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  • Chemistry  (27,504)
  • Inorganic Chemistry  (4,775)
  • Fluid Mechanics and Thermodynamics
  • 1965-1969  (23,864)
  • 1945-1949  (3,703)
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  • 1
    Publication Date: 2011-08-12
    Description: Source function solution for radiative heat transfer through nonisothermal absorbing and emitting gray gas
    Keywords: Fluid Mechanics and Thermodynamics
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  • 2
    Publication Date: 2011-08-11
    Description: Hypersonic turbulent boundary layers transformation to incompressible form
    Keywords: Fluid Mechanics and Thermodynamics
    Type: AIAA Journal; Volume 5; p. 1202-1203
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  • 3
    Publication Date: 2011-08-12
    Description: Turbulence and longitudinal heat transfer for accelerating and decelerating flow using Navier- Stokes, continuity and energy equations
    Keywords: Fluid Mechanics and Thermodynamics
    Type: Zeitschrift fuer Angewandte Mathematik und Mechanik; Volume 48; p. 87-98
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  • 4
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    In:  Other Sources
    Publication Date: 2019-06-27
    Description: No abstract available
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-CR-130666 , RP-SR-0001-APP-B
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  • 5
    Publication Date: 2019-06-27
    Description: Although tungsten-uranium dioxide composites appear very promising, as fuel element materials for high-temperature nuclear rocket reactors, one of the major problems with these materials is the loss of fuel at reactor operating temperatures (near or above 4500 F). Substantial fuel losses occur by vaporization whenever the uranium dioxide is directly exposed to elevated temperature environments and by fuel migration and vaporization when reactor operating conditions that involve thermal cycling are simulated. Several methods of minimizing fuel loss have been evaluated and appear quite promising.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-TM-X-1059 , E-2590 , GRC-E-DAA-TN44079
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  • 6
    Publication Date: 2019-06-27
    Description: No abstract available
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-TM-X-1336 , L-5185
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  • 7
    Publication Date: 2019-06-27
    Description: No abstract available
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-TM-X-1109 , L-4517
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  • 8
    Publication Date: 2019-06-26
    Description: Uranium losses during thermal cycling of tungsten - uranium dioxide composites to 2500 C in flowing purified hydrogen for specimens initially containing 35 volume percent uranium dioxide were reduced by the use of thorium dioxide, calcium oxide, or yttrium oxide as additives in solid solution with the uranium dioxide. The effectiveness of the additives decreased in the order yttrium oxide, calcium oxide, and thorium dioxide. Stabilization of uranium dioxide by calcium oxide or yttrium oxide can be explained in part on the basis of the introduction of oxygen vacancies into the fluorite lattice and the associated lowered partial molar free energy of oxygen. The difference in the effectiveness of calcium oxide and yttrium oxide is discussed, and a possible explanation of the observed behavior is proposed. Of the concentrations of yttrium oxide tested (i.e., 2. 5, 5, and 10 mole percent), 10 mole percent of yttrium oxide was the most effective in pre venting loss of uranium from composities.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-TM-X-1295 , E-3238
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  • 9
    Publication Date: 2019-06-27
    Description: This study program was conducted to obtain a sound theoretical understanding of and a valid analytical method for predicting the performance of porous plate water boilers.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-CR-65991 , HSER-3509
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  • 10
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    In:  Other Sources
    Publication Date: 2019-07-12
    Description: The rate of heat transfer between a fluid stream in turbulent flow and a smooth, solid wall is largely controlled by the relatively high resistance of the laminar sublayer next to the wall. Although this laminar layer ii extremely thin, heat can be transferred through it only by molecular diffusion. Hence the resistance of this layer is very much greater than for a layer the same thickness farther out in the stream where turbulent exchange is the controlling factor. The thickness of the laminar layer is difficult to define precisely, since there is a gradual transition to the turbulent flow outside, but for the usual scale of many engineering applications almost half the temperature difference between the fluid and the wall occurs in a layer of a few thousands of an inch in thickness. When the wall is made of porous material and a coolant gas is forced through the wall into the stream, it has been found that a very small flow rate of the coolant is remarkably effective in keeping the wall at a low temperature. The coolant flow rate required is such as to give an average velocity normal cooling wall of the order of 1 per cent of the main stream velocity. This flow rate is so low that clearly the injected gas must act as an insulator rather than as a normal coolant. Because of its relatively low velocity, the injected gas can have very little influence on heat convection or momentum transfer in the turbulent stream, and its effect must be confined to the laminar sublayer. The possible influence of the coolant flow on the thickness of the laminar layer will be discussed in Section V.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: JPL-PR-4-50
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  • 11
    Publication Date: 2019-06-27
    Description: Approximately 2 minutes 13 seconds after lift-off of the Apollo 6 mission, abrupt changes of strain, vibration, and acceleration measurements were indicated in the S-IVB, instrument unit, adapter, lunar module, and command and service modules; photographs showed objects coming from the area of the adapter. The adapter, however, continued to sustain the required loads with no impairment of the mission. The investigation was first focused upon the understanding of the coupled vibration modes and characteristics of the launch vehicle and spacecraft.' Extensive test programs were conducted. It was eventually concluded that the adapter failure was not caused by vibration. Extensive study of the airborne photography and other evidence indicated that a large area of the adapter had lost inner facesheet from the honeycomb sandwich panels. Loads and stresses resulting from vibration were determined to be insufficient to initiate such a failure. The investigation was then directed toward determining the range of pressures that could have been trapped in the Apollo 6 adapter sandwich panels, and toward determining the tolerance of the panels to withstand pressure with various degrees of flaws such as adhesive voids and facesheet dents. The degradation effects of moisture and heat exposure on the adhesive strength were also studied and tested. These tests and analyses led to the conclusion that pressure internal to the sandwich panels could have caused the failure, if a large flaw existed. The pressure buildup would have been caused by aerodynamic heating effects on air and moisture trapped in the panel. The probable cause of the failure was found in the original ultrasonic inspection scan record of the affected adapter panel. In the center of the region where the adapter failed, horizontally along the station 709 panel splice, the record contained two thick anomalous lines extending several feet. Without an X-ray record of this region, the significance of this particular scan record cannot be fully understood. However, since all other evidence had indicated that the adhesive had to be weakened in a rather large area to initiate the failure, the investigation was focused intently upon the station 709 splices of other adapters. Sufficient information was developed to verify that deficient assembly techniques have consistently resulted in abnormalities in the structure at this station. These abnormalities were identified in adapters 12, 13, 14, 15, and 16. Before the splice abnormalities were pinpointed, corrective action was taken to reduce pressure "buildup in the honeycomb panels and to reduce heat degrading effects on the adhesive. This was done by drilling vent holes in the inner facesheet and covering the outer facesheet with cork. The adapters having identified abnormalities in the station 709 splice are being repaired, and the contractor is investigating ways of avoiding these -abnormalities in panels yet to be bonded.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-TM-X-70374 , MSC-PT-R-68-22 , ANOMALY-6 , JSC-E-DAA-TN62388
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  • 12
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    In:  CASI
    Publication Date: 2019-06-27
    Description: No abstract available
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-CR-129890 , LMA790-1 , LMA790-01001C
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  • 13
    Publication Date: 2019-07-11
    Description: A large number of papers have been devoted to the problem of integration of equations of two-dimensional steady nonvertical adiabatic motion of a gas. Most of these papers are based on the application of the hodograph method of S. A. Chaplygin in which the plane of the hodograph of the velocity is taken as the region of variation of the independent variables in the equations of motion; the equations become linear in this plane. The exact integration of these equations is, however, obtained in the form of infinite series containing hypergeometric functions. The obtaining of such solutions and their investigation involves extensive computations. As a result, methods have been developed for the approximate integration of the equations of motion first transformed to a linear form. S. A. Chaplygin first pointed out such an approximate method applicable to flows in which the Mach number does not exceed 0.4.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1239 , Prikladnaia Matematika I Mekhanika, Tom XI
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  • 14
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    In:  CASI
    Publication Date: 2019-07-11
    Description: A study is made herein of the irrotational adiabatic motion of a gas in the transition from subsonic to supersonic velocities. A shape of the de Laval nozzle is given, which transforms a homogeneous plane-parallel flow at large subsonic velocity into a supersonic flow without any shockwaves beyond the transition line from the subsonic to the supersonic regions of flow. The method of solution is based on integration near the transition line of the gas equations of motion in the form investigated by S. A. Christianovich.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1236 , Prikladnaia Matematika I Mekhanika, Tom XI
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  • 15
    Publication Date: 2019-07-11
