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  • Articles  (2)
  • nylon  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 11 (1987), S. 71-88 
    ISSN: 0308-0501
    Keywords: Combustion products ; literature reviews ; nylon ; pyrolysis, thermal decomposition ; toxicity ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The literature on polyamides was reviewed to determine the nature and extent of information available on these materials which are commonly used in consumer and industrial applications. This review was limited to aliphatic polyamides normally called nylon and excludes aromatic polyamides such as Nomex and bicomponent polymers consisting of nylon and other polymers. The review was further limited to those publications in English through June 1984. Typical pyrolysis products from a broad range of nylons do not appear to differ greatly. Many of the decomposition products detected in vacuum pyrolysis experiments appear as products of thermal degradation in inert and air atmospheres. In air, a general reduction in the quantities of heavier hydrocarbons is noted along with an increase in the production of CO, CO2, H2O, NH3, HCN and NOx. The toxicity of the thermal degradation products from various types of nylon has been evaluated by nine different protocols. Reported LC50 values range from 10.8 m l-1 to 61.9 mg l-1. Dyes apparently do not affect the materials' combustion products toxicity but an increase in the amount of backcoating on a nylon fabric increases toxicity. Time to death measurements show that volatile products from nylons are less toxic than those from rayons or cotton, while the blending of wool with nylon greatly increases the toxicity of the thermal decomposition products. In general, however, the overall toxicity of the thermal degradation products from nylon do not appear to be greatly different than those from many other polymeric materials. Large-scale test results are ambiguous, and it is difficult to interpret the results in terms of a single component in a multicomponent system.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0308-0501
    Keywords: ABS ; plastics ; chemistry ; combustion products ; literature reviews ; nylon ; polyester ; polyethylene ; polystyrene ; polyvinyl chloride ; pyrolysis products ; polyurethane foams ; rigid foams ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of literature reviews was undertaken by the National Bureau of Standards to examine the toxicity and chemistry of the effluents produced when seven plastics were decomposed under various thermal and atmospheric condition. These plastics are: acrylonitrile-butadiene-styrenes, nylons, polyesters, polyethylenes, polystyrenes, poly(vinyl chlorides) and rigid polyurethane foams. The English-language literature on each of these was reviewed and published as a separate report of the National Bureau of Standards. Over 400 different thermal decomposition products, many common to more than one plastic, were identified. The toxicity of most of these individual products is products, many common to more than one plastic, were identified. The toxicity of most of these individual products is unknown and an assessment of the toxicity of the multitude of possible combinations is not feasible at this time. Therefore a variety of bioassay toxicity protocols have been used to assess the toxicity of the gaseous atmospheres generated by the thermal decomposition of these plastics. In general, these seven plastics did not produce unusually or extremely toxic pyrolysis or combustion products when compared with those of other synthetic or natural materials. In a few cases involving additives, toxic products of concern were produced.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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