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  • Wiley-Blackwell  (71,400)
  • 1985-1989  (52,677)
  • 1950-1954  (9,876)
  • 1935-1939  (8,847)
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  • 1
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    Wiley-Blackwell
    In:  Journal of Zoology, 214 (2). pp. 189-197.
    Publication Date: 2020-07-17
    Description: The cuttlefish ingests much skeleton from the crustaceans and fish it preys upon. The skeletal pieces are relatively large and their dimensions bear a close relationship to the length of the buccal mass and diameter of the oesophagus. The structures of the buccal mass are instrumental in the breakdown of prey and orientation of long pieces of skeleton to ensure their entry into the oesophagus. Many pieces of skeletal material present in the stomach contents still have attached muscles, showing that there is little, or no, external digestion. Skeletal material may be important for long-term maintenance of young Sepia in captivity.
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  • 2
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    Wiley-Blackwell
    In:  Journal of Zoology, 218 (4). pp. 603-608.
    Publication Date: 2020-07-17
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  • 3
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    Wiley-Blackwell
    In:  Marine Ecology, 8 . pp. 1-20.
    Publication Date: 2017-10-05
    Description: Benthic metabolism and standing stocks were investigated in the deep Red Sea between 21o and 27oN, Activity was assessed by the determination of respiration rates with a shipboard method and by calculating oxygen consumption from the activity in the electron transport system. We attempted to compare results from different latitudes within the warm Red Sea and with data from cold Atlantic environments. Our investigations were part of an environmental risk assessment to evaluate future mining of metalliferous sediments from the Atlantis II Deep.
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  • 4
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    Wiley-Blackwell
    In:  Journal of Zoology, 212 (2). pp. 303-324.
    Publication Date: 2020-07-17
    Description: The diet of the king penguin Aptenodytes patagonicus at Marion Island was examined throughout the year by analysis of stomach samples. Fish accounted for 87% by wet mass, 75% by numbers and 69% by reconstituted mass. Their proportional importance by wet mass increased from 68% during winter to almost 100% in summer and probably reflects a real increase in their local availability. Squid comprised most of the remainder with crustaceans forming less than 1% of the diet by numbers. Prey items were generally small, the most abundant being three species of myctophid fish, Krefftichthys anderssoni, Protomyctophum tenisonì and Electrona carlsbergi, and a squid Kondakovia longimana. King penguins took both juvenile and adult Krefftichthys anderssoni and P. tenisoni, but only adult E. carlshergi. The juvenile and adult modal size classes of K. anderssoni and P. tenisoni increased from March through to February and the proportion of juvenile to adult fish increased in winter. The increase in the modal size class of the K. anderssoni/P. tenisoni complex during the year probably reflects growth of the fish, rather than movement of different populations in and out of the area exploited by king penguins. All squid consumed were probably juveniles. The modal size class of Kondakovia longimana increased from March to August, but in September to October smaller squid again formed a large proportion of the squid component of the diet. Numbers of measurable squid beaks recovered from November to February were low. This is the first time that mesopelagic myctophid fish have been shown to comprise a major component of the diet of a vertebrate predator in the Southern Ocean.
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  • 5
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    Wiley-Blackwell
    In:  Lethaia, 21 (4). pp. 375-382.
    Publication Date: 2020-07-15
    Description: In the animal kingdom evolutionary size changes involved increasing, decreasing and stationary patterns. Planktic and benthic Foraminifera chiefly increased their size during evolution. This increase, however, did not always occur gradually, but could be interrupted by periods when the animals maintained or even decreased in size. The rate of the size increase is different for the various species examined, some benthic forms grew only 10% during the Oligocene-Pleistocene interval, while for others this figure was up to 96%. Some benthic species increased in size in certain areas, but not in others. It is not improbable that some phylogenetic trends of planktic Foraminifera representing, according to stratigraphers, the evolution of one species into another, represent in reality, from the biological point of view, specimens of the same species which changed their size and in addition some minor morphological traits which are encompassed by the normal span of intraspecific variability. A comprehensive understanding and explanation of the size change of Foraminifera needs much additional research.
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  • 6
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    Wiley-Blackwell
    In:  Nordic Journal of Botany, 7 (3). pp. 359-363.
    Publication Date: 2018-10-02
    Description: Blidingia minima var. ramifera is reported for the first time in eastern North America. It occurs in the Gulf of St. Lawrence, Nova Scotia and in Maine. In the estuary of the West and Rights Rivers (Antigonish Harbour, Nova Scotia) it is the most common intertidal alga and during its maximum growth period (June‐August) covers 75–90% of the intertidal zone for several km of shoreline at the mouth of the Rights River. In culture, spore germination and early development were typical of the taxon as described from Europe. The taxon is raised to specific status as Blidingia ramifera stat. nov. Blidingia subsalsa is confirmed from New England based on observations of spore germination in plants from Maine and Connecticut.
