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  • Articles  (437)
  • Polymer and Materials Science  (437)
  • Inorganic Chemistry
  • 1975-1979  (437)
  • Medicine  (437)
  • Geosciences
  • Biology
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 9 (1975), S. 207-211 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The surface properties of Ag3Sn are important in the amalgamation process so that mechanical abrasion is generally necessary to get a satisfactory amalgam. Therefore, the present study was undertaken to characterize the surface of Ag3Sn after several types of surfaces treatments.Homogeneous polycrystalline rods of Ag3Sn were prepared in vacuo from high purity (99.99%) Ag and Sn. Specimens were sliced from these rods and prepared as follows: (1) mechanically polished, (2) polished as in (1) and allowed to sit in air for three days and (3) polished as in (1) and electrolytically etched. Each of these specimens was examined by Auger electron spectroscopy.The results showed that after mechanical abrasion the surface film was primarily oxide and the Ag to Sn ratio was lower than the bulk composition, indicating preferential oxidation of Sn. After sitting in air sulfur was also present on the surface and the Ag to Sn ratio was greater than that immediately after polishing, indicating the formation of Ag2S. After electrolytic etching some oxide was still present, but only a trace of sulfide was found. However, the Ag to Sn ratio was greater than that for mechanically polished specimens, indicating preferential dissolution of Sn. Therefore, it is seen that the surface preparation of Ag3Sn has a marked effect on Ag and Sn concentrations and the nature of films at the surface.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 9 (1975), S. 255-256 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 9 (1975), S. 265-272 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: A streaming potential experiment was conducted on in vitro bone to determine the effects polyvalent salts have on bone zeta potential. Polyvalent metal salts would be introduced into local physiological electrolytes by corrosion of a metal implant or dissolution of a ceramic implant. It was hypothesized that a change in zeta potential of mineralized tissue, resulting from the introduction of polyvalent salts, could be a cause of tissue instability at the implant interface. Zeta potentials measured in bone were on the order of a few millivolts. Strongly hydrolytic metal cations such as Al+3 and Fe+3 did not have sufficient activity in buffered neutral electrolytes to alter bone zeta potential. Results suggest that less hydrolytic cations of high valence, and large polarizable anions may affect bone zeta potential.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 9 (1975), S. 315-326 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The wettability characteristics of the contact lens material, PHEMA, with respect to water have been determined by using the sessile drop, and the captive air bubble techniques of contact angle goniometry. It is concluded that on PHEMA gels water does not spread spontaneously. Large hysteresis has been observed in the advancing and receding contact angles. This suggests that this hydrogel surface is capable of changing its free energy through reorientation of the polymer side chains and chain segments depending on the nature of the adjacent phase. The water content of the gels does not appear to have an effect on water wettability in the hydration range investigated. The minor wettability differences among the various gels studied were most likely due to differences in surface structure and segmental mobility due to inherent variations in the method of preparation. Small but consistent differences were found between the contact angles measured by the captive bubble method and those obtained by the sessile drop method, the former values being higher. These differences may not be method-related artifacts and cannot be explained at the present time.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 9 (1975), S. 453-463 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Dogs were dialyzed with collagen and cuprophane membranes, human renal failure patients were dialyzed with cuprophane membranes, and samples of the membranes were observed by scanning electron microscopy at different time periods. Fixation was done in glutaraldehyde and cacodylate buffer, and samples were dried at the critical point. All cellular elements were well preserved and appeared viable. Cuprophane adsorbed platelets almost selectively in dog dialyses, whereas collagen adsorbed a smaller number and more heterogeneous group of cells. In contrast to these findings, when cuprophane was used in clinical dialyses, the cell population was predominantly polymorphonuclear leukocytes.
    Additional Material: 7 Ill.
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  • 6
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The concept of surface-active comonomers of higher functionality is propsed as a means of increasing reliability of the bonding between preventive and restorative dental materials and tooth structures.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 9 (1975) 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 10 (1976), S. 371-375 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The weight-loss method was employed to determine the diffusion coeffcients of mercury in Ag2Hg3 alloy at temperatures in the range of 64-120°C. Diffusion coeffcients for nonhomogeneous specimens obey the relationship: \documentclass{article}\pagestyle{empty}\begin{document}$$ D = 2.18 \times 10^{ - 2} \exp \left({\frac{{ - 9.58 \times 10^3 }}{{RT}}} \right)\left({{{{\rm cm}^2 } \mathord{\left/ {\vphantom {{{\rm cm}^2 } {\sec }}} \right. \kern-\nulldelimiterspace} {\sec }}} \right) $$\end{document} Diffusion coeffcients for nonhomogeneous samples were found to be an order of magnitude greater than values found for homogeneous samples.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 10 (1976), S. 445-453 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Various methods of roughening type 316 stainless steel substrate surfaces for flame-spraying alumina (Al2O3) were investigated and tested for the best alumina-to-metal bond strength. Best strength values were obtained by means of roughening via anodic polarization pitting of the stainless steel. Subsequent in vitro testing indicated a severe loss in bond strength following exposure to aerated Ringer's solution. It is suggested that the utilization of flame-sprayed devices has potential in orthopedic prostheses, but precautions must be observed.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 10 (1976), S. iii 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
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