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  • 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
  • AGU  (4)
  • Springer  (4)
  • The Mineralogical Society  (2)
  • Molecular Diversity Preservation International
  • Nature Publishing Group
  • 1
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    Hydrothermal alteration of oceanic crust in the West Philichemistry investigationppine Sea Basin(Ocean Drilling Program Leg 195,Site 1201): inferences from a mineral (2006)
    Springer
    Details
    Publication Date: 2017-04-04
    Description: Secondary minerals of a 91 meters-thick sequence of pillow basalts cored during ODP Leg 195 (Site 1201, West Philippine Basin) were investigated to reconstruct the hydrothermal alteration history and regime. The basement was first buried by red clays, and then by a thick turbidite sequence, thereby isolating it from seawater. The basalts are primitive to moderately fractionated, texturally variable from hypocrystalline and spherulitic to intersertal, sub-ophitic and intergranular. Relic primary minerals are plagioclase, clinopyroxene and opaques. Hydrothermal alteration pervasively affected the basalts, generating secondary clay minerals (mostly glauconite, minor Al-saponite and Fe-beidellite, Na-zeolites, minor alkali-feldspar and calcite. The secondary mineral paragenesis and mutual relationships suggest that the hydrothermal alteration occurred under zeolite-facies conditions, at temperatures 100-150 C. The main phase of alteration occurred under oxidizing conditions, with a high seawater rock ratio, in an open-circulation regime, at temperatures of 30-60 C, with precipitation of abundant glauconite and iddingsite. A later stage of alteration occurred at ca. 70 C, with precipitation of abundant Na-zeolites and minor calcite, in a more restricted circulation regime as a consequence of basement burial under the sedimentary cover, which supplied an altered, Ca-rich and Magma-sulfate-poor water causing precipitation of almost pure calcite.
    Description: Published
    Description: 87-112
    Description: open
    Keywords: west Philippine ; Mineral chemistry ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    First Italian occurrence of cumengéite from Vesuvius: crystal-structure refinement and revision of the chemical formula (2008)
    The Mineralogical Society
    Details
    Publication Date: 2017-04-04
    Description: The first Italian occurrence of cumengéite, a rare Pb and Cu hydroxychloride, is described from Vesuvius (Italy). Italian cumengéite has a volcanic origin (it occurs in the fumarole), which is unique for that mineral. The mineralogy of Vesuvius' fumarole is outlined briefly. A powder X-ray diffraction. (XRD) pattern of cumengéite is presented. The crystal structure of cumengéite has been refined (R = 0.036) using single-crystal XRD data. CumengeÂite is tetragonal, space group I4/mmm, a 15.1007(2), c 24.4940(4) A Ê. In the structure of cumengeÂite there are five independent Pb atoms, which are linked to 6-9 anions in five different ways. The structural study revealed the presence of two independent and previously unobserved water molecules, and led to the revision of the accepted chemical formula for the mineral: the new formula is Cu20Pb21Cl42(OH)40x6H2O. Analytical data taken from the literature for cumengéite from Boléo, Mexico (the type locality), as well as a new structural study carried out on the type material confirmed the new formula.
