ISSN:
0032-3888
Schlagwort(e):
Chemistry
;
Chemical Engineering
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
,
Physik
Notizen:
The concepts of Linear Elastic Fracture Mechanics (LEFM) are applied to polypropylene, a homopolymer and two copolymers, with a view to characterizing their brittle behavior at slow rates (0.5 cm/min) in terms of a fracture toughness, KIc. The effect of thickness, notch sharpness, and the mode of loading on KIc have been investigated in order to determine the plane strain toughness values, KcI for the materials. The two types of material are compared in terms of their toughness values over a range of temperatures between +30 and -160°C. Evidently, the small amounts of ethylene added to the copolymers show plasticizing effects, suppressing the yield stress and the ductile-brittle transition temperature. In addition, the copolymers exhibit a ductile-brittle region between -100 and -45°C where notch strengthening is apparent in the tension mode and a slow crack growth region between -45 and -30°C where slow growth precedes unstable fracture. The homopolymer, however, shows no clear evidence of such intermediate regions, except for slight amounts of slow growth above 0°C, and becomes ductile around 30°C.
Zusätzliches Material:
9 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pen.760200309
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