    Description: By means of characteristics theory, formulas for the numerical treatment of stationary compressible supersonic flows for the two-dimensional and rotationally symmetrical cases have been obtained from their differential equations.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1211 , ZWB Forschungsbericht; Rept-1581
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  • 16
    Publication Date: 2019-07-11
    Description: The turbulent flow in a conical diffuser represents the type of turbulent boundary layer with positive longitudinal pressure gradient. In contrast to the boundary layer problem, however, it is not necessary that the pressure distribution along the limits of the boundary layer(along the axis of the diffuser) be given, since this distribution can be obtained from the computation. This circumstance, together with the greater simplicity of the problem as a whole, provides a useful basis for the study of the extension of the results of semiempirical theories to the case of motion with a positive pressure gradient. In the first part of the paper,formulas are derived for the computation of the velocity and.pressure distributions in the turbulent flow along, and at right angles to, the axis of a diffuser of small cone angle. The problem is solved.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1137 , Central Aero-Hydrodynaical Institute Reports; Rept-462
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  • 17
    Publication Date: 2019-07-12
    Description: Strain gages were used to measure blade vibrations possibly causing failure in the 10-stage compressor of the 19XB jet-propulsion engine. The seventh and tenth stages were of great concern as a result of failures experienced by the manufacturer. Strain-gage records were obtained from all stages during acceleration, deceleration, and constant speed runs. Curves are presented herein showing the maximum allowable vibratory stress for a given speed, the change of the damping coefficient with the mounting of a strain gage at the base of the blade, the effect of rotor speed, on blade natural frequency, and the effect of the order of first bending-mode vibration on stress. It was found that for all stages the lower the order of vibration the higher the stress but no destructive vibrations were detected.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-RM-SE8A28
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  • 18
    Publication Date: 2019-07-12
    Description: An investigation has been conducted on a one-sixth segment of an annular turbojet combustor to determine the effects of modification in air-flow distribution and total-pressure loss on the performance of the segment. The performance features investigated during this series of determinations were the altitude operational limits and the temperature-rise efficiency. Altitude operational limits of the combustor segment, for the 19XB engine using the original combustor-basket design were approximately 38,000 feet at 17,000 rpm and 26,000 feet at 10,000 rpm. The altitude operational limits were approximately 50,000 feet at 17,000 rpm and 38,000 feet at 10,000 rpm for a combustor-basket design in which the air-passage area in the basket was redistributed so as to admit gradually no more than 20 percent of the air along the first half of the basket. In this case the total pressure loss through the combustor segment was not appreciably changed from the total-pressure loss for the original combustor basket design. Altitude operational limits of the combustor segment for the 19XB engine were above 52,000 feet at 17,000 rpm and were approximately 23,000 feet at 10,000 rpm for a combustor-basket design in which the distribution of the air-passage area in the basket was that of the original design but where the total-pressure loss was increased to 19 times the inlet reference kinetic pressure at an inlet-to-outlet density ratio of 2.4. The total-pressure loss for the original design was 14 times the inlet kinetic reference pressure at an inlet-to-outlet density ratio of 2.4.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-RM-SE7K16
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  • 19
    Publication Date: 2019-08-14
    Description: Rheology conference - continuum theory, stress and strain distribution analysis, polymer fluids and solids, testing techniques, and dispersions
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-CR-80887
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  • 20
    Publication Date: 2019-08-13
    Description: A heat-transfer investigation was conducted with air flowing through an electrically heated silicon carbide tube with a rounded entrance, an inside diameter of 3/4 inch, and effective heat-transfer length of 12 inches over a range of Reynolds numbers up to 300,000 and a range of average inside-tube-wall temperatures up to 2500 R. The highest corresponding local outside-tube-wall temperature was 3010 R.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA/RM-E9D12
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  • 21
    Publication Date: 2019-07-11
    Description: The calculation of the phenomena within the boundary layer of bodies immersed in a flow underwent a decisive development on the basis of L. Prandtl's trains of thought, stated more than forth years ago, and by numerous later treatises again and again touching upon them. The requirements of the steadily improving aerodynamics of airplanes have greatly increased with the passing of time and recently research became particularly interested in such phenomena in the boundary layer as are caused by small external disturbances. Experimental results suggest that, for instance, slight fluctuations in the free stream velocities as they occur in wind tunnels or slight wavelike deviations of outer wing contours from the prescribed smooth course as they originate due to construction inaccuracies may exert strong effects on the extent of the laminar boundary layer on the body and thus on the drag. The development of turbulence in the last part of the laminar portion of the boundary layer is, therefore, the main problem, the solution of which explains the behavior of the transition point of the boundary layer. A number of reports in literature deal with this problem,for instance, those of Tollmien, Schlichting, Dryden, and Pretsch. The following discussion of the behavior of the laminar boundary layer for periodically oscillating pressure variation also purports to make a contribution to that subject.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1228 , Ludwig Prandtl zum 70. Geburtstage, Schriften der Deutschen Akademie der Luftfahrtforschung, Publications of the Germany academy for Aviation Research; 247-255
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  • 22
    Publication Date: 2019-07-11
    Description: Some aerodynamic relations are derived which exist between two infinitely long airfoils if one is in a straight flow and the other in oblique flow, and both present the same profile in the direction of flow.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1158 , Deutsche Luftfahrtforschung, Forschungsbericht; Rept-1497
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  • 23
    Publication Date: 2019-07-11
    Description: At the request of the Junkers Aircraft and Engine Construction Company, Engine Division, Dessau Main Plant, an investigation was made using the interferometer method on the two turbine-blade profiles submitted. The interferometer method enables making visible the differences in density and consequently the boundary layers that develop when a flow is directed on the profile. Recognition of the points on the profile at which separation of flow occurs is thus possible. By means of the interference photographs the extent of the dead-water region may be ascertained. The size of the dead-water region provides evidence as to the quality of the flow and allows a qualitative estimate of the amount of the flow losses. Interference photographs thus provide means of judging the utility of profiles under specific operating conditions and provide suggestions for possible changes of profile contours that might help to improve flow relations. Conclusions may be drawn concerning the influence of the blade-spacing ratio, the inlet-air angle, and the connection between the curvature of the profile contour and the point of separation of the flow from the profile surface.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1171 , Deutsche Luftfahrtforschung, Untersuchungen und Mitteilungen; Rept-2096
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  • 24
    Publication Date: 2019-07-11
    Description: The cavitation in nozzles on airfoils of various shape and on a sphere are experimentally investigated. The limits of cavitation and the extension of the zone of the bubbles in different stages of cavitation are photographically established. The pressure in the bubble area is constant and very low, jumping to high values at the end of the area. The analogy with the gas compression shock is adduced and discussed. The collapse of the bubbles under compression shock produces very high pressures internally, which must be contributory factors to corrosion. The pressure required for purely mechanical corrosion is also discussed.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1078 , Eidgenoessische Technische Hochschule
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  • 25
    Publication Date: 2019-07-11
    Description: This paper includes the following topics: 1) Characteristic differential equations; 2) Treatment of practical examples; 3) First example: Diffuser; and 4) Second Example: Nozzle.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1244 , Chapter 4, Technische Hoschschule Dresden, Archives No. 44; Rept-44/4
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  • 26
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    In:  CASI
    Publication Date: 2019-07-11
    Description: This paper contains a tabulation of functions of the Mach number which are frequently used in high-speed aerodynamics. The tables extend from M = 0 to M = 10.0 in increments of 0.01 and are based on the assumption that air is a perfect gas having a specific heat ratio of 1.400.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-RM-L7K26
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  • 27
    Publication Date: 2019-09-05
    Description: Spontaneous ignition temperature, ignition temperature, and transition temperature for metal-oxidizing gas system models of solid propellant rocket engine combustion processes
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-CR-93541 , REPT.-816
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  • 28
    Publication Date: 2019-08-14
    Description: The conference on Turbojet-Engine Thrust-Augmentation Research was organized by the NACA to present in summarized form the results of the latest experimental and analytical investigations conducted at the Lewis Flight Propulsion Laboratory on methods of augmenting the thrust of turbojet engines. The technical discussions are reproduced herewith in the same form in which they were presented. The original presentation in this record are considered as complementary to, rather than substitutes for, the committee's system of complete and formal reports.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA Conference on Turbojet-Engine Thrust - Augmentation Research; Oct 28, 1948; Cleveland, OH; United States
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  • 29
