ALBERT

Description: Abstract The famous association of metagabbros, eclogites, glaucophanites, jadeite rocks and ultramafics from the island of Syros forms a distinct lithostratigraphic or tectonic unit. It is interpreted as a high-pressure metamorphic ophiolite suite. This paper provides geochemical and Sr-isotope constraints on the geotectonic setting in which the magmatic protoliths of the Syros metabasites were formed. A compositional gap exists between the metagabbros with Mg-numbers [Mg# = Mg/(0.85Fetot + Mg) atomic ratio] of 0.75-0.88 on the one hand and eclogites and garnet-glaucophanites on the other hand with Mg# of 0.35-0.62, and maximum total iron contents of up to 18 wt.% FeOtot. Metagabbros from various localities and glaucophanites collected around Manna form geochemically coherent groups with smooth correlations between compatible as well as immobile incompatible elements and Mg#. By contrast, the behaviour of immobile incompatible elements, and to some extent also of compatible elements, is highly unsystematic in the eclogites and garnet-glaucophanites. Also, the more mobile elements display a wide scatter in all rocks. This, in conjunction with the unsystematic variation of Sr-isotopes, is thought to be due to secondary alteration. From the strong correlation of Ni and Cr with Mg# and the flat REE patterns lacking Eu-anomalies, a cumulus nature is inferred for olivine, clinopyroxene, and spinel, associated with intercumulus formation of plagioclase in the magmatic protoliths of the metagabbros. There is no direct genetic link between these rocks and the precursors of the Manna-type glaucophanites with REE characteristics typical of N- to T-type MORB. The extremely high geochemical diversity of the eclogites and garnet-glaucophanites from Syros favours individual evolution of their protoliths in small magma bodies as suggested for superferric eclogites from the Western and Ligurian Alps, as well as the ferrogabbros from the ophiolites of the Northern Apennines. From the geochemistry of the Syros metabasites along with the initial 87Sr/86Sr ratios of the metagabbros between 0.7031 and 0.7033, as well as an eNd value of 7.7 from a garnet glaucophanite, the magmatic protoliths are inferred to have formed in a back-arc setting. By analogy to the association of gabbros and ferrogabbros adjacent to the Atlantis II fracture zone of the SW Indian Ridge, we further suggest an origin at a spreading ridge in proximity to a transform fault.

Description: Test specimens of methane hydrate were grown under static conditions by combining cold, pressurized CH4 gas with H2O ice grains, then warming the system to promote the reaction CH4 (g) + 6H2O (s???l) ??? CH4??6H2O. Hydrate formation evidently occurs at the nascent ice/liquid water interface, and complete reaction was achieved by warming the system above 271.5 K and up to 289 K, at 25-30 MPa, for approximately 8 hours. The resulting material is pure methane hydrate with controlled grain size and random texture. Fabrication conditions placed the H2O ice well above its melting temperature before reaction completed, yet samples and run records showed no evidence for bulk melting of the ice grains. Control experiments using Ne, a non-hydrate-forming gas, verified that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting is easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably at temperatures well above its melting point. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T= 140-200 K, Pc= 50-100 MPa, and ????= 10-4-10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to a higher degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; x-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.

Description: Cyanobacteria are important constituents of most aquatic ecosystems on earth, and planktonic forms frequently show mass development in lakes and estuaries. Despite extensive scientific efforts directed towards research on cyanobacteria, a comprehensive theory explaining their success is lacking. Because cyanobacteria comprise a diverse group of organisms, it is concluded that any analysis of the conditions leading to cyanobacterial dominance in pelagic ecosystems should consider at least three different subgroups, classified based on presence or absence of (i) buoyancy regulation and (ii) the ability to fix molecular nitrogen. In this review, nine single-factor hypotheses regarding regulation of cyanobacterial development are examined against the background of physiological and ecological characteristics of these organisms. Special emphasis has been put on understanding differences in nitrogen metabolism between cyanobacteria and algae which directly relate to a hypothesis conceming inorganic nitrogen forms and cyanobacterial success previously presented by our research group. The review lends support to the theory that cyanobacteria have a low competitive ability for nitrate compared with algae and a high ability to compete for ammonium, particularly under nitrogen-limiting conditions. Finally it is concluded that to understand cyanobacterial devlopment and how high Standing Stocks in pelagic ecosystems are maintained requires parts o f all the single-factor hypotheses initially presented.

Description: We describe a new and efficient technique to grow aggregates of pure methane hydrate in quantities suitable for physical and material properties testing. Test specimens were grown under static conditions by combining cold, pressurized CH4 gas with granulated H2O ice, and then warming the reactants to promote the reaction CH4(g) + 6H2O(s→l) → CH4·6H2O (methane hydrate). Hydrate formation evidently occurs at the nascent ice/liquid water interface on ice grain surfaces, and complete reaction was achieved by warming the system above the ice melting point and up to 290 K, at 25−30 MPa, for approximately 8 h. The resulting material is pure, cohesive, polycrystalline methane hydrate with controlled grain size and random orientation. Synthesis conditions placed the H2O ice well above its melting temperature while reaction progressed, yet samples and run records showed no evidence for bulk melting of the unreacted portions of ice grains. Control experiments using Ne, a non-hydrate-forming gas, showed that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting are easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably to temperatures well above its ordinary melting point while reacting to form hydrate. Direct observations of the hydrate growth process in a small, high-pressure optical cell verified these conclusions and revealed additional details of the hydrate growth process. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T = 140−200 K, Pc = 50−100 MPa, and ε = 10-4−10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to an unusually high degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; X-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.

Description: The chemical composition of sediments from the Reykjanes Ridge is controlled by allochthonous and autochthonous processes. The surface sediments are characterized by relatively high contents of calciumoxide and strontium. Calcium and strontium dominate in the carbonate phase due to the high content of biogenic carbonate. A high percentage of iron and manganese are bound to oxides and hydroxides. An indication of hydrothermal activity was not observed. A considerable portion of adsorbed barium is transported in clay minerals. The higher amounts of aluminium in glacial sequences indicate an enhanced input of terrigenous material; the increase of stable bonding elemen~s points toward the large influence of detrital minerals. The distinct differences in the bonding characteristics of elements in these marine sediments in comparison to fluvial and coastal - deposits could be due to the different environmental conditions.

Description: Evolution of the Caribbean Plate can be modeled by motions about six successive rotation poles. Opening of Cayman Trough has occurred since 49.5 Ma through westward motion of the Caribbean Plate, eastern Greater Antilles and Chortis Block. Before 49.5 Ma, the eastern Greater-Antilles were west of Cuba, and the southeastern margins of Yucatan and the Nicaragua Rise (Chortis) were aligned. From 67.5 to 49.5 Ma the Caribbean Plate rotated clockwise, opening the Yucatan Basin. From 100 Ma to 67.5 Ma, the Caribbean Plate, with Cuba attached, moved along the southeastern margin of Yucatan-Chortis. At 130 Ma it was attached to northwestern South America.