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  • Industrial Chemistry  (9,655)
  • 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
  • resilience
  • Wiley-Blackwell  (9,664)
  • Blackwell Publishing Ltd  (4)
  • American Chemical Society
Collection
Years
  • 1
    Publication Date: 2017-04-04
    Description: The tectonic deformation of the Lipari-Vulcano complex, one of the most important active volcanic areas of Mediterranean region, is studied here through the analysis of ten years (1996-2006) of GPS data from both 3 permanent and 13 non-permanent stations. This area can be considered crucial for the understanding of the Eurasia-Africa plates interaction in the Mediterranean area, and, in general, this work emphasize a methodological approach, already applied in other areas worldwide (e.g. Shen et al., 1996, El-Fiki and Kato, 1999) where geodetic data and strain parameters maps of critical areas can help to improve our understanding of their geodynamical aspects. In this framework, this study is aimed at providing a kinematic deformation model on the basis of the dense geodetically estimated velocities of the Lipari-Vulcano complex. In particular, the observed deformation pattern can be described by a mix between 1) the main N-S regional compression and 2) a NNE-SSW compression with a small right-lateral strike slip component acting along a tectonic structure N°40W trending located between the two islands. This pattern was inspected through a simplified synthetic model.
    Description: This research has benefited from funding provided by the Italian Presidenza del Consiglio dei Ministri – Dipartimento della Protezione Civile (DPC).
    Description: Published
    Description: 370–377
    Description: 1.9. TTC - Rete GPS nazionale
    Description: JCR Journal
    Description: reserved
    Keywords: GPS ; Aeolian Islands ; strain ; modelling ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: The 2009 April 6, Mw= 6.3 L’Aquila earthquake occurred within a complex system of NW–SE trending normal faults in the Abruzzi Central Apennines (Italy). We analyse the coseismic deformation as measured by 〉70 global positioning system (GPS) stations, both from continuous and survey-mode networks, providing unprecedented details for a moderate normal faulting earthquake in Italy from GPS measurements. We use rectangular, uniform-slip, dislocations embedded in an elastic, homogeneous and isotropic half-space and a constrained, non-linear optimization algorithm, to solve for the best-fitting rectangular dislocation geometry and coseismic-slip distribution. We use a bootstrap approach to investigate uncertainties in the model parameters and define confidence bounds for all the inverted parameters. The rupture occurred on a N129°E striking and 50° southwestward dipping normal fault, in agreement with geological observations of surface breaks along the Paganica fault. Our distributed slip model exhibits a zone of relatively higher slip (〉60 cm) between ∼1.5 and ∼11 km depth, along a roughly downdip, NW–SE elongated patch, confined within the fault plane inverted assuming uniform-slip. The highest slip, of the order of ∼1 m, occurred on a ∼16 km2 area located at ∼5 km depth, SE of the mainshock epicentre. The analysis of model resolution suggests that slip at depth below ∼5 km can be resolved only at a spatial scale larger than 2 km, so a finer discretization of different asperities within the main patch of coseismic-slip is not allowed by GPS data. We compute the coseismic Coulomb stress changes in the crustal volume affected by the major aftershocks, and compare the results obtained from the uniform-slip and the heterogeneous-slip models. We find that most of the large aftershocks occurred in areas of Coulomb stress increase of 0.2–13 bar and that a deepening of the slip distribution down to a depth greater than 6 km in the SE part of the fault plane, in agreement with the inverted slip model, can explain the deepest, April 7, Mw 5.3 aftershock.
