ALBERT

Description: Sediments from near the basement of a number of Deep Sea Drilling Project (DSDP) sites, from the Bauer Deep, and from the East Pacific Rise have unusually high transition metal-to-aluminum ratios. Similarities in the chemical, isotopic, and mineralogical compositions of these deposits point to a common origin. All the sediments studied have rare-earth-element (REE) patterns strongly resembling the pattern of sea water, implying either that the REE's were coprecipitated with ferromanganese hydroxyoxides (hydroxyoxides denote a mixture of unspecified hydrated oxides and hydroxides), or that they are incorporated in small concentrations of phosphatic fish debris found in all samples. Oxygen isotopic data indicate that the metalliferous sediments are in isotopic equilibrium with sea water and are composed of varying mixtures of two end-member phases with different oxygen isotopic compositions: an iron-manganese hydroxyoxide and an iron-rich montmorillonite. A low-temperature origin for the sediments is supported by mineralogical analyses by x-ray diffraction which show that goethite, iron-rich montmorillonite, and various manganese hydroxyoxides are the dominant phases present. Sr87/Sr86 ratios for the DSDP sediments are indistinguishable from the Sr87/Sr86 ratio in modern sea water. Since these sediments were formed 30 to 90 m.y. ago, when sea water had a lower Sr87/Sr86 value, the strontium in the poorly crystalline hydroxyoxides must be exchanging with interstitial water in open contact with sea water. In contrast, uranium isotopic data indicate that the metalliferous sediments have formed a closed system for this element. The sulfur isotopic compositions suggest that sea-water sulfur dominates these sediments with little or no contribution of magmatic or bacteriologically reduced sulfur. In contrast, ratios of lead isotopes in the metalliferous deposits resemble values for oceanic tholeiite basalt, but are quite different from ratios found in authigenic marine manganese nodules. Thus, lead in the metalliferous sediments appears to be of magmatic origin. The combined mineralogical, isotopic, and chemical data for these sediments suggest that they formed from hydrothermal solutions generated by the interaction of sea water with newly formed basalt crust at mid-ocean ridges. The crystallization of solid phases took place at low temperatures and was strongly influenced by sea water, which was the source for some of the elements found in the sediments.

Description: Basalt underlying early Campanian chalk at Deep Sea Drilling Project (DSDP) Site 163 is divided into seven extrusive cooling units bounded by glassy margins. The margins have dips of 15° to 70°, suggestive of pillow flows rather than tabular flows. The margins are fresh sideromelane (glass) grading inward to opaque and reddish-brown globules containing microcrystalline material with radial, undulose extinction. Relative to adjacent sideromelane, the reddish-brown globules are enriched in sodium and calcium, whereas the opaque globules are depleted in these elements and enriched in iron and magnesium. It appears that basalt just inside the pillow margins has differentiated in place into globules of two distinct compositions. This globule zone grades inward to less rapidly cooled pyroxene varioles and intergrowths of plagioclase and opaque minerals. In the center of the thicker cooling units, the texture is diabasic. Alteration and calcite vein abundance are greatest at pillow margins and decrease inward; the interior of the thickest cooling unit is only slightly altered, and calcite veins are absent. Chemical analysis of whole rock by atomic absorption spectrophotometry, and of sideromelane by electron microprobe, indicates that the rock is a slightly weathered tholeiite. The atomic absorption analyses, except the one nearest the top of the basalt, are relatively uniform and similar to the sideromelane microprobe analyses, including those near the top of the basalt. This suggests that deep penetration is not necessary to get through the severely altered layer at the basalt surface, and that within this altered layer, analyses of sideromelane may be more representative of crustal composition than analyses of whole rock.

Description: The JOIDES Pacific Advisory Panel proposed Site 37 to meet two principal objectives: to determine the significance of the magnetic anomaly pattern, and the longitudinal profile of the sediment sequence in the eastern Pacific. Site 37 was to be located on the same magnetic anomaly as was Site 33 (#10, 32 million years age), for comparison across the intervening Mendocino Fracture Zone. As basement had not been reached at Site 33, this objective could not be met specifically. However, sediment comparison across the fracture zone was possible.

Description: The nonfossiliferous nature of most of the thin sediment sequence at Site 37 had provided little biostratigraphic information for the northern end of the proposed section of sites along 140°W longitude. In an attempt to provide a biostratigraphically more meaningful hole as the high latitude terminus of the meridional section, an additional site (Site 38) was drilled between the Mendocino and Pioneer Fracture Zones.

Description: DSDP 161 is located on the lower west flank of the East Pacific Rise about midway between the Clipperton and Clarion fracture zones which define the boundaries of a large structural block in the eastern Pacific. The site is about 4,000 km west of the present crest of the Rise. It is located near the northern edge of a zone of thick Cenozoic sediments which marks the general location of the equatorial zone of high biological productivity.

Description: Site 32 was proposed by the Pacific Advisory Panel at a location over a strong positive magnetic anomaly (Number 13 on the Pittman-Heirtzler scale, 38 million years) where samples of the basement and the basal sediment would be of value in testing hypotheses for origin of the linear magnetic anomalies from this part of the Pacific. Comparison of this site, south of the Pioneer Fracture Zone, with later sites north of the Fracture Zone would be the basis for evaluating the discontinuity formed by the Pioneer.

Description: The proposed location of Site 33 was over north-south Magnetic Anomaly 10 (Pittman-Heirtzler, 32 million years) in order (a) to provide a basis for comparison of the age of the basal sediments with the age based on the magnetic anomaly, (b) to provide a basis for evaluation of relative movement along the Pioneer and Mendocino Fracture Zones, and (c) by being paired with Site 34, to provide comparison of basement materials for adjacent positive and negative magnetic anomalies.

Description: For temperature investigations, a core in the Mediterranean Sea (No 189 of the Swedish Deep-Sea Expedition 1947-1948) was sampled at approximately 10 m intervals. Globigerina dubia, G. inflata and Globigerinoides rubra were seperated from each sample and their test were investigated for stable oxygen isotopic measurement. Oxygen isotopic analysis showed the following: 1) Ten stages are indicated. 2) The temperature minimum of stage 2 corresponds to a racliocarbon age of 17,200 years. 3) Temperature maxima of odd stages are about equal to the modern August mean, except that of stage 5 which is considerably higher and, probably reflects the influx of ice melt water. 4) Temperature minima of even stages are all very low, especially that of stage 2, and reflect conditions similar to those now prevailing around Newfoundland. 5) The temperature record indicates that during most of the time covered by the core, the Mediterranean was cooler than at present and that conditions similar to the present occurred only during comparatively short intervals. 6) Minor temperature fluctuations occur, especially in the warmer stages, which are of doubtful significance. 7) An average rate of sedimentation of 4.3 cm/1000 years is indicated for the whole core.

Description: DSDP 159 is one of a series of sites in the eastern equatorial Pacific on the west flank of the East Pacific Rise. It was selected by the Pacific Site Selection Panel on the premise that if hydrothermal processes on the crest of the East Pacific Rise supply the transition metals, a broad zone of such deposits should be present immediately above basement over the entire flank of the Rise.