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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (11)
  • 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis  (9)
  • ddc:551.9
  • AGU  (16)
  • Blackwell Publishing Ltd  (6)
  • American Chemical Society
  • American Physical Society
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  • 1
    Publication Date: 2020-11-12
    Description: Accepted for publication in Journal of Geophysical Research. Copyright (2010) American Geophysical Union.
    Description: Carbon dioxide (CO2) diffuse degassing structures (DDS) at Furnas Volcano (São Miguel Island, Azores) are mostly associated with the main fumarolic fields, evidence that CO2 soil degassing is the surface expression of rising steam from the hydrothermal system. Locations with anomalous CO2 flux are mainly controlled by tectonic structures oriented WNW-ESE and NW-SE and by the geomorphology of the volcano, as evidenced by several DDS located in depressed areas associated with crater margins. Hydrothermal soil CO2 emissions in Furnas volcano are estimated to be ~ 968 t d-1. Discrimination between biogenic and hydrothermal CO2 was determined using a 1 statistical approach and the carbon isotope composition of the CO2 efflux. Different sampling densities were used to evaluate uncertainty in the estimation of the total CO2 flux, and showed that a low density of points may not be adequate to quantify soil emanations from a relatively small DDS. Thermal energy release associated to diffuse degassing at Furnas caldera is about 118 MW (from an area of ~ 4.8 km2) based on the H2O/CO2 ratio in fumarolic gas. The DDS affect also Furnas and Ribeira Quente villages, which are located inside the caldera and in the south flank of the volcano, respectively. At these sites, 58% and 98% of the houses are built over hydrothermal CO2 emanations, and the populations are at risk due to potential high concentrations of CO2 accumulating inside the dwellings. Keywords: Soil diffuse degassing; soil CO2 flux; emission rates; Azores archipelago 2
    Description: Published
    Description: B12208
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: Soil CO2 emissions ; Furnas volcano ; volcano monitoring. ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2017-04-04
    Description: We modeled Pnl phases from several moderate magnitude earthquakes in the eastern Mediterranean to test methods and develop path calibrations for determining source parameters. The study region, which extends from the eastern part of the Hellenic arc to the eastern Anatolian fault, is dominated by moderate earthquakes that can produce significant damage. Our results are useful for analyzing regional seismicity as well as seismic hazard, because very few broadband seismic stations are available in the selected area. For the whole region we have obtained a single velocity model characterized by a 30 km thick crust, low upper mantle velocities and a very thin lid overlaying a distinct low velocity layer. Our preferred model proved quite reliable for determining focal mechanism and seismic moment across the entire range of selected paths. The source depth is also well constrained, especially for moderate earthquakes.
    Description: Published
    Description: N/A or not JCR
    Description: reserved
    Keywords: Body wave propagation ; earthquake parameters ; lithosphere ; upper-mantle ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: The Colli Albani is a Quaternary quiescent volcano, located a few kilometers southeast of Rome (Italy). During the past decade, seismic swarms, ground deformation, and gas emissions occurred in the southwestern part of the volcano, where the last phreatomagmatic eruptions (27 ka) developed, building up several coalescent craters. In the frame of a Dipartimento Protezione Civile – Istituto Nazionale di Geofisica e Vulcanologica project aimed at the definition and mitigation of volcanic hazard, a temporary array of seismic stations has been deployed on the volcano and surrounding areas. We present results obtained using receiver functions analysis for eight stations, located upon and around the volcanic edifice, and revealing how the built of the volcanic edifice influenced the prevolcanic structures. The stations show some common features: the Moho is almost flat and located at 23 km, in agreement with the thinning of the Thyrrenian crust. Also the presence of a shallow limestone layer is a stable feature under every station, with a variable thickness between 4 and 5 km. However, some features change from station to station, indicating a local complexity of the crustal structure: a shallow discontinuity dividing the Plio-Pleistocene sediments by the Meso-Cenozoic limestones, and a localized anisotropic layer, in the central part of the old structure, which points of the deformation of the limestones. Other two strongly anisotropic layers are detected under the stations in lower crust and upper mantle, with symmetry axis directions related to the evolution of the volcano complex.