    Description: Published
    Description: 473-489
    Description: 1.9. Rete GPS nazionale
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Satellite geodesy ; Space geodetic surveys ; Earthquake ground motions ; Earthquake source observations ; Earthquake interaction, forecasting, and prediction ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: We present an improved evaluation of the current strain and stress fields in Southern Apennines (Italy) obtained through a careful analysis of geodetic, seismological and borehole data. In particular, our analysis provides an updated comparison between the accrued strain recorded by geodetic data, and the strain released by seismic activity in a region hit by destructive historical earthquakes. To this end, we have used 9 years of GPS observations (2001-2010) from a dense network of permanent stations, a dataset of 73 well constrained stress indicators (borehole breakouts and focal mechanisms of moderate to large earthquakes), and published estimations of the geological strain accommodated by active faults in the region. Although geodetic data are generally consistent with seismic and geologic information, previously unknown features of the current deformation in southern Italy emerge from this analysis. The newly obtained GPS velocity field supports the well-established notion of a dominant NE-SW-oriented extension concentrated in a ~50 km wide belt along the topographic relief of the Apennines, as outlined by the distribution of seismogenic normal faults. Geodetic deformation is, however, non uniform along the belt, with two patches of higher strain-rate and shear stress accumulation in the north (Matese Mountains) and in the south (Irpinia area). Low geodetic strain-rates are found in the Bradano basin and Apulia plateau to the east. Along the Ionian Sea margin of southern Italy, in southern Apulia and eastern Basilicata and Calabria, geodetic velocities indicate NW-SE extension which is consistent with active shallow-crustal gravitational motion documented by geological studies. In the west, along the Tyrrhenian margin of the Campania region, the tectonic geodetic field is disturbed by volcanic processes. Comparison between the magnitude of the geodetic and the seismic strain-rates (computed using a long historical seismicity catalogue) allow detecting areas of high correlation, particularly along the axis of the mountain chain, indicating that most of the geodetic strain is released by earthquakes. This relation does not hold for the instrumental seismic catalogue, as a consequence of the limited time span covered by instrumental data. In other areas (e.g. Murge plateau in central Apulia), where seismicity is very low or absent, the yet appreciable geodetic deformation might be accommodated in aseismic mode. Overall, the excellent match between the stress and the strain-rate directions in much of the Apennines indicates that both earthquakes and ground deformation patterns are driven by the same crustal forces.
    Description: Published
    Description: 1270-1282
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Satellite geodesy ; Plate motions ; Neotectonics ; Europe ; Apennines ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-04
    Description: This article has been accepted for publication in Geophysical Journal International ©: The Authors 2003. Published by Oxford University Press on behalf of The Royal Astronomical Society. All rights reserved.
    Description: In this study, we modify and extend a data analysis technique to determine the stress orientations between data clusters by adding an additional constraint governing the probability algorithm. We apply this technique to produce a map of the maximum horizontal compressive stress (S_Hmax) orientations in the greater European region (including Europe, Turkey and Mediterranean Africa). Using the World Stress Map dataset release 2008, we obtain analytical probability distributions of the directional differences as a function of the angular distance, θ. We then multiply the probability distributions that are based on pre-averaged data within θ〈3° of the interpolation point and determine the maximum likelihood estimate of the S_Hmax orientation. At a given distance, the probability of obtaining a particular discrepancy decreases exponentially with discrepancy. By exploiting this feature observed in the World Stress Map release 2008 dataset, we increase the robustness of our S_Hmax determinations. For a reliable determination of the most likely S_Hmax orientation, we require that 90% confidence limits be less than ±60° and a minimum of three clusters, which is achieved for 57% of the study area, with small uncertainties of less than ±10° for 7% of the area. When the data density exceeds 0.8×10^-3 data/km2, our method provides a means of reproducing significant local patterns in the stress field. Several mountain ranges in the Mediterranean display 90° changes in the S_Hmax orientation from their crests (which often experience normal faulting) and their foothills (which often experience thrust faulting). This pattern constrains the tectonic stresses to a magnitude similar to that of the topographic stresses.
    Description: This work was supported by the DPC-INGV 2008-2010 S1 project, the EU-FP7 project “Seismic Hazard Harmonization in Europe” (SHARE; Grant agreement no. 226967), and project MIUR-FIRB "Abruzzo" (code: RBAP10ZC8K_003).