    Description: Published
    Description: 1037-1045
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: cumengéite ; Vesuvius ; Italy ; Crystal scructure ; Crystal-chemical formula ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Transient processes in Stromboli’s shallow basaltic system inferred from dolerite and magmatic breccia blocks erupted during the 5 April 2003 paroxysm (2010)
    Springer
    Details
    Publication Date: 2017-04-04
    Description: We describe the mineralogy, geochemistry, and mesomicrostructure of fresh subvolcanic blocks erupted during the 5 April 2003 paroxysm of Stromboli (Aeolian Islands, Italy). These blocks represent ∼50 vol.% of the total erupted ejecta and consist of fine- to medium-grained basaltic lithotypes ranging from relatively homogeneous dolerites to strongly or poorly welded magmatic breccias. The breccia components are represented by angular fragments of dolerites entrapped in a matrix of vesiculated (lava-like to scoriae) crystal-rich (CR) basalt. All of the studied blocks are cognates with the CR basalt of the normal Strombolian activity or lavas and they are often coated by a few-centimeter thick layer of crystal-poor (CP) basaltic pumice erupted during the paroxysm. We suggest that they result from the rapid increase of pressure and related subvolcanic rock failure that occurred shortly before the 5 April 2003 explosion, when the uppermost portion of the edifice inflated and suffered brecciation as the result of the sudden rise of the gas-rich CP basalt that triggered the eruption. Dolerites and magmatic matrix of the breccias show major and trace element compositions that match those of the CR basalts erupted during normal Strombolian activity and effusive events at Stromboli volcano. Dolerites consist of (a) phenocrysts normally found in the CR basalts and (b) late-stage magmatic minerals such as sanidine, An60-28 plagioclase, Fe–Mn-rich olivines (Fo68-48), phlogopite, apatite, and opaque mineral pairs (magnetite and ilmenite), most of which are never found both in lava flows and scoriae erupted during the persistent explosive activity that characterizes typical Strombolian behavior. Subvolcanic crystallization of the Stromboli CR magma, leading to slowly cooled equivalents of basalts, could result from transient drainage of the magma from the summit craters to lower levels. Fingering and engulfing of the material that collapsed from the summit crater floor into the shallow basaltic system during the late evening of 28 December 2002 coupled with the short break in the summit persistent explosions between December 2002 and March 2003 permitted the CR magma pockets to solidify as dolerites, which were confined to the uppermost portion of the system and thus not involved in the ongoing flank effusive activity. Crystal size distribution of the basaltic blocks and crystallization of the finer-grained (〈0.1 mm) mafic minerals of the dolerites over a time interval of ∼100 days closely agrees with the above interpretation. Vesicle filling (miarolitic cavities) locally found in some dolerites, with minerals deposited as vapor-phase crystallization is a result of continuous gas percolation through the rocks of the uppermost portion of the volcanic system. Poorly welded magmatic breccias formed during syn-eruptive processes of 5 April 2003, when the paroxysm strongly shattered the shallow subvolcanic system and many dolerite fragments were entrapped in the CR magma. In contrast, the high degree of welding between the dolerite clasts and the CR basaltic matrix in the strongly welded magmatic breccias provides a snapshot of subvolcanic intrusions of the CR basalt into the dolerite when, after a 2-month break in activity, CR magmas started to rise again to the summit craters. Blocks similar to these subvolcanic ejecta of 5 April 2003 were also erupted during previous paroxysms (e.g., 1930) suggesting that changes in the usual Strombolian activity (e.g., short breaks in the persistent mild explosions and/or flank effusive activity) lead to transient crystallization of dolerites in the shallow plumbing system.
    Description: Published
    Description: 795-813
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Basalt ; Subvolcanic crystallization ; Dolerite ; Magmatic breccia ; Stromboli ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    Dynamics of 2004–2005 Mt. Etna effusive eruption as inferred from petrologic monitoring (2005)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: From early September to early November, during the 2004–2005 Mt. Etna effusive eruption, petrologic monitoring was enabled by near-vent sampling of erupting lava and onsite SEM-EDS capabilities at INGV-CT. Significant differences in composition and temperature of lava erupted from 2920–2620 m and 2820–2320 m vents, attest to variably evolved shallow magmatic conditions within a geometrically complex storage volume. The petrography and glass compositions of water-quenched samples indicate that the magma feeding the 2004–2005 activity was likely to have been stored in the shallow plumbing system during the 2000 and 2001 activity, where it experienced volatile loss and extensive crystallization. Both geophysical and petrologic data suggest that this eruption was not triggered by the intrusion of a new dike from depth, but it was more likely that existing shallow magma reservoirs were passively mobilized and erupted in response to edifice deformation.
    Description: Published
    Description: 1-5
    Description: partially_open
    Keywords: Mineralogy and Petrology: Petrography, microstructures, and textures ; Mineralogy and Petrology: Igneous petrology ; Volcanology: Eruption mechanisms and flow emplacement ; Volcanology: Volcano monitoring ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Thermal model of the Vesuvius magma chamber (2007)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: A thermal modeling of the Vesuvius is presented, based on its magmatic and volcanic history. A 2D numerical scheme has been developed to evaluate the heat transfer inside and around a magma body, the latent heat of crystallization and the inputs of magma from the asthenosphere to a crustal reservoir. Assuming a ratio 〉1 between velocities of magma ascending in the conduit and magma laterally displaced in the reservoir, the results indicate that, after 40 ka, the reservoir is vertically thermally zoned. As a consequence it hosts magma batches that can individually differentiate, mix and be contaminated by the crust, and produce the spectrum of isotopic compositions of the Vesuvian products. The thermal model reproduces the geothermal gradient and the brittle-ductile transition (250– 300 C) at 6 km of depth (the maximum depth of earthquake foci) only after 0.5–1 Ma, implying a long lived magma chamber below the volcano.
