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  • Polymer and Materials Science  (10,782)
  • 1970-1974  (10,782)
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Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 153-155 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 160-160 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 161-167 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Anodische Polarisation von Wolfram in neutralen und alkalischen Lösungen bei anodischem FilmwachstumDie anodische Polarisation von Wolfram wurde in neutralen (Na2SO4, 1 NaCl) und alkalischen Lösungen (Ammoniumborat, Na2CO3, Na3PO4, NaOH) galvanostatisch und unter Bedingungen untersucht, welche Deckschichtbildung an der Anode ermöglichen. Die Geschwindigkeit der Oxidschichtbildung wurde in Abhängigkeit von der Stromdichte sowie der Art und der Konzentration des Elektrolyten berechnet. In alkalischen Lösungen findet Deckschichtbildung bei Potentialen oberhalb 100 V statt, sofern mit verdünnten Lösungen und hoher Stromdichte gearbeitet wird. Aufgrund der Tatsache, daß die reziproke Kapazität und das Potential vom Logarithmus der Stromdichte abhängig sind, wird nachgewiesen, daß für diesen Fall die Ionenleitung im starken elektrischen Feld Gültigkeit hat. Abschließend werden Angaben zur Zunahme der Oxidschichtdicke mit dem Stromdurchgang, zu den Konstanten des Exponentialgesetzes und dem elektrischen Feld gemacht und der Zusammenbruch der Oxidschicht beschrieben.
    Notes: Anodic polarization of W has been studied in neutral (Na2SO4, NaCl) and alkaline solutions (ammonium borate, Na2CO3, Na3PO4, and NaOH) by the galvanostatic method under conditions which lead to anode film growth. The rate of oxide growth has been calculated as a function of current density, nature and concentration of electrolyte. Film growth to potentials above 100 V is achieved in alkaline solutions, provided the solution is dilute and the current density is high. The applicability of the high field ionic conduction has been verified from the dependence of both reciprocal capacity and potential on the logarithm of current density. Data are recorded for the coulometric increase of oxide thickness. The constants of the exponential law, and the electric field.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 186-187 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Green rust on brassIn the electrical circuit fo a car formation of patina was observed on a brass plate in contact with a copper wire. The products formed were identified as orthorombic \documentclass{article}\pagestyle{empty}\begin{document}$$ ({\rm Cu},{\rm Zn}){\rm SO}_4 \cdot 2({\rm Cu},{\rm Zn})({\rm OH})_2 $$\end{document} The sulfur-containing rubber sheath above the brass plate seems to be one of the causes of the formation of this corrosion product.
    Notes: Auf einem in Kontakt mit Kupferdraht stehenden Messingblech wurde im Stromkreis eines Automobils die Bildung von Patina beobachtet. Die dabei entstehenden Produkte wurden als orthorhombische \documentclass{article}\pagestyle{empty}\begin{document}$$ ({\rm Cu},{\rm Zn}){\rm SO}_4 \cdot 2({\rm Cu},{\rm Zn})({\rm OH})_2 $$\end{document} identifiziert. Eine der Ursachen für die Bildung dieses Korrosionsproduktes scheint der schwefelhaltige Gummimantel zu sein, unter dem sich das Messingblech befand.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 205-205 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 218-220 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 229-230 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. XII 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 247-254 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Taking account of corrosion in the design of chemical apparatusThe selection of materials is of prime importance in the design of chemical plant because it is necessary to take account, in addition to mechanical stresses, of corrosive influences, in particular where local corrosive attack is to be expected. When using dissimilar metals suitable measures must be taken to prevent contact corrosion. The design must be free from crevices as far as possible in order to avoid crevice corrosion. This requirement must be given due consideration in connection with weld design, too. Discharge devices must enable the plant to be completely emptied in order to prevent shutdown corrosion. Flow velocities must be limited in order to prevent any intensification of corrosion by turbulence, or to avoid erosion corrosion. Simultaneous mechanical stresses and corrosive attack must be taken account of at the design stage in order to prevent stress corrosion cracking and corrosion fatigue. suitable countermeasures include reduction of stress levels, avoiding stress peaks, mitigation of corrosive effects, utilization of more resistant materials, making use of suitable thermal treatments and using protective coatings. Feasible anti-corrosion design ist demonstrated on some construction details.
    Notes: Beim Entwurf von Chemieanlagen ist die Werkstoffwahl von besonderer Bedeutung, da neben den mechanischen Beanspruchungen auch die korrosiven Einflüsse beachtet werden müssen, insbesondere bei Gefahr lokaler Korrosionseinwirkung. Beim Zusammenbau verschiedener Metalle müssen Maßnahmen eingeplant werden, die eine Kontaktkorrosion verhindern. Die konstruktive Gestaltung soll weitgehend spaltfrei ausgeführt werden, um der Spaltkorrosion auszuweichen. Hierauf sind auch Art und Ausführung von Schweißnähten abzustimmen. Entleerungseinrichtungen müssen eine vollständige Entleerung der Apparate gestatten, damit Stillstandskorrosionen verhindert werden. Strömungsgeschwindigkeiten sind zu begrenzen, um eine Korrosionserhöhung durch Turbulenz oder auch durch Erosionskorrosion zu vermeiden. Bei mechanischer Beanspruchung und gleichzeitiger Korrosion sollten alle Möglichkeiten zur Verhinderung von Spannungsrißkorrosion und Schwingungsrißkorrosion schon bei der Gestaltung berücksichtigt werden. Hierzu gehören Niedrighaltung der Spannungen, Vermeidung von Spannungsspitzen, Milderung der Korrosionseinwirkung, Verwendung beständigerer Werkstoffe, Ausnutzung der Möglichkeit einer Wärmebehandlung und die Verwendung von Schutzüberzügen. An konstruktiven Gestalungsbeispielen werden Möglichkeiten der Korrosionsverhinderung gezeigt.
    Additional Material: 16 Ill.
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