    Description: Published
    Description: 3.1. Fisica dei terremoti
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: 4.2. TTC - Modelli per la stima della pericolosità sismica a scala nazionale
    Description: JCR Journal
    Description: partially_open
    Keywords: Neotectonics ; Seismicity and tectonics ; Fractures and faults ; Intra-plate processes ; Plate motions ; Dynamics: gravity and tectonics ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-04
    Description: We present an up-to-date high resolution picture of the ongoing crustal deformation field of Italy, based on an extensive combination of permanent and non-permanent GPS observations carried out since 1994. In addition, we present an updated map of contemporary SHmax orientations computed by a multidisciplinary data set of well-constrained stress indicators, including both published results and novel analyses. The comparison of stress and geodetic strain-rates directions reveals that both patterns are near-parallel over a large part of the investigated area, highlighting that crustal stress and surface deformation are driven by the same mechanism. The comparison of the azimuthal patterns of surface strain and mantle deformation shows a modest correlation on the Alps and a low correlation along the Apennines chain and the Calabro-Peloritan Arc. Along the Apennines chain, this feature suggests the occurrence of significant strain partitioning and crust–mantle mechanical decoupling. Along the Calabro-Peloritan Arc, the apparent low correlation reflects a different mantle–crust mechanism of deformation to the ongoing subduction and rollback of the Ionian slab. In addition, the superposition of regional/local effects related to second-order sources (crustal lateral density changes, strength contrasts), which at regional/local scale modulate the crustal stress/strain-rate pattern, cannot be ruled out.
    Description: Published
    Description: 969-985
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Plate motions ; Seismic anisotropy ; Kinematics of crustal and mantle deformation ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: We used the SBAS DInSAR analysis technique to estimate the interseismic deformation along the western part of the Doruneh fault system (DFS), northeastern Iran. We processed 90 ENVISAT images from four different frames from ascending and descending orbits. Three of the ground velocity maps show a significant interseismic signal. Using a simple dislocation approach we model 2-D velocity profiles concerning three InSAR data set relative to the western part of the DFS, obtaining a good fit to the observations. The resulting model indicates that a slip rate of ∼5mmyr−1 accumulates on the fault below 10 km depth, and that in its western sector the Doruneh fault is not purely strike-slip (left-lateral) as in its central part, but shows a significant thrust component. Based on published geological observations, and assuming that all interseismic deformation is recovered with a single event, we can estimate a characteristic recurrence interval between 630 and 1400 yr.
    Description: Published
    Description: 622-628
    Description: 1.10. TTC - Telerilevamento
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Image processing; Satellite geodesy; Seismic cycle; Radar interferometry; Seismicity and tectonics; Continental tectonics: strike-slip and transform. ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: In this study, we revisit the mechanism of the 1976 Friuli (NE Italy) earthquake sequence (main shocks M w 6.4, 5.9 and 6.0). We present a new source model that simultaneously fits all the available geodetic measurements of the observed deformation. We integrate triangulation measurements, which have never been previously used in the source modelling of this sequence, with high-precision levelling that covers the epicentral area. We adopt a mixed linear/non-linear optimization scheme, in which we iteratively search for the best-fitting solution by performing several linear slip inversions while varying fault location using a grid search method. Our preferred solution consists of a shallow north-dipping fault plane with assumed azimuth of 282◦ and accommodating a reverse dextral slip of about 1 m. The estimated geodetic moment is 6.6 × 1018 Nm (M w 6.5), in agreement with seismological estimates. Yet, our preferred model shows that the geodetic solution is consistent with the activation of a single fault system during the entire sequence, the surface expression of which could be associated with the Buia blind thrust, supporting the hypothesis that the main activity of the Eastern Alps occurs close to the relief margin, as observed in other mountain belts. The retrieved slip pattern consists of a main coseismic patch located 3–5 km depth, in good agreement with the distribution of the main shocks. Additional slip is required in the shallower portions of the fault to reproduce the local uplift observed in the region characterized by Quaternary active folding. We tentatively interpret this patch as postseismic deformation (afterslip) occurring at the edge of the main coseismic patch. Finally, our rupture plane spatially correlates with the area of the locked fault determined from interseismic measurements, supporting the hypothesis that interseismic slip on the creeping dislocation causes strain to accumulate on the shallow (above ∼10 km depth) locked section. Assuming that all the long-term accommodation between Adria and Eurasia is seismically released, a time span of 500–700 years of strain-accumulating plate motion would result in a 1976-like earthquake.
