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  • General Chemistry  (77,716)
  • 550 - Earth sciences
  • Wiley-Blackwell  (77,716)
  • GeoForschungsZentrum GFZ  (5)
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  • 1
    Publication Date: 2022-11-14
    Keywords: 550 - Earth sciences
    Language: German , English
    Type: info:eu-repo/semantics/report
    Format: application/pdf
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  • 2
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    GeoForschungsZentrum GFZ
    In:  Scientific Technical Report STR
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Language: German
    Type: info:eu-repo/semantics/doctoralThesis
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  • 3
    Publication Date: 2020-02-12
    Description: Die Ergebnisse der Untersuchungen im Rahmen des DFG-Projekts erweitern und verbessern die bisherige Kenntnis über den rezenten Spannungszustand von Mitteleuropa. Die Meßergebnisse vom Raum Sachsen-Thüringen als Teil des Grenzgebietes Böhmisches Massiv gegen das südwestliche Vorland beruhen auf oberflächennahen in-situ-Messungen. Obwohl sie nur die Spannungsverteilung der obersten Kruste wiederspiegeln, ergeben sie ein interpretierbares Bild. Trotz ermittelter Variabilität der Spannungsrichtungen und - Intensitäten ist eine Geologie-relevante Felderung in Gebiete mit relativ homogenen Spannungsrichtungen erkennbar. In-situ-Spannungsmessungen sind offenbar trotz aller Einschränkungen, die den Autoren bewußt sind, geeignet, das unterschiedliche rezente Verhalten geologischer Strukturen zu ermitteln. Nachweisbar ist der Einfluß rezent aktiver regionaler Störungszonen auf das Spannungsfeld: Gestützt wird die Aussagefähigkeit der Meßdaten durch zahlreiche Ergebnisse anderer Autoren (und Methoden), mit denen sie in der Regel übereinstimmen.
    Keywords: 550 - Earth sciences
    Language: German
    Type: info:eu-repo/semantics/report
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  • 4
    Publication Date: 2020-02-12
    Description: Within a few years after the German reunification, most open pit lignite mines in the Central German Lignite Mining District have been shut down leaving more than 200km2 of devastated land in Saxony (Germany) even now. These areas are in demand of short term conceptions for future landuse and suitable recultivation methods. This thesis investigates, how thermal infrared (TIR) remote sensing in particular can provide valuable information, which is required to assist the landuse planning in identifying and classifying critical areas. In order to establish the mining of the lignitic seams the overburden Quatemary and Tertiary sediments had been removed and dumped in conveyor bridge dumps. The Tertiary sediments contain the mineral pyrite, which reacts to sulfuric acid under wet oxidizing conditions. The acidification of the dumps is not only strongly affecting the chemical characteristics of groundwater and residual lakes but also the stability of slopes leaving the risk of slides and subsidences. For a risk assessment of the aff~cted areas the geochemical and mineralogical composition as well as compositional changes of the dumps have to be explored. This is giving strong motivation for the application of remote sensing methods to answer the short term demands of landuse planners. Hyperspectral scanner data were acquired over two open pits (Espenhain, Zwenkau). The used scanner is DLR's Digital Airbome Imaging Spectrometer (DAIS 7915) which records data in 79 bands from the visible to thermal infrared. To allow a quantitative approach by means of empirical methods, the airbome data had to undergo a number of correction procedures and accompanying ground truth measurements had to be carried out. For a quantitative analysis of the target area, the data were calibrated and atmospherically corrected. Atmospheric modeling is based on the software packages SENSAT and ATCOR using the MODTRAN code. Interna! distortions of the imagery were corrected from flight attitude information and the data were finally geocoded to Gauß-Krüger-coordinates. A total of 77 field sarnples were taken to develop quantification algorithms based on spectral characteristics. Chemical and mineralogical analyses (GFZ Potsdam) as well as thermal infrared laboratory spectrometry (2.5-14μm) were performed. The samples were found tobe mainly composed of quartz (50-90 weigth percent), alkaline feldspars (5-20 wt.% ), kaolinite (0-15 wt.%), illite (2-20 wt.%) and pyrite (0-4 wt.%). In the TIR, many rock-forming minerals (e.g. silicates) show characteristic spectral features. To investigate the influence of different grain sizes on the spectral behavior, the particulate material was ground to grain sizes 〈63μm. Both, the fine homogenized and the original dump sediments were measured. The mineralogical quantitative sarnple composition was correlated with the spectral features measured in the laboratory. Different approaches were investigated to quantify the rnineralogical composition including absorption band depths and spectral angle mapping (SAM). The analysis in the laboratory allowed a determination of kaolinite and quartz contents of the overburden dumps. By transferring the regressions obtained from laboratory spectroscopy to atmospherically corrected and calibrated DAIS 7915 data, quartz contents were successfully mapped. Due to the broad TIR bands of DAIS, the spectral features of kaolinite were not resolved in the airbome data. A temperature map derived from night-time DAIS thermal infrared data were evaluated with respect to exothermic pyrite oxidation, too. The fresh Tertiary dumps in Zwenkau show thermal anomalies which seem to be related to exothermic oxidation processes. As a final outlook, the potential of the ASTER sensor, which is planned to be launched in early 1999, was evaluated. The TIR bands of ASTER are likely tobe a powerful tool for the mapping of quartz contents of particulate material. However, the low geometric resolution in the thermal infrared (90m pixel size) causes limitations for a structural analysis. Therefore, the Multi-Sensor-Multi-Resolution Technique (MMT) was used to unmix the low resolution bands using the higher resolution reflective ASTER bands (15-30m pixel size). The results show a significant improvement of the images. The MMT algorithm allows a further spectral investigation of the unmixed TIR data. The results presented in this work show that remote sensing data can provide useful information for a quantitative assessment and monitoring of environmental impacts. The combined use of the wavelength region from the VIS to TIR produces characteristic features that allow a differentiation of the mineralogical components, which could not have been achieved with either data set separately.
