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  • Organic Chemistry  (5,482)
  • Ecology
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  • 1980-1984  (3,457)
  • 1950-1954  (2,099)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of mathematical biology 12 (1981), S. 343-354 
    ISSN: 1432-1416
    Keywords: Ecology ; Periodic differential equations ; Optimization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Mathematics
    Notes: Summary The theory developed here applies to populations whose size x obeys a differential equation, $$\dot x = r(t)xF(x,t)$$ in which r and F are both periodic in t with period p. It is assumed that the function r, which measures a population's intrinsic rate of growth or intrinsic rate of adjustment to environmental change, is measurable and bounded with a positive lower bound. It is further assumed that the function F, which is determined by the density-dependent environmental influences on growth, is such that there is a closed interval J, with a positive lower bound, in which there lies, for each t, a number K(t) for which $$F(K(t),t) = 0$$ and, as functions on J × ℝ, F is continuous, while ∂F/∂x is continuous, negative, and bounded. Because x(t) = 0, 〉 0, or 〈 0 in accord with whether K(t) = x(t), K(t) 〉 x(t), or K(t) 〈 x(t), the number K(t) is called the “carrying capacity of the environment at time t”. The assumptions about F imply that the number K(t) is unique for each t, depends continuously and periodically on t with period P, and hence attains its extrema, K min and K max. It is, moreover, easily shown that the differential equation for x has precisely one solution x * which has its values in J and is bounded for all t in ℝ; this solution is of period p, is asymptotically stable with all of J in its domain of attraction, and is such that its minimum and maximum values, x min * and x max * , obey $$K_{min} \leqslant x_{min}^* \leqslant x_{max}^* \leqslant K_{max}^* .$$ The following question is discussed: If the function F is given, and the function r can be chosen, which choices of r come close to maximizing, x min * ? The results obtained yield a procedure for constructing, for each F and each ɛ 〉 0, a function r such that x min * 〉 K max − ɛ.
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  • 2
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    Journal of mathematical biology 18 (1983), S. 255-280 
    ISSN: 1432-1416
    Keywords: Population dyamics ; Ecology ; Periodic solutions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Mathematics
    Notes: Abstract A model of the competition of n species for a single essential periodically fluctuating nutrient is considered. Instead of the familiar Michaelis-Menten kinetics for nutrient uptake, we assume only that the uptake rate functions are positive, increasing and bounded above. Sufficient conditions for extinction are given. The existence of a nutrient threshold under which the Principle of Competitive Exclusion holds, is proven. For two species systems the following very general result is proven: All solutions of a τ-periodic, dissipative, competitive system are either τ-periodic or approach a τ-periodic solution. A complete description of the geometry of the Poincaré operator of the two species system is given.
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  • 3
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    Archives of microbiology 139 (1984), S. 351-354 
    ISSN: 1432-072X
    Keywords: Aerobic denitrification ; Thiosphaera pantotropha ; Nitrate reduction ; Bacterial selection ; Ecology ; Oxygen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract During studies on the denitrifying mixotroph, Thiosphaera pantotropha, it has been found that this organism is capable of simultaneously utilizing nitrate and oxygen as terminal electron acceptors in respiration. This phenomenon, termed aerobic denitrification, has been found in cultures maintained at dissolved oxygen concentrations up to 90% of air saturation. The evidence for aerobic denitrification was obtained from a number of independant experiments. Denitrifying enzymes were present even in organisms growing aerobically without nitrate. Aerobic yields on acetate were higher (8.1 g protein/mol) without than with (6.0 g protein/mol) nitrate, while the anaerobic yield with nitrate was even lower (4 g protein/mol). The maximum specific growth rate of Tsa. pantotropha was higher (0.34 h-1) in the presence of both oxygen (〉80% air saturation) and nitrate than in similar cultures not supplied with nitrate (0.27 h-1), indicating that the rate of electron transport to oxygen was limiting. This was confirmed by oxygen uptake experiments which showed that although the rate of respiration on acetate was not affected by nitrate, the total oxygen uptake was reduced in its presence. The original oxygen uptake could be restored by the addition of denitrification inhibitors.
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  • 4
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    Environmental management 5 (1981), S. 495-505 
    ISSN: 1432-1009
    Keywords: Suitability analysis ; Land-use assessment ; Ecology ; Planning ; Human ecology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Beginning with the passage of the National Environmental Policy Act in 1969, the federal government of the United States has enacted numerous pieces of legislation intended to protect or conserve the environment. Other national governments have also enacted environmental legislation during the past two decades. State and local governments have also adopted policies concerned with environmental planning and management. Multiple laws and overlapping governmental agency responsibilities have confused development and resource management efforts. A comprehensive methodology that integrates the legal mandates and the agency missions into a common and unified framework is needed. Ecological planning offers such a method. Application of the method allows planners and resource managers to better understand the nature and character of the land and/or resource and therefore make better decisions about its appropriate use or management. The steps taken in an ecological planning process—1) goal setting, 2) inventory and analysis of data, 3) suitability analysis, 4) developing alternatives, 5) implementation, 6) administration, and 7) evaluation—are outlined and explained. Hand-drawn overlays and computer programs as techniques for handling ecological planning information are compared. Observations and suggestions for further research are offered.
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  • 5
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    Environmental management 4 (1980), S. 111-124 
    ISSN: 1432-1009
    Keywords: Carolinian ; Ecology ; Ideology ; Policy ; Rondeau ; Technology ; Wildland Management ; Parks
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This is a critical examination of some of the basic concepts that have guided management of parks and related reserves, often termed wildlands. Study is focussed on Rondeau Provincial Park, Ontario, and on concepts such as wilderness, primeval forest, and the Carolinian forest. Deer culling and other management policies and practices have been based upon the idea that the highly valued sassafras, tulip, and other species of the Carolinian forest are decreasing due to browsing. Field mapping and analysis of historic vegetation records indicate that this trend is not in fact occurring. Historic research also reveals difficulties in defining the Carolinian or other perceived types of forest for management purposes. A major reassessment of ideology and management policy and practice seem to be required in Rondeau and other wildlands. Vague or general concepts such as wilderness or preservation should be strongly complemented and supported by more precise statements of objectives, a learning attitude, and experimentation and research. As a result of the technical uncertainties and value judgments frequently involved, management should also be based upon the expressed preferences and continuing involvement of citizens.
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  • 6
    ISSN: 1432-072X
    Keywords: Bacillus tusciae ; New species ; Taxonomy ; Ecology ; Chemolithoautotrophy ; Hydrogen oxidation ; Hydrogenase ; Thermophily ; Geothermal manifestation ; Solfatara
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A thermophilic, chemolithoautotrophic, hydrogen-oxidizing sporeformer has been isolated from ponds in a solfatara in the geothermal area of Tuscany (Italy). Some physicochemical parameters of the habitat were determined. The habitat was characterized by the presence of molecular hydrogen in the escaping gases, a very low content of phosphate and organic matter. Temperature and water level in the ponds varied widely. The organism formed oval, subterminal spores, which swelled distinctly the sporangium. Optimal growth occured between pH 4.2 and 4.8 at 55°C. It grew best under autotrophic conditions, but organic substrates including short chain fatty acids, amino acids and alcohols could also support heterotrophic growth. Sugars were not metabolized. The hydrogenase was soluble but did not reduce pyridine nucleotides. Based on its morphological and biochemical features, the organism belongs to the genus Bacillus, but differs from all the previously described species. It is therefore proposed as constituting a new species, Bacillus tusciae.
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  • 7
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    Archives of microbiology 131 (1982), S. 107-111 
    ISSN: 1432-072X
    Keywords: Cyanophyta ; Cyanobacteria ; Oscillatoria rubescens ; Photosynthetic pathways ; Photosynthetic enzymes ; Ecology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Short term14C labelling experiments and enzymatic activities related to primary pathways of photosynthesis have been studied in the cyanophytaOscillatoria rubescens D.C. from axenic cyclostat cultures. Responses of samples from cultures with different amounts of nitrogen are presented and compared. Variations in photosynthetic pigments are used to quantify the degree of nitrogen starvation at different levels. PEPcarboxylase activity remains low and is not affected by nitrogen starvation. RuBPcarboxylase activity is lowered to nearly two thirds of its normal metabolic rate by starvation but PEPcarboxykinase and aspartate aminotransferase activities are significantly higher in this case. Malate dehydrogenase is slightly altered and malic enzyme is never active. Starved algae replaced in fresh complete media fix rapidly14C in nitrogen compounds such as amino acids. Results are discussed in regard to both physiological and ecological characteristics ofO. rubescens. PEPcarboxykinase can play a role in making efficient use of HCO 3 - .
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  • 8
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    Hydrobiologia 73 (1980), S. 181-193 
    ISSN: 1573-5117
    Keywords: Ecology ; feeding ; invertebrate behavior ; larval biology ; Rotifer ; sessile rotifer ; substrate-dependent survivorship ; substrate selection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
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  • 9
    ISSN: 1573-5133
    Keywords: Cichlid ; Ecology ; Behavior ; Evolution ; Tropics ; Polymorphism ; Central America ; Lake Malawi ; Africa
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Cichlasoma citrinellum is a polymorphic species whose individual coloration varies from the dark grey markings typical of the species to yellow, orange, and red. In Lake Jiloá, Nicaragua the depth distribution of these latter, nongrey, golden morphs shows dramatic seasonal variation. In the height of the dry season in February over 50% of the gold morphs occur above 9 m, but as the breeding season approaches they migrate deeper such that less than 7% of the gold population occurs above 9 m at the onset of the breeding season. During the rainy season when breeding occurs most of the gold morphs occur below 15 m. It appears that gold morphs ‘voluntarily’ move into deeper water to breed rather than being aggressively forced deeper by larger, territorial grey morphs as was implied in an earlier paper (McKaye & Barlow 1976). Since the morphs of this species assortatively mate and select different habitats in which to breed, future sympatric splitting of this species is possible. Likely examples of sympatric speciation and of incipient speciation in the family Cichlidae are discussed.