    Publication Date: 2019-08-14
    Description: Continuum mechanics, stress-strain distributions, and polymer physics - rheology conference
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-CR-80886
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  • 30
    Publication Date: 2019-08-14
    Description: Water vapor effects on burning rate of aluminum and magnesium wires at atmospheric pressure
    Keywords: Fluid Mechanics and Thermodynamics
    Type: WSCI 66-4 , Combustion Institute Western States Section Spring Meeting; Apr 25, 1966 - Apr 27, 1966; Denver, CO; United States
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  • 31
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    In:  CASI
    Publication Date: 2019-07-13
    Description: The condensation of water vapor in an air consequences: acquisition of heat (liberated heat vaporization; loss of mass on the part of the flowing gas (water vapor is converted to liquid); change in the specific gas constants and of the ratio k of the specific heats (caused by change of gas composition). A discontinuous change of state is therefore connected with the condensation; schlieren photographs of supersonic flows in two-dimensional Laval nozzles show two intersecting oblique shock fronts that in the case of high humidities may merge near the point of intersection into one normal shock front.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1174 , Heeres-Versuchsstelle; 66/72
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  • 32
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    In:  CASI
    Publication Date: 2019-07-13
    Description: The recent experiments by Jakob and Erk, on the resistance of flowing water in smooth pipes, which are in good agreement with earlier measurements by Stenton and Pannell, have caused me to change my opinion that the empirical Blasius law (resistance proportional to the 7/4 power of the mean velocity) was applicable up to arbitrarily high Reynolds numbers. According to the new tests the exponent approaches 2 with increasing Reynolds number, where it remains an open question whether or not a specific finite limiting value of the resistance factor lambda is obtained at R = infinity. With the collapse of Blasius' law the requirements which produced the relation that the velocity in the proximity of the wall varied in proportion to the 7th root of the wall distance must also become void. However, it is found that the fundamental assumption that led to this relationship can be generalized so as to furnish a velocity distribution for any empirical resistance law. These fundamental assumptions can be so expressed that for the law of velocity distribution in proximity of the wall as well as for that of friction at the wall, a form can be found in which the pipe diameter no longer occurs, or in other words, that the processes in proximity of a wall are not dependent upon the distance of the opposite wall.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1231 , Zeitschrift fuer Angewandte Matematik und Mechanik; 5; 2; 136-139
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  • 33
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    In:  CASI
    Publication Date: 2019-07-13
    Description: The flow about a conical body of an ideal compressible fluid is considered. Assume that the velocity of the oncoming flow at infinity W is directed along the z-axis. The system of Cartesian coordinates x, y, z with origin at the vertex of the cone O is shown. From the considerations,of the dimensional theory, it may be found that along any ray issuing from O the components of the velocity u, v, W+w along the coordinate axes will maintain a constant value. It is further assumed that the conical body has such shape and disposition relative to the flow that u, v, and w are small in comparison with W.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1245 , Prikladnaya Matematika I Mekhanika; X; 513-520
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  • 34
    Publication Date: 2019-07-13
    Description: For a certain Mach number of the oncoming flow, the local velocity first reaches the value of the local velocity of sound (M = 1) at some point on the surface of the body located within the flow. This Mach number is designated the critical Mach number M(sub cr). By increasing the flow velocity, a supersonic local region is formed bounded by the body contour and the line of transition from subsonic to supersonic velocity. As is shown by observations with the Toepler apparatus, at a certain flow Mach number M 〉 M(sub cr) a shock wave is formed near the body that closes the local supersonic region from behind. The formation of the shock wave is associated with the appearance of an additional resistance defined as the wave drag. In this paper, certain features are described of the flow in the local supersonic region, which is bounded by the contour of the body and the transition line, and conditions are sought for which the potential flow with the local supersonic region becomes impossible and a shock wave occurs. In the first part of the paper, the general properties of the potential flow in the local supersonic region, bounded by the contour of the profile and the transition line, are established. It is found that at the transition line, if it is not a line of discontinuity, the law of monotonic variation of the angle of inclination of the velocity vector holds (monotonic law). An approximation is given for the change in velocity at the contour of the body. The flow about a contour having a straight part is studied. In the second part of the paper, an approximation is given of the magnitudes of the accelerations at the interior points of the supersonic region. With the aid of these approximations, it is shown that for profiles convex to the flow the breakdown of the potential flow,associated with an increase of the Mach number of the oncoming flow, cannot be due to the formation of an envelope of the characteristics within the supersonic region. On the basis of the monotonic law, the transitional Mach number M is found, beyond which the potential flow with local supersonic region becomes impossible.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1213 , Prikladnaya Matematika i Mekhanika; 10; 4; 481-502
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  • 35
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    In:  CASI
    Publication Date: 2019-07-13
    Description: In the present paper, the motion of a gas in a plane-parallel Laval nozzle in the neighborhood of the transition from subsonic to supersonic velocities is studied. In a recently published paper, F. I. Frankl, applying the holograph method of Chaplygin, undertook a detailed investigation of the character of the flow near the line of transition from subsonic to supersonic velocities. From the results of Tricomi's investigation on the theory of differential equations of the mixed elliptic-hyperbolic type, Frankl introduced as one of the independent variables in place of the modulus of the velocity, a certain specially chosen function of this modulus. He thereby succeeded in explaining the character of the flow at the point of intersection of the transition line and the axis of symmetry (center of the nozzle) and in studying the behavior of the stream function in the neighborhood of this point by separating out the principal term having, together with its derivatives, the maximum value as compared with the corresponding corrections. This principal term is represented in Frankl's paper in the form of a linear combination of two hypergeometric functions. In order to find this linear combination, it is necessary to solve a number of boundary problems, which results in a complex analysis. In the investigation of the flow with which this paper is concerned, a second method is applied. This method is based on the transformation of the equations of motion to a form that may be called canonical for the system of differential equations of the mixed elliptic-hyperbolic type to which the system of equations of the motion of an ideal compressible fluid refers. By studying the behavior of the integrals of this system in the neighborhood of the parabolic line, the principal term of the solution is easily separated out in the form of a polynomial of the third degree. As a result, the computation of the transitional part of the nozzle is considerably simplified.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1212 , Prikladnaya Matematika I Mekhanika; 10; 4; 503-512
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  • 36
    Publication Date: 2019-07-13
    Description: There are investigated the problems of the flow of a supersonic jet out of a vessel with plane side walls and the problem of the supersonic flow about a wedge when there is a zone of local subsonic velocities ahead of the wedge.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1155 , Bulletin de L'Academie des Sciences de L'URSS; 9; 121-143
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  • 37
    Publication Date: 2019-07-11
    Description: This paper makes the following assumptions: 1) The flowing gases are assumed to have uniform energy distribution. ("Isoenergetic gas flows," that is valid with the same constants for the the energy equation entire flow.) This is correct, for example, for gas flows issuing from a region of constant pressure, density, temperature, end velocity. This property is not destroyed by compression shocks because of the universal validity of the energy law. 2) The gas behaves adiabatically, not during the compression shock itself but both before and after the shock. However, the adiabatic equation (p/rho(sup kappa) = C) is not valid for the entire gas flow with the same constant C but rather with an appropriate individual constant for each portion of the gas. For steady flows, this means that the constant C of the adiabatic equation is a function of the stream function. Consequently, a gas that has been flowing "isentropically",that is, with the same constant C of the adiabatic equation throughout (for example, in origination from a region of constant density, temperature, and velocity) no longer remains isentropic after a compression shock if the compression shock is not extremely simple (wedge shaped in a two-dimensional flow or cone shaped in a rotationally symmetrical flow). The solution of nonisentropic flows is therefore an urgent necessity.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1187 , Rept-44/1
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  • 38
    Publication Date: 2019-07-11
    Description: The authors regret that due to the lack of time the investigations could not be carried out to a more finished form. Especially in the first part it was intended to include a few further applications and to use them in the general considerations of this part. In spite of the fact that the intentions of the authors could not be realized, the authors felt that it would serve the aims of the competition to present part I in its present fragmentary form. The topics include: 1) A Few General Remarks Covering the Prandtl-Busemann Method; and 2) Effect of Compressibility in Axially Symmetrical Flow around an Ellipsoid.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1233 , Lilienthal-Gesellschaft fuer Luftfahrtforschung Bericht S 13/1, Part 1; 40-68; Rept-13/1
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  • 39
    facet.materialart.
