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  • 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
  • Elsevier Science Limited  (9)
  • Springer  (4)
  • AMRA  (1)
  • Molecular Diversity Preservation International
  • Nature Publishing Group
  • 1
    Publication Date: 2020-10-29
    Description: Turrialba volcano lies in the southern sector of the Central American Volcanic Front (CAVF) in Costa Rica. The geochemistry of major and trace elements, and Sr and Nd isotopes of a selected suite of volcanic rocks ranging in composition from basaltic andesite to dacite and belonging to the last 10 ka of activity of Turrialba volcano is described, together with the He-, Ne-, and Ar-isotope compositions of fluid inclusions hosted in olivine and pyroxene crystals. Most of the variability in the rock chemistry is consistentwith typical trends of fractional crystallization, but there is an outlying group of andesites that displays an adakite-like composition (with a consistent depletion in high-field-strength elements and a marked enrichment in Sr) and low 3He/4He ratios (7.0–7.2 Ra). The trace-element composition of these rocks is typical of subduction-related magmas influenced by an OIB-like component at the source associated with the subduction of the Galapagos seamounts. The 87Sr/86Sr (0.703612–0.703678) and 143Nd/144Nd (0.512960–0.512984) ratios of the bulk rocks vary within narrowranges, and are among the least-radiogenic isotope signatures of the CAVF volcanoes. The 3He/4He ratios measured in fluid inclusions hosted in olivine crystals (up to 8.1 Ra) are among the highest for the CAVF, and indicate that radiogenic 4He from fluids derived fromthe subducting slab contribute negligibly to the mantle wedge. The difference in He isotopes between most of studied rocks and those showing adakite-like features reasonably reflects two distinct components in the local mantle: (1) a MORB-like component, characterized by the highest He-isotope ratios (7.8–8.1 Ra), and (2) an OIB-like component, characterized by lower He-isotope ratios (7.0–7.2 Ra), coming from the subduction of the Galapagos seamounts. An overview at the regional scale indicates that high He-isotope ratios are peculiar to the two extreme sectors of the CAVF (Costa Rica to the south and Guatemala to the north), whereas in the central sector (Nicaragua) the magma source is probably contaminated by slab fluids. For the past few years Turrialba volcano has been in a volcanic unrest phase that has included a series of explosions, the most recent of which occurred between October 2014 and May 2015. The volcano is subject to an ongoing safety alert due to the possibility of a magmatic eruption. One of the crucial questions to be addressed is the kind of eruption that can be expected, and hence what type of magma is likely to be involved. The high 3He/4He ratios (7.8–8.0 Ra) measured during 2011 at high-temperature fumaroles of Turrialba craters are comparable to those measured in fluid inclusions of basaltic andesites that erupted in 1864–1866, suggesting that the magma currently feeding the shallow plumbing system has similar geochemical characteristics to the most recently erupted magma.
    Description: Published
    Description: 319-335
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Turrialba ; 3He/4He ratio ; Fluid inclusions ; Adakite ; MORB mantle ; OIB mantle ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-05-17
    Description: We report results from mineralogical, geochemical and isotopic analyses of the three youngest pyroclastic products (ca. 86 ky) belonging to the Sabatini Volcanic District (Roman Province, central Italy). By means of thermometers, hygrometers and oxygen barometers, we have estimated that the crystallization temperature of magma progressively decreases over time (910–740 °C),whereas the amount ofwater dissolved in the melt and fO2 progressively increases as compositions of magmas become more differentiated (4.5–6.4 wt.% H2O and 0.4–2.6 ΔQFM buffer, respectively). Thermodynamic simulations of phase equilibria indicate that geochemical trends in mafic magmas (MgO N 4 wt.%) can be reproduced by abundant fractionation of olivine and clinopyroxene (~50 wt.% crystallization), while the trends of more evolved magmas (MgO ≤ 4 wt.%) originated by fractional crystallization of plagioclase and sanidine (~45 wt.% crystallization). The behavior of trace elements highlights that magmatic differentiation is controlled by polybaric differentiation that includes: (1) prolonged fractionation of mafic, anhydrous minerals from a primitive, H2O-poor magma at depth and (2) extraction of a more evolved, H2O-rich magma that crystallizes abundant felsic and subordinated hydrous minerals at shallow crustal levels. Assimilation and fractional crystallization modeling also reveal that magmas interacted with the carbonate rocks of the subvolcanic basement. The effect of carbonate assimilation accounts for both trace element and Sr–Nd isotopic variations inmagmas, suggesting amaximumdegree of carbonate assimilation of less than 5 wt.%.
