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  • Analytical Chemistry and Spectroscopy  (4,318)
  • Geochemie
  • Geodäsie
  • 1980-1984  (4,321)
  • 1
    facet.materialart.
    Unknown
    Reimer
    In:  Herausgeberexemplar
    Publication Date: 2024-07-02
    Description: Über den paläozoischen Sedimenten im Dakhla-Becken folgen überwiegend fluvio-kontinentale Sedimente des Mesozoikums, die sich aufgrund ihrer gleichartigen Ausbildung innerhalb des Beckens in Ost-West-Erstreckung verfolgen lassen. Die pauschal als "Nubischer Sandstein" bezeichneten klastischen Sedimente konnten in sechs Formationen gegliedert und ihre strati graphische Stellung weitgehend gesichert werden. Die Einheiten der Nubischen Gruppe heißen von unten nach oben: Six Hills Formation (Basal Clastics), Abu Ballas Formation (Lingula Shale), Sabaya Formation (Desert Rose Beds), Maghrabi Formation (Plant Beds), Taref Formation (Taref Sandstein) und Mut Formation (Variegated Shales). Sie sind fast ausschließlich der Kreide bis zum Maastricht zugehörig. Der Sedimentationsraum gehört zu einem sich nach Nordwesten vertiefenden Becken zwischen der Calanscio-Uweinat-Schwelle im Westen und dem Kharga-Upl ift im Osten. Die Sandstein-Formationen bestehen in der Körnerfraktion ausschließlich aus Quarz, Zirkon, Turmalin, Rutil und Leukoxen und zeigen bei den Tonmineralen eine absolute Kaolinitvormacht. Die überwiegend tonigen Formationen, mit unterschiedlichen Tonmineral-Vergesellschaffungen, deuten auf eine Sedimentation in einem flachen Epikontinentalmeer hin. Die Sedimente der Nubischen Gruppe entstammen Gebieten mit lateritischer Verwitterung. Die Resedimentation erfolgte unter gleichen Klimabedingungen, wie synsedimentäre Bodenbildung und Sesquioxid-Krusten zeigen. Die Faktoren-Analyse ergab folgende Elementgruppen: Ti, Nb, Zr und Cr: Elemente, die überwiegend in Schwermineralen auftreten ; Mn, Co, Ni und Cu: adsorptiv an Mn gebunden und in manganreichen Krusten angereichert ; Y, SE; an Tonminerale angelagerte Elemente ; Ca, Sr, Rb und Pb: an Tonminerale gebundene Elemente. Eisen konnte keiner dieser Gruppen zugeordnet werden. Da die fünf Elementgruppen in den Formationen der Nubischen Gruppe charakteristisch verteilt sind, ist eine Unterscheidung der Formationen aufgrund der Elementverteilung möglich.
    Description: The Paleozoic sediments within the Dakhla Basin are overlain by fluvio-continental sediments of Mesozoic age which can be traced in the. basin in east-west extension caused by their similar development. The clastic sediments, generally called "Nubian Sandstone", could be subdivided into six formations and their: stratigraphic position could be more or less assured. The units of the Nubia Group are named from the bottom towards the top as follows: Six Hills Formation (Basal Clastic Unit), Abu Ballas Formation (Lingula Shale Unit), Sabaya Formation (Desert Rose Unit), Maghrabi Formation (Plant Bed Unit), Taref Formation (Taref Sandstone Unit), and Mut Formation (Variegated Shale Unit). Stratigraphically they are nearly exclusively of Cretaceous up to Maastrichtian age. The area of sedimentation is a basin between the Calanscio-Uweinat Uplift in the west and the Kharga Uplift in the east. The bottom of the basin dips towards the northwest. The more sandy units contain as grains exclusively quartz, zircone, turmaline, rutile and leocoxene. The same units show as a clay-mineral an absolute predominance of kaolinite. The chiefly clayey units with a different association of clayminerals point at a sedimentation in a shallow epicontinental sea. The sediments of the Nubia Group are descended from regions with a lateritic weathering. The resedimentation took place under the same climatic conditions as it is shown by syn sedimentary development of soil horizons and sesquioxide crusts. The factor analysis caused the following groups of elements: Ti, Nb, Zr and Cr: elements which occur mainly in heavy minerals ; Mn, Co, Ni and Cu: elements which are bound adsorptively at Mn and are concentrated in crusts with a high content of manganese ; Y and R.E.E.: elements which are attached to clayminerals ; Ca, Sr, Rb and Pb: elements which are bound at clayminerals. Iron could not be associated with one of these groups. As the five groups of elements are distributed characteristically in the units of the Nubia Group, a differentiation of the units is possible based on the dissamination of the elements.
