ALBERT

Description: A non-Fickian physico-chemical model for electrolyte transport in high-ionic strength systems is developed and tested with laboratory experiments with copper sulfate as an example electrolyte. The new model is based on irreversible thermodynamics and uses measured mutual diffusion coefficients, varying with concentration. Compared to a traditional Fickian model, the new model predicts less diffusion and asymmetric diffusion profiles. Laboratory experiments show diffusion rates even smaller than those predicted by our non-Fickian model, suggesting that there are additional, unaccounted for processes retarding diffusion. Ionic diffusion rates may be a limiting factor in transporting salts whose effect on fluid density will in turn significantly affect the flow regime. These findings have important implications for understanding and predicting solute transport in geologic settings where dense, saline solutions occur.

Description: This review is intended to cover the principal developments that have occurred within the last six years in the paleomagnetic study of marine sediments. Recent work utilizing the reflecting-light microscope indicates that detrital high-temperature Fe-Ti oxides are probably responsible for most of the magnetic remanence in marine sediments. These minerals possess a spectrum of coercivities that makes it necessary to use alternating-field—demagnetization techniques to isolate stable components. It is possible to use the standard magnetic stratigraphy for the last 4 m.y. of earth history derived from terrestrial lavas. Using the ages of the magnetic boundaries from this time scale it is possible by extrapolation and interpolation to better determine the ages of the major events. The ages of these events in increasing age are Jaramillo, 0.87 to 0.92 m.y.; Olduvai, 1.71 to 1.86 m.y.; Kaena, 2.82 to 2.90 m.y.; Mammoth, 3.0 to 3.085 m.y.; Cochiti, 3.72 to 3.82 m.y.; Nunivak, 3.97 to 4.14 m.y.; ‘c’ event of the Gilbert series, 4.33 to 4.65 m.y. Through the use of long cores from the central Pacific and through correlation using fossil datums, it has been possible to extend the magnetic stratigraphy back to the upper middle Miocene to magnetic epoch 5. It is concluded that very short magnetic events are probably short-term excursions of the field and not true magnetic events. It is shown that the field of the earth averages to an axial-dipole field within a period of 27,000 years and that the field over the last two million years has acted as a geocentric axial dipole. The evidence shows that when reversals of the dipole occur, the values of the reversed inclination are not significantly different from the normal values. The use of magnetic stratigraphy in marine geology has opened up a new era in study of sedimentary processes and evolution of marine organisms.

Description: Grain‐size‐dependent flow mechanisms tend to be favored over dislocation creep at low differential stresses and can potentially influence the rheology of low‐stress, low‐strain rate environments such as those of planetary interiors. We experimentally investigated the effect of reduced grain size on the solid‐state flow of water ice I, a principal component of the asthenospheres of many icy moons of the outer solar system, using techniques new to studies of this deformation regime. We fabricated fully dense ice samples of approximate grain size 2±1 μm by transforming “standard” ice I samples of 250±50 μm grain size to the higher‐pressure phase ice II, deforming them in the ice II field, and then rapidly releasing the pressure deep into the ice I stability field. At T≤200 K, slow growth and rapid nucleation of ice I combine to produce a fine grain size. Constant‐strain rate deformation tests conducted on these samples show that deformation rates are less stress sensitive than for standard ice and that the fine‐grained material is markedly weaker than standard ice, particularly during the transient approach to steady state deformation. Scanning electron microscope examination of the deformed fine‐grained ice samples revealed an unusual microstructure dominated by platelike grains that grew normal to the compression direction, with c axes preferentially oriented parallel to compression. In samples tested at T≥220 K the elongation of the grains is so pronounced that the samples appear finely banded, with aspect ratios of grains approaching 50:1. The anisotropic growth of these crystallographically oriented neoblasts likely contributes to progressive work hardening observed during the transient stage of deformation. We have also documented remarkably similar microstructural development and weak mechanical behavior in fine‐grained ice samples partially transformed and deformed in the ice II field.

