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  • International Union of Crystallography (IUCr)
  • Cambridge University Press
  • 2020-2022  (2,931)
  • 1980-1984  (15,481)
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  • 1
    Publication Date: 2020-08-24
    Description: The effect of freshwater sources on wintertime sea-ice CO2 processes was studied from the glacier front to the outer Tempelfjorden, Svalbard, in sea ice, glacier ice, brine and snow. March–April 2012 was mild, and the fjord was mainly covered with drift ice, in contrast to the observed thicker fast ice in the colder April 2013. This resulted in different physical and chemical properties of the sea ice and under-ice water. Data from stable oxygen isotopic ratios and salinity showed that the sea ice at the glacier front in April 2012 contained on average 54% of frozen-in glacial meltwater. This was five times higher than in April 2013, where the ice was frozen seawater. In April 2012, the largest excess of sea-ice total alkalinity (AT), carbonate ion ([CO32−]) and bicarbonate ion concentrations ([HCO3−]) relative to salinity was mainly related to dissolved dolomite and calcite incorporated during freezing of mineral-enriched glacial water. In April 2013, the excess of these variables was mainly due to ikaite dissolution as a result of sea-ice processes. Dolomite dissolution increased sea-ice AT twice as much as ikaite and calcite dissolution, implying different buffering capacity and potential for ocean CO2 uptake in a changing climate.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
    Publication Date: 2020-09-24
    Description: Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.
    Repository Name: EPIC Alfred Wegener Institut
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  • 3
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    Cambridge University Press
    In:  EPIC3Life in extreme environments - Insights in biological capability, Ecological Reviews, Cambridge, Cambridge University Press, 16 p., pp. 218-233, ISBN: 978-1-108-72420-3
    Publication Date: 2020-10-05
    Repository Name: EPIC Alfred Wegener Institut
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  • 4
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    Cambridge University Press
    In:  EPIC3Environmental Conservation, Cambridge University Press, pp. 1-6, ISSN: 0376-8929
    Publication Date: 2021-01-20
    Repository Name: EPIC Alfred Wegener Institut
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  • 5
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    Cambridge University Press
    In:  EPIC3Journal of Glaciology, Cambridge University Press, 67(261), pp. 84-90
    Publication Date: 2021-01-25
    Description: The validity of any glaciological paleo proxy used to interpret climate records is based on the level of understanding of their transfer from the atmosphere into the ice sheet and their recording in the snowpack. Large spatial noise in snow properties is observed, as the wind constantly redistributes the deposited snow at the surface routed by the local topography. To increase the signal-tonoise ratio and getting a representative estimate of snow properties with respect to the high spatial variability, a large number of snow profiles is needed. However, the classical way of obtaining profiles via snow-pits is time and energy-consuming, and thus unfavourable for large surface sampling programs. In response, we present a dual-tube technique to sample the upper metre of the snowpack at a variable depth resolution with high efficiency. The developed device is robust and avoids contact with the samples by exhibiting two tubes attached alongside each other in order to (1) contain the snow core sample and (2) to access the bottom of the sample, respectively. We demonstrate the performance of the technique through two case studies in East Antarctica where we analysed the variability of water isotopes at a 100 m and 5 km spatial scales.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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  • 6
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    Cambridge University Press
    In:  EPIC3Radiocarbon, Cambridge University Press, 62(4), pp. 865-871, ISSN: 0033-8222
    Publication Date: 2020-09-24
    Description: Beyond ~13.9 cal kBP, the IntCal20 radiocarbon (14C) calibration curve is based upon combining data across a range of different archives including corals and planktic foraminifera. In order to reliably incorporate such marine data into an atmospheric curve, we need to resolve these records into their constituent atmospheric signal and marine reservoir age. We present results of marine reservoir age simulations enabling this resolution, applying the LSG ocean general circulation model forced with various climatic background conditions and with atmospheric radiocarbon changes according to the Hulu Cave speleothem record. Simulating the spatiotemporal evolution of reservoir ages between 54,000 and 10,700 cal BP, we find reservoir ages between 500 and 1400 yr in the low- and mid-latitudes, but also more than 3000 yr in the polar seas. Our results are broadly in agreement with available marine radiocarbon reconstructions, with the caveat that continental margins, marginal seas, or tropical lagoons are not properly resolved in our coarse-resolution model.
    Repository Name: EPIC Alfred Wegener Institut
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  • 7
    Publication Date: 2020-09-24
    Description: The concentration of radiocarbon (14C) differs between ocean and atmosphere. Radiocarbon determinations from samples which obtained their 14C in the marine environment therefore need a marine-specific calibration curve and cannot be calibrated directly against the atmospheric-based IntCal20 curve. This paper presents Marine20, an update to the internationally agreed marine radiocarbon age calibration curve that provides a non-polar global-average marine record of radiocarbon from 0–55 cal kBP and serves as a baseline for regional oceanic variation. Marine20 is intended for calibration of marine radiocarbon samples from non-polar regions; it is not suitable for calibration in polar regions where variability in sea ice extent, ocean upwelling and air-sea gas exchange may have caused larger changes to concentrations of marine radiocarbon. The Marine20 curve is based upon 500 simulations with an ocean/atmosphere/biosphere box-model of the global carbon cycle that has been forced by posterior realizations of our Northern Hemispheric atmospheric IntCal20 14C curve and reconstructed changes in CO2 obtained from ice core data. These forcings enable us to incorporate carbon cycle dynamics and temporal changes in the atmospheric 14C level. The box-model simulations of the global-average marine radiocarbon reservoir age are similar to those of a more complex three-dimensional ocean general circulation model. However, simplicity and speed of the box model allow us to use a Monte Carlo approach to rigorously propagate the uncertainty in both the historic concentration of atmospheric 14C and other key parameters of the carbon cycle through to our final Marine20 calibration curve. This robust propagation of uncertainty is fundamental to providing reliable precision for the radiocarbon age calibration of marine based samples. We make a first step towards deconvolving the contributions of different processes to the total uncertainty; discuss the main differences of Marine20 from the previous age calibration curve Marine13; and identify the limitations of our approach together with key areas for further work. The updated values for ΔR, the regional marine radiocarbon reservoir age corrections required to calibrate against Marine20, can be found at the data base http://calib.org/marine/.
