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  • Articles  (40)
  • Zinc  (40)
  • 1980-1984  (40)
  • 1945-1949
  • Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition  (40)
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  • Articles  (40)
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  • 1
    ISSN: 1573-5036
    Keywords: Cadmium ; Lead ; Copper ; Zinc ; Yield
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Concentrations of Cd, Pb and Cu in the roots, stems and leaves of bulgarian bush beans (Phaseolus vulgaris L.) were determined for plants grown in various soils of increasing levels of contamination of these metals. Most of each heavy metal absorbed by plants was retained in roots. Concentrations of Cd, Pb and Cu in roots increased in response to soil concentrations, whereas, in stems, only Cd and Pb concentrations increased and Cu concentration was relatively constant. It is thought that Cu transport to the stele was metabolically controlled, whereas Cd and Pb reached the stem by leakage across non suberised areas of the endodermis. Uptake of heavy metals was associated with a decrease in zinc content in plants and a decrease in yield. By regression analysis decrease in both zinc content and plant yield could be best related to Cd content in stems. Possible reasons for these effects are discussed.
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  • 2
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    Plant and soil 81 (1984), S. 145-149 
    ISSN: 1573-5036
    Keywords: Calcium phosphate ; Copper ; Coprecipitation ; Iron phosphate ; Solution cultures ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Coprecipitation of Cu and Zn in insoluble phosphates of Fe and Ca from a modified Long Ashton nutrient solution was found to be highly pH dependent. In one experiment, more than 95% and 75% of the Cu and Zn respectively were removed from solution after two days at pH 6.5 while at pH 5.0 less than 30% and 20% respectively were removed. Significant desorption of both metals took place within one day after acidification.
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  • 3
    ISSN: 1573-5036
    Keywords: Absorption ; Aluminium ; Boron ; Copper ; Factorial design ; Iron ; Manganese ; Nutrient solutions ; pH ; Phosphorus uptake ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The sorption of phosphorus from nutrient solution and the pH change in the nutrient solution were monitored over a 24 hour period forTrifolium repens L. cv. ‘Grasslands Huia’ plants. Two different concentration levels of micro-nutrients (B, Cu, Fe, Mn and Zn) and Al formed the factors of a fractional replicate of a 26 factorial design. Measurements were made at four time intervals (30 minutes after the plants were placed on the pots, 3 hours, 6 hours and 24 hours later). In addition to phosphorus, fourteen other nutrients (including nitrate and ammonium) were monitored throughout the experiment. The sorption of phosphorus was significantly influenced by both aluminium and iron. The effect of aluminium and iron on phosphorus sorption is attributed to physico-chemical sorption processes involving the root surface. However the effect on the removal of phosphorus by boron, copper, manganese and zinc was observed only as first order interaction effects —B−Zn, Cu−Zn, Mn−Zn. Thus these three elements (B, Cu and Mn) only affect phosphorus removal in conjunction with zinc. Aluminium and iron together had a separate but very significant effect on the removal of phosphorus at most periods throughout the experiment. In contrast, pH was affected only by aluminium, iron (the pH drop was enhanced) and manganese (the pH drop was decreased) as main effects independent of the other treatment elements.
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  • 4
    ISSN: 1573-5036
    Keywords: Bioavailability ; Sewage sludge ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary In order to appraise the relation between the physico-chemical forms of Zn and its availability to plants or water, we introduced various forms of this element in experimental systems according to whether it was associated with soil, mineral fertilizers or sewage sludges. These sludges were rich in organic matter and carbonates and one of them contained iron and aluminium oxides and hydroxides. The physico-chemical forms of Zn in soils and sludges were determined following a selective extraction procedure which showed that only a small amount of this metal was associated with the easily available phase. In accordance with these results, the exportsvia vegetables and leached waters were very low, regardless of the treatment.
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  • 5
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    Plant and soil 82 (1984), S. 3-14 
    ISSN: 1573-5036
    Keywords: Concentration ; Growth ; Rice ; Salt-sensitive ; Salt tolerant ; Yield ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary To study the effect of salinity and Zn levels on growth, yield, and nutrient composition of rice (Oryza sativa L.), an experiment was conducted at IRRI with three levels of salinity (ECe 2.5, 5.6, and 8.7) and three levels of Zn (0, 10, and 20 mg Zn/kg soil), and two rices (salt-tolerant experimental line IR10198-66-2 and salt-sensitive variety IR28). Salinity decreased plant height; yield-contributing characters; and shoot, straw, and grain yields in IR28. In contrast, salinity up to ECe 5.6 did not affect these plant parameters in experimental line IR10198-66-2 but at ECe 8.7, it decreased the panicle weight and shoot, straw, and grain yields. The application of Zn at rates as high as 10 mg/kg soil increased the height and improved the yield-contributing characters and the shoot, straw, and grain yields in IR28; it has no effect in IR10198-66-2. In general, the shoot, straw, and grain yields were higher in IR10198-66-2 than in IR28. Salinity increased the concentrations of N, Na, Mg, and Cu and decreased the concentration of K in shoot and straw of IR28. However, in IR10198-66-2, salinity did not affect the concentrations of K, Na, and Mn, but at its highest level (ECe 8.7) increased those of N and Cu. In grains, salinity increased the concentrations of Na, Fe, and Zn; decreased those of P and Mn; and did not affect those of N, K, Ca, Mg, and Cu in both varieties. The application of Zn at rates up to 10 mg Zn/kg soil reduced the concentration of Na and increased that of K in IR28 but had no effect on the concentration of Na and K in IR10198-66-2. In both varieties, Zn application reduced the concentrations of P, Ca, Mg, and Fe and increased those of Zn and Mn. IR10198-66-2 had lower concentrations of Na, Ca, Mn, Fe, Zn, and Cu and higher concentrations of K and Mg than IR28.