Description: The 1964 Alaskan earthquake (Ms ≈ 8.4) involved a segment of the eastern Aleutian arc 800 gm long; the 1960 Chilean earthquake sequence (Ms ≈ 8.5) affected roughly 100 km of the southern Peru-Chile arc. These two major events are strikingly similar in that (1) seismicity was shallow (〈70 km), the earthquake focal regions and most of the associated tectonic deformation being between the oceanic trenches and volcanic chains of the two arcs; (2) regional vertical displacements were characterized by broad asymmetric downwarps elongate parallel to the arcs with flanking zones of marked uplift on the seaward sides and minor, possibly local, uplift on the landward sides; and (3) horizontal displacements, where determined by retriangulation, involved systematic shifts in a generally seaward direction and transverse tensile strains across the zones of subsidence. Surface displacements and seismicity for both events are compatible with dislocation models involving predominantly dip-slip movement of 20 meters or more on major complex thrust faults (megathrusts) inclined at average angles of about 9° beneath the eastern Aleutian arc and perhaps 20° beneath the Peru-Chile arc. The thrust-fault mechanism deduced for both the Alaskan and Chilean earthquakes is broadly consistent with the concept that the sectors of the Pacific rim in which they occurred are major zones of convergence along which the oceanic plates progressively underthrust the less mobile America plate. Directions of convergence between lithospheric plates at these arcs as deduced primarily from paleomagnetic data are in reasonably good agreement with the observed earthquake-related deformation; the deduced rates of convergence, however, appear to be too high in the eastern Aleutian arc and too low in the southern Peru-Chile arc. Despite gross similarities in tectonic setting and the present style of earthquake-related deformation, the geologies of the continental margins in the eastern Aleutian arc and southern Peru-Chile arc differ significantly. This difference suggests that Mesozoic and Cenozoic sediments and volcanic rocks conveyed into the eastern Aleutian trench have progressively accreted to the Alaskan continental margin, whereas most or all of the material carried into the southern Peru-Chile trench has disappeared beneath the Chilean continental margin.

Description: Dissolved and atmospheric nitrous oxide (N2O) were measured on the legs 3 and 5 of the R/V Meteor cruise 32 in the Arabian Sea. A cruise track along 65°E was followed during both the intermonsoon (May 1995) and the southwest (SW) monsoon (July/August 1995) periods. During the second leg the coastal and open ocean upwelling regions off the Arabian Peninsula were also investigated. Mean N2O saturations for the oceanic regions of the Arabian Sea were in the range of 99–103% during the intermonsoon and 103–230% during the SW monsoon. Computed annual emissions of 0.8–1.5 Tg N2O for the Arabian Sea are considerably higher than previous estimates, indicating that the role of upwelling regions, such as the Arabian Sea, may be more important than previously assumed in global budgets of oceanic N2O emissions.

Description: This report includes discussions of elastic and viscoelastic models for water-saturated porous media, and measurements and computations of elastic constants including compressibility, incompressibility (bulk modulus), rigidity (shear modulus), Lamé's constant, Poisson's ratio, density, and compressional- and shear-wave velocity. The sediments involved are from three major physiographic provinces in the North Pacific and adjacent areas: continental terrace (shelf and slope), abyssal plain (turbidite), and abyssal hill (pelagic). It is concluded that for small stresses (such as from a sound wave), water-saturated sediments respond elastically, and that the elastic equations of the Hookean model can be used to compute unmeasured elastic constants. However, to account for wave attenuation, the favored model is ‘nearly elastic,’ or linear viscoelastic. In this model the rigidity modulus μ and Lamé's constant λ in the equations of elasticity, are replaced by complex Lamé constants (μ + iμ′) and (λ + iλ′), which are independent of frequency; μ and λ represent elastic response (as in the Hookean model), and iμ′ and iλ′ represent damping of wave energy. This model implies that wave velocities and the specific dissipation function 1/Q are independent of frequency, and attenuation in decibels per unit length varies linearly with frequency in the range from a few hertz to the megahertz range. The components of the water-mineral system bulk modulus are porosity, the bulk modulus of pore water, an aggregate bulk modulus of mineral grains, and a bulk modulus of the structure, or frame, formed by the mineral grains. Good values of these components are available in the literature, except for the frame bulk modulus. A relationship between porosity and dynamic frame bulk modulus was established that allowed computation of a system bulk modulus that was used with measured values of density and compressional-wave velocity to compute other elastic constants. Some average laboratory values for common sediment types are given. The underlying methods of computation should apply to any water-saturated sediment. If this is so, values given in this paper predict elastic constants for the major sediment types.

