ISSN:
0009-2940
Schlagwort(e):
Molecule-induced radical formation, kinetics of
;
Catalysis
;
ESR spectroscopy
;
Radical clock
;
Isokinetic relationship
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Bimolecular Formation of Radicals by H-Transfer, 7[1]. - Bimolecular Formation of Radicals via H-Transfer with Catalysis by 7H-Benz[de]anthraceneThe transfer hydrogenation of α-methylstyrene (2) by 9,10-dihydroanthracene (1) (DHA) with 7H-benz[de]anthracene (8) as a catalyst proceeds already at 210-260°C. Isotopic labeling, ESR spectroscopy, radical clock experiments, solvents effects, and thermochemical calculations support the postulated stepwise radical mechanism induced by bimolecular formation of radicals.
Zusätzliches Material:
4 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19941270419
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