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  • 7
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 507-510 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 8
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 513-516 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 9
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    AIChE Journal 31 (1985), S. 520-522 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 10
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 522-522 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 11
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    AIChE Journal 31 (1985), S. 741-746 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Hydrodynamic characteristics of an in vitro membrane permeation system for controlled drug delivery studies were investigated by measuring dissolution rates of benzoic acid in various aqueous solutions of polyethylene glycol 400. The mass transfer coefficient was well correlated in terms of three dimensionless numbers: Sherwood, Schmidt, and Reynolds numbers. By using the correlation equation, the intrinsic permeation rate of testosterone through silicone membranes was precisely extracted from the experimental data obtained under various nonideal flow conditions.
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  • 12
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    AIChE Journal 31 (1985), S. 697-699 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 13
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 14
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    AIChE Journal 31 (1985), S. 781-787 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new device for solid-solid and gas-gas continuous mixing, based on the impingement of two streams, was developed and successfully tested. It was found that in comparison to other available solid-solid pneumatic mixers, such as the fluidized bed, spouted bed, air mixer, and mixing silo, the new device is very convenient and easy to operate and more energy-efficient. This is also true for gas-gas mixing when compared with a fluidized bed. A model for the gas phase behavior in the mixing of two gases was successfully tested, which supplements the picture of the solid particles behavior predicted from a model previously derived by the authors.
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  • 15
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    AIChE Journal 31 (1985), S. 857-859 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 16
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 703-703 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 17
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    AIChE Journal 31 (1985), S. 807-811 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple, lumped-parameter model has been developed to predict the length and shape of a parison on the basis of experimental swell data and the storage modulus of the resin. The applicability and limitations of the model are demonstrated by comparing its predictions with experimental observations of parison behavior.
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  • 18
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    AIChE Journal 31 (1985), S. 721-728 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Both intrinsic kinetics and rates of decomposition in larger particles were determined for a Colorado shale by weight-loss measurements in TGA-type equipment. The data for small granular particles indicated first-order intrinsic kinetics up to a fractional weight change that depended on the temperature level. In the experiments with larger particles, gas, particle-surface, and particle-center temperatures measured in separate runs showed that both gas-to-particle and intra-particle temperature differences were significant.A heat transfer model was evaluated by using the intrinsic kinetics data, measured heat transfer coefficients, and shale properties from the literature, to predict weight loss and particle-center temperatures for the larger particles. Comparison with observed results showed good agreement in general, although there was some deviation in weight-loss results at low temperatures.The combined set of intrinsic kinetics data and rates for larger particles should be useful for further studies of pyrolysis models.
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  • 19
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 747-752 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Many measurements of ice growth rates in NaCl solutions have been made to determine the role of natural convection in the control of such growth rates. The results of two analyses are presented. In one, only thermal natural convection is treated for growth in pure water. The second treats the simultaneous effects of both mass and thermal natural convection in salt solutions. This second analysis correctly predicts higher ice growth rates in dilute salt solutions than in pure water.
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  • 20
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    AIChE Journal 31 (1985), S. 863-864 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 21
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    AIChE Journal 31 (1985), S. 788-794 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrodrynamic behavior of a 1.0 × 10-1 m dia. Scheibel column packed with a material preferentially wetted by the dispersed phase has been investigated with and without mass transfer. Drop size and size distribution and dispersed phase holdup were measured as a function of flow rates, agitator speed, packing pad height, and mass transfer direction in a 24 factorial design. Flooding rates were measured and found to be dependent on the impeller position.
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  • 22
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mathematical model described in Part I is applied to predict CH4 and tar yields in rapid hydropyrolysis of softening coal particles. Predicted effects of pressure and particle size agree with trends previously measured in a screen heater apparatus.
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  • 23
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 943-949 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The converter warmup model developed previously (Oh and Cavendish, 1985) has been used to simulate the performance of a packed-bed converter during the cold-start portion of vehicle emissions tests. Despite the highly transient converter inlet conditions, the model successfully predicts tailpipe mass emissions as a function of time.
