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  • 1
    Publication Date: 2022-06-09
    Description: Near-continuous monitoring both of gas emissions (CO2, CH4 and H2S) and of water temperature at Santa Venera al Pozzo thermal springs (SE foot of Mt. Etna volcano, Sicily, Italy) was conducted from December 2017 to April 2019, using a novel and cheaper Chromatography Monitoring System (CMS) coupled with a water temperature sensor. The results showed methane as predominant gas and temporal changes in gas concentrations that were in part due to daily fluctuations, which caused small amplitude variations, and in part due to non-environmental causes. These latter were correlated with the occurrence of strong earthquakes and slow tectonic events related to magmatic intrusions, but not with input of magmatic gases into the thermal aquifer, given the nonmagmatic origin of all monitored gases. Methane spikes were observed during many volcano-tectonic events and call for a deep source of this gas. H2S was detected only during the strongest local tectonic events, including a Mw 4.9 earthquake, suggesting that this gas has a common origin as CH4 (i.e., mixing between microbial and thermogenic gas), but it is released only when tectonic stress is applied for sufficiently long periods as to cause H2S oversaturation in the hydrothermal aquifer. Water temperature decreases were also observed immediately after the two strongest earthquakes in the area, which helped us produce a comprehensive model to explain the observed geochemical variations. Our approach allowed revealing the great sensitivity of gases such as CH4 and especially H2S to tectonic stress, thus making them valuable indicators of impending strong tectonic or volcanotectonic events.
    Description: Published
    Description: 229388
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Earthquakes ; Volcanic activity ; Geothermal systems ; Fluids ; Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: The first geochemical data showing the existence of an active degassing activity over a large seismically active sector of the Southern Alps (Friuli Region, NE Italy) are presented. The dissolved gases, helium and carbon isotopic systematics of 46 water samples taken from 13 sites running along E–W and NE–SW faults besides the natural degassing of a 5000 km2 wide area are investigated. The chemical composition of the dissolved gases revealed that a CO2-rich gas phase feeds the local groundwaters. 3He/4He ratios (R) normalized to the atmospheric 3He/4He ratio (Ra=1.39×10−6) and corrected for the atmospheric contamination (R/Rac), range from 0.29 to 1 as a result of a two component (radiogenic and atmospheric) mixing. The δ13C values of total dissolved inorganic carbon (TDIC) ranging from −15.28 to −0.75‰ vs. PDB, show the occurrence of multiple gas–water interactions. The mixing between the atmospheric air and a crustal source and the gas–water interactions occurring at various extents appears to be the main control on the observed He–C systematics. The natural CO2 degassing was evaluated by a soil gas survey carried out by a grid of about 100 measuring sites located over the area that generated destructive seismic sequences (e.g. the Gemona sequence of 1976; main shocks M6.4 of 6th May and M6.1 of 11th and 15th September). The results obtained show that a significant amount of crustal-originated gases are released over the continental area of Eastern Southern Alps. The evidence that carbon dioxide is associated with radiogenic-type helium denotes the lack of the mantle as primary energy and degassing source, highlighting the possibility that CO2 is produced by thermo-mechanical processes occurring at seismogenic depth. The information provided here may be used to start up a long-term geochemical monitoring of this seismically active area and could be able to detect the modifications occurring to the circulating fluids to gain a better insight on the relationships between the fluids' geochemistry and the activity of the local seismogenic faults.