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  • 10
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    Environmental biology of fishes 5 (1980), S. 109-116 
    ISSN: 1573-5133
    Keywords: Bay ; Dispersal ; Ecology ; Egg type ; Fish larvae ; Islands ; Points ; Rocky habitats ; Species turnover
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Reef fish community composition in three segments of a peninsular rocky shoreline in the Gulf of California was estimated over four periods by visual observation. ‘Point’ and ‘bay’ segments had regular and distinct species compositions over most periods while a ‘middle’ segment was least distinct but consistently had the greatest number of species. Compositional change along the peninsula was least regular during the coldest sea temperature period (April). Mean species turnover between segments was highest between point and bay. Within segments, the point had greater compositional predictable composition (lowest species turnover). When species with regular frequency of encounter were classified into ‘point’, ‘middle’, ‘bay’, and ‘no trend’ groups it was found that comparatively more ‘point’ species had pelagic eggs and comparatively more ‘bay’ species had demersal eggs. Beta diversity of rocky-shore fishes along the physical gradient of the Punta Doble peninsula reflects a transition between exposed and protected rocky shoreline communities. The correlated physical environmental characteristics associated with exposed and protected habitats are discussed in relation to diversity regulation and dispersal strategies in reef fishes.
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  • 11
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    Environmental biology of fishes 6 (1981), S. 95-103 
    ISSN: 1573-5133
    Keywords: Behavior ; Ecology ; Parental care ; Reproductive cycles ; Colonial nesting ; Etroplus maculatus ; Etroplus suratensis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The Asian cichlids,Etroplus maculatus (the orange chromide) and E. suratensis (the green chromide) in Sri Lanka reproduce twice during the year when water conditions are favorable for nest construction and maintaining visual contact with offspring. These are the drier premonsoonal and monsoonal seasons when water turbidity decreased and salinity increased. When breeding in isolation orange chromide pairs selected dense vegetation where nests were camouflaged. During the peak breeding cycle (July) orange chromide pairs selected sparse vegetation for nesting as a compromise between survival of young and availability of adult food. These areas were also occupied by foraging non-breeding conspecifics which increased the threat of cannibalism of offspring. Under these pressures most orange chromides nested in colonies which helped decrease both actual and attempted cannibalism. The sympatric green chromide does not forage during nesting and nest site selection was determined mainly by factors favoring offspring survival. Biparental care is exhibited by both species. One member of an orange chromide pair stands guard over offspring while the other leaves the territory to forage — their roles are reversed every few minutes. The total parental investment is equivalent to the full investment of a single parent. Monogamy appears to be maintained by their metabolic constraints. In the green chromide both parents are vigilant over offspring and neither forages thus spending twice as much time in parental investment.
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  • 12
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    Environmental biology of fishes 6 (1981), S. 361-365 
    ISSN: 1573-5133
    Keywords: Mimicry ; Shamming death ; Africa ; Fish ; Chafing ; Predation ; Ecology ; Cyrtocara
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Haplochromis (=Cyrtocara) livingstoni, one of the predatory cichlids of the sand community of Lake Malawi, Africa, occurs at a density of 1.3 individuals per hectare. They are territorial, defending areas 15 m wide by 40 m long along the interface of sand andVallisneria weed beds. Individuals use a ‘death feigning’ hunting pattern to capture prey. From a position of lying on their sides semiburied in the sand, these fish attack small cichlids. During four hours of SCUBA observations three successful attacks from this position were seen. After an attack the small cichlids scatter and the predator moves on toward a new aggregation of fish where it again plays dead. Individuals feign death an average of seven times per thirty minutes watch. Death feigning behavior is initiated in two ways. The fish either 1) is stationary with its ventral surface on or close to the sand, and then falls onto its side, or 2) drops from the water colum into `lying on side' position. The initial behavioral actions of the latter method are similar to chafing behavior. But instead of chafing the sand and rising again off the bottom, the fish plows into the sand and remains immobile. These data further add to the evidence that cichlids are remarkably flexible in their feeding behavior.
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  • 13
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    Environmental biology of fishes 7 (1982), S. 177-180 
    ISSN: 1573-5133
    Keywords: Temperature ; Behavior ; Ecology ; Fisheries ; Fish ; Marine juveniles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Sixteen yearling winter flounder, tested individually for 3-day periods in electronic shuttleboxes, voluntarily occupied an 8–27°C range of temperature, with a modal final thermal preferendum of 18.5°C (mean 18.7°C, median 19°C, midpoint 17.5°C, s.d. 1.9°C, S k + 0.33). The locomotor activity pattern of the yearling fish in the laboratory was markedly nocturnal, with mean hourly nocturnal activity exceeding mean hourly diurnal activity by a factor of 3.4. Maximum activity occurred at 0300 EST, minimum activity at 1400 EST. While activity generally increased with temperature, a local activity minimum occurred at 18.7°C, coinciding with the 24-hour mean final thermal preferendum. Comparison of these laboratory data with previously published field data suggest that behavioral responses to temperature and light play significant roles in determining age- and size-specific differences in seasonal depth stratification and onshore-offshore distributions in this species.
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  • 14
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    Environmental biology of fishes 9 (1983), S. 41-53 
    ISSN: 1573-5133
    Keywords: Artificial reefs ; Competition ; Intermediate disturbance ; Ecology ; Mortality ; Predation ; Recruitment ; Stability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis In January 1977, a record breaking cold spell caused fish kills at Big Pine Key, Florida. Census data collected before and after the cold spell from a series of model reefs constructed in 1975 showed a significant drop in mean number of reef fish species and individuals. Following this disturbance, high recruitment of juveniles occurred, presumably due to reduced competition, predation, or a combination of these. Model and natural patch reef communities examined the summer following the cold spell (1977) were significantly different from those examined the summer before (1976) and the second summer following the cold spell (1978). During the summer of 1977, a significantly smaller mean fish size and a significantly greater mean number of species and individuals were observed. Increased species richness following the cold spell is consistent with the intermediate disturbance hypothesis. Contrary to some theoretical predictions, results suggest reef fish communities are highly resilient to some regional disturbance.
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  • 15
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    Plant and soil 69 (1982), S. 293-297 
    ISSN: 1573-5036
    Keywords: Ecology ; Frankia ; Nitrogen fixation ; Water potential
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Growth responses of Frankia isolates to decreasing water potential were monitored in systems where potentials were controlled by KCl, NaCl and Polyethylene glycol. The highest potential tested was −2 bar (basal medium). The general pattern emerging was that isolates fromAlnus glutinosa, A. viridis andComptonia peregrina showed declining growth at potentials below −2 to −5 bar. AMyrica gale isolate showed declining growth with decreasing potential. All isolates were more sensitive to decreases in potential in a matric controlled than an osmotic controlled system. They all showed approximately 50 percent growth reduction at −5 to −8 bar, and meagre growth at −16 bar after 35 days. The Comptonia isolate was the most vigorous at low potentials. Nitrogen fixation ability was monitored for two isolates. Highest specific activities were observed between −3 and −5 bar for the Myrica isolate and between −5 and −7.5 bar for theA. glutinosa isolate.
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  • 16
    ISSN: 1573-5036
    Keywords: Actinorhizas ; (Actinomycetes) ; Ecology ; Hippophaë ; (Mystiflora: Elaeagnaceae) ; Longidorus ; (Nematoda: Longidoridae) ; Nodulation ; Soil ; sterization ; Vegetational succession ; Tylenchorhynchus (Nematoda: Tylenchrohynchidae)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Hippophaë rhamnoides seedlings were grown in sterilized and unsterilized soil from a decliningH. rhamnoides scrub, to which different numbers ofLongidorus sp. andTylenchorhynchus microphasmis were added. In sterilized and unsterilized soil, retardation of growth, content of dry matter in the shoots, and incidence of deformed short lateral roots of test plants were positively correlated with counts of both nematode species. Nitrogen content in the shoots, nodulation on the roots of test plants and increase increase in nematodes were negatively correlated with the initial number of both nematode species in sterilized soil. In unsterilized soil, an unknown biotic factor was present that reduces growth ofH. rhamnoides, nodulation and multiplication of the nematodes. This factor seems to interact with the nematodes in reducing growth ofH. rhamnoides.
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  • 17
    ISSN: 1573-5036
    Keywords: Chitin ; Chitinase ; Chitinglycanohydrolase ; E. C. 3.2.1.14 ; Ecology ; Fertilizers ; Rhizosphere effects ; Soil enzymes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Chitinase activity was determined by incubating a mixture of toluene-treated soil with 1% (w/w) colloidal chitin suspension for 18 h at 37°C and then, after dilution, assaying the amount of N-acetyl-glucosamine released. Maximal chitinase activity was observed at 45°C and optimal pH for enzymatic reaction was 5.0–5.5. Soil chitinase activity decreased with increasing soil depth and was significantly affected by crop cover and fertilization regime. Chitin added to soil stimulated chitinase activity. Enzyme activity was correlated with the soil fungal population but not with numbers of actinomycetes or bacteria. A specialized mycoflora was associated with chitin decomposition.
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  • 18
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    Hydrobiologia 76 (1981), S. 87-96 
    ISSN: 1573-5117
    Keywords: Ecology ; production ; Gulf of Bothnia ; pelagial ; benthos
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Production biology in the Bothnian Bay is discussed and compared to that of the southern parts of the Baltic. Severe ice-conditions, low water temperatures in spring and early summer and a pronounced water-colouring cause a delay of the spring development of phytoplankton and a low annual production in the Bothnian Bay. This delay makes possible a higher efficiency of the pelagic system as the zooplankton fauna can develop in harmony with the food resources. The downward transport of energy and matter to the bottom communities from an efficient pelagial should be small and temporally unpredictable, which is thought to be an adequate explanation of the observed very low benthic fauna biomasses in the Bothnian Bay.
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  • 19
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    Environmental biology of fishes 11 (1984), S. 121-130 
    ISSN: 1573-5133
    Keywords: Ecology ; Habitat ; Feeding ; Age ; Growth ; Reproduction ; Mississippi
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Etheostoma swaini, the gulf darter, was collected from the Black Creek drainage in southern Mississippi (February 1978 – April 1979). The gulf darter generally inhabits small- to moderate-size creeks and occurs over a sand or sandy mud bottom, often in association with aquatic vegetation or a layer of organic debris. Larval dipterans were the most important food items, both numerically and volumetrically. Chironomids were found in 71–100% of the stomachs in all except the unusual March 16 collection. The length frequency distribution and the scale annuli analysis indicated there were three year-classes present in the population at any one time. Fifty-one percent of the specimens taken were less than 12 months old. During the mid-February to late March spawning season gulf darters were most often collected over clean gravel or gravelsand substrates. Laboratory observations suggest that the female burrows into the gravel where the demersal, adhesive eggs are deposited. Female gulf darters significantly outnumbered males at a ratio of 59:41.
