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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases  (2)
  • Akadémiai Kiadò  (1)
  • American Association for the Advancement of Science  (1)
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  • 1
    Publication Date: 2021-01-27
    Description: In this work we report new data on He abundances and isotope ratios (3He/4He) from gas associated to some thermal and CO2-rich mineral waters in N-Portugal. Collected gas samples are mainly CO2-dominant except two sites where gas is N2-rich. All the sampling sites are characterized by exceptionally high helium contents with 3He/4He ratios, corrected for air contamination, varying considerably from 0.09 to 2.68 Ra. In all sites, the 3He/4He ratios are higher than that typical for stable continental areas thus indicating a variable but not-negligible (up to 30%) contribution of mantle-derived primordial He. In all the CO2-rich waters, CO2/3He ratios and 13CCO2 are comparable with mantle values, thus suggesting a magmatic origin also for CO2. On the contrary, in the N2-rich waters He is mainly radiogenic, and CO2 is organic in origin. Since no recent volcanic activity is observed in NW Iberia, high 3He/4He values could be due, at least, to three processes: a) releasing of gas from the local upper mantle through deep extensional fault systems; b) releasing of magmatic volatiles from crustal reservoir(s) formed during past volcanic activity; c) degassing of a subsurface emplaced magma body. Mantle He flux in N-Portugal has been estimated to be up to 3 orders of magnitude higher than that typical for stable continental areas, thus suggesting, in this area, the presence of a tensional tectonic regime. This implies that mantle gases could migrate upward probably through inherited tectonic structures reactivated by neotectonic activity. The third possible scenario seems to be less plausible since seismic surveys carried out in NW Iberian did not find any significant evidence of mantle intrusion in the crust. The observed spatial variability in mantle-derived contribution could reflect the geometry of the granitic plutons in this area, thus supporting the hypotheses of an upper mantle degassing. Alternatively, it could be the result of a lateral migration of magmatic volatiles stored in a crustal reservoir.
    Description: Published
    Description: Budapest, Hungary
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Helium isotopes ; NW Iberian peninsula ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 2
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    American Association for the Advancement of Science
    Publication Date: 2017-04-04
    Description: BREVIA
    Description: Current emission inventories require an additional "unknown" source to balance the global atmospheric budgets of ethane (C2H6). Here, we provide evidence that a substantial part of the missing source can be attributed to natural gas seepage from petroliferous, geothermal, and volcanic areas. Such geologic sources also inject propane (C3H8) into the atmosphere. The analysis of a large data set of methane (CH4), ethane, and propane concentrations in surface gas emissions of 238 sites from different geographic and geologic areas, coupled with published estimates of geomethane emissions, suggests that Earth's degassing accounts for at least 17% and 10% of total ethane and propane emissions, respectively.
    Description: Published
    Description: 478
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: Ethane ; Propane ; Geologic emissions ; Seepage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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