    Repository Name: EPIC Alfred Wegener Institut
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  • 8
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    Cambridge University Press
    In:  EPIC3Polar Record, Cambridge University Press, 57(e12), pp. 1-6, ISSN: 0032-2474
    Publication Date: 2021-04-15
    Description: The distribution, density and percentage contribution of pack ice seals during ship-board censuses in the marginal sea ice zone beyond the Lazarev Sea in spring 2019 are presented. Adult/juvenile crabeater seals (n = 19), leopard seals (n = 3) and Ross seals (n = 10) were sighted during 582.2 nm of censuses along the ship’s track line in the area bounded by 00°00’–22°E and 56°–60°S. Antarctic fur seals (n = 21) were only encountered on the outer fringes of the pack ice, and Weddell seals were absent due to their primary use of fast ice and inner pack ice habitats close to the coast. Crabeater seal sightings included juveniles (n = 2) and another four groups of 2–3 unclassified crabeater seals, singletons (n = 5), single mothers with pups (n = 3) and a family group (n = 1 triad). Only one leopard seal attended a pup, while no Ross seal pups were located. The survey was likely of insufficient effort, in both extent (north of 60°S) and duration (18 days), to locate seals in considerable numbers this early (late October/early November) in their austral spring breeding season.
    Repository Name: EPIC Alfred Wegener Institut
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  • 9
    Publication Date: 2020-05-27
    Description: Volcanism and metamorphism are the principal geologic processes that drive carbon transfer from the interior of Earth to the surface reservoir.1–4 Input of carbon to the surface reservoir through volcanic degassing is balanced by removal through silicate weathering and the subduction of carbon-bearing marine deposits over million-year timescales. The magnitude of the volcanic carbon flux is thus of fundamental importance for stabilization of atmospheric CO2 and for long-term climate. It is likely that the “deep” carbon reservoir far exceeds the size of the surface reservoir in terms of mass;5,6 more than 99%of Earth’s carbon may reside in the core, mantle, and crust. The relatively high flux of volcanic carbon to the surface reservoir, combined with the reservoir’s small size, results in a short residence time for carbon in the ocean–atmosphere–biosphere system (~200 ka).7 The implication is that changes in the flux of volcanic carbon can affect the climate and ultimately the habitability of the planet on geologic timescales. In order to understand this delicate balance, we must first quantify the current volcanic flux of carbon to the atmosphere and understand the factors that control this flux.
    Description: Published
    Description: 188-236
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 10
    Publication Date: 2021-01-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Reimer, P. J., Austin, W. E. N., Bard, E., Bayliss, A., Blackwell, P. G., Ramsey, C. B., Butzin, M., Cheng, H., Edwards, R. L., Friedrich, M., Grootes, P. M., Guilderson, T. P., Hajdas, I., Heaton, T. J., Hogg, A. G., Hughen, K. A., Kromer, B., Manning, S. W., Muscheler, R., Palmer, J. G., Pearson, C., van der Plicht, J., Reimer, R. W., Richards, D. A., Scott, E. M., Southon, J. R., Turney, C. S. M., Wacker, L., Adolphi, F., Buentgen, U., Capano, M., Fahrni, S. M., Fogtmann-Schulz, A., Friedrich, R., Koehler, P., Kudsk, S., Miyake, F., Olsen, J., Reinig, F., Sakamoto, M., Sookdeo, A., & Talamo, S. The Intcal20 Northern Hemisphere radiocarbon age calibration curve (0-55 cal kBP). Radiocarbon, 62(4), (2020): 725-757, doi:10.1017/RDC.2020.41.
    Description: Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.
    Description: We would like to thank the National Natural Science Foundation of China grants NSFC 41888101 and NSFC 41731174, the 111 program of China (D19002), U.S. NSF Grant 1702816, and the Malcolm H. Wiener Foundation for support for research that contributed to the IntCal20 curve. The work on the Swiss and German YD trees was funded by the German Science foundation and the Swiss National Foundation (grant number: 200021L_157187). The operation in Aix-en-Provence is funded by the EQUIPEX ASTER-CEREGE, the Collège de France and the ANR project CARBOTRYDH (to EB). The work on the correlation of tree ring 14C with ice core 10Be was partially supported by the Swedish Research Council and the Knut and Alice Wallenberg foundation. M. Butzin was supported by the German Federal Ministry of Education and Research (BMBF) as Research for Sustainable Development (FONA; http://www.fona.de) through the PalMod project (grant number: 01LP1505B). S. Talamo and M. Friedrich are funded by the European Research Council under the European Union’s Horizon 2020 Research and Innovation Programme (grant agreement No. 803147-RESOLUTION, awarded to ST). CA. Turney would like to acknowledge support of the Australian Research Council (FL100100195 and DP170104665). P. Reimer and W. Austin acknowledge the support of the UKRI Natural Environment Research Council (Grant NE/M004619/1). T.J. Heaton is supported by a Leverhulme Trust Fellowship RF-2019-140\9. Other datasets and the IntCal20 database were created without external support through internal funding by the respective laboratories. We also would like to thank various institutions that provided funding or facilities for meetings.
    Keywords: calibration curve ; radiocarbon ; IntCal20
    Repository Name: Woods Hole Open Access Server
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  • 11
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    Cambridge University Press | New York
    In:  http://aquaticcommons.org/id/eprint/2263 | 403 | 2015-04-28 21:06:50 | 2263
    Publication Date: 2021-07-12
    Description: Executive Summary:Observations show that warming of the climate is unequivocal. The global warming observed over the past 50 years is due primarily to human-induced emissions of heat-trapping gases. These emissions come mainly from theburning of fossil fuels (coal, oil, and gas), with important contributions from the clearing of forests, agricultural practices, and other activities.Warming over this century is projected to be considerably greater than over the last century. The global average temperature since 1900 has risen by about 1.5ºF. By 2100, it is projected to rise another 2 to 11.5ºF. The U.S.average temperature has risen by a comparable amount and is very likely to rise more than the global average over this century, with some variation from place to place. Several factors will determine future temperature increases. Increases at the lower end of this range are more likely if global heat-trapping gas emissions are cut substantially. If emissions continue to rise at or near current rates, temperature increases are more likely to be near the upper end of the range. Volcanic eruptions or other natural variations could temporarily counteract some of the human-induced warming, slowing the rise in global temperature, but these effects would only last a few years.Reducing emissions of carbon dioxide would lessen warming over this century and beyond. Sizable early cuts in emissions would significantly reduce the pace and the overall amount of climate change. Earlier cuts in emissions would have a greater effect in reducing climate change than comparable reductions made later. In addition, reducing emissions of some shorter-lived heat-trapping gases, such as methane, and some types of particles, such as soot, would begin to reduce warming within weeks to decades.Climate-related changes have already been observed globally and in the United States. These include increases in air and water temperatures, reduced frost days, increased frequency and intensity of heavy downpours, a rise in sea level, and reduced snow cover, glaciers, permafrost, and seaice. A longer ice-free period on lakes and rivers, lengthening of the growing season, and increased water vapor in the atmosphere have also been observed. Over the past 30 years, temperatures have risen faster in winter than in any other season, with average winter temperatures in the Midwest and northern Great Plains increasing more than 7ºF. Some of the changes have been faster thanprevious assessments had suggested.These climate-related changes are expected to continue while new ones develop. Likely future changes for the United States and surrounding coastal waters include more intense hurricanes with related increases in wind, rain, and storm surges (but not necessarily an increase in the number of these storms that make landfall), as well as drier conditions in the Southwest and Caribbean. Thesechanges will affect human health, water supply, agriculture, coastal areas, and many other aspectsof society and the natural environment.This report synthesizes information from a wide variety of scientific assessments (see page 7) and recently published research to summarize what is known about the observed and projected consequences of climate change on the United States. It combines analysis of impacts on various sectors such as energy, water, and transportation at the national level with an assessment of key impacts on specific regions of the United States. For example, sea-level rise will increase risks of erosion, storm surge damage, and flooding for coastal communities, especially in the Southeast and parts of Alaska. Reduced snowpack and earlier snow melt will alter the timing and amount of water supplies, posingsignificant challenges for water resource managementin the West. (PDF contains 196 pages)