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  • 24
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    AIChE Journal 31 (1985), S. 973-981 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Prior studies have demonstrated that char gasification rates vary with conversion, showing a maximum at an intermediate level. In this work experimentally determined char-air reaction rates and corresponding pore structures are compared to assess the applicability of a previously proposed random pore model and to extract pertinent chemical and physical parameters. Results on six different chars are presented and analyzed to obtain structure parameters, intrinsic kinetics, and activation energies. Agreement between two independent evaluations of the structure parameters demonstrates the degree of applicability of the random pore model and supports the view that rate variations with conversion are controlled by pore structural changes, even though overall rates also include contributions of intrinsic reactivity.
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  • 25
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    AIChE Journal 31 (1985), S. 1010-1018 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The nature of the interaction between the flowing phases in a cocurrent gas-liquid downflow through packed beds depends on the type of the flow regime. The interaction is poor and geometric in nature in gas-continuous flow and becomes high and dynamic in pulse flow due to gas dispersion, acceleration, and mixing of the liquid in the pulses. Models to calculate pressure drop in each of the flow regimes are presented, taking into account the respective interactions. Experimental data on pressure drops and liquid holdups were measured in gas-continuous flow for 3 mm glass spheres and 6 mm Raschig rings. An air-water system is used. The literature data on pressure drops and the experimental data, covering liquid velocities from 0.001 m/s to 0.029 m/s and gas velocities from 0.097 m/s to 2 m/s, were compared with the calculated values. It was found that the pressure drop due to dynamic interaction can be as low as 10% and as much as 80% of the total pressure drop for the data examined in this work. An empirical correlation for holdup in gas-continuous flow is given for Rashig rings.
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  • 26
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    AIChE Journal 31 (1985), S. 1039-1040 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 27
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    AIChE Journal 31 (1985), S. 1051-1051 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 28
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    AIChE Journal 31 (1985), S. 1338-1348 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical model was developed to predict the heat and mass transfer phenomena in porous materials. A water-filled sandstone was heated in a convective oven and its water loss rates and temperature profiles were compared with theoretical results. In addition to local temperatures, moisture content, gas densities and pressure, this model also predicts the fluid flow pattern in the heated sample.
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  • 29
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    AIChE Journal 31 (1985), S. 1349-1359 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamic behavior of deep-bed filtration was studied by considering two limiting situations. In the first case it was assumed that deposition leads to the presence of a reasonably smooth deposite layer over filter grains. In the second case particle aggregates, once formed, were assumed to remain rigid and the deposited particles to act as additional collectors. The effect on filter performance of the media change resulting from the presence of these two types of deposits was examined quantiatively.
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  • 30
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    AIChE Journal 31 (1985), S. 1249-1262 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The combustion of processed shale is analyzed. By using a coordinate system moving with the same velocity as the combustion zone a model is obtained for the fully developed temperature wave. Of particular interest is the interpretation of this wave in terms of the kinetics and thermal effects of the reactions that are involved.
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  • 31
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    AIChE Journal 31 (1985), S. 1297-1303 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of the reaction of carbon dioxide with mono- and diethanolamine in such nonaqueous solvents as methanol, ethanol, and 2-propanol and in water were studied using a stirred tank absorber with a plane gas-liquid interface at 303 K. The reaction was found to be of first order with respect to carbon dioxide for every solvent. The order of reaction with respect to ethanolamine was found to be unity only for an aqueous solution of monoethanolamine and for the other solutions, ranged from 1.4 to 2, depending on the solvent species. The reaction order was increased in the order of water, methanol, ethanol, and 2-propanol. The variation of the reaction order with the solvent species could be explained in terms of a reaction scheme via a zwitterion. Almost linear dependence of the logarithm of the reaction rate constant on the solubility parameter of the solvent was derived.
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  • 32
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    AIChE Journal 31 (1985), S. 1329-1337 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Adsorption of organics inot activated carbon particles within a fixed-bed adsorber is modeled using the concept of mixing cells. The adsorption isotherm of these organics is taken to be rectangular because of the commonly observed strong affinity of organics into activated carbons. The model equations are solved by a singular perturbation method, and this results in a graphical procedure similar to that of McCabe and Thiele used in distillation column design. Such a graphical procedure provides a quick means to determine the adsorbate profiles along the adsorber for a given time and also the breakthrough curve, which reflects the performance of the adsorber.
