ALBERT

Description: Abstract. Clouds are assumed to play an important role in the Arctic amplification process. This motivated a detailed investigation of cloud processes, including radiative and turbulent fluxes. Data from the aircraft campaign ACLOUD were analyzed with a focus on the mean and turbulent structure of the cloudy boundary layer over the Fram Strait marginal sea ice zone in late spring and early summer 2017. Vertical profiles of turbulence moments are presented from contrasting atmospheric boundary layers (ABLs) from 4 d. They differ by the magnitude of wind speed, boundary-layer height, stability, the strength of the cloud-top radiative cooling and the number of cloud layers. Turbulence statistics up to third-order moments are presented, which were obtained from horizontal-level flights and from slanted profiles. It is shown that both of these flight patterns complement each other and form a data set that resolves the vertical structure of the ABL turbulence well. The comparison of the 4 d shows that especially during weak wind, even in shallow Arctic ABLs with mixing ratios below 3 g kg-1, cloud-top cooling can serve as a main source of turbulent kinetic energy (TKE).Well-mixed ABLs are generated where TKE is increased and vertical velocity variance shows pronounced maxima in the cloud layer. Negative vertical velocity skewness points then to upside-down convection. Turbulent heat fluxes are directed upward in the cloud layer as a result of cold downdrafts. In two cases with single-layer stratocumulus, turbulent transport of heat flux and of temperature variance are both negative in the cloud layer, suggesting an important role of large eddies. In contrast, in a case with weak cloud-top cooling, these quantities are positive in the ABL due to the heating from the surface. Based on observations and results of a mixed-layer model it is shown that the maxima of turbulent fluxes are, however, smaller than the jump of the net terrestrial radiation flux across the upper part of a cloud due to the (i) shallowness of the mixed layer and (ii) the presence of a downward entrainment heat flux. The mixed-layer model also shows that the buoyancy production of TKE is substantially smaller in stratocumulus over the Arctic sea ice compared to subtropics due to a smaller surface moisture flux and smaller decrease in specific humidity (or even humidity inversions) right above the cloud top. In a case of strong wind, wind shear shapes the ABL turbulent structure, especially over rough sea ice, despite the presence of a strong cloud-top cooling. In the presence of mid-level clouds, cloud-top radiative cooling and thus also TKE in the lowermost cloud layer are strongly reduced, and the ABL turbulent structure becomes governed by stability, i.e., by the surface–air temperature difference and wind speed. A comparison of slightly unstable and weakly stable cases shows a strong reduction of TKE due to increased stability even though the absolute value of wind speed was similar. In summary, the presented study documents vertical profiles of the ABL turbulence with a high resolution in a wide range of conditions. It can serve as a basis for turbulence closure evaluation and process studies in Arctic clouds.

Description: The presence of reactive bromine in polar regions is a widespread phenomenon that plays an important role in the photochemistry of the Arctic and Antarctic lower troposphere, including the destruction of ozone, the disturbance of radical cycles, and the oxidation of gaseous elemental mercury. The chemical mechanisms leading to the heterogeneous release of gaseous bromine compounds from saline surfaces are in principle well understood. There are, however, substantial uncertainties about the contribution of different potential sources to the release of reactive bromine, such as sea ice, brine, aerosols, and the snow surface, as well as about the seasonal and diurnal variation and the vertical distribution of reactive bromine. Here we use continuous long-term measurements of the vertical distribution of bromine monoxide (BrO) and aerosols at the two Antarctic sites Neumayer (NM) and Arrival Heights (AH), covering the periods of 2003–2021 and 2012–2021, respectively, to investigate how chemical and physical parameters affect the abundance of BrO. We find the strongest correlation between BrO and aerosol extinction (R=0.56 for NM and R=0.28 for AH during spring), suggesting that the heterogeneous release of Br2 from saline airborne particles (blowing snow and aerosols) is a dominant source for reactive bromine. Positive correlations between BrO and contact time of air masses, both with sea ice and the Antarctic ice sheet, suggest that reactive bromine is not only emitted by the sea ice surface but by the snowpack on the ice shelf and in the coastal regions of Antarctica. In addition, the open ocean appears to represent a source for reactive bromine during late summer and autumn when the sea ice extent is at its minimum. A source–receptor analysis based on back trajectories and sea ice maps shows that main source regions for BrO at NM are the Weddell Sea and the Filchner–Ronne Ice Shelf, as well as coastal polynyas where sea ice is newly formed. A strong morning peak in BrO frequently occurring during summer and that is particularly strong during autumn suggests a night-time build-up of Br2 by heterogeneous reaction of ozone on the saline snowpack in the vicinity of the measurement sites. We furthermore show that BrO can be sustained for at least 3 d while travelling across the Antarctic continent in the absence of any saline surfaces that could serve as a source for reactive bromine.