    Keywords: Conservation ; Management ; Pollution ; Earth Sciences ; Environment ; Policies
    Repository Name: AquaDocs
    Type: monograph
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  • 12
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    Cambridge University Press
    In:  EPIC3The Species–Area Relationship, The Species–Area Relationship, Cambridge University Press, pp. 438-456
    Publication Date: 2020-11-04
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 13
    Electronic Resource
    Electronic Resource
    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 1-6 
    ISSN: 0022-278X
    Source: Cambridge Journals Digital Archives
    Topics: Ethnic Sciences , History , Political Science , Economics
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  • 14
    Electronic Resource
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 547-563 
    ISSN: 0022-278X
    Source: Cambridge Journals Digital Archives
    Topics: Ethnic Sciences , History , Political Science , Economics
    Notes: In 1961, soon after the beginning of the first United Nations Development Decade, a conference of African Ministers of Education was convened by Unesco. The meeting resolved, inter alia, that by the year 1980 primary schooling throughout the continent should be ‘universal, compulsory and free’.1 As we have now reached that date, it is appropriate to review progress. A few countries have achieved the goal, but many others have fallen short. This article will examine the experience of the last two decades, and assess its implications for ultimate objectives and the strategies for achieving them. Despite national policy variations and divergent social and economic conditions, instructive overall patterns may be discerned.
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  • 15
    Electronic Resource
    Electronic Resource
    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 565-594 
    ISSN: 0022-278X
    Source: Cambridge Journals Digital Archives
    Topics: Ethnic Sciences , History , Political Science , Economics
    Notes: In the last few years there has been a growing interest in that very considerable and hitherto mostly unrecorded part of the economic life of the Third World which flourishes outside the state and foreign-owned medium and large-scale concerns. This great mass of non-enumerated enterprises and activities is a major source of employment and production. For the purpose of this article, it will be argued that many of those undertaking research in this sector can be regarded as belonging to one or other of two fairly distinct schools of thought formed by (1) a number of officials from the International Labour Organisation, the World Bank, and other international and government agencies, as well as some purely academic writers,1 and (2) the majority of social scientists attached to the British Sociological Association Development Group, some of whom operate to a greater or lesser extent within a Marxian or neo-Marxian perspective.2 For purposes of abbreviation only, these will be referred to as the ‘I.L.O.’ and the ‘Radical’ groups.
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  • 16
    Electronic Resource
    Electronic Resource
    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 595-624 
    ISSN: 0022-278X
    Source: Cambridge Journals Digital Archives
    Topics: Ethnic Sciences , History , Political Science , Economics
    Notes: In his classic study of decentralisation and development, Henry Maddick argued that economic growth and social modernisation depend in part on the ability of Third-World govenments to diffuse responsibility for development planning and administration, to expand participation in economic activities, and to promote new centres of creativity within society. Over-concentration of administrative authority stifles development, Maddick insisted; it leads to waste and corruption, delays action, and creates irrational and inefficient management practices, the costs of which developing countries cannot afford.1 To illustrate his point, Maddick cited the effects of the centralised supply system in the Sudan in the late 1950s, through which ‘shoes made in Fasher were sent 400 miles by rail to Khartoum where the whole shoe supply was concentrated. When Fasher wanted shoes for school children and government personnel it had to send to Khartoum for them.’ He also noted that school desks and equipment for the provincial city of Juba had to be ordered from Khartoum, which was 900 miles away and connected only by inefficient river transport, even though the wood from which the furniture was made originally came from Juba.2
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  • 17
    Electronic Resource
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 625-646 
    ISSN: 0022-278X
    Source: Cambridge Journals Digital Archives
    Topics: Ethnic Sciences , History , Political Science , Economics
    Notes: Theories of modernisation and social change have been increasingly challenged during the past decade by events in the Middle East and other areas of the developing world. Leaders of oil-rich nations are choosing to industrialise but not to westernise, and Islamic revivals are shaping new patterns of political and social development. For example, improvements in female status can no longer be regarded as the inevitable concomitants of industrialisation; to the contrary, gender inequality may actually be exacerbated by national resurgences of religious and cultural traditions which often accompany planned social change.1
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  • 18
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 647-665 
    ISSN: 0022-278X
    Source: Cambridge Journals Digital Archives
    Topics: Ethnic Sciences , History , Political Science , Economics
    Notes: Foreign investment in South Africa during the past 20 years has been subject to criticism form several diverse schools of thought, ranging from those who believe it has contributed to country's economic growth without improving the condition of the black workers, to those who maintain that – at best – apartheid has been modernised rather than fundamentally changed.Today the focus of attention has shifted to collective bargaining and trade union rights, to the action that can be taken on their own behalf by the ecomomically underprivileged and the politically dispossessed, and to the assistance which foreign-owned companies have been given in improving the terms and conditions of employment of their own non-white employees by the codes of conduct that have quite recently been adopted by their own governments.
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  • 19
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 705-708 
    ISSN: 0022-278X
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    Topics: Ethnic Sciences , History , Political Science , Economics
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  • 20
    ISSN: 0022-278X
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    Topics: Ethnic Sciences , History , Political Science , Economics
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  • 21
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 667-704 
    ISSN: 0022-278X
    Source: Cambridge Journals Digital Archives
    Topics: Ethnic Sciences , History , Political Science , Economics
    Notes: People of quite diverse social position and perspective have turned to economic growth as a source of political change in South Africa. Contained within the concept of growth, they maintain, are processes — capital accumulation and class formation, business enterprise and markets, changing skill and capital requirements – that, at the very least, allow some blacks a more secure and higher living standard, that may bring greater equality between the races, or more profoundly, confound traditional racial lines and privileges of quite diverse social position and perspective have turned to economic growth as a source of political change in South Africa. Contained within the concept of growth, they maintain, are processes — capital accumulation and class formation, business enterprise and markets, changing skill and capital requirements – that, at the very least, allow some blacks a more secure and higher living standard, that may bring greater equality between the races, or more profoundly, confound traditional racial lines and privileges. Indeed, some argue that growth undermines the foundations of the racial state. Many of those who posit a relationship between economics and politics, take the next logical step: supporting actions, including foreign investment, that foster economic growth and, presumably, political change in South Africa.