    Keywords: 550 - Earth sciences
    Language: German
    Type: info:eu-repo/semantics/doctoralThesis
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  • 5
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    GeoForschungsZentrum GFZ
    In:  Scientific Technical Report STR
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Language: English
    Type: info:eu-repo/semantics/report
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  • 6
    ISSN: 1434-193X
    Keywords: Photocycloaddition ; Ring opening ; Oxetanes ; 1,2-Diols ; Alkyldealkoxylation ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The ring opening of 3-isopropyl-2-phenyl-3-oxetanol (2a) by various nucleophiles has been studied. In the presence of BF3 as a Lewis acid, a clean reaction at the less substituted C-4 position was observed and the corresponding 1,2-diols 6-11 and 21-23 were isolated in diastereomerically pure form (47-97% yield). Alkyl-, aryl-, alkynyl- and alkenyllithium compounds proved to be suitable carbon nucleophiles. Deprotonated thiols were used as sulfur nucleophiles. An alkoxide derived from benzyl alcohol and an amide derived from benzylamine reacted less readily under these conditions, yielding the 1,2,3-trifunctional compounds 24 (42% yield) and 26 (54% yield). Other 2-phenyl-3-oxetanols such as 2b and 2c can also be employed as electrophiles, whereas 2-anisyl derivatives preferentially undergo rearrangement reactions, as exemplified by the conversion of oxetane 16 to the hydroxy ketone 17 (84% yield). The superior behaviour of 3-oxetanols as compared to their silyl derivatives in reactions with nucleophiles became evident from the reaction of 3-silyloxyoxetane 1a with alkyllithium reagents. A β elimination occurred upon treatment with nBuLi, which, after pericyclic ring opening and addition of nBuLi, yielded the allylic alcohol 20.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1434-193X
    Keywords: Azoalkanes ; DBO ; Fluorescence quenching ; Exciplexes ; Hydrogen transfer ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fluorescence of the DBO derivatives 1-3 is efficiently quenched by olefins and arenes, exciplex formation and hydrogen transfer operate as quenching mechanisms. The electron-accepting ester groups in the azoalkanes 1-3 promote significantly more effective quenching compared to the parent DBO. Steric hindrance accounts for the differences in the quenching efficiencies, but electronic effects dominate
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1434-193X
    Keywords: Mannich bases ; γ-Amino alcohols ; Grob fragmentation ; (Z)-Alkenes ; Oxetanes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quaternized γ-amino alcohols 5 derived from ternary iminium salts 2 are stereospecifically converted into both unsaturated aldehydes/ketones 6 with a (Z)-C—C double bond in a Grob-type fragmentation and highly functionalized oxetanes 7 by intramolecular substitution.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2201-2207 
    ISSN: 1434-193X
    Keywords: Antibiotics ; Asymmetric synthesis ; β-Lactams ; Michael additions ; Multicomponent reactions ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Lithium dialkylcuprates react either in a sequential one-pot or in a domino “three-component” fashion with chiral Michael acceptors, like Oppolzer's N-enoyl-2,10-camphorsultams 7 and 11 or ‘Evans’ N-enoyl-4-phenyl-1,3-oxazolidin-2-ones 8 and 13, and N-(methoxycarbonylmethylidene)(4-methoxyphenyl)amine 9 to afford the corresponding cis-3-alkyl-4-methoxycarbonyl-1-(4-methoxyphenyl)azetidin-2-ones 10, 14-15 in overall yields of 40-67% and enantiomeric excesses of 91-99%.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2229-2235 
    ISSN: 1434-193X
    Keywords: 3-Nitro-ω-benzylideneacetophenone ; Carbanions ; Michael addition ; Intramolecular vicarious nucleophilic substitution of hydrogen ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-Nitro-ω-benzylideneacetophenone (1) reacts with carbanions containing leaving groups to give addition products to the electrophilic side chain. As a result of conjugated addition and subsequent intramolecular vicarious nucleophilic substitution of hydrogen (VNS) in the nitroaromatic ring of 1 in the position para to the nitro group, 4-cyano-7-nitro-3-phenyl-1,2,3,4-tetrahydronaphthalen-1-one and 4-cyano-7-nitro-3-phenylnaphth-1-ol are obtained. Smooth intramolecular VNS in the position para to the nitro group was observed for 4-chloro-1-(3-nitrophenyl)-3-phenyl-4-(p-tosyl)butanol.
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