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    In:  CASI
    Publication Date: 2019-07-11
    Description: In the present paper which deals with the heat transfer between the gas and the wall for large temperature drops and large velocities use is made of the method of Dorodnitsyn of the introduction of a new independent variable, with this difference, however, that the relation between the temperature field (that is, density) and the velocity field in the general case considered is not assumed given but is determined from the solution of the problem. The effect of the compressibility arising from the heat transfer is thus taken into account (at the same time as the effect of the compressibility at the large velocities). A method is given for determining the coefficients of heat transfer and the friction coefficients required in many technical problems for a curved wall in a gas flow at large Mach numbers and temperature drops. The method proposed is applicable both for Prandtl number P = 1 and for P not equal to 1.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1229 , Prikladnaya Matematika I Mekhanika, Tom X; 449-474
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  • 40
    Publication Date: 2019-07-11
    Description: The present report consists of two parts. The first part deals with the two-dimensional stationary flow in the presence of local supersonic zones. A numerical method of integration of the equation of gas dynamics is developed. Proceeding from solutions at great distance from the body the flow pattern is calculated step by step. Accordingly the related body form is obtained at the end of the calculation. The second part treats the relationship between the displacement thickness of laminar and turbulent boundary layers and the pressure distribution at high speeds. The stability of the boundary layer is investigated, resulting in basic differences in the behavior of subsonic and supersonic flows. Lastly, the decisive importance of the boundary layer for the pressure distribution, particularly for thin profiles, is demonstrated.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1189 , Lilienthal-Gesellschaft fuer Luftfahrtforschung Bericht S13/1 Teil; 7-24
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  • 41
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    In:  CASI
    Publication Date: 2019-07-11
    Description: There has been under development for the high-speed wind tunnel of the LFA an optical measuring arrangement for the qualitative and quantitative investigation of flow. By the use of interference measurements, the determination of density at the surface of the bodies being tested in the air stream and in the vicinity of these bodies can be undertaken. The results obtained so far in the simple preliminary investigations show that it is possible, even at a low Reynolds number, to obtain the density field in the neighborhood of a test body by optical means. Simple analytical expressions give the relation between density, pressure, velocity, and temperature. In addition to this, the interference measurement furnishes valuable data on the state of the boundary layer, that is, the sort of boundary layer (whether laminar or turbulent), as well as the temperature and velocity distribution.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1253 , Forschungsbericht; Rept-1167
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  • 42
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    In:  CASI
    Publication Date: 2019-07-11
    Description: It is known that compression shocks which lead from supersonic to subsonic velocity cause the flow to separate on impact on a rigid wall. Such shocks appear at bodies with circular symmetry or wing profiles on locally exceeding sonic velocity, and in Laval nozzles with too high a back pressure. The form of the compression shocks observed therein is investigated.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1150 , Deutsche Luftfahrtforschung; Rept-1850
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  • 43
    Publication Date: 2019-07-11
    Description: The characteristics of the position and form of the transition surface through the critical velocity are computed for flow through flat and round nozzles from subsonic to supersonic velocity. Corresponding considerations were carried out for the flow about profiles in the vicinity of sonic velocity.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1147 , Deutsche Luftfahrtforchung; Rept-1992
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  • 44
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    In:  CASI
    Publication Date: 2019-07-11
    Description: The flow laws of the actual flows at high Reynolds numbers differ considerably from those of the laminar flows treated in the preceding part. These actual flows show a special characteristic, denoted as turbulence. The character of a turbulent flow is most easily understood the case of the pipe flow. Consider the flow through a straight pipe of circular cross section and with a smooth wall. For laminar flow each fluid particle moves with uniform velocity along a rectilinear path. Because of viscosity, the velocity of the particles near the wall is smaller than that of the particles at the center. i% order to maintain the motion, a pressure decrease is required which, for laminar flow, is proportional to the first power of the mean flow velocity. Actually, however, one ob~erves that, for larger Reynolds numbers, the pressure drop increases almost with the square of the velocity and is very much larger then that given by the Hagen Poiseuille law. One may conclude that the actual flow is very different from that of the Poiseuille flow.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1218
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  • 45
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    In:  CASI
    Publication Date: 2019-07-11
    Description: Contents include the following: Characteristic differential equations - initial and boundary conditions. Integration of the second characteristic differential equations. Direct application of Meyer's characteristic hodograph table for construction of two-dimensional potential flows. Prandtl-Busemann method. Development of the pressure variation for small deflection angles. Numerical table: relation between deflection, pressure, velocity, mach number and mach angle for isentropic changes of state according to Prandtl-Meyer for air (k = 1.405). References.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1243 , Chapter 3,Technische Hochschule Dresden, Archives No. 44/3; Rept-44/3
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  • 46
    Publication Date: 2019-07-11
    Description: Six, 3-inch-chord symmetrical airfoil sections having systematic variations in thickness and thickness location were tested at Mach numbers near flight values for propeller-shank sections. The tests, the results of which are presented in the form of schlieren photographs of the flow past each model and pressure-distribution charts for two of the model, were performed to illustrate the effects of compressibility on the flow past thick symmetrical airfoil sections. Representative flow photographs indicated that at Mach numbers approximately 0.05 above the critical Mach number a speed region was reached in which the flow oscillated rapidly and the separation point and the location of the shock wave were unstable. Fixing the transition on both surfaces of the airfoil was effective in reducing these rapid oscillations. The pressure distributions showed that the section normal-force coefficients for thick airfoils were very erratic at subcritical speeds; at supercritical speeds the section normal-force coefficients for the thick airfoils became more regular. Drag coefficients showed that considerable drag decreases can be expected by decreasing the model thickness ratio.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-RM-L6J17a
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  • 47
    Publication Date: 2019-07-11
    Description: A heat-transfer investigation was conducted with air flowing through an electrically heated silicon carbide tube with a rounded entrance, an inside diameter of 3/4 inch, and an effective heat-transfer length of 12 inches over a range of Reynolds numbers up to 300,000 and a range of average inside-tube-wall temperature up to 2500 R. The highest corresponding local outside-tube-wall temperature was 3010 R. Correlation of the heat-transfer data using the conventional Nueselt relation wherein physical properties of the fluid were evaluated at average bulk temperature resulted in a separation of data with tube-wall-temperature level. A satisfactory correlation of the heat-transfer data was obtained, however, by the use of modified correlation parameters wherein the mass velocity G (or product of average air density and velocity evaluated at bulk temperature P(sub b)V(sub b)) in the Reynolds number was replaced by the product of average air velocity evaluated at the bulk temperature and density evaluated at either the average inside-tube-wall temperature or the average film temperature; in addition, all the physical properties of air were correspondingly evaluated at either the average inside-tube-wall temperature or the average film temperature.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-RM-E9D12-Pt-3 , Rept-1115-Pt-3
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  • 48
    Publication Date: 2019-07-10
