologies were used to measure Radon (222Rn) in soil, based on both passive and active detection system. The first technique consisted of Solid State Nuclear Track Detectors (SSNTD), CR-39 type, and allowed integrated measurements. The second one consisted of a portable device for short time measurements. The last consisted of a continuous measurement device for extended monitoring, placed in selected sites. Soil 222Rn activity was measured together with soil Thoron (220Rn) and soil carbon dioxide (CO2) efflux, and it was compared with the content of radionuclides in the rocks. Two different soil gas horizontal transects were investigated across the Pernicana fault system (NE flank of Mount Etna), from November 2006 to April 2007. The results obtained with the three methodologies are in a general agreement with each other and reflect the tectonic settings of the investigated study area. The lowest 222Rn values were recorded just on the fault plane, and relatively higher values were recorded a few tens of meters from the fault axis on both of its sides. This pattern could be explained as a dilution effect resulting from high rates of soil CO2 efflux. Time variations of 222Rn activity were mostly linked to atmospheric influences, whereas no significant correlation with the volcanic activity was observed. In order to further investigate regional radon distributions, spot measurements were made to identify sites having high Rn emissions that could subsequently be monitored for temporal radon variations.. SSNTD measurements allow for extended-duration monitoring of a relatively large number of sites, although with some loss of temporal resolution due to their long integration time. Continuous monitoring probes are optimal for detailed time monitoring, but because of their expense, they can best be used to complement the information acquired with SSNTD in a network of monitored sites..
    Description: Work founded by Istututo Nazionale di Geofisica e Vulcanologia and Dipartimento Protezione Civile, Italy
    Description: Published
    Description: 178-185
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Soil Radon and Thoron activity ; soil CO2 efflux ; Pernicana fault system ; volcano-tectonic monitoring ; Mount Etna ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2017-04-04
    Description: Recent studies have shown that geological emissions of methane are an important greenhouse-gas source. Remarkable amounts of methane, estimated in the order of 40-60 Tg yr-1, are naturally released into the atmosphere from the Earth’s crust through faults and fractured rocks. The main source is natural gas, both microbial and thermogenic, produced in hydrocarbon-prone sedimentary basins and injected into the atmosphere through macro-seeps (onshore and offshore mud volcanoes and other seeps) and microseepage, an invisible but pervasive flux from the soil. This source is now evaluated for Europe on the basis of a literature survey, new field measurements and derived emission factors. The up-scaling criteria recommended by the EMEP/CORINAIR guidelines are applied to the local point and area source data. In Europe, 25 countries host oil and/or natural gas reservoirs and potentially, or actually, emit geological methane. Flux data, however, are available only from 10 countries: the onshore or offshore petroliferous sectors of Denmark, Italy, Greece, Romania, Spain, Switzerland, United Kingdom and Black Sea countries (Bulgaria, Ukraine, Georgia). Azerbaijan, whose emissions due to mud volcanism are known to be relevant, is included in the estimate. The sum of emissions, regional estimates and local measurements, related to macro-seeps leads to a conservative total value of about 2.2 Tg yr-1. Together with the potential microseepage fluxes from the petroliferous basins, estimated on the basis of the Total Petroleum System concept (around 0.8 Tg yr-1), the total European seepage is projected to 3 Tg yr-1. This preliminary figure would represent, in terms of magnitude, the second natural methane source for Europe after wetlands. The estimate will have to be refined by increasing the number of seepage measurements both on lands, where there is high potential for microseepage (e.g., Germany, Hungary, Romania, Ukraine, Belarus, Russia, Georgia) and in coastal marine areas (the North Sea, the Black Sea, offshore Greece and Italy) where emission factors and the extent of the underwater seeping area are not completely known.
    Description: Published
    Description: 1430-1443
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; Natural emissions ; Geological sources ; Seepage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2017-04-04
    Description: The Chimaera gas seep, near Antalya (SW Turkey), has been continuously active for thousands of years and it is known to be the source of the first Olympic fire in the Hellenistic period. New and thorough molecular and isotopic analyses including methane (approximately 87% v/v; δ to the power of 13 C1 from -7.9‰ to -12.3‰; δ to the power of 13 D1 from -119‰ to -124‰), light alkanes (C2 + C3 + C4 + C5 = 0.5%; C6+: 0.07%; δ to the power of 13 C2 from -24.2‰ to -26.5‰; δ to the power of 13 C3 from -25.5‰ to -27‰), hydrogen (7.5–11%), carbon dioxide (0.01–0.07%; δ to the power of 13 CCO2: -15‰), helium (approximately 80 ppmv; R/Ra: 0.41) and nitrogen (2–4.9%; δ to the power of 15 N from -2‰ to -2.8‰) converge to indicate that the seep releases a mixture of organic thermogenic gas, related to mature type III kerogen occurring in Palaeozoic and Mesozoic organic-rich sedimentary rocks, and abiogenic gas produced by low-temperature serpentinization in the Tekirova ophiolitic unit. Methane is not related to mantle or magma degassing. The abiogenic fraction accounts for about half of the total gas released, which is estimated to be well beyond 50 ton year to the power of -1. Ophiolites and limestones are in contact along a tectonic dislocation leading to gas mixing and migration to the Earth’s surface. Chimaera represents the biggest emission of abiogenic methane on land discovered so far. Deep and pressurized gas accumulations are necessary to sustain the Chimaera gas flow for thousands of years and are likely to have been charged by an active inorganic source.
    Description: Published
    Description: 263-273
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: abiogenic methane ; isotopic composition ; ophiolites ; seep ; serpentinization ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2017-04-04
    Description: The ‘‘Santa Maria di Leuca" Cold-Water Coral (CWC) province (northern Ionian Sea) was investigated for the first time to detect eventual occurrence of methane anomalies as a possible indication of hydrocarbon seepage stimulating the coral growth. Most coral mounds have developed in correspondence with tectonic scarps and faults, orthogonal to the southern margin and trending NW-SE, which could be potential sites of gas escape. A visual and instrumental inspection was performed by using a new deep-sea probe equipped with video-cameras, sonar, CTD, methane sensors, and a water sampler. Eight areas were explored by 10 surveys, depths ranging from 380 to 1100 m, for a total of more than 26h of continuous video and instrumental recording. Sediments were also sampled by gravity corers and analysed in laboratory. The images allowed to assess distribution, abundance and geometry of the colonies, most of which are developed on morphological highs often characterised by tectonic scarps. All data indicate however the lack of a significant occurrence of methane, both in seawater and sediments. No direct or indirect expressions of gas seepage were recognised on the seabed. Weak methane anomalies were detected only in seawater at the base of some fault-linked scarps, where more reducing conditions and bacterial methanogenesis are possibly enhanced by less water circulation. The faults are not fluid-bearing as previously suggested by high-resolution geophysical signatures. The development of the coral colonies thus cannot be attributed to seeping fluids, but to a favourable physiographic position with exposure to nutrient-rich currents.
    Description: In press
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; Corals ; Seepage ; Marine geology ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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