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  • 6
    ISSN: 1573-5036
    Keywords: Availability ; Corn ; Extractability ; Heavy application ; Immobilization ; Phosphorus ; Plant parts ; Translocation ; Uptake ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The influence of heavy applications of P (100, 200 and 400 ppm P) and Zn (12.5 and 25 ppm) fertilizers on their extractabilities, availabilities and uptake by corn grown in highly calcareous soil was investigated. A significant increase was found in the levels of (NH4)2CO3-EDTA-extractable Zn either by Zn-applications alone or together with P. The amounts of NaHCO3-extractable P were also increased with P additions and the influence of Zn applications was not clear. Phosphorus application generally increased the plant dry weight. In the soils treated with P and Zn fertilizers, that increase was mostly related to P rather to Zn. In the soils not treated with Zn, P additions increased Zn uptake by the plants. On the other side, in the soils treated with Zn, P additions decreased Zn uptake. Phosphorus concentration in the whole plant and/or in the different plant parts was increased by P application without being significantly affected by Zn addition. The plants showed greater response to 12.5 ppm Zn application than to 25 ppm. Plants grown for 4 weeks contained lower amounts of Zn relative to those grown for 8 weeks. The influence of plant age on P content was not as clear as occurred with Zn.
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  • 7
    ISSN: 1573-5036
    Keywords: Acid soil ; Complexed metals ; Copper ; Iron oxides ; Lime ; Manganese oxides ; Organic matter ; Redistribution ; Trace metals ; Waterlogging ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The redistribution of zinc and copper in a soil as a result of waterlogging has been studied using selective extractants to remove metals held by specific mechanisms. Waterlogging over a period of 16 weeks resulted in a lowering of soluble, exchangeable and organically bound zinc and copper. There is a concomitant increase in the levels of these metals held by specific adsorption (acetic acid extractable) and by poorly ordered oxides (oxalate extractable). It is suggested that the breakdown of these oxides of iron and manganese, which is brought about by waterlogging, provides surfaces with high adsorptive capacity for zinc and copper. Addition of 1% dried grass or 1% lime to the soil caused an acceleration in metal redistribution. Some of the copper released was retained in the standing water, presumably as a soluble chelate. This was not the case with zinc.
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  • 8
    ISSN: 1573-5036
    Keywords: Dry-matter production ; Potassium ; Potato ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Field experiment was conducted during 1980–81 on the Indo-Gangetic alluvial soil of Pura, Kanpur to study the effects of added potassium and zinc on dry-matter production and uptake of these nutrients by potato crop. Increasing supply of potassium and zinc significantly increased the dry-matter production and concentration and uptake of respective nutrients in different crop components. The effects of combined application of potassium and zinc was positive in influencing the dry-matter production and K, Zn uptake by potato crop. Increasing supply of potassium showed beneficial effect on the absorption and translocation of zinc in plant system indicating thereby greater utilization of fertilizer zinc by the crop. Increasing supply of zinc, however, could not influence the concentration of potassium.
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  • 9
    ISSN: 1573-5036
    Keywords: Farmyard manure ; Gypsum ; Iron ; Manganese ; Phosphorus ; Rice ; Rice husk ; Sodic soil ; Submergence ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Effect of amendments, gypsum (12.5 tonnes/ha), farmyard manure (30 tonnes/ha), rice husk (30 tonnes/ha) and also no amendment (control) on the availability of native Fe, Mn and P and applied Zn in a highly sodic soil during the growth period of rice crop under submerged conditions was studied in a field experiment. Soil samples were collected at 0, 30, 60 and 90 days of crop growth. Results showed that extractable Fe (1N NH4OAC pH 3) and Mn (1N NH4OAC pH 7) increased with submergence upto 60 days of crop growth but thereafter remained either constant or declined slightly. Application of farmyard manure and rice husk resulted in marked improvement of these elements over gypsum and control. Increases in extractable Mn (water soluble plus exchangeable) as a result of submergence and crop growth under different amendments were accompanied by corresponding decreases in easily reducible Mn content of the soil. Application of 40 kg zinc sulphate per hectare to rice crop could substantially raise the available Zn status (DTPA extractable) of the soil in gypsum and farmyard manure treated plots while the increase was only marginal in rice husk and control plots indicating greater fixation of applied Zn. Available P (0.5M NaHCO3 pH 8.5) behaved quite differently and decreased in the following order with crop growth: gypsum〉rice husk〉farmyard manure〉control.
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  • 10
    ISSN: 1573-5036
    Keywords: Copper ; Manganese ; Molybdenum ; Phosphorus ; Rice ; Waterlogging ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Laboratory incubation experiments were conducted with low-land rice soil to study the effect of applying three different levels of molybdenum (0, 2.5 and 5.0 ppm) and phosphorus (0, 100 and 200 ppm), in all possible combinations, on the changes in available Mo, P, Mn, Zn and Cu in soil. The results showed that application of Mo at both the levels increased the content of extractable Mo and P but decreased those of Cu and Mo in soil whereas application of Mo at higher level only increased the content of extractable Zn in soil. Application of P at both the levels decreased the content of extractable Mo, Mn and Cu but increased that of P whereas it showed an inconsistent effect on the extractable Zn content in soil. The P × Mo interaction effect was found to be beneficial for the content of P, Mo and Zn only. During the initial period of incubation all elements except Cu recorded an increase but with the progress of incubation period the content of all the elements except Mn gradually declined.