    Description: Published
    Description: B09313
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Receiver Function ; Colli Albani ; crustal structure ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-04
    Description: More than 100 3 ~ e / 4i~soeto pe ratios were measured in CO,-dominated gas samples collected during the 1997-1 998 seismic crisis that shook the Umbria-Marche, Central Apennines, Italy. Although the gas emissions were located in a typical "crustal" environment the measured values delineate variable mixing proportions between mantle-derived and crustal helium. During the monitoring period anomalous 3 ~ e P r~atieos were observed, together with a significant increase of fluid outflows. The observed 3 ~ e Pa~noema lies appear to be driven by stress-induced crustal deformations affecting micro-fracturing and bulk permeability and, in turn, by a seismogenic-induced modification of the crustal permeability of rocks. Since crustal deformations can also occur aseismically, the geochemical anomalies must be considered indicators of processes occurring below the surface, which could eventually help to estimate the probability increase of an impending earthquake, instead of pure empirical precursors.
    Description: Published
    Description: 839-842
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: helium ; earthquakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 5
    Publication Date: 2017-04-04
    Description: We present results from a teleseismic receiver-function study of the crustal structure in the central Apennines (Italy). Data from fifteen stations deployed in a linear transect running along the N42 degree parallel were used for the analysis. A total number of 364 receiver functions were analyzed. The crustal structure has been investigated using the neighborhood algorithm inversion scheme proposed by Sambridge [1999a], obtaining crustal thicknesses, bulk crustal VP/VS ratio and velocity-depth models. In each inversion, the degree of constraint of the different parameters has been appraised by the Bayesian inference algorithm by Sambridge [1999b]. The study region is characterized by crustal complexities and intense tectonic activity (recent volcanism, orogenesis, active extensional processes), and these complexities are reflected in the receiver functions. However, the relatively close spacing among the seismometers (about 20 km) helped us in the reconstruction of the crustal structure and Moho geometry along the transect. Crossing the Apennines from west to east, the Moho depth varies by more than 20 km, going from a relatively shallow depth (around 20 km) on the Tyrrhenian side, deepening down to about 45 km depth beneath the external front of the Apenninic orogen, and rising up again to about 30 km depth in correspondence of the Adriatic foreland. Despite the strong variability of the crustal thickness, the average crustal VS values show little variation along the transect, fluctuating around 3 km/s. The average VP values obtained from the VS and VP /VS are generally lower than 6 km/s.
    Description: Published
    Description: B12306
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: open
    Keywords: Crustal structure ; Receiver Function ; central Apennines ; Moho ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 6
    Publication Date: 2017-04-04
    Description: Geodynamic evolution of southern Italy can be understood within the framework of the Mediterranean- Alpine System. Subduction of a plate along the Sicily- Calabrian forearc under the Tyrrhenian Sea has been suggested by many geophysicists, although it is not yet confirmed and remains somewhat controversial. Helium isotope ratios provide useful information on the geotectonic structure of the region. We report here the 3He/4He ratios of terrestrial gas samples from southern Italy. The observed 3He/4He ratios are relatively high in the Eolian volcanic arc region and low in the other areas. Dichotomous explanations are presented. Firstly volcanic arc-forearc hypothesis suggests the subduction along the Sicily-Calabrian forearc. Secondly horizontal transport hypothesis is described based on the relationship between the ratios and radial distance from the recent spreading basin in Southern Tyrrhenian Sea.
    Description: Published
    Description: 511-514
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: helium isotopes ; tectonics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 7
    Publication Date: 2012-02-03
    Description: A station (FAGN) installed on a segment of the fault system that generated the April 2009 L’Aquila earthquakes shows larger ground motions compared to nearby stations. Spectral ratios using 304 earthquakes result in a station amplification significantly varying event by event in the frequency band 1–8 Hz. The resulting pattern of amplitude dependence on causative earthquake location reveals that the strongest (up to a factor of 10) amplifications occur for tightly clustered aftershocks aligned with the fault dip beneath FAGN thus indicating a fault‐guided effect. Fault models are investigated in a grid‐search approach by varying velocity, Q, width and depth of the fault zone. Although the problem solution is not unique and there are strong trade‐offs among the model parameters, constraints from observations yield a deep trapping structure model where the most likely values of velocity reduction, Q and damage zone width are 25%, 20, and 280 m, respectively.