Description: The distributions and transports of deepwater masses at the western boundary in the tropical Atlantic off Brazil have been studied on three surveys along 35 degrees W and 5 degrees S and one at 10 degrees S. Transports are obtained from direct measurements of the velocity fields (Pegasus profiling system and lowered acoustic Doppler current profiler) and from geostrophic computations. Using chlorofluoromethane (CFM) and hydrographic distributions, four water masses could be identified forming the North Atlantic Deep Water (NADW) system. Two of these have a high CFM content, the ''shallow upper NADW'' (SUNADW) and the ''overflow lower NADW'' (OLNADW). These exhibit the highest velocity signals at 35 degrees W, where distinct flow cores seem to exist; most of the southeastward flow of the SUNADW (centered around 1600 m) occurs 320 km offshore between 3 degrees 09'S and 1 degrees 50'S (9.7 +/- 3.3 Sv); farther north in that section, a highly variable reversing flow is found in a second velocity maximum. The transport of OLNADW (centered around 3800 m) of 4.6 +/- 2.6 Sv is guided by the Parnaiba Ridge at 1 degrees 45'S, 35 degrees W. The water masses located between the two CFM maxima, the Labrador Sea Water (LSW) and the LNADW old water mass (LNADW-old), did not show any persistent flow features, however, a rather constant transport of 11.1 +/- 2.6 Sv was observed for these two layers. The total southeastward flow of the NADW at 35 degrees W showed a transport of 26.8 +/- 7.0 Sv, if one neglects the reversing SUNADW north of 1 degrees 50'S. At 5 degrees S the flow of all deepwater masses shows vertically aligned cores; the main southward transport occurred near the coast (19.5 +/- 5.3 Sv). The boundary current is limited offshore by a flow reversal, present in all three surveys, but located at different longitudes. At 10 degrees S a southward transport of 4.7 Sv was observed in November 1992. However, the section extended only to 32 degrees 30'W, so that probably a significant part of the flow has been missed. An important result is the large transport variability between single cruises as well as variability of the spatial distribution of the flow at 35 degrees W, which could lead to large uncertainties in the interpretation of single cruise observations. Despite these uncertainties we suggest a circulation pattern of the various deepwater masses near the equator by combining our mean transport estimates with other observations.