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  • 11
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    Plant and soil 69 (1982), S. 131-134 
    ISSN: 1573-5036
    Keywords: Alluvial soil ; Copper ; Interaction ; Iron ; Manganese ; Moisture ; Phosphorus ; Rice ; Waterlogging ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Laboratory incubation experiments were conducted with three clay loam lowland rice soils (Haplustalf) to study the effect of application of three different levels of Cu(0, 1.25, 2.5 ppm) and Mn (0, 10, 20 ppm) in all possible combinations on the changes in the DTPA extractable Zn, Cu, F, Mn and Brays 2 extractable P in soil. The results showed that application of Cu decreased the content of extractable Zn, Fe, Mn and P in soils, the rate of decrease gradually declining with the progress of incubation period. Application of Mn also depressed the content of extractable Cu, Fe and P but increased that of extractable Zn.
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  • 12
    ISSN: 1573-5036
    Keywords: Boron ; Calcium ; Copper ; Genotypic differences ; Iron ; Magnesium ; Manganese ; Mineral nutrition ; Molybdenum ; Nitrogen ; Phosphorus ; Plant adaptation ; Plant breeding ; Potassium ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Plant genotypes differ in their uptake, translocation, accumulation, and use of mineral elements. Examples of genotype differences to iron, nitrogen, phosphorus, potassium, calcium, magnesium, manganese, boron, copper, zinc, and molybdenum are discussed. Current knowledge is sufficient to indicate that many crop plants can be improved for the efficient use of mineral elements and better adaptation to mineral stress conditions.
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  • 13
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    Plant and soil 72 (1983), S. 77-83 
    ISSN: 1573-5036
    Keywords: Copper ; Gezira soils ; Iron ; Micronutrient availability ; Microbial activity ; Manganese ; Oxidation ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The three major soil series comprising the Gezira scheme (Sudan) are Hosh, Suleimi, and Laota. Surface soil samples from each soil series were employed to study the effect of soil moisture on the DTPA-extractable micronutrient cation under aerobic conditions. The study continued for 8 weeks using an incubation technique at two levels of soil moisture (continuously moist and moist/dry cycles). The DTPA-extractable Cu, Fe, Mn and Zn from air-dry soil samples were much higher compared to values from their incubated counterparts. For the three soils the CO2 production (microbial activity) reached the maximum in 5 weeks and then levelled off while the lowest values of micronutrient cation from the incubated soils were obtained between 2 to 8 weeks. Generally, the study suggests that the hot dry months preceding crop growth should increase clay surface acidity and hence availability of mironutrient cations.
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  • 14
    ISSN: 1573-5036
    Keywords: Cadmium ; Copper ; Heavy metals ; Lead ; Pollution ; Soil solution ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Of 20 Dutch soils, concentrations in the soil solution and total contents of Zn, Cd, Pb and Cu were determined. In addition, distribution constants were measured for Cd and Pb. Soil solution concentrations of the heavy metals as well as their total contents in the soil and exchangeable fraction, calculated with the distribution coefficients, were compared with uptake in vegetables grown in pots. Log-log plots of concentrations in the plant and the soil solution concentrations showed the best correlation for Cu, Cd and Zn. Increasing Zn appeared to increase Cd uptake at high solution concentrations of Cd and to decrease uptake at low solution concentrations. For Pb generally no significant relationship between plant uptake and soil solution concentration or any other soil parameter for Pb could be found.
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  • 15
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    Plant and soil 74 (1983), S. 137-140 
    ISSN: 1573-5036
    Keywords: Copper ; Forest soils ; Greece ; Manganese ; Total concentrations ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Total concentrations of Mn, Zn and Cu were determined in soil samples from 144 profiles located in remote forested areas throughout the mainland of Greece. Bio-accumulation of Mn and Zn in the humic horizon took place only in moderately acid soils (pH 5–6). Mean concentrations of Mn, Zn and Cu, in the mineral section of the soil profiles, were 1383, 93, and 51 ppm, respectively. Soils from hard limestone and basic and ultrabasic igneous rock contain these three minor elements at significantly higher concentrations compared to soils from the rest of the soil parent materials. In most of the soil profiles concentration of Cu increased, and of Mn decreased, with soil depth. Concentrations of Mn, Zn and Cu in the underlaying “rocks” were within the range of their average concentrations found in the mineral soil, except for hard limestone where much lower concentrations of these elements have been found. The latter supports the theory that the parent material of soils associated with limestones might not be a solution product of the limestone rock.
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  • 16
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    Plant and soil 66 (1982), S. 91-99 
    ISSN: 1573-5036
    Keywords: Apple orchards ; Native zinc ; Selective distribution coefficient ; Soil profiles ; Zinc ; Zinc extractants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Labile pool, selective distribution coefficient and adsorption maxima of zinc were measured. Labile pool decreased while selective distribution coefficient increased with increasing depth in all soil profiles. The values of adsorption maxima of zinc corresponded to selective distribution coefficient. The relative efficiency of four extractantsviz 0.05M CA(NO3)2 0.1M Mg(NO3)2; 0.01M EDTA−NH4OAc and 0.005M DTPA-triethanolamine mixture in predicting the availability of native soil zinc to apple was tested. The correlation study indicated that all extractants are good index of zinc availability to apple trees. DTPA-extractable zinc is as efficient as its labile pool(E-value) in predicting the availability of native soil zinc to apple trees. This study also suggested that soil profile should be sampled upto a depth of 30–60 cm for providing a better prediction of availability of native soil zinc to apple trees.
