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  • Wiley-Blackwell  (79,187)
  • 2005-2009  (46)
  • 1980-1984  (43,083)
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  • 1
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    Wiley-Blackwell
    In:  Journal of Zoology, 179 (3). pp. 291-295.
    Publication Date: 2020-07-17
    Description: The cartilaginous tubercles of the mantle of the squid Cranchia scabra have been examined with the scanning electron microscope. Some tubercles are small, simple nodules whereas others are large with a complex Maltese cross form. The varying shapes and sizes probably represent a developmental sequence. The possible role of the tubercles is discussed.
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  • 2
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    Wiley-Blackwell
    In:  Journal of Quaternary Science, 23 (1). pp. 3-20.
    Publication Date: 2017-04-06
    Description: Investigations indicate that the Iceland Ice Sheet was reduced in size during MIS 3 but readvanced to the shelf break at the LGM. Retreat occurred very rapidly around 15 k–16 k cal. yr BP. By contrast, the margin of the ice sheet on the East Greenland shelf, north of the Denmark Strait, was at or close to the shelf break during MIS 3 and 2 and retreat starting ∼17 k cal. yr BP. Quantitative X-ray diffraction analysis of the 〈2 mm sediment fraction was undertaken on 161 samples from Iceland and East Greenland diamictons, and from cores on the slopes and margins of the Denmark Strait. Weight% mineralogical data are used in a principal component analysis to differentiate sediments derived from the two margins. The first two PC axes explain 52% of the variance. These associations are used to characterise sediments as being affiliated with (a) Iceland, (b) East Greenland or (c) mixed. The contribution from Iceland becomes prominent during MIS 2. The extensive outcrop of early Tertiary basalts on East Greenland between 68° and 71° N is an alternative source for basaltic clasts and North Atlantic sediments with εNd(0) values close to ±0.
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  • 3
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    Wiley-Blackwell
    In:  Journal of Quaternary Science, 25 (5). pp. 633-650.
    Publication Date: 2017-12-19
    Description: Two cores were recovered in the southeastern part of Lake Shkodra (Montenegro and Albania) and sampled for identification of tephra layers. The first core (SK13, 7.8 m long) was recovered from a water depth of 7 m, while the second core (SK19, 5.8 m long) was recovered close to the present-day shoreline (water depth of 2 m). Magnetic susceptibility investigations show generally low values with some peaks that in some cases are related to tephra layers. Naked-eye inspection of the cores allowed the identification of four tephra layers in core SK13 and five tephra layers in core SK19. Major element analyses on glass shards and mineral phases allowed correlation of the tephra layers between the two cores, and their attribution to six different Holocene explosive eruptions of southern Italy volcanoes. Two tephra layers have under-saturated composition of glass shards (foiditic and phonolitic) and were correlated to the AD 472 and the Avellino (ca. 3.9 cal. ka BP) eruptions of Somma-Vesuvius. One tephra layer has benmoreitic composition and was correlated to the FL eruption of Mount Etna (ca. 3.4 cal. ka BP). The other three tephra layers have trachytic composition and were correlated to Astroni (ca. 4.2 cal. ka BP), Agnano Monte Spina (ca. 4.5 cal. ka BP) and Agnano Pomici Principali (ca. 12.3 cal. ka BP) eruptions of Campi Flegrei. The ages of tephra layers are in broad agreement with eight 14C accelerator mass spectrometric measurements carried out on plant remains and charcoal from the lake sediments at different depths along the two cores. The recognition of distal tephra layers from Italian volcanoes allowed the physical link of the Holocene archive of Lake Shkodra to other archives located in the central Mediterranean area and the Balkans (i.e. Lake Ohrid). Five of the recognised tephra layers were recognised for the first time in the Balkans area, and this has relevance for volcanic hazard assessment and for ash dispersal forecasting in case of renewed explosive activity from some of the southern Italy volcanoes. Copyright © 2009 John Wiley & Sons, Ltd.
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  • 4
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    Wiley-Blackwell
    In:  Journal of Quaternary Science, 24 (5). pp. 437-449.
    Publication Date: 2018-05-15
    Description: This paper presents a temperature reconstruction of the past 1000 years for Central Europe, based on chronological records. The advantages and limitations of this hermeneutic, text-based approach are discussed and the statistic methodology is introduced. Historical documents represent direct observation of weather and atmospheric conditions with highest temporal resolution available and precise dating. A major advantage of these extensive data is that they allow the reconstruction of large numbers of variables such as winter temperature, precipitation, pressure patterns or climate extremes as well as floods or storms. Within this hermeneutic climatological research approach, even human impacts and social dimensions of climate development can be examined. In order to quantify the historical information, statistical methods are applied, based on an index approach.
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  • 5
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    Wiley-Blackwell
    In:  Oikos, 27 (3). pp. 367-376.
    Publication Date: 2017-03-31
    Description: Some of the basic assumptions implied in the theory of limiting similarity of coexisting competitors were investigated experimentally in the case of three congeneric, deposit feeding snails. The species show character displacement with respect to size when coexisting. In experimental containers with a natural substrate, interspecific, exploitative competition between snails of the same size range is as intense as intraspecific competition. Diatoms of a given size range, which constitute the most important food, show a "logistic" growth response to grazing, and individual growth of the snails is linearly related to diatom density. The previous observation that the snails show size dependent selection for ingested particle sizes is extended to show that this mechanism leads to a real resource partitioning between snails of different sizes. Size frequency distribution of diatoms in the sediment is a function of the sizes of grazing snails. Size selection of ingested sand grains may also be significant for resource partitioning since the migration rate of the attached microflora between sand grains seems to be slow relative to its growth on the individual sand grains.
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  • 6
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    Wiley-Blackwell
    In:  Journal of Zoology, 170 (4). pp. 451-462.
    Publication Date: 2020-07-17
    Description: The dry weight and the crest length of the upper and lower beak, the length of the radula ribbon, the average width of the base of the six proximal and distal rachidian teeth as well as the total number of these teeth have all been related to the live body weight of octopuses between 1.1 and 4440 g. From any one of these parameters it is possible to estimate the size and approximate age of the animal.
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  • 7
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    Wiley-Blackwell
    In:  Journal of Zoology, 181 (4). pp. 527-559.
    Publication Date: 2020-07-17
    Description: Features of the brain of this oceanic squid have been investigated and related, as far as possible, to its habits and mode of life. The body and arms are much vacuolated for buoyancy and the animal probably lives with the head upwards. The very long whip-like tentacles are not vacuolated and perhaps hang downwards. They are covered by numerous minute pedunculated suckers, perhaps providing a sticky surface. A special nerve running outside the brain carries signals from the arms and tentacles to the magnocellular lobe, which is very large and of complex structure. However, there are no giant cells and the mantle is weak. Propulsion is mainly by the large fins, which are controlled from the magnocellular lobe, presumably using the information from the arms and tentacles.
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  • 8
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    Wiley-Blackwell
    In:  Marine Ecology, 28 (1). pp. 152-159.
    Publication Date: 2020-07-14
    Description: Meiobenthos densities and higher taxon composition were studied in an active gas seepage area at depths from 182 to 252 m in the submarine Dnieper Canyon located in the northwestern part of the Black Sea. The meiobenthos was represented by Ciliata, Foraminifera, Nematoda, Polychaeta, Bivalvia, Gastropoda, Amphipoda, and Acarina. Also present in the sediment samples were juvenile stages of Copepoda and Cladocera which may be of planktonic origin. Nematoda and Foraminifera were the dominant groups. The abundance of the meiobenthos varied between 2397 and 52,593 ind.·m−2. Maximum densities of Nematoda and Foraminifera were recorded in the upper sediment layer of a permanent H2S zone at depths from 220 to 250 m. This dense concentration of meiobenthos was found in an area where intense methane seeps were covered by methane-oxidizing microbial mats. Results suggest that methane and its microbial oxidation products are the factors responsible for the presence of a highly sulfidic and biologically productive zone characterized by specially adapted benthic groups. At the same time, an inverse correlation was found between meiofauna densities and methane concentrations in the uppermost sediment layers. The hypothesis is that the concentration of Nematoda and Foraminifera within the areas enriched with methane is an ecological compromise between the food requirements of these organisms and their adaptations to the toxic H2S.