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  • 20
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    Environmental biology of fishes 11 (1984), S. 173-190 
    ISSN: 1573-5133
    Keywords: Percidae ; Etheostomatini ; Darters ; Ecomorphology ; Embryology ; Ecology ; Early life history
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The early development of northern logperch, Percina caprodes semifasciata, was examined from an ecological perspective and in relation to the theory of saltatory ontogeny. Steps, the intervals of relative homeostasis, separated by thresholds, rapid switches to new form and function resulting from canalization of changes in the preceeding step, are described and related to environmental factors. Adaptive shifts in growth allometries provided further evidence of the saltatory nature of ontogeny. Logperch eggs are small (1.2 mm diameter), demersal, and adhesive. The simple embryonic respiratory system reflects high oxygen availability on the lotic spawning grounds. Hatching occurs early, relative to other darters, and free embryos are pelagic. The small free embryos presumably drift downstream to lentic areas, where small planktonic food is more abundant. Logperch are therefore nonguarding, open substrate spawning lithopelagophils and, along with other Percina species, have not advanced from ancestral percid reproductive styles. Percina species have generally remained in ancestral habitats-rivers and lakes. The close correlation between developmental patterns of logperch and environmental factors is therefore interpreted as a restriction based on retention of ancestral characteristics, not as evidence of novel adaptations to new habitats.
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  • 21
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    Environmental biology of fishes 5 (1980), S. 117-133 
    ISSN: 1573-5133
    Keywords: Cycles ; Communities ; Diversity ; Ecology ; Estuary ; Multiple regressions ; Oceanography ; Salinity ; Seasons ; Time-series analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis From November 1975 to April 1977 nocturnal dermersal fish were sampled fortnightly at ten sites in Serpentine Creek using a three meter beam trawl with a 3.2 cm mesh net. Forty-five species from thirty-four families were obtained totalling 14 518 individuals with the six most abundant species comprising approximately 72% of the catch. Using multiple regression techniques with Fourier transformations, the mean number of species (S) and abundance (N) of all fish were found to conform to a regular annual cyclical pattern with maxima in April and May. A trend toward declining abundances of individuals and species was present. Shannon (H′) and Gleason (G) diversity indices showed no regular seasonal trends and are considered poor indicators of pollution. In comparison with other estuarine studies at different latitudes Serpentine Creek conforms to the theory that more tropical waters have the greatest faunal diversity. Seventeen of the 22 most abundant species demonstrated a regular annual cycle of abundance. The number of species, abundance and diversity measures were greatest about 1 km from the mouth of the creek and gradually declined upstream. This was the region with highest macrobenthos diversity and with the most stable abiotic values. Temperature and/or salinity were positively correlated with the abundance of eleven species. The species were placed in five groups according to their periodic characteristics. The proportion of ‘resident’ species was low and this is consistent with Tyler's (1971) theory of temperature stabilized fish assemblages. The known biology of six species is related to their occurrence. Salinity and temperature values in the creek exhibit an annual cycle which preceeds that of Bramble Bay by approximately one month. Rainfall in the watershed was correlated with observed salinity values. It is postulated that salinity is the common feature between temperate and tropical estuaries in the maintenance of community cycles.
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  • 22
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    Environmental biology of fishes 11 (1984), S. 277-299 
    ISSN: 1573-5133
    Keywords: Percidae ; Etheostomatini ; Ecomorphology ; Embryology ; Ecology ; Early life history ; Heterochrony
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The early development of rainbow darter, Etheostoma caeruleum, was examined from an ecological perspective. Steps and thresholds of ontogeny to completion of body squammation are defined, and related to environmental factors. Rainbow darter eggs are about 2 mm diameter, considerably larger than those of related logperch (Percina caprodes). The embryonic vitelline respiratory plexus is much more extensive. The pelagic interval characteristic of logperch and ancestral percids is eliminated and onset of exogenous feeding is delayed. The larger larvae of the rainbow darter can begin feeding directly on aquatic insects, and complete their life cycle in streams. Therefore, shifts in the timing of important thresholds (e.g. exogenous feeding) are ecologically important. Furthermore, early maturation and/or delayed bone and scale formation may be responsible for reductions in the lateralis system and scalation in this and other darter species.
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  • 23
    ISSN: 1573-5133
    Keywords: Fish ; Nematode ; Populations ; Life cycle ; Host factors ; Ecology ; Parasites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis A total of 314 white suckers (Catostomus commersoni) taken monthly during May to December 1975 and in April and May 1976 from southern Lake Huron, Ontario, Canada, were examined forCapillaria catostomi. Prevalence determined from fresh white suckers (66%) was significantly lower than from frozen white suckers (81%). However, there was no significant difference in prevalence ofC. catostomi in samples taken at monthly intervals; in male and female white suckers; or in the age categories. Mean intensity of infection was not significantly different in fresh (9.6 [± 13.41]) or frozen (10.4 [± 13.11]) white suckers. There was no significant difference in intensities between monthly samples in male and female white suckers or in the age categories. Suckers were infected with 1–172 worms. The percentage of male, female and immature worms did not change with sex or age of host or by month. The frequency distribution showed the parasites were overdispersed. A possible life cycle forC. catostomi involving an oligochaete intermediate host is discussed and an attempt made to explain the almost constant levels of prevalence and intensity.
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  • 24
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    Environmental biology of fishes 5 (1980), S. 27-32 
    ISSN: 1573-5133
    Keywords: Salvelinus fontinalis ; Salmo salar (ouananiche) ; Ecology ; Salmonids ; Atlantic salmon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The age structures of brook charr (Salvelinus fontinalis) and ouananiche (Salmo salar) stocks inhabiting a large rapid the river Méo, tributary to the Caniapiscau River were used to compare population stability and production of these species in north central Quebec. The brook chart stock was stable whereas ouananiche showed considerable variation in year class strength. Stock estimates were not significantly different for the two species although the brook charr estimate was 1.5 that of the ouananiche. Production estimates differed by a greater margin because of different growth patterns. Brook chair production was estimated at 19.4 kg ha−1 yr−1. Above age 2+ it was 11.4 kg ha−1 yr−1 which compares with 4.8 kg ha−1 yr−1 for the same age groups of ouananiche.
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  • 25
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    Environmental biology of fishes 6 (1981), S. 207-211 
    ISSN: 1573-5133
    Keywords: Fish ; Ecology ; Population density ; Exploitation ; Tagging ; Catch per effort
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Population and exploitation estimates were made from angler recaptures of Chautauqua Lake muskellunge,Esox masquinongy Mitchill. Fish were tagged during Conservation Department studies in 1941–1946, 1961–1965 and 1976–1978. Population estimates of adult fish ranged from one to seven fish per hectare and angler exploitation rates of tagged fish fluctuated from 3.8% to 14.1%. Relative catch indicators suggest a major decline in the lake's muskellunge population during the last decade. Overexploitation, habitat alteration and interspecific competition with recently introduced fish species were cited as probable causes of the decline.
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  • 26
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    Environmental biology of fishes 6 (1981), S. 213-218 
    ISSN: 1573-5133
    Keywords: Australia ; Communities ; Cycles ; Diversity ; Ecology ; Estuary ; Lunar periodicity ; Migration ; Sub-tropics ; Tides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis A series of 10 sites were sampled at new and full moon phases in a vertically homogenous estuary, Serpentine Creek, Queensland, Australia. Forty-five species (14,518 individuals) were caught and analysed using standardized Shannon & Gleason diversity indices, and total number of species and individuals. The coefficients of variation for these values were greater for times than for sites. There were no significant differences between 14 pairs of new and full moon phases fort,t,t, andt, or between mean number of individuals for the 16 most abundant species. If significant variations do exist within months, then experiments should be done between spring and neap tides as this study found no differences between the spring tides associated with new and full moon phases.
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  • 27
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    Environmental biology of fishes 6 (1981), S. 371-375 
    ISSN: 1573-5133
    Keywords: Anguilliformes ; Anguillidae ; Leptocephalus ; Fish larvae ; Horizontal distribution ; Vertical distribution ; Spawning area ; Migration ; Ultrasonic tracking ; Hydrography ; Ecology ; North Atlantic ; Anguilla anguilla ; A. rostrata
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis This report presents preliminary results of the 1979 Sargasso Sea expedition from February to May 1979. Information is given on horizontal and vertical distribution of eel larvae and adults, adult eel tracking and pelagic trawling. Related matters such as electrophoretic studies on anguilliform larvae, feeding of eel larvae, predation on leptocephali, occurrence of other anguilliform larvae and hydrography are mentioned.
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  • 28
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    Environmental biology of fishes 7 (1982), S. 121-136 
    ISSN: 1573-5133
    Keywords: Seasonality ; Predator-prey ; Predator interference ; Turnoverrate ; Diversity ; Ecology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Development of the fish community on a submerged 16 m barge and variation in fish abundance on nearby transects were surveyed twice monthly for twenty months. A steady increase in abundance was observed for certain fishes on the barge, whereas a few species exhibited distinct seasonal variation on both the barge and transects. Most of the seasonal species settled between March and May. Some seasonal species appeared to be site selective in their settlement and consequently settled juveniles were clumped in their distribution. An abundance of preferred topographical features may be why settlement was relatively high at the study site and indirectly why predators became significantly (r3 = 7.67***, N = 37) more abundant at the study area during the months of maximum prey settlement. Concurrent settlement of several species during the same few months may be important because juveniles become an abundant food source to predators during those few months only. Periodic swamping of predators by abundant juvenile prey may improve the chances for individuals of rarer prey species to be overlooked and therefore be succesfully recruited.
