ALBERT

Description: The Latest Danian Event (LDE; ~62.15 Ma) is a major double-spiked eccentricity-driven transient warming event and carbon cycle perturbation (hyperthermal) in the early Paleocene, which has received significantly less attention compared to the larger events of the late Paleocene–early Eocene. A better understanding of the nature of the LDE may broaden our understanding of hyperthermals more generally and improve our knowledge of Earth system responses to extreme climate states. Here we present planktic and benthic foraminiferal Mg/Ca and B/Ca records that shed new light on changes in South Atlantic temperature and carbonate chemistry during the LDE. Our planktic Mg/Ca record reveals a pulsed increase in sea surface temperature of at least ~1.5°C during the older carbon isotope excursion, and ~0.5°C during the younger isotope excursion. We observe drops in planktic and benthic B/Ca, synchronous with pronounced negative excursions in benthic δ13C, which suggest a shift in the carbonate system towards more acidic, dissolved inorganic carbon-rich conditions, in both the surface and deep ocean. Conditions remain more acidic following the LDE, which we suggest may be linked to an enhanced ocean alkalinity sink due to changes in the make-up of planktic calcifiers, hinting at a novel feedback between calcifier ecology and ocean-atmosphere CO2.

Description: Paired benthic foraminiferal trace metal and stable isotope records have been constructed from equatorial Pacific Ocean Drilling Program Site 1218. The records include the two largest abrupt (〈1 Myr) increases in the Cenozoic benthic oxygen isotope record: Oi‐1 in the earliest Oligocene (∼34 Ma) and Mi‐1 in the earliest Miocene (∼23 Ma). The paired Mg/Ca and oxygen isotope records are used to calculate seawater δ18O (δw). Calculated δw suggests that a large Antarctic ice sheet formed during Oi‐1 and subsequently fluctuated throughout the Oligocene on both short (〈0.5 Myr) and long (2–3 Myr) timescales, between about 50 and 100% of its maximum earliest Oligocene size. The magnitudes of these fluctuations are consistent with estimates of sea level derived from sequence stratigraphy. The transient expansion of the Antarctic ice sheet at Mi‐1 is marked in the benthic δ18O record by two positive excursions between 23.7 and 22.9 Ma, each with a duration of 200–300 kyr. Bottom water temperatures decreased by ∼2°C over the 150 kyr immediately prior to both rapid δ18O excursions. However, the onset of each of these phases of ice growth is synchronous, within the resolution of the records, with the onset of a 2°C warming over ∼150 kyr. We suggest that the warming during these glacial expansions reflect increased greenhouse forcing prompted by a sudden decrease in global chemical weathering rates as Antarctic basement silicate rocks became blanketed by an ice sheet. This represents a negative feedback process that might have operated during major abrupt growth phases of the Antarctic ice sheet.

Description: Current climate change may induce positive carbon cycle feedbacks that amplify anthropogenic warming on time scales of centuries to millennia. Similar feedbacks might have been active during a phase of carbon cycle perturbation and global warming, termed the Paleocene-Eocene Thermal Maximum (PETM, 56 million years ago). The PETM may help constrain these feedbacks and their sensitivity to warming. We present new high-resolution carbon isotope and sea surface temperature data from Ocean Drilling Project Site 959 in the Equatorial Atlantic. With these and existing data from the New Jersey shelf and Maud Rise, Southern Ocean, we quantify the lead-lag relation between PETM warming and the carbon input that caused the carbon isotope excursion. We show ~2 ºC of global warming preceded the CIE by millennia, strongly implicating CO2-driven warming triggered a positive carbon cycle feedback. We further compile new and published barium (Ba) records encompassing continental shelf, slope and deep-ocean settings. Based on this compilation, average Ba burial rates approximately tripled during the PETM, which may require an additional source of Ba to the ocean. Although the precipitation pathway is not well constrained, dissolved Ba stored in sulfate-depleted pore-waters below methane hydrates could represent an additional source. We speculate the most complete explanation for early warming and rise in Ba supply is that hydrate dissociation acted as a positive feedback and caused the CIE. This could imply hydrates are more temperature-sensitive than previously considered, and may warrant reconsideration of the political assignment of 2 °C warming as a safe future scenario.

Description: It contains three tables that correspond to the supplementary information of the article mentioned above. Tables S3 and S4 can be found within the Supplementary Information document. Table S1 contains high-resolution bulk and benthic carbon and oxygen stable isotope data from ODP Hole 702B across the Middle Eocene Climatic Optimum (40 Ma). Table S2 contains benthic foraminiferal data (relative abundance and ecology index) and accumulation rates from ODP Hole 702B across the Middle Eocene Climatic Optimum (40 Ma). Table S5 contains middle Eocene ODP Hole 702B XRF core scanning data, high-resolution bulk and benthic carbon and oxygen stable isotope data from ODP Site 1263 and age model correlation tie points between drill sites for ODP Sites 1263, 738 and 702B as well tie points for a detailed astronomical age model for ODP Site 1263 (La2010b solution).