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  • Organic Chemistry  (6,042)
  • SPACE SCIENCES
  • Seismicity
  • 1990-1994  (4,912)
  • 1940-1944  (1,525)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 142 (1994), S. 545-565 
    ISSN: 1420-9136
    Keywords: Seismicity ; cellular automata ; fracture mechanics ; b values ; complexity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We present a cellular automaton model which simulates the process of seismogenesis using rules for evolution which are derived from the field of fracture mechanics, and include an interplay of positive and negative feedbacks. We describe the implementation of this model, and its analysis, in a massively parallel environment using the Connection Machine. Starting from a lattice with a fractal distribution of fracture toughnesses, theb value evolves in a way which closely mimics both the evolutions ofb value observed in the laboratory and derived from earthquake catalogues, reaching a broad and irregular maximum in the period preceding a major event, and declining rapidly during catastrophic failure. We conclude that the processes modelled are a reasonable representation of those occurring in Nature, and that the cellular automaton paradigm is a valuable way of simulating these processes on a large scale in an economical manner.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 138 (1992), S. 569-589 
    ISSN: 1420-9136
    Keywords: Seismicity ; slide-blocks ; chaos ; earthquakes ; fractals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We present a systematic analysis of the dynamical behavior introduced by fault zone heterogeneities, using a simple mass-spring model with velocity-weakening friction. The model consists of two sliding blocks coupled to each other and to a constant velocity driver by clastic springs. The state of this system can be characterized by the positions of the two blocks relative to the driver. Symmetry stabilizes the system and generates only cyclic behavior. For an asymmetric system where the frictional forces for the two blocks are not equal, the solutions exhibit chaotic behavior. The transition from stable cyclic behavior to chaos is characterized by the period-doubling route to chaos. Lyapunov exponents are computed to quantify the deterministic chaos and to locate the onset of the chaotic evolution in parameter space. In many examples of deterministic chaos, chaotic behavior of a low-order system implies chaos in similar higher order systems. Thus, our results provide substantial evidence that crustal deformation is an example of deterministic chaos.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 136 (1991), S. 449-458 
    ISSN: 1420-9136
    Keywords: Seismicity ; focal mechanism ; intraplate earthquakes ; Bolivia ; Andean Cordillera ; seismotectonics ; South America
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Intraplate seismic activity in Bolivia is mainly located in the central region (16°–19°S, 63°–67°W) which includes the East Andean Cordillera and the Sub-Andean Sierras. At this region there is a bend in the trend of the main geological structures from NW-SE in the north to N-S in the south. Focal mechanisms have been calculated for 10 earthquakes of magnitudes 4.9–5.6, using first motionP-waves from long period instruments. Their solutions correspond to reverse faulting, some with a large component of strike-slip motion. Their solutions can be grouped into two types; one with pure reverse faulting on planes with azimuth NW-SE and the other with a large strike-slip component on planes with azimuths nearly N-S or WNW-ESE. The maximum stress axis (P-axis) is practically horizontal (dipping less than 5°) oriented in a mean N56°E direction. This orientation may be related with the direction of compression resulting from the collision of the Nazca plate against the western margin of the South American continent. Wave-form analysis of long-periodP-waves for one event restricts the focal depth to 8 km in the Sub-Andean region. Seismic moments and source dimensions determined from spectra of Rayleigh waves are in the range of 1016–1017Nm and 17–24 km, respectively. The Central Bolivia region can be considered as a zone of intraplate deformation situated between the Bolivian Altiplano and the Brazil shield.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 142 (1994), S. 419-445 
    ISSN: 1420-9136
    Keywords: Seismicity ; fracture ; elastodynamics ; friction ; earthquakes ; boundary integral equations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We discuss the effects of rate-dependent friction on the propagation of seismic rupture on active faults. Several physicists using Burridge and Knopoff's box and spring model of faulting have proposed that fault complexity may arise from the spontaneous development of a self-similar stress distribution on the fault plane. If this model proves to be correct, it has important consequences for the origin of the complexity of seismic sources. In order to test these ideas on a more realistic earthquake model, we developed a new boundary integral equation method for studying rupture propagation along an antiplane fault in the presence of nonlinear rate-dependent friction. We study rupture dynamics of models with single and twin asperities. In our models, asperities are places on the fault with a higher value of prestress. Othewise all fault parameters are homogeneous. We show that for models with such asperities, a slip velocity weakening friction leads to the propagation of supersonic healing phases and to the spontaneous arrest of fracture if the prestress outside the asperities is low enough. For models with asperities, we can also observe narrow slip velocity pulses, qualitatively similar to the so-called Heaton pulses observed in some earthquake accelerograms. We also observe a complex distribution of stress after the rupture that depends on details of the initial distribution of asperities and on the details of the friction law.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 140 (1993), S. 317-330 
    ISSN: 1420-9136
    Keywords: Seismicity ; spatio-temporal variations ; seismic gaps ; southern Peru ; northern Chile