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  • 29
    ISSN: 1573-5036
    Keywords: Catalase ; Ecology ; Fertilizers ; H2O2∶H2O2 oxidoreductase ; Rhizosphere effects ; Soil enzymes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Catalase activity of a loamy sand under a 3-year crop rotation in the southeastern U.S.A. was monitored. Corn (Zea mays L.), cotton (Gossypium hirsutum L.), and soybean [Glycine max (L.) Merr.] were the summer crops in the rotation. Winter wheat (Triticum aestivum L.) was planted after corn, and soybean was followed by a winter fallow period. Cotton was followed by a mixture of common vetch (Vicia sativa L.) and crimson clover (Trifolium incarnatum Gibelli & Belli) which was eventually plow-incorporated as a green manure. Highest mean catalase activities were recorded in soil under the wheat, soybean, and winter legume crops; lowest activities were found in soil bearing corn and cotton, and during the winter fallow period. The fertilization regime influenced soil catalase activity independently of the crop. Soil deficient in any of the major elements showed low enzyme activity. Highest activity was found in soil fertilized with P and K, and with N supplied by a winter legume crop. Addition of supplementary mineral nitrogen to this regime reduced catalase activity. Elimination of the winter legume crop from an otherwise complete fertilization regime resulted in a drastic reduction in enzyme activity. In soil receiving a complete fertilization regime there was a close correlation between soil catalase and xylanase activities. A similar correlation between these two enzymes was not found in soil receiving incomplete fertilization.
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    Plant and soil 56 (1980), S. 123-139 
    ISSN: 1573-5036
    Keywords: Actinorhizas ; Ecology ; Endophyte distribution ; Hippophaë rhamnoides ; Infective potential ; Nodulation ; Root nodules
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The infective potential (IP) of nodule homogenates from field-grownHippophaë rhamnoides L. ssp.rhamnoides was determined by counting the number of nodules formed on test plants after inoculation with various dilutions of the homogenates. The IP was almost constant,i.e. 105 to 106 per gram of fresh nodule material. Methods to store nodule material without loss of IP were tested. The IP of air-dried nodule powders stored at 6°C hardly decreased during a period of more than a year. Data are presented on the IP of soil samples from sites representing various stages of dune formation. BeforeH. rhamnoides appeared, the IP was low: 1 to 36 nodules were formed on test plants per kg of soil. This low IP was due to low numbers of infective endophyte particles in these soils. During the succession of theH. rhamnoides scrub, the IP of the soil increased, due to the increase in the number of endophyte particles in the soil. Gradually, however, nodulation was limited by other environmental factors. The nature of these factors is discussed.
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    Plant and soil 61 (1981), S. 71-80 
    ISSN: 1573-5036
    Keywords: Ecology ; Fluorescent antibody ; Immunofluorescence ; Rhizobium japonicum ; Rhizosphere ; Root surfaces ; Soybean
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Populations of nativeRhizobium japonicum 123 in the rhizospheres of field and pot grown plants as determined by immunofluorescence were calculated on the basis of root surface area. The density ofR. japonicum 123 on the root fluctuated between a few hundred to over a thousand per square centimeter of root surface. As root volume expanded rapidly, the Rhizobium density fell to less than one hundred per unit area. There was no appreciable effect due to different plant, nitrogen amendment, or addition of another strain ofR. japonicum, on the surface density of the nativeR. japonicum population on roots. Nor did the native population influence the added strain. Direct examination of root surface segments revealed that naturalized rhizobia existed sparsely on root surfaces in the form of short rods. They were observed to be attached sideways or in a polar manner on root hairs, epidermal cells, and at junctions of tap and lateral roots. There was no evidence of specific stimulation of the homologous Rhizobium by the host plant as a prelude to nodulation.
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  • 32
    ISSN: 1573-5036
    Keywords: Actinorhizas ; Ecology ; Gamma irradiation ; Hippophaë rhamnoides ; Longidorus ; Nematode ; Nodulation ; Root nodules ; Soil sterilization ; Succession
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary To explain the decline of Hippophaë scrub in the vegetation succession in the dunes of The Netherlands, the growth and nodulation of Hippophaë plants grown in pots, using soil from an early stage (site AH) and a post-optimum stage (site HP), were investigated. In HP-soil nodulation, yield, and the nitrogen and phosphorus content of test plants were always lower and the number of necrotic nodules and the dry matter content were always higher than in AH-soil, even after inoculation with crushed nodules and the addition of a nutrient solution. Plants in HP-soil also had darker roots, less root hairs, a higher number of short lateral roots and a higher percentage of dead roots than those in AH-soil. These characteristics of adverse growth conditions disappeared upon ignition or gamma-irradiation of HP-soil. Possible explanations of these results are discussed. The degeneration of Hippophaë scrub cannot be ascribed to the age of the plants, the absence of sufficient infective endophyte particles or to abiotic factors such as unfavourable physical (particle size) or chemical soil conditions but is caused by biotic factors. No indications were obtained that plant-pathogenic fungi and bacteria are involved. HP-soil in contrast to AH-soil, however, contained large numbers of the nematodeLongidorus sp., a species known to cause root deformations. The conclusion was that this nematode is one of the biotic factors involved in the degeneration of the Hippophaë scrub. This degeneration is due to a restriction of the root system resulting in a low phosphate uptake, a low nodulation capacity and, as a consequence, a low nitrogen content. The results demonstrate that biotic soil factors are important in influencing succession in higher plant communities.
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  • 33
    ISSN: 1432-1955
    Keywords: Argas persicus ; Bionomics ; Ecology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract The fowl tickArgas (Persicargas) persicus occurs in warm areas of Slovakia, where its distribution is limited by the 650–700 mm annual average isohyet and the +8° C annual average isotherm. In Slovakia, larvae hatch from spring to autumn, and nymphal and adult moultings occur chiefly in July and August. Larvae feed for four days, nymphs and adults for less than one hour. The tick develops and reproduces during the warm season in the wild but throughout the year under favourable laboratory conditions in which the life cycle requires 17 months.
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  • 34
    ISSN: 1871-4528
    Keywords: Altersresistenz ; Temperatur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Description / Table of Contents: Summary The effect of soil moisture on the growth and development of the potato cultivar Uran and on the proportion of virus-infected tubers was investigated in a 4-year series of pot experiments. Soil moisture was adjusted to two levels; dry and optimum, at various times before and after inoculation. One isolate each of the strains PVYN and PVYO were used in each case to inoculate the plants. Tuber infection was recorded 60 days after inoculation and at maturity. Dry conditions during the growing period checked growth, delayed flowering, lengthened the growing period, and reduced tuber yield, which was at its lowest when dry conditions were maintained from flowering to harvesting. The percentage virus-infested tubers from plants in dry conditions was approximately twice that of plants grown under optimum conditions (Table 1). This applied however only to infections with PVYN. Almost all tubers were infected with PVYO regardless of soil moisture content. Low temperatures after inoculation presented tuber infection by both isolates (Table 2).
    Abstract: Résumé L'influence de l'humidité du sol sur la croissance et sur le taux de tubercules atteints par le virus Y, a été examinée par un essai en pots pendant 4 ans, avec la variété de pomme de terre Uran contaminée par le PVY. Deux procédés d'humidité du sol ont été examinés: des conditions arides et une humidité optimale avant l'inoculation et pendant des périodes de différente durée après l'inoculation. Pour l'inoculation des plantes, des souches de virus PVYN et PVYO ont été utilisées. Les tubercules ont été examinés 60 jours après l'inoculation, et à la maturité complète des plantes. Les conditions de sécheresse ont freiné la croissance, retardé l'époque de floraison, prolongé la période de végétation et influencé le rendement d'une manière négative. Le rendement le plus bas a été obtenu lorsque la sécheresse s'étendait de la floraison à la récolte. Comparativement aux plantes cultivées dans des conditions optimales d'humidité, le manque d'eau a eut pour effet de doubler le nombre de tubercules contaminés par le virus (tableau 1). Ce dernier résultat est cependant valable uniquement pour la souche PVYN, tandis que pour la souche PVYO, les tubercules étaient pratiquement tous contaminés indépendamment du taux d'humidité. Les températures basses après l'inoculation ont empêché la contamination des tubercules pour les deux souches de virus (tableau 2).
    Notes: Zusammenfassung Der Einfluss von Bodenfeuchtigkeit und Temperatur auf die Höhe des Knollenbefalls wurde an der Kartoffelsrote ‘Uran’ für je ein Isolat der Kartoffelvirus-Y-Stammgruppen PVYN und PVYO in Topfversuchen ermittelt. Pflanzen, die nach Inokulation mit PVYN zu verschiedenen Zeiten der Trockenheit ausgesetzt waren, zeigten et wa doppelt soviel infizierte Knollen als diejenigen, die bei optimalen Feuchtigkeitsverhältnissen aufwuchsen. Nach Inokulation mit PVYo wurden solche Unterschiede nicht festgestellt, die Knollen waren hier in allen Fällen fast vollständig befallen. Niedrige Temperaturen nach der Inokulation verhinderten bei beiden Virusisolaten weitgehend den Befall der Knollen.
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    Plant ecology 48 (1982), S. 123-131 
    ISSN: 1573-5052
    Keywords: Ecology ; Fringe communities ; Numerical classification ; Ostrya carpinifolia woods ; Phytogeographic elements ; Phytosociology ; Southern Alps (N-Italy) ; Vegetation dynamics ; Wood edge communities
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Forest regeneration in the vegetation complex of the submontane belt in the Southern Alps involves the active participation ofOstrya carpinifolia woods and their wood edge communities. The corresponding syndynamical processes are described by employing phytosociological, phytogeographical and ecological methods. It is concluded that: (i) The communities of the grassland-wood transition are of major importance in the successional developments in this man-made vegetation complex. (ii) Many species occurring in the region of the deciduous forests of Eurasia find their refuge in such transitional communities and are supposed to play an important part in the succession. (iii) Ostrya carpinifolia is considered as an early successional tree species.