    Description: thesis
    Description: DFG, SUB Göttingen
    Keywords: ddc:551 ; Nubischer Sandstein ; Stratigraphie ; Geochemie ; Sedimentologie
    Language: German
    Type: doc-type:book
    Format: 93
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  • 2
    facet.materialart.
    Unknown
    Berlin: Reimer
    In:  Herausgeberexemplar
    Publication Date: 2024-04-18
    Description: Anatektische Schmelzen haben bei der Entstehung granitischer bis dioritischer Magmen in der Erdkruste eine entscheidende Bedeutung. Die große Tiefe und breite Ausdehnung, in der sich sialische Granitisations-Prozesse vollziehen, bedingen aber auch die Seltenheit ihres Aufschlusses an der Erdoberfläche. An Stelle dieser Übergänge metamorph -〉 magmatisch in situ (ERDMANNSDÖRFFER, 1948) wurden daher stets die wesentlich kleinräumigeren Erscheinungen in Migmatiten untersucht. Man ging dabei von der Voraussetzung aus, daß diese als "Modell Systeme" anzusehen sind (MEHNERT, 1968/71). Die meisten geochemischen Untersuchungen zu diesem Thema berücksichtigten bisher nur die Hauptelemente. Angaben über Spurenelement-Konzentrationen basieren meist nur auf wenigen Einzelanalysen. Als Grundlage der hier vorgelegten Zusammenfassung geochemischer Daten zur Migmatitgenese dienten im wesentlichen die petrologischen Untersuchungen anatektischer Gesteine von MEHNERT und von BÜSCH (Zitate im Text). Diese Basis wurde durch Hinzunahme von neueren Literaturdaten erweitert. Die Analyse einer möglichst großen Anzahl von Einzelproben von Gneisen, Leukosomen und Melanosomen auf Haupt-, Neben- und Spurenelemente und die Berücksichtigung der Auswirkungen der Streuungen erbrachte neue Erkenntnisse…
    Description: thesis
    Description: DFG, SUB Göttingen
    Keywords: ddc:552.4 ; ddc:551.9 ; Geochemie ; Migmatit ; Schwarzwald
    Language: German
    Type: doc-type:book
    Format: 82
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 151-151 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 248-252 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Column loadability - overload phenomenon ; Non-classical approach to theory of loadability ; Effect on retention times, peak shape ; Effect of column length ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The usual concepts of the dynamics of an overloaded solute band fail to explain several phenomena such as the typical “leading-tail” shape and retention deviations exhibited by overloaded peaks, and why these defects are more commonly observed in short columns. These and other related deviations from theory can be rationalized by a non-classical approach to the overloading phenomenon.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 257-260 
    ISSN: 0935-6304
    Keywords: Liquid adsorption chromatography, LSC, LC ; LC with binary mobile phase ; Solute-solvent association ; Solvent-solvent association ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Analytical equations for the capacity ratio in liquid adsorption chromatography with a binary mobile phase, involving solute-solvent and solvent-solvent association in the mobile and surface phases, have been derived. Very simple equations have been obtained for higher values of mole fraction of the more efficient eluting solvent.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 265-265 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 286-290 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary ; Discrimination due to FID ; Effect of carrier gas flow changes on detector sensitivity ; Hydrogen as carrier gas ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The sensitivity of an FID may change when the carrier gas flow rate changes during a chromatographic run. Sample parts which are eluted at reduced FID sensitivity produce a reduced peak area, hence are discriminated as compared to other components. Sensitivity changes were studied for hydrogen as carrier gas. For the detector tested, differences in the carrier gas flow rates of 1 ml/min shifted the FID sensitivity by 1 to 5% (depending on the fuel gas supply). Thus the stability of the sensitivity is no longer ensured as soon as the carrier gas flow rate is changed manually or by an automatic programmer during an analysis. Sensitivity drifts may also occur during temperature programmed runs with a pressure regulated carrier gas supply since the gas flow through the capillary drops with increasing temperature. Such shifts in the response became noticeable as soon as relatively high carrier gas flow rates combined with long range temperature programmes were used. The typical patterns of such discriminations are shown, closing with a discussion on the possibilities for minimizing such undesired effects.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 301-302 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Polychlorinated biphenyls ; Liquid crystal phase ; Choice of stationary phases for analysis ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 305-306 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, micro HPLC ; Temperature effect ; Cooled column ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 337-344 
    ISSN: 0935-6304
    Keywords: Gas Chromatography ; Capillary, glass ; Surface deactivation ; High temperature silylation ; Applications ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper describes the results of a study on the deactivation of the surface of glass capillary columns by high temperature silylation (HTS). The different steps, leaching, washing, dehydration and HTS were optimized. A practical procedure yielding a high percentage of very good columns is given. The influence of leaching and HTS on the temperature stability and coating efficiency of capillary columns coated with OV-1 was studied. The inertness of the glass surface after HTS is demonstrated by several examples.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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