    Description: Published
    Description: L24305
    Description: 3.1. Fisica dei terremoti
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: reserved
    Keywords: L'Aquila earthquake ; fault zone ; trapped waves ; site amplification ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2017-04-04
    Description: On 10 September 2005 at 1711 LT (1511 UT) a loud boom was heard on the Ischia island. A clear seismic signal was also recorded by the seismic monitoring network of the Neapolitan volcanic areas (Ischia, Campi Flegrei, and Mount Vesuvius) and on a regional station (Mount Massico). On the basis of the seismic recordings and on acoustic phenomena reports, we relate this event to the atmospheric explosion (airburst) of a bolide about 15 km SW of Ischia at an elevation of about 11.5 km. The location has been obtained through nonlinear traveltime inversion in a realistic atmospheric model including wind effects. We show, using statistical estimators, how the traveltime pattern is due to both atmospheric winds and the bolide trajectory. Using the same reasoning we discard a human origin (supersonic jet or sea-air missile). In addition, we also propose a new algorithm for fast acoustic traveltime computation for a supersonic moving source.
    Description: Published
    Description: B10307
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2017-04-04
    Description: This paper presents the results of hydrogeochemical and seismological studies carried out at Mt. Vesuvius during the period June 1998 – December 2005. Hydrogeochemical data show the occurrence of slowly varying long-term variations in the total dissolved salts and bicarbonate contents of the groundwaters, accompanied by a general decline in water temperatures. The temporal distributions of air temperature and rainfall in the Vesuvius area suggest that these variations do not depend on changes in the hydrological regime. The changes in the geochemical parameters are accompanied by slight variations in both the seismicity rate and energy release. A further relationship between seismic activity and fluid discharge rate is highlighted by a particular episode that occurred in August 2005, when a soil thermal anomaly was observed a few weeks before the occurrence of a very shallow earthquake. Moment-tensor analysis of this earthquake suggests that the most plausible source mechanism is a shear faulting combined with the opening of tensile crack. This feature is often observed in volcanic areas and it is usually related to fluid-/gas-driven rock fracturing. The observed seismological, hydrological, and geochemical temporal changes are interpreted not as changes of the volcanic system, but in terms of an external forcing as identified in the variation of the regional and local stress field acting on the volcano. This study has inferences onto the evaluation of the state of activity of volcanic systems and the eventual detection of unrest phenomena.
    Description: Published
    Description: B05206
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Vesuvius ; seismicity ; fluid circulation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 10
    Publication Date: 2017-04-04
    Description: During local and regional earthquakes, an evident amplification of horizontal ground motion is observed at two seismological stations near the Tremestieri fault, on the southeastern flank of Mt. Etna volcano. Rotated-component spectral ratios show a narrow spectral peak around 4-Hz along a N40°E direction. A conventional polarization analysis using the eigenvectors of the covariance matrix confirms the very stable directional effect enhancing the approximately NE-SW elongation of the horizontal ground motion in the fault zone. The effect is evident during the entire seismogram and independent of source backazimuth as well as distance and depth of earthquakes. The same polarization is observed in ambient noise as well. This consistency allowed us to use microtremors for checking ground motion polarization along and across the Tremestieri fault zone with a high spatial resolution. The result is a stable polarization of horizontal motion in the entire area, interesting a broad frequency band. To check whether this ground motion property is recurrent and understand a possible relationship with fault strike, faulting style, or orientation of fractures, ambient noise was recorded on other mapped faults of the Mt. Etna area, the Moscarello, Acicatena and Pernicana faults. The latter, in particular, is characterized by different strike and faulting style. A systematic tendency of ambient noise to be polarized is found in all of the faults. A picture emerges where normal faults of the eastern flank show a E-W to NE-SW polarization that changes on the Pernicana fault, which develops approximately E-W and is characterized by a prevailing NW-SE to NS polarization. Directions of polarization were never parallel to the fault strike. Moreover, polarization persists too far away from the fault trace, excluding an effect limited to a narrow low velocity zone hosted between harder wall rocks. Both these observations rule out an interpretation in terms of fault-trapped waves. The cause of observed polarizations will be the subject of future studies. However, the consistency with recent results of velocity anisotropy in a part of the investigated area suggests a possible role of attenuation anisotropy on horizontal amplitude variations versus azimuth.