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    Plant ecology 44 (1981), S. 13-24 
    ISSN: 1573-5052
    Keywords: Aceri-Fagetum ; Alpine timberline ; Dynamics of stands ; Ecology ; Fagus silvatica ; Morphogenesis ; Polycormons ; Vegetative regeneration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary In the Central Europaean mountain ranges, the alpine timberline is usually formed by Picea abies or by other conifers (Larix decidua, Pinus mugo, Pinus cembra). Unlike in the East Europaean mountains, the Balkan Peninsula, the Europaean Mediterranean and Les Vosges, Fagus silvatica occurs sporadically on the alpine timberline in this area where it forms very specific woods. This type of the alpine timberline is bound to the association Aceri-Fagetum (Bartsch 1940, Moor 1952). This association is found on the highest sites of the Fagion alliance in the subalpine vegetation zone. Within this zone, the association is bound to localities with heavy snowfall and a submaritime climat. It occupies larger areas in the Swiss Jura and in Les Vosges. In other Central Europaean mountains (the Alps, Schwarzwald, Krkonoše etc.) it occus in isolated areas only. Many trunk deformations and bush forms are found with Fagus on a large scale in the snow impacted localities (steep slopes, periphery of corries, avalanche slopes etc.). Crawling and sliding snow causes these growth deformations in the Fagus seedlings since their first year. The general increase of the vegetative propagation is a remarkable and exceptional response of Fagus in adapting to these extreme growth conditions. Under alpine timberline conditions, the generative propagation is very limited. The vegetative shoots with adventitious root systems are formed mainly from branches layering in the humus. The typical monocormonal tree-form of Fagus from lower altitudes turns in this way into a polycormon. From an evolutionary point of view, it is a suitable substitution; but from the ecological viewpoint, however, it is a sturdy growth form. In its typical form, the polycormon is formed by a number of vegetative shoots, which may be deformed but are very elastic and resistent. The number of shoots in a polycormon varies from 3–5 below, and up to 40–50 at and above the timberline. They are formed by shoots of a number of filial successions. The decay of a polycormon results from decreasing vitality of single shoots or, very often, it is caused by the impact of snow and ice. Considering, however, the fact that single shoots have a sufficient adventitious root system and are thus physiologically independent, the dying of the other shoots does not mean a danger for the existence of the remaining part of the polycormon. The age of a polycormon as a whole is difficult to determine. Fagus polycormons can be considered as a typical growthform of the highest sites of the association Aceri-Fagetum. No other tree species is able to form close stands under these conditions. This phenomenon is of primary importance for the existence of this plant community. The unusual character of the structure and dynamics of the highest Aceri-Fagetum stands gives rise to a special type of the alpine timberline which should be understood not as a ‘line’ but as a transitional zone between the closed stands and the hon-wooded plant communities of the subalpine vegetation zone. The dynamic succession of the Fagus polycormons guarantees the stability of the Fagus stands forming the alpine timberline.
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  • 37
    ISSN: 1573-5052
    Keywords: Alyssum serpyllifolium subspecies ; Nickel accumulation ; Nickel tolerance ; Ecology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Experiments were carried out on the tolerance to, and uptake of, nickel by three iberian subspecies of Alyssum serpylliforium Desf. Two of these subspecies, the serpentine-endemic ssp. lusitanicum from Bragança, Portugal and ssp. malacitanum from Málaga, Spain, are hyperaccumulators (〉 1000 μg/g in dried material) of nickel. Their possible ancestor, ssp. serpyllifolium (from Granada, Spain) was a non-accumulator of this element. Seeds of the two serpentine-endemics germinated extensively in nickel concentrations up to 12 000 μg/g (1.2%) whereas ssp. serpyllifolium only germinated in nickel concentrations below 60 μg/ml. Tolerance tests involving measurement of new root lengths of excised seedlings placed in varying nickel concentrations, again showed much greater tolerance of the two serpentinophytes. In both series of experiments, the order of tolerance was: ssp. lusitanicum 〉 ssp. malacitanum 〉 ssp. serpyllifolium. In pot trials involving seedlings of ssp. malacitanum grown in mixtures containing varying amounts of calcium, magnesium, and nickel, the most important finding was that plants will tolerate higher nickel contents in the soil when excess calcium is added. This is achieved by lowering the uptake of nickel. There appeared to be some concomitant reduction in calcium uptake in the presence of nickel, and some increase in uptake of magnesium. The resultant lower calcium/magnesium ratio in the plant, though not symptomatic of a favourable condition for colonization of serpentine soils, probably results from a mechanism which renders nickel innocuous to the plant at the expense of calcium uptake. It is suggested that the physiological characters of ssp. lusitanicum and ssp malacitanum are sufficiently different to support arguments for promoting the latter to full specific rank as has now been done for ssp. lusitanicum.
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    Plant ecology 55 (1984), S. 57-64 
    ISSN: 1573-5052
    Keywords: Ecology ; Hepaticae ; Pioneer vegetation ; Resurrection (poikilohydric) plants ; Riccia ; South West Africa
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Three associations of the Nanocyperion teneriffae Lebrun 1947 (Sporoboletalia festivi Lebrun 1947) are described. They are physiognomically and ecologically similar to associations of the Mediterranean Isoeto-Nanojuncetea Br.-Bl. et Tx. 1943 and Helianthemetalia guttati Br.-Bl. 1940. They are rich in very specialized therophytes and resurrection plants.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 279-286 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Convenient Synthesis of 4-Oxo-tetrahydropyrimidinesEnamino-nitriles as 6 or 11 yield 4-oxo-pyrimidines (2; 2a; 10; 12a-c) on treatment with cyclohexanone in basic media. Analogous compounds are obtained using acetone, butyraldehyde, benzaldehyde or substituted benzaldehydes.
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  • 40
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: The “Normalizing Factor” for the Tomato Mutant chloronerva. XV. Peptide Analogues of the Phytosiderophore NicotianamineSome peptide analogues of the phytosiderophore nicotianamine, (2S, 3′S, 3″S)-N-[3-(3-amino-3-carboxypropylamino)-3-carboxypropyl]-azetidine-2-carboxylic acid, have been synthesized from protected amino acids by the EEDQ or the DCC method. They exhibited no biological effect with regard to the phenotypical normalization of the tomato mutant chloronerva.
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  • 41
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-Aza-3-chloro-2-propeniminium salts 5, which are easily available by the addition of formamide chlorides 1 to nitriles 2 react smoothly with hydrazines 9 giving rise to 1,3-disubstituted 1,2,4,-triazoles 11. When the 2-aza-3-chloro-2-propeniminium salts 5 are hydrolysed first the resulting N-acyl-formamidinium salts 6 react with hydrazines 9 to 1,5 disubstituted 1,2,4-triazoles 13 via isolable N-acyl-formamidrazones 12.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 303-310 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quantum Chemical Investigations of the Molecular and Electronic Structure of Simple Azomethine Imines and Related CompoundsThe molecular and electronic structure of simple azomethinimines are investigated by means of MINDO/3 and CNDO/2 calculations. The calculated molecular geometry is compared with X-ray results obtained for these compounds. Except for the NN-bond lengths MINDO/3 satisfactorily describes the molecular structure of azomethinimine and related π-electronic systems. The charges at the atoms along the conjugated chain are alternating as in polymethines. The terminal carbon atom carries a negative charge. This charge brings about an appreciable shielding of this carbon atom such as found in the 13C-n.m.r. spectrum. This result does not contradict a stabilization of azomethinimines in the crystal via = CH…O=C interactions.
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 261-268 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Stereochemical Investigations of Heterocyclic Compounds. XII. Structural Investigations of 1-(2-Amino-1-cyano-2-thio)ethene Pyridinium YlidesTwo isomerization processes were found by 1H-d-n. m. r. characterized by ΔG* = 67 ± 4 KJ/mol for E- Z-isomerization and ΔG* = 46 ± 5 KJ/mol for the hindered rotation of the pyridine substituent in 1a. The structure of 1b was solved by direct method. Crystals are monoclinic space group P21/n, a = 13.682(3), b = 9.452(1), C = 19.713(6) Å, β = 96.42(2)°, V = 2533.3 Å3, Dx = 1.328 Mg · m-3, Z = 8. Both E- and Z-isomeres of 2b are found in the crystal lattice. The amino—C distance with 1.369 (1,387) Å is shorter than the theoretical single bond distance. The formal —C=C— double bond with 1.377 (1.391) Å is considerably longer than 1.337 Å observed in the some alkenes.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 320-328 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of Oligodeoxyribonucleotides on a Polystyrene Grafted Polytetrafluorethylene Support via Phosphotriester Intermediates
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 342-348 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quinazolincarboxylic Acids. I. Quinazolin-4-on(2,4-dion)-3-acetic Acids and Esters
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  • 46
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 374-380 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effects of temperature, structure and sulphuric acid concentration on the selectivity of the oxidation of aliphatic ketones (R1COR2) (1a-g) by thallic sulphate have been investigated. With increasing temperature the quantity of internal α-hydroxyketone (3a-d) decreases and the quantity of 1-hydroxyketone (2a-d) increases in the oxidation of methyl alkyl ketones (R2〉CH3) (1a-d). The same concerns to the oxidation products of hexan-3-one (1e): 2-hydroxy-hexan-3-one (2e) and 4-hydroxy-hexan-3-one (3e), respectively. “The inverse selectivity temperature” (IST) for oxidation of linear methyl alkyl ketones (1a-c) and hexan-3-one (1e) has been found. With the use of the linear free-energy relationship it has been found that the selectivity of the reaction decreases with increasing the polar and steric effects of substituents R1, R2. With increasing the sulphuric acid concentration the selectivity of the oxidation of methyl alkyl ketones (1a, 1d) increases.
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  • 47
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 401-406 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Electrophilic Reactions on the Maleimide Double BondThe aminosubstituted maleimides 1 are deprotonated to the anions 2, which are reacted with various electrophiles. By this way with heterocumulenes, acid chlorides and vinylogous acid chlorides the new acylated maleimides 3-6, 9, 10 are isolated. This reaction presents a method of direct acylation on the maleimide double bond.
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  • 48
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    Topics: Chemistry and Pharmacology
    Notes: Light Induced Polymer and Polymerization Reactions. 14. Radical Photopolymerization by Potassium Trisoxalato Cobaltate Arylonium Salts Systems.The photopolymerization of acrylamide (AA) by trisoxalato cobaltate ([Co(ox)3]3⊖) is inefficient because the produced nucleophilic ·CO2⊖-radicals are oxidized or they terminate with polymer radicals. If onium compounds are added to this system the initiation efficiency is increased as follows : p-CH3OC6H4N2⊕〉Ph2I⊕〉PhCOCH2S(CH3)2⊕〉Ph3S⊕. By means of quantum yield measurements a mechanism was proposed including the electron transfer from ·CO2⊖ to onium compounds. The produced radicals also initiate the polymerization of AA. The exponent m of the polymerization rate (vp ≍ [AA]m) is decreased from 1.4 to 1.1 in the presence of Ph2I⊕, deciding the decrease of termination reaction between ·CO2⊖ and polymer radicals. In comparison with K3[Fx(ox)3] the corresponding cobalt complex possesses higher polymerization quantum yields for AA.