Description: During March 1994 a survey of the western boundary of the tropical Atlantic, between 10 degrees N and 10 degrees S, was carried out by conductivity-temperature-depth and current profiling using shipboard and lowered acoustic Doppler current profilers. In the near-surface layer, above sigma. = 24.5, the inflow into the boundary regime came dominantly from low latitudes; out of the 14 Sv that crossed the equator in the upper part of the North Brazil Current (NBC), only 2 Sv originated from south of 5 degrees S, while 12 Sv came in from the east at 1 degrees-5 degrees S with the South Equatorial Current (SEC). After crossing the equator near 44 degrees W, only a minor fraction of the near-surface NBC retroflected eastward, while a net through flow of about 12 Sv above sigma. = 24.5 continued northwestward along the boundary, By contrast, in the isopycnal range sigma. = 24.5-26.8 encompassing the Equatorial Undercurrent (EUC), the source waters of the equatorial circulation were dominantly of higher-latitude South Atlantic origin. While only 3 Sv of eastern equatorial water entered the region through the SEC at 3 degrees-5 degrees S, there was an inflow of 10 Sv of South Atlantic water in the North Brazil Undercurrent (NBUC) along the South American coast that originated south of 10 degrees S, The transport of 14 Sv arriving at the equator along the boundary in the undercurrent layer was almost entirely retroflected into the EUC with only marginal northern water additions along its path to 35 degrees W. The off-equatorial undercurrents in the upper thermocline, the South and North Equatorial Undercurrents carried only small transports across 35 degrees W, of 5 Sv and 3 Sv, respectively, dominantly supplied out of SEC recirculation rather than out of the boundary current. Still deeper, three zonal undercurrents were observed: the westward-flowing Equatorial Intermediate Current (EIC) in the depth range 200-900 m below the EUC, and two off-equatorial eastward undercurrents, the Northern and Southern Intermediate Countercurrents (NICC, SICC) at 400-1000 m and 1 degrees-3 degrees latitude. In the lower part of the NBUC there was an Antarctic Intermediate Water (AAIW) inflow along the coast of 6 Sv, and there was a clear connection at the AAIW level to the SICC by low salinities and high oxygens and a weaker suggestion also that some supply of the NICC might be through AAIW out of the deep NBUC.

Description: The modification of the exchange flow in a deep southern hemisphere passage, resembling the Vema Channel, by frictionally induced secondary circulation is investigated numerically. The hydrostatic primitive equation model is a two-dimensional version of the sigma-coordinate Princeton Ocean Model. The time dependent response of a stratified along-channel flow, forced by barotropic or baroclinic pressure gradients, is examined. Near the bottom, where the along-channel now is retarded, there is cross-channel Ekman nux that is associated with downwelling on the eastern side and upwelling on the western side of the channel. In the presence of stratification the cross-channel flow rearranges the density structure, which in turn acts on the along-channel velocity via the thermal wind relation. Eventually the cross-isobath Ekman flux is shut down. In the case of baroclinically driven flow of Antarctic Bottom Water through the Vema Channel the model reproduces the observed shape of the deep temperature profiles and their cross-channel asymmetry. The model offers an explanation that is alternative or supplementary to inviscid multilayer hydraulic theory that;was proposed in earlier studies. It explains the extremely thick bottom boundary layers in the center and on the western slope of the channel. The deep thermocline is spread out in the west and sharpened in the east, and the coldest water is found on the eastern side of the deep trough; The modified density field reduces the along-channel flow near the bottom and focuses it into a narrow jet on the eastern side of the channel.

Description: A theoretical model of CO2aq-dependent phytoplankton carbon isotope fractionation (єp) and abundance (δ13Corg) is compared to observed isotopic trends with temperature and [CO2aq] in the ocean. It is shown that the model's δ13Corg response to surface ocean temperature and to [CO2aq] can simulate observed trends when the other independent model variables (phytoplankton cell growth rate, cell size, cell membrane CO2 permeability, and enzymatic isotope fractionation) are held at realistic, constant values. The possible contribution made by each of these variables to the residual scatter in δ13Corg about its trends with temperature and [CO2aq] is quantified, thus estimating a maximum isotopic sensitivity to changes in each of these variables. The model response to growth rate and especially cell size, however, appears to be unrealistically high. This may occur because the net isotopic effects of such factors may be attenuated through dependent and isotopically offsetting variations among variables. The model's indicated sensitivity to such factors as CO2 permeability, enzymatic fractionation, cell size, and cell surface area/volume provides mechanisms whereby changes in species composition can play a significant role in affecting observed variations in oceanic δ13Corg. Overall, the model is consistent with earlier suggestions that marine δ13Corg and єp variability can be explained by carbon isotope fractionation evoked by CO2aq-dependent phytoplankton. This has important implications for interpreting carbon isotopic variability encountered in plankton and their organic constituents in the present-day ocean and in the marine sedimentary record.