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The spatio-temporal variation of seismicity in the southern Peru and northern Chile seismic gaps is analyzed with teleseismic data (m b ≥5.5) between 1965 and 1991, to investigate whether these gaps present the precursory combination of compressional outer-rise and tensional downdip events observed in other subduction zones. In the outer-rise and the inner-trench (0 to 100 km distance from the trench) region, lower magnitude (5.0≤m b 〈5.5) events were also studied. The results obtained show that the gaps in southern Peru and northern Chile do not present compressional outer-rise events. However, both gaps show a continuous, tensional downdip seismicity. For both regions, the change from compressional to tensional regime along the slab occurs at a distance of about 160 km from the trench, apparently associated with the coupled-uncoupled transition of the interplate contact zone. In southern Peru, an increase of compressional seismicity near the interplate zone and of tensional events (5.0≤m b ≤6.3) in the outer-rise and inner-trench regions is observed between 1987 and 1991. A similar distribution of seismicity in the outer-rise and inner-trench regions is observed with earthquakes (m b 〈5.5). In northern Chile there is a relative absence of compressional activity (m b ≥5.5) near the interplate contact since the sequence of December 21, 1967. After that, only a cluster of low-magnitude compressional events has been located in the area 50 to 100 km from the trench. The compressional activity occurring near the interplate zone in both seismic gaps represents that a seismic preslip is occurring in and near the plate contact. Therefore, if this seismic preslip is associated with the maturity of the gap, the fact that it is larger in southern Peru than in northern Chile may reflect that the former gap is more mature than the latter. However, the more intense downdip tensional activity and the absence of compressional seismicity near the contact zone observed in northern Chile, may also be interpreted as evidence that northern Chile is seismically more mature than southern Peru. Therefore, the observed differences in the distribution of stresses and seismicity analyzed under simple models of stress accumulation and transfer in coupled subduction zones are not sufficient to assess the degree of maturity of a seismic gap.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 132 (1990), S. 311-329 
    ISSN: 1420-9136
    Keywords: Seismicity ; codaQ ; Q variations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Seismicity in the La Cerdanya region of the eastern Pyrenees has been accurately mapped for the first time using data from a local seismic network. The majority of earthquakes lies on or near the La Cerdanya fault or secondary faults to the south. Coda magnitudes determined for these earthquakes, using magnitude relations from other regions, range between −0.5 and 2.2. These are, however, presumed to be underdetermined values sinceQ values appear to be very low in the La Cerdanya region. CodaQ values at a frequency of 1.5 Hz range between 17 and 120, the lowest values being obtained for the most seismically active regions. CodaQ values also increase with increasing distance, a result which indicates decreasing seismic attenuation with increasing depth in the crust.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effect of substituents (X = H, Me, or F at C(6), R = H or Me at C(2′) of the allyl side chain) on the photoisomerization (λ = 350 nm) of 6-allylcyclohex-2-enones 1 in MeCN is studied. Substituents X control the overall efficiency of intramolecular [2 + 2] photocycloadduct formation (Φ: Me 〉 F 〉 H) but do not exercise an influence on the orientation of addition of the exocyclic double bond to the enone C=C bond. In contrast, replacement of the prop-2-enyl (R = H) by a 2-methylprop-2-enyl (R = Me) side chain causes a change in the tricyclo[3.3.1.02,7]nonan-6-one 4 vs. tricyclo[4.2,1.03,8]nonan-7-one (5) product ratio from 100:0 (R = H) to roughly 2:1 (R = Me) but has almost no bearing on the relative rates of conversion of 1 to products. For C(6)-unsubstituted enones 1aa and 1ba (X = H), the efficiency of cyclization becomes low enough so that lumiketone rearrangement to bicyclohexanones 6 and 3-isopropylcyclopent-2-enones 9 becomes competitive. Enones 9 undergo consecutive intramolecular [2 + 2] photocycloaddition to tricyclo[3.2.1.03,6]octan-2-ones 7 and to tricyclo[3.2.1.03,6]octan-7-ones 8, compounds 8 only being formed when R = Me.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Substituent, Heteroatom, and Solvent Effects on the Thermal-Bleaching Kinetics and Absorption Spectra of Photomerocyanines Issued from Spiro[indoline-oxazines]Quantitative information useful for the development of new photochromic systems is obtained from the study of heteroatom and substituent effects on the thermal-bleaching kinetics and the absorption spectra of the photomerocyanines issued from spiro[indoline-oxazines]. The effect on photochromic properties of the presence of N-atoms either in the dimethine bridge or in the aromatic rings has been investigated through the comparison of spiro[indoline-naphthopyrans] C with spiro[indoline-naphthoxazines] A and with spiro[indoline-quinolinoxazines] B. Besides the occurrence of biexponential thermal-bleaching kinetics in non-polar solvents is observed: a tentative explanation for this observation is given which involves the formation, in either sequential or parallel steps, of energetically distinct stereoisomers of the opened form.
    Additional Material: 3 Ill.
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  • 9
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the electron transfer between reduced spinach [2Fe-2S]-ferredoxin and the optically active complexes [Co((R,R)- or (S,S)-alamp)py]+ (I), [Co((R,R)- or (S,S)-promp)H2O]+ (IIa), and [Co((R,R)- or (S,S)-promp)py]+ (IIb) have been investigated. The reactions are stereoselective, and for I and IIa, the Stereoselectivity strongly depends on temperature due to large differences in the activation enthalpy between enantiomeric reagents. Isokinetic behaviour is observed between enantiomers, the ΔΔHΔ-Λ# values being largely compensated by the ΔΔSΔ-Λ# values. The compensation behaviour is explained by the combination of stereochemical interactions and desolvation processes on formation of the precursor complex or the transition state.
    Additional Material: 5 Ill.
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  • 10
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A stereocontrolled synthetic route to optically pure (-)-(S)-ipsenol (1), the pheromone of Pityokteines curvidens and various other bark-beetle species is described. Key step of the synthesis is an enantioselective aldol reaction using a chiral titanium-carbohydrate complex (Scheme 1). The carboxylate function of the optically pure β-hydroxy acid 5 thus obtained in mol quantities is then elaborated to the diene moiety by standard methodology (Scheme 2).
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