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  • 9
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    Wiley-Blackwell
    In:  Journal of Zoology, 158 (4). pp. 475-483.
    Publication Date: 2020-07-17
    Description: An automatic food dispenser was designed for use with Octopus vulgaris Lamarck. One live crab was delivered each time the octopus pulled a white shape attached to the dispenser. The apparatus provided a continuous record of the time and frequency of feeding over periods of up to 15 days.
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  • 10
    Publication Date: 2017-12-19
    Description: This paper presents an event stratigraphy based on data documenting the history of vegetation cover, lake-level changes and fire frequency, as well as volcanic eruptions, over the Last Glacial–early Holocene transition from a terrestrial sediment sequence recovered at Lake Accesa in Tuscany (north-central Italy). On the basis of an age–depth model inferred from 13 radiocarbon dates and six tephra horizons, the Oldest Dryas–Bølling warming event was dated to ca. 14 560 cal. yr BP and the Younger Dryas event to ca. 12 700–11 650 cal. yr BP. Four sub-millennial scale cooling phases were recognised from pollen data at ca. 14 300–14 200, 13 900–13 700, 13 400–13 100 and 11 350–11 150 cal. yr BP. The last three may be Mediterranean equivalents to the Older Dryas (GI-1d), Intra-Allerød (GI-1b) and Preboreal Oscillation (PBO) cooling events defined from the GRIP ice-core and indicate strong climatic linkages between the North Atlantic and Mediterranean areas during the last Termination. The first may correspond to Intra-Bølling cold oscillations registered by various palaeoclimatic records in the North Atlantic region. The lake-level record shows that the sub-millennial scale climatic oscillations which punctuated the last deglaciation were associated in central Italy with different successive patterns of hydrological changes from the Bølling warming to the 8.2 ka cold reversal. Copyright © 2006 John Wiley & Sons, Ltd.
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  • 11
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    Wiley-Blackwell
    In:  Journal of Zoology, 188 (1). pp. 53-67.
    Publication Date: 2020-07-17
    Description: The movements of the isolated buccal mass of Octopus vulgaris have been investigated. The beaks undergo rhythmic cycles of activity in the absence of applied stimulation and after electrical stimulation of the inter-buccal connective. Initial opening, closing, retraction and re-opening phases of movement are described. This cycle of movements is taken to resemble those in the intact animal. Anatomical and electrical evidence identifies the superior mandibular muscle as being partly responsible for the closing and retraction phases of movement. The inferior buccal ganglion determines the sequence of these buccal movements, but modification by sensory feed-back from the musculature is also implied. The preparation will allow a closer comparison of the control of movement in cephalopods and gastropods.
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  • 12
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    Wiley-Blackwell
    In:  Journal of Zoology, 179 (1). pp. 19-83.
    Publication Date: 2020-07-17
    Description: Taonius megalops is a neutrally buoyant oceanic squid, very different in form when young and old. The young, has a round, sac-like mantle and relatively long tentacles, while the adult has an elongated cone-like mantle and relatively short tentacles. The transition in shape and form is gradual and has been followed in animals of between 3 and 180 mm dorsal mantle length. Statistical tests on various parameters investigated, both external and internal, revealed good correlation with the dorsal mantle length and confirmed the descriptions of the development of the chromatophores and subocular light organs with growth. It was concluded that these animals, captured in the Atlantic Ocean, all belonged to the species T. megalops Prosch 1849. This study has permitted us to suggest a tentative outline of the life cycle, although no adults were present in the material available.
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  • 13
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    Wiley-Blackwell
    In:  Journal of Zoology, 202 (3). pp. 441-447.
    Publication Date: 2020-07-17
    Description: A crab which has been captured and paralysed by an octopus but retrieved 1 1/2 min later cannot at first be pulled apart by the experimenter: 27 min later it can be dismembered easily. This demonstrates that there is external digestion when Octopus vulgaris feeds upon crabs. However, it is strictly limited at this stage to the arthrodial membrane and the musculo-skeletal attachment mechanisms as the exoskeleton separates at the joints allowing the muscles to be drawn out of the appendages. And yet, two hours after capture, pieces of crab meat are still recognizable in the octopus's stomach. The process of paralysing and cleaning a crab was noticeably slowed after the surgical removal of the radula, salivary papilla or the lateral buccal palps.
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  • 14
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    Wiley-Blackwell
    In:  Journal of Zoology, 150 (1). pp. 1-9.
    Publication Date: 2020-07-17
    Description: The changes in body weight of 12 octopuses, fed on fish or crabs, were followed under laboratory conditions for periods of 1 to 7 1/2 months. The food intake was estimated and compared with the changes in body weight of the octopuses; 25 to 55% of the total intake of food appeared to be incorporated. The range of the average increase in weight over the whole observation period of each of the animals was 1.9 to 7.7g per day (1 to 7 1/2 months); the mean value was 4.8g per day. The effect of changing the diet of small octopuses (fish or crab)was followed for four weeks but there was no evidence that alteration of the diet affected the rate of changes in body weight of animals of more than 47g initial body weight.
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  • 15
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    Wiley-Blackwell
    In:  Magnetic Resonance in Chemistry, 45 (12). pp. 1072-1075.
    Publication Date: 2020-07-15
    Description: Diosmetin, 5,7,3′-trihydroxy-4′-methoxyflavone shows chemopreventive, antimutagenic, and antiallergic effects. On the other hand, chrysoeriol, 5,7,4′-trihydroxy-3′-methoxyflavone induced nodABC-lacZ in Rhizobium meliloti. Both of them belong to hydroxymethoxy- flavones. One major difference between diosmetin and chrysoeriol is the substituted position of hydroxyl and methoxyl groups. In order to elucidate the relationships between their structures and activity, one of the first things to be done is the determination of their structures. However, most flavones occur widely in nature, and thus it is difficult to obtain in sufficient amounts from natural sources to identify their structures. Assignments of NMR data of several hydroxymethoxyflavones may help us to identify novel flavonoid compounds isolated from natural sources based on their NMR experiments. Therefore, we report here the complete assignments of 1H and 13C NMR data of 13 hydroxymethoxyflavones.
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  • 16
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    Wiley-Blackwell
    In:  Journal of Zoology, 186 (1). pp. 95-108.
    Publication Date: 2020-07-17
    Description: Reproductive mechanisms in the seven species of the thecosomatous pteropod genus Limacina are described and compared. All species are protandrous hermaphrodites. Five species–L. bulimoides, L. helicina, L. lesueuri, L. retroversa and L. trochiformis–have a similar reproductive anatomy in which the gonoduct leading from the gonad to the common genital pore functions as a seminal vesicle in the male and is elaborated into mucous and albumen glands in the female. The male system consists of a prostate gland and penis connected to the common genital pore by an external ciliary tract. All five species have a free-swimming veliger stage which hatches from free-floating egg masses. Limacina helicoides has the same reproductive anatomy but is ovoviviparous, with embryos retained in capsules in the mucous gland until they are juveniles of 50 mm in shell diameter. Limacina inflata lacks mucous and albumen glands and a penis; a spermatophore formed by the prostate gland is used in aphallic sperm transfer. This species exhibits brood protection with un-encapsulated embryos retained in the mantle cavity until they are released as veligers measuring 0067 mm in diameter. L. inflata is the most abundant of the seven species despite lowered fecundity; reasons for its ecological success are discussed.