    Description: Published
    Description: 1279-1294
    Description: 3.1. Fisica dei terremoti
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: seismic cycle; earthquake source observations ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2017-04-04
    Description: For decades, many authors have attempted to define the location, geometry and kinematics of the causative fault for the 1908 December 28, M 7.1 earthquake that struck the Messina Straits between Sicily and Calabria (southern Italy). The coseismic displacement caused a predominant downwarping of the Straits and small land uplift away from it, which were documented by levelling surveys performed 1 yr before and immediately after the earthquake. Most of the source models based on inversion of levelling data suggested that the earthquake was caused by a low angle, east-dipping blind normal fault, whose upper projection intersects the Earth surface on the Sicilian (west) side of the Messina Straits.An alternative interpretation holds that the causative fault is one of the high-angle, west-dipping faults located in southern Calabria, on the eastern side of the Straits, and may in large part coincide with the mapped Armo Fault. Here, we critically review the levelling data with the aim of defining both their usefulness and limits in modelling the seismogenic fault. We demonstrate that the levelling data alone are not capable of discriminating between the two oppositely dipping fault models, and thus their role as a keystone for modellers is untenable. However, new morphotectonic and geodetic data indicate that the Armo Fault has very recent activity and is accumulating strain. The surface observations, together with appraisal ofmacroseismic intensity distribution, available seismic tomography and marine geophysical evidence, lends credit to the hypothesis that the Armo and possibly the S. Eufemia faults are part of a major crustal structure that slipped during the 1908 earthquake.
    Description: Published
    Description: 1025-1041
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake source ; Messina Straits ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: We present a strategy to thoroughly investigate the effects of prominent topography on the surface tilt due to a spherical pressure source. We use Etna's topography as a case of study and, for different source positions, we compare the tilt fields calculated through (i) a 3-D boundary element method and (ii) analytical half-space solutions. We systematically determine (i) the source positions leading to the strongest tilt misfits when numerical and analytical results are compared and (ii) the surface areas where the strongest distortions in the tilt field are most likely to be observed. We also demonstrate that, under critical circumstances, in terms of respective positions of pressure source and observation points, results of inversion procedures aimed at retrieving the source parameters can be misleading, if tilt data are analysed using models that do not account for topography.
    Description: Published
    Description: 1471–1481
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Numerical approximations and analysis ; Transient deformation ; Volcano monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2021-06-27
    Description: Social inequalities lead to flood resilience inequalities across social groups, a topic that requires improved documentation and understanding. The objective of this paper is to attend to these differences by investigating self‐stated flood recovery across genders in Vietnam as a conceptual replication of earlier results from Germany. This study employs a regression‐based analysis of 1,010 respondents divided between a rural coastal and an urban community in Thua Thien‐Hue province. The results highlight an important set of recovery process‐related variables. The set of relevant variables is similar across genders in terms of inclusion and influence, and includes age, social capital, internal and external support after a flood, perceived severity of previous flood impacts, and the perception of stress‐resilience. However, women were affected more heavily by flooding in terms of longer recovery times, which should be accounted for in risk management. Overall, the studied variables perform similarly in Vietnam and Germany. This study, therefore, conceptually replicates previous results suggesting that women display slightly slower recovery levels as well as that psychological variables influence recovery rates more than adverse flood impacts. This provides an indication of the results' potentially robust nature due to the different socio‐environmental contexts in Germany and Vietnam.
    Keywords: 333.7 ; flood recovery ; resilience ; societal equity ; vulnerability
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  • 11
    Publication Date: 2021-09-29
    Description: Coping with the growing impacts of flooding in EU countries, a paradigm shift in flood management can be observed, moving from safety‐based towards risk‐based approaches and holistic perspectives. Flood resilience is a common denominator of most of the approaches. In this article, we present the ‘Flood Resilience Rose’ (FRR), a management tool to promote harmonised action towards flood resilience in European regions and beyond. The FRR is a result of a two‐step process. First, based on scientific concepts as well as analysis of relevant policy documents, we identified three ‘levels of operation’. The first level refers to the EU Floods Directive and an extended multi‐layer safety approach, comprising the four different layers of protection, prevention, preparedness and recovery, and related measures to be taken. This level is not independent but depends both on the institutional (second level) and the wider (third level) context. Second, we used surveys, semi‐structured interviews and group discussions during workshops with experts from Belgium, Denmark, Germany, the Netherlands and the United Kingdom to validate the definitions and the FRR's practical relevance. The presented FRR is thus the result of rigorous theoretical and practical consideration and provides a tool capable to strengthen flood risk management practice.