    Description: Published
    Description: B10306
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: open
    Keywords: polarization ; fault zones ; Etna volcano ; microtremors ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
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  • 11
    Publication Date: 2017-04-04
    Description: We report measurements of Hg, SO2, and halogens (HCl, HBr, HI) in volcanic gases from Masaya volcano, Nicaragua, and gaseous SO2 and halogens from Telica volcano, Nicaragua. Mercury measurements were made with a Lumex 915+ portable mercury vapor analyzer and gold traps, while halogens, CO2 and S species were monitored with a portable multi gas sensor and filter packs. Lumex Hg concentrations in the plume were consistently above background and ranged up to 350 ng/m3. Hg/SO2 mass ratios measured with the real-time instruments ranged from 1.1*10-7 to 3.5*10-5 (mean 2*10-5). Total gaseous mercury TGM)concentrations measured by gold trap ranged from 100 to 225 ng/m3. Reactive gaseous mercury accounted for 1% of TGM, while particulate mercury was 5% of the TGM. Field measurements of Masaya’s SO2 flux, combined with the Hg/SO2 ratio, indicate a Hg flux from Masaya of 7.2 Mg/a-1. At Masaya’s low temperature fumaroles, Hg/CO2 mass ratios were consistently around 2*10-8, lower than observed in the main vent (Hg/CO2 10-7). Low-temperature fumarole Hg fluxes from Masaya are insignificant (150 g a-1). Ratios of S, C and halogen species were also measured at Masaya and Telica volcanoes. CO2/SO2 ratios at Masaya ranged from 2.8 to 3.9, comparable to previously published values. At Masaya molar Br/SO2 was 3*10-4 and I/SO2 was 2*10-5, suggesting fluxes of 0.2–0.5 Mg HBr d-1 and 0.02–0.05 Mg HI d-1. At Telica the Br/SO2 ratio was also 3*10-4 and the I/SO2 ratio was 5.8*10-5, with corresponding fluxes of 0.2 Mg HBr d-1 and 0.06 Mg HI d-1. Gases at both volcanoes are enriched in I relative to Br and Cl, compared to gases from volcanoes elsewhere.
    Description: This work was funded by NERC grant NE/ C511180/1/.
    Description: Published
    Description: B06203
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mercury ; Halogen ; Volcanic emissions ; Masaya volcano ; Telica volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 12
    Publication Date: 2017-04-04
    Description: In this paper we achieve three goals: (1) We demonstrate that crack tips governed by friction laws, including slip weakening, rate- and state-dependent laws, and thermal pressurization of pore fluids, propagating at supershear speed have slip velocity functions with reduced high-frequency content compared to crack tips traveling at subshear speeds. This is demonstrated using a fully dynamic, spontaneous, three-dimensional earthquake model, in which we calculate fault slip velocity at nine points (locations) distributed along a quarter circle on the fault where the rupture is traveling at supershear speed in the inplane direction and subshear speed in the antiplane direction. This holds for a fault governed by the linear slip-weakening constitutive equation, by slip weakening with thermal pressurization of pore fluid, and by rate- and state-dependent laws with thermal pressurization. The same is also true even assuming a highly heterogeneous initial shear stress field on the fault. (2) Using isochrone theory, we derive a general expression for the spectral characteristics and geometric spreading of two pulses arising from supershear rupture, the well-known Mach wave, and a second lesser known pulse caused by rupture acceleration. (3) We demonstrate that the Mach cone amplification of high frequencies overwhelms the de-amplification of high-frequency content in the slip velocity functions in supershear ruptures. Consequently, when earthquake ruptures travel at supershear speed, a net enhancement of high-frequency radiation is expected, and the alleged ‘‘low’’ peak accelerations observed for the 2002 Denali and other large earthquakes are probably not caused by diminished high-frequency content in the slip velocity function, as has been speculated.