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  • 22
    ISSN: 0022-278X
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    Topics: Ethnic Sciences , History , Political Science , Economics
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  • 23
    ISSN: 0022-278X
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    Topics: Ethnic Sciences , History , Political Science , Economics
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  • 24
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 715-717 
    ISSN: 0022-278X
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    Topics: Ethnic Sciences , History , Political Science , Economics
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  • 25
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 717-719 
    ISSN: 0022-278X
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    Topics: Ethnic Sciences , History , Political Science , Economics
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  • 26
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 719-720 
    ISSN: 0022-278X
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  • 27
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 1-10 
    ISSN: 0022-278X
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  • 28
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 722-728 
    ISSN: 0022-278X
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    Topics: Ethnic Sciences , History , Political Science , Economics
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  • 29
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    Cambridge : Cambridge University Press
    The @journal of modern African studies 19 (1981), S. 499-502 
    ISSN: 0022-278X
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    Topics: Ethnic Sciences , History , Political Science , Economics
    Notes: Urban unemployment and underemployment are widespread problems in Africa, perhaps more so than on other continents. It is a truism, apparently accepted by most governments, that capital is scarce, and that the rate of development and employment creation are constrained by the relative scarcity of capital equipment and the slow rate of capital formation. And yet these two observations, challengeable but generally accepted as commonplace and obvious truths, co-exist in much of Africa with a paradoxical third statement: that much of the urban capital stock, particularly in the modern-service sectors – government, education, large-scale commerce, finance, etcetera – is utilised at a very low rate, typically of the order of 25–30 per cent of the potential maximum. This brief note speculates on the reasons for this state of affairs, and explores the consequences of adopting a possible policy designed to produce a significant change.
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    The @journal of modern African studies 19 (1981), S. 513-515 
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    The @journal of modern African studies 19 (1981), S. 221-256 
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    Notes: Virtually all analyses of Lesotho's political framework have agreed that strong elements of national identity have neither forestalled domestic conflict nor served to promote a unified assault on awesome economic problems. Hence many writers imply that a major asset, rarely found in independent Africa, has been wasted.1 Roger Leys has perceptively applied dependency theories of a ‘labour reserve’ economy to Lesotho,2 and spends considerable effort on historical analysis aimed at demonstrating the duration and pervasiveness of this process of systematic underdevelopment. In his conclusion he suggests that ‘the long and courageous battle of the Basotho to assert their dignity and worth is in fact a resource and political weapon of incomparable significance in the long-term battle for the liberation of southern Africa.’ Leys infers that national and class identities are interrelated, and possibly reinforcing, when he says that ‘the history of the struggle of the Basotho people and the very degree of their integration into the black working class of South Africa is a formidable weapon.’3
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    The @journal of modern African studies 19 (1981), S. 307-335 
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    Notes: Ethiopia has long been regarded as the only African state, along with Liberia, to have escaped the ravages of European colonialism, the epitome of African independence and self-determination.1 It was also considered a stable, relatively integrated, and viable political community amidst a continent of new states characterised by chronic instability.2 But by 1974, most if not all of these myths were in the process of being broken, as Ethiopia struggled for its very existence against pressures from within and without that threatened to dismember the Empire.
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    The @journal of modern African studies 19 (1981), S. 337-339 
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    The @journal of modern African studies 19 (1981), S. 345-347 
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    The @journal of modern African studies 19 (1981), S. 348-350 
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    The @journal of modern African studies 19 (1981), S. 347-348 
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    The @journal of modern African studies 19 (1981), S. 350-351 
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    The @journal of modern African studies 19 (1981), S. 356-357 
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    The @journal of modern African studies 19 (1981), S. 75-105 
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    Notes: Mauritius became independent on 12 March 1968, and was then said to be the paradigm of the small isolated, poor, dependent country, only emerging from the colonial era to fall immediately into neocolonialism – the Third World's Third World.
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    The @journal of modern African studies 19 (1981), S. 107-132 
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    Notes: In 1955 the South African Government began to demolish a black freehold suburb in Johannesburg, and to relocate its inhabitants in a state-controlled township. Resistance to these moves by the leading black political organisation of the time, the African National Congress (A.N.C.), was short-lived and unsuccessful. Despite its abortive nature, the attempt to oppose the destruction of Sophiatown was historically significant for several reasons.
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    The @journal of modern African studies 19 (1981), S. 57-73 
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    Notes: In the course of several field studies carried out during 1978–9 on behalf of the Working Group on Recurrent Costs established by the Comité Inter-états de Lutte contre la Sécheresse dans le Sahel and the Club du Sahel, it became clear that imperfect functioning of domestic capital markets hampers the efforts of Sahelian governments to raise domestic non-tax resources for budget finance. Inasmuch as the operation and maintenance of development projects compete for a severely limited pool of uncommitted government revenues – that is, revenues not committed to debt service, meeting the civil service payroll, and other inflexible obligations – reforms that augment this pool are of particular interest from the viewpoint of ensuring that these projects function properly once established.
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    The @journal of modern African studies 19 (1981), S. 133-161 
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    Notes: Legislation in the former British colonial territories exhibited a pair of paradoxes. First, it spoke in legalese, a patois that only judges and lawyers can read easily. Many laws concerning development, however, addressed ordinary citizens. Second, drafters invented and used a specialised style to reduce official and judicial discretion by making legislation more precise, but this frequently endowed officials with discretion as broad as the unbroken sky. In Africa, the uses of legalese seemed to war with the purposes for which it was developed.
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    The @journal of modern African studies 18 (1980), S. 1-4 
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    The @journal of modern African studies 18 (1980), S. 711-712 
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    The @journal of modern African studies 18 (1980), S. 411-425 
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    Notes: Late in 1979 the Zambian Government unveiled its Third National Development Plan which will guide policies until the year 1984, and this implies that problems of unemployment, particularly in urban areas, will be partly overcome by an expansion of self-employment possibilities.Such was the enthusiasm for the new initiative that the absence of reliable information surrounding it was largely ignored. This article attempts to provide relevant data concerning a number of issues which will be vital in implementing any measures to encourage self-employment in the so-called ‘informal sector’ of the Zambian economy. In particular we shall endeavour to quantify the likely flows into the labour force, particularly from the educational system, the possible growth of formal wage employment in urban areas, and the current size and composition of the informal sector. Finally, conclusions are drawn concerning the possible rôle of this sector in absorbing the unemployed in the plan period.