Description: Springtime Arctic mixed-phase convection over open water in the Fram Strait as observed during the recent ACLOUD (Arctic CLoud Observations Using airborne measurements during polar Day) field campaign is simulated at turbulence-resolving resolutions. The first objective is to assess the skill of large-eddy simulation (LES) in reproducing the observed mixed-phase convection. The second goal is to then use the model to investigate how aerosol modulates the way in which turbulent mixing and clouds transform the low-level air mass. The focus lies on the low-level thermal structure and lapse rate, the heating efficiency of turbulent entrainment, and the low-level energy budget. A composite case is constructed based on data collected by two research aircraft on 18 June 2017. Simulations are evaluated against independent datasets, showing that the observed thermodynamic, cloudy, and turbulent states are well reproduced. Sensitivity tests on cloud condensation nuclei (CCN) concentration are then performed, covering a broad range between pristine polar and polluted continental values. We find a significant response in the resolved mixed-phase convection, which is in line with previous LES studies. An increased CCN substantially enhances the depth of convection and liquid cloud amount, accompanied by reduced surface precipitation. Initializing with the in situ CCN data yields the best agreement with the cloud and turbulence observations, a result that prioritizes its measurement during field campaigns for supporting high-resolution modeling efforts. A deeper analysis reveals that CCN significantly increases the efficiency of radiatively driven entrainment in warming the boundary layer. The marked strengthening of the thermal inversion plays a key role in this effect. The low-level heat budget shifts from surface driven to radiatively driven. This response is accompanied by a substantial reduction in the surface energy budget, featuring a weakened flow of solar radiation into the ocean. Results are interpreted in the context of air–sea interactions, air mass transformations, and climate feedbacks at high latitudes.

Description: The thermokarst lakes of permafrost regions play a major role in the global carbon cycle. These lakes are sources of methane to the atmosphere although the methane flux is restricted by an ice cover for most of the year. How methane concentrations and fluxes in these waters are affected by the presence of an ice cover is poorly understood. To relate water body morphology, ice formation and methane to each other, we studied the ice of three different water bodies in locations typical of the transition of permafrost from land to ocean in a continuous permafrost coastal region in Siberia. In total, 11 ice cores were analyzed as records of the freezing process and methane composition during the winter season. The three water bodies differed in terms of connectivity to the sea, which affected fall freezing. The first was a bay underlain by submarine permafrost (Tiksi Bay, BY), the second a shallow thermokarst lagoon cut off from the sea in winter (Polar Fox Lagoon, LG) and the third a land-locked freshwater thermokarst lake (Goltsovoye Lake, LK). Ice on all water bodies was mostly methane-supersaturated with respect to atmospheric equilibrium concentration, except for three cores from the isolated lake. In the isolated thermokarst lake, ebullition from actively thawing basin slopes resulted in the localized integration of methane into winter ice. Stable δ13C-CH4 isotope signatures indicated that methane in the lagoon ice was oxidized to concentrations close to or below the calculated atmospheric equilibrium concentration. Increasing salinity during winter freezing led to a micro-environment on the lower ice surface where methane oxidation occurred and the lagoon ice functioned as a methane sink. In contrast, the ice of the coastal marine environment was slightly supersaturated with methane, consistent with the brackish water below. Our interdisciplinary process study shows how water body morphology affects ice formation which mitigates methane fluxes to the atmosphere.