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  • 17
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    Plant and soil 66 (1982), S. 423-427 
    ISSN: 1573-5036
    Keywords: Cobalt ; Copper ; Iron ; Manganese ; Plant uptake ; Trace metals ; Waterlogging ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The uptake of trace metals by two plant species (French bean and maize) has been measured on two soils subjected to various waterlogging regimes. Uptake of both manganese and iron was increased due to soil waterlogging, although reoxidation of the soil affected iron more than manganese. Zinc and copper uptake was influenced by a species factor; French bean (Phaseolus vulgaris) showed preferential uptake of zinc, whereas maize (Zea mays) took up copper preferentially. Uptake of cobalt by both species was increased due to waterlogging, following the pattern of manganese. The abilities of these species to take up trace metals from soil followed the pattern predicted by selective extraction of soil for manganese, iron and cobalt, but not for zinc and copper.
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  • 18
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    Plant and soil 69 (1982), S. 85-95 
    ISSN: 1573-5036
    Keywords: Apple ; Bentonite ; Clay ; Malus spp. ; Micronutrients ; Slow release ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The feasibility of zinc supply to apples (Malus spp. var. Golden Delicious) by various Zn-bentonite preparations implanted in the trunk was studied. A preliminary experiment included four preparations and was conducted in one plantation in 1980. A larger scale experiment in 1981, tested Zn-bentonite (ZnB) and Zn-bentonite + ZnEDTA (ZnBEA) in four plantations in the south, center and north of Israel. Clay tablets were implanted in holes drilled in the tree trunk in April. The youngest, fully developed leaves on the new growth were sampled periodically and Zn content was determined. ZnB and ZnBEA implanted at the rate of 15 mg Zn/cm trunk circumference significantly increased Zn content above that of the control trees until mid-September. The ZnBEA preparation supported significantly higher leaf concentrations than the ZnB preparation. Peak concentrations in trees treated with the ZnBEA preparation were 75.8, 47.4, 38.4, and 23.7 ppm in the four plantations and occurred in May. The Zn concentration in the youngest leaves decreased during the season but there was evidence that in some cases Zn behaved as a phloem mobile element. Soil, climate and previous zinc treatments affected considerably the Zn concentration found in leaves in the four plantations making it impossible to identify a single critical concentration level. No damage to the trees was observed as a result of the drilling and implantation of the clay tablets. Clay analysis at the end of the season showed that about two-thirds of the Zn added to the trees was used. The amount of Zn supplied per tree in the implantation procedure was 80–90% lower than that supplied in the routine spraying operations.
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  • 19
    ISSN: 1573-5036
    Keywords: Availability ; Copper ; Extractability ; Sewage sludge ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Dried digested sewage sludge (cake) was mixed, in varied proportions, with three contrasting soils and cropped intermittently to ryegrass or young barley over a period of 710 days. Results are presented for periods 1–4, 13–16 and 22–23 months after the sludge and soil were mixed. At any given time the quantities of Cu or Zn that wereextractable (by EDTA or acetic acid) from a given soil showed a simple relationship to the ‘total’ quantities of Cu and Zn present. Theavailability of these elements to test crops also showed a simple relationship to their ‘total’ quantities. As a result the quantities available or extractable at any given time appeared to be related to each other also. However, though the extractabilities of Cu and Zn changed with time in some cases, and the availabilities of Cu and Zn changed with time in some cases, the changes were not matched. Increased extractability did not necessarily lead to increased uptake, and in some cases uptake increased even when extractability did not. It should not be assumed too readily therefore that because, at a given time after a soil is sludged, the quantities of added Cu and Zn that are extractable or available are sometimes correlated, the former actually measures the latter.There is no reason to assume that extractants remove all or only the forms of combination of Cu or Zn that may be taken up by crops.
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  • 20
    ISSN: 1573-5036
    Keywords: Copper ; Copper complex ; Corn ; Heavy metals ; Nutrient solutions ; Tetraethylenepentamine ; Tetren ; Zea mays L ; Zinc ; Zinc complex
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Complex formation of copper with tetraethylenepentamine (tetren) has some pronounced effects on the rate of uptake of the metal in corn, grown on nutrient solutions. At normal copper levels (0.02 ppm) in the medium, complex formation leads to a nearly hundredfold decrease in the rate of uptake, growth rate being slightly improved. Similar effects are observed at high copper levels (0.05 and 1 ppm) in which case the growth rate, severely affected in the absence of tetren, can be restored to normal values. High excess of tetren in the medium leads to copper-deficiency. Evidence is presented that the metal is taken up and translocated to the shoot as a metal complex and that its rate of translocation through the xylem is higher than for the aqueous ion. The effects in the case of zinc are similar although somewhat less marked.
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  • 21
    ISSN: 1573-5036
    Keywords: Cadmium ; Cation exchange ; Copper ; Heavy metals ; Illite clay ; Nickel ; Organic matter ; Tetraethylenepentamine ; Tetren ; Transition metal complexes ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The ion exchange behavior of heavy metals (Cu, Zn, Ni, Cd) in soils is shown to be strongly influenced by complex formation with tetraethylenepentamine (tetren). In a heavy clay (illite) soil, the metal (complex) concentration in the equilibrium solution is lowered by some two orders of magnitude, as compared to the aqueous metal ions. In a sandy loam, in which the exchange properties are nearly exclusively due to organic matter, the addition of tetren leads to a significant increase of the metal (complex) in solution. These effects are interpreted in terms of the high adsorption selectivity of the metal complexes for clay particles (illite clay) and the competition of tetren with the chelating groups of the humic fraction (sandy loam). In this case the resulting tetren complexes remain in solution and can be immobilized by addition of small amounts of clay to such a soil.