    Description: Published
    Description: 28-38
    Description: 2IT. Laboratori sperimentali e analitici
    Description: JCR Journal
    Description: open
    Keywords: Sabatini Volcanic District ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Secondary minerals of a 91 meters-thick sequence of pillow basalts cored during ODP Leg 195 (Site 1201, West Philippine Basin) were investigated to reconstruct the hydrothermal alteration history and regime. The basement was first buried by red clays, and then by a thick turbidite sequence, thereby isolating it from seawater. The basalts are primitive to moderately fractionated, texturally variable from hypocrystalline and spherulitic to intersertal, sub-ophitic and intergranular. Relic primary minerals are plagioclase, clinopyroxene and opaques. Hydrothermal alteration pervasively affected the basalts, generating secondary clay minerals (mostly glauconite, minor Al-saponite and Fe-beidellite, Na-zeolites, minor alkali-feldspar and calcite. The secondary mineral paragenesis and mutual relationships suggest that the hydrothermal alteration occurred under zeolite-facies conditions, at temperatures 100-150 C. The main phase of alteration occurred under oxidizing conditions, with a high seawater rock ratio, in an open-circulation regime, at temperatures of 30-60 C, with precipitation of abundant glauconite and iddingsite. A later stage of alteration occurred at ca. 70 C, with precipitation of abundant Na-zeolites and minor calcite, in a more restricted circulation regime as a consequence of basement burial under the sedimentary cover, which supplied an altered, Ca-rich and Magma-sulfate-poor water causing precipitation of almost pure calcite.
    Description: Published
    Description: 87-112
    Description: open
    Keywords: west Philippine ; Mineral chemistry ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 478 bytes
    Format: 1006865 bytes
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  • 4
    Publication Date: 2017-04-04
    Description: We describe the mineralogy, geochemistry, and mesomicrostructure of fresh subvolcanic blocks erupted during the 5 April 2003 paroxysm of Stromboli (Aeolian Islands, Italy). These blocks represent ∼50 vol.% of the total erupted ejecta and consist of fine- to medium-grained basaltic lithotypes ranging from relatively homogeneous dolerites to strongly or poorly welded magmatic breccias. The breccia components are represented by angular fragments of dolerites entrapped in a matrix of vesiculated (lava-like to scoriae) crystal-rich (CR) basalt. All of the studied blocks are cognates with the CR basalt of the normal Strombolian activity or lavas and they are often coated by a few-centimeter thick layer of crystal-poor (CP) basaltic pumice erupted during the paroxysm. We suggest that they result from the rapid increase of pressure and related subvolcanic rock failure that occurred shortly before the 5 April 2003 explosion, when the uppermost portion of the edifice inflated and suffered brecciation as the result of the sudden rise of the gas-rich CP basalt that triggered the eruption. Dolerites and magmatic matrix of the breccias show major and trace element compositions that match those of the CR basalts erupted during normal Strombolian activity and effusive events at Stromboli volcano. Dolerites consist of (a) phenocrysts normally found in the CR basalts and (b) late-stage magmatic minerals such as sanidine, An60-28 plagioclase, Fe–Mn-rich olivines (Fo68-48), phlogopite, apatite, and opaque mineral pairs (magnetite and ilmenite), most of which are never found both in lava flows and scoriae erupted during the persistent explosive activity that characterizes typical Strombolian behavior. Subvolcanic crystallization of the Stromboli CR magma, leading to slowly cooled equivalents of basalts, could result from transient drainage of the magma from the summit craters to lower levels. Fingering and engulfing of the material that collapsed from the summit crater floor into the shallow basaltic system during the late evening of 28 December 2002 coupled with the short break in the summit persistent explosions between December 2002 and March 2003 permitted the CR magma pockets to solidify as dolerites, which were confined to the uppermost portion of the system and thus not involved in the ongoing flank effusive activity. Crystal size distribution of the basaltic blocks and crystallization of the finer-grained (〈0.1 mm) mafic minerals of the dolerites over a time interval of ∼100 days closely agrees with the above interpretation. Vesicle filling (miarolitic cavities) locally found in some dolerites, with minerals deposited as vapor-phase crystallization is a result of continuous gas percolation through the rocks of the uppermost portion of the volcanic system. Poorly welded magmatic breccias formed during syn-eruptive processes of 5 April 2003, when the paroxysm strongly shattered the shallow subvolcanic system and many dolerite fragments were entrapped in the CR magma. In contrast, the high degree of welding between the dolerite clasts and the CR basaltic matrix in the strongly welded magmatic breccias provides a snapshot of subvolcanic intrusions of the CR basalt into the dolerite when, after a 2-month break in activity, CR magmas started to rise again to the summit craters. Blocks similar to these subvolcanic ejecta of 5 April 2003 were also erupted during previous paroxysms (e.g., 1930) suggesting that changes in the usual Strombolian activity (e.g., short breaks in the persistent mild explosions and/or flank effusive activity) lead to transient crystallization of dolerites in the shallow plumbing system.