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  • 17
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    Wiley-Blackwell
    In:  In: Biofouling. , ed. by Dürr, S. and Thomason, J. Wiley-Blackwell, Weinheim, pp. 73-86. ISBN 978-1-4051-6926-4
    Publication Date: 2012-02-23
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  • 18
    Publication Date: 2020-07-24
    Description: Myrionecta rubra, a ubiquitous planktonic ciliate, has received much attention due to its wide distribution, occurrence as a red tide organism, and unusual cryptophyte endosymbiont. Although well studied in coastal waters, M. rubra is poorly examined in the open ocean. In the Irminger Basin, North Atlantic, the abundance of M. rubra was 0–5 cells/ml, which is low compared with that found in coastal areas. Distinct patchiness (100 km) was revealed by geostatistical analysis. Multiple regression indicated there was little relationship between M. rubra abundance and a number of environmental factors, with the exception of temperature and phytoplankton biomass, which influenced abundance in the spring. We also improve on studies that indicate distinct size classes of M. rubra; we statistically recognise four significantly distinct width classes (5–16, 12–23, 18–27, 21–33 μm), which decrease in abundance with increasing size. A multinomial logistic regression revealed the main variable correlated with this size distribution was ambient nitrate concentration. Finally, we propose a hypothesis for the distribution of sizes, involving nutrients, feeding, and dividing of the endosymbiont.
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  • 19
    Publication Date: 2015-10-06
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  • 20
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    Wiley-Blackwell
    In:  Oikos, 33 (2). pp. 316-322.
    Publication Date: 2015-10-06
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  • 21
    Publication Date: 2020-07-27
    Description: Understanding the influence of growth temperature and carbon dioxide (CO2) on seed quality in terms of seed composition, subsequent seedling emergence and early seedling vigour is important under present and future climates. The objective of this study was to determine the combined effects of elevated temperature and CO2 during seed-filling of parent plants on seed composition, subsequent seedling emergence and seedling vigour of red kidney bean (Phaseolus vulgaris). Plants of cultivar ‘Montcalm’, were grown at daytime maximum/nighttime minimum sinusoidal temperature regimes of 28/18 and 34/24 °C at ambient CO2 (350 μmol mol−1) and at elevated CO2 (700 μmol mol−1) from emergence to maturity. Seed size and seed composition at maturity and subsequent per cent emergence, early seedling vigour (rate of development) and seedling dry matter production were measured. Elevated CO2 did not influence seed composition, emergence, or seedling vigour of seeds produced either at 28/18 or 34/24 °C. Seed produced at 34/24 °C had smaller seed size, decreased glucose concentration, but significantly increased concentrations of sucrose and raffinose compared to 28/18 °C. Elevated growth temperatures during seed production decreased the subsequent per cent emergence and seedling vigour of the seeds and seedling dry matter production of seed produced either at ambient or elevated CO2.
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  • 22
    Publication Date: 2015-09-01
    Description: Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is a high spatial resolution analytical method which has been applied to the analysis of silicic tephras. With current instrumentation, around 30 trace elements can be determined from single glass shards as small as ∼ 40 µm, separated from tephra deposits. As a result of element fractionation during the ablation process using a 266 nm laser, a relatively complex calibration strategy is required. Nonetheless, such a strategy gives analyses which are accurate (typically within ±5%) and have an analytical precision which varies from ∼ ±2% at 100 ppm, to ∼ ±15% at 1 ppm. Detection limits for elements used in correlation and discrimination studies are well below 1 ppm. Examples of the application of trace element analysis by LA-ICP-MS in tephra studies are presented from the USA, New Zealand and the Mediterranean. Improvements in instrumental sensitivity in recent years have the potential to lower detection limits and improve analytical precision, thus allowing the analysis of smaller glass shards from more distal tephras. Laser systems operating at shorter wavelengths (e.g. 193 nm) are now more widely available, and produce a much more controllable ablation in glasses than 266 nm lasers. Crater sizes of 〈10 µm are easily achieved, and at 193 nm many of the elemental fractionation issues which mar longer wavelengths are overcome. By coupling a short wavelength laser to a modern ICP-MS it should be possible to determine the trace element composition of glass shards as small as 20 µm and, providing sample preparation issues can be overcome, the determination of the more abundant trace elements in glass shards as small as 10 µm is within instrumental capabilities. This will make it possible to chemically fingerprint tephra deposits which are far from their sources, and will greatly extend the range over which geochemical correlation of tephras can be undertaken.
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  • 23
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    Wiley-Blackwell
    In:  Journal of Fish Biology, 75 (5). pp. 960-996.
    Publication Date: 2015-09-14
    Description: Absolute barriers to dispersal are not common in marine systems, and the prevalence of planktonic larvae in marine taxa provides potential for gene flow across large geographic distances. These observations raise the fundamental question in marine evolutionary biology as to whether geographic and oceanographic barriers alone can account for the high levels of species diversity observed in marine environments such as coral reefs, or whether marine speciation also operates in the presence of gene flow between diverging populations. In this respect, the ecological hypothesis of speciation, in which reproductive isolation results from divergent or disruptive natural selection, is of particular interest because it may operate in the presence of gene flow. Although important insights into the process of ecological speciation in aquatic environments have been provided by the study of freshwater fishes, comparatively little is known about the possibility of ecological speciation in marine teleosts. In this study, the evidence consistent with different aspects of the ecological hypothesis of speciation is evaluated in marine fishes. Molecular approaches have played a critical role in the development of speciation hypotheses in marine fishes, with a role of ecology suggested by the occurrence of sister clades separated by ecological factors, rapid cladogenesis or the persistence of genetically and ecologically differentiated species in the presence of gene flow. Yet, ecological speciation research in marine fishes is still largely at an exploratory stage. Cases where the major ingredients of ecological speciation, namely a source of natural divergent or disruptive selection, a mechanism of reproductive isolation and a link between the two have been explicitly documented are few. Even in these cases, specific predictions of the ecological hypothesis of speciation remain largely untested. Recent developments in the study of freshwater fishes illustrate the potential for molecular approaches to address specific questions related to the ecological hypothesis of speciation such as the nature of the genes underlying key ecological traits, the magnitude of their effect on phenotype and the mechanisms underlying their differential expression in different ecological contexts. The potential provided by molecular studies is fully realized when they are complemented with alternative (e.g. ecological, theoretical) approaches.
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  • 24
    Publication Date: 2020-04-28
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  • 25
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    Wiley-Blackwell
    In:  Geofluids, 6 . pp. 241-250. Date online first: 2006
    Publication Date: 2017-08-02
    Description: Groundwater seeps are known to occur in Eckernförde Bay, Baltic Sea. Their discharge rate and dispersion were investigated with a new schlieren technique application, which is able to visualize heterogeneous water parcels with density anomalies down to Drt ¼ 0.049 on the scale of millimeters. With the use of an inverted funnel, discharged fluids can be captured and the outflow velocity can be determined. Overall, 46 stations could be categorized by three different cases: active vent sites, seep-influenced sites, and non-seep sites. New seep locations were discovered, even at shallow near-shore sites, lacking prominent sediment depression, which indicate submarine springs. The detection of numerous seeps was possible and the groundwater-influenced area was defined to be approximately 6.3 km2. Flow rates of between 0.05 and 0.71 l m)2 min)1 were measured. A single focused fluid plume, which was not disturbed by the funnel was recorded and revealed a flux of 59.6 ± 20 ml cm)2 min)1 and it was calculated that this single focused plume would be strong enough to produce a flow rate through the funnel of 1.32 ± 0.44 l m)2 min)1. The effect of different seep-meter funnel sizes is discussed.