    Description: Published
    Description: B05304
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: supershear ruptures ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 13
    Publication Date: 2017-04-04
    Description: Most empirical studies on the decay of the rate of aftershock with time after a main shock assume the simple power law described by the modified Omori model (MOM). A couple of alternative models, also including an exponential decay at long times, have been proposed in the last decades: the modified stretched exponential (MSE) model and the band-limited power law (LPL). The first aim of this work is to discuss the functional properties of such models and the relations existing on their parameters. In particular, we derive, in term of common transcendental functions, the analytical integrals of the LPL and MSE rate functions, which are useful to simplify and speed up computations. We also define, as a function of the parameters of the LPL, two characteristic times tb and ta, which correspond approximately to the delay time c of the MOM and the exponential decay relaxation time t0 of the MSE, respectively. Hence, the MOM, the MSE, and the LPL models can be compared among each other in terms of the same set of four general parameters: (1) the power law exponent, (2) the initial delay time, (3) the exponential relaxation time (1 for the MOM), and (4) a normalization parameter, which can be related in some cases to the total number of potential aftershocks. A second aim of this paper is to test the ability of maximum likelihood methods to detecting the most appropriate decay model among alternatives. By the analysis of sequences simulated according to a MSE or a LPL we show that if the assumed exponential decay relaxation time is shorter than the time window over which the sequence is observed, the Akaike and Bayesian information criteria select correctly the true model (MSE or LPL). Conversely, when the relaxation time is definitely longer than the observing window, the information criteria usually prefer the MOM, but the maximum likelihood of the true model is higher, and if the data set of shocks is sufficiently large, the order of magnitude of the simulated characteristic time of the exponential decay can be estimated quite consistently. Hence, when analyzing real sequences, the possible emergence of the exponential decay might be hidden by the short duration of the time window if the standard information criteria are considered. Moreover, when the relaxation time is short, the estimated power law exponent p for the MOM results definitely higher than that assumed in the simulation. This indicates that high values of p (〉1.5–2.0), sometimes observed in real sequences, might be due to the (not modeled) early startup of the negative exponential decay. Our analysis cannot decide which model is the most appropriate in describing the temporal behavior of aftershock rate after a main shock but suggests that the assumption of a model also including the exponential decay is generally preferable as it allows capture of all of the features of sequence decay.
    Description: Published
    Description: B01305
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: aftershock ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 14
    Publication Date: 2017-04-04
    Description: Shallow earthquakes occurring in the southern part of the Tyrrhenian basin excite a long-duration low-frequency coda that propagates efficiently along paths crossing the Tyrrhenian Sea. Seismograms recorded at regional distances in the Italian peninsula are analysed in the frequency-time domain and compared with synthetics computed in simple vertically varying media. Based on results of our modeling, we interpret the coda as short-period (5-10 s) suboceanic Rayleigh waves. Their large amplitude and long duration, that we emphasize here, are explained as due to the influence of the Tyrrhenian water layer over a fast seafloor with little S-wave attenuation (QS〉 300). A satisfactory fit of amplitude and duration of the observed waveforms is obtained assuming a young oceanic model with an average water column of 1 to 2 km and relatively high S-wave velocity (2.5 km/s) in the shallow crust.
    Description: Published
    Description: L22605
    Description: JCR Journal
    Description: reserved
    Keywords: suboceanic Rayleigh waves ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 15
    Publication Date: 2017-04-04
    Description: Several gas emissions, distributed along 200 km of the Southern Apennine axial zone, have been investigated. This portion of the sedimentary chain, which constitutes the accretionary prism of the westward subduction of the Adriatic plate, is subjected to a tensile stress field responsible of high-magnitude earthquakes. The studied emissions are generally CO2-dominated, have 3He/4He ratios in the range of 0.09-2.84 Ra, and display both 3He and 4He outputs in the range of those reported for the Italian active volcanoes Phlegrean Fields and Vulcano. The helium isotope ratios, together with the amount of released gas, indicate that a huge amount of mantle-derived helium is released over all the investigated area. Our geochemical data and the geophysical peculiarities of the region, such as the high heat flow and the low resistivity of rocks below a depth of 15 km, coherently indicate the presence of melt intruded into the crust along lithospheric faults. Magma intrusions along the axial part of the Southern Apennine sedimentary chain are certainly unusual, since volcanism in Central and Southern Italy is concentrated along the perityrrhenian margin of the peninsula. We suggest that melt is promoted by adiabatic uprise of the asthenosphere in the mantle wedge beneath the Apennines and it is subsequently intruded along tensile lithospheric faults, strongly affecting the thermal state of the lower crust. An inter-relation between the geodynamics, the melt intrusions and the genesis of the large earthquakes (up to M = 7.1) in the region is suggested.