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  • 33
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    AIChE Journal 31 (1985), S. 1372-1380 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical and experimental investigation is presented for mass transfer to a rotating hemispherical electrode when direct current (DC) superimposed with symmetrical triangular- or square-wave alternating current (AC) is used for electrolysis. A film model is used for the analysis of AC concentration components. The limiting AC current density corresponding to a zero instantaneous surface concentration and the phase shift between the applied AC and the periodic potential changes are calculated and compared to the experimental studies. The experimental data agreed with the theoretical prediction to within ±8% in the regime of a dimensionless AC frequency K = (ω/Ω)Sc1/3 greater than 1 and less than 180. The mass transfer behavior with the triangular and square waves is further compared to that of the sinusoidal current. It is found that for a given AC frequency and rotational speed, the limiting AC current density on the electrode decreases in the order of traingular-wave AC 〉 sinusoidal AC 〉 square-wave AC.
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  • 34
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    AIChE Journal 31 (1985), S. 1397-1400 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 35
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    AIChE Journal 31 (1985), S. 1401-1404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 36
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    AIChE Journal 31 (1985), S. 1427-1434 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The transient responses of a fixed-bed reactor to step increases and decreases in CO, O2, and/or CO2 feed concentrations were measured and interpreted. It is shown that dynamic methods yield vastly more phenomenological and mechanistic information than steady state measurements, with significantly less experimental effort.
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  • 37
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    AIChE Journal 31 (1985), S. 1582-1584 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 38
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The surface rejuvenation model of the turbulent burst process, already developed for the momentum and heat transfer processes, is applied to the field of mass transfer. The range of applicability of the theory, previously shown to be valid for the Prandtl number range 0.7 to 64 is extended to Schmidt numbers of 6,500 without introducing any new parameters. Concentration and temperature profiles for high Schmidt and Prandtl numbers are in agreement with experimental data. Theoretical expressions for Sherwood and Stanton numbers are calculated and shown to be in agreement with experimental data over five orders of magnitude.
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  • 39
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    AIChE Journal 31 (1985), S. 1632-1644 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The generalized relationships of Lee and Kesler for the thermodynamic properties of nonpolar fluids have been combined with an accurate equation of state for water which is utilized as the reference substance for polar fluids for reduced temperatures from 0.4 to 2.5 and reduced pressures to 10. The input data required are the critical temperature, critical pressure, acentric factor, and a polarity factor Y obtained from experimental pressure-volume-temperature data. Comparisons between calculated and experimental thermodynamic properties indicate that highly accurate results are obtained by the method of this study for most polar fluids. A modified procedure is presented for the compressibility factors of substances with large acentric factors such as alcohols. Tabulated values of the polar fluid correction terms are presented for the compressibility factor, fugacity coefficient, and enthalpy, entropy, and heat capacity departures for the complete range investigated.
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    AIChE Journal 31 (1985), S. 1721-1724 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 31 (1985), S. 1725-1727 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 31 (1985), S. 1740-1741 
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    AIChE Journal 31 (1985) 
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    AIChE Journal 31 (1985), S. 1791-1800 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The simultaneous diffusion and adsorption of water vapor into specially prepared silica gel and activated carbon desiccants was experimentally studied for laminar flow through an isothermally maintained parallel-plate channel. The equilibrium characteristics and tortuosities of the various desiccant sheets used were experimentally determined.The data were compared with a modified Rosen model. The Rosen model predicts outlet concentrations from the knowledge of adsorption equilibrium constants, diffusion, and mass transfer coefficients. A comparison of computed and measured concentrations as a function of sorption time shows that with independently measured equilibrium and effective diffusion coefficients, the modified Rosen model became completely predictive.
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    AIChE Journal 31 (1985), S. 1645-1654 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for the adsorption of phenol in a fixed bed of a polymeric adsorbent is developed. Model parameters (equilibrium parameters, capacity factor, axial dispersion, film mass transfer coefficient, and intraparticle effective diffusivity) are experimentally determined from independent experiments. Numerical solution of the model equations uses the method of lines with double orthogonal collocation in finite elements. The model is used for the prediction of breakthrough curves and is part of a package for the design of cyclic processes.
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    AIChE Journal 31 (1985), S. 1707-1713 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Computer simulations of periodically cycled columns predicted improvements in column performance of greater than 200% for systems with nonlinear equilibrium curves. Experiments distilling methanol-water mixtures have verified those predictions for periodic cycling with a single plate. The extension of the theory to multiple-plate columns fails in usual distillation apparatus due to liquid mixing during the liquid flow period. To overcome this problem a new tray design consisting of a sieve plate and inclined surfaces has introduced an effective liquid time delay. Although the predicted efficiencies of 200% were not realized due to vapor movement hindering the tray action, a wide range of operating conditions provided good overall column efficiencies of 140%.