    Description: Published
    Description: 76–85
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Fluids ; Faults ; geochemistry ; isotopes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: The Miano borehole of 1047 m depth is located close to the river Parma in the Northern Apennines, Italy. A measuring station is installed to observe the discharge of fluids continuously since November 2004. The upwelling fluid of this artesian well is a mixture of thermal water and methane as main components. In non-seismogenic areas, we would expect a relative constant fluid emission perhaps overlaid with long term variations from that kind of deep reservoirs during the time. However, the continuously record of the fluid emission, in particular the water discharge, the gas flow rate and the water temperature, show periods of stable values interrupted by anomalous periods of fluctuations in the recorded parameters. The anomalous variations of these parameters are of low amplitude in comparison to the total values but significant in their long-term trend. Meteorological influences of rain and barometric pressure were not detected in recorded data probably due to reservoir depth and relatively high reservoir overpressure. Influences due to the ambient temperature after the discharge were evaluated by statistical analysis. We consider that recorded changes in fluid emission parameters can be interpreted as a mixing process of different fluid components in depth by variations in pore pressure as result of seismogenic stress variation. Local seismicity was analyzed in comparison to fluid’s physico-chemical data. The analysis supports the idea of an influence to fluid transport conditions due to geodynamic processes exist. Water temperature data show frequent anomalies probably connected with possible precursory phenomena of local seismic events.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids ; Earthquakes ; Continous monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: The first comprehensive geochemical data-set of the fluids circulating over a 14,000 km2-wide seismicprone area of the Southern Apennines, Calabria Region (Italy), is presented here. The geochemical investigations were carried out with the twofold aim of constraining the origin and interactions of the circulating fluids and to investigate possible relationships with local faults. Sixty samples of both thermal and cold waters were collected, from which the dissolved gases were extracted. The geochemical features of the water samples display different types and degrees of water–rock interactions, irrespective of the outlet temperature. The calculated equilibrium temperatures of the thermal waters (60–160 C) and the low heat flow of thewhole study area, are consistent with a heating process due to deep water circulation and rapid upflow through lithospheric structures. The composition of the dissolved gases reveals that crustal-originating gases (N2 and CO2-dominated) feed all the groundwaters. The 3He/4He ratios of the dissolved He, in the range of 0.03–0.22Rac for the thermal waters and 0.05–0.63Rac for the cold waters (Rac = He isotope ratio corrected for atmospheric contamination), are mainly the result of a two-component (radiogenic and atmospheric) mixing, although indications of mantle-derived He are found in some cold waters. As the study area had been hit by 18 of the most destructive earthquakes (magnitude ranging from 5.9 to 7.2) occurring over a 280-a time span (1626–1908) in the Southern Apennines, the reported results on the circulating fluids may represent the reference for a better inside knowledge of the fault-fluid relationships and for the development of long-term geochemical monitoring strategies for the area.
    Description: Published
    Description: 540–554
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids ; Geochemistry ; Faults ; Seismicity ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: The Miano borehole, 1047 m deep, is located close to the river Parma in the Northern Apennines, Italy. A measuring station has been installed to observe the discharge of fluids continuously since November 2004. The upwelling fluid of this artesian well is a mixture of thermal water and CH4 as main components. In non-seismogenic areas, a relatively constant fluid emission would be expected, perhaps overlaid with long term variations from that kind of deep reservoir over time. However, the continuous record of the fluid emission, in particular the water discharge, the gas flow rate and the water temperature, show periods of stable values interrupted by anomalous periods of fluctuations in the recorded parameters. The anomalous variations of these parameters are of low amplitude in comparison to the total values but significant in their long-term trend. Meteorological effects due to rain and barometric pressure were not detected in recorded data probably due to reservoir depth and relatively high reservoir overpressure. Influences due to the ambient temperature after the discharge were evaluated by statistical analysis. Our results suggest that recorded changes in fluid emission parameters can be interpreted as a mixing process of different fluid components at depth by variations in pore pressure as a result of seismogenic stress variation. Local seismicity was analyzed in comparison to the fluid physico-chemical data. The analysis supports the idea that an influence on fluid transport conditions due to geodynamic processes exists. Water temperature data show frequent anomalies probably connected with possible precursory phenomena of local seismic events.
    Description: Published
    Description: 555–571
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids ; Seismicity ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
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    Elsevier
    In:  Amsterdam, 528 pp., Elsevier, vol. 32, no. XVI:, pp. 227-235, (ISBN 0231-12739-1 hb, 0231127383 pb)
    Publication Date: 2000
    Keywords: Seismics (controlled source seismology) ; Applied geophysics ; Wave propagation ; Waves ; Acoustics ; Fluids ; Textbook of geophysics
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  • 7
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    Oxford Univ. Press
    In:  Oxford, Oxford Univ. Press, vol. 3, pp. 158, (ISBN 0-444-50968-2)
    Publication Date: 1964
    Keywords: Textbook of physics ; Friction ; Physical properties of rocks ; Fluids
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  • 8
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    Elsevier
    In:  Amsterdam, 530 pp., Elsevier, vol. 37, no. XVI:, pp. 227-235, (ISBN 0231-12739-1 hb, 0231127383 pb)
    Publication Date: 2002
    Keywords: Seismics (controlled source seismology) ; Applied geophysics ; Wave propagation ; Waves ; Textbook of geophysics ; Acoustics ; Fluids ; High frequency ... ; Kirchoff ; seismic Migration ; Layers ; Channel waves
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  • 9
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    Oxford Univ. Press
    In:  New York, 330 pp., Oxford Univ. Press, vol. 1, no. 1, pp. 65-66, (ISBN 0-19-850694-5)
    Publication Date: 2004
    Keywords: Textbook of physics ; critical ; phenomena, ; elementary ; particles, ; phase ; transitions, ; Ising
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  • 10
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 1, no. ALEX(01)-FR-77-01, AFTAC Contract F08606-76-C-0025, pp. 95-104, (ISBN 1-85312-745-0)
    Publication Date: 1998
    Keywords: Inversion ; Elasticity ; Geothermics ; Scattering ; soil ; Modelling ; Fluids ; Acoustics
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