    Description: Published
    Description: 13569-13578
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: melt intrusions ; gas geochemistry ; tectonic structures ; seismicity ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 16
    Publication Date: 2017-04-04
    Description: Despite the advance in our understanding of the carbon exchange between terrestrial ecosystems and the atmosphere, semiarid ecosystems have been poorly investigated and little is known about their role in the global carbon balance. We used eddy covariance measurements to determine the exchange of CO2 between a semiarid steppe and the atmosphere over 3 years. The vegetation is a perennial grassland of Stipa tenacissima L. located in the SE of Spain. We examined diurnal, seasonal and interannual variations in the net ecosystem carbon balance (NECB) in relation to biophysical variables. Cumulative NECB was a net source of 65.7, 143.6 and 92.1 g C mˉ2 yrˉ1 for the 3 years studied, respectively. We separated the year into two distinctive periods: dry period and growing season. The ecosystem was a net source of CO2 to the atmosphere, particularly during the dry period when large CO2 positive fluxes of up to 15 μmol mˉ2 sˉ1 were observed in concomitance with large wind speeds. Over the growing season, the ecosystem was a slight sink or neutral with maximum rates of -2.3 μmol mˉ2 sˉ1. Rainfall events caused large fluxes of CO2 to the atmosphere and determined the length of the growing season. In this season, photosynthetic photon flux density controlled day-time NECB just below 1000 μmol mˉ2 sˉ1. The analyses of the diurnal and seasonal data and preliminary geological and gas-geochemical evaluations, including C isotopic analyses, suggest that the CO2 released was not only biogenic but most likely included a component of geothermal origin, presumably related to deep fluids occurring in the area. These results highlight the importance of considering geological carbon sources, as well as the need to carefully interpret the results of eddy covariance partitioning techniques when applied in geologically active areas potentially affected by CO2-rich geofluid circulation.
    Description: Published
    Description: 539–554
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: alpha grass ; carbon sequestration ; ecosystem respiration ; eddy covariance ; geogas ; geothermal activity ; grasslands ; net ecosystem carbon balance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 17
    Publication Date: 2017-04-04
    Description: We report here on the first hydrogen determinations in the volcanic gas plume of Mount Etna, in Italy, which we obtained during periodic field surveys on the volcano’s summit area with an upgraded MultiGAS. Using a specific (EZT3HYT) electrochemical sensor, we resolved H2 concentrations in the plume of 1–3 ppm above ambient (background) atmosphere and derived H2‐SO2 and H2‐H2O plume molar ratios of 0.002–0.044 (mean 0.013) and 0.0001–0.0042 (mean 0.0018), respectively. Taking the above H2‐SO2 ratios in combination with a time‐averaged SO2 flux of 1600 Gg yr−1, we evaluate that Etna contributes a time‐averaged H2 flux of ∼0.65 Gg yr−1, suggesting that the volcanogenic contribution to the global atmospheric H2 budget (70,000–100,000 Gg yr−1) is marginal. We also use our observed H2‐H2O ratios to propose that Etna’s passive plume composition is (at least partially) representative of a quenched (temperatures between 750°C and 950°C) equilibrium in the gas‐magma system, at redox conditions close to the nickel‐nickel oxide (NNO) mineral buffer. The positive dependence between H2‐SO2, H2‐H2O, and CO2‐SO2 ratios suggests that H2 is likely supplied (at least in part) by deeply rising CO2‐rich gas bubbles, fluxing through a CO2‐depleted shallow conduit magma.
    Description: Published
    Description: B10204
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrogen ; Mount Etna ; Open-vent volcano ; plume ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 18
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 19
    Publication Date: 2017-04-04
    Description: This thematic issue of Geofluids includes 11 papers representing the three main topics discussed in the 10th edition of the International Conference on Gas Geochemistry (ICGG-10): (i) gas in petroleum systems and seepage, (ii) gas in geothermal systems and volcanoes and (iii) gas, seismicity and geohazards. ICGG-10 was held in 2009 in Romania, a country extraordinarily rich in surface gas manifestations, that offers innumerable opportunities for innovative studies on gas geochemistry. We briefly describe the present knowledge on gases occurring both in petroliferous sedimentary basins and geothermal areas of Romania. The 11 contributions of this special issue, which include data from eight countries, are then summarised. Based on these papers and other works presented at the ICGG-10, we find that significant advances in analytical capabilities, data treating and interpretation have led to innovative insights into the origin, distribution and environmental impact of gases migrating to the Earth’s surface. It is increasingly clear, in particular, that gas geochemistry can be more effective for petroleum exploration, volcano-tectonic, geodynamic and environmental studies, if multiparametric studies are performed and the data are interpreted in the geological context.