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    AIChE Journal 31 (1985), S. 1736-1739 
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    AIChE Journal 31 (1985), S. 1747-1751 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 31 (1985), S. 1752-1754 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The conventional equilibrium-stage model that uses a component-independent stage efficiency and a nonequilibrium-stage model, in which mass transfer rate equations are solved simultaneously with the stage conservation equations, are employed to solve four representative distillation design problems. There are large differences between the number of stages predicted by the two models for a specific separation of the more volatile component. The differences arise from two causes: the way in which the liquid phase resistances and equilibrium equations are used in the models, and the consequences of diffusional interaction effects. Neglect of the latter may lead to an underdesigned column; there is between a 9 and 15% difference in the stage requirements predicted by the nonequilibrium model with a rigorous mass transfer model and a nonequilibrium model which ignores interaction effects.
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    Notes: Application of the model of Part I is made to several systems with various graphitized carbon blacks over wide ranges of temperatures and submonolayer coverage. Agreement with all data for equilibrium and transport is probably within experimental error.
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    AIChE Journal 32 (1986), S. 159-162 
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    AIChE Journal 31 (1985), S. 2083-2085 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 32 (1986) 
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    AIChE Journal 32 (1986), S. 195-199 
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    Notes: The use of singular perturbation approximation for estimating parameters in stiff ordinary differential equations is illustrated. A sequential parameter estimation approach, in which the difficult-to-estimate parameters are introduced in higher-order terms of the perturbation solution, is developed and illustrated. This approach is shown to provide excellent initial estimates, to be computationally efficient, and to be insensitive to initial guesses for the parameters. Aspects of data requirements for this problem estimation are discussed.
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    Notes: The mathematical model outlined in Part I is recast in a form suitable for numerical computation. The spatial derivatives are replaced by finite-difference expressions, which leads to a set of ordinary differential equations coupled to a set of nonlinear algebraic relations. This system is solved using existing integration techniques. The resulting algorithm simulates the characteristic behavior of the classical modes of electrophoresis, which is shown by examples involving moving boundary electrophoresis and isoelectric focusing. In the first example two different integration schemes are used and their accuracy and stability investigated. The second example illustrates the versatility of the methodology.
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    AIChE Journal 32 (1986), S. 255-262 
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    Notes: Low-pressure, low-temperature adsorption of N2 and CO2 were studied in beds of 4A molecular sieves. System parameters were estimated by a comparison of experimental results and a molecular-flow theoretical model. Nitrogen data followed theoretical prediction. Theory adequately represented pressure above the bed for CO2, while pressure drops deviated deviated significantly from the model.
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    AIChE Journal 32 (1986), S. 291-296 
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    Notes: The Stefan-Maxwell equations have been used to predict single-electrolyte diffusion and ternary tracer diffusion in concentrated electrolyte solutions. Variations in diffusivity due to concentration have been shown to be related to the relaxation effect and viscosity changes of solution. Specific equations are presented to evaluate the ion-ion and ion-solvent interaction coefficients appearing in the Stefan-Maxwell equations. These equations, when tested against experimental data, gave an accurate description of the process at up to 4.0 M concentrations and for trace species mobilities differing by a factor of ten.
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    AIChE Journal 32 (1986), S. 309-312 
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    AIChE Journal 32 (1986), S. 163-166 
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    AIChE Journal 32 (1986), S. 341-343 
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    AIChE Journal 32 (1986), S. 177-185 
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    Notes: The stability characteristics of an aerosol reactor in a continuous stirred tank configuration have been investigated theoretically. Three dimensionless parameters, the surface tension group ∑, reaction rate group R, and residence time group θc, suffice to determine the dynamic behavior of this system. The stability of the unique steady state was investigated using linear analysis. Numerical integration of the full nonlinear equations shows that the dynamic behavior was in accord with the predictions of the linear stability theory. The system exhibits limit-cycle behavior in the unstable part of the parameter space. In the unstable region, a simple linear relation was found between the period of the numerically computed solutions and the bifurcation parameter, θc. The results of this study are in qualitative agreement with the experimental results of Badger and Dryden (1939).
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    AIChE Journal 32 (1986), S. 207-214 
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    Notes: A general model is developed for the electrophoresis of soluble materials. The model describes the evolution of concentration fields for a set of compounds which undergo transport by flow, diffusion, and migration in an electric field and simultaneously participate in rapid dissociation-association reactions. Modes of electrophoresis requiring special treatment can now be studied in a unified context. As an example of its utility, the model is used analytically to study a process known as isotachophoresis. In Part II two electrophoretic separation processes are simulated numerically, demonstrating the model's versatility.
