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  • Fibers  (8)
  • Alkenes  (5)
  • Wiley-Blackwell  (13)
  • Institute of Physics
  • Molecular Diversity Preservation International (MDPI)
  • 1960-1964  (13)
Collection
Keywords
Publisher
  • Wiley-Blackwell  (13)
  • Institute of Physics
  • Molecular Diversity Preservation International (MDPI)
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    The Oxidation of Olefins with Palladium Chloride Catalysts (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 80-88 
    Details
    ISSN: 0570-0833
    Keywords: Oxidation ; Palladium ; Catalysis ; Alkenes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The oxidation of olefins to carbonyl compounds with palladium compounds, especially the oxidation of ethylene to acetaldehyde, is at present carried out on a technical scale. The reaction takes place via a palladium-olefin complex, the formation of which is inhibited by halide ions. Hydrolysis to the carbonyl compound is inhibited by hydrogen ions. The knowledge gained by studying the reaction of olefins with pure solutions of palladium salts allows important conclusions to be drawn concerning the action of technical catalyst solutions containing copper and palladium chloride.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196200801
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  • 2
    Electronic Resource
    Electronic Resource
    Type and Extent of Isomerization of Straight-Chain Mono-olefins during the Koch Carboxylic Acid SynthesisReported in part at the meeting of the Gesellschaft Deutscher Chemiker, Aachen 1961; Angew. Chem. 73, 767 (1961). (1963)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 719-722 
    Details
    ISSN: 0570-0833
    Keywords: Koch carboxylic acid synthesis ; Carboxylic acids ; Alkenes ; Isomerization ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: When straight-chain mono-olefins, from pentene to decene, are subjected to the Koch carboxylic acid synthesis by the addition of CO and H2O or CH3OH in the presence of strongly acidic catalysts, not only the expected secondary acids, but also mixtures of a specific type of tertiary acids or their methyl esters are formed. When the catalysts contain boron trifluoride, the secondary acids are formed in ratios of isomers which are, within the scope of this investigation, independent of the experimental conditions and which agree well with the values calculated from the isomer equilibria of the corresponding n-olefins. Using concentrated sulfuric acid as catalyst, a larger proportion of tertiary acids is obtained than with BF3-catalysis, and amongst the secondary acids, those isomers predominate in which the COOH group is situated near the centre of the molecule.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196307191
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  • 3
    Electronic Resource
    Electronic Resource
    Pyrrolidone, Capryllactam and Laurolactam as new Monomers for Polyamide FibersFrom a lecture delivered at the meeting of the Plastics and Rubber Section of the Gesellschaft Deutscher Chemiker on April 9th, 1962, in Bad Nauheim (Germany). (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 430-435 
    Details
    ISSN: 0570-0833
    Keywords: Pyrrolidone ; Polyamides ; Fibers ; Lactams ; Polymerization ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The industrial production of capryllactam (1-azacyclononan-2-one) and of laurolactam (1-azacyclotridecan-2-one) starts with cyclization of acetylene or butadeine to give cyclooctatetraene or cyclooctadiene, or cyclization of butadiene to give cyclododecatriene. Further steps are: oxidation of the cyclic hydrocarbon to the ketone, formation of the oxime, and rearrangement of the latter with sulfuric acid. Pyrrolidone can be prepared from acetylene and formaldehyde by way of butyrolactone. The behavior of the lactams during polycondensation is described and the properties of the resulting fibers are compared with those of the known polyamide fibers.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196204301
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  • 4
    Electronic Resource
    Electronic Resource
    Polar Addition of Hydrogen Halides onto OlefinsThis work was supported by a grant from the National Science Foundation. (1964)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 3 (1964), S. 245-249 
    Details
    ISSN: 0570-0833
    Keywords: Addition ; Alkenes ; Electrophilic reactions ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Various structures have been proposed for the intermediates of electrophilic additions onto olefins; these include halonium ions, classical carbonium ions, π-complexes (i.e. nonclassical carbonium ions), and π-complexes with back-coordination. It is shown here that it is impossible to use any one of these entities alone to explain all such electrophilic additions; the electrophile itself determines the nature of the transition state formed. Polar addition of hydrogen halides onto olefins appears to proceed via a classical carbonium ion which does not occur as the free ion but as an undissociated ion pair. Various other mechanisms have been excluded by studies reported here of the stereochemical course of such additions.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196402451
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  • 5
    Electronic Resource
    Electronic Resource
    Emulsion Polymerization of Vinyl Monomers under the Influence of Ionizing Radiation (1963)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 295-308 
    Details
    ISSN: 0570-0833
    Keywords: Emulsion polymerization ; Polymerization ; Polymerization ; Alkenes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ionizing radiation induces the polymerization of some vinyl monomers in aqueous emulsion with high radiation yields. With identical emulsion compositions, the kinetics of this reaction and the kinetics of emulsion polymerization induced by water-soluble initiators are very similar. The rate of reaction in emulsion polymerization is about one hundred times greater than in bulk polymerization. The initiation of emulsion polymerization by means of ionizing radiation permits uniform “illumination” of the reacting volume, as well as almost any desired variation in the frequency of initiation during the reaction. The sharp decrease in the overall rate of reaction when initiation is interrupted during emulsion polymerization of styrene induced by γ-rays contradicts the earlier concept of sharply separated reaction zones.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196302951
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  • 6