    Description: Published
    Description: L17302
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
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    The Campanian Ignimbrite (southern Italy) geochemical zoning: insight on the generation of a super-eruption from catastrophic differentiation and fast withdrawal (2007)
    Springer
    Details
    Publication Date: 2017-04-04
    Description: More than ca 100 km3 of nearly homogeneous crystal-poor phonolite and ca 100 km3 of slightly zoned trachyte were erupted 39 ka during the Campanian Ignimbrite super eruption, the most powerful in the Neapolitan area. Partition coefficient calculations, equilibrium mineral assemblages, glass compositions and texture were used to reconstruct compositional, thermal and pressure gradients in the pre-eruptive reservoir as well as timing and mechanisms of evolution towards magma chamber overpressure and eruption. Our petrologic data indicate that a wide sill-like trachytic magma chamber was active under the Campanian Plain at 2.5 kbar before CI eruption. Thermal exchange between high liquidus (1199 C) trachytic sill and cool country rocks caused intense undercooling, driving a catastrophic and fast (102 years) in situ fractional crystallization and crustal assimilation that produced a water oversaturated phonolitic cap and an overpressure in the chamber that triggered the super eruption. This process culminated in an abrupt reservoir opening and in a fast single-step high decompression. Sanidine phenocrysts crystal size distributions reveal high differentiation rate, thus suggesting that such a sill-like magmatic system is capable of evolving in a very short time and erupting suddenly with only short-term warning.
    Description: Published
    Description: On line First
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Super eruption ; Crystal size distribution ; Partition coefficients ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 7
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    Newly discovered submarine flank eruption at Stromboli volcano (Aeolian Islands, Italy) (2008)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: The NW submarine portion of Stromboli volcano has been investigated by deep-towed sidescan sonar, bathymetric surveys, video camera runs and dredging during two research cruises in 2002 and 2004. The surveys resulted in the identification of an extensive pillow lava field (106-107m3) at about 2300 m of water depth and 9 km from the shoreline of Stromboli Island. The pillow lavas have a unique composition that does not match any known subaerial product, although a limited affinity exists with those erupted during the Neostromboli eruptive cycle of the island (13–6 ka). This is the first finding of a submarine eruption on the northern side of Stromboli and improves the knowledge of its flank activity and volcanic hazards. This eruption is interpreted as marking the onset of a new volcanic cycle from the edifice periphery fed by a new, distinct magma mixed with traces of the previous magma that survived the emptying of the Neostromboli magma chamber.
    Description: Published
    Description: L16310
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli ; flank eruption ; pillow lava ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    D’ansite-(Mn), Na21Mn2+(SO4)10Cl3 and d’ansite-(Fe), Na21Fe2+(SO4)10Cl3, two new minerals from volcanic fumaroles (2013)
    The Mineralogical Society
    Details
    Publication Date: 2017-04-04
    Description: The new minerals d’ansite-(Mn), Na21Mn2+(SO4)10Cl3, and d’ansite-(Fe), Na21Fe2+(SO4)10Cl3, occur as encrustations in fumaroles at Vesuvius, Naples, Italy and La Fossa crater, Vulcano, Aeolian Islands, Italy, respectively. Both minerals are cubic and crystallize in space group I4¯ 3d. D’ansite-(Mn) forms colourless translucent tristetrahedral crystals up to 0.2 mm on edge; d’ansite-(Fe) forms aggregates of colourless to white complex isometric crystals of about the same size. Chemical analyses obtained by energy-dispersive spectrometry on an electron microprobe gave the following mean compositions: d’ansite-(Mn), Na2O 39.37, MnO 3.46, MgO 0.13, SO3 49.99, Cl 6.36, O=Cl 1.44, total 97.87 wt.%, c o r r e s p o n d i n g t o a n e m p i r i c a l f o r m u l a , on t h e ba s i s o f 43 a n i o n s , of Na20.61(Mn2+ 0.79Mg0.05)S0.84S10.13O40.09Cl2.91; and d’ansite-(Fe), Na2O 39.12, FeO 4.18, MgO 0.12, SO3 49.91, Cl 6.81, O=Cl 1.54, total 98.60 wt.%, corresponding to an empirical formula of Na20.42(Fe2+ 0.94Mg0.05)S0.99S10.08O39.89Cl3.11. The six strongest reflections in the X-ray powder diffraction pattern of d’ansite-(Fe) [listed as dobs(A˚) (I) (hkl)] are as follows: 2.807(100)(044), 2.570(37)(235), 1.714(29)(129), 3.384(27)(233), 3.113(26)(134), 2.108(15)(237). The unit-cell parameters obtained from single-crystal data are 15.9291(9) and 15.882(3) A ˚ for d’ansite-(Mn) and d’ansite-(Fe), respectively. The structure of both minerals was refined, using single-crystal diffraction data, to final R parameters of 0.0309 and 0.0336 on reflections with I 〉 2s(I). The structure contains three independent Na sites, one of which is partially occupied by Mn2+ or Fe2+, two independent sulfate anions and one chlorine site.