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  • 26
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    Wiley-Blackwell
    In:  Journal of Fish Biology, 12 (4). pp. 311-323.
    Publication Date: 2017-07-11
    Description: In brackish water the variety of marine and freshwater parasite species is considerably reduced. The distribution in brackish water of most marine endoparasites is restricted by the salinity tolerance of their hosts, most of the parasite species are more tolerant than their hosts. The influence of salinity and temperature on nine species has been examined; first stage larvae of Contracaecum aduncum develop in 0-32‰ salinity; Cryptocotyle lingua proved to be infective at salinities down to 4‰. The greatest resistance was found in Anisakis larvae from herring Clupea harengus, which survived for more than half a year. Parasites in the fish intestines appear to be unaffected by changing water salinities, as the osmolarity in the intestines stays nearly constant. Marine ectoparasites (Acanthochondria depressa, Lepeophtheirus pectoralis) survive about three times longer than freshwater species (Piscicola geometra, Argulus foliaceus) when salinity is 16‰. High temperature increases the effects of adverse salinities on parasites. There is evidence that none of these ecto-parasitic species can develop within the range of 7-20‰ salinity.
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  • 27
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    Wiley-Blackwell
    In:  In: Biofouling. , ed. by Dürr, S. and Thomason, J. Wiley-Blackwell, Weinheim, pp. 100-108. ISBN 978-1-4051-6926-4
    Publication Date: 2012-02-23
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  • 28
    Publication Date: 2017-01-31
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  • 29
    Publication Date: 2016-06-29
    Description: Quantitative X-ray diffraction analysis of the 〈2mm sediment fraction was carried out on 1257 samples (from the seafloor and 16 cores) from the Iceland shelf west of 188 W. All but one core (B997-347PC) were from transects along troughs on theNW to N-central shelf, an area that in modern and historic times has been affected by drift ice. The paper focuses on the non-clay mineralogy of the sediments (excluding calcite and volcanic glass). Quartz and potassium feldspars occupy similar positions in an R-mode principal component analysis, and oligoclase feldspar tracks quartz; these minerals are used as a proxy for ice-rafted detritus (IRD). Accordingly, the sum of these largely foreign minerals (Q&K) (to Icelandic bedrock) is used as a proxy for drift ice. A stacked, equi-spaced 100 a record is developed which shows both low-frequency trends and higher-frequency events. The detrended stacked record compares well with the flux of quartz (mg cm-2 a-1) at MD99-2269 off N Iceland. The multi-taper method indicated that there are three significant frequencies at the 95% confidence level with periods of ca. 2500, 445 and 304 a. Regime shift analysis pinpoints intervals when there was a statistically significant shift in the average Q&K weight %, and identifies four IRDrich events separated by intervals with lower inputs. There is some association between peaks of IRD input, less dense surface waters (from d18O data on planktonic foraminifera) and intervals of moraine building.
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  • 30
    Publication Date: 2017-09-14
    Description: An experimental study was performed to disentangle parental and environmental effects on the growth of Atlantic cod Gadus morhua larvae and juveniles. Eggs were collected during the spawning season from spawning pairs (families) kept separately in specially designed spawning compartments. Newly hatched larvae were released simultaneously into two mesocosms of 2500 and 4400 m3. Larval growth was monitored by sampling over a 10 week period, after which juveniles were transferred to on-growing tanks, where they were tagged and kept for up to 2 years. Maternal origin was determined by individual microsatellite genotyping of the larvae (n = 3949, 24 families) and juveniles (n = 600). The results showed significant positive correlations between egg size and larval size during the whole mesocosm period. Correlations, however, weakened with time and were no longer significant at the first tank-rearing sampling at an age of 9 months. Significant family-specific differences in growth were observed. The coefficient of variation (c.v.) was calculated in order to examine variation in standard length of larvae during the mesocosm period. Inter-family c.v. was on average 69% of intra-family c.v. Differences in zooplankton densities between the two mesocosms were reflected in larval growth, condition factor and c.v. Low food abundance appeared to reduce c.v. and favour growth of larvae that showed relatively slow growth at high food abundance. It is suggested that genetically determined variation in growth potential is maintained by environmental variability.
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  • 31
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    Wiley-Blackwell
    In:  International Journal of Climatology, 29 (12). pp. 1731-1744.
    Publication Date: 2020-03-19
    Description: The annual cycle of extreme 1-day precipitation events across the UK is investigated by developing a statistical model and fitting it to data from 689 rain gauges. A generalized extreme-value distribution (GEV) is fit to the time series of monthly maxima, across all months of the year simultaneously, by approximating the annual cycles of the location and scale parameters by harmonic functions, while keeping the shape parameter constant throughout the year. We average the shape parameter of neighbouring rain gauges to decrease parameter uncertainties, and also interpolate values of all model parameters to give complete coverage of the UK. The model reveals distinct spatial patterns for the estimated parameters. The annual mean of the location and scale parameter is highly correlated with orography. The annual cycle of the location parameter is strong in the northwest UK (peaking in late autumn or winter) and in East Anglia (where it peaks in late summer), and low in the Midlands. The annual cycle of the scale parameter exhibits a similar pattern with strongest amplitudes in East Anglia. The spatial patterns of the annual cycle phase suggest that they are linked to the dominance of frontal precipitation for generating extreme precipitation in the west and convective precipitation in the southeast of the UK. The shape parameter shows a gradient from positive values in the east to negative values in some areas of the west. We also estimate 10-year and 100-year return levels at each rain gauge, and interpolated across the UK.
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  • 32
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    Wiley-Blackwell
    In:  Journal of Zoology, 210 (1). pp. 137-147.
    Publication Date: 2020-07-17
    Description: Epipelagic pterotracheid heteropods and young cranchiid squids rely primarily on transparency for concealment; yet they have opaque structures, the eyes and visceral organs that compose the visceral nuclei, which can only be camouflaged in other ways. These two groups have achieved convergent solutions to this problem. The visceral nucleus has a narrow and conical shape and a covering layer of iridophores that lies parallel to the surface of the organ. The eyes also have iridophore layers and tapered shapes. A minimal ventral silhouette results when the long axes of the visceral nucleus and eyes are oriented vertically, with the narrowest ends directed downward. In pterotracheids, this is actively achieved by tilting the nucleus and eyes and flexing the body and proboscis. In cranchiids, tilting of the organs alone suffices and adjustments are accomplished much more rapidly than in the pterotracheids.
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  • 33
    Publication Date: 2016-07-28
    Description: Coccoliths were studied from the ODP Hole 1002C and core PL07-39PC in the Cariaco Basin. Increases in Emiliania huxleyi are synchronous with decreases of Gephyrocapsa oceanica and vice versa. A new index (GEX) based on the relative abundances of these two taxa is proposed, and correlates with various other proxies. It is shown that GEX can serve as upwelling proxy. This confirms that the Intertropical Convergence Zone shifted north during the Bølling/Allerød, south during the Younger Dryas and back north during the Preboreal. The upwelling proxy shows few discrepancies with the terrigenous record.
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  • 34
    Publication Date: 2016-05-27
    Description: A visible tephra horizon in the NGRIP ice core has been identified by geochemical analysis as the Fugloyarbanki Tephra, a widespread marker horizon in marine cores from the Faroe Islands area and the northern North Atlantic. An age of 26 740 ± 390 yr b2k (1s uncertainty) is derived for this tephra according to the new Greenland Ice Core Chronology (GICC05) based on multiparameter counting of annual layers. Detection of this tephra for the first time within the NGRIP ice core provides a key tie-point between marine and ice-core records during the transition between MIS 3 and 2. Identification of this volcanic event within the Greenland records demonstrates the future potential of using tephrochronology to precisely correlate palaeoarchives in widely separated localities that span the last glacial period, as well as providing a potential method for examining the extent of the radiocarbon marine reservoir effect at this time.