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  • 22
    ISSN: 1573-5036
    Keywords: Ammonification ; Eh ; Flooded soils ; Iron ; Manganese ; Nitrate reduction ; Phosphorus ; pH ; Salinity and extractable cations ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The electro-chemical and chemical kinetics of six California rice soils were significantly influenced by the presence of salts up to an EC of 9 mmhos/cm in saturation extract (ECe). Subsamples of each soil salinity treatment were incubated for periods up to 10 weeks after flooding. Most of the changes in Eh and pH values took place in the first 3–4 weeks after submergence. Salinity decreased pH values, but slightly increased the redox-potential. Both ammonification and nitrate reduction were significantly decreased, by increasing soil salinity. Salinity up to 9 mmhos/cm did not affect levels of Bray and Kurtz extractable P, but increased the water extractable Ca, Mg, K and Mn. In DTPA extract, salinity in incubated soils had no effect on Zn in 4 soils, but it decreased Fe in acid and neutral soils. Possible explanations for the electro-chemical and chemical kinetic changes due to flooding and salinity are discussed.
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  • 23
    ISSN: 1573-5036
    Keywords: Cadmium ; Chemical activity ; Copper ; Inorganic salt ; Nickel ; Plant uptake ; Sludgeborne ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary A greenhouse experiment was conducted in order to evaluate the chemical activity and the uptake by Italian ryegrass (Lolium perenne cv. S24) of Zn, Cu, Cd and Ni added to a sandy and a heavy clay soil in two different forms: as inorganic salts and sludge-borne. The chemical activity of heavy metals as evaluated with different extractants was higher for the inorganic salt treatment and for the sandy soil, indicating that the chemical form of the metal and soil characteristics largely affect their extractability. The different chemical activity was also reflected in plant uptake. For all metals the degree of plant accumulation decreased in the following order: sandy soil-salt ≫ sandy soil-sludge〉 clay soil-salt〉clay soil-sludge. These findings indicate that caution must be used when using results of inorganic salt treatments and different soil types to evaluate plant uptake of heavy metals from sludge amended soils.
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  • 24
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    Plant and soil 79 (1984), S. 101-121 
    ISSN: 1573-5036
    Keywords: Base saturation ; Bio-climatic zones ; Calcium ; Clay accumulation ; Copper ; C:N ratio ; EDTA ; Forest soils ; Greece ; Iron ; Magnesium ; Manganese ; Nitrogen ; Phosphate ; Potassium ; Soil classification ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Soils derived from a number of different parent materials (lithologies) and developed along a climatic gradient, manifested by the altitudinal succession of natural vegetation zones (Mediterranean, sub-Mediterranean, Mountainous and Pseudoalpine), were sampled throughout mainland Greece. In soils derived from siliceous parent materials low in clay, acidity increase and percent base saturation decreases from the Mediterranean to the Pseudoalpine vegetation zones. Clay illuviation is found mainly in soils developed in the Mediterranean and the sub-Mediterranean zones. No such changes are apparent in clayey soils rich in bases. Organic matter content of the mineral portion of the soil profile increases by a factor of 2 with a decrease in mean annual air temperature of about 10°C. The pattern of change in clay and soil organic matter content with climate is in relatively good agreement with soil development trends in the area, when soil profiles are named according to the FAO-Unesco soil map of the world. Concentrations of Ca and Mg decrease and those of total N, total and extractable P, K, Fe, Mn and Zn increase from the Mediterranean to the Mountainous zone. Within the same zone, however, concentrations of N, Ca, K, Fe, Mn and Zn decrease, but those of Mg, total and extractable P increase with soil depth. The concentrations of most macro- and micronutrients in the humic horizon are several times higher than those in the mineral portion of the soil profile due to biological enrichment.
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    Plant and soil 55 (1980), S. 139-144 
    ISSN: 1573-5036
    Keywords: Iron ; Manganese ; Nickel toxicity ; Rye grass ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Rye grass (Lolium perenne, cv.S-23) was grown for 4 weeks in a non-calcareous Seaton loam soil with varying amounts of Ni as NiSO4. The purpose of this investigation was to study the Ni toxicity and the relationship of Ni with other essential elements. Nickel depressed shoot yield at all levels except at the lowest levelviz 30 μg Ni/g soil. Nickel concentration of 50 μg/g in shoots did not reduce the dry matter production in rye grass although slight chlorosis did appear at this level. The Ni and Fe concentration of the shoots increased and that of Mn and Zn decreased with increasing rates of Ni application. Uptake of Mn and Zn decreased at all level of Ni. But Fe uptake showed a slight increase at the first two levels and a profound depression at the subsequent levels. The pattern of Ni uptake is different, being highest at the middle level and decreasing on both sides which showed that the increase of Ni concentration of shoots is not proportional to the reduction in the yield. The Ni−Fe ratio rather than Ni and Fe concentration in plants has shown better relationship with the toxic effects of Ni. The implications of Ni phytotoxicity are discussed with particular reference to serpentine soils.