Description: Methane emissions from boreal and arctic wetlands, lakes, and rivers are expected to increase in response to warming and associated permafrost thaw. However, the lack of appropriate land cover datasets for scaling field-measured methane emissions to circumpolar scales has contributed to a large uncertainty for our understanding of present-day and future methane emissions. Here we present the Boreal–Arctic Wetland and Lake Dataset (BAWLD), a land cover dataset based on an expert assessment, extrapolated using random forest modelling from available spatial datasets of climate, topography, soils, permafrost conditions, vegetation, wetlands, and surface water extents and dynamics. In BAWLD, we estimate the fractional coverage of five wetland, seven lake, and three river classes within 0.5 × 0.5∘ grid cells that cover the northern boreal and tundra biomes (17 % of the global land surface). Land cover classes were defined using criteria that ensured distinct methane emissions among classes, as indicated by a co-developed comprehensive dataset of methane flux observations. In BAWLD, wetlands occupied 3.2 × 106 km2 (14 % of domain) with a 95 % confidence interval between 2.8 and 3.8 × 106 km2. Bog, fen, and permafrost bog were the most abundant wetland classes, covering ∼ 28 % each of the total wetland area, while the highest-methane-emitting marsh and tundra wetland classes occupied 5 % and 12 %, respectively. Lakes, defined to include all lentic open-water ecosystems regardless of size, covered 1.4 × 106 km2 (6 % of domain). Low-methane-emitting large lakes (〉10 km2) and glacial lakes jointly represented 78 % of the total lake area, while high-emitting peatland and yedoma lakes covered 18 % and 4 %, respectively. Small (〈0.1 km2) glacial, peatland, and yedoma lakes combined covered 17 % of the total lake area but contributed disproportionally to the overall spatial uncertainty in lake area with a 95 % confidence interval between 0.15 and 0.38 × 106 km2. Rivers and streams were estimated to cover 0.12  × 106 km2 (0.5 % of domain), of which 8 % was associated with high-methane-emitting headwaters that drain organic-rich landscapes. Distinct combinations of spatially co-occurring wetland and lake classes were identified across the BAWLD domain, allowing for the mapping of “wetscapes” that have characteristic methane emission magnitudes and sensitivities to climate change at regional scales. With BAWLD, we provide a dataset which avoids double-accounting of wetland, lake, and river extents and which includes confidence intervals for each land cover class. As such, BAWLD will be suitable for many hydrological and biogeochemical modelling and upscaling efforts for the northern boreal and arctic region, in particular those aimed at improving assessments of current and future methane emissions. Data are freely available at https://doi.org/10.18739/A2C824F9X (Olefeldt et al., 2021).

Description: Lakes in permafrost regions are dynamiclandscape components and play an important role for climatechange feedbacks. Lake processes such as mineralizationand flocculation of dissolved organic carbon (DOC), oneof the main carbon fractions in lakes, contribute to thegreenhouse effect and are part of the global carbon cycle.These processes are in the focus of climate research, butstudies so far are limited to specific study regions. Inour synthesis, we analyzed 2167 water samples from 1833lakes across the Arctic in permafrost regions of Alaska,Canada, Greenland, and Siberia to provide first pan-Arcticinsights for linkages between DOC concentrations andthe environment. Using published data and unpublisheddatasets from the author team, we report regional DOCdifferences linked to latitude, permafrost zones, ecoregions,geology, near-surface soil organic carbon contents, andground ice classification of each lake region. The lakeDOC concentrations in our dataset range from 0 to1130 mg L−1(10.8 mg L−1median DOC concentration).Regarding the permafrost regions of our synthesis, wefound median lake DOC concentrations of 12.4 mg L−1(Siberia), 12.3 mg L−1(Alaska), 10.3 mg L−1(Greenland),and 4.5 mg L−1(Canada). Our synthesis shows a significantrelationship between lake DOC concentration and lakeecoregion. We found higher lake DOC concentrationsat boreal permafrost sites compared to tundra sites. Wefound significantly higher DOC concentrations in lakesin regions with ice-rich syngenetic permafrost deposits(yedoma) compared to non-yedoma lakes and a weak butsignificant relationship between soil organic carbon contentand lake DOC concentration as well as between ground icecontent and lake DOC. Our pan-Arctic dataset shows that theDOC concentration of a lake depends on its environmentalproperties, especially on permafrost extent and ecoregion, aswell as vegetation, which is the most important driver of lakeDOC in this study. This new dataset will be fundamental toquantify a pan-Arctic lake DOC pool for estimations of theimpact of lake DOC on the global carbon cycle and climatechange.