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  • 35
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    Wiley-Blackwell
    In:  Journal of Zoology, 207 (4). pp. 511-519.
    Publication Date: 2020-07-17
    Description: A study of the diet of Sepia officinalis and S. elegans in the Ria de Vigo has shown that crustaceans are the most abundant prey in both species, followed by fish. Changes in the food composition of both species occur with growth. The type of prey eaten by the two sexes of these species is very similar. The possibility of trophic competition between juveniles of S. qficinalis and S. elegans is discussed.
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  • 36
    Publication Date: 2017-10-05
    Description: Natural communities are constantly changing due to a variety of interacting external processes and the temporal occurrence and intensity of these processes can have important implications for the diversity and structure of marine sessile assemblages. In this study, we investigated the effects of temporal variation in a disturbance regime, as well as the specific timing of events within different regimes, on the composition and diversity of marine subtidal fouling assemblages. We did this in a multi-factorial experiment using artificial settlement tiles deployed at two sites on the North East coast of England. We found that although there were significant effects of disturbances on the composition of assemblages, there were no effects of either the variation in the disturbance regime or the specific timing of events on the diversity or assemblage composition at either site. In contrast to recent implications we conclude that in marine fouling assemblages, the variability in disturbance regimes (as a driving force) is unimportant, while disturbance itself is an important force for structuring robust ecosystems.
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  • 37
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    Wiley-Blackwell
    In:  In: Microbial Ecology of the Oceans. Wiley-Blackwell, Hoboken, NJ, pp. 383-441. 2. Edition ISBN 978-0-470-04344-8
    Publication Date: 2019-12-06
    Type: Book chapter , NonPeerReviewed
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  • 38
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    Wiley-Blackwell
    In:  Fish and Fisheries, 9 (4). pp. 450-461.
    Publication Date: 2016-12-13
    Description: Archived scales and otoliths constitute a unique source of DNA that potentially enables extension of the temporal scale of genetic studies of fish populations by decades and even centuries. We review recent insights into fish population and conservation genetics obtained using analysis of DNA from archived samples. This involves both new knowledge about demographic parameters and population structure in wild populations and insights into consequences of anthropogenic pressure resulting from over-harvesting, habitat degradation and stocking. We show that the latter category of studies have led to significant changes of management practices. Ongoing improvement of genetic methods will undoubtedly further expand the ability to utilize historical DNA samples. We envisage that temporal comparisons of large numbers of coding genes will lead to novel insights into selective responses of fish populations to anthropogenic challenges, particularly fisheries-induced selection and global warming. However, both acquisition and storage of historical DNA samples can be hurdles to temporal genetic analyses, while degradation and low copy number in historical DNA samples render genetic data from such sources prone to technical artefacts. We summarize recommendations for storage of samples and DNA extraction and provide checklists for validation of genotyping results. Finally, we stress that validation procedures also involve documentation of the time and population of origin of historical samples, and the inferences drawn should account for the technical and statistical uncertainties associated with historical DNA analysis.
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  • 39
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    Wiley-Blackwell
    In:  Limnology and Oceanography, 23 (4). pp. 735-739.
    Publication Date: 2020-11-05
    Description: The effects of hydrostatic pressure and dissolved oxygen concentration on oxygen consumption rates were examined in the mesopelagic, vertically migrating squid Histioteuthis heteropsis from southern California offshore waters. Elevated hydrostatic pressure (to 136 atm) had no significant effects on oxygen consumption rates at 5°C. Lox oxygen concentrations (〈0.5 ml O2 liter -1) depressed rates of oxygen consumption. These findings suggest that biosis may be necessary to supply the total nergy needs of this species at daytime depths in the oxygen minumum layer off southern California.
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  • 40
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    Wiley-Blackwell
    In:  Journal of Quaternary Science, 21 (6). pp. 645-675.
    Publication Date: 2018-10-22
    Description: Intra‐plate volcanism in western Europe shows statistically significant episodicity during the Quaternary period. By comparing the known ages for eruptions in France and Germany, which are compiled here, with a composite oxygen isotope record, we have investigated the link between this episodic volcanism and the climate record over the last two million years. We show that increased volcanism between 415–400 ka and 17–5 ka correlates with warming phases at the end of the last Weichselian (Devensian) and earlier Elsterian (Anglian) glacial stages. The three significant caldera explosions in the eastern Eifel, Germany, are all associated with warming phases at the onset of interglacials. The growth and decay of nearby ice sheets suggest that surface changes in continental mass distribution during glacial Milankovich cycles could provide a mechanism for this correlation by means of the distal effects of flexural loading on the lithosphere.
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  • 41
    Publication Date: 2017-09-14
    Description: An analysis of mass (M) and standard length (LS) data for larval, juvenile and adult sprat (Sprattus sprattus; Clupeidae) revealed marked changes in the allometric scaling factor (b in inline image). For sprat 〈44 mm LS, b was 5·0, whereas in larger juveniles and adults, b was c. 3·4 indicating a relatively protracted metamorphic period for this species.
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  • 42
    Publication Date: 2019-09-11
    Description: To investigate and disentangle the role of major histocompatibility complex (MHC)‐based ‘good genes' and ‘compatible genes' in mate choice, three‐spined sticklebacks Gasterosteus aculeatus with specific MHC IIB genotypes were allowed to reproduce in an outdoor enclosure system. Here, fish were protected from predators but encountered their natural parasites. Mate choice for an intermediate genetic distance between parental MHC genotypes was observed, which would result in intermediate diversity in the offspring, but no mate choice based on good genes was found under the current semi‐natural conditions. Investigation of immunological variables revealed that the less‐specific innate immune system was more active in individuals with a genetically more divergent MHC allele repertoire. This suggests the need to compensate for an MHC‐diminished T‐cell repertoire and potentially explains the observed mate choice for intermediate MHC genetic distance. The present findings support a general pattern of mate choice for intermediate MHC diversity (i.e. compatible genes). In addition, the potentially dynamic role of MHC good genes in mate choice under different parasite pressures is discussed in the light of present and previous results.
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  • 43
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    Wiley-Blackwell
    In:  Journal of Fish Biology, 75 . pp. 290-294.
    Publication Date: 2017-09-14
    Description: Individual behaviour of Atlantic cod Gadus morhua in the presence of hypoxic water was measured in situ in the vertically stratified Bornholm Basin of the Baltic Sea. Considering all recaptured individuals, the use of hypoxic habitat was comparable to data derived by traditional survey data, but some G. morhua had migrated towards the centre of the c.100 m deep basin and spent about a third of their time at oxygen saturation 〈50%, possibly to forage on zoobenthos. Maximal residence time per visit in such hypoxic water was limited to a few hours, allowing for the digestion of consumed prey items in waters with sufficient dissolved oxygen.
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  • 44
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    Wiley-Blackwell
    In:  Journal of Fish Biology, 67 . pp. 1585-1602.
    Publication Date: 2017-09-14
    Description: The seasonal growth trajectories of wild Atlantic salmon Salmo salar juveniles by age group within the Margaree River, Canada, are described. Circuli counts from scales were used to infer growth rates at different ages and these were used to predict the proportions of age 2‐ and 3‐year old smolts from different portions of the watershed. In the wild Atlantic salmon juveniles from the Margaree River, there was no bimodality in fork length frequencies and no 1 year old smolts were produced. Water temperature differences during the growing season were insufficient to explain the differences in growth rates and size at age among the sites sampled. There was a positive association between the growth rate in the first year and the subsequent age at smoltification. In the Margaree River, differences in tributary specific growth rates and size at age were expected to produce important differences in the relative ages at smoltification.