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  • 49
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 341-344 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Oxidation of Some Alkyl- and Alkenylferrocenes by Bis(triphenylsilyl) Chromate (VI)In vorangehenden Mitteilungen [1-3] haben wir über die Oxidation von primären und sekundären Alkoholen mit Ferrocenyl-Substituenten mittels Bis(triphenylsilyl)-chromat(VI) in aprotischen Lösungsmitteln berichtet. Dabei konnte keine Oxidation des Ferrocens zum Ferricenium-Kation beobachtet werden. Die Reaktionen verlaufen selektiv und führen mit hohen Ausbeuten zur Bildung der entsprechenden Carbonylverbindungen. In dieser Mitteilung sind die Ergebnisse unserer bisherigen Untersuchungen zur Oxidation von Alkyl- und Alkenylferrocenen mit Bis(triphenylsilyl)-chromat(VI) unter ähnlichen Reaktionsbedingungen zusammengefaßt.
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 350-351 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 51
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  • 52
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    Topics: Chemistry and Pharmacology
    Notes: The Determination of Enantiomeric Purity of Intermediates for Prostaglandins by N. M. R. SpectroscopyIm Rahmen einer Prostaglandinsynthese waren chirale Ringschlüsselprodukte durch mikrobielle Transformation gewonnen worden [1]. Zur vollständigen Charakterisierung dieser Ringschlüssel-produkte war die Kenntnis ihrer optischen Reinheit unerläßlich. Wir haben für diese Untersuchungen die 1H-NMR-Spektroskopie unter Verwendung eines chiralen Verschiebungsreagenzes eingesetzt.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 505-510 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Hammett-like Correlations between 13C-NMR Chemical Shifts and Substituent Constants on Aniles of p-Nitrocinnamaldehyde
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  • 55
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 417-421 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaktionen mit 3,1-Benzoxazin-4-onen. II. Verhalten von 6,8-Dibrom-2-methyl-3,1-benzoxazin-4-on in Friedel-Craft's und Grignard-Reaktionen6,8-Dibrom-2-methyl-benzoxazin-4-on (1) reagiert mit verschiedenen aromatischen Kohlenwasserstoffen unter Friedel-Crafts-Bedingungen zu O-Acetylaminobenzophenon-Derivaten 2.Die Reaktion von 1 mit Organomagnesiumhalogeniden führt durch Addition von einem Mol des Reagenzes zu den Ketonen 2 und 5 bzw. durch Addition von zwei Mol zu den Carbinolen 4. Diese unterliegen in einigen Fällen einer gleichzeitigen Dehydratisierung, die zu den Benzoxazin-Derivaten 6 führt.
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  • 56
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    Topics: Chemistry and Pharmacology
    Notes: Electrochemical Oxidation of Organic Compounds in Fluorosulfuric Acid. IV. Voltammetric Investigation of the Formation and of the Anodic Behaviour of Some Benzyl Cations and Arenium IonsThe anodic behavior of a series of benzylic alcohols, ethers or acetates 1-10, benzyl cyanides 11-21 and aromatic hydrocarbons 22-35 is investigated by cyclic voltammetry in fluorosulfuric acid at -76°C. The oxidation of the benzyl cations ArCH+2 formed from a part of the benzylic compounds leads at potentials by 0,7 to 0.8 V more positive than those of the neutral compounds with addition of SO3F- to stable cation radicals ArCH2OSO2F+. In a further oxidation step another CH3-group is functionalized to CH2OSO2F. The anodic peak potentials of the arenium ions are by about 1.1 V more positive than those of the nonprotonated hydrocarbons. The dissociation equilibrium of ArCH2OSO2F und the protonation equilibrium of the hydrocarbons are discussed in terms of the donor ability of the aromatic compounds at borderline cases.
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 429-436 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Analytical Problems of the Reaction between Polymer Supported Phosphino Groups and Methyl IodideA series of different crosslinked styrene-divinylbenzene-copolymers bearing diphenyl phosphinomethyl groups was reacted with methyl iodide in ethanol. The quaternization has been controlled by elementary analysis of P and I and by ir spectroscopy using a key band at 1123/cm. The spectroscopic method gave satisfactory results with sample amounts of 5 mg polymer in KBr discs. In resins containing up to 7% divinylbenzene the methylation was almost quantitative within 1 h refluxing. However, in highly crosslinked polymers ( 〉 10% DVB) containing residues of free chloromethyl groups and intraresin quaternized phosphino groups we observed side reactions in boiling ethanol. These could be avoided by performing the methylation in toluene at room temperature.
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 437-445 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α-Substituted Phosphonates. 43. Synthesis and Reactivity of 1,2,3,4-Tetrahydroisochinolin-1-phosphonatesN-Alkyl- and N-arylsubstituted 1,2,3,4-tetrahydroisochinolin-1-phosphonates 1 have been synthesized from the corresponding 3,4-dihydroisochinoliniumbromides 7 and triethyl-phosphite. The N-unsubstituted 1,2,3,4-tetrahydroisochinolin-1-phosphonate 10 is available starting from the 1,2,3,4-tetrahydroisochinolin-1-phosphonic acid by esterification with triethylformate and splitting off the formyl group of the primarily formed N-formyl derivative 14. - N-Quarternated tetrahydroisochinolines 19 and the 1-phosphorylated derivatives 17, respectively react with triethyl-phosphite in an unexpected way by dealkylation and not by splitting off the isochinolinring. - By Horner-synthesis with 1 the 1-aralkylidene-isochinolines 23 are available in moderate yields.
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  • 59
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    Topics: Chemistry and Pharmacology
    Notes: Photochemical Primary Processes of Xanthene Dyes. II. Investigations of the Influence of Anionic Micelles on the Primary Processes of Selenopyronine by Flash ExcitationIn aqueous solutions containing anionic micelles, the dye cations of selenopyronine are present at the micellar surface. If the concentration of the dye ions is much lower than the concentration of micelles, only monomolecular triplet decay (k1aM = 2 · 10-3s-1) is observed. Under these conditions, the half-oxidized and half-reduced form of selenopyronin is not formed. If the concentration of the dye ions is much higher than the concentration of micelles, two or more dye ions are present at every micelle, and a fast bimolecular decay of the triplet state during the flash is observed. The quenching of the triplet state with p-benzoquinone (k7aM = 1,9 · 109 l/mol s), DABCO (k10aM = 1,6 · 107 l/mol s) and EDTA (k11aM = 1,3 · 105 l/mol s) and the decay processes of the half-reduced and half-oxidized form in the micellar solution are investigated.
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 489-495 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On the Conformational Behaviour of Isomeric Phenyl Pyrimidines  -  Molecular and Crystal Structure of 5-Chloro-2-(4-n-hexyloxyphenyl)-pyrimidineThe title compound crystallizes in the triclinic space group P1 with a = 979.6(1) pm, b = 1048.8(3) pm, c = 1629.9(1) pm, α = 89.51(1)°, β = 100.62(1)°, γ = 71.50(1)° and four molecules per unit cell. The structure has been solved by direct methods and refined to a final R value of 0.058. The molecules adopt a fully stretched and nearly planar form and show a parallel arrangement in the crystal lattice. The results are discussed in relation to the conformational and mesomorphic behaviour of isomeric substituted phenyl pyrimidines.
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 496-500 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaktionen von [2.2]Paracyclophanen in Schmelzen. I. Reaktion von [2.2]Paracyclophan-4,5,12,13-tetracarbonsäuredianhydriden mit Phenylessigsäure und N-ArylcarbamatenThe parent hydrocarbon [2.2] paracyclophane (1) exhibits transanular electronic interaction and the two benzene rings behave as dependent π system towards the chemical reactions [1a-c]. We wish to study the effect of transanular electronic interaction on the chemical behaviour of the an hydride moity in 2[2a-d]. It has been reported that 2 is less reactive in comparison with phthalic anhydride, since an attempted conversion of 2 into a tetraester failed [2b] The reaction in melts between phtahlic anhydride, pryomillitic acid dianhydride (3) and carbamates yields the corresponding imides [3].
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 517-520 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine neue Synthese für 2- und 4-Cyclopropylpyridine
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 521-523 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Catalyzed Liquid-Phase Oxidation of cis- and trans-β-Methylstyrene
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 525-525 
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    Keywords: Chemistry ; Organic Chemistry
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 524-525 
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    Keywords: Chemistry ; Organic Chemistry
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 849-852 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyanoethylation of HydroquinazolinonesBy the reaction of acrylonitrile with octahydroquinazolinone-spirocyclohexane (1), cyanoethyl-octahydroquinazolinone-spirocyclohexane (2) is formed. Compound 2 and hydrogen-peroxide yield 5a-cyanoethyl-5-oxo-perhydro-oxaziridino[3,2-j]-quinazolin-2-spirocyclohexane (5). 2-Phenyl-octahydroquinazolinone (7) and acrylonitrile form 3,5a-biscyanoethyl-2-phenyl-octahydroquinazolinone-(4) (8). Compound 8 and hydrogenperoxide yield 3-phenyl-4,5a-biscyanoethyl-4-oxoperhydro-oxaziridino[3,2-j]-quinazoline (9). Compound 9 rearranges with ferrous sulphate to 3,4a-bis-cyanoethyl-4-oxo-8a-hydroxy-2-phenyl-octahydro-quinazoline (10).
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 876-892 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: About the Photochromic and Thermochromic Effect of Benzil PhenylhydrazonesBenzil phenylhydrazone 1 synthesized from benzil and phenylhydrazine possesses s-trans-E configuration detected by means of quantum chemical calculations and its spectral data. Upon irradiation a photochromic process proceeds with a λ-shift Δ λ ≈ 80 nm. The photoproduct has an s-cis-Z configuration. The quantum yields of the EZ-isomerization measured by spectroscopic methods depend on solvent (ΦEZ= 0,077 in CH3OH, ΦEZ= 0,22 in n-hexane), but are independent of the excitation wavelengths and O2. Benzil N-methylphenylhydrazone 2 is inactive under stationary irradiation. Both the Z/E-isomerization of 1 and 2 are be sensitized by benzil and m-methoxyacetophenone. On the basis of kinetic measurements the quantum yields of sensitized reactions of 1 are calculated (ΦEZsens = 0,43; ΦZEsens = 0,57). In protic solvents benzil phenylhydrazone 1 has thermochromic properties caused by E/Z-isomerizations. The measured activation parameters of these reactions are small. It is assumed that both the photoinduced and thermal isomerizations proceed via azo intermediates, as indicated by flash photolysis experiments.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 899-909 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photooxidation of Leuco Dyes. VIII. Time Resolved Investigations of the Mechanism of the Photooxidation of Leucocrystal VioletThe photooxidation of leucocrystal violet has been reexamined by means of conventional and laser flash photolysis as well as spin trap experiments. Three radical transients have been observed and assigned to the cation radical (λmax ≈ 490, 530 nm), the neutral radical with one—NCH3—CH2 moiety (λmax ≈ 480 nm) and the triphenyl methyl radical derivative (λmax ≈ 400 nm).