    Description: European Regional Development Fund http://dx.doi.org/10.13039/501100008530
    Keywords: 551.48 ; flood defence measures ; governance and institutions ; integrated flood risk management ; resilience
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  • 12
    Publication Date: 2022-05-24
    Description: Earthquake source inversions based on space-borne Synthetic Aperture Radar interferometry (InSAR) are used extensively. Typically, however, only the line-of-sight (LoS) surface displacement component is measured, which is mainly sensitive to the vertical and E–W deformations, although well-established methods also exist to estimate the flight-path component, which is highly sensitive to the N–S displacement. With high-resolution sensors, these techniques are particularly appealing, because accuracies in the order of 3 cm can be achieved, while retaining spatial resolutions between 45 m and a few km, depending on the required level of filtering. We discuss the application to COSMO-SkyMed SAR imagery of the Spectral Diversity or Multi Aperture Interferometry technique, presenting the first SAR flight-path displacement field associated with the Mw 6.3, 2009 L’Aquila event (central Apennines). Finally, we observe and characterize a previously unknown misregistration pattern.
    Description: Published
    Description: 28-35
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Crustal Deformation ; Multi Aperture Interferometry MAI ; InSAR ; L'Aquila Earthquake ; Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2022-05-24
    Description: We present an application of the novel SISTEM approach, to obtain the dense 3D ground deformation pattern produced by the April 6, 2009, Mw 6.3 L’Aquila earthquake. This event, characterized by a SW-dipping normal fault with thousands of foreshocks and aftershocks located in the depth range 5–15 km, is the most destructive to have struck the Abruzzo region since the major 1703 seismic sequence. The surface deformation, revealed by the SISTEM through the integration of GPS with interferometric measurements from the ENVISAT and ALOS satellites, shows a deformed area extending towards SE along the Aterno valley, in agreement with seismological and other geodetic observations. We inverted the SISTEM results using an optimization algorithm based on the genetic algorithm, providing an accurate spatial characterization of ground deformation. Our results improve previous kinematic solutions for the Paganica fault and allow identification of additional faults that have contributed to the observed complex ground deformation pattern.
    Description: Published
    Description: 79-85
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: JCR Journal
    Description: restricted
    Keywords: L'Aquila earthquake, SISTEM, GPS ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
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  • 14
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949) 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 15
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 6-8 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Die Anordnung dient zur Messung von Dampfdruckerniedrigungen verdünnter Lösungen (10-3 Mol/l) insbesondere assoziierender Substanzen. Es wurde eine Meßanordnung entwickelt, in der die durch kleine Druckdifferenzen verursachte Ausbuchtung der Wölbung des Meniskus eines Hg-Manometers nach dem Prinzip eines Photometers lichtelektrisch mit einem Vakuumthermoelement gemessen wird. Die Anordnung gestattet unabhängig vom Gesamtdruck noch Druckschwankungen von 10-4 mm Hg zu messen.
    Additional Material: 4 Ill.
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  • 16
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Es werden einige Regeleinrichtungen besprochen, die zum Aufbau von im wesentlichen automatisch arbeitenden Destillationskolonnen sowohl für diskontinuierlichen als auch für kontinuierlichen Betrieb führten.
    Additional Material: 9 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 1-6 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Unsere wichtigsten chemischen Großsynthesen gehen von Acetylen bzw. vom Kohlenoxyd-Wasserstoff-Gemisch aus. Die Arbeiten im letzten Jahrzehnt bezweckten, diese Rohstoffe unmittelbar aus dem Ferngas zu gewinnen. Von den entwickelten Verfahren verdient insbesondere das Sauerstoff-Verfahren Beachtung. Es liefert ein Synthesegas mit nur noch 0,2% Methan und ist unempfindlich gegen den im Ferngas vorhandenen organischen Schwefel. Eine etwa folgende Umsetzung des Kohlenoxydes mit Wasserdampf zu CO2 und Wasserstoff kann in unmittelbarem Ánschluß an der Kohlenwasserstoff-Spaltung vorgenommen werden, so daß kein neuer Dampfverbrauch auftritt. Während in der folgenden Arbeit über das Verfahren zur Verarbeitung des gesamten Ferngases auf Kohlenoxyd und Wasserstoff berichtet wird, wird in einer weiteren Arbeit die chemische Verwertung der einzelnen Bestandteile des Ferngases behandelt.