    Description: In the lecture series starting today author want to give a survey of a field of aerodynamics which has for a number of years been attracting an ever growing interest. The subject is the theory of flows with friction, and, within that field, particularly the theory of friction layers, or boundary layers. A great many considerations of aerodynamics are based on the ideal fluid, that is the frictionless incompressibility and fluid. By neglect of compressibility and friction the extensive mathematical theory of the ideal fluid, (potential theory) has been made possible. Actual liquids and gases satisfy the condition of incomressibility rather well if the velocities are not extremely high or, more accurately, if they are small in comparison with sonic velocity. For air, for instance, the change in volume due to compressibility amounts to about 1 percent for a velocity of 60 meters per second. The hypothesis of absence of friction is not satisfied by any actual fluid; however, it is true that most technically important fluids, for instance air and water, have a very small friction coefficient and therefore behave in many cases almost like the ideal frictionless fluid. Many flow phenomena, in particular most cases of lift, can be treated satisfactorily, - that is, the calculations are in good agreement with the test results, -under the assumption of frictionless fluid. However, the calculations with frictionless flow show a very serious deficiency; namely, the fact, known as d'Alembert's paradox, that in frictionless flow each body has zero drag whereas in actual flow each body experiences a drag of greater or smaller magnitude. For a long time the theory has been unable to bridge this gap between the theory of frictionless flow and the experimental findings about actual flow. The cause of this fundamental discrepancy is the viscosity which is neglected in the theory of ideal fluid; however, in spite of its extraordinary smallness it is decisive for the course of the flow phenomena.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1217
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  • 49
    Publication Date: 2019-07-12
    Description: Wind-tunnel tests of a full-scale model of the Republic XF-91 airplane having swept-back wings and a vee tail were conducted to determine both the stability and control characteristics of the model longitudinally, laterally, and directionally. Configurations of the model were investigated involving such variables as external fuel tanks, a landing gear, trailing-edge flaps, leading-edge slats, and a range of wing incidences and tail incidences.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-RM-SA9C04
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  • 50
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    In:  CASI
    Publication Date: 2019-11-09
    Description: No abstract available
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-TM-X-69018 , SNA-8-D-027-VOL-4-REV-1 , JSC-E-DAA-TN75258
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  • 51
    Publication Date: 2019-08-15
    Description: The flutter characteristics of several wings with an aspect-ratio of 4.0, a taper ratio of 0.2, and a quarter-chord sweepback of 45 deg. have been investigated analytically for Mach numbers up to 2.0. The calculations were based on the modified-strip-analysis method, the subsonic-kernel-function method, piston theory, and quasi-steady second-order theory. Results of t h e analysis and comparisons with experiment indicated that: (1) Flutter speeds were accurately predicted by the modified strip analysis, although accuracy at t h e highest Mach numbers required the use of nonlinear aerodynamic theory (which accounts for effects of wing thickness) for the calculation of the aerodynamic parameters. (2) An abrupt increase of flutter-speed coefficient with increasing Mach number, observed experimentally in the transonic range, was also indicated by the modified strip analysis. (3) In the low supersonic range for some densities, a discontinuous variation of flutter frequency with Mach number was indicated by the modified strip analysis. An abrupt change of frequency appeared experimentally in the transonic range. (4) Differences in flutter-speed-coefficient levels obtained from tests at low supersonic Mach numbers in two wind tunnels were also predicted by the modified strip analysis and were shown to be caused primarily by differences in mass ratio. (5) Flutter speeds calculated by the subsonic-kernel-function method were in good agreement with experiment and with the results of the modified strip analysis. (6) Flutter speed obtained from piston theory and from quasi-steady second-order theory were higher than experimental values by at least 38 percent.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-TN-D-4230
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  • 52
    Publication Date: 2019-08-16
    Description: Characteristic methods for nonstationary flows have been published only for the special case of the isentropic flow up until the present, althought they are applicable in various places to more difficult questions too. This report derives the characteristic method for the flows which depend only on the position coordinates and time. At the same time the treatment of compression shocks is shown.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1196 , Zentrale fuer Wissenschaftliches Berichtswesen der Luftfahrtforschung des Generalluftzeugmeisters (ZWB); 1744
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  • 53
    facet.materialart.
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    In:  CASI
    Publication Date: 2019-08-16
    Description: The investigation of the flow in a centrifugal pump indicated that the flow patterns in frictional fluid are fundamentally different from those in frictionless fluid. In particular, the dead air space adhering to the section side undoubtedly causes a reduction of the theoretically possible delivery head. The velocity distribution over a parallel circle is also subjected to a noticeable change as a result of the incomplete filling of the passages. The relative velocity on the pressure side of the vane, which for passages completely filled with active flow would differ little from zero even at comparatively lower than normal delivery volume, is increased, so that no rapid reverse flow occurs on the pressure side of the vane even for smaller delivery volume. It was established, further, that the flow ceases to be stationary for very small quantities of water. The inflow to the impeller can be regarded as radial for the operating range an question. The velocity triangles at the exit are subjected to a significant alteration in shape ae a result of the increased peripheral velocity, which may be of particular importance in the determination of the guide vane entrance angle.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1089 , Mitteilungen des Hydraulischen Instituts der Technischen Hochschule; 4; 1-27
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  • 54
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    In:  CASI
    Publication Date: 2019-08-15
    Description: On the basis of certain formulas recently established by L. Prandtl for the turbulent interchange of momentum in stationary flows, various cases of "free turbulence" - that is, of flows without boundary walls - are treated in the present report. Prandtl puts the apparent shearing stress introduced by the turbulent momentum interchange. This present report deals first with the mixing of an air stream of uniform velocity with the adjacent still air, than with the expansion or diffusion of an air jet in the surrounding air space.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1085 , Zeitschrift fuer angewandte Mathematik und Mechanik; 6; 1-12
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  • 55
    Publication Date: 2019-08-15
    Description: As a turbine rotor turns, the blades traverse the wake zones of the nozzle vanes. A periodic fluctuation of the pressure distribution around the circumference of the rotor blade is therefore caused. It was desired to investigate quantitatively this effect. At the same time, the magnitude of the force acting upon one profile of the rotor-blade lattice at various positions of this lattice relative to the nozzle lattice was to be determined.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1173 , Reports of the Lattice Conference: Berichte der Gittertagung; Mar 27, 1944 - Mar 27, 1944; Brunswick,; Germany|Berichte der Gittertagung; 95-100; M325/44g
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  • 56
    Publication Date: 2019-07-12
    Description: The heat losses from the envelope surface of a U.S. Navy K-type airship are evaluated to determine if the use of heat is a feasible means of preventing ice and snow accumulations on lighter-than-air craft during flight and when moored uncovered. Consideration is given to heat losses in clear air (no liquid water present in the atmosphere) and in probable conditions of icing and snow. The results of the analysis indicate that the amount of heat required in flight to raise the surface temperature of the entire envelope to the extent considered adequate for ice protection, based on experience with tests of heavier-than-air craft, is very large. Existing types of heating equipment which could be used to supply this quantity of heat would probably be too bulky and heavy to provide a practical flight installation. The heat requirements to provide protection for the nose and stern regions in assumed mild to moderate icing conditions appear to be within the range of the capacity of current types of heating equipment suitable for flight use. The amount of heat necessary to prevent snow accumulations on the upper surface of the airship envelope when moored uncovered under all conditions appear to be excessive for the heating equipment presently available for flight use, but could possibly be achieved with auxiliary ground heating equipment.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-RM-SA6L20
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  • 57
    Publication Date: 2019-07-13
    Description: Test results are present for cascades of airfoils in retarded flow and increasing pressure as corresponds to the case of the impeller of an axial propeller pump and propeller fan.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1190 , Transactions of the Society of Mechanical Engineers; 3; 13; 334-344
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  • 58
    facet.materialart.