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 545-550 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kinetic Studies on the Autoxidation of OlefinsThe oxidabilities \documentclass{article}\pagestyle{empty}\begin{document}$ {{{\rm k}_{\rm p} } \mathord{\left/ {\vphantom {{{\rm k}_{\rm p} } {\sqrt {2{\rm k}_{\rm t} } }}} \right.\kern-\nulldelimiterspace} {\sqrt {2{\rm k}_{\rm t} } }} $\end{document} at 50°C were determined for 37 olefins, using chlorobenzene as the solvent and azodiisobutyronitril as the initiator. In the group of acyclic aliphatic olefins the oxidability rises with increasing number of alkyl groups bound to the double bond. This is also true for cyclic olefins, but in this case the ring size has also a great influence on the oxidability. So the oxidability decreases from five-ring to eight-ring cycloolefins. Particularly high oxidabilities are found in the case of olefins in which a phenyl group is attached directly to the C—C-double bond.
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 551-560 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-α-Bromacetyl-coumarines as Synthones for Heterocyclic Substituted Coumarines3-α-Bromacetyl-coumarines 2 react easily and in high yields with thiourea and thioamide derivatives 3 and 5, resp., to 4-coumar-3′-yl-thiazoles 4 and 6, resp., as well as with N,N-disubstituted thioamides 11 and N,N,N′,N′-tetraalkylthiourea 12 to 5-coumar-3′-yl-oxathioliumsalts 13 and 14, respectively. In a two-step reaction 2 can be transformed by reaction with aniline 17 to 4-coumar-3′-yl-imidazoles 21 and 5-coumar-3′-yl-oxazoliumsalts 22, resp., via aminoketone intermediates 18.
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    Notes: Determination of Configurations by the Aid of Sterically Corresponding Epoxides. VIII. Glycidic Nitriles. I. Synthesis of 4-Aryl-1-oxaspiro(2,5)octane-2-nitriles and 4-Aryl-1-oxaspiro(2,5)octane-2-carboxylic Acid Methyl EstersThe condensation of 2-aryl-cyclohexan-1-ones (1-5) with ClCH2CN or ClCH2CO2CH3 at 80°C in the presence of NaH and in dimethoxyethane yields the corresponding glycidic nitriles and the glycidic esters, respectively. The configuration and the preferred conformation of the two isomeric 1-oxaspiro-[2,5]octane derivatives (12 A and 12 B) formed have been determined by 1H-n.m.r. spectroscopy. Some earlier results from BOEKELHEIDE and SCHILLING and from SCHWARTZMAN and WOODS have been corrected.
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    Notes: Partial Syntheses of Cardenolides and Cardenolide Analogues. VI. (20R)- and (20S)-Cardanolides(20R)-Dihydrodigitoxigenin (2) and (20S)-dihydrodigitoxigenin (4) as well as their 3-acetates 3 and 5, respectively, were synthesized by catalytic hydrogenation of the appropriate cardenolides and separation by column chromatography on silica of the mixtures of stereoisomers. Hydroxymethylation of 3 and 5 followed by selective elimination yielded (20S)- and (20R)-14-hydroxy-22-methylene-5β,14β-cardanolide 3-acetate (10 and 16), respectively.The biological activities of the synthesized 20-stereoisomeric cardanolides are investigated and discussed. Cardanolides 10 and 16 have a strong inhibitory activity on the proliferation of Ehrlich ascites carcinoma cells in suspension culture.
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    Notes: Partial Syntheses of Cardenolides and Cardenolide Analogues. VII. Synthesis of A/B-cis- and C/D-cis-linked Steroidal Mono- and Bis (α-methylene-γ-butyrolactones)The synthesis of A/B-cis- and C/D-cis-linked steroidal mono- and bis(α-methylene-γ-butyrolactones) 10-13, 18 and 24 by Reformatsky-type reaction of 3β-acetoxy-14-hydroxy-5β, 14β-androstan-17-one( 6), 14-hydroxy-5β, 14β-androstane-3,17-dione (8), 3β-acetoxy-14-hydroxy-5β,14β-pregnan-20-one (17) and 14-hydroxy-5β,14β-pregnane-3,20-dione (23), respectively, with ethyl α-(bromomethyl)acrylate is described. All steroidal lactones exhibit strong inhibitory activity on the proliferation of Ehrlich ascites carcinoma cells in suspension culture. For inhibitory activity the lactone moiety at C-17 of the steroid molecule is more important than the lactone moiety at C-3 and C-20, respectively.
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 607-611 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Partial Syntheses of Cardenolides and Cardenolide Analogues. IX. Cardenolide Derivatives with an Unsaturated Aldehyde Function at the Lactone RingOxidation of 22-allyl-digitoxigenin-3-acetate [1] and 22-allyl-digitoxin (4) with selenium dioxide resulted in the introduction of an oxygen function into the unsaturated C-22 substituent of the cardenolide molecule. The isolated compounds were the 22-(3′-oxo-prop-1′-en-1′-yl)-derivatives 3 and 6 of 1 and 4, respectively. The molecular biological activity of 3 was estimated to be about six times higher than that of the parent compound 1.
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  • 75
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    Topics: Chemistry and Pharmacology
    Notes: Partial Syntheses of Cardenolides and Cardenolide Analogues. VIII. Lactone Ring-Alkylated CardenolidesBase-catalyzed alkylation of digitoxigenin (1), digitoxin (2), digoxigenin (3), and gitoxigenin-3,16-diacetate (4) with allyl bromide, allyl chloride or n-propyl bromide in DMF resulted in the formation of the 22-allyl-, 21ξ,22-diallyl-, 22-propyl-, and 21ξ,22-dipropyl-derivatives 5-14, respectively.The determination of the molecular biological activity of the derivatives yielded valuable information.
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  • 76
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 612-626 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Electrochemical Oxidation of Organic Compounds in Fluorosulfuric Acid. V. Anodic Behaviour of Aromatic Nitrocompounds, Nitriles, Amines, Acetamides, and OximesThe anodic behaviour of a series of methyl substituted nitrobenzenes, benzonitriles, aniline derivatives, acetanilides and acetophenone oximes was investigated by cyclic voltammetry at platinum electrodes in HSO3F at -76°C. With the exception of the parent compounds and partly of the monomethyl derivatives relatively stable cation radicals could be detected. In a second anodic wave in many cases the functionalization of a CH3-group to CH2-OSO2F took place. From a comparison of the peak potentials and from the dependence of the voltammetric curves on the scan rate follows that the aniline derivatives are oxidized without deprotonation of the -NH3+ group, whereas for the nitrocompounds, nitriles and acetanilides a deprotonation of the functional group is coupled with the oxidation, and the cation radicals are stable onyl in the deprotonated state. A kinetic study of the subsequent reaction of some nitrocompounds was made and the deviating behavior of some acetanilides was found to be due to the anodic dimerization to benzidine derivatives.
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  • 77
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 699-707 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On the Pyrolysis of Pent-1-ene-4,4,5,5,5-d5The distribution of deuterium in the main products of thermal decomposition of pent-1-ene-4,4,5,5,5-d5 at 550 to 650°C was studied and interpreted. The results include conclusions on kinetic isotope effects, on relative reactivities of different C-H-bonds, on the proportion of terminal and nonterminal addition of methyl radicals, and on the importance of a radical isomerisation reaction. It was shown that the molecular decomposition (Retro-En-Reaction) cannot successfully compete with the radical way in the temperature range above 600°C
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  • 78
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    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 729-741 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Pyrylium Compounds. XVIII. 2-Alkoxy-2H-pyrans from Tetra- and Pentasubstituted Pyrylium SaltsAlkali alkoxides add regioselectively to 2,3,4,6-tetrasubstituted pyrylium salts 7 (R'= H), affording high yields of colourless crystalline 2-alkoxy-2H-pyrans 9. The latte are also formed simply on refluxing 7 in the corresponding alcohol with triethylamine as proton acceptor. 3,5-Dialkylsubstituted 2,4,6-triarylpyrylium salts react analogously. The 2H-pyran structure of the adducts obtained follows from their n.m.r., i.r., u.v. and mass spectra as well as from their reaction with tetracyanoethylene to cycloadducts of type 10. Acids regenerate from 9 the original pyrylium cations, whereas reaction of 9 with nitromethane or ethyl cyanoacetate provides benzene derivatives. -- The novel starting pyrylium salts 7b--o are characterized by u.v./vis data and by transformation into the corresponding pyridine derivatives
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  • 79
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    Keywords: Chemistry ; Organic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: On the Conformational Behaviour of Substituted Phenylbenzoates - Molecular and Crystal Structure of the Nematogenic Compound 4′-(ß-Cyanoethyl)-phenyl-4-n-pentoxybenzoateThe title compound crystallizes in the monoclinic space group P21/n with a = 1567.6(2) pm, b = 915.5(1) pm, c = 1459.1(1) pm, β = 115.30(1)°, and four molecules per unit cell. The structure has been solved by direct methods and refined to R = 0.104. The molecules adopt a markedly stretched form and show a parallel arrangement of their long axes in the crystal lattice. The molecular and crystal structure is discussed in relation to the mesomorphic behaviour of the compound.A theoretical conformational analysis has been performed for the isolated phenylbenzoate molecule using the EPEN/2 method, its results are compared with the experimental torsion angles in a series of substituted phenylbenzoates.