    Additional Material: 10 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 19-24 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Nach den verfügbaren amerikanischen Quellen wird zusammenfassend über die seit etwa 1940 in Amerika erreichten Fortschritte auf dem Gebiet der Sauerstoff-Erzeugung und -Anwendung berichtet, besonders über Versuche an Austauschböden und Trennkolonnen für kleinere, meist leichtbewegliche Anlagen, über die Mittel zur Kälteerzeugung, über die Herstellung und den Versand von flüssigem Sauerstoff sowie über die unmittelbare Erzeugung von hochkomprimiertem Sauerstoff für die Flaschenfüllung durch Verdampfung des flüssigen Sauerstoffs im Zerlegungsapparat. Weiter wird ein neuer Austauschertyp besprochen und auf neu erschlossene Anwendungsgebiete für billigen, mäßig reinen Sauerstoff hingewiesen.
    Additional Material: 6 Ill.
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  • 19
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 15-18 
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    Notes: Bei Kohlenoxyd-Hydrierungen unter Drucken zwischen 300 und 1000 at und Temperaturen über 400° erwiesen sich z. T. sog. „kohlenoxydfeste“ metallische Werkstoffe, insbesondere Stähle mit mehr als 13% Chrom, für den praktischen Betrieb als ungeeignet, obwohl sie anscheinend von Kohlenoxyd nicht abgebaut wurden. Es wurden daher 20 derartige Stähle und 6 eisenfreie Metallproben gegenüber Wassergas bei 1000 at und Temperaturen zwischen 300 und 450° untersucht und aus den Ergebnissen Folgerungen für die praktische Verwendungsmöglichkeit im Apparafebau gezogen.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 24-30 
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 31-31 
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 31-32 
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 48-48 
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 48-48 
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    Notes: Die Angabe, daß sich die Ausscheidung von Härtebildern mit Orthophosphaten in wässeriger Lösung unter Bildung von Tricalciumphosphat vollziehe, ist unzutreffend. Der Niederschlag dürfte vielmehr die Formel des Hydroxylapatits haben.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 49-57 
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    Notes: Bis 1940 war die Anwendung hoher Vakua fast nur auf das Laboratorium beschränkt, in der Technik evakuierte nur die Röhrenindustrie bis auf Drucke von beinahe 10-7 mm Hg, aber es handelte sich auch hier meist nur um verhältnismäßig kleine Volumina. Die anschließende Entwicklung wurde durch mehrere Ereignisse besonders gefördert: durch die Konstruktion hervorragender Pumpen in Deutschland und Amerika, durch die Schaffung guter Gläser in Jena, durch die Erfolge der Vakuumdestillation von Fetten, Ölen und empfindlichen organischen Substanzen in England, Deutschland und später in USA, und schließlich durch das amerikanische Atombombenprojekt, wo bereits bei der Gasdiffusions- und elektromagnetischen Trennung der Uran-Isotope die ersten großen Vakuum-Probleme auftraten. Heute ist selbst die großtechnische Erzeugung von Hochvakuum zwischen -100° und + 1000° C ein untergeordnetes Problem der Verfahrenstechnik geworden.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 61-63 
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    Notes: Es wird über Versuche mit zwei Ausführungen von Pilzglocken aus Porzellan berichtet, die in Rektifizierböden eingebaut waren. Wirkung, Druckverlust und Flüssigkeitsinhalt der Sälen wurden ermittelt. Um eine gute Wirkung zu erreichen, müssen die Einzelabmessungen des Bodens entsprechend gewählt werden. Auch der Einbau einer Staurippe erhöht die Bodenwirkung.
