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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (7)
  • Blackwell Publishing Ltd  (4)
  • Agu  (3)
  • Cell Press
  • Nature Publishing Group
Collection
Years
  • 1
    Publication Date: 2017-04-04
    Description: We report here on the real-time measurement of CO2 and SO2 concentrations in the near-vent volcanic gas plume of Mount Etna, acquired by the use of a field portable gas analyzer during a series of periodic field surveys on the volcano’s summit. During the investigated period (September 2004 to September 2005), the plume CO2/SO2 ratio ranged from 1.9 to 10.8, with contrasting composition for Northeast and Voragine crater plumes. Scaling the above CO2/SO2 ratios by UV spectroscopy determined SO2 emission rates, we estimate CO2 emission rates from the volcano in the range 0.9–67.5 kt d 1 (average, 9 kt d 1). About 2 kt of CO2 were emitted daily on average during quiescent passive degassing, whereas CO2 emission rates from Etna’s summit were 10–40 times larger during the 2004–2005 effusive event (with a cumulative CO2 release of 3800 kt during the 6 months of the eruption). Such a syneruptive increase, ascribed to the replenishment of the shallow (〈6 km) volcanic plumbing system by CO2-rich (0.25 wt %) more primitive magmas, supports the potential of CO2 output rates as key parameters for volcanic hazard assessment.
    Description: Published
    Description: B09207
    Description: JCR Journal
    Description: reserved
    Keywords: carbon dioxide ; Mt. Etna ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: A new method using ammonia solutions in pre-evacuated quartz bottles has been experimented for volcanic gas sampling and analysing. Various tests (reproducibility, variability and comparison with known methods such as NaOH pre-evacuated bottles and acid condensates) have been performed to check for their efficiency. By using ammonia solutions, acid gases (St, HCl, HF), carbon dioxide, noncondensible gases (N2, Ar, …) and metallic trace elements (MTE) can be measured with standard methods (HPLC, GC, titrimetry, ICP-MS). Results showthat acid gases, CO2 and noncondensible gases are sampled and analysedwith similar efficiency inNH4OHbottles than by using the known and accurate NaOH method.Moreover, a key point is that NH4OH solutions, after undergoing adequate processing (oxidation and acidification) allow also precise MTE measurements by using standard ICP-MS methods. Such MTE measurements appear much more reliable than those performed on acid condensates. Pre-evacuated ammonia bottles appear therefore as an optimum tool to collect volcanic gases and to obtain their complete chemical composition.
    Description: Published
    Description: 244-256
    Description: JCR Journal
    Description: reserved
    Keywords: lcanic gas; sampling ; acid gases ; noncondensible gases ; metallic trace elements ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Finding the geometry of aquifers in an active volcano is important for evaluating the hazards associated with phreatomagmatic phenomena and incidentally to address the problem of water supply. A combination of electrical resistivity tomography (ERT), self-potential, CO2, and temperature measurements provides insights about the location and pattern of ground water flow at Stromboli volcano. The measurements were conducted along a NE-SW profile across the island from Scari to Ginostra, crossing the summit (Pizzo) area. ERT data (electrode spacing 20 m, depth of penetration of 200 m) shows the shallow architecture through the distribution of the resistivities. The hydrothermal system is characterized by low values of the resistivity (〈50 W m) while the surrounding rocks are resistive (〉2000 W m) except on the North-East flank of the volcano where a cold aquifer is detected at a depth of 80 m (resistivity in the range 70–300 W m). CO2 and temperature measurements corroborate the delineation of the hydrothermal body in the summit part of the volcano while a negative self-potential anomaly underlines the position of the cold aquifer.