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    The @journal of modern African studies 18 (1980), S. 427-441 
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    Notes: Discussion of industrial activity in capitalist Third-World countries has usually centred on a series of dualistic frameworks, most recently the opposition between the so-called ‘formal’ and ‘informal’ sectors of an economy. Such dichotomies attempt to divide the activities of labour as cleanly as possible into two groups sharing common characteristics. The categories that emerge – modern/traditional, large/small-scale, formal/informal – overlap to a considerable degree because, in effect, they all attempt, with varying crudity, to compare the socio-economic characteristics of those dominant capitalist enterprises which are based on intensive capital, high-level technology, and a large scale of production, with those activities in the economy which are not based on such features. As such, the second category tends to have both negative and residual components.
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    The @journal of modern African studies 18 (1980), S. 443-468 
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    Notes: The constitutional development of Nigeria which started under the British occupation has been marked by two fundamental principles: the decision to set the political evolution of the country on a federal basis, and the effort, far less successful, to integrate the traditional institutions into a modern political system. This second principle will be the subject of this article, which I hope will also shed some light on the complex relationships between tradition and modernity, and thus show the importance of ‘primordial loyalties’ in political life.
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    The @journal of modern African studies 18 (1980), S. 493-508 
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    Notes: The potential for superpower confrontation on the Horn of Africa in 1977 and 1978 focused world attention on Somalia. For a few brief months, the popular press published regular accounts of President Siad Barre's military campaign in the Ogaden desert against neighbouring Ethiopia. The U.S. Department of State heralded the rôle of Soviet and Cuban advisers in the conflict. When Somalia ousted the Russian forces and abrogated the Treaty of Friendship and Co-operation with the U.S.S.R., the move was interpreted as a major diplomatic setback for Moscow. Now, as quickly as it erupted, the news flow about the Horn has halted.
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    The @journal of modern African studies 18 (1980), S. 509-524 
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    Notes: When Henry Kissinger became Secretary of State in September 1973 he instructed all American embassy personnel to monitor human rights in the countries in which they were serving. President Jimmy Carter was not responsible for America's interest in human rights, only for the policy of affirmative action. When his Assistant Secretary for Human Rights commenced work she found only two members of the State Department permanently assigned to the task, and her sole guideline was the manual for setting up her office.
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    The @journal of modern African studies 18 (1980), S. 525-531 
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    Notes: Throughout Ghana many commercial passenger vehicles bear mottos and names, boldly written on their bodies, usually at the front. The widespread nature of these inscriptions would seem to suggest that they are a part of the occupational sub-culture, namely the distinctive pattern of behaviour, norms, and customs which serves to identify commercial transportation. A general theme running throughout the present study is that this sub-culture reflects not only the unique needs of the drivers, but also the socio-economic and cultural environment within which they operate.
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    The @journal of modern African studies 18 (1980), S. 533-540 
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    Notes: The Lesotho Minister for Agriculture, Co-operatives, and Marketing was reported recently to have shaken the delegates at the World Conference on Agrarian Reform and Development in Rome by his observation on the value of such intergovernmental gatherings on the subject of development:
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    The @journal of modern African studies 18 (1980), S. 1-4 
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    The @journal of modern African studies 18 (1980), S. 1-6 
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    The @journal of modern African studies 18 (1980), S. 541-549 
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    Notes: On 22 October 1966, 393 students, all but 70 of them from the University College, demonstrated in Dar es Salaam against the Tanzania Government's proposals for National Service to be compulsory for students completing their education at Form VI level and above.1 Marching through the streets of the capital to show their disapproval, and carrying banners some of which read ‘Colonialism was Better’2 they were diverted to State House, where they had to deliver their ultimatum to the President, Mwalimu Julius K. Nyerere, in person. Flanked by his Ministers, he listened to their demand that unless the terms of the National Service were changed they would not accept the scheme in spirit: ‘Let our bodies go, but our souls will remain outside the scheme’. In his reply, the President made it clear that he had no intention of forcing anyone into National Service against his will. But since these students were unwilling to serve the nation, they should be returned immediately to their parental homes. Whereupon the demonstrators were rounded up by waiting (and obviously prepared) police, finger-printed, and despatched under armed guards to their homes throughout the country.
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    The @journal of modern African studies 18 (1980), S. 237-256 
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    Notes: There is general agreement that sports are used for political purposes. The controversy over whether this should or should not be the case is really a struggle about how they should be used. Those who argue for the separation of sports and politics tend to be satisfied with the existing use, while those against the separation tend to be dissatisfied with the present situation. The positions are rational: each group seeks to use this arena to achieve its own political objectives. Although some involvement of politics in sports appears universal, the degree varies considerably from country to country.
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    The @journal of modern African studies 18 (1980), S. 181-200 
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    Notes: Only a few social scientists outside the field of Middle East studies are aware that in the sovereign state of Libya today there is no government. Indeed, it is not likely to have one so long as the country's strongman, Colonel Mu'ammar al-Qadhafi,1 continues to be the leader of the Libyan revolution. This has been the case ever since 2 March 1977, when the institution of government in its traditional legal-bureaucratic sense was dismantled, and the people's authority, exercised through people's congresses and committees, was proclaimed. By this action, Libya initiated in practice the so-called era of jamahiriya—the era of the masses and the practice of direct democracy – and has taken a number of steps in that direction. A recent example was the renaming of some of its embassies overseas as ‘people's bureaux’, with Libyan students and citizens taking charge of their functions and management.2 This action, instigated personally by Qadhafi, was intended to illustrate to the world that since Libya has no government, ordinary Libyan citizens overseas represent themselves directly to foreign peoples.
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    The @journal of modern African studies 18 (1980), S. 281-295 
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    Notes: Although the analysis which follows centres upon the West African state of Mali, much of what is said applies in varying measure to other examples of military state capitalism in Africa and elsewhere. Its importance is underscored by the fact that this is an increasingly common régime variant in the Third World. Similarly, domestic militarism has been transformed from an unusual occurrence to a phenomenon which evokes little more than a déjà vu response. Today nearly half of the governments of the ‘South’ are directly or indirectly dominated by the military, whereas three decades ago little more than 15 per cent could be so classified.