Description: Arctic river deltas and deltaic near-shore zones represent important land–ocean transition zones influencing sediment dynamics and nutrient fluxes from permafrost-affected terrestrial ecosystems into the coastal Arctic Ocean. To accurately model fluvial carbon and freshwater export from rapidly changing river catchments as well as assess impacts of future change on the Arctic shelf and coastal ecosystems, we need to understand the sea floor characteristics and topographic variety of the coastal zones. To date, digital bathymetrical data from the poorly accessible, shallow, and large areas of the eastern Siberian Arctic shelves are sparse. We have digitized bathymetrical information for nearly 75 000 locations from large-scale (1:25 000–1:500 000) current and historical nautical maps of the Lena Delta and the Kolyma Gulf region in northeastern Siberia. We present the first detailed and seamless digital models of coastal zone bathymetry for both delta and gulf regions in 50 and 200 m spatial resolution. We validated the resulting bathymetry layers using a combination of our own water depth measurements and a collection of available depth measurements, which showed a strong correlation (r〉0.9). Our bathymetrical models will serve as an input for a high-resolution coupled hydrodynamic–ecosystem model to better quantify fluvial and coastal carbon fluxes to the Arctic Ocean, but they may be useful for a range of other studies related to Arctic delta and near-shore dynamics such as modeling of submarine permafrost, near-shore sea ice, or shelf sediment transport. The new digital high-resolution bathymetry products are available on the PANGAEA data set repository for the Lena Delta (https://doi.org/10.1594/PANGAEA.934045; Fuchs et al., 2021a) and Kolyma Gulf region (https://doi.org/10.1594/PANGAEA.934049; Fuchs et al., 2021b), respectively. Likewise, the depth validation data are available on PANGAEA as well (https://doi.org/10.1594/PANGAEA.933187; Fuchs et al., 2021c).

Description: Stable water isotopologues of snow, firn and ice cores provide valuable information on past climate variations. Yet single profiles are generally not suitable for robust climate reconstructions. Stratigraphic noise, introduced by the irregular deposition, wind-driven erosion and redistribution of snow, impacts the utility of high-resolution isotope records, especially in low-Accumulation areas. However, it is currently unknown how stratigraphic noise differs across the East Antarctic Plateau and how it is affected by local environmental conditions. Here, we assess the amount and structure of stratigraphic noise at seven sites along a 120 km transect on the plateau of Dronning Maud Land, East Antarctica. Replicated oxygen isotope records of 1 m length were used to estimate signal-To-noise ratios as a measure of stratigraphic noise at sites characterised by different accumulation rates (43-64 mm w.e. a-1), snow surface roughnesses and slope inclinations. While we found a high level of stratigraphic noise at all sites, there was also considerable variation between sites. At sastrugi-dominated sites, greater stratigraphic noise coincided with stronger surface roughnesses, steeper slopes and lower accumulation rates, probably related to increased wind speeds. These results provide a first step to modelling stratigraphic noise and might guide site selection and sampling strategies for future expeditions to improve high-resolution climate reconstructions from low-Accumulation regions.