    Description: Published
    Description: 457-462
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; international conference on gas geochemistry ; natural gas ; romania ; seeps ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2022-04-01
    Description: Temperate forest soils are often considered as an important sink for atmospheric carbon (C), thereby buffering anthropogenic CO2 emissions. However, the effect of tree species composition on the magnitude of this sink is unclear. We resampled a tree species common garden experiment (six sites) a decade after initial sampling to evaluate whether forest floor (FF) and topsoil organic carbon (Corg) and total nitrogen (Nt) stocks changed in dependence of tree species (Norway spruce—Picea abies L., European beech—Fagus sylvatica L., pedunculate oak—Quercus robur L., sycamore maple—Acer pseudoplatanus L., European ash—Fraxinus excelsior L. and small‐leaved lime—Tilia cordata L.). Two groups of species were identified in terms of Corg and Nt distribution: (1) Spruce with high Corg and Nt stocks in the FF developed as a mor humus layer which tended to have smaller Corg and Nt stocks and a wider Corg:Nt ratio in the mineral topsoil, and (2) the broadleaved species, of which ash and maple distinguished most clearly from spruce by very low Corg and Nt stocks in the FF developed as mull humus layer, had greater Corg and Nt stocks, and narrow Corg:Nt ratios in the mineral topsoil. Over 11 years, FF Corg and Nt stocks increased most under spruce, while small decreases in bulk mineral soil (esp. in 0–15 cm and 0–30 cm depth) Corg and Nt stocks dominated irrespective of species. Observed decadal changes were associated with site‐related and tree species‐mediated soil properties in a way that hinted towards short‐term accumulation and mineralisation dynamics of easily available organic substances. We found no indication for Corg stabilisation. However, results indicated increasing Nt stabilisation with increasing biomass of burrowing earthworms, which were highest under ash, lime and maple and lowest under spruce. Highlights We studied if tree species differences in topsoil Corg and Nt stocks substantiate after a decade. The study is unique in its repeated soil sampling in a multisite common garden experiment. Forest floors increased under spruce, but topsoil stocks decreased irrespective of species. Changes were of short‐term nature. Nitrogen was most stable under arbuscular mycorrhizal species.
    Description: Deutsche Forschungsgemeinschaff (DFG)
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
    Type: doc-type:article
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  • 21
    Publication Date: 2017-04-04
    Description: Natural gas seeps in the Alpine region are poorly investigated. However, they can provide useful information regarding the hydrocarbon potential of sedimentary Alpine units and related geofluid migration, typically controlled by pressurized gas accumulations and tectonics. A gas seep located near Giswil, in the Swiss Northern Alps, was investigated, for the first time, for molecular and isotopic gas composition, methane flux to the atmosphere, and gas flux variations over time. The analyses indicated that the gas was thermogenic (CH4 〉 96%; d13C1: )35.5& to )40.2&) and showed evidence of subsurface petroleum biodegradation (13C-enriched CO2, and very low C3+ concentrations). The source rock in the region is marine Type II kerogen, which is likely the same as that providing thermogenic gas in the nearby Wilen shallow well, close to Lake Sarnen. However, the lack of d13CCO2 and d13C3 data for that well prevented us from determining whether the Wilen and Giswil seeps are fed by the same reservoir and seepage system. Gas fluxes from the Giswil seep, measured using a closedchamber system, were significant and mainly from two major vents. However, a substantial gas exhalation from the soil occurs diffusely in an area of at least 115 m2, leading to a total CH4 output conservatively estimated to be at least 16 tonnes per year. Gas flux variations, monitored over a 1-month period by a special tent and flowmeter, showed not only daily meteorological oscillations, but also an intrinsic ‘pulsation’ with periods of enhanced flux that lasted 2–6 h each, occurring every few days. The pulses are likely related to episodes of gas pressure build-up and discharge along the seepage system. However, to date, no relationship to seismicity in the active Sarnen strike-slip fault system has been established.
    Description: Published
    Description: 476-485
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Alps ; isotopes ; methane ; organic geochemistry ; seeps ; Switzerland ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 22
    Publication Date: 2022-09-27
    Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.
    Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.9 ; ddc:551.49
    Language: English
    Type: doc-type:article
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