    Description: Published
    Description: L17304
    Description: JCR Journal
    Description: reserved
    Keywords: hydrogeology ; Stromboli volcano ; CO2 ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Despite the advance in our understanding of the carbon exchange between terrestrial ecosystems and the atmosphere, semiarid ecosystems have been poorly investigated and little is known about their role in the global carbon balance. We used eddy covariance measurements to determine the exchange of CO2 between a semiarid steppe and the atmosphere over 3 years. The vegetation is a perennial grassland of Stipa tenacissima L. located in the SE of Spain. We examined diurnal, seasonal and interannual variations in the net ecosystem carbon balance (NECB) in relation to biophysical variables. Cumulative NECB was a net source of 65.7, 143.6 and 92.1 g C mˉ2 yrˉ1 for the 3 years studied, respectively. We separated the year into two distinctive periods: dry period and growing season. The ecosystem was a net source of CO2 to the atmosphere, particularly during the dry period when large CO2 positive fluxes of up to 15 μmol mˉ2 sˉ1 were observed in concomitance with large wind speeds. Over the growing season, the ecosystem was a slight sink or neutral with maximum rates of -2.3 μmol mˉ2 sˉ1. Rainfall events caused large fluxes of CO2 to the atmosphere and determined the length of the growing season. In this season, photosynthetic photon flux density controlled day-time NECB just below 1000 μmol mˉ2 sˉ1. The analyses of the diurnal and seasonal data and preliminary geological and gas-geochemical evaluations, including C isotopic analyses, suggest that the CO2 released was not only biogenic but most likely included a component of geothermal origin, presumably related to deep fluids occurring in the area. These results highlight the importance of considering geological carbon sources, as well as the need to carefully interpret the results of eddy covariance partitioning techniques when applied in geologically active areas potentially affected by CO2-rich geofluid circulation.
    Description: Published
    Description: 539–554
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: alpha grass ; carbon sequestration ; ecosystem respiration ; eddy covariance ; geogas ; geothermal activity ; grasslands ; net ecosystem carbon balance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: This thematic issue of Geofluids includes 11 papers representing the three main topics discussed in the 10th edition of the International Conference on Gas Geochemistry (ICGG-10): (i) gas in petroleum systems and seepage, (ii) gas in geothermal systems and volcanoes and (iii) gas, seismicity and geohazards. ICGG-10 was held in 2009 in Romania, a country extraordinarily rich in surface gas manifestations, that offers innumerable opportunities for innovative studies on gas geochemistry. We briefly describe the present knowledge on gases occurring both in petroliferous sedimentary basins and geothermal areas of Romania. The 11 contributions of this special issue, which include data from eight countries, are then summarised. Based on these papers and other works presented at the ICGG-10, we find that significant advances in analytical capabilities, data treating and interpretation have led to innovative insights into the origin, distribution and environmental impact of gases migrating to the Earth’s surface. It is increasingly clear, in particular, that gas geochemistry can be more effective for petroleum exploration, volcano-tectonic, geodynamic and environmental studies, if multiparametric studies are performed and the data are interpreted in the geological context.
    Description: Published
    Description: 457-462
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; international conference on gas geochemistry ; natural gas ; romania ; seeps ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: Natural gas seeps in the Alpine region are poorly investigated. However, they can provide useful information regarding the hydrocarbon potential of sedimentary Alpine units and related geofluid migration, typically controlled by pressurized gas accumulations and tectonics. A gas seep located near Giswil, in the Swiss Northern Alps, was investigated, for the first time, for molecular and isotopic gas composition, methane flux to the atmosphere, and gas flux variations over time. The analyses indicated that the gas was thermogenic (CH4 〉 96%; d13C1: )35.5& to )40.2&) and showed evidence of subsurface petroleum biodegradation (13C-enriched CO2, and very low C3+ concentrations). The source rock in the region is marine Type II kerogen, which is likely the same as that providing thermogenic gas in the nearby Wilen shallow well, close to Lake Sarnen. However, the lack of d13CCO2 and d13C3 data for that well prevented us from determining whether the Wilen and Giswil seeps are fed by the same reservoir and seepage system. Gas fluxes from the Giswil seep, measured using a closedchamber system, were significant and mainly from two major vents. However, a substantial gas exhalation from the soil occurs diffusely in an area of at least 115 m2, leading to a total CH4 output conservatively estimated to be at least 16 tonnes per year. Gas flux variations, monitored over a 1-month period by a special tent and flowmeter, showed not only daily meteorological oscillations, but also an intrinsic ‘pulsation’ with periods of enhanced flux that lasted 2–6 h each, occurring every few days. The pulses are likely related to episodes of gas pressure build-up and discharge along the seepage system. However, to date, no relationship to seismicity in the active Sarnen strike-slip fault system has been established.
    Description: Published
    Description: 476-485
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Alps ; isotopes ; methane ; organic geochemistry ; seeps ; Switzerland ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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