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    AIChE Journal 32 (1986), S. 344-346 
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    AIChE Journal 32 (1986), S. 269-275 
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    Notes: A computer model of a single-pass, rotary-drum dryer with or without a centerfill flighting section, describes the drying behavior of wood particles within the drum. This part of a two-part study examines heat and mass transfer, which are shown to be partly dependent on the pattern of particle flow and on retention time. Comparison of simulation results with drying data based on moisture content of outlet particles from a large-scale rotary dryer was favorable, with a root mean square error of 22.2%.
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    AIChE Journal 32 (1986), S. 419-425 
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    Notes: Existing models for laminar flow in tubular reactors neglect radial velocities in the momentum transport equation. The axial velocity distribution is calculated assuming fully developed flow wherein axial velocities are in local equilibrium with the radial viscosity profile. A test of this assumption has been devised using a representative model of the Newtonian viscosity, μ(r, z), and by reconstructing the radial velocity components using the continuity equation. The assumption of fully developed flow is shown to be a valid approximation for typical polymerization reactions. However, the fact that radial velocities are negligible with respect to momentum transport does not mean they are negligible with respect to convective diffusion of heat and mass. Radial convection is shown to be important for typical polymerization and heat transfer examples.
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    AIChE Journal 32 (1986), S. 335-337 
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    AIChE Journal 32 (1986), S. 537-546 
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    Notes: An analytical solution of thermally coupled system (TCS) optimization was found. Energy requirements of the TCS were minimized provided that the ternary solution being separated is ideal. The TCS is energetically profitable in comparison with other sequences of distillation columns. The solution method can be used for the synthesis of separation systems and for screening calculations, due to the great simplicity of the result.
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    AIChE Journal 32 (1986), S. 566-574 
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    Notes: Hydrogenation of α-methyl styrene with Pd/Al2O3 catalyst was studied in a three-phase stirred slurry reactor. Responses to step inputs of H2 in N2 carrier gas provided temporal moments that allowed estimation of separate values for reversible adsorption and irreversible surface reaction rates for reactant H2. Mass transfer resistances are either estimated from other sources and shown to be small, or are evaluated from the flow rate dependence of the moments. The adsorption equilibrium constant for H2 on the catalyst was measured with reaction product cumene as the solvent. For temperatures between 290 and 322 K adsorption appears to have the dominant influence on the overall rate of hydrogenation. The energy of activation for the adsorption step was found to be 8 kcal/mol.
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    AIChE Journal 32 (1986), S. 575-591 
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    Notes: A procedure based on averaging the conservation equations in a homogeneous, disordered fibrous medium is used to demonstrate that in the limit of long times, macroscopic versions of Fick's and Fourier's laws may be used to relate the average flux to the average gradient in driving force. The asymptotic behavior in the limit of low volume fraction of the effective diffusivity (or conductivity) in such a medium is determined for all values of the Peclet number, P = Ua/Df, where U is the average velocity through the bed, a is the fiber radius, and Df is the molecular diffusivity of the solute in the fluid. The convective disturbance caused by the fibers is found to have a large influence on the rate of mass transfer even at moderate Peclet numbers and low volume fraction.
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    AIChE Journal 32 (1986), S. 616-623 
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    Notes: Flow rate and concentration measurements in a steady state process are reconciled by weighted least squares so that the conservation laws and other constraints are obeyed. Two projection matrices are constructed in turn, in order to decompose the problem into three subproblems to be solved in sequence. The first matrix eliminates all unmeasured component flow rates and concentrations from the equations; the second then removes the unmeasured total flow rates. The adjustments to component flow rates are iteratively determined, starting with guessed values of unmeasured total flow rates.Chi-square and normal test statistics are derived by linearizing the equations, to allow detection of gross errors in imbalances and adjustments of measurements.
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    AIChE Journal 32 (1986), S. 592-606 
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    Notes: The problem of synthesizing processing systems via simultaneous structural and parameter optimization is addressed in this paper. Based on a superstructure representation for embedding alternative configurations, a general mixed-integer nonlinear programming (MINLP) framework is presented for the synthesis problem. An efficient outer-approximation algorithm is described for the solution of the underlying optimization problem, which is characterized by linear binary variables and continuous variables that appear in nonlinear functions. The proposed algorithm is based on a bounding sequence that requires the analysis of few system configurations, and the solution of a master problem that identifies new candidate structures. Application of the proposed algorithm is illustrated with the optimal synthesis of gas pipelines.