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    The @journal of modern African studies 18 (1980), S. 330-332 
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    The @journal of modern African studies 18 (1980), S. 332-334 
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    The @journal of modern African studies 18 (1980), S. 334-337 
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    The @journal of modern African studies 18 (1980), S. 1-4 
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    The @journal of modern African studies 18 (1980), S. 1-22 
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    Notes: In October 1970, after the civil war had ended, General Yakubu Gowon reiterated his earlier pledge that military rule would be terminated on 1 October 1976, but two years before that date he postponed the return to civilian rule indefinitely on the grounds that Nigerians had not yet demonstrated ‘moderation and self-control in pursuing sectional ends’.1 In July 1975, nine years after his own elevation to Head of the Federal Military Government (F.M.G.), Gowon was removed by a coup d'état led by Brigadier Murtala Mohammed, who cited mismanagement as the immediate reason. However, after the coup, ‘well-placed spokesmen for the new administration...reaffirmed that the goals of the coup were to restore the good image of the military and to create conditions which will make reactive military intervention unnecessary in the future’.2
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    The @journal of modern African studies 18 (1980), S. 143-150 
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    Notes: Disappointed with the development performance of most Third-World countries during the past two decades, many scholars and public officials have looked for a more effective strategy. They are concerned not merely with the extent of growth, but where it has occurred, with evidence that relatively little of the benefits of increased productivity has ‘trickled down’ to the poorer half of the populations of these lands. Capital-intensive methods have raised expectations in both the urban and the rural areas without generating adequate employment opportunities or distributing the benefits of growth equitably. As a consequence, the many poor remain as desperately disadvantaged as they ever were, making a re-evaluation of development priorities, within as well as outside of Africa, of the utmost importance at this juncture.
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    Topics: Geosciences , Physics
    Notes: Transparent yellow-greenish single crystals of Pb6GeO8 were obtained by spontaneous crystallization from a melt with a molar ratio of PbO:GeO2 = 4.7:1. The compound is monoclinic, probable space group P21/a, a = 52.665 (12), b = 15.063 (4), c = 23.949 (6) Å and β = 111.03 (5)°; Dm(293 K) = 8.65 (3), Dx = 8.653 Mg m−3 for Z = 64 formula units. Pb11Ge3O17 was synthesized by sintering high-purity oxides PbO and GeO2 of molar ratio 3.69:1 at 990 K. The compound is also monoclinic, probable space groups C2/c or Cc, a = 25.117 (5), b = 15.440 (2), c = 45.529 (13) Å and β = 103.20 (4)°; Dm(293 K) = 8.55 (2), Dx = 8.560 Mg m−3 for Z = 32.
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    Applied crystallography online 13 (1980), S. 311-315 
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    Topics: Geosciences , Physics
    Notes: Series of chalcopyrite-type solid solutions AgGaxIn1−xSe2 and CuGaxIn1−xSe2, 0≤x≤1, have been prepared by direct synthesis from the melt. The space group is I\bar 42d (No. 122), Z = 4. The unit-cell parameters a and c and the ratio c/a change linearly with x. Powder data at 298 K are given for AgGaSe2, AgGa0.80In0.20Se2, AgGa0.70In0.30Se2, AgGa0.40In0.60Se2, AgGa0.20In0.80Se2 and AgInSe2, and for CuGaSe2, CuGa0.60In0.40Se2, CuGa0.30In0.70Se2 and CuInSe2.
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    Applied crystallography online 13 (1980), S. 318-337 
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    Applied crystallography online 13 (1980), S. 338-339 
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    Topics: Geosciences , Physics
    Notes: If the length of the focal spot is increased while the width remains constant, X-ray output can be increased without changing the specific loading on the anode.
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 13 (1980), S. 391-394 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: To increase the integrated reflexion intensity of a monochromating crystal, the strain distributed due to impurity introduction can be utilized and, compared with conventional mechanical processing, can be a more controllable method. From this viewpoint, numerical computations on the dynamical diffraction theory for distorted crystals have been performed for the 220 reflexion of Cu Kα X-rays by Si crystals with several different strain distributions; the one changing linearly with depth from −10−3 at the surface to zero at 28 μm depth gives the maximum integrated intensity within the restriction that the full width of the intensity profile is 100′′. The integrated intensity in this case is 5.3 and 4.5 times as strong as that of a perfect crystal plate for σ and π polarizations respectively. It is more enhanced for shorter wavelengths, e.g. nine times for Mo Kα. In addition, that intensity profiles for distributed strains are cut sharply at both ends is certainly favourable for the purpose of monochromating white X-rays. A preliminary experiment with an intentionally processed sample showed a fourfold intensity increase for a σ-polarized Cu Kα line with a full width of 80′′.
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  • 74
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    Applied crystallography online 13 (1980), S. 401-401 
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  • 75
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    Applied crystallography online 13 (1980), S. 88-92 
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    Topics: Geosciences , Physics
    Notes: The device described here has been designed to perform microcreep experiments and, simultaneously, to get X-ray topographic images of the sample. Such dynamic experiments are now possible with white synchrotron radiation (LURE-DCI Orsay). The sample material, germanium, is hard to machine; so a simple shape was chosen (rectangular platelet 20 × 5 × 0–2 mm). The grip system is quite simple and the whole assembly is compact enough to be adapted to fit a standard goniometer head. Temperatures as high as 923 K in air and forces up to few tens of Newtons can be reached. The first experiments on Ge bicrystals have shown the device to perform as expected.
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  • 76
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    Applied crystallography online 13 (1980), S. 78-87 
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    Topics: Geosciences , Physics
    Notes: A polished plate of type Ia natural diamond, containing regions which had been bombarded by electrons of energy between 2.0 and 4.5 GeV to total doses of 1̃024 electrons m−2 in polarized-photon production experiments, was examined, both before and after annealing at 1133 K for 8 h, using birefringence, cathodoluminescence photography and spectroscopy, X-ray topography and a novel method for mapping differences of interplanar spacing; `dilatation topography'. The annealing effected some reduction of overall strain, but it also generated an enhancement of diffraction contrast and cathodoluminescence at certain grown-in defects that the specimen contained. By means of dilatation topographs, interplanar spacings in a region of maximum electron-beam damage were compared with those in least-damaged regions some millimetres away. In the case of (110) planes that had been grazed by the electron beam, the maximum relative expansion, Δd/d, in damaged regions so found was reduced from 1.2 × 10−3 to 0.9 × 10−3 by the annealing. Evidence was obtained that the magnitude of expansion in the region of maximum damage was dependent upon crystallographic direction. Criteria are suggested for selection of diamonds to be used in polarized-photon production experiments.
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  • 77
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    Applied crystallography online 13 (1980), S. 93-95 
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    Topics: Geosciences , Physics
    Notes: Cell data for monoclinic sebacic acid COOH(CH2)8COOH, C10H18O4, and dodecanedioic acid COOH(CH2)10COOH, C12 H22O4, are accurately given: (C10) a = 15.064 (6), b = 4.987 (4), c = 10.142 (6) Å, β = 133.14 (5)°; (C12) a = 17.594 (8), b = 4.933 (3), c = 10.174 (5) Å, β = 132.35 (3)°. It is shown that crystallographic data for molecular alloys [C10]x[C12]1 −x are significantly different for those prepared by fusion (m.a.f.) and those by sublimation (m.a.s.). X-ray powder data are given for the two series of solid solutions.
