ALBERT

Description: Magnetic polarity stratigraphies from ODP Leg 177 'high resolution' sites indicate Brunhes sedimentation rates in the 12-25 cm/kyr range, with a trend of decreasing sedimentation rates with increasing age. Magnetite is the principal remanence-carrying mineral. Downcore alteration of magnetite and authigenic growth of iron sulfides introduces a high coercivity diagenetic remanence carrier (pyrrhotite). The change in pore water sulfate with depth in the sediment tends to be in step with the decrease in magnetization intensity, indicating the link between sulfate reduction and magnetite dissolution. Shipboard pass-through magnetometer data are generally very noisy due to a combination of weak magnetization intensities, drilling-related core deformation, and the influence of authigenic iron sulfides. Post-cruise progressive demagnetization of discrete samples aids the magnetostratigraphic interpretation, as these measurements are less influenced by low magnetization intensities and drilling-related deformation. The magnetostratigraphic interpretations provide much-needed calibration for biostratigraphic events in the high latitude southern oceans. Apart from the ODP Hole 745B (Kerguelen Plateau), published Plio-Pleistocene magnetostratigraphies from ODP sites in the Southern Ocean are poorly constrained. For this reason, we compare interpolated ages of 11 radiolarian events and one diatom event that occur at Hole 745B and Leg 177 sites.

Description: At Ocean Drilling Program (ODP) Site 1090 (lat 42°54.8'S, long 8°54.0'E) located in a water depth of 3702 m on the Agulhas Ridge in the sub-Antarctic South Atlantic, ~300 m of middle Eocene to middle Miocene sediments were recovered with the advanced piston corer (APC) and the extended core barrel (XCB). U-channel samples from the 70-230 meters composite depth (mcd) interval provide a magnetic polarity stratigraphy that is extended to 380 mcd by shipboard whole-core and discrete sample data. The magnetostratigraphy can be interpreted by the fit of the polarity-zone pattern to the geomagnetic polarity time scale (GPTS) augmented by isotope data and bioevents with documented correlation to the GPTS. Three normal-polarity subchrons (C5Dr.1n, C7Ar.1n, and C13r.1n), not included in the standard GPTS, are recorded at Site 1090. The base of the sampled section is correlated to C19n (middle Eocene), although the interpretation is unclear beyond C17r. The top of the sampled section is correlated to C5Cn (late early Miocene), although, in the uppermost 10 m of the sampled section, a foraminifer (Globorotalia sphericomiozea) usually associated with the Messinian and early Pliocene has been identified. 87Sr/86Sr, d13C, and d18O values measured on foraminifera, including the d18O and d13C shifts close to the Eocene/Oligocene boundary, support the correlation to the GPTS. For the interval spanning the Oligocene/Miocene boundary, benthic d13C, d18O, and 87Sr/86Sr records from Site 1090 can be correlated to isotope records from ODP Site 929 (Ceara Rise), providing support for the recently-published Oligocene/Miocene boundary age (22.92 Ma) of Shackleton et al.

Description: Approximately one thousand sediment samples from ODP Site 1123 on the Chatham Rise, east of New Zealand, have been examined for inorganic elemental concentrations. ODP 1123 provides a record of sediment drift deposition under the Deep Western Boundary Current, the main inflow of deep water to the Pacific Ocean since the Early Oligocene, though a major hiatus spans the late Early Oligocene to the Early Miocene. Normalisation of the elemental concentrations by aluminium was used to allow for the effects of variable carbonate dilution. The elemental ratios were used as proxies for sediment composition and as palaeoceanographic indices. The samples were collected at a resolution designed to sample adequately any variation in elemental ratios at the scale of the Milankovitch orbital cycles. The sampled intervals span the Early Oligocene, Early Miocene, mid-Miocene and Late Pleistocene to Recent. Anomalous Si/Al, K/Al, Ti/Al values in the upper Pleistocene section, often associated with horizons of low carbonate, are attributed to tephras derived from North Island. Not all of the tephras detected geochemically had been detected visually in the cores. A total of 37 tephra events between 1.17 Ma BP and the present are recognised based on this and the shipboard investigations. The tephra events cluster at intervals of approximately 326 000 years (326 ka) perhaps due to variations in eruption frequency on North Island and/or to variations in the regional palaeowind intensity and direction. In the Late Pleistocene to Recent P/Al (inferred nutrient availability), percent calcium carbonate (%CaCO3) and Ba/Al (inferred productivity) varied regularly at a period of 40 000 years with these factors lagging minimum global ice volumes (interglacials). During the mid-Miocene CaCO3, Ba/Al, P/Al and Si/Al all gradually increased with %CaCO3 and P/Al showing regular 138 000-yr cyclicity and Ba/Al showing 44-ka cyclicity. Inferred productivity (Ba/Al) may have been rising in association with increasing nutrient availability (P/Al) at the same time as increased vigour of the Deep Western Boundary Current that was connected to a period of rapid ice-sheet growth in Antarctica. In the Early Miocene P/Al and Si/Al were much higher than subsequently and both %CaCO3 and P/Al exhibited 131 000-yr cycles. By far the highest nutrient levels and inferred productivity at this site apparently occurred during the Early Oligocene as revealed by long-term changes in P/Al and Si/Al. A progressive rise in K/Al, but stable Ti/Al from the Early Oligocene to the Recent probably indicates increased proportions of illite in the clay mineral fraction of the drift sediments caused by increased flux of debris from the Southern Alps.