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    Notes: Tracer diffusivities measured with the Taylor dispersion technique are reported for carbon tetrachloride, s-trioxane, 12-crown-4, 15-crown-5, and 18-crown-6 in acetonitrile, benzene, and chlorobenzene across ranges of temperature. It is demonstrated that Stokes' law corrected with a microfriction factor successfully accounts for the diffusion behavior of even disk-shaped crown ethers. Solute and solvent molecules being effectively spherical in the context of Stokes' law, the tracer diffusion of crown ethers is found to be satisfactorily represented by a rough-hard-sphere model for molecular diffusion. The degree of success increases with decreasing solvent polarity. The diffusion data for carbon tetrachloride are also used to extend the basis of the recently developed reduced equation for the tracer diffusion of nonelectrolytes in liquids over wide temperature ranges.
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    Notes: A radiotracer-based method of measuring local particle deposition profiles and reentrainment rates in an electrostatic precipitator has been developed and demonstrated. In tests performed on a pilot-scale precipitator, differences in local deposition profiles obtained with and without a predeposited layer of dust on the plate were observed. Rates of reentrainment due to gas friction (aerodynamic drag) and to particle impaction on the plate were measured separately, and correlated with a semiepirical formula. Both friction and impaction reentrainment rates were found to vary as powers of the difference between the gas velocity and a minimum velocity required for reentrainment. The impaction reentrainment was found to vary as a power of the inlet dust loading.
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    AIChE Journal 31 (1985), S. 95-102 
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    Notes: The separation of mixtures of helium and methane using a single column of activated carbon in a pressure swing adsorption process was studied experimentally. Process performace was predicted with an average error of 10% or less by a local-equilibrium well-stirred cell model in which dead volumes at the feed and product ends of the column were accounted for. Systematic differences between experiment and model were ascribed to omission from the model of flow resistance and heat release.
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    AIChE Journal 31 (1985), S. 90-94 
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    Notes: A model is presented which relates the crystal size distribution (CSD) from a mixed-suspension, mixed-product-removal (MSMPR) crystallizer to the distribution of growth rates. This model is based on the assumption that individual contact nuclei have some inherent growth rate which remains constant, but the growth rate may vary from crystal to crystal. The crystal size distribution can be calculated from prior knowledge of the growth rate distribution. Even a limited knowledge of only the coefficient of variation and the mean growth rate permits an approximation of the expected crystal size distribution. Conversely, estimates of the mean and variance of the growth rate distribution can be determined from the moments of the CSD from an MSMPR crystallizer.
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    AIChE Journal 31 (1985), S. 103-111 
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rates of calcination of two types of limestones, ranging in particle size from 1 to 90 μm, were measured over the temperature range 516 to 1,000°C. A kinetic model based on the B.E.T. (Brunauer-Emmett-Teller method) surface area of the CaCO3 correlates the results over 5 orders of magnitude in reaction rate. The B.E.T. surface area of CaO formed by rapid calcination in dispersed-particle systems is 50 to 90 m2/g.
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    AIChE Journal 31 (1985), S. 111-118 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Toor's (1969) hypothesis is extended to the second-order, series-parallel reaction. A second closure relates the mixing for the second reaction to the first. The equations are solved for conversion and selectivity for a turbulent reactor configuration. The analysis is extended to incorporate concepts of residence time distribution, segregation, and maximum mixedness.
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    AIChE Journal 31 (1985), S. 119-126 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the effect of liquid viscosity on the initiation of roll waves in a horizontal gas-liquid flow are presented. These results are interpreted by an analysis based on the calculation of the growth of long wavelength disturbances.
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  • 81
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    AIChE Journal 32 (1986), S. 853-856 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 82
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  • 83
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  • 84
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    AIChE Journal 32 (1986), S. 914-931 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new high-performance multivariable time delay compensator is presented that contains the Ogunnaike-Ray compensator as a special case, reduces to the Smith predictor for a single delay, and approaches the realizable part of the process inverse as a limit. The straightforward design procedure is illustrated with several distillation control examples.
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    AIChE Journal 32 (1986) 
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    AIChE Journal 32 (1986), S. 865-868 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 31 (1985), S. 157-160 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 88
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    AIChE Journal 32 (1986), S. 1015-1024 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The multiinput/multioutput pole-placement self-tuning controller (MIMO PPSTC) previously developed by McDermott and Mellichamp is used to control a fixed-bed autothermal reactor with internal countercurrent heat exchange. The performance of the controller is demonstrated using step changes in the set points and in the primary disturbance variables. It is shown that the complete temperature profile can be maintained by controlling two temperatures in the catalyst bed: one just before the hot spot and the other at the exit of the bed. Simulated results using a 36th-order nonlinear reactor model operating at both an open-loop upper stable steady state and an open-loop unstable steady state are presented. Experimental results for a fixed-bed autothermal reactor operating at an upper stable state are presented.