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  • 45
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    Wiley-Blackwell
    In:  Oikos, 117 (5). pp. 754-762.
    Publication Date: 2019-09-23
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  • 46
    Publication Date: 2020-03-20
    Description: Speciation and the maintenance of recently diverged species has been subject of intense research in evolutionary biology for decades. Although the concept of ecological speciation has been accepted, its mechanisms and genetic bases are still under investigation. Here, we present a mechanism for speciation that is orchestrated and strengthened by parasite communities acting on polymorphic genes of the immune system. In vertebrates, these genes have a pleiotropic role with regard to parasite resistance and mate choice. In contrasting niches, parasite communities differ and thus the pools of alleles of the adapted major histocompatibility complex (MHC) also differ between niches. Mate choice for the best‐adapted MHC genotype will favour local adaptations and will accelerate separation of both populations: thus immune genes act as pleiotropic speciation genes –‘magic traits’. This mechanism should operate not only in sympatric populations but also under allopatry or parapatry. Each individual has a small subset of the many MHC alleles present in the population. If all individuals could have all MHC alleles from the pool, MHC‐based adaptation is neither necessary nor possible. However, the typically small optimal individual number of MHC loci thus enables MHC‐based speciation. Furthermore, we propose a new mechanism selecting against species hybrids. Hybrids are expected to have super‐optimal individual MHC diversity and should therefore suffer more from parasites in all habitats.
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  • 47
    Publication Date: 2017-01-31
    Description: Human activities have differentially altered biogeochemical cycling at local, regional and global scales. We propose that a stoichiometric approach, examining the fluxes of multiple elements and the ratio between them, may be a useful tool for better understanding human effects on ecosystem processes and services. The different scale of impacts of the elements carbon, nitrogen and phosphorus and the different nature of their biogeochemical cycles, imply a large variation of their stoichiometric ratios in space and time and thus divergent impacts on biota. In this paper, we examine the effects of anthropogenic perturbations on nutrient ratios in ecosystems in two examples and one case study. Altered stoichiometry in agricultural systems (example 1) can affect not only crop yield and quality but also the interactions between plants and their pollinators, pests and pathogens. Human activities have also altered stoichiometry in coastal ecosystems (example 2). Increased N loading has especially lead to increased N:P and reduced Si:N ratios, with detrimental effects on ecosystem services derived from coastal pelagic food webs, such as fish yield and water quality. The terrestrial–aquatic linkage in stoichiometric alterations is illustrated with a case study, the Mississippi River watershed, where anthropogenic activities have caused stoichiometric changes that have propagated through the watershed into the northern Gulf of Mexico. Coupled with altered stoichiometric nutrient inputs are the inherent differences in variation and sensitivity of different ecosystems to anthropogenic disturbance. Furthermore, the connections among the components of a watershed may result in downstream cascades of disrupted functioning. Applying a multiple element perspective to understanding and addressing societal needs is a new direction for both ecological stoichiometry and sustainability.
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  • 48
    Publication Date: 2021-06-22
    Description: In this work, we analyse continuous measurements of microseisms to assess the reliability of the fundamental resonance frequency estimated by means of the horizontal-to-vertical (H/V) spectral ratio within the 0.1–1 Hz frequency range, using short-period sensors (natural period of 1 s). We apply the H/V technique to recordings of stations installed in two alluvial basins with different sedimentary cover thicknesses—the Lower Rhine Embayment (Germany) and the Gubbio Plain (Central Italy). The spectral ratios are estimated over the time–frequency domain, and we discuss the reliability of the results considering both the variability of the microseism activity and the amplitude of the instrumental noise. We show that microseisms measured by short period sensors allow the retrieval of fundamental resonance frequencies greater than about 0.1–0.2 Hz, with this lower frequency bound depending on the relative amplitude of themicroseism signal and the self-noise of the instruments. In particular,we show an examplewhere the considered short-period sensor is connected to instruments characterized by an instrumental noise level which allows detecting only fundamental frequencies greater than about 0.4 Hz. Since the frequency at which the peak of the H/V spectral ratio is biased depends upon the seismic signal-to-instrument noise ratio, the power spectral amplitude of instrumental self-noise should be always considered when interpreting the frequency of the peak as the fundamental resonance frequency of the investigated site.
    Description: Published
    Description: 175-184
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: open
    Keywords: site effects ; fourier analysis ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2017-04-04
    Description: Geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of Monticchio, Southern Italy. These lakes are located in two maars that formed 140 000 years ago during Mt. Vulture volcano s last eruptive activity. Isotopic analyses suggest that CO2 and helium are of magmatic origin; the latter displays 3He ⁄ 4He isotope ratios similar to those measured in olivines of the maar ejecta. In spite of the fact that the amount of dissolved gases in the water is less than that found in Lake Nyos (Cameroon), both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites, even though they are located in a region currently considered inactive. This could be of special significance in very popular tourist areas such as the Monticchio lakes, which are visited by about 30 000 people throughout the summer, for the most part on Sundays.
    Description: Published
    Description: 83-87
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic gases ; gas hazard ; crater lakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 50
    Publication Date: 2017-04-04
    Description: On 2009 April 6, the Central Apennines were hit by an Mw = 6.3 earthquake. The region had been shaken since 2008 October by seismic activity that culminated in two foreshocks with Mw 〉 4, 1 week and a few hours before the main shock. We computed seismic moment tensors for 26 events with Mw between 3.9 and 6.3, using the Regional Centroid Moment Tensor (RCMT) scheme. Most of these source parameters have been computed within 1 hr after the earthquake and rapidly revised successively. The focal mechanisms are all extensional, with a variable and sometimes significant strike-slip component. This geometry agrees with the NE–SW extensional deformation of the Apennines, known from previous seismic and geodetic observations. Events group into three clusters. Those located in the southern area have larger centroid depths and a wider distribution of T-axis directions. These differences suggest that towards south a different fault systemwas activated with respect to the SW-dipping normal faults beneath L’Aquila and more to the north.
    Description: In press
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: JCR Journal
    Description: open
    Keywords: moment tensor ; seismotectonics ; L'Aquila ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 51
    Publication Date: 2017-04-04
    Description: The strong motion data of 2009 April 6 L’Aquila (Central Italy) earthquake (Mw = 6.3) and of 12 aftershocks (4.1 ≤ Mw ≤ 5.6) recorded by 56 stations of the Italian strong motion network are spectrally analysed to estimate the source parameters, the seismic attenuation, and the site amplification effects. The obtained source spectra for S wave have stress drop values ranging from 2.4 to 16.8 MPa, being the stress drop of the main shock equal to 9.2 MPa. The spectral curves describing the attenuation with distance show the presence of shoulders and bumps, mainly around 50 and 150 km, as consequence of significant reflected and refracted arrivals from crustal interfaces. The attenuation in the first 50 km is well described by a quality factor equal to Q( f ) = 59 f 0.56 obtained by fixing the geometrical spreading exponent to 1. Finally, the horizontal-to-vertical spectral ratio provides unreliable estimates of local site effects for those stations showing large amplifications over the vertical component of motion.
    Description: Published
    Description: 1573–1579
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: open
    Keywords: Generalized inversion ; strong-motion ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 52
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 1-25 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Molecular theories of polymer rheology are reviewed with emphasis on predictions of the more familiar properties: non-Newtonian viscosity and normal stress in steady shear, complex viscosity in oscillatory shear, and elongational viscosity in extensional flow. Both dilute and concentrated solutions are discussed, with emphasis on the former. An important objective is clarification of polymer modeling strategies and how they are related to polymer structure. The intended readership consists of those engineers familiar in a general way with continuum polymer rheology, but with no special expertise in polymer physical or theoretical chemistry.