    Electronic Resource
    Electronic Resource
    β-Lactams, Their Polymerization and Use as Raw Materials for FibersFrom a lecture delivered on April 9th, 1962 at a meeting of the GDCh-Fachgruppe “Kunstsoffe and Kautschuk” Plastics and Rubber Division of the German Chemical Society in Bad Nauheim. (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 481-488 
    Details
    ISSN: 0570-0833
    Keywords: Lactams ; Polymerization ; Fibers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Lactams can be prepared by cyclization of β-aimno acid esters. Recently they have become available also from olefins by addition of N-carbonysulfamyl chloride (isocyanatosulfonyl chloride) and from aldehydes by reaction with N-carbonylsulfamyl chloride and ketene. Condensative or anionic polymerization results in polyamides the chains of which contain many more amide groups than the chains of polyamides of the nylon-6 type. Hence the new polymers resemble silk moreclosely. Fibers and films can be prepared from solution.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196204811
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  • 7
    Electronic Resource
    Electronic Resource
    Dyeing of Poly(acrylonitrile) Fibers with Azatrimethinecyanines (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 532-537 
    Details
    ISSN: 0570-0833
    Keywords: Polyacrylonitrile ; Fibers ; Azatrimethinecyanines ; Dyes/Pigments ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Like all basic dyes, azatrimethinecyanines possess a good dyeing affinity for acrylic fibers. Compounds with isolated nitrogen atoms in the trimethine chain show insufficient light fastness, whereas good to excellent fastness to light is displayed by compounds having neighboring nitrogen atoms in the chain. Thus, a working hypothesis stating that the light fastness of trimethinecyanines on acrylic fibers is improved by progressive replacement of methine groups by nitrogen atoms has been partially confirmed.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196205321
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  • 8
    Electronic Resource
    Electronic Resource
    Elastomeric Fibers Based on PolyurethanesFrom a report delivered on April 10th, 1962 at the meeting of the GDCh-Fachgruppe “Kunststoffe und Kautschuk” (Plastics and Rubber Group of the German Chemical Society) in Bad Nauheim. (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 419-424 
    Details
    ISSN: 0570-0833
    Keywords: Elastomers ; Fibers ; Polyurethanes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Highly elastic polyurethanes suitable for fiber production can be obtained by various synthetic routes based on diisocyanate polyaddition processes. Macrodiisocyanates obtained from long chain diols and diisocyanates are allowed to react with polyamines during fiber formation (chemical spinning process) or the macrodiisocyanates are treated in solvents (e.g. dimethylformamide) with polyamines to give highly viscous, spinnable solutions of polymer. Both methods yield highly elastic polymers with wide-mesh network structures. The production of polyurethane fibers and their structures and physical properties are described.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196204191
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  • 9
    Electronic Resource
    Electronic Resource
    Copolymers and Fibers from VinylidenedicarbonitrileLecture at the Meeting of the Gesellschaft Deutscher Chemiker, Section “Kunststoffe und Kautschuk”, on April 10th. 1962 at Bad Nauheim (Germany). (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 425-430 
    Details
    ISSN: 0570-0833
    Keywords: Copolymers ; Fibers ; Vinylidenedicarbonitrile ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vinyldendicarbonitrile (Vinylidene cyanide) on free redical catalyzed copolymerization shows a much stronger tendency to form 1:1 alternating copolymers than acrylonitrile. While bulk poly(vinylidene cyanide) fails to crystallize, despite its molecular symmetry, several alternating copolymers are readily crystallizable, notably those containing butadiene, isoprene, isobutylene, or vinylidene chloride. Fibers have been prepared from a number of the higher melting copolymers and examined for physical properties. Fibers from the vinyl acetate and vinyl chloride copolymers show expectional elastic behavior both when dry and wet. The fiber from the vinylidene cyanide |vinyl acetate alternating copolymer (Darvan® nytril fiber) is only moderately oriented and is characterized by exceptional softness and excellent elastic recovery and resilience, both when dry and wet.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196204251
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  • 10
    Electronic Resource
    Electronic Resource
    Reactions of Olefins with the Titanium-Carbon BondDedicated to Prof. Dr. Karl Ziegler on the occasion of his 65th birthday (1963)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 704-714 
    Details
    ISSN: 0570-0833
    Keywords: Titanium ; Alkenes ; Polymerization ; Titanium ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: At low temperatures, ethylene and α-olefins (Δ1-olefins or 1-alkenes) are rapidly converted into oligomrs by the two-component organometallic catalyst CH3TiCl3·CH3AlCl2. To achieve smooth oligomerizations, aromatic or chlorinated hydrocarbons must be used as solvents. Although the activity of the titanium-carbon bond is enhanced by the aluminum component of the catalyst, the aluminum and its methyl group do not participate in the reaction proper; the latter proceeds exclusively at the titanium-carbon bond. The reaction will olefins can be used as an analytical method for the quantitative determination of the titanium-carbon bond in admixture with the organoaluminum component. It is thus possible to follow the reaction leading to formation of the catalyst from titanium tertrachloride, as well as the processes occurring at the titanium-carbon bond during the oligomerization of olefins. All the observations indicate that the catalyst possesses an ionic structure which is determined by the solvent. It is shown that the initial reaction step probably involves formation of a complex between the olefin and the alkyltitanium cation. The reaction scheme proposed is based on organometallic reactions which are characterized by carbanion and hydride transfers within the olefin-cation complex. This mechanism, which is unusual for Ziegler catalysts, is due to the predominance of hydride transfers.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196307041
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