Description: We present mid-Pliocene (4.3-2.6 Ma) benthic stable oxygen and carbon isotope data from Ocean Drilling Program Site 1092 (ODP Leg 177) drilled in the sub-Antarctic sector of the Southern Ocean. The results are compared with the stable isotope results from nearby Site 704 (ODP Leg 114). Oxygen isotope data show that minimum values are about 0.5 per mil less than those of the Holocene, which is consistent with the results from Site 704, indicating only minor deglaciation of Antarctica during the studied interval. Oxygen isotope data from both Site 1092 and Site 704 are slightly higher relative to Pacific values during several intervals which could be related to the contribution of warm, saline North Atlantic Deep Water (NADW). Comparisons of benthic carbon isotope gradients between sites located in the North Atlantic, sub-Antarctic sector of the Southern Ocean, and Pacific indicate that at times, the gradient between the Southern Ocean and the Pacific evolved differently than the Atlantic-Pacific gradient. This suggests that variations in NADW strength alone might not be responsible for the observed carbon isotope values in the Southern Ocean.

Description: In 1998 Ocean Drilling Program Leg 181 off southwest New Zealand obtained cores from Site 1123 (41°47.2'S, 171°29.9'W; 3290 m water depth) on the Chatham Rise. Site 1123 sampled the North Chatham Sediment Drift, which is located between 169°W and 175°W at depths of 2200-4500 m (Carter, McCave, Richter, Carter, et al., 1999, doi:10.2973/odp.proc.ir.181.2000). This site is located just north of the productive surface waters associated with the Subtropical Front. The cores provide a relatively complete record of sedimentation on the Chatham Drift back to the early Miocene and beyond a stratigraphic gap into the early Oligocene. Drift sedimentation is partly indicated by modern paleoceanographic observations and by extensive microfossil reworking throughout the recovered sediment (Carter and McCave, 1994, doi:10.1029/94PA01444; Carter, McCave, Richter, Carter, et al., 1999, doi:10.2973/odp.proc.ir.181.2000). Approximately 1000 sediment samples from the lower Oligocene, lower Miocene, middle Miocene, and upper Pleistocene have been analyzed geochemically for elemental concentrations. The stratigraphic intervals sampled at 5- to 10-cm intervals are listed in Table T1. The elemental concentrations, normalized by aluminium concentrations, provide proxies for factors such as nutrient levels, siliciclastic and volcaniclastic sediment composition, and bottom-water redox conditions. This approach was prompted by successes with Miocene and Oligocene deep-sea sediment elemental ratios obtained from the Ceara Rise in the western equatorial Atlantic (Weedon and Shackleton, 1997, doi:10.2973/odp.proc.sr.154.129.1997). The results for Ba/Al in the Pleistocene were discussed by Hall et al. (2001, doi:10.1038/35090552), and an interpretation of a selection of additional elemental ratios from all the stratigraphic intervals was provided by Weedon and Hall (2004, doi:10.1016/S0025-3227(04)00024-6). However, many components listed here, particularly the trace elements and rare earth elements, were not considered by Weedon and Hall (2004, doi:10.1016/S0025-3227(04)00024-6).

Description: We have carried out a multiphase analysis of samples from ODP Site 177-1092, Meteor Rise, subantarctic South Atlantic. Samples were analyzed for ice-rafted debris (IRD [see Table T1]) and stable isotopes from benthic foraminifera [see Murphy et al., 2002, doi:10.1016/S0031-0182(01)00495-3]. Both analyses were performed on the same samples. Additional work was performed to identify the paleomagnetic stratigraphy. The analyzed samples range in age from about 2.6(?) Ma to 4.6 Ma, a time span that saw considerable global warmth, but witnessed overall global refrigeration and the transition to truly bipolar glaciations. IRD arrived frequently during the Early and early Late Pliocene, but only as 'background rafting' (occasional grains per sample). The first identifiable IRD above background rafting is associated with marine isotope stage (MIS) KM4 (~3.18 Ma). Successive IRD peaks become larger, the same pattern as noted at nearby Site 114-704. A very large peak near the top of the record, approximately 2.8 Ma, is considered to represent a hiatus. Peaks below 51.3 meters composite depth (mcd) coincide with positive excursions of the oxygen isotopic record, and with negative excursions of the carbon isotopic curve, a pattern also noted at Site 114-704. However, the reasonably large IRD peak at 51 mcd (tentatively identified with MIS G11) coincides with a positive excursion on the carbon isotopic curve and negative excursion on the oxygen isotopic curve. This relationship suggests a northern hemisphere interglacial, rising sea level, destabilization of the Antarctic margin, and delivery of Antarctic icebergs to the Southern Ocean. Such a mechanism has recently been suggested by Kanfoush et al. (2000, doi:10.1126/science.288.5472.1815) for latest Pleistocene stadial/interstadial oscillations. Here we suggest that such a mechanism may have been in place on glacial/interglacial time scales as early as the Late Pliocene.