    Additional Material: 6 Ill.
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  • 53
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 58-61 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is shown that a pulse-response technique can be used with the Wicke-Kallenbach type of diffusion cell to determine effective diffusivities in catalyst pellets. The diffusivity is a function of the retention time of the pulse of diffusing gas in the pellet. Experimental values obtained with an alumina pellet agreed well with expected results for this type of material.
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  • 54
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 72-76 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Total pressure measurements taken for the ternay systems acetone-chloroform-methanol and chloroform-ethanol-n-heptane at 50°C are reduced by Barker's method and correlated by an equation similar to one proposed by Wohl (1953).
    Additional Material: 9 Ill.
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  • 55
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 77-83 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In most industrial applications the linear model used for optimization by linear programming involves significant uncertainties and inaccuracies in the model parameters. This paper presents a framework which allows uncertainties in the matrix elements of the linear program to be taken into account without requiring detailed knowledge of the statistical characterstics of these uncertainties. Three cases for the inequality constrained problem are considered: independent variations in the array elements, column dependent variations, and row dependent variations. In each case the problem can still be solved as a linear program. In the first two cases, the problem size is doubled, while for the row dependent case a finitely terminating cutting plane algorithm is constructed.
    Additional Material: 1 Tab.
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  • 56
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 96-102 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The transformation of the energy equation from the mass average to the volume average reference frame exposes a pseudo Dufour effect. The theoretical model for absorption into a stagnant liquid including this effect, the heat of absorption, variable density, an interfacial velocity, and an arbitrary equilibrium condition at the interface is able to predict experimental data over a wide range of conditions. The data consisted of liquid temperature profiles and mass transfer rates into a stagnant liquid. The ammonia-water system exhibited interfacial temperature rises from 6.9°K to 18.2°K. The interfacial temperature rise for the propane-decane system was 1.3°K. Simpler theoretical models were able to predict the mass transfer rates or the temperature profiles.
    Additional Material: 7 Ill.
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  • 57
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 109-115 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bubble size is one of the most important parameters in the design and simulation of a fluidized-bed reactor.A correlation of the bubble size and growth in fluidized beds of various diameters is developed. A maximum bubble diameter determined from the bubble coalescence is incorporated in the correlation to relate the effect of the bed diameter on the bubble size.Experimental data of bubble size reported are used to develop and test the validity of the correlation. The bubble diameters calculated using this correlation show good agreement with the observed bubble diameters.
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    AIChE Journal 21 (1975), S. 176-177 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 21 (1975), S. 181-183 
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    AIChE Journal 21 (1975), S. 187-189 
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    AIChE Journal 21 (1975), S. 198-200 
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    AIChE Journal 21 (1975), S. 203-203 
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    AIChE Journal 21 (1975), S. 206-206 
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    AIChE Journal 21 (1975), S. 372-379 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The objective of this study was to determine the mixing characteristics of two-phase, confined, coaxial jets. Gas composition, gas velocity, and particle mass flux radial profiles were obtained at different axial stations using 20% by weight of 6 or 30 μm spherical aluminum particles in the primary stream. Additional tests were conducted without particles. Radial profiles for gas composition, velocity, and particle flux were correlated using the principle of similarity. In the gas phase, mass mixed more rapidly than momentum, and the 6 μm particles mixed less rapidly than mass or momentum. Systems with low primary density and low secondary velocity mixed most rapidly. An implicit numerical model was developed to predict the rate of mixing of the gas/particle mixture. The model included coupled dynamic and thermal nonequilibrium effects between the gas and solid phases. Comparisons of model predictions and experimental results were good.
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    AIChE Journal 21 (1975), S. 534-540 
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    Notes: Gas absorption accompanied by instantaneous bimolecular reaction in turbulent liquids (Re 〉 1200) is treated in terms of an eddy diffusion model. The species balance equations are integrated for the eddy diffusivity varying as the square of the distance from the free surface. Experimental mass transfer coefficients were measured in a wetted-wall column for the absorption of carbon dioxide in aqueous sodium hydroxide solutions. Experimental results were obtained for carbon dioxide partial pressures of 1.0 and 1.5 atm. and for sodium hydroxide concentrations varying between 0.020 and 0.220 N over the Reynolds number range 1400 to 5400. The experimental data showed good agreement with the theoretical calculations, the mean deviation being 8.2%.
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    AIChE Journal 21 (1975), S. 567-571 
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    Notes: A new method of analyzing the behavior of dynamic systems containing time delays is presented. The method, which is based on the construction of a subsidiary system where the delayed state variables are approximated by Taylor series expansion, is simple and easy to apply. The stability and the region of stability of the subsidiary equation correspond closely to that of the original system.
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    AIChE Journal 21 (1975), S. 594-595 
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    AIChE Journal 21 (1975), S. 575-582 
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    Notes: The objective of this work is to experimentally examine mass transfer during liquid-liquid extraction in the system acetonitrile-benzene-n-heptane. The interfacial characteristics of the system are simultaneously investigated. (Part I deals with the diffusion properties of the system).The mass transfer experiments are conducted in a stirred extraction cell of the Lewis type. The transfer between an unsaturated and nearly saturated phase is studied. The mass transfer coefficients for the partially miscible binary system, and for those ternary experiments in which the slope of the operating line was negative are found to be independent of the driving force. A photographic investigation, which employed the schlieren technique, indicates that Marangoni-type instabilities are absent in such experiments. However, in ternary experiments, in which the slope of the operating line is positive and above a certain critical value the mass transfer coefficients decreases as equilibrium approached. The schlieren results confirm the presence of interfacial turbulence for this case.The driving-force dependence of the turbulent mass transfer coefficients is explaine using a surface renewal model. The model provides a correlation for the results of ternary experiments in which interfaical turbulence is present.
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    AIChE Journal 21 (1975), S. 597-598 
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    AIChE Journal 21 (1975), S. 604-606 
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    AIChE Journal 21 (1975), S. 613-615 
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    AIChE Journal 21 (1975), S. 623-623 
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    AIChE Journal 21 (1975), S. 623-623 
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    AIChE Journal 21 (1975), S. 560-566 
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    Notes: The limits of superheat of thirteen light hydrocarbons and four light halocarbons were experimentally measured at one atmosphere using a superheating column. While there was some variation in the number of degrees to which a compound could be superheated before boiling explosively, in all cases the reduced limits TL/Tc were close to 0.88. The measured superheat limits of three binary hydrocarbon systems and several ternary mixtures were close to mole fraction averages of the limits of the pure components. The results of both pure components and mixtures paralleled predictions of Beegle (1973), based on thermodynamic stability theory. Limits of pure components agreed closely with limits predicted from homogeneous nucleation theory.
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    AIChE Journal 21 (1975), S. 583-593 
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    Notes: Two classes of random waves exist on falling films at flow rates of practical interest; large waves which carry the bulk of the liquid and small waves which cover the substrate. In this paper statistics of the large waves are presented and compared with existing theory. These waves are bimodal in character at ReL 〉 700. The form drag of the large waves is shown to contribute negligibly the observed pressure drop in the gas phase. It is thus concluded that the small wave structure controls the fluid resistance and transfer processes in the gas while the large waves control these same processes in the liquid film.
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    AIChE Journal 21 (1975), S. 596-597 
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    AIChE Journal 21 (1975), S. 600-601 
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    AIChE Journal 21 (1975), S. 609-610 
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    AIChE Journal 21 (1975), S. 799-804 
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    Notes: This paper presents the development and real-time implementation of a time-optimal control algorithm for a continuous stirred-tank reactor. A multivariable time-optimal control law is derived and an Extended Kalman Filter formuated for on-line estimation and filtering. The work demonstrates the powerful capability of real-time computation and decision-making in optimal control and optimal estimation of process states.