    Description: Published
    Description: 795-813
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Basalt ; Subvolcanic crystallization ; Dolerite ; Magmatic breccia ; Stromboli ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: More than ca 100 km3 of nearly homogeneous crystal-poor phonolite and ca 100 km3 of slightly zoned trachyte were erupted 39 ka during the Campanian Ignimbrite super eruption, the most powerful in the Neapolitan area. Partition coefficient calculations, equilibrium mineral assemblages, glass compositions and texture were used to reconstruct compositional, thermal and pressure gradients in the pre-eruptive reservoir as well as timing and mechanisms of evolution towards magma chamber overpressure and eruption. Our petrologic data indicate that a wide sill-like trachytic magma chamber was active under the Campanian Plain at 2.5 kbar before CI eruption. Thermal exchange between high liquidus (1199 C) trachytic sill and cool country rocks caused intense undercooling, driving a catastrophic and fast (102 years) in situ fractional crystallization and crustal assimilation that produced a water oversaturated phonolitic cap and an overpressure in the chamber that triggered the super eruption. This process culminated in an abrupt reservoir opening and in a fast single-step high decompression. Sanidine phenocrysts crystal size distributions reveal high differentiation rate, thus suggesting that such a sill-like magmatic system is capable of evolving in a very short time and erupting suddenly with only short-term warning.
    Description: Published
    Description: On line First
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Super eruption ; Crystal size distribution ; Partition coefficients ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: Si parla delle geodiversità mineralogiche del Somma-Vesuvio che rappresenta una delle aree per estensione tra le più ricche di specie minerali al mondo
    Description: Published
    Description: 11-14
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: open
    Keywords: Geoparco ; Somma-Vesuvio ; Minerali ; Locaità-Tipo ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 7
    Publication Date: 2017-04-04
    Description: Mt. Etna volcano is located in a complex tectonic setting, with large sectors of its eastern flank sliding seaward at different rates. According to recent petrologic studies, the Etna's plumbing system has a multifaceted geometry, variable in space and time and consisting of storage zones at different depths, where magma ascending to the surface undergoes various processes, mainly fractional crystallization and mixing. In this framework we investigated a possible cause–effect relationship between the flank displacement and pre-eruptive magmatic processes in the shallow plumbing system (b5 km b.s.l.) during the decade 1995–2005. In particular, we analyzed petrography, mineral chemistry, geochemistry, Sr and Nd isotopes of the products emitted from 1995 to 2001 by the four summit craters of Etna (South-East, North-East, Bocca Nuova and Voragine). Results integrated with petrologic data already available in literature for the investigated decade, allowed us to better constrain the temporal evolution of the magmatic processes occurring in the Etna's shallow plumbing system (mainly mixing between compositionally and isotopically distinct magmas and fractional crystallization), and to make inferences on its geometry. Furthermore, a comparison between petrologic data and deformative patterns evidences that, from 1995 to July 2001, the aforementioned pre-eruptive magmatic processes did not significantly influence the volcano eastern flank dislocation, which stayed slow and fairly regular. By contrast, the onset of the 2001 flank eruption leads to an acceleration of the movement as a consequence of the ascent, of a primitive, volatile-rich, subaphyric basaltic magma from a deeper (about 10 km b.s.l.) reservoir, during the 2001 and 2002–03 activity. At least for the decade 1995–2005, pre-eruptive magmatic processes in the shallow portion (b5 km b.s.l.) of Etna's plumbing system, did not directly affect the movement of the volcano's eastern flank. Conversely, a magma intrusion which forcefully opens a new path from a deeper zone (about 10 km b.s.l.) of the plumbing system, causes a dramatic increase of deformative pattern, which strongly accelerates the slide of the eastern flank, as occurred during both 2001 and 2002–03 eruptions.