    Description: Published
    Description: 2773–2783
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: d’ansite-(Mn) ; d’ansite-(Fe) ; Vesuvius ; Vulcano Island ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    Rapid differentiation in a sill-like magma reservoir: a case study from the campi flegrei caldera (2012)
    Nature Publishing Group
    Details
    Publication Date: 2017-04-04
    Description: In recent decades, geophysical investigations have detected wide magma reservoirs beneath quiescent calderas. However, the discovery of partially melted horizons inside the crust is not sufficient to put constraints on capability of reservoirs to supply cataclysmic eruptions, which strictly depends on the chemical-physical properties of magmas (composition, viscosity, gas content etc.), and thus on their differentiation histories. In this study, by using geochemical, isotopic and textural records of rocks erupted from the high-risk Campi Flegrei caldera, we show that the alkaline magmas have evolved toward a critical state of explosive behaviour over a time span shorter than the repose time of most volcanic systems and that these magmas have risen rapidly toward the surface. Moreover, similar results on the depth and timescale of magma storage were previously obtained for the neighbouring Somma-Vesuvius volcano. This consistency suggests that there might be a unique long-lived magma pool beneath the whole Neapolitan area.
    Description: Published
    Description: article 712
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: N/A or not JCR
    Description: open
    Keywords: magma ; campi flegrei caldera ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Degassing, crystallization and eruption dynamics at Stromboli: trace element and lithium isotopic evidence from 2003 ashes (2011)
    Springer
    Details
    Publication Date: 2017-04-04
    Description: During its 1800-year-long persistent activity the Stromboli volcano has erupted a highly porphyritic (HP) volatile-poor scoriaceous magma and a low porphyritic (LP) volatile-rich pumiceous magma. The HP magma is erupted during normal Strombolian explosions and lava effusions, while the LP one is related to more energetic paroxysms. During the March–April 2003 explosive activity, Stromboli ejected two typologies of juvenile glassy ashes, namely highly vesicular LP shards and volatile-poor HP shards. Their textural and in situ chemical characteristics are used to unravel mutual relationships between HP and LP magmas, as well as magma dynamics within the shallow plumbing system. The mantle-normalized trace element patterns of both ash types show the typical arc-lava pattern; however, HP glasses possess incompatible element concentrations higher than LP glasses, along with Sr and Eu negative anomalies. HP shards are generally characterized by higher Li contents (to ~20 ppm) and lower δ7Li values (+1.2 to −3.8‰) with respect to LP shards (Li contents of 7–14 ppm and δ7Li ranging between +4.6 and +0.9‰). Fractional crystallization models based on major and trace element compositions, combined with a degassing model based on open-system Rayleigh distillation and on the assumption that melt/fluidDLi 〉 1, show that abundant (~30%) plagioclase precipitation and variable degrees of degassing can lead the more primitive LP magma to evolve toward a differentiated (isotopically lighter) HP magma ponding in the upper conduit and undergoing slow continuous degassing-induced crystallization. This study also evidences that in March 2003 Stromboli volcano poured out a small early volume of LP magma that traveled slower within the conduit with respect to later and larger volumes of fast ascending LP magma erupted during the April 5 paroxysm. The different ascent rates and cooling rates of the two LP magma batches (i.e., pre- and post-paroxysm) resulted in small, but detectable, differences in their chemical signatures. Finally, this study highlights the high potential of in situ investigations of juvenile glassy ashes in petrologic and geochemical monitoring the volcanic activity and of Li isotopes as tracers of degassing processes within the shallow plumbing system.
    Description: Published
    Description: 541-561
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli ; Volcanic ash ; Lithium isotopes ; Degassing-induced crystallization ; Petrologic monitoring ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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