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    AIChE Journal 21 (1975), S. 817-820 
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    AIChE Journal 21 (1975), S. 622-623 
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    AIChE Journal 21 (1975), S. 625-656 
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    Notes: Drag reduction by dilute solutions of linear, random-coiling macromolecules in turbulent pipe flow is reviewed. The experimental evidence is emphasized in three sections concerned with the graphical display of established features of the phenomenon, data correlation and analysis, and the physical mechanism of drag reduction.
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    AIChE Journal 21 (1975), S. 677-686 
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    Notes: This paper presents a unified approach for obtaining system reliability and availability parameters from block diagram representations of process systems. It starts with computer algorithms for obtaining the minimal paths in a system, then shows how this information can be combined with unit reliability data to obtain the overall system reliability, and the response of system reliability to changes in unit reliability (sensitivities). It then demonstrates how these sensitivities can be used to optimize the system reliability and availability by equipment redundancy. Extension of the methodology to the automated production of system fault trees as well as the mathematical relationship between fault trees and block diagrams are noted.
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    AIChE Journal 21 (1975), S. 706-713 
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    Notes: Liquid holdup and mass transfer rates were measured in a 2.58-cm I.D. tube, packed with glass beads and granular CuO · ZnO catalyst or β-naphthol particles, and operated as a trickle bed. Gas-to-liquid (water) transport coefficients were determined from absorption and desorption experiments with oxygen at 25°C and 1 atm. Liquid-to-particle mass transfer was studied using β-naphthol particles.Holdup and both mass transfer coefficients were unaffected by gas flow rate but increased with liquid rate. The data were correlated with equations that could be used for predicting mass transfer coefficients at high temperatures and pressures for use in the reaction studies reported in Part II.
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    AIChE Journal 21 (1975), S. 735-743 
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    Notes: A new method to reduce vapor-liquid equilibrium data of binary mixtures and to evaluate a thermodynamic model is presented. It is based on the principle of maximum likelihood. Deviations between all measured and predicted quantities are calculated and confidence limits in model parameters are evaluated from the given estimates of experimental errors. Many examples illustrate the practical applications of the method.
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    AIChE Journal 21 (1975), S. 763-769 
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    Notes: The reduction of oxygen in neutral saline solution and in seawater was studied using the rotating disk electrode (RDE). The objective was to test the applicability of the RDE as a primary reference standard for the measurement of oxygen concentrations below 0.1 ppm in seawater. Limited success was achieved with an activated platinum electrode. A gold electrode was less effective. If one postulates that the 2-electron reduction of oxygen at an activated RDE is rapid, it appears that little or no 4-electron reduction occurs and that the subsequent 2-electron reduction or catalytic decomposition of hydrogen peroxide is relatively slow. The anodic activation procedure developed appears to impart a transient catalytic activity to the electrode surface for the peroxide reaction(s).
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    AIChE Journal 21 (1975), S. 786-791 
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    Notes: Effective reaction rates and selectivities on surfaces having active and inactive regions are calculated for systems in which diffusion of reactants and products through a boundary layer is significant. With a single reaction it is shown that rates are larger than those calculated assuming area weighted averages. The selectivity of production of an intermediate in a series of reactions on a heterogeneous surface is higher than on a homogeneous surface, and with parallel reactions selectivities may be lower or higher depending on the kinetics of the competing reaction.Numerical examples from NH3 oxidation on a Pt gauze and CO oxidation in the automotive converter indicate that these effects may be important in determining selectivities and conversions in some industrial reactors.
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    AIChE Journal 21 (1975), S. 1022-1024 
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    AIChE Journal 21 (1975), S. 1037-1037 
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    AIChE Journal 21 (1975), S. 872-878 
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    Notes: The von Karman analogy between heat transfer and momentum transfer in turbulent fluids is shown to apply to heat transfer through wavy liquid films in horizontal, stratified, gas-liquid flow. Nusselt numbers predicted from the analogy are shown to be in good agreement with experimental data for air-water flows involving three-dimensional wavy films and large-amplitude roll waves. The Nusselt numbers encountered with these turbulent water films are found to be in the same range as those associated with condensation of organics in horizontal tubes under stratified flow conditions.
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    AIChE Journal 21 (1975), S. 865-872 
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    Notes: The behavioral features of a mixture containing many species each of which participates in two competing parallel first-order reactions may deviate significantly from those of the individual species. For example, the grouped selectivity may depend on the conversion and attain up to N-2 extremal values where N is the number of the reactants in the mixture. The kinetics of the grouped species depends on the composition of the feed and can be of an unconventional functional form. The use of empirical grouped kinetics may lead to unexpected pitfalls. For example, grouped rate expressions based on experiments carried out in one reactor may not be adequate for predicting the behavior in a reactor with a different residence time distribution.
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    AIChE Journal 21 (1975), S. 901-910 
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    Notes: In this paper an analysis is made of the hydrodynamic stability of a Boussinesq viscoelastic fluid undergoing plane Couette flow with a superposed temperature gradient. Of special interest is the effect of including the dissipation term in the energy equation. This term is shown to destabilize the fluid for most values of disturbance wave number and material parameters and to cause overstability for all values of the Brinkman number. At a critical Weissenberg number of 1, a rheological instability is developed which is essentially independent of the Reynolds, Prandtl, and Brinkman numbers.
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    AIChE Journal 21 (1975), S. 931-939 
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    Notes: Flow parameters were measured in a baffled, turbulent, stirred tank agitated by a six-blade, disk style turbine. The working fluid was air. Mean and fluctuating velocities were measured between the blades of the impeller with a probe mounted on the spinning impeller. Mean velocities, turbulent velocities, one-dimensional energy spectra, and Eulerian autocorrelation functions were measured in the impeller stream by using the shielded hot-wire anemometer of Gunkel et al. (1971) which permits the measurement of turbulence parameters in flows of very high turbulence intensity. Reliable impeller pumping capacities were obtained yielding Qrad/ND3 = 1.0 at the impeller periphery. An energy balance on a control volume containing the impeller and the impeller stream showed that the energy put into the tank via the impeller appeared as a net efflux of kinetic energy leaving the control volume. Therefore, most of the energy input to the tank is dissipated in the bulk of the tank.
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    AIChE Journal 21 (1975), S. 965-974 
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    Notes: Numerical solution of steady laminar flow in helically coiled tubes of square cross section for Dean numbers from 0.8 to 307.8 reveal two regimes of secondary flow. Up to Dean number of 100, the expected secondary flow pattern appears with twin counterrotating vortices. Above Dean numbers of 100, a new secondary flow regime, reported here for the first time, appears with four vortices. Flow visualization and pressure drop experiments confirm the transition.
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    AIChE Journal 21 (1975), S. 985-996 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The penetration of drugs and other micromolecules through intact human skin can be regarded as a process of dissolution and molecular diffusion through a composite, multilayer membrane, whose principal barrier to transport is localized within the stratum corneum. A mathematical model of the stratum corneum as a two-phase protein-lipid heterogeneous membrane (in which the lipid phase is continuous) correlates the permeability of the membrane to a specific penetrant with the water solubility of the penetrant and with its lipid-protein partition coefficient.Experimentally measured permeabilities of human skin to a variety of drugs have been found to conform to this model. The extraordinarily low permeability of skin to most micromolecules appears to arise from the very low diffusivity of such molecules in the intercellular lipid phase.
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    AIChE Journal 21 (1975), S. 1016-1017 
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    AIChE Journal 21 (1975), S. 1024-1027 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 1223-1225 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 1225-1227 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
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