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  • 78
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    Applied crystallography online 13 (1980), S. 95-96 
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    Notes: The cell constants for the title compound, HMTSFT–CNQ4, (C12F4N4).(C12H12Se4), M.W. 748.21, were determined from a single crystal exposed on a Syntex P{\bar 1} automated diffractometer and then refined from precision powder data with Cr Kα1 (2.28962 Å): a = 21.906 (5), b = 12.918 (3), c = 4.0184 (10) Å and β = 91.658 (10)°; U = 1136.7 Å3, Z = 2, space group C2/m; Dc = 2.186 Mg m−3.
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  • 79
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    Applied crystallography online 13 (1980), S. 128-131 
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    Topics: Geosciences , Physics
    Notes: A &psgr;-φ goniometer with two axes of rotation, driven by stepping motors, was designed as an attachment for a horizontal &thgr;/2&thgr; goniometer. By means of this arrangement it is possible to measure strains and compute stresses in single crystals and in separate crystals of a bicrystal or a coarse-grained polycrystalline specimen. The available rotations also make it possible to investigate residual macrostresses and textures in polycrystalline specimens. Results of the test measurements on a tensile specimen of a molybdenum single-crystal are given.
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  • 80
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    Applied crystallography online 13 (1980), S. 132-134 
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    Notes: A calculation of γ(r), the correlation function which gives the X-ray scattering of a cubic object of uniform density, is given for the full range of r. A new method, which can be applied to other systems, is used. The function γ(r) and its first derivative are everywhere continuous, but γ′′(r) is discontinuous at r = L and r = L□2 (L = cube edge length). This leads to an intersect distribution of unexpected shape. The scattering intensity as a function of angle is calculated by Fourier inversion of γ(r).
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  • 81
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    Applied crystallography online 13 (1980), S. 135-140 
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    Notes: An experimental method is described which enables the inelastically scattered X-ray component to be removed from diffractometer data prior to radial density function analysis. At each scattering angle an energy spectrum is generated from a Si(Li) detector combined with a multi-channel analyser from which the coherently scattered component is separated. The data obtained from organic polymers has an improved signal/noise ratio at high values of scattering angle, and a commensurate enhancement of resolution of the RDF at low r is demonstrated for the case of PMMA (ICI `Perspex'). The method obviates the need for the complicated correction for multiple scattering.
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  • 82
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    Applied crystallography online 13 (1980), S. 148-153 
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    Notes: Until now, the calculation of intensities diffracted by layer structures has only been treated in the two extreme cases, namely (i) the layers interfere completely and (ii) the layers do not interfere (turbostratic structures). The present paper develops the mathematical treatment which allows the calculation in the intermediate case, namely when layers are only partially interfering.
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  • 83
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    Applied crystallography online 13 (1980), S. 141-147 
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    Notes: A niobium tungsten bronze crystal with a nominal composition 3 Nb2O5.8WO3 gives circular diffuse scattering in the electron diffraction pattern. The diffuse rings change shape and size when the crystal is reduced at high temperature. The observations are explained by improving the cluster model proposed by De Ridder, Van Tendeloo, Van Dyck & Amelinckx [Phys. Status Solidi A (1977), 41, 555–560]; the present clusters are composed of nine pentagonal-tunnel sites. The 1 MV high-resolution electron microscope images reveal that the clusters have several different atomic arrangements and compositions. The relation between the clusters and the micro-domains, formed in the initial stage of long-range ordering, is clarified.
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  • 84
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    Applied crystallography online 13 (1980), S. 163-167 
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    Notes: Analysis of Bragg X-ray intensities collected on a single-crystal diffractometer with a pyrolitic graphite monochromator in the diffracted beam has revealed small systematic errors which are a consequence of the necessarily large illuminated area of monochromator crystal.
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  • 85
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    Applied crystallography online 13 (1980), S. 154-162 
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    Notes: The amount of information which can be obtained from a small-angle X-ray experiment can be considerably increased by orienting the solute particles with external forces during the scattering experiment. In this paper it is shown that orientation by flow, for instance through a capillary tube, gives additional information about size, shape, flexibility and rotational diffusion of the particles. The only requirement, in order to obtain flow-oriented samples, is that the solute particles must be relatively large and asymmetric. On the other hand, if the scattering curve is dependent on the flow rate through the capillary, it can immediately be concluded that the solute particles are asymmetric (or they are deformed in the hydrodynamic field). Equations describing the relationship between flow rate, molecular shape and scattered intensity are given, and theoretical intensity patterns for some representative cases are presented. It follows that there is a fundamental difference in scattering patterns for oblate and prolate ellipsoids of revolution. This difference can be used to differentiate between these two cases. Some experimental results obtained using inorganic model colloids are presented.
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  • 86
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    Applied crystallography online 13 (1980), S. 168-175 
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    Topics: Geosciences , Physics
    Notes: An analysis of the small-angle scattering problem based on Shannon sampling is presented. It is shown that this approach leads to an accurate assessment of the information contained in a given data set and rigorous estimates of the errors inherent in the parameters derived therefrom.
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  • 87
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    Applied crystallography online 14 (1981), S. 3-7 
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    Notes: There has recently been an increased amount of interest in laboratory equipment for extended X-ray absorption fine-structure (EXAFS) measurements. In an earlier paper a facility for performing such measurements easily in a few hours was described in some detail. In this paper, further development of the techniques is reported. The use of high-power rotating-anode X-ray generator, the design of an X-ray curved-crystal spectrometer, the factors governing the proper choice of monochromator crystals and the design of fast-counting detectors and electronics are discussed. In addition, it is shown how errors caused by characteristic lines in the spectrum can be eliminated by use of a flux stabilization circuit.
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  • 88
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    Applied crystallography online 14 (1981), S. 24-27 
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    Topics: Geosciences , Physics
    Notes: Photographic neutron intensity measurements on a 2 mm3 single-crystal of triclinic lysozyme are compared with conventional neutron diffractometer data. The reflections were recorded with the oscillation technique. The structure factors were derived from the optical densities scanned by an automatic microdensitometer and processed by computer programs. A statistical analysis shows that the photographic data are of about the same accuracy as recently collected diffractometer data. For the same flux and crystal volume the data collection time is reduced by up to two orders of magnitude.
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  • 89
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    Applied crystallography online 14 (1981), S. 43-50 
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    Notes: A device is described which uses liquid nitrogen to generate a cold or hot gas stream which is blown directly onto the crystal mounted on an X-ray diffractometer. With a specially constructed high-vacuum (〈 1.3 × 10–5 Pa) jacketed silica Dewar tube, it can operate between 83 and 1120 K with a stability over long time periods of ± ¼ K below and ± 1 K above ambient temperature. In the latter case the short-time stability is ± ¼ K for hours. It gives an inert atmosphere at elevated temperatures and allows extensive data collection for the accurate determination of crystal structures. The evaporator, the automatic refilling system and the silica Dewar tube are described.
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  • 90
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    Applied crystallography online 14 (1981), S. 60-61 
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    Notes: A fitting method is proposed for X-ray diffraction profiles which requires only a small number of parameters.