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    Notes: Die hier beschriebenen Methoden sollen es dem Schichtarbeiter mit einfachen Mitteln ermöglichen, kurzfristig eine gefährliche Acetylen-Anreicherung zu erkennen. Die Ergebnisse werden mit denen quantitativer Methoden verglichen.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 68-70 
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 67-67 
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    Notes: Der im folgenden beschriebene Kolbenverdichter arbeitet mit ungeschmierten Kolben und Stopfbüchsen. Die Abdichtung wird durch Labyrinthdichtungen erreicht. Dadurch behält das verdichtete Medium die ursprüngliche Reinheit, so daß der Verdichter in der chemischen Industrie und der Lebensmittelindustrie da verwendet werden kann, wo völlig reine Druckluft gebraucht wird.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 71-73 
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 68-68 
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    Notes: In den letzten Jahren hat die Fluorchemie, insbesondere die verschiedener organischer fluorierter Verbindungen, erheblich an praktischer Bedeutung gewonnen. Da in einigen Veröffentlichungenz. B. DECHEMA-Werkstofftabellen 1948; ferner Ind. Engng. Chem. 39, 12a u. 91a [1947]. bereits auf die gute Eignung des Silbers als Apparatebauwerkstoff für technische Reaktionen mit Fluorverbindungen hingewiesen worden ist, seien nachstehend einige quantitative Angaben gemasht, die das Ergebnis einer 1944 laboratoriumsmäßig durchgeführten Korrosionsprüfung darsfellen.
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    Notes: Die technisch-wissenschaftliche Forschung der letzten Jahrzehnte brachte eine Erweiterung und Vertiefung unserer Erkenntnisse über die beim gekoppelten Wärme- und Stoffaustausch sich abspielenden Vorgänge. Trotzdem blieben noch Fragen ungeklärt, deren erschöpfende Behandlung für die rechnerische Erfassung baispielsweise der Trocknungsvorgänge unerläßlich ist. Zu diesen Fragen gehört der Zusammenhang zwischen Luftzustand und Gutstemperatur während des Trocknens bei bestimmten Arten der Gasströmung. Im folgenden werden diese Verhältnisse untersucht, wobei sich eine gute Übereinstimmung zwischen theoretischen und experimentellen Ergebnissen ergibt.
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    Notes: Die bisherigen Definitionen des Wirkungsgrades von Wärmeaustauschern konnten zwangsläufig nicht in jeder Hinsicht befriedigen. Es wird auch immer schwierig sein, einen Wirkungsgrabegriff auf energetischer Grundlage aufzustellen, solange der Wärmeaustauschapparat allein betrachtet wird, da sich Wärme- und Druckverluste jeweils verschieden auswirken. Daher sollte auch das Arbeitsverfahren, in das der Wärmeaustauscher eingeschaltet ist, mit in Betracht gezogen werden. Im folgenden wird gezeigt, daß sich dann ein auf energetischer Grundlage beruhender Gütegradbegriff schaffen läßt, der zwar von Fall zu Fall neu aufgestellt werden muß, dafür aber eine Reihe von Vorteilen für den Erzeuger und den Abnehmer von Wäreaustauschapparaten bietet.
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    Notes: Der Auslaufbecher DIN 53211 ist ein einfaches, praktisch leicht zu handhabendes Betriebs-Gerät zur Beurteilung der Konsistenz besonders von Farben und Lacken. Die vorliegende Untersuchung zeigt, innerhalb welcher Grenzen der Auslaufbecher tatsächlich geeignet ist, ein zuverlässiges Maß für die Konsistenz mit ihren Nebenerscheinungen, z. B. für die Viskosität usw., zu sein. Der experimentelle Zusammenhang zwischen Auslaufzeit und Viskosität wird durch Versuche mit 11 Normalflüssigkeiten ermittelt. Die genaue Analyse der Versuchsergebnisse gibt einen interessanten Einblick in die Strömungsvorgänge bei diesem Gerät.