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    In:  CASI
    Publication Date: 2019-07-13
    Description: With water as driving medium and delivered medium in a device similar to a simple jet apparatus, the pressure and velocity fields of the mixing zone were explored with a pitot bar; the ratio of delivered to driving volume ranged between the values 0, 1, 2, and 4. An attempt was also made to analyze the mixing flow mathematically by integration of the equation of motion, with the aid of conventional formulas for the turbulent shearing stress, but this succeeded only approximately for the very simplified case that a driving jet is introduced in an unlimited parallel flow, while the pressure over the whole mixing field is assumed to be constant. In spite of these dissimilar assumptions for the theory and the experiment, the form of the measured and the computed velocity profiles indicates a very high degree of approximation. The pressure rise, which was approximated by Flugel's formulas, disclosed good agreement with the measured values.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1096 , Forschung auf dem Gebiete des Ingenieurwesens; 12; 1; 16-30
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  • 59
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    In:  CASI
    Publication Date: 2019-07-13
    Description: The characteristics introduced by the turbulence in the process of the flame propagation are considered. On the basis of geometrical and dimensional considerations an expression is obtained for the velocity of the flame propagation in a flow of large scale of turbulence.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1110 , Journal of Technical Physics; 13; 10-Sep
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  • 60
    Publication Date: 2019-07-13
    Description: On the basis of photographic pictures the laminar flow at a pipe inlet was measured and compared with other measurements and computational results. The test setup is described in detail, and a series of the pictures obtained for turbulent flow is given.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1109 , Forschung auf dem Gebiete des Ingenieurwesens; 8; Pt 1; 42-47
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  • 61
    Publication Date: 2019-07-13
    Description: The present report deals with the effect of turbulence on the propagation of the flame. Being based upon experiments with laminar as well as turbulent Bunsen flames, both the physico-chemical and the hydro-dynamical aspects of the problem are analyzed. A number of new deductions, interesting from the point of view of engine combustion and other very rapidly changing flame reactions, are made.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NACA-TM-1112 , Zeitschrift fuer Elektrochemie und Angewandte Physikalische Chemiw; 46; 11; 601-626
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  • 62
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    In:  CASI
    Publication Date: 2019-10-02
    Description: Preliminary Apollo 14 (Mission H-3) trajectory data for the July 1970 launch window are presented in this document. A general mission profile is presented, and approximate variations of selected mission parameters are indicated. Note that the information in this document is preliminary and will be updated in the Apollo 14 (Mission H-3) operational trajectory documents.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NASA-TM-X-69432 , MSC-01293 , MSC-IN-69-FM-328 , JSC-E-DAA-TN73749
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  • 63
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    In:  CASI
    Publication Date: 2019-08-27
    Description: NHB 7121.2 is the initial publication of the guidelines for implementation of the Phased Project Planning (PPP) concept prescribed by NPD 7121,1A. These guidelines are applicable to the planning and approval activities which lead to the implementation of major new research and development projects as defined in NPD 7121.1A as well as to major modifications or extensions of approved projects. They should, therefore, be reflected in the Project Approval Documents which serve as the basic documentation for project definition, guidance and control throughout NASA. The purpose of PPP is to provide, through defined phases, an adequate basis for management decisions on the extent to which project activities can be properly undertaken and commitments made. However, these guidelines do not prescribe detailed format and content of plans and other documents and reports used to apply the PPP concept. Similarly, the work content of phases and the information requirements described herein are not checklists. They are included to assist in understanding the intent of the PPP concept and should not be viewed as rigid or inflexible. PPP, as a concept for orderly planning and definition of new major R&D undertakings, must be adapted to the peculiarities of each individual case. However, the flexibility permitted for adaptation should not be considered as a license for major variation which would compromise the objectives that underlie the concept. Cognizant NASA officials are expected to pursue their project planning and definition activities in reasonable conformance with these guidelines and to request only those exceptions or deviations which are clearly necessary and justified. These guidelines will be modified as determined necessary on the basis of experience. Comments or suggestions for changes should be directed to the Office of Organization and Management.
    Keywords: Fluid Mechanics and Thermodynamics
    Type: NHB-7121.2
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  • 64
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 5 (1965), S. 246-253 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Studies of polypropylene oxyluminescence show the luminous intensity to be dependent upon the degre of oxidation. The length of the low intensity level portion of the luninescence curve, or pseudo induction period, was found to be a measure of the useful stabilizer life, and the intensity of this portion indicative of the effectiveness of stabilization. The effect of peroxide decomposers was studied and results indicate that peroxide reactions are major producers of luminescence. Analysis of the accepted modes of polymer oxidation, in view of our luminescence findings, indicate that the rate of luminescence buildup should depend upon ease of R. formation and the luminous intensity should be dependent on peroxy radical concentration. The effect of tertiary-carbon content on luminescence was also investigated, and luminous intensity was found to be dependent upon the amount of polymer branching. Model Compounds having slight structural variations were examined and were found to produce different intensity-time curves during oxidation, which may be attributed to ease of formation of a reactive site and subsequent peroxy radical reactions.
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  • 65
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 5 (1965), S. 263-269 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Sixteen polymers containing thiazole and aromatic rings in the polymer chain were prepared and investigated for the production of fibers and films that would be useful up to about 500°C. None of these polymers was completely satisfactory. Some of the polymers gave tough fibers and films, but they had relatively low melting points (〈300°C). Other polymers did not melt below 500°C, but they did not have good fiber and film forming properties because of their low molecular weights. Fibers and films of one of the polymers (polytetramethylenephenylenethiazole) were prepared, and their physical properties, hydrolytic stabilites under acid and alkaline conditions, and resistence to ultraviolet and gamma radiations were determined.
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  • 66
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper is an account of some studies of the mechanism of degradation of an uncrosslinked polyurethan prepared from poly(propylene oxide) (PPO) and 2,4-tolylene diisocyanate (TDI) at temperatures up to 320°C in a vacuum or inert atmosphere. Fractionation of polymers before and after degradation provides information about the mechanism of degradation since the molecular weight distributions obtained are dependent on the mode and sites of bond scission. A recent publication describes the column elution method of fractionation developed for undergraded and slightly degraded PPG-TDI. PPO-TDI gives essentially most probable molecular weight distributions at an initial intrinsic viscosity [η] of ∼ 0.68 dl/g and also after degradation to [η] ∼ 0.24 dl/g. This invariancy of the distribution strongly suggests a randon scission process. Other types of degradation, e.g., free-radical unzipping initiated at the chain ends, could also give invariant most probable distributions. However, such depolymerizations would be accompanied by much larger extents of volatilization than were observed for these polymers (〈5% volatilization).