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  • 80
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photoinduced Decomposition of Arene Diazonium Salts by Metal OxalatesArene diazonium salts were decomposed by the irradiation of K3[Fe(oX)3] and K3 [Co(ox)3]. The dediazonation is caused by electron transfer reactions between ·CO-2 and in the case of the former complex also by [Fe(ox)2]2- -species. As intermediates aryl radicals were found by spin trapping with nitroso durene. The dediazonation quantum yields (0,15--1,21) depend on the reduction potentials of the salts and on the oxalate concentration. By electron acceptor substituted diazonium salts the values are the same as those of the K3[Fe(ox)3]-actinometer. In the case of p-dialkylaminobenzene diazonium salt-types an electron transfer takes places with ·CO-2 only whereas the reaction with [Fe(ox)2]2- is neglectable. A Hammett-correlation for the electron transfer of Fe(II)-species with a ϱ-value of 1.7 was found. The investigated systems are efficient initiators of the photopolymerization.
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  • 81
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    Keywords: Chemistry ; Organic Chemistry
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  • 82
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 360-366 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Preparation of β-Substituted trans-Ethylene Diphenylphosphines and Sulphides by P(0) and P(S)-activated OlefinationMethylene bis-diphenylphosphine monoxide (3c) in tuluene reacts regiospecifically and stereoselectively with aldehydes in the presence of potassium tert-butoxide to ß-substituted transethylene diphenylphosphines 6, which can be oxidized to the sulphides 2 by sulphur in acetone. These sulphides 2 are to be obtained also directly from methylene bis-diphenylphosphine oxide sulphide 3b and methylene bis-diphenylphosphine disulphide 3d, respectively, under the same olefination conditions. But the yields are smaller and the purification of the raw products is much more difficult, if 3d is used.
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  • 83
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 599-604 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The present work deals with the synthesis of 6-aryl-2-ethoxycarbonyl pyridazin-3(2H)-ones (2) as useful synthetic intermediates because they allow formation of a new hydrazides (3), hydrazidoyl chlorides (4) and the highly reactive nitrile imine species (5). Dimerization and reaction of the latter species with benzonitrile, benzaldehyde and their p-methoxy and p-nitro derivatives provides a convenient method for the synthesis of substituted 1, 2, 4, 5-tetrazines (6), 1, 2, 4-triazoles (7) and 1, 3, 4-oxadiazoles (8), respectively, with pyridazin-3(2H)-one moiety.
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  • 84
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 737-746 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyanic Acid Esters. 35. On Formation and Consecutive Reactions of N-Cyanato Phthalimide. New Specifically Activated and Blocked Isatoic Acid DerivativesDepending on the reaction conditions N-hydroxy-phthalimide affords on treatment with cyanogen bromide via N-cyanato phthalimide 2 the iminocarbonate 3 and isatoic acid derivatives 7 and 16. Both the latter react with nucleophiles as isatoic acid derivatives activated on the carboxylic group and protected on the carbamic group or vice versa, furnishing N,N-bis alkoxycarbonyl anthranilic acid amides 9, N-alkoxycarbonyl anthranilic acid amides 12, o-alkoxycarbonyl phenyl ureas 17 and the benzotriazepin-2,5-dione 14. The structures of the new compounds are proved by 1H-n.m.r. and 13C-n.m.r. measurements as well as independent synthesis.
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  • 85
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Deactivation Behaviour of Arenes and Heteroarenes. XLI. Structural and Environmental Effects on the Intramolecular [π4s + π4s]- Photocycloaddition Reaction of α, ω-Bis-(9-acridiziniumyl) - alkanes.Fluorescence characteristics, including quantum yields and decay times, and quantum efficiencies for the reversible intramolecular [π4s + π4s]- photocycloaddition reaction for a series of α, ω-bis-(9-acridiziniumyl)-alkanes have been measured in several solvents and they have been compared with those of the model compounds acridizinium-ion. and 9-methyl-acridizinium-ion. These parameters of the bichromophores depend on the number of CH2-groups of chromophor linkage. The title compounds investigated were divided into groups of common behaviour, and differences are due to increasing bond angle strain and coulomb-repulsion in the photocyclomer state.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 779-790 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On the Catalytic Dimerization of Acrylic Acid Derivatives by Palladium Complexes. IV. The Dimerization of Methyl Methacrylate.Methyl methacrylate has been dimerized to a mixture of 2.5-di(methoxycarbonyl)-hex-1-ene(1) and (E)-2.5-di(methoxycarbonyl)-hex-2-ene (2) by catalytic systems containing dichlorobis (nitrile)-palladium (II) complexes and silver tetrafluoroborate, Codimerization experiments with methyl acrylate show a lower reactivity of methyl methacrylate. Oxidative addition of ß-chloro methyl methacrylate to tetrakis (triphenylphosphine) palladium (O) gave ß-polladio methyl methacrylates (8, 9) suitable for model investigations of the catalytic reaction. A proposal is given for a mechanism via pd(IV) intermediates.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 811-816 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 804-810 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass Spectrometric Fragmentation of 4-Substituted 5-Hydroxynaphth[2,1-d]1,3-oxathiol-2-onesThe mass spectra of 5-hydroxynaphth[2,1-d]1,3-oxathiol-2-ones 1a-1x have been studied. They show characteristic fragmentations with participation of neighbouring groups. Investigations of isotopically labelled 4-alkyl and 4-acyl derivatives give evidence for the formation of cyclic ionic structures.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 823-828 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Dependence of UV-Spectra of Substituted Naphthalenesulfonic Acids upon the pH-Value - A Contribution in Order to Elucidate the Structure of Acid Azo Dyes
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 910-916 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A detailed kinetic analysis is presented of the transient sultone (A2) formation which proceeds thermally from a photogenerated intermediate species after flash excitation of bromo thymol blue and bromo xylenol blue in the presence of quinoline, pyridine and 4-methyl pyridine in toluene solution. The sultone ring cleavage is a bimolecular reaction with the base resulting in a hydrogen-bridged molecular complex (A1) which equilibrates consecutively with the most stable rotamer of the ion pair (A3). The rate constants for the latter reaction are controlled essentially by conformational changes rather than by the proper proton transfer.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 924-934 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Diels-Alder-Reactions. IX. On the Formation and the Thermolysis of Isomeric TricyclopentadienesThe formation of isomeric tricyclopentadienes by codimerisation of cyclopentadiene with endo- and exo-dicyclopentadiene between 100 and 140°C in the liquid phase, and the retrodiene reaction of the main isomeres of the tricyclopentadiene fraction by gas phase thermolysis were studied kinetically between 230 and 310°C. The rate constants and the parameters of activation were determined.
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  • 92
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 941-946 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 10β;-Chloro-estra-1,4-dienes as Intermediates of the Introduction of a 9(11)-Double Bond in Estra-1,3,5(10)-trienesThe synthesis of 9(11)-didehydro-estra-1,3,5(10)-trienes 5 starting from estra-1,3,5(10)-trienes 1 is described. 1 can be transformed into the ketals 2 and 3 by means of isocyanuric acid chloride and an alcohol such as methanol or ethylene glycol in the absence of moisture.The ketals 2 and 3 are sensitive against hydrolysis and react in the presence of water and traces of acid under formation of chlorodienone 4. Dehydrochlorination of 2, 3 and 4 with potassium-tert.-butylate in dimethylsulfoxide gives the 9(11)-didehydro compounds 5. The reaction mechanism of the electrophilic addition of positive chlorine and alcohol to the aromatic A-ring of 1 is discussed.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 955-961 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Pyrylium Compounds. XXV. Quantum Chemical Calculations Concerning the Valence Isomerization of 2-Amino-2H-pyran and -thiopyranThe equilibrium 2-amino-2H-pyran 6 ⇌ 5-amino-2,4-dien-1-one 7 was investigated using the semi-empirical MINDO/3 and MNDO methods. In accordance with experimental findings for the substituted derivatives 1/2a-d, the introduction of a methyl group into the position 3 of 6 or the exchange of oxygen by sulfur shifts the equilibrium towards the cyclic structures 8 and 10, respectively. Polar solvents, the influence of which was estimated applying the reaction field approach as well as the solvaton theory, and entropy effects are calculated to favour the ring-open valence isomer 7. These results also correspond to experimental results.
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  • 94
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    Topics: Chemistry and Pharmacology
    Notes: Photocatalytical Systems. LXIV. Theoretical Investigations of the Charge Transfer and of the Photochemical Reactivity of d6 Transition Metal Complexes with π Acceptor LigandsQuantum chemical investigations concerning the charge transfer interactions between a d6 complex fragment and heterocyclic nitrogen ligands are reported. The influence of inductive, mesomeric and steric effects on the π acceptor ability of the isolated ligand and on the electronic structure of the pentacyano-ferrate(II) mixed ligand compounds has been investigated and possibilities to sensitize spectrally the Fe(CN)5L3- system (L= pyridine-type ligand) with regard to their photochemical reactivity are discussed.
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  • 95
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    Keywords: Chemistry ; Organic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Investigations of the Photo-Fading of Tautomeric Azo Dyes. VI. The Photochemical Oxidation by Singlet Oxygen of Phenylazoacetylacetones and PhenylazopyrazolonesThe dye-sensitized photo-oxidation by singlet oxygen of phenylazoacetylacetones (1) and Phenylazopyrazolones (2) has been investigated. The photo-fading of dyes is accelerated in the presence of Methylene Blue, a sensitizer of singlet oxygen, in airsatured methanolAn excellent relationship exists between the fading-rate of a series of dyes (1) and Hammett-σ-constants. An unexpected trend was found for photo-fading of a series of dyes (2). The Hammett plot consists of two parts, with a negative slope derived from electron-releasing substituents and a positive slope derived from electron-withdrawing substituents. The anomalous photo-fading is due to an attack of singlet oxygen on the more reactive anion of the phenylazopyrazolones in the case of electron-withdrawing substituents. In methanol containing acetic acid the dyes (2) exist only as the hydrazone tautomers. Under these conditions the fading-rate show a linear relationship with σ-constants.
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 994-998 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 1008-1010 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 1016-1020 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Prostaglandins and Prostaglandin Intermediates. XI. Synthesis of Optically Active Bicyclic Lactones - Convenient Intermediates for 8-Methyl Prostaglandins
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 1027-1033 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quinazoline Carboxylic Acids. III. Quinazolin-4-on-3-benzoic Acids and Esters
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    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 1034-1036 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fluorescence Properties of Polymethine Dyes with Bridged Chains
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