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  • 91
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    Applied crystallography online 14 (1981), S. 61-62 
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    Notes: Complete solid solution is observed amongst the compounds of the type M1MgCr2(VO4)3 (where M1 = K, Rb or Tl). The solid-solution series obtained show linear changes in peak positions and peak intensities in their X-ray diffraction patterns. The crystallographic behaviour with respect to the value of x for (RbxK1−xMgCr2(VO4)3 and (TlxK1−x)MgCr2(VO4)3 solid solutions is discussed.
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  • 92
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    Applied crystallography online 14 (1981), S. 64-65 
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    Notes: Indexed powder patterns of the monoclinic phase, stable at room temperature, and of the orthorhombic phase, stable for T 〉 786 K, are given. The cell dimensions are: a = 15.737 (8), b = 9.231 (5), c = 18.224 (9) Å, β = 125.46 (2)° at 295 K; a = 9.330 (3), b = 12.868 (5), c = 9.242 (3) Å at 818.6 K. Linear equations describing the thermal expansion of the two phases of ferric molybdate are reported. To verify if ferric molybdate can incorporate excess MoO3, measurements on non-stoichiometric samples were also made: no evidence of the presence of excess MoO3 was found.
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  • 93
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    Applied crystallography online 14 (1981), S. 68-68 
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    Notes: High-temperature As2O5 at 768 ± 5 K is tetragonal with a = 8.577 (1), c = 4.637 (1) Å, V = 341.2 Å3, Z = 4, Dc = 4.475 Mg m−3. Indexed powder data are given.
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  • 94
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    Applied crystallography online 14 (1981), S. 85-93 
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    Notes: A flat, relatively thin (9 mm) xenon-filled multiwire proportional counter with two-dimensional, 2 μs delay line readout of a 270 × 300 mm active area has been developed for use as a position-sensitive area X-ray detector in the 8 keV energy region (Cu Kα) used in crystallographic structure work with large biological molecules. Its quantum detection efficiency for 8 keV X-ray photons is about 0.5, a value which is spatially uniform to within ± 2%. Its dead-time loss fraction at a typical data collection rate of 30000 photons s−1 is 12%. The detector has spatial resolution for X-rays of 0.6 mm FWHM in the horizontal direction and 2 mm, the anode wire spacing, in the vertical direction. The effects of parallax are found to be limited and do not seriously increase the apparent size of the diffracted beams. The position sensitivity of this detector is geometrically linear to within 0.5 mm across its active surface. Routine maintenance of the detector requires the attention of a skilled technician but is not time consuming. For four years, this detector has been used to measure millions of reflection intensities from crystals of many different proteins. The down time due to the detector has averaged less than four days per year, considerably less than the down time of other components of the data collection system. Four new protein structures have now been solved using data from this detector. Also, a considerable amount of data have been collected at higher resolution or at different temperatures with crystals of other proteins.
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  • 95
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    Applied crystallography online 14 (1981), S. 124-130 
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    Notes: The sources of systematic error in the X-ray diffractometer method of stress measurement are discussed. The errors in stress measurement and correction procedures for their elimination are described and quantitatively assessed.
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  • 96
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    Applied crystallography online 14 (1981), S. 117-123 
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    Notes: The diffraction aspect and rough cell parameters of a crystal to be studied are usually known before mounting the crystal on a diffractometer. Such data are used for orientation purposes in the method described. An ordered list of indexed 2θ values is calculated from which an optimum 2θ for a peak search is derived. The peaks found are centered, their possible unique indices are derived by comparison of the observed 2θ values with the calculated values. Two intense reflections with few indexing ambiguities are selected to define the crystal orientation. Their possible pairs of indices are found by considering combinations of indices related to the unique indices by the Laue-group symmetry and for which the calculated angle between the reciprocal vectors is comparable with the observed angle. Only the non-equivalent orientations defined by these initial pairs will be accepted. An initial pair will be rejected if the indices of both reflections can be transformed into those of a previously accepted pair by a single Laue-group symmetry operator of the first kind. The correct setting is usually obvious from a very short list of possible orientations and is retained. This simple approach has been programmed and treats all symmetries without branching of the logic. Rhombohedral crystals can be referred to hR or rP cells. The possible non-equivalent settings due to metric ambiguities, to pseudo-symmetry or to symmetry are exhaustively listed, but no symmetry-related setting is indicated. This scheme has automatically oriented more than 40 crystals from the seven crystal systems in 20–50 min each. The wavelength, the cell parameters and the short symbol of a valid space group in the correct diffraction aspect are the only input.
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    Applied crystallography online 14 (1981), S. 137-139 
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    Notes: Neutron time-of-flight powder data have been collected for forsterite [Mg2SiO4; Pbnm (D162h, No. 62); Z = 4, a = 4.7534 (1), b = 10.1989 (2), c = 5.9813 (1) Å] with the ZING-P′ high-resolution diffractometer at Argonne National Laboratory. Forty-seven variables, including anisotropic temperature-factor coefficients, were refined with a profile-fitting procedure to R(profile) = 2.10% and R(Rietveld) = 3.53%. Positional and thermal parameters are in good agreement with those determined from recent X-ray and neutron single-crystal diffraction experiments. Results suggest that powder data can be used to obtain accurate positional parameters and reasonable temperature factors for moderately complex structures.
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    Applied crystallography online 14 (1981), S. 139-141 
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    Notes: A Kratky small-angle X-ray camera was modified so as to allow the use of a one-dimensional (one-dimensional) position-sensitive detector (PSD) with it. The modification was designed in such a way that most of the calibrations, necessary for subsequent correction of the collected intensity data, can be performed with little alteration in the collimation geometry or the electronics settings. In particular, the calibration of the uniformity of detector efficiency can be performed by repeated vertical travel of the detector at a constant speed across a beam scattered from a sample.
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    Applied crystallography online 14 (1981), S. 145-148 
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    Notes: A computer program for the separation of a composite peak into the components and the background has been written in Fortran. Each component is approximated by a function of the form y(x) = c [1 + ({{x - d}\over{e}})^{2}]^{-f}, where c, d, e and f are the parameters to be determined by a least-squares method. Arbitrary, known or assumed relations among the parameters of different components may be read in to reduce the number of independent parameters and save computation time or, in other cases, to offer a better chance of separating a complex composite peak by varying a subset of the parameters.
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    Applied crystallography online 14 (1981), S. 151-153 
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    Notes: A computer program has been written with the aim of calculating the domain of an atom in a structure. The domain may be limited by planes situated half-way between the atoms, or at a distance that takes into account the relative radii of the atoms. Data concerning this domain and the corresponding coordination polyhedron are computed and printed. Punched cards, to be used in a special plotting program, can also be produced. Three types of weighted coordination number are calculated.
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