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  • 26
    ISSN: 1573-5036
    Keywords: Activation products ; Antimony ; Black soils ; Cerium ; Cesium ; Cobalt ; Concentration ratio ; Fission products ; Flooding ; Iron ; Laterites ; Manganese ; Rice ; Ruthenium ; Uptake ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The absorption of gamma-emitting fission products106Ru,125Sb,137Cs and144Ce and activation products59Fe,58Co.54Mn and65Zn by rice plants grown on two contrasting tropical soils, namely, a blak soil (pellustert) and a laterite (oxisol), and the effects of flooding were studied under controlled conditions. Results indicated greater uptake of106Ru and125Sb from the black soil than from the laterite. In contrast, the uptake of144Ce and137Cs was greater in the laterite than in the black soil. Flooding treatment enhanced the uptake of all these fission products by rice plants in the laterite soil whereas this effect was observed only for125Sb and137Cs in the black soil. The plant uptake of activation products from the two soil types showed maximum accumulation of65Zn followed by54Mn,59Fe and58Co in both soil types. Besides, uptake of these nuclides was greater from the laterite soil than from the black soil. Flooding treatment for rice while showing a reduction of59Fe uptake, showed an increase in plant uptake of58Co,54Mn and65Zn in both soil types.
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  • 27
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    Plant and soil 62 (1981), S. 183-192 
    ISSN: 1573-5036
    Keywords: Liming ; Nitrogen ; Rice ; Submerged rice ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The effect of N and Zn on the yield of submerged rice and uptake of N and Zn was studied on limed and unlimed soils in greenhouse. Nitrogen was applied at the rate of 0,80 and 160 ppm through urea, ammonium sulphate and ammonium nitrate, Zn at 0 and 10 ppm in limed (4% CaCO3) and unlimed soils. Liming (4% CaCO3) decreased dry matter yield of rice at tillering, heading and straw and grain at maturity significantly against unlimed treatments. Ammonium sulphate gave highest yield with all applied doses followed by ammonium nitrate and urea. Zinc at 10 ppm increased dry matter and grain yield significantly over no Zn treatment in rice. The N sources gave N concentration and uptake in rice plants in decreasing order: $$Ammonium sulphate 〉 Ammonium nitrate 〉 Urea.$$ The highest N concentration was recorded with 160 ppm followed by 80 ppm N through any source and lowest in control. The application of Zn increased and liming decreased N concentration and uptake by rice at all sampling stages. Highest N concentration (2.37 to 3.92%) was observed at tillering followed at heading (0.48 to 1.05%). At maturity N in grain ranged from 0.69 to 1.13% whereas in straw from 0.24 to 0.41%. There were positive significant interactions of N(S) x N(L), N(S) and N(L) x Zn and negative interaction with lime on yield, N concentration (%) and N uptake (mg/pot). The application of N sources and levels and Zn increased Zn uptake (μg/pot), and liming decreased it. But 160 ppm N through any source decreased straw Zn concentration over 80 ppm N in absence of added Zn, however, effects on grain were not so strong particularly that of 160 ppm, when 10 ppm Zn was also added even 160 ppm N increased Zn concentration over 80 ppm significantly in both straw and grain. In this case the effect of N sources on Zn concentration was in the order: $$Ammonium sulphate 〉 Urea 〉 Ammonium nitrate.$$
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  • 28
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    Plant and soil 62 (1981), S. 305-308 
    ISSN: 1573-5036
    Keywords: Liming ; Nitrogen ; Phosphorus ; Rice ; Tryptophan ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The effects of Zn, P, N and CaCO3 on tryptophan concentration in rice grain were studied in greenhouse at Haryana Agricultural University. Zinc application upto 20 ppm increased tryptophan concentration in rice grain. Zn-EDTA gave highest increase followed by ZnSO4 and then ZnO. Liming at the rate of 4 and 8 per cent decreased tryptophan concentration significantly. Phosphorus application upto 100 ppm also decreased tryptophan significantly but Zn in combination with P increased tryptophan and overcame negative effect of P. Nitrogen application upto 120 ppm increased tryptophan concentration. There was positive interaction between Zn and N. Ammonium sulphate gave highest tryptophan followed by ammonium nitrate and then urea. The tryptophan concentration ranged between 766 ppm and 2011 ppm in paddy grain. The lowest tryptophan concentration was in the plants treated with 8 per cent lime in absence of added Zn and highest with 10 ppm Zn through Zn-EDTA.
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  • 29
    ISSN: 1573-5036
    Keywords: Boron ; Copper ; Iron ; Manganese ; Zinc ; Microelements ; Sunflower
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Boron, copper, iron, manganese and zinc concentrations were measured in sunflower leaves from plants grown hydroponically in a closed continuous flow system and with boron concentrations ranging from deficient to toxic. Leaves were analyzed at the stage of flower development. There was a highly significant inverse correlation between B concentration in solution and Mn concentration in leaves. Cu, Fe and Zn concentrations in the leaves were not changed by the different B levels, although the B concentration in leaves increased with an increasing concentration in solution, showing a close correlation each other.
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  • 30
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    Plant and soil 63 (1981), S. 377-393 
    ISSN: 1573-5036
    Keywords: Capacity factor ; Iron ; Self-diffusion coefficients ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Self-diffusion coefficients of zinc and iron were determined in acid soil of Palampur and alluvial soil of Ludhiana under varying pH, CaCO3, moisture, carrier and phosphorus levels. Increase in pH caused tremendous reductions in self-diffusion coefficients (Da) of both zinc and iron in soil. The selfdiffusion coefficients of both these elements were drastically reduced as a result of CaCO3 application. The Da values of zinc and iron increased with the decrease in moisture tension and increase in carrier and phosphorus levels. The decrease in Da values were associated with increase in capacity factor.