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    AIChE Journal 32 (1986), S. 959-970 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Most published “interaction measures” can produce misleading results and often do not measure the true closed-loop interaction. Therefore, closed-loop transmittances are defined mathematically as direct, parallel, disturbance, and interaction transfer functions and it is shown that the direct Nyquist array design method includes an excellent basis for interaction analysis.
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    AIChE Journal 32 (1986), S. 1053-1053 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 32 (1986), S. 1057-1066 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Various ways of building quasi-Newton matrix approximations that satisfy the special form of the Gibbs-Duhem equation are studied. Partition symmetry, the separability of the functions in γ and in φ, and the method of iterated projections are used in order to develop thermodynamically consistent matrix approximations with good secant information. Many examples are presented which show that exploiting the special form of the Gibbs-Duhem equation results in improved numerical performance. Ways of exploiting the Gibbs-Helmholtz equation in addition to the special form of Gibbs-Duhem equation, and thus the isobaric form of the Gibbs-Duhem equation, are also discussed.
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    AIChE Journal 32 (1986), S. 1125-1131 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The composition and temperature dependence of the mutual diffusion coefficient near the liquid-liquid critical point of methanol-n-hexane mixtures has been determined by Gouy interferometry. The critical exponent was found to be 0.685. Constant-temperature extrapolation to zero diffusivity located the spinodal curve. Spinodal loci calculated from the NRTL model are inconsistent with the experimentally determined values.
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    AIChE Journal 32 (1986), S. 1233-1241 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper investigates the application of spatially adaptive numerical methods in the solution of one-dimensional premixed combustion problems. The selection of grid points by equidistribution of positive weight functions across consecutive mesh intervals is considered. The method is applied in the solution of a steady premixed laminar flame problem and a time-dependent freely propagating flame problem. The adaptive numerical results are compared with corresponding equispaced calculations.
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    AIChE Journal 32 (1986), S. 1253-1262 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A universally valid formal expression for the composition dependence of solute and solvent fugacity coefficients in any dilute binary system far from criticality is derived in this paper. In the present context, dilution denotes the y1 → O limit, regardless of the mixture's molar density. The results are independent of the system under study and of the choice of equation of state. The solute fugacity coefficient is simply the product of a composition-independent term (the infinite dilution fugacity coefficient) and an exponential decay composition correction. These two parameters have important thermodynamic implications: their temperature and pressure derivatives are related to the solute's partial molar enthalpy and volume, respectively. When applied to activity coefficients, the same theoretical analysis yields universal relationships for the composition dependence of activity coefficients which can be used as consistency checks for empirical correlations. The relationship between infinite dilution activity and fugacity coefficients can be used to estimate relative solubilities of a given solute in different solvents. Excellent agreement is found when the theoretical expressions are tested with three different binary systems involving a nonvolatile solid solute and a supercritical fluid.
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    AIChE Journal 31 (1985), S. 201-208 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The collection mechanism of polystyrene latices of 0.6 μm in diameter in electroflotation has been examined both theoretically and experimentally as extension of our previous work (1980). To avoid the change of surface state of particle bubble, the experiment was conducted under the condition that the concentration of CTAB (cetyl trimethylammonium bromide), cationic surfactant in the solution, is within the 90% of its initial concentration. It is of interest that the theory predicts the collection efficiency to vary as di-1.91.
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    AIChE Journal 31 (1985), S. 208-215 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Axisymmetric submerged jets of dilute solutions of poly(ethylene oxide) and polyacrylamide of high molecular weight were studied using a two-component laser Doppler velocimeter. At from 40-60 jet diameters from the source the small eddies are suppressed in the solutions studied. The behavior of the large eddies depends upon the elastic nature of the solution.
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    AIChE Journal 31 (1985), S. 215-221 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is shown that the conventional Smith dead-time compensator can be modified in a fashion which leads to significant improvements in its regulatory capabilities for measurable disturbances or inputs. The proposed modification utilizes effectively the existing prediction capabilities of the conventional dead-time compensator and eliminates the need for a separate feedforward controller in many circumstances under which it is normally employed. The modified dead-time compensator possesses simultaneous feedforward and feedback actions. An additional tuning parameter which controls the degree of dead-time cancellation allows the designer to shape the response according to requirements. Illustrative examples show the advantages of the modified scheme.
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    AIChE Journal 32 (1986), S. 1208-1210 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 32 (1986), S. 1224-1226 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 32 (1986), S. 1232-1232 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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