    Description: Published
    Description: 75-89
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna, Bulk rock composition, Volcano plumbing system, Mixing, Fractional crystallization, Flank instability ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2017-04-04
    Description: Both large (i.e. from hundreds to thousands of metres thick) and small (i.e. from centimetres to a few metres thick) magmatic intrusions are characterized by mineral compositional variations proceeding from the outermost to the innermost part of the intrusive body. However, in the case of large intrusions, mineral compositions become progressively more primitive (e.g. An-rich plagioclases and En-rich pyroxenes) from the chilled margin towards the interior; whereas, the opposite occurs for small intrusive bodies. Since it is unclear to what extent variable cooling rate conditions may alter the phase compositions, we have performed isothermal and dynamic experiments within a temperature interval of 1250–1100 °C using four different cooling rates of 150, 50, 10 and 2.5 °C/h. Numerical simulations of thermal regimes in and around small and large magmatic intrusions have also been performed and compared with phase compositional variations observed in our laboratory experiments. Results indicate that, over rapid cooling rate conditions, the crystal compositions faithfully reproduce those of high-temperature formations, i.e. An-rich plagioclases, En-rich pyroxenes and Usp-poor spinels. However, such a process is limited to a maximum distance of 2–3 m from the margin of the intrusion. Moreover, in active volcanic systems, heat fluxes are released from the main regions of magma storage into host rocks; therefore, only magmas solidifying at the contact of cold wall rocks may develop chilled margins with features related to rapid cooling rate conditions. In the presence of hot host rocks, thermal gradients are significantly reduced and the role played by cooling dynamics on textural and compositional variations of minerals is practically negligible.
    Description: Published
    Description: 28-46
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: restricted
    Keywords: Magmatic intrusion Cooling rate Partition coefficient Thermometer ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: The aim of this study is to determine and characterise the control exerted by parent rock texture on sand composition as a function of grain size. The sands investigated were generated from granitoid parent rocks by the Rhone, Damma and Sidelen glaciers, which drain the Aar Massif in the Central Alps (Switzerland), and were deposited in glacial and fluvio-glacial settings. Mechanical erosion, comminution (crystal breakdown and abrasion) and hydraulic sorting are the most important processes controlling the generation of sediments in this environment, whereas chemical and/or biochemical weathering plays a negligible role. By using a GIS-based Microscopic Information System (MIS), five samples from the glacier-drained portions of the Aar basement have been analysed to determine textural parameters such as modal composition, crystal size distribution and mineral interfaces (types and lengths). Petrographic data of analysed sands include traditional point counts (Gazzi-Dickinson method, minimum of 300 points) as well as textural counts to determine interface types, frequency, and polycrystallinity in phaneritic rock fragments. According to Pettijohn's classification, grain‐size dependent compositions vary from feldspathic litharenite (0φ fraction) via lithic arkose (1φ and 2φ) to arkose (3φ and 4φ). Compositional differences among our data set were compared to modern plutoniclastic sands from the Iberian Massif (Spain) and the St. Gabriel Mts. (California, USA), which allowed us to assess the role exerted by glaciers in generating sediments. By combining data from the MIS with those from petrographic analysis, we outlined the evolution of mineral interfaces from the parent rocks to the sediments.
    Description: Published
    Description: 93-107
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: partially_open
    Keywords: Textural parameters ; Grain size; ; Composition ; Glacial environment ; Sediment generation ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2017-04-04
    Description: In recent decades, geophysical investigations have detected wide magma reservoirs beneath quiescent calderas. However, the discovery of partially melted horizons inside the crust is not sufficient to put constraints on capability of reservoirs to supply cataclysmic eruptions, which strictly depends on the chemical-physical properties of magmas (composition, viscosity, gas content etc.), and thus on their differentiation histories. In this study, by using geochemical, isotopic and textural records of rocks erupted from the high-risk Campi Flegrei caldera, we show that the alkaline magmas have evolved toward a critical state of explosive behaviour over a time span shorter than the repose time of most volcanic systems and that these magmas have risen rapidly toward the surface. Moreover, similar results on the depth and timescale of magma storage were previously obtained for the neighbouring Somma-Vesuvius volcano. This consistency suggests that there might be a unique long-lived magma pool beneath the whole Neapolitan area.
    Description: Published
    Description: article 712
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: N/A or not JCR
    Description: open
    Keywords: magma ; campi flegrei caldera ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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