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  • 31
    ISSN: 1573-5036
    Keywords: Available zinc ; Critical levels ; Chemical methods ; Green gram ; Phaseolus aureus ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Studies were conducted in 22 non-calcareous soils (India) to evaluate various extractants,viz. (6N HCl, 0.1N HCl, EDTA (NH4)2CO3, EDTA NH4OAc, DTPA+CaCl2 and 1M MgCl2) to find critical levels of soil and plant Zn for green gram (Phaseolus aureus Roxb.). The order of extractability by the different extractants was 6N HCl〉0.1N HCl〉EDTA (NH4)2CO3〈EDTA NH4OAc DTPA+CaCl2〉1M MgCl2. Critical levels of 0.48 ppm DTPA × CaCl2 extractable Zn, 0.80 ppm EDTA NH4OAc extractable Zn, 0.70 ppm EDTA (NH4)2CO3 extractable Zn, and 2.2 ppm 0.1N HCl extractable Zn were estimated for the soils tested. The critical Zn concentration in 6 weeks old plants was found to be 19 ppm. The 0.1N HCl method gave the best correlation (r=0.588**) between extractable Zn and Bray's per cent yield, while with DTPA+CaCl2, it was slightly low (r=0.542**). The DTPA + CaCl2 method gave significant (r=0.73**) correlation with plant Zn concentration. The 0.1N HCl gave the higher correlation with Zn uptake (r=0.661**) than DTPA (r=0.634**) 6N HCl and 1M MgCl2 method gave nonsignificant positive relationship with Bray's per cent yield. For noncalcareous soils apart from the common use of DTPA+CaCl2, 0.1N HCl can also be used for predicting soil available Zn. The use of 0.1N HCl would be much cheaper than DTPA and other extractants used in the study.
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  • 32
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    Plant and soil 63 (1981), S. 491-495 
    ISSN: 1573-5036
    Keywords: Calcium ; Copper ; Flowers ; Iron ; Leaves ; Magnesium ; Nitrogen ; Nutrient uptake ; Phosphorus ; Potassium ; Koots ; Shoots ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Cucumber (Cucumis sativus) plants were grown in Hoagland solution to which 20 to 2000 ppm of a soil fulvic acid (FA) were added. The addition of 100 to 300 ppm of FA produced highly significant increases in the growth and development of above and below ground plant parts, in the uptake of nutrient elements (N, P, K, Ca, Mg, Cu, Fe and Zn), and in the formation of numbers of flowers per plant. Effects of adding 500 and more ppm of FA were less beneficial.
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  • 33
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    Plant and soil 64 (1982), S. 393-401 
    ISSN: 1573-5036
    Keywords: Barley ; Cysteine ; Potassium ; Sulfur ; Translocation ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Maximum uptake of Zn in barley (Hordeum vulgare L.) seedlings occurred from nutrient solutions containing SO4−S at 3.5 ppm and K at 6 ppm. Decreased translocation of Zn from roots to tips was observed when plants were grown with lower levels of S and K. Cysteine substituted for SO4-ion as a source of S in Zn absorption, and more Zn was absorbed with cysteine than with sulfate. The effect of K on Zn absorption seems to be influenced by S nutrition in plants.
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  • 34
    ISSN: 1573-5036
    Keywords: Copper ; Fertilizers ; Intensive cropping ; Iron ; Lime ; Manure ; Manganese ; Micronutrient ; Weedicide ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary An assessment of the status of available micronutrients has been made in a long term field experiment on a fixed rotation of soybean-potato-wheat at the Ranchi Agricultural College, Kanke on acid soil. Results of eight years fertilizer applications with lime has resulted in reduction of available micronutrients whereas the FYM application with balanced dose of chemical fertilizers increased the available micronutrients of soil. The maximum loss of 1.0 Zn and 13.2 Fe kg/ha respectively were from the lime treated plots with balanced dose of fertilizers and the highest gain of 0.26 Zn, 1.08 Cu, 13.2 Fe and 54.0 Mn kg/ha respectively were recorded from the FYM treated plots with balanced dose of chemical fertilizers. Organic carbon was significantly positive correlated with av. Zn & Mn, whereas av. Mn significantly negative correlated with pH. Other relationship were found to be non significant.
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  • 35
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    Plant and soil 66 (1982), S. 271-277 
    ISSN: 1573-5036
    Keywords: Aleppo pine ; Cadmium ; Chromium ; Greece ; Heavy metals ; Lead ; Manganese ; Nickel ; Pinus halepensis ; Pollution ; Soil ; Sulfate ; Thriasian plain ; Vegetation ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The Thriasian Plain near Athens in Greece is a site of concentrated industrial development. Total concentrations of Pb, Cd and extractable SO4 2− in surface soil samples collected from this area, were found to be, respectively, 2–7, 6–34 and 2–20 times higher than those in similar soil samples from parts of the country remote from industrial activity. Total concentrations of Pb, Cd, Zn, Cr and S in samples of olive leaves from the same area were found to be, respectively, 4–40, 3–10, 3–9, 2–6 and 17–21 times higher than those found in samples of olive leaves from rural sites. Leaves of cabbages growing in the area contained between 0.82 and 40 μg/g (wet weight) of Pb. Addition of Cd, Ni and Cu to a calcareous potted soil at concentrations of 100, 200 and 200 ppm increased the concentrations of the metals in the needles of Aleppo pine (Pinus halepensis) seedlings to 4.5, 3.5 and 10 ppm, respectively, after 7 months growth in the nursey.