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  • 67
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 6 (1966), S. 65-70 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Moisture present in epoxy anhyride composites may hydrolyze the anhydride and cause major changes in the mechanical and chemical properties of the final composite. Heat distortion data and infrared spectroscopy are used to analyze the changes caused by the presence of the moisture. As the concentraton of water is increased, there is a decrease in the heat distortion or gass transition temperature. The decrease is due to a change in the crosslinking network and is caused by the reduction of the functonality of the epoxy group for acid as compared to the anhydride. Where rigid specifications must be met it is essential that the moisture level in the fillers, resins, etc. be kept constant.
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    Polymer Engineering and Science 6 (1966) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 69
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    Polymer Engineering and Science 6 (1966), S. 117-123 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: There is considerable literature on the behavior of polyethylene below 200°C and above 400°C. This paper presents results on both high and low density polyethylene between 2000 and 400°C, a range of practical import for various fabrication and processing steps. Practical exposure times may be short and the experimental procedures were designed to give meaningful results for times as low as 1 min. The principal effects are chain-session and oxidation. Session was isolated by applying an atmosphere of pure nitrogen and proved uite shlow at 300°C but rapid at 400°C. The course of scission and produces discoloration, odor, and rising carbonyl content. A brief discussion is given of the role of diffusion in oxidation.
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    Polymer Engineering and Science 6 (1966), S. 97-112 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The application of silane coupling action produces significant improvements in physical properties in various thermpolastic resin systems. Both glass-reinforced thermoplastics and the more conventional filled thermoplastic resin systems were studied. An order of specificity between resin and coupling agent exists for thermoplastic resins similar to that of thermosets. The interaction with thermosets is considered copolymerization, wereas that with thermoplastics is not yet clearly defined. The silanes are incorporated by pre-treatment (best for glass reinforcement) or by addition during normal compounding. Fillers are added for a specific result, often with sacrifice of physical strength. Data presented show that silane addition upgrades filled thermoplastics to the level of clear resins and sometimes above. The effect of silanes on electrical properties of filled thermoplastics are also reported.
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    Polymer Engineering and Science 6 (1966), S. 127-130 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An optical method has been developed to provide quantitative results useful for characterizing the crazing of transparent plastics. The procedure consists of the detection of discontinuities in a beam of light that scans the specimen in a direction perpendicular to the line of crazing. The light is transmitted to a photomultiplier that is connected with an amplifying system and a recorder that provides a diagram of the light energy modulated by the lines of crazing. The specimen is scanner both before and after subjecting it to a treatment that causes crazing, and the crazing index is considered to be the difference between the area below the two curves.
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    Polymer Engineering and Science 6 (1966), S. 169-172 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Many rigid PVC compounds show a sharp transition from tough to brittle fracture with decreasing temperature in impact testing, and this temperature becomes a criterion of compound quality in addition to the impact strength observed at specific temperatures. This BT (brittle fracture) has been investigated individuall in commercial and experimental elastomer modified rigid PVC compounds. Factors affecting the BT include speciman thickness, composition and processing conditions. Apparently the discontinuity in impact behavior is a sudden manifestation of a gradual change, resulting in a near ten-fold decrease in notched impact strength without any obvious change in properties. The BT provides a continuous scale for comparing impact properties of compounds, and is thus more versatile and sensitive than impact tests run at a single temperature.
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  • 73
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    Polymer Engineering and Science 6 (1966), S. 158-168 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow of polymer melts is normally laminar, but pseudoplastic in character. That is, flow rate increases in proportion to a power higher then 1, usually between 1.5 and 4, of the applied pressure difference. Viscosities are extremely high - more then a mollion times that of water - so considerable heat is generated in the flowing melt by viscous dissipation of flow energy. This mode of heat generation is put to good practial use in the screw extruder, a device that converts plastic pellets into hot melt for shaping into pipe, sheets, coatings and molded products. Equations are given for computing flow rates and viscous dissipation rates. Heating (except by viscous working) and cooling of polymers are slow processes because all these materials are poor heat conducts nad their extreme viscosities make convection impracticable. The princliples of heat transfer are reviewed, and the solutions are given for some transient-conduction problems frequenlty encountered in processing. Equations are given for judging the operation of extruders.
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    Polymer Engineering and Science 6 (1966), S. 182-184 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 75
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    Polymer Engineering and Science 6 (1966), S. 203-212 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Tangential flow of a “power law” model fluid between two concentric cylinders is analyzed. A constant angular pressure gradient is imposed and one of the cylinders is rotating at a constant angular velocity. This type of flow is of interest in screw extrusion theory. The error in the superposition, i.e., linear addition of tangential pressure and drag flows, for a “power law” model fluid, is quantitatively calculated and plotted in the form of a correction factor. Tangential pressure flow is compared to a pressure flow between parallel plates and additional correction factor to account for the curvature is derived and plotted. The applicability of the “power law” model for flow of polymer melts in extruders is also discussed.
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    Polymer Engineering and Science 6 (1966), S. 198-202 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This article describes a general mathematical model summarized in the form of a computer program for the plasticating extruder. The model combines features of the metering-zone model previously published, the melting-zone model described in paper No. I of this series, and a feed-zone model based on an extension of known theories. It is based on theoretical models for each zone unified and improved by non-linear estimation to accurately describe the extrusion experiments.The mathematical model predicts temperature, pressure, and melt channel width profiles of the plastic being processed in the plasticating extruder as a function of design and operating variables of the machine. It enables for the first time the design of the whole machine based on temperature and pressure profiles, including new combinations of cylindrical and tapered roots.
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    Polymer Engineering and Science 6 (1966), S. 213-216 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The development of a fractional crystallization technique for characterization of polypropylenes with respect to stereoregularity is described. It is a simple technique which is attractive for routine analysis and under suitable conditions yields quantitative data with good reproducibility. Separation by fractional crystallization from hot xylene solution is shown to take place according to polymer crystallizability and is relatively independent of molecular weight. It thus represents an alternative and in some ways superior approach to the more commonly used fractional extraction method. Preliminary work indicates that the fractional crystallization method may prove of value in establishing correlations between the stereoregular nature of polypropylenes and their physical properties.
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    Polymer Engineering and Science 6 (1966), S. 244-247 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The density and tensile property changes in polypropylene resulting from various post-crystallization aging procedures are investigated with the aim of (1) establishing standard procedures for the evaluation of these properties and (2) determining which conditioning treatment will provide optimum tensile properties. The morphology and resultant tensile behavior of polypropylene are particularly sensitive to conditioning treatments in the temperature range 145-160°C. A procedure for compression molding plaques, carrying out isothermal annealing treatment in the 100-170°C range and gradual cooling is described. The dependence on annealing temperature of the density, elongation, tensile modulus and yield stress is given.
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    Polymer Engineering and Science 6 (1966), S. 260-262 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Some earlier observations on the influence of molecular weight, plasticizer, and irradiation on the thermal conductivity of polymers is reviewed. Also some new data on polystyrene and some new calculations based on the theory of Hansen and Ho are presented. These data show almost a two fold increase in the thermal conductivity of polystyrene as the molecular weight goes from 900 to 100,000. Data on the moleculer weight effect on thermal conductivity appear to be consistent with the theoretical calculations.