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    Notes: Die Aufzeichnung polarographischer Kurven in Tintenschrift gestattet einfachstes Modellieren und Auswerten der Kurven. Für den Betrieb normaler Tintenschreiber unter Verstärkung der Elektrodenströme mittels Verstärker in Saugschaltung1 wurde während des Krieges ein vollelektrisch arbeitendes Zusatzgerät durchgebildet, in dem alle erforderlichen Schaltelemente und Verstellorgane zur Kurvenaufnahme untergebracht sind. Die einfach zu bedienende, robuste und universell verwendbare polarographische Meßeinrichtung läßt sich auch in technischen Betrieben zur Durchführung von Serienanalysen verwenden. Seine Wirkungsweise wird im folgenden unter Beifügung einiger charakteristischer Kurven erläutert.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 110-114 
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    Notes: Vielen Betrieben steht Kühlwasser zur Verfügung, das reich an Carbonathärte ist und daher leicht Versteinungen der Leitungen hervorruft. Um diese Steinbildung zu verhindern, hat sich der Zusatz geringer Mengen an Natriumhexametaphosphat bewährt. Während man zur Prüfung der Brauchbarkeit von Zusätzen bisher einfache Becherglasversuche angestellt hat, haben die Verfasser ein geeignetes, im Laboratorium durchführbares Prüfverfahren entwickelt, wobei die wesentlichen betrieblichen Faktoren berücksichtigt werden können. Im folgenden wird diese Apparatur beschrieben und dann werden damit erzielte Versuchsergebnisse mitgeteilt, die mit den in der Praxis gemachten Erfahrungen gut übereinstimmen. In einem Anhang wird schließlich über Becherglasversuche mit organischen Zusätzen berichtet.
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    Notes: In der vorhergehenden Arbeit1 war über ein Verfahren berichtet worden, nach dem aus Ferngas durch Totalspaltung mit Sauerstoff Synthesegas gewonnen werden kann. Das Ferngas enthält jedoch eine Reihe von wertvollen Bestandteilen, die für die Verarbeitung auf Synthesegas zu schade sind. Im folgenden wird beschrieben, wie diese Produkte zu isolieren sind und welche Möglichkeit für ihre Weiterverarbeitung gegeben ist. Dabei wird insbesondere das Sauerstoff-Verfahren besprochen, bei dem Methan und Sauerstoff erst nach vollendeter Mischung einer Flammenreaktion unterworfen werden, die durch Einspritzen von Wasser unterbrochen wird.
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    Notes: Das indirekte Verfahren, nach dem Phosphat- bzw. Fluor-lonen durch die Extinktionsabnahme des Eisensalicylat-Komplexes bestimmt werden, kann auch für die Bestimmung der Schwefelsäure in Nitriersäure-Gemischen nutzbar gemacht werden.
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    Notes: Als Beitrag zur Weiterentwicklung des Verfahrens wird die Struktur von Zerstäubernebeln und die Tropfenbewegung besprochen und ein Weg zur Berechnung des Trocknungsverlaufes gezeigt.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 139-142 
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    Notes: Fehler in der Bemessung von Vakuumleitungen führen im chemischen Betrieb nicht nur zu einer Erhöhung der laufenden Kosten, sondern können auch Anlaß zu Qualitäts minderungen geben, da dann bei höheren Drucken und damit bei unzulässig hohen Temperaturen gearbeitet werden muß. Es werden daher im folgenden Richtlinien für die Bemessung von Vakuumleitungen aufgestellt und an H and eines Nomogrammes erläutert.
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    Notes: Die härtbaren und thermoplastischen Kunststoffe sowie die synthetischen Kautschuksorten werden wegen ihrer Korrosionsbeständigkeit an zahlreichen Stellen des chemischen Apparatebaues verwendet, darüber hinaus auch in der Textilchemie, Nahrungsmittelindustrie und Metallurgie als Baumaterial oder als Hilfsmittel für Geräte, Anlagen und Apparate.
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    Notes: Die Bedeutung, die das Pektin für die Lebensmittelversorgung und für andere zahlreiche Industriezweige erlangt hat, gibt Veranlassung dazu die verschiedenen Methoden aufzuzeigen, die zu seiner Gewinnung führen, und kurz auf die Wege hinzuweisen die in der Weiterentwicklung des bisher Erreichten von der neueren Forschung beschritten werden.
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