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  • 36
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    Plant and soil 66 (1982), S. 361-372 
    ISSN: 1573-5036
    Keywords: French beans ; Iron ; Manganese ; Micronutrients ; Phaseolus vulgaris ; pH Rhizosphere ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In pot experiments the relationships between rhizosphere pH, the extractable levels of Fe, Mn and Zn in the soil and their uptake into the roots and shoots of dwarf French beans have been studied. Variations in rhizosphere pH were induced by applying three different sources of nitrogencholine phosphate, ammonium phosphate and calcium nitrate-to an initially homogenised soil (preadjusted to either pH 7 or 8). The rhizosphere pH was found to be significantly lower following the application of either ammonium or choline phosphates and to be increased by calcium nitrate treatment. The Fe and Zn contents of both shoot and root were inversely proportional to rhizosphere pH. The Mn contents also increased with decreasing pH but a sharp increase was apparent below pH 5.5. The shoot Fe, Zn and Mn content were significantly correlated with the extractable levels determined in the rhizosphere and non-rhizosphere soil.
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    Plant and soil 66 (1982), S. 299-316 
    ISSN: 1573-5036
    Keywords: Bio-toxic ; Cadmium ; Contamination ; Copper ; Copper ; Health hazard ; Heavy metals ; Lead ; Localisation ; Migration ; Nickel ; Pollution ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The migration of common bio-toxic heavy metals in two typical soils of Japan under the influence of various leaching solutions was investigated. The results of the present study have indicated that the Pb and Cu ions were less mobile than those on Zn and Cd. Thus, the former two ions have largely been concentrated in the surface horizon while the latter two have been localised in the sub-surface layers. Ni has exhibited greater mobility than other heavy metals under all the leaching stress in both the soils. It is clear from the present study that Ni, Cd and Zn might pose a greater threat of ground water pollution than Cu and Pb. The specific migration properties of each metal ion varied depending on the nature of the ion and leaching solutions. The major soil factors governing the mobility of heavy metals in the soils have been discussed in the light of the results of the present investigation.
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  • 38
    ISSN: 1573-5036
    Keywords: Ammonification ; Cadmium ; Heavy metals ; Kinetics ; Lead ; Nitrification ; Perfusion incubations ; Polluted soils ; Selection ; Toxicity ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The sensitivity of the mineralization of nitrogen by a range of soils contaminated with heavy metals (up to 340 μg Cd g−1, 7500 μg Pb g−1 and 34000 μg Zn g−1) to the addition of heavy metals in solution were studied using pot incubations (ammonification) and a soil perfusion technique (nitrification). The ammonification of peptone showed little correlation between treatments with Cd, Zn (1000 and 5000 μg g−1) and Pb (10000 and 20000 μg g−1) and origin of the soil. Nitrification was considerably more sensitive to heavy metals than ammonification. All the soils had active, often large, populations of ammonifying and nitrifying organisms which showed substantial similarities between the soils. The rate of nitrifying activity (NO3−N production) was logrithmic in most cases. The presence of tolerant populations of nitrifying organisms in the contaminated soils was demonstrated. Tolerance was also eventually acquired after a longer lag phase, by the non-contaminated soil populations although the rate of activity was often reduced. Metals added in solution were adsorbed by the soil within 4 hours. Differences in toxicity between metal salts (chlorides, sulphates and acetate) were attributed to the amount left in solution. However, in many instances, acetate was found to stimulate all the stages in the mineralisation of nitrogen.
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  • 39
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    Plant and soil 71 (1983), S. 371-380 
    ISSN: 1573-5036
    Keywords: Apple ; Calcium ; Copper ; Iron ; Irradiance ; Magnesium ; Manganese ; Nitrogen ; Nutrient uptake rate ; Phosphorus ; Potassium ; Scion effects ; Season ; Source of nitrogen ; Temperature ; Tissue nutrient level ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The rates of uptake of nutrients from solution by apple roots were measured (a) in a root laboratory, using intact roots of mature trees growing under field conditions and (b) in controlled environment using young trees. Maximum nitrate inflows into Discovery/M.9 roots under field conditions were only slightly lower than those into roots of the same genotype in controlled environment, but up to 80 times lower than those into roots of Worcester Pearmain seedlings. At any given external P concentration, P inflows into roots of field-grown trees were about 2.5-times lower than those into the roots of young trees in controlled environment. Nitrate inflows were constant above a solution concentration of 20 mmol m−3 in both field-grown and small trees. In both cases, phosphate inflows increased linearly with solution concentration up to 10 mmol m−3. Among the various plant and environmental factors influencing nutrient uptake characteristics of apple roots were: the scion genotype, tissue nutrient levels, root origin, the form in which N is supplied, level of irradiance of the shoot, root temperature and the season of the year. The effects of these factors are illustrated with examples.
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  • 40
    ISSN: 1573-5036
    Keywords: Availability ; Maize ; Manure ; Slurry ; Transformation ; Zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Assuming that their efficiency might possibly be improved by natural complex formation, inorganic Zn salts were mixed into organic manures before decomposition. These mixtures were allowed to decompose aerobically and anaerobically, to produce Zn-enriched manures and slurries, for 75 and 50 days, respectively. Fractionation of Zn in the final product revealed that the water-solubility of ZnSO4 decreased and that of ZnO increased on mixing the compounds with organic matter. Most of the added Zn remained in exchangeable form and the amount of chelated Zn increased with the time of decomposition. Plant availability of Zn from Zn-enriched manure was less and from Zn-enriched slurry was more than that of equal amounts of ZnSO4. Available soil Zn was also higher in soils treated with Zn-enriched slurry than with any other material.
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