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    Polymer Engineering and Science 6 (1966), S. 273-278 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Thermal oxidation in linear polyethylene is mainly confined to disordered regions in which scission reactions cause crystallization and eventual deterioration of mechanical properties. Gel formation is negligible at 100°C. As degradation proceeds, comparable changes occur in the intrinsic viscosities of melt and solution-crystallized liner polymers, indicating that chain folds are regularly arranged and are resistant to oxidative scission. Breakdown is much more extensive in branched and crosslinked polymers since crosslinking retards oxidative crystallization and branching increases the volume fraction of substrate ultimately accessible to oxygen.
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    Polymer Engineering and Science 6 (1966), S. 295-298 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For a system of equivalent bonds undergoing random bond scission it is reasonable to assume that the rate of bond breaking (hence the rate of creation of new molecules) reported in the literature and data presented here demonstrate that the number of molecules created is not proportional to the time of thermal treatment hence they seem to belie this reasonable hypothesis. Other authors have adduced the presence of some non-equivalent bonds in order to account for the observed cruvature and still retain the hypothesis. Implicit in these arguments is the assumption of a steady-state concentration of reactive fragments. Our analysis explores the consequences of abandoning the steady-state assumption and shows that a quantitative explanation of the observed degradation behavior may be had by this means wihile still retaining the hypothesis of a constant probability of a bond being broken per unit time.
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    Polymer Engineering and Science 6 (1966), S. 248-254 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Most polymers exhibit a very fluid melt rheology during extrusion and can be distorted, drawn down, and cooled without building excessive residual stresses into the product. In contrast, rigid vinyl is usually extruded as a stiff, almost selfsupporting mass. Care must be taken to prevent the formation ot oriented stresses in the product which will be relieved during long periods of exposure resulting in dimensional instability and related loss of physical properties. A newly developed method of in-line annealing has shown to be an effective means of relieving oriented stresses developed during extrusion. By use of this instrumented technique, rigid vinyl products can be controlled to much tighter shrinkage specifications in a single step process, thereby eliminating post-annealing treatments.
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    Polymer Engineering and Science 6 (1966) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer Engineering and Science 6 (1966), S. 282-284 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 6 (1966), S. 299-305 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Residence time distribution (RTD) is a spectral property of contiuous chemical reactors. Batch reactors may be viewed as having “monodisperse” residence time distributions. This article discusses molecular weight distributions (MWDs) of polymeic materials formed in continuous and in semicontinuos process and how they are affected by reaction time distributions. All synthetic high polymers, even those Prepared in batch reaction, possess a MWD which may sometimes, for a given monomer, be altered chemically by a proper choice of catalyst and diluent. An interesting concept suggested by the present work is the prospect of “tailoring” the MWD for a given monomer-catalyst-diluent system physically by selecting appropriate reactor conditions. Hence, althought this work involves analysis the results may provide a guide to synthesis.
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    Polymer Engineering and Science 6 (1966), S. 369-372 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Commercial films, elastomers, and fibers have valuable in-use properties below 300°C. Astronautic requirements, however, may evaentually call for materials that withstand 500 hrs at 300°C or 100 hrs at 500°C while fully retaining their useful properties. The most significant advances in the synthesis and preparation of heat resistant polymer have been made since 1959 with new synthetic methods such as interfacial polymerization, cyclopolymerization, and intramolecular polymer post-cyclopolymerization, and intramolecular olymer post-cyclization reactions. It is the purpose of this paper to discuss the structural relationships among those heat resistant, orgainc polymers that were reported to give strong films and fibers. Those heat resistant polymers, which have not yet been fabricated into films and fibers are not included in this review.
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    Polymer Engineering and Science 7 (1967) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Polymer Engineering and Science 6 (1966), S. 373-376 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Monodisperse and polydisperse polystyrenes of equal weight average molecular weight (Mw) are evaluated for melt flow behavior in an Instron capillary rheometer and for injection molding behavior in a 12 ounce in-line reciprocationg screw injection molding machine. The influence of molecular weight distribution on the shape of the flow curves is deconstrated over a wide range of shear rate and temperature. The influence is also reflected in injection molding behavior as defined by pressure to fill or flash the mold at a given melt temperature. Studies of capillary rheometer data for correlation with injection moling beghavior indicate poor agreement when low shear rate viscosity data are used. Good agrement is foun using high shear rate viscosity data in the range 103 to 104 sec-1 Striking crossover points on melt rheology and injection colding area diagram curvs are found with the monodisperse and polydisperse polystyrenes of the same M These crossovers shift with melt temperature and make possible the determination of a “controlling shear rate” for the injection molding process. This is found to be 3500 sec-1 for short shot and 6200 sec-1 for flash with the ASTM test specimen mold used in this study.
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    Polymer Engineering and Science 7 (1967), S. 24-25 
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    Keywords: Chemistry ; Chemical Engineering
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    Polymer Engineering and Science 7 (1967), S. 45-51 
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    Keywords: Chemistry ; Chemical Engineering
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    Polymer Engineering and Science 7 (1967), S. 58-62 
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    Keywords: Chemistry ; Chemical Engineering
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    Polymer Engineering and Science 7 (1967), S. 253-256 
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    Polymer Engineering and Science 7 (1967), S. 264-268 
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    Polymer Engineering and Science 7 (1967), S. 222-223 
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    Keywords: Chemistry ; Chemical Engineering
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    Polymer Engineering and Science 8 (1968), S. 89-100 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The stress-strain characteristic of polymeric binders and solid propellants are dependent on the crosslink density, molecular weight between crosslinks, molecular weight distribution in the binder formulation, volume fraction of filler, and the interaction between the binder and filler particles. This investigation is directed toward elucidation of solid propellant microscopic response and failure mechanisms through characterization of the constitutive effects of crosslink density, molecular weight distribution and curing agent ratio in the binder formulation, and filler fraction. This was accomplished on the ERLA/PBAA propellant system through investigation of three binder formulations with the same curing agent ratio but different crosslink densities; five binder formulations with different curing agent ratios; and four formulations with up to 69.9% by volume of filler.Uniaxial stress-strain characteristics were determined on each formulation at displacement rates of 0.2 to 20.0 in/min at isothermal test conditions ranging from 75 to -90°F. The failure characteristics of a viscoelastic material represent a curve in the three-dimensional space of stress, strain, and time. The ultimate property data on each formulation are presented as projections of this failure curve on the stress-strain, stress-time, and strain-time planes, respectively. Relationships are developed for the dependence of the stress-time, strain-time, and stress-strain failure envelopes on the volume fraction of bound rubber, crosslink density, molecular weight distribution and curing agent ration in the binder component, and the volume fraction of filler.
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    Polymer Engineering and Science 8 (1968), S. 58-63 
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    Keywords: Chemistry ; Chemical Engineering
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    Polymer Engineering and Science 8 (1968), S. 82-88 
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    Notes: Two independent methods for predicting the deformation of free openings of arbitrary shape in a viscoelastic plate are illustrated.The first method is experimental and is based on the interference of two systems of lines representing the initial and final positions of the material. To demonstrate the moire method, the creep compliance function for polymethylmethacrylate is determined as preliminary information. This function is used as input data in the ensuing theoretical analysis to insure realistic viscoelastic behavior.The second method involves techniques to approximate viscoelastic displacements from known elasticity solutions and known material properties.The methods are applied to two examples: (1) The square hole - to determine the motion of an opening of complicated shape; and (2) an ellipse loaded at 45° - to indicate qualitative agreement with an existing prediction of the motion of cracks in a viscous plate.
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    Polymer Engineering and Science 8 (1968), S. 116-125 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A simple, versatile biconical rehemoter has been developed. This device provides shear creep and creep recovery data for polymer melts over a temperature range of 200-500°F. and a range of applied shear stresses from 2 × 103 to 9 × 105 dynes/cm2.Extensive reheological data have been obtained for two samples each of polyisobutylene and high-density polyethylene. These illustrate the value of the device in obtaining data useful for predicting and understanding the processing properties of polymer melts.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 8 (1968) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
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