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  • American Geophysical Union (AGU)
  • 2020-2023  (1)
  • 1980-1984  (1)
  • 1
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    American Geophysical Union (AGU)
    In:  EPIC3Earth's Future, American Geophysical Union (AGU), 10(9), ISSN: 2328-4277
    Publication Date: 2022-11-06
    Description: In this study we assessed the representation of the sea surface salinity (SSS) and liquid freshwater content (LFWC) of the Arctic Ocean in the historical simulation of 31 CMIP6 models with comparison to 39 Coupled Model Intercomparison Project phase 5 (CMIP5) models, and investigated the projected changes in Arctic liquid and solid freshwater content and freshwater budget in scenarios with two different shared socioeconomic pathways (SSP2-4.5 and SSP5-8.5). No significant improvement was found in the SSS and LFWC simulation from CMIP5 to CMIP6, given the large model spreads in both CMIP phases. The overestimation of LFWC continues to be a common bias in CMIP6. In the historical simulation, the multi-model mean river runoff, net precipitation, Bering Strait and Barents Sea Opening (BSO) freshwater transports are 2,928 ± 1,068, 1,839 ± 3,424, 2,538 ± 1,009, and −636 ± 553 km3/year, respectively. In the last decade of the 21st century, CMIP6 MMM projects these budget terms to rise to 4,346 ± 1,484 km3/year (3,678 ± 1,255 km3/year), 3,866 ± 2,935 km3/year (3,145 ± 2,651 km3/year), 2,631 ± 1,119 km3/year (2,649 ± 1,141 km3/year) and 1,033 ± 1,496 km3/year (449 ± 1,222 km3/year) under SSP5-8.5 (SSP2-4.5). Arctic sea ice is expected to continue declining in the future, and sea ice meltwater flux is likely to decrease to about zero in the mid-21st century under both SSP2-4.5 and SSP5-8.5 scenarios. Liquid freshwater exiting Fram and Davis straits will be higher in the future, and the Fram Strait export will remain larger. The Arctic Ocean is projected to hold a total of 160,300 ± 62,330 km3 (141,590 ± 50,310 km3) liquid freshwater under SSP5-8.5 (SSP2-4.5) by 2100, about 60% (40%) more than its historical climatology.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed
    Format: application/pdf
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  • 2
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    American Geophysical Union (AGU)
    In:  Geophysical Research Letters, 7 (10). pp. 797-800.
    Publication Date: 2020-07-30
    Description: The rate of reaction of OH with CS2 to form OCS by reaction (1) has been measured through observation of O14CS following 254 nm equation image photolysis of mixtures of H2O2 with 14CS2. The OH concentrations have been monitored through simultaneous measurement in the same cell of either (a) the oxidation of CO to CO2, or (b) the removal of a hydrocarbon such as C3H8 or iso-C4H10. The upper limit for the formation of OCS based on (a) corresponds to a rate constant k1 〈 0.3 × 10−14 cm³ molecule−1 sec−1. Other chemical reactions in the system have led to the formation of both 14CO and 14CO2, indicating the existence of a complex combination of reactions such that the observed O14CS need not have been formed by (1). The rate of reaction (1) is sufficiently slow that it is neither an important atmospheric sink for CS2 nor an important source for atmospheric OCS. The reaction of OH with OCS has not been measured in these experiments, but by analogy with k1 it is probably not an important atmospheric sink for OCS nor an important source of SO2.